US7582592B2 - Skin cleansing composition comprising a polyoxyethylene alkylether sulfate, ether carboxylic acid-type surfactant, alkyl polyglycoside and a higher fatty acid or higher alcohol - Google Patents

Skin cleansing composition comprising a polyoxyethylene alkylether sulfate, ether carboxylic acid-type surfactant, alkyl polyglycoside and a higher fatty acid or higher alcohol Download PDF

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Publication number
US7582592B2
US7582592B2 US12/115,206 US11520608A US7582592B2 US 7582592 B2 US7582592 B2 US 7582592B2 US 11520608 A US11520608 A US 11520608A US 7582592 B2 US7582592 B2 US 7582592B2
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ingredient
skin cleansing
cleansing composition
composition according
carbon atoms
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US20090023623A1 (en
Inventor
Naoko Yamamoto
Masaki Shimizu
Natsuko Toshida
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Kao Corp
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Kao Corp
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to a skin cleansing composition.
  • Skin cleansing compositions are required to exhibit good lathering and to provide an excellent feeling in use.
  • JP-A-2006-206443 discloses that a skin cleansing composition, which contains a phosphate ester salt-type surfactant containing myristylphospholic acid ester salt, myristic acid or myristyl alcohol, and water and has a slightly acidic property, gives little skin irritation, shows good foamability, and produces fine, creamy and lubricious foam, and provides an excellent feeling in use.
  • the present invention provides a skin cleansing composition containing, in addition to water, the following ingredients (A) to (D):
  • a total amount of the ingredients (A), (B) and (C) ranges from 5 to 30 wt % based on the whole composition, with the ingredient (A) amounting to from 20 to 80 wt %, the ingredient (B) amounting to from 7 to 70 wt %, and the ingredient (C) amounting to from 7 to 70 wt %, the amount of the ingredient (D) ranges from 0.3 to 3 wt % based on the whole composition, and a pH of the composition ranges from 4.5 to 7 when diluted to 5 wt % with deionized water.
  • the skin cleansing composition according to the present invention can produce abundant foam of fine and smooth quality without an increase in foam viscosity.
  • a cleansing means especially a nylon towel or nylon sponge widely used by consumers, it, therefore, makes it possible to readily create foam and to wash the body with comfort.
  • the present invention relates to a skin cleansing composition, which can produce abundant foam of fine and smooth quality without an increase in foam viscosity and allows washing of the body with comfort.
  • a skin cleansing composition equipped with the above-described properties can be obtained by choosing a specific combination of surfactants from surfactants for cleansing compositions and using them in combination with a higher fatty acid and/or a higher alcohol in specific proportions.
  • R—O(CH 2 CH 2 O) n —SO 3 X wherein R represents an alkyl or alkenyl group having from 10 to 18 carbon atoms, n stands for a number of from 0.5 to 5 on average, and x represents a hydrogen atom, alkali metal, alkaline earth metal, ammonium or organic ammonium.
  • an alkali metal such as sodium or potassium
  • an alkaline earth metal such as calcium or magnesium
  • ammonium an ammonium derived from an alkanolamine such as monoethanolamine, diethanolamine or triethanolamine
  • a cation derived from a basic amino acid such as arginine or lysine
  • the ether carboxylic acid-type surfactant as the ingredient (B) is one of a class of compounds each containing a hydrophobic group and a carboxyl group via a polyoxyethylene chain or glycol ether unit.
  • examples include alkyl ether carboxylic acids or salts thereof, hydroxy ether carboxylic acids or salts thereof, and alkylamide ether carboxylic acids or salts thereof.
  • alkylether carboxylic acids or salts thereof are preferred in terms of feeling in rinsing. They can be represented by the following structural formulas, respectively.
  • R represents an alkyl or alkenyl group having from 10 to 18 carbon atoms
  • n stands for a number of from 0.5 to 10 on average
  • x represents a hydrogen atom, alkali metal, alkaline earth metal, ammonium or organic ammonium.
  • an alkali metal such as sodium or potassium
  • an alkaline earth metal such as calcium or magnesium
  • ammonium an ammonium derived from an alkanolamine such as monoethanolamine, diethanolamine or triethanolamine
  • a cation derived from a basic amino acid such as arginine or lysine
  • the alkyl polyglycosides as the ingredient (C) is a nonionic surfactant derived from a saccharide and a higher alcohol, and its examples include those represented by the following formula: R—O(CH 2 CH 2 O) m -Z x wherein R represents an alkyl group having from 8 to 20 carbon atoms, m stands for a number of from 0 to 10 on average, Z represents a saccharide residual group having 5 or 6 carbon atoms, and x stands for a number of from 1 to 5 on average.
  • R may more preferably be an alkyl group having from 9 to 15 carbon atoms, or a mixture of such alkyl groups.
  • Z pentose or hexose is more preferred, with glucose being even more preferred.
  • m may stand more preferably for a number of from 0 to 5 on average, and x may stand more preferably for a number of from 1 to 3 on average.
  • a total content of the ingredients (A), (B) and (C) is from 5 to 30 wt %, with a range of from 10 to 20 wt % being preferred from the viewpoints of the fineness of foam and the ease of creation of foam from a nylon towel or the like.
  • the individual ingredients (A), (B) and (C) can be broken down preferably into the ingredient (A): from 20 to 80 wt %, the ingredient (B): from 7 to 70 wt % and the ingredient (C): from 7 to 70 wt %, all based on the total amount of the ingredients (A), (B) and (C).
  • the higher fatty acid and/or higher alcohol as the ingredient (D) may be preferably those having from 10 to 18 carbon atoms, more preferably those having from 12 to 15 carbon atoms. It is even more preferred to use a higher fatty acid having from 10 to 18 carbon atoms and a higher alcohol having from 10 to 18 carbon atoms in combination.
  • the higher fatty acid and higher alcohol may be used at a weight ratio of preferably from 80:20 to 20:80, more preferably from 70:30 to 30:70 in that this weight ratio can produce fine foam and can avoid an increase in foam viscosity to permit easy creation of foam from a nylon towel or the like.
  • the ingredient (D) one or more of higher fatty acids and higher alcohols can be used. From the viewpoints of the volume and fineness of foam and the avoidance of an increase in foam viscosity to permit easy creation of foam from a nylon towel or the like, the ingredient (D) may be contained at preferably from 0.3 to 3 wt %, more preferably from 0.5 to 1.5 wt % in the whole composition.
  • the skin cleansing composition according to the present invention may further contain (E) an alkylglyceryl ether.
  • E an alkylglyceryl ether.
  • the incorporation of this additional ingredient is preferred from the standpoint of foamability performance.
  • alkylglyceryl ether monoglyceryl ether containing an alkyl or alkenyl group having from 4 to 12 carbon atoms is preferred, with a monoalkylglyceryl ether containing an alkyl group having from 6 to 10 carbon atoms being more preferred.
  • Preferred alkyl groups include n-hexyl, n-octyl, 2-ethylhexyl, and n-decyl.
  • one or more alkylglyceryl ethers can be used as the ingredient (E).
  • the ingredient (E) may be contained at preferably from 0.25 to 3 wt %, more preferably from 0.5 to 1.5 wt % in the whole composition.
  • the skin cleansing composition according to the present invention may also contain other surfactants employed in a usual cleansing composition.
  • surfactants employed in a usual cleansing composition.
  • Specific examples include an anionic surfactant such as alkylbenzenesulfonate, ⁇ -olefinsulfonate, alkanesulfonate, ⁇ -sulfo fatty acid ester salt, a monoalkyl phosphate ester salt and acyl-L-glutamate; a nonionic surfactant such as polyoxyalkylene alkyl ether, fatty acid mono- or di-alkanolamide, polyoxyalkylene block polymer, glycerin fatty acid ester; a cationic surfactant such as a quaternary ammonium salt; and an amphoteric surfactant such as carbobetaine, sulfobetaine, imidazolinium betaine, hydroxybetaine and fatty acid amidobetaine.
  • the skin cleansing composition according to the present invention may further contain various ingredients, which are commonly employed in cleansing compositions, as needed. It is possible to contain, for example, a humectant such as propylene glycol, dipropylene glycol, glycerin and sorbitol; a viscosity adjuster such as methylcellulose, polyoxyethylene glycol distearate; an antimicrobial agent such as triclosan and trichlorcarban; an anti-inflammatory such as potassium glycyrrhizinate and tocopherol acetate; a preservative such as methylparaben, butylparaben, phenoxyethanol and benzoate salts; and in addition, a colorant, a fragrance, an ultra violet absorber, an antioxidant and the like, as needed.
  • a humectant such as propylene glycol, dipropylene glycol, glycerin and sorbitol
  • a viscosity adjuster such as methylcellulose, polyoxyethylene glyco
  • the skin cleansing composition according to the present invention can be produced in a manner known per se in the art by weighing the ingredients and mixing them in a desired order in water or an aqueous medium composed mainly of water and containing another water-soluble solvent such as an alcohol. It can be applied as a body shampoo, facial wash, hand soap, cleansing preparation or the like.
  • the skin cleansing composition according to the present invention has a pH of from 4.5 to 7, preferably a pH of from 4.5 to 6.5 when diluted to 5 wt % with deionized water.
  • the adjustment to a pH in such a range is preferred, because the thus pH-adjusted skin cleansing composition is good in lathering, foam volume and foam quality and gives little skin irritation during cleansing.
  • the pH of the skin cleansing composition can be adjusted, as needed, with a pH adjuster such as an inorganic acid such as hydrochloric acid, sulfuric acid or phosphoric acid; an organic acid such as citric acid, succinic acid, lactic acid, malic acid, pyrrolidonecarboxylic acid, tartaric acid or glycolic acid; an acidic amino acid such as glutamic acid or aspartic acid; a hydroxide such as sodium hydroxide or potassium hydroxide; ammonia or aqueous ammonia; or a basic amino acid such as arginine or lysine.
  • a pH adjuster such as an inorganic acid such as hydrochloric acid, sulfuric acid or phosphoric acid
  • an organic acid such as citric acid, succinic acid, lactic acid, malic acid, pyrrolidonecarboxylic acid, tartaric acid or glycolic acid
  • an acidic amino acid such as glutamic acid or aspartic acid
  • a hydroxide such as sodium hydro
  • the skin cleansing composition according to the present invention may preferably be in a liquid form having a viscosity of not higher than 20,000 mPa ⁇ s, desirably not higher than 8,000 mPa ⁇ s at 25° C.
  • the above-described viscosity can be measured using a vibro-viscometer (manufactured by A & D Co., Ltd.; Model: “CVJ5000”, trade name).
  • Skin cleansing compositions of the formulas shown in Table 1 to Table 4 were produced. With respect to the skin cleansing compositions obtained, the pHs of these 5 wt % aqueous solutions were measured. Further, they were assessed for foam volume, foam fineness, the ease of creation of foam from a nylon towel and cleansing comfort. The results are also shown in Table 1 to Table 4.
  • the pH of each composition was measured at 25° C. using a pH meter (manufactured by Horiba, Ltd.; Model No.: “F-22”, trade name) after the composition was diluted to 20-fold with deionized water to obtain a 5 wt % aqueous solution.
  • Each composition was diluted with hard water (hardness: 4 mg/L) to 150-fold to provide a sample.
  • the sample (7.5 mL) was placed in a graduated 50-mL glass cylinder equipped with a stopper cock, and the stopper cock was placed thereon.
  • a shaker manufactured by Iwaki Sangyo K.K.; Model No.: “UNIVERSAL SHAKER V-SX”, trade name
  • the cylinder was shaken for 30 seconds at a rate of 300 strokes/min, and immediately after the completion of the shaking, the volume of foam was read.
  • the measurement results were ranked in accordance with the following assessment standards.
  • Each composition was diluted with hard water (hardness: 4 mg/L) to 10-fold to provide a sample.
  • the sample (7.5 mL) was placed in a graduated 50-mL glass cylinder equipped with a stopper cock, and the stopper cock was placed thereon.
  • the shaker manufactured by Iwaki Sangyo K.K.; Model No.: “UNIVERSAL SHAKER V-SX”, trade name
  • the cylinder was shaken for 30 seconds at a rate of 300 strokes/min, and immediately after the completion of the shaking, an image of the sample was captured ( ⁇ 50 magnification) by DSA (manufactured by Keyence Corporation; digital microscope; Model No.: “VHX-100”, trade name).
  • the particle sizes of 20 foam bubbles were measured, and their average was recorded as an average bubble size.
  • the measurement results were ranked in accordance with the following assessment standards.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
US12/115,206 2007-05-14 2008-05-05 Skin cleansing composition comprising a polyoxyethylene alkylether sulfate, ether carboxylic acid-type surfactant, alkyl polyglycoside and a higher fatty acid or higher alcohol Active US7582592B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007127840 2007-05-14
JP2007-127840 2007-05-14

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US7582592B2 true US7582592B2 (en) 2009-09-01

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US (1) US7582592B2 (enrdf_load_stackoverflow)
EP (1) EP1994922B1 (enrdf_load_stackoverflow)
JP (1) JP5685360B2 (enrdf_load_stackoverflow)
CN (1) CN101305970B (enrdf_load_stackoverflow)
TW (1) TWI434703B (enrdf_load_stackoverflow)

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CN101305970B (zh) 2011-12-28
TW200843799A (en) 2008-11-16
JP5685360B2 (ja) 2015-03-18
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EP1994922A1 (en) 2008-11-26
CN101305970A (zh) 2008-11-19

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