US7430049B2 - Method and device for analyzing the surface of a substrate - Google Patents
Method and device for analyzing the surface of a substrate Download PDFInfo
- Publication number
- US7430049B2 US7430049B2 US10/432,269 US43226904A US7430049B2 US 7430049 B2 US7430049 B2 US 7430049B2 US 43226904 A US43226904 A US 43226904A US 7430049 B2 US7430049 B2 US 7430049B2
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- substrate
- test pattern
- scanning
- variations
- image
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- Expired - Fee Related, expires
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/30—Measuring arrangements characterised by the use of optical techniques for measuring roughness or irregularity of surfaces
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/95—Investigating the presence of flaws or contamination characterised by the material or shape of the object to be examined
- G01N21/958—Inspecting transparent materials or objects, e.g. windscreens
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/24—Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures
- G01B11/25—Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures by projecting a pattern, e.g. one or more lines, moiré fringes on the object
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/95—Investigating the presence of flaws or contamination characterised by the material or shape of the object to be examined
- G01N21/956—Inspecting patterns on the surface of objects
Definitions
- the invention relates to a process and a device for scanning a surface of a shaped substrate, the said scan particularly allowing the detection of local defects and the three-dimensional measurement of the shape of a substrate having a reflective surface.
- the invention will be more particularly described with reference to scanning of the surface of windows and even more specifically to the scanning of curved windows intended for the automotive industry.
- the methods which are normally used consist in observing the laminated window in terms of transmission or reflection according to standardized methods, such as by visual observation outside the production line and after the assembly of the laminated window. As previously explained, such a check is too late and has an adverse effect upon production costs.
- the checking method is mechanical; sensors take punctual measurements so as to compare them to those of a template consistent with the idle time.
- this method constitutes a labour cost, in particular for the positioning of the sensors relative to each new window geometry to be checked, as well as a cost of supplies for the measurements, particularly the need for a distinct template for each window geometry, costs in which a reduction would be increasingly welcome.
- the inventors have thus set themselves the task of designing a method for scanning a surface, particularly a reflective surface, which does not have the drawbacks of the methods previously stated and, in particular, by which a reflective surface of a shaped substrate can be scanned in a precise and repetitive manner and by which, in particular, the costs of checking the consistency of windows on a production line are reduced.
- This object has been achieved according to the invention by the use of a process for scanning a surface of a substrate, which process consists in taking at least one reflected image of at least one test pattern on the said surface and extracting by digital processing local phases in two directions, characterized in that variations in local slopes are calculated by digital processing from the local phases in order to deduce therefrom variations in curvature or variations in altitude of the said surface.
- a first type of surface scan leads from the phase extraction to the resultant deduction of variations in local slopes, which variations, by means of a calculation by derivation, allow variations in local curvatures to be defined.
- Such a scan allows the presence of defects on the surface of a substrate to be determined.
- a second type of surface scan leads from the phase extraction to the resultant deduction of variations in local slopes, which variations, by means of a calculation by integration, allow altitude deviations to be defined in order to establish the variation in overall three-dimensional shape of the substrate.
- the image is taken reflected on a reflective surface.
- test pattern or test patterns a plurality being able to be used in the case of a complex surface
- the reflected image is taken instantaneously.
- the scanning method according to the invention envisages the adoption of a test pattern, the design of which can be deformed, whereby an image of the said test pattern can be obtained which is substantially less distorted than that of an ordinary test pattern owing to the curvature of a substrate when a rounded substrate is scanned.
- the invention can thus advantageously be applied to the scanning of rounded substrates, such as curved windows.
- the scan being usually effected on the convex surface of such curved windows, the process according to the invention envisages the use of a test pattern, the size of which is dictated by that of the window, bearing in mind that the captured image is that of the test pattern on a convex surface.
- a real or physical test pattern is envisaged, the size of which, as previously stated, is dictated by the size of the substrate and more particularly by its shape.
- Such a test pattern is more particularly suitable for taking an image on reflective surfaces.
- a virtual test pattern is used; this is constituted in this case, for example, by a projected test pattern, the image of which is preferably taken reflected on the substrate.
- a preferred embodiment of the invention consists in using a flat test pattern, the design of which is deformed.
- Another embodiment envisages a rounded test pattern; in this latter case, the design, which would be non-deformed if the test pattern were flat, is once again deformed such as envisaged by the invention. It is further possible to envisage a combination of these two embodiments, by realizing a rounded test pattern comprising a design which would already be deformed if the test pattern were flat.
- the test pattern is designed such as to compensate rigorously for the curvature of the scanned substrate.
- Such an embodiment is industrially conceivable in the case of a scanning of identical substrates.
- the production series relate to limited numbers of windows, whereas the number of windows which are different, and hence possess different curvatures, is very large.
- the inventors thus envisage a deformation of the design of the test pattern compatible with the scanning of several models of substrates having different curvatures.
- Tests have shown that the choice of a deformation of the design which does not allow strict compensation of the rounding of the substrate yielded precise and reliable scanning results; indeed, the deformation of the design of the test pattern according to the invention allows the at least partial compensation of the deformation of the image taken on the shaped substrate and thus allows satisfactory scanning in the zones of curvature and better scanning of the peripheral zones of the substrate.
- An advantageous realization of the invention envisages scanning of the substrate in dynamic state, that is to say in motion or in the course of deformation.
- the scanning is effected on a substrate moving past on a conveyor.
- the invention has the advantage of being able to be used to scan moving substrates. It therefore additionally offers an advantage in terms of productivity and production costs, owing to the speed of its execution.
- the substrate in travel on a conveyor is advantageously placed by mechanical positioning means in a position suitable for facilitating the digital processing, in particular for best realizing a comparison of the reflected image of the test pattern with a reference test pattern. Also, prior to carrying out the scan, the passing substrates are positioned identically in the two directions of the plane formed by the conveyor.
- the processing of the image according to the invention comprises several stages, in particular a stage of superimposing the reflected image of the test pattern onto a reference test pattern in such a way as to obtain a moiré, the phase extraction stage being realized, for example, according to a “phase stepping” method.
- phase stepping This method is described in the article “Design of algorithms for phase measurements by the use of phase stepping”, signed by Yves Surrel and published in Applied Optics Vol. 35, No. 1, dated 1 Jan. 1996.
- the stage following the extraction of local phases consists in comparing these phases to reference phases, deducing therefrom phase variations and correcting these phase variations through the use of a sensitivity factor s, which is heavily dependent upon the observation conditions and the measurement tools used, such as to calculate the variations in local slopes.
- the scan which is thus obtained according to the invention allows, in particular, a check to be made of the surface state of a substrate and, in addition, an overall scan to be made which allows measurement of the rounding of the substrate, that is to say the variation in three-dimensional shape of the substrate.
- the process thus described according to the invention allows the productivity and production costs of, in particular, curved windows to be further improved; indeed, the current requirements in relation to curving within the automotive industry are very demanding and call for rigorous checking.
- the methods currently used generally call for an off-line checking apparatus.
- the apparatuses allow either a checking of the periphery or, increasingly, a checking of the whole of the surface, required in order to meet the aesthetic requirements.
- the necessary apparatuses are therefore either mechanical sensors, which have a not insignificant cost, or a three-dimensional checking machine, in the most demanding cases, which makes use of a marble. In this latter case, the apparatus is dedicated to a single type of window and gives rise to a very considerable cost; in addition, the measurement times are very long.
- the scanning process according to the invention which allows the rounding to be checked, also has the advantage of carrying out a scan without contact and without any preparation of pre-treatment of the surface to be scanned. That procures a certain advantage in the production of a thin glass pane, that is to say having a thickness less than 2.5 mm. Indeed, such panes of glass are very sensitive to contact throughout the production phase and, if subjected to a contact, can find their rounding damaged during the checking.
- This process can equally well be applied to the checking of the rounding for toughened monolithic glasses, such as for the side windows or backlights of vehicles.
- the invention has a further advantage in the checking of thin glass panes; these thin glass panes can be intended, for example, for fitting in automotive vehicles to form side windows.
- the thin glass panes are put together in pairs using a plastics film, made of polyvinyl butyral (PVB) for example, to form a laminated window.
- PVB polyvinyl butyral
- the scanning process according to the invention which consists in obtaining an image of a glass pane, will allow the quality of the laminated window to be predicted through the use of mathematical modelling and, in particular, numerical calculation; indeed, the knowledge according to the process of the image of two panes of glass intended to be put together to form a laminated window will yield information regarding the optical quality of the laminated window.
- the process according to the invention thus allows laminated windows which are unacceptable in terms of their optical quality to be detected prior to their assembly.
- the invention thus prevents all recycling problems arising from the presence of two materials and it further improves, of course, the productivity of the production process for such laminated windows.
- the scanning process according to the invention is effected on a substrate in the course of deformation. According to such an application of the process according to the invention, it is possible to check the rounding of the substrate during the course of its deformation.
- the invention advantageously envisages this checking being carried out with reference to the concave face of the substrate, in particular when the said substrate is supported by mechanical tools during its deformation, for example by frames or rollers in the case of windows.
- the scan according to the invention will be carried out on the convex face of the substrate.
- the invention likewise proposes a device for realizing the process according to the invention.
- the device according to the invention comprises at least one camera, a flash-type pulse lighting, digital image-processing means and at least one test pattern, the projection of which covers the whole of the surface of the substrate, the design of the test pattern being able to be deformed in at least one direction.
- the camera is advantageously a digital camera; such a camera allows the digitalization to be made at the level of the CCD pick-up. That has the advantage that no analogue signal is transported by cables within which it can be damaged and, furthermore, deteriorations in the signal due to an analogue/digital conversion are likewise avoided.
- the pulse-type lighting is envisaged and is suitable for obtaining a clear image of the substrate in travel or in the course of deformation; advantageously, a laser or laser diode type lighting is used.
- the luminosity is chosen, moreover, so as to illuminate the whole of the surface of the test pattern in a homogeneous manner.
- the digital processing means are fit to generate a moiré and comprise algorithms for phase extraction calculation, for conversion calculation and for derivation or integration calculation.
- the device according to the invention when it relates to the scanning of a moving substrate, is advantageously used above a conveyor.
- This conveyor is preferably designed to offer a dark surface and thus to enhance the contrast of the image captured by the camera; the conveyor is constituted, for example, by a belt conveyor, of the carpet type, the colour of which is advantageously dark and preferably black.
- the conveyor has a very precise inherent flatness in order to define a precise supporting plane for the substrate to be measured.
- the camera is placed above the test pattern.
- the optical axis of the camera lens is normal to the surface of the substrate at the centre of the field of observation when a single test pattern is used; in other words, the direction of observation of the camera is normal to the surface of the substrate at the centre of the field of observation.
- the optical axis of the projector is parallel and close to the optical axis of the camera.
- mechanical positioning means are advantageously provided on the conveyor, which allow the substrate to be positioned in the two directions formed by the plane of the conveyor in a position suitable for facilitating the digital processing.
- These means are all means known to the person skilled in the art, for example systems of limit stops and/or guide rails.
- the device according to the invention when it relates to the scanning of a substrate in the course of deformation, is advantageously placed in a warm chamber, for example in the case of the curving of a window realized in just such a warm chamber. According to other processes for the curving of windows, the device is used at ambient temperature.
- the device thus described according to the invention can therefore be used to scan a surface, particularly a reflective surface, of a substrate, which is in particular shaped and preferably transparent.
- the invention first of all allows the state of such a surface to be checked and hence the defects to be scanned.
- a check can thus allow the origin of the defects to be understood and for these to be remedied by appropriate action upon the device or upon the production or forming process.
- the scanning of the surface of each of the monolithic windows will allow the optical quality of the laminated window to be predicted.
- the operation corresponds in this case to a numerical calculation based on the two images obtained and to an appropriate statistical processing.
- the invention can additionally allow measurement of the variation in overall three-dimensional shape of a shaped substrate.
- the scan which can be made in dynamic state, allows either the shape of the obtained substrate to be checked or the evolution of the shape to be checked when the scan is done in the course of deformation.
- the invention can also allow the inherent flatness of a substrate to be measured. Indeed, the knowledge of the scan according to the invention made of the surface of the substrate, which brings defects to light and yields its three-dimensional configuration, allows the inherent flatness of the said substrate to be checked for applications of flat substrates. Such checking of the inherent flatness is, for example, useful for window applications, for example in the building trade field. This checking of the inherent flatness becomes very important for other applications of windows, in particular in the field of visual display screens.
- the inherent flatness must be very strict, in particular in order to satisfy the manipulations to which the window is subjected during all the treatments effected for the purpose of realizing a screen; in order to prevent it being damaged during manipulations for leading the window from one treatment to another, the said window is transported by suction devices which limit the contacts and the assaults of tools on the glass. Manipulations of this type by the use of suction call for a perfect inherent flatness of the window in order to prevent any risk of fall of the transported window.
- the above-stated visual display screens are all types of screens which have to be subjected to treatments such as coating applications, engravings, etc. and are, for example, plasma screens, field emission displays (FED), micropoint screens.
- FED field emission displays
- a checking of the inherent flatness of a window can likewise be sought for the realization of vacuum windows or flat lamps, for which a limited and regular space is sought between two glass panes.
- a final advantage of the scanning method according to the invention for checking the inherent flatness of a substrate is that, as in the preceding cases, it can be carried out rapidly and, moreover, on substrates in travel, for example on a conveyor, and therefore without risk of lowering the production rates.
- FIG. 1 shows a diagram illustrating the scanning principle.
- FIG. 2 shows a diagram representing an application of the invention for checking window glazing.
- FIG. 1 represents a device illustrating the measurement principle according to the invention, resulting in an instantaneous image being taken of a test pattern 1 reflected on a substrate 2 .
- the image of the test pattern is, as previously stated, advantageously obtained with the aid of a CCD camera 3 in order to avoid all risks of damage to the captured signal.
- the test pattern 1 used is advantageously a flat, physical test pattern, the design of which can, for example, be deformed in that it contains shaped lines.
- the instantaneous image is advantageously obtained by the use of a flash-type lighting system 4 ; this is constituted, for example, by a laser diode.
- the test pattern 1 according to the invention particularly where a curved substrate 2 is scanned, has a design which is deformed such that the image of the test pattern captured in reflection on the said substrate displays quasi-parallel lines, these being strictly parallel given that the deformation of the design of the test pattern compensates for the rounding of the substrate.
- a deformation of the test pattern design is advantageously chosen which will produce satisfactory results in terms of scans for a range of substrates having different curvatures.
- the measurement is preferably realized on the convex face of the substrate, particularly in order to obtain a better contrast, and consequently calls for a test pattern of relatively large size such that its reflected image covers the whole of the surface of the substrate to enable the whole of the surface to be scanned.
- the image captured by the camera 3 is transmitted to a computer 5 in order to be processed, in a number of stages, by digital processing means.
- the image of the reflected test pattern taken by the camera is digitalized, it is superimposed onto a reference test pattern to form a moiré, the reference test pattern being able, for example, to be constituted by the pixels of the camera.
- a map is extracted of the local phases relating to the elementary areas of the surface of the substrate.
- the local phases are compared to memorized reference phases deriving from a measurement of a reference sample or from a calculation produced by CAD (computer-aided design), in order to deliver phase variations. From the phase variations, the variations in slopes are calculated by means of a sensitivity factor s, which is heavily dependent upon the observation conditions and the measurement tools used.
- the variations in local slopes are next used in a calculation by derivation algorithm or in a calculation by integration algorithm in order respectively to show the presence of surface defects 6 , 7 , the knowledge of which is obtained precisely in two directions, or to measure the variation in three-dimensional shape of the substrate.
- FIG. 2 represents a diagram of an installation which allows a scan according to the invention of the surface of a window 8 in travel on a conveyor 9 .
- the window 8 which arrives on the conveyor is first of all reorientated in a direction perpendicular to its direction of advancement on the conveyor 9 , with the aid of two guides 10 , 11 .
- These guides 10 , 11 will allow the window 8 to be orientated in the desired direction, the latter having already possessed an approximate orientation imposed when it was deposited onto the conveyor.
- the trajectory of the window 8 is next interrupted by two limit stops 12 supported by an arm 13 , the position of which can be altered in a vertical direction.
- the window 8 comes into contact with a first limit stop 12 , it is blocked at this point and the conveyor causes the said window to pivot until it comes into contact with the second limit stop 12 ; the window then finds itself reorientated, in its direction of advancement, in a predefined position suitable for best effecting the comparison of the reflected image of the screen pattern with the reference screen pattern.
- the device for lifting the arm 13 is next actuated such that the limit stops 12 no longer obstruct the passage of the window 8 , which thus continues its travel on the conveyor 9 .
- the device for lifting the arm 13 is advantageously actuated automatically as soon as the window 8 is in contact with the two limit stops 12 .
- the ascent of the limit stops 12 is designed to be very quick such that it does not risk damaging the window 8 , which has its convex surface upwards and is therefore higher in its centre than on the edge which was in contact with the limit stops 12 .
- the properly positioned window 8 then passes under a detector 14 , for example an optical detector, which will determine the moment of triggering of the flash attached to the capture of an image of the window 8 .
- This triggering of the flash occurs as soon as the window 8 is located beneath the test pattern 15 , such that the image captured by the camera 16 of the test pattern 15 reflected on the window covers the entirety of the convex surface of the said window 8 .
- the captured signal is next transmitted to a computer, in which it is processed according to the algorithms for “phase stepping”, conversion and derivation or integration calculation.
- the scanning method of the invention allows large surfaces of m 2 proportions, such as a window, to be scanned in dynamic state and with very good resolution in the order of 10 ⁇ m.
- results obtained lead to possible detection of the defects or to a knowledge of the rounding of the window. This information can then be used to intervene in stages in the window production process and to remedy the defects. In other cases and particularly for the realization of laminated windows, the results allow the quality of the window to be known in advance and possibly for the window not to be made if the optical properties are not satisfactory.
- the device described above has been adopted by way of example, but the tools used can be more numerous, for example several cameras and test patterns, in particular where it is a case of scanning complex shapes having, for example, different curvatures. These will be studied using several reflected images of a plurality of test patterns recorded by several cameras, the whole of the surface of the substrate having to be covered by reflected test patterns.
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Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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FR00/15050 | 2000-11-22 | ||
FR0015050A FR2817042B1 (fr) | 2000-11-22 | 2000-11-22 | Procede et dispositif d'analyse de la surface d'un substrat |
PCT/FR2001/003658 WO2002042715A1 (fr) | 2000-11-22 | 2001-11-21 | Procede et dispositif d'analyse de la surface d'un substrat |
Publications (2)
Publication Number | Publication Date |
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US20060050284A1 US20060050284A1 (en) | 2006-03-09 |
US7430049B2 true US7430049B2 (en) | 2008-09-30 |
Family
ID=8856740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US10/432,269 Expired - Fee Related US7430049B2 (en) | 2000-11-22 | 2001-11-21 | Method and device for analyzing the surface of a substrate |
Country Status (9)
Country | Link |
---|---|
US (1) | US7430049B2 (fr) |
EP (1) | EP1336076A1 (fr) |
JP (1) | JP2004514882A (fr) |
KR (1) | KR20030045196A (fr) |
CN (1) | CN100371677C (fr) |
AU (1) | AU2002218393A1 (fr) |
BR (1) | BR0115538A (fr) |
FR (1) | FR2817042B1 (fr) |
WO (1) | WO2002042715A1 (fr) |
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US20120207380A1 (en) * | 2009-10-21 | 2012-08-16 | Saint-Gobain Glass France | Method for analyzing the quality of a glazing unit |
US20120293808A1 (en) * | 2011-01-18 | 2012-11-22 | Arizona Board Of Regents On Behalf Of The University Of Arizona | System and method for non-contact metrology of surfaces |
US8415648B2 (en) | 2008-02-15 | 2013-04-09 | Pilkington Group Limited | Method of determination of glass surface shapes and optical distortion by reflected optical imaging |
US9470641B1 (en) | 2015-06-26 | 2016-10-18 | Glasstech, Inc. | System and method for measuring reflected optical distortion in contoured glass sheets |
US9841276B2 (en) | 2015-06-26 | 2017-12-12 | Glasstech, Inc. | System and method for developing three-dimensional surface information corresponding to a contoured glass sheet |
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FR3015033B1 (fr) | 2013-12-13 | 2015-12-04 | Saint Gobain | Procede et dispositif d'analyse de la surface d'un substrat |
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CN107707793A (zh) * | 2017-09-26 | 2018-02-16 | 浙江工业大学 | 一种用于表面特征检测的表面图像获取方法 |
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- 2001-11-21 CN CNB018193005A patent/CN100371677C/zh not_active Expired - Fee Related
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US7589844B2 (en) * | 2005-07-15 | 2009-09-15 | Asahi Glass Company, Limited | Shape inspection method and apparatus |
US20080316501A1 (en) * | 2005-07-15 | 2008-12-25 | Asahi Glass Company Limited | Shape inspection method and apparatus |
US8415648B2 (en) | 2008-02-15 | 2013-04-09 | Pilkington Group Limited | Method of determination of glass surface shapes and optical distortion by reflected optical imaging |
US8861831B2 (en) * | 2009-10-21 | 2014-10-14 | Saint-Gobain Glass France | Method for analyzing the quality of a glazing unit |
US20120207380A1 (en) * | 2009-10-21 | 2012-08-16 | Saint-Gobain Glass France | Method for analyzing the quality of a glazing unit |
US9068904B2 (en) * | 2011-01-18 | 2015-06-30 | Arizona Board Of Regents On Behalf Of The University Of Arizona | System and method for non-contact metrology of surfaces |
US20120293808A1 (en) * | 2011-01-18 | 2012-11-22 | Arizona Board Of Regents On Behalf Of The University Of Arizona | System and method for non-contact metrology of surfaces |
US9470641B1 (en) | 2015-06-26 | 2016-10-18 | Glasstech, Inc. | System and method for measuring reflected optical distortion in contoured glass sheets |
US9841276B2 (en) | 2015-06-26 | 2017-12-12 | Glasstech, Inc. | System and method for developing three-dimensional surface information corresponding to a contoured glass sheet |
US9846129B2 (en) | 2015-06-26 | 2017-12-19 | Glasstech, Inc. | System and method for measuring reflected optical distortion in contoured glass sheets |
US9851200B2 (en) | 2015-06-26 | 2017-12-26 | Glasstech, Inc. | Non-contact gaging system and method for contoured panels having specular surfaces |
US9933251B2 (en) | 2015-06-26 | 2018-04-03 | Glasstech, Inc. | Non-contact gaging system and method for contoured glass sheets |
US9952037B2 (en) | 2015-06-26 | 2018-04-24 | Glasstech, Inc. | System and method for developing three-dimensional surface information corresponding to a contoured sheet |
US9952039B2 (en) | 2015-06-26 | 2018-04-24 | Glasstech, Inc. | System and method for measuring reflected optical distortion in contoured panels having specular surfaces |
Also Published As
Publication number | Publication date |
---|---|
AU2002218393A1 (en) | 2002-06-03 |
WO2002042715A1 (fr) | 2002-05-30 |
FR2817042A1 (fr) | 2002-05-24 |
BR0115538A (pt) | 2003-09-02 |
JP2004514882A (ja) | 2004-05-20 |
US20060050284A1 (en) | 2006-03-09 |
CN1568419A (zh) | 2005-01-19 |
KR20030045196A (ko) | 2003-06-09 |
FR2817042B1 (fr) | 2003-06-20 |
EP1336076A1 (fr) | 2003-08-20 |
CN100371677C (zh) | 2008-02-27 |
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