US8518810B2 - Method for manufacturing a semiconductor device - Google Patents
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- US8518810B2 US8518810B2 US13/225,790 US201113225790A US8518810B2 US 8518810 B2 US8518810 B2 US 8518810B2 US 201113225790 A US201113225790 A US 201113225790A US 8518810 B2 US8518810 B2 US 8518810B2
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000004065 semiconductor Substances 0.000 title claims abstract description 41
- 230000001133 acceleration Effects 0.000 claims abstract description 52
- 239000012535 impurity Substances 0.000 claims abstract description 52
- 238000005468 ion implantation Methods 0.000 claims abstract description 41
- 150000002500 ions Chemical class 0.000 claims abstract description 25
- 230000005540 biological transmission Effects 0.000 claims abstract description 18
- 238000002834 transmittance Methods 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 3
- 238000005530 etching Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 230000007423 decrease Effects 0.000 abstract description 6
- 230000035515 penetration Effects 0.000 description 6
- 238000009825 accumulation Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
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- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/26506—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
- H01L21/26513—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors of electrically active species
- H01L21/2652—Through-implantation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/266—Bombardment with radiation with high-energy radiation producing ion implantation using masks
Definitions
- Embodiments described herein relate generally to a method for manufacturing a semiconductor device.
- a semiconductor device such as a solid-state image pickup device has been known, in which transfer registers are formed as a plurality of impurity layers extending in lines in such a manner that the impurity layers become deeper toward a transfer direction of charges.
- transfer registers are formed as a plurality of impurity layers extending in lines in such a manner that the impurity layers become deeper toward a transfer direction of charges.
- charges can be transferred efficiently, as well as the charges can be prevented from being transferred in a backward direction.
- these impurity layers can be formed using a grating mask in which light transmittance is different depending on positions. More specifically, a resist layer on a semiconductor substrate is exposed using the grating mask in which light transmittance is controlled so that the light transmittance gradually increases toward a transfer direction of charges. Subsequently, the exposed resist layers are developed. Then, residual resist films that have portions in which the film thickness gradually decreases toward the transfer direction of charges are formed. When ions are implanted into the semiconductor substrate using the residual resist films as a mask, impurity layers are formed in which the layers gradually become deeper toward the transfer direction of charges in accordance with the film thicknesses of the residual resist films.
- this conventional manufacturing method of the solid-state image pickup device has a problem in that the film thicknesses of the residual resist films greatly deviate from a desired film thickness.
- the depths of the impurity layers formed deviate from desired depths depending on the film thickness. Therefore, it is impossible to stably form impurity layers having a desired inner potential.
- step potential since a potential difference between inner potentials of adjacent impurity layers (step potential) changes, it impossible to stably obtain an effect of accumulating charges and preventing backward flow of the accumulated charges. Accordingly, the efficiency of charge transfer is deteriorated, and a solid-state image pickup device satisfying product characteristics cannot be formed.
- Embodiments of the present invention are described in view of resolving the above problem, and it is an object to provide a method for manufacturing a semiconductor device capable of satisfying desired product characteristics even if the film thicknesses of residual resist films vary.
- FIG. 1 is a top view illustrating an essential portion of a horizontal transfer register formed by a manufacturing method of a solid-state image pickup device according to the present embodiment
- FIG. 2 is a cross sectional view illustrating an essential portion of the horizontal transfer register taken along an alternate long and short dashed line A-A′ of FIG. 1 ;
- FIG. 3 is across sectional view, corresponding to FIG. 2 , for explaining the manufacturing method of the solid-state image pickup device according to the present embodiment and showing a step of forming a resist layer;
- FIG. 4 is a cross sectional view of the solid-state image pickup device, corresponding to FIG. 2 , for explaining a step of exposing the resist layer according to the manufacturing method of the present embodiment
- FIG. 5 is atop view illustrating a grating mask applied in the step shown in FIG. 4 ;
- FIG. 6 is a cross sectional view of the solid-state image pickup device, corresponding to FIG. 2 , for explaining a step of forming residual resist films according to the manufacturing method of the present embodiment
- FIG. 7 is a cross sectional view of the solid-state image pickup device, corresponding to FIG. 2 , for explaining a step of forming impurity layers according to the manufacturing method of the present embodiment
- FIG. 8 is an explanatory diagram for explaining a reference potential and a step potential
- FIG. 9 is a graph illustrating a first relationship between the film thickness of the residual resist film and an inner potential of an impurity layer formed by ion implantation via the residual resist films;
- FIG. 10 is a graph illustrating a relationship between an ion acceleration voltage and a linear limit/a penetration limit
- FIG. 11 is a graph illustrating a relationship between the acceleration voltage and the dose amount of ions required for obtaining a desired reference potential
- FIG. 12 is a graph illustrating a second relationship between the film thickness of the residual resist film and the inner potential of an impurity layer formed by ion implantation via the residual resist films.
- FIG. 13 is a graph illustrating a third relationship between the film thickness of the residual resist film and the inner potential of an impurity layer formed by ion implantation via the residual resist films.
- a method for manufacturing a semiconductor device includes the steps of forming a resist layer having a uniform film thickness on a semiconductor substrate, exposing the resist layer using an exposure mask having a plurality of transmission regions whose transmittances change toward a transfer direction of charges, developing the exposed resist layer and thereby forming a plurality of residual resist films whose film thicknesses change according to the transmittances of the exposure mask, and forming, within the semiconductor substrate, a plurality of impurity layers forming an inner potential having a predetermined reference potential and a predetermined step potential by implanting ions using an ion implantation device into the semiconductor substrate through the residual resist films, wherein an acceleration voltage and a dose amount of the ion implantation device are determined so that an error of the inner potential caused by an error of the film thicknesses of the residual resist films stays within a permissible range.
- a solid-state image pickup device produced by the method for manufacturing of the solid-state image pickup device according to the present embodiment includes a plurality of pixel unit each composed of a photodiode is arranged in a matrix form, a charge accumulation unit connected to the pixel unit for accumulating the charges generated by the pixel unit, and a CCD (Charge Coupled Device) transfer register for transferring the charges accumulated in the accumulation unit to an output unit.
- the CCD transfer register includes vertical transfer registers each connected to the charge accumulation unit and a horizontal transfer register connected to the vertical transfer registers.
- FIG. 1 is a top view illustrating an essential portion of the horizontal transfer register.
- FIG. 2 is a cross sectional view illustrating an essential portion of the horizontal transfer register taken along an alternate long and short dashed line A-A′ of FIG. 1 .
- a P-type well layer 12 in a belt shape is formed on a surface of an N-type semiconductor substrate 11 made of, e.g., silicon.
- an N-type semiconductor substrate 11 made of, e.g., silicon.
- a plurality of N+ type impurity layers 13 are arranged and formed in rows in a longitudinal direction of the well layer 12 .
- a first to a third impurity region 13 - 1 , 13 - 2 and 13 - 3 are arranged in this order along a direction opposite to a transmission direction of charges.
- the first impurity region 13 - 1 has a constant depth at the deepest portion.
- the third impurity region 13 - 3 has a constant depth at the shallowest portion, which is further explained later.
- the second impurity region 13 - 2 has a depth gradually decreasing from the deepest portion to the shallowest portion.
- the third impurity region 13 - 3 having a shallowest depth in each impurity layer 13 joins with the first impurity region 13 - 1 having a deepest portion of the adjacent impurity layer 13 at a surface of the well layer 12 .
- a plurality of transfer electrodes 15 made of, e.g., polysilicon, are arranged with an oxide film 14 interposed between the transfer electrodes 15 and the impurity region.
- Each of the transfer electrodes 15 is located over a part of the first impurity region 13 - 1 , the second impurity region 13 - 2 , and the third impurity region 13 - 3 .
- the oxide film 14 is made of, e.g., silicon oxide, uniformly formed on the semiconductor substrate 11 .
- each of this plurality of transfer electrodes 15 has the same width, which is arranged in parallel and spaced from each other, so as to cross the well layer 12 .
- clock pulses of positive and negative voltages are alternately applied to every other transfer electrodes 15 , which control a potential formed in each impurity layer 13 , thereby transferring the charges.
- the oxide film 14 is formed on the semiconductor substrate 11 on which the well layer 12 is formed, and subsequently, the resist layer 16 is uniformly formed on the oxide film 14 .
- the grating mask 17 has a plurality of transmission regions 17 A arranged in rows spaced apart from each other.
- the transmission region 17 A is a region in which the light transmittance continuously decreases toward the transfer direction of charges.
- FIG. 5 shows a top view of the grating mask 17 .
- the grating mask 17 applied in this step can control the amount of light transmission by arranging a light intercepting film in a form of a plurality of dots made of chromium film and the like on a surface of a substrate having light transmitting property such as glass plate.
- light intercepting films having a larger dot size may be arranged in regions where light transmittance is desirably reduced.
- the mask 17 applied in this step is obtained including the transmission region 17 A in which the light transmittance gradually decreases toward the transfer direction of charges.
- the transmission region 17 A may be realized by adjusting density of light intercepting films having the same dot size in a unit area of the grating mask. In this case, the arrangement density is increased in regions where light transmittance is desirably reduced.
- the resist layer 16 when the resist layer 16 is exposed to exposure light through the grating mask 17 shown in FIG. 5 , the amount of the exposure light corresponding to the transmittance of the transmission region 17 A is irradiated onto the resist layer 16 , so that the resist layer 16 hardens more in a portion where the amount of exposure light is high.
- the exposed resist layer 16 is developed. Therefore, the resist layer 16 that is not hardened in the exposure step is dissolved, whereby a plurality of residual resist films 18 having film thicknesses in accordance with the transmittances of the transmission regions 17 A of the grating mask 17 are formed, which are arranged in a row spaced from each other.
- Each residual resist film 18 formed in this step includes a first resist region 18 - 1 and a second resist region 18 - 2 .
- the film thickness of the first resist region 18 - 1 is continuously decreased toward the transfer direction of charges.
- the second resist region 18 - 2 is integrally formed with the portion of the first resist region 18 - 1 having a thickest portion and the second resist region 18 - 2 has a constant thickness corresponding to the thickest portion.
- the film thickness of the second resist region 18 - 2 can satisfy product characteristics of the solid-state image pickup device. The method for determining the film thickness will be explained later in detail.
- the same grating mask 17 is used multiple times to expose (shot) the region while the position of the mask 17 is moved.
- a so-called step exposure is employed.
- each shot is performed after the position of the grating mask 17 is aligned, but the positioning process inevitably involves a position error. If a resist film having a desired film thickness is provided between the pluralities of residual resist films 18 , the resist layer 16 corresponding to the position between the pluralities of residual resist films 18 is exposed twice due to the error of the position of the grating mask 17 .
- the first impurity region 13 - 1 that is formed by ions implanted through the resist film has a depth greatly different from a desired depth, which causes an inner potential, i.e., a reference potential Pb, to be greatly different from the desired value.
- the first impurity region 13 - 1 that is formed by ions implanted through a portion between the pluralities of residual resist films 18 can be formed with a stable depth regardless of the above problem. Therefore, this prevents the reference potential Pb from varying.
- the thickness of each residual resist film 18 involves an error as shown in FIG. 6 , due to variation of the amount of exposure light emitted by the exposure device, for example. Therefore, the film thicknesses of the pluralities of residual resist films 18 vary from film to film.
- FIG. 6 shows that the film thicknesses of the pluralities of residual resist films 18 greatly vary within the same shot in the step exposure. The variation of the film thickness of the residual resist film 18 occurs in the same manner in each of the pluralities of residual resist films 18 formed in each different shot. Further, the variation occurs in the same manner in the pluralities of residual resist films 18 formed on different wafers.
- an ion implantation device 19 implants N-type ions 20 such as phosphorous (P) into the well layer 12 using the pluralities of residual resist films 18 as a mask, as shown in FIG. 7 .
- the depths of the implanted ions 20 depend on the film thicknesses of the residual resist films 18 due to collision cross section and film thickness dependence. Accordingly, the impurity layers 13 are formed to have depths corresponding to the film thicknesses of the residual resist films 18 .
- the acceleration voltage and the dose amount of the ion implantation device 19 are set such that the variation of the inner potentials formed by the impurity layers 13 stays within a permissible range for the product.
- the method for deciding the acceleration voltage and the dose amount will be explained later in detail.
- the residual resist films 18 are removed, and the transfer electrodes 15 are formed at predetermined positions on each impurity layer 13 by patterning process, for example. Therefore, the horizontal transfer register as shown in FIG. 2 is formed.
- the method for deciding the acceleration voltage and the dose amount of the ion implantation device 19 and the method for deciding the film thickness of the second resist region 18 - 2 will be explained.
- the film thickness of the second resist region 18 - 2 will be referred to as the film thickness of the residual resist film 18 .
- FIG. 8 is a diagram for explaining the product characteristics of the solid-state image pickup device.
- a dotted line described in the lower part of the impurity layers 13 indicates the inner potential formed by the impurity layers 13 .
- the lower the dotted line goes, the higher the inner potential is.
- the product characteristics include a reference potential Pb and a step potential Ps.
- the reference potential Pb is the inner potential formed by the deepest portion of the second impurity region 13 - 2 .
- the step potential Ps is a difference between the reference potential Pb and the inner potential at the shallowest portion of the second impurity region 13 - 2 .
- the step potential Ps also varies according to this variation, but for this variation, a permissible range is defined for each product. This range is referred to as a permissible margin of the step potential Ps.
- the reference potential Pb is given by charge transfer capacity required by the product. When the charge transfer capacity is desired to be raised, the reference potential Pb may be set at a high level.
- the step potential Ps is given by the transfer efficiency that is required by the product.
- the transfer efficiency can be increased by increasing the step potential Ps.
- the acceleration voltage and the dose amount of the ion implantation device 19 are determined to satisfy the product characteristics on the basis of the relationship between the film thickness of the residual resist film 18 and the inner potential of the impurity layer 13 formed by ion implantation via the residual resist films 18 .
- FIG. 9 is a graph illustrating a first relationship between the film thickness of the residual resist film 18 and the inner potential of the impurity layer 13 .
- a dotted line in the figure is a graph for the case where the ion implantation is performed with an acceleration voltage of 320 kV.
- a solid line in the figure is a graph for the case where the ion implantation is performed with an acceleration voltage of 520 kV.
- the inner potential decreases as the film thickness of the residual resist film 18 increases regardless of the acceleration voltage.
- a rate of decrease of the inner potential (hereinafter referred to as slope of the graph) is different in some part according to the increase of the film thickness of the residual resist film 18 . This phenomenon is found by the inventors of the present application.
- the slope of the graph is constant within a range of the film thickness from 0 to 0.14 ⁇ m.
- the absolute value of the slope of the graph increases with the increase of the film thickness of the residual resist film 18 , when the film thickness becomes larger than 0.14 ⁇ m.
- the slope of the graph becomes zero, though it is not shown in the figure, when the film thickness of the residual resists film 18 further increases. This means that the implanted ions 20 no longer penetrate through the residual resist film 18 .
- the range of the film thickness where the slope of the graph is constant expands to a range of 0 to 0.42 ⁇ m.
- the absolute value of the slope of the graph increases as the film thickness of the residual resist film 18 increases, and when the film thickness of the residual resist film 18 is further increased, the smallest film thickness at which the slope of the graph becomes zero increases.
- the range of the film thickness of the residual resist film 18 in which the slope of the graph is constant is defined as a linear region L
- the maximum value of the linear region L is defined as a linear limit.
- the smallest film thickness of the residual resist film 18 at which the slope of the graph becomes zero is defined as a penetration limit. Accordingly, it is understood from FIG. 9 that when the acceleration voltage increases, the linear region L expands and the linear limit increases. When the acceleration voltage increases, the penetration limit also increases, which is not shown in the figure.
- FIG. 10 is a graph illustrating a relationship between the ion acceleration voltage of the ions 20 of the ion implantation device 19 and the linear limit/the penetration limit.
- a line A represents the linear limit
- a line B represents the penetration limit.
- the linear limit and the penetration limit increase in a linear manner as the acceleration voltage of the ions 20 increases. This phenomenon is also found by the inventors of the present application.
- FIG. 9 is referenced again.
- the method for deciding the acceleration voltage and the dose amount of the ion implantation device 19 and the method for deciding the film thickness of the residual resist film 18 are derived from FIG. 9 . More specifically, first, a temporary acceleration voltage and a temporary dose amount of the device are determined so that the reference potential Pb becomes 4.1 V before the appropriate acceleration voltage and the appropriate dose amount are ultimately derived.
- FIG. 11 is a graph illustrating a relationship between the acceleration voltage and the dose amount of ions required for obtaining the desired reference potential Pb.
- a line C represents a relationship therebetween that is needed to obtain a reference potential Pb of 2.5 V
- a line D represents a relationship therebetween that is needed to obtain a reference potential Pb of 3.5V
- a line E represents relationship therebetween that is needed to obtain a reference potential Pb of 4.5 V.
- the temporary acceleration voltage and the temporary dose amount may be determined on the basis of the relationships as shown in FIG. 11 .
- the temporary acceleration voltage may be set at 320 kV
- the temporary dose amount may be set at such dose amount that the reference potential Pb becomes 4.1 V as referred to FIG. 11 .
- the film thickness of the residual resist film 18 that is needed to obtain the desired step potential Ps is determined.
- the temporary film thickness of the residual resist film 18 that is needed to obtain a step potential Ps of 1.5 V is 0.28 ⁇ m.
- the absolute value of the slope of the graph at this film thickness is large, and the permissible variation of the film thickness of the residual resist film 18 for satisfying the permissible margin ⁇ 0.3 V of the step potential Ps is ⁇ 0.04 ⁇ m.
- the variation of the film thickness of ⁇ 0.08 ⁇ m could not be avoided.
- the variation of the inner potential according to the variation of the actual film thickness cannot be brought within the permissible margin. That is, when ion implantation is performed with the acceleration voltage and the dose amount of the ion implantation device 19 as described above, it is impossible to produce a product satisfying the required product characteristics.
- the acceleration voltage of the ion implantation device 19 is increased on the basis of the phenomenon found by the inventors of the present application. More specifically, the acceleration voltage of the ion implantation device 19 is set so that the variation of the inner potential according to the variation of the actual film thickness of the residual resist film 18 stays within the permissible margin of the step potential Ps.
- FIG. 9 shows that the acceleration voltage is, for example, 520 kV as shown by the solid line.
- the actual film thickness of the residual resist film 18 is determined.
- the solid line of FIG. 9 indicates that the actual film thickness of the residual resist film 18 that is needed to obtain the step potential Ps of 1.5 V is 0.46 ⁇ m.
- the absolute value of the slope of the graph at this film thickness is less than the absolute value of the slope of the graph at the temporary film thickness, and the permissible variation of the film thickness of the residual resist film 18 for satisfying the permissible margin ⁇ 0.3 V of the step potential Ps is expanded up to ⁇ 0.08 ⁇ m, which is equivalent to the variation of the actual film thickness of the residual resist film 18 . Therefore, the variation of the inner potential according to the variation of the actual film thickness can be brought within the permissible margin.
- the ion implantation is performed with the acceleration voltage and the dose amount of the ion implantation device 19 as described above, a product satisfying the required product characteristics can be produced.
- FIG. 12 is a graph illustrating a relationship between the film thickness of the residual resist film 18 and the inner potential of an impurity layer 13 .
- a dotted line in the figure is a graph of ion implantation with an acceleration voltage of 320 kV.
- a solid line in the figure is a graph of ion implantation with an acceleration voltage of 520 kV.
- the acceleration voltage is increased to 520 kV
- the ion implantation is performed with the acceleration voltage and the dose amount of the ion implantation device 19 as described above, a product satisfying the required product characteristics can be produced.
- FIG. 13 is a graph illustrating a relationship between the film thickness of the residual resist film 18 and the inner potential of the impurity layer 13 .
- a dotted line in the figure is a graph of ion implantation with an acceleration voltage of 320 kV.
- a solid line in the figure is a graph of ion implantation with an acceleration voltage of 520 kV.
- the acceleration voltage is increased to 520 kV
- the ion implantation is performed with the acceleration voltage and the dose amount of the ion implantation device 19 as described above, a product satisfying the required product characteristics can be produced.
- the acceleration voltage and the dose amount of the ion implantation device 19 and the film thickness of the residual resist film 18 are derived as described above.
- impurity layers 13 are formed by setting the acceleration voltage and the dose amount of the ion implantation device 19 so that the variation of the step potential Ps caused by the variation of the film thickness of the residual resist film 18 stays within the permissible range. Therefore, even when the film thicknesses of the residual resist films 18 vary, the solid-state image pickup device satisfying the product characteristics can be formed.
- the transfer efficiency of charges in the horizontal transfer register produced according to such method is 90% or more. As compared with the conventional transfer efficiency of 40% to 60%, the deterioration of the transfer efficiency can be prevented, and the transfer efficiency is greatly improved.
- the manufacturing method of the horizontal transfer register of the CCD transfer register in which the conductivity type of the impurity layer 13 is N-type has been explained.
- the manufacturing method of the solid-state image pickup device according to the present embodiment may be applied to a manufacturing method of a vertical transfer register.
- the method for manufacturing a solid-state image pickup device may be applied to a method for manufacturing a horizontal transfer register of a CCD transfer register in which the conductivity type of an impurity layer 13 is P-type.
- FIGS. 9 , 12 and 13 are modified to graphs, which are horizontally reversed with the same horizontal and vertical axes.
- FIGS. 10 and 11 become graphs in which the slopes are negative.
- the method for manufacturing a solid-state image pickup device may be applied to a method for manufacturing a CMOS transfer register.
- the conductivity type of each layer is not limited.
- the manufacturing method of the solid-state image pickup device according to the present embodiment can be applied to any method for manufacturing a semiconductor device as long as it includes a step of forming an impurity layer formed with a potential gradually getting deeper toward a transfer direction of charges.
- the resist layer 16 applied in the above embodiment is a negative-type resist layer.
- a positive resist layer may be employed as a resist layer.
- the grating mask 17 applied in the above embodiment with a reversed transmittance may be used as a grating mask for this case.
- the resist layer 16 may be made of a material whose dissolution shows a minor change with respect to an etching liquid. This prevents the film thickness of the resist film 18 from varying, and therefore, the deterioration of the transfer efficiency is reduced, and the transfer efficiency is greatly improved.
- a grating mask may be employed in which another transmission region is formed in a portion between a transmission region and a non-transmission region enclosing the transmission region, wherein another transmission region has a transmittance substantially between these transmittances of these regions. This prevents formation of a dip on the resist film 18 , and therefore, the deterioration of the transfer efficiency is further reduced, and the transfer efficiency is greatly improved.
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JP7325167B2 (ja) * | 2017-03-16 | 2023-08-14 | 富士電機株式会社 | 半導体装置の製造方法 |
CN109103082B (zh) * | 2018-08-06 | 2020-09-11 | 上海华虹宏力半导体制造有限公司 | 浮栅的制作方法和分裂栅闪存 |
US11862691B2 (en) | 2019-11-01 | 2024-01-02 | Raytheon Company | Field effect transistor having field plate |
CN112420718A (zh) * | 2020-11-18 | 2021-02-26 | 长江存储科技有限责任公司 | 半导体结构及其形成方法、对准方法 |
CN115079322B (zh) * | 2022-06-30 | 2024-03-12 | 歌尔光学科技有限公司 | 光栅结构及其加工方法、镜片及头戴显示设备 |
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JP2009170653A (ja) | 2008-01-16 | 2009-07-30 | Iwate Toshiba Electronics Co Ltd | 半導体装置の製造方法 |
US8307310B2 (en) * | 2009-01-28 | 2012-11-06 | Kabushiki Kaisha Toshiba | Pattern generating method, method of manufacturing semiconductor device, computer program product, and pattern-shape-determination-parameter generating method |
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JP3185339B2 (ja) * | 1992-03-19 | 2001-07-09 | ソニー株式会社 | 電荷結合素子の製造方法 |
JP2000260972A (ja) * | 1999-03-05 | 2000-09-22 | Toshiba Corp | 固体撮像装置およびその製造方法 |
JP2009212213A (ja) * | 2008-03-03 | 2009-09-17 | Iwate Toshiba Electronics Co Ltd | 半導体装置の製造方法 |
JP2010147252A (ja) * | 2008-12-18 | 2010-07-01 | Sharp Corp | イオン注入方法、および半導体装置の製造方法 |
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US6753948B2 (en) * | 1993-04-27 | 2004-06-22 | Nikon Corporation | Scanning exposure method and apparatus |
US20010011981A1 (en) * | 1996-12-27 | 2001-08-09 | Tsunenori Yamamoto | Active matrix addressed liquid crystal display device |
US6798509B2 (en) * | 2001-08-20 | 2004-09-28 | Hitachi, Ltd. | Methods and instruments for fluorescence detection |
JP2009170653A (ja) | 2008-01-16 | 2009-07-30 | Iwate Toshiba Electronics Co Ltd | 半導体装置の製造方法 |
US8307310B2 (en) * | 2009-01-28 | 2012-11-06 | Kabushiki Kaisha Toshiba | Pattern generating method, method of manufacturing semiconductor device, computer program product, and pattern-shape-determination-parameter generating method |
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JP5204184B2 (ja) | 2013-06-05 |
JP2012064861A (ja) | 2012-03-29 |
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