US6310154B1 - Solid acids as catalysts for the preparation of hydrocarbon resins - Google Patents
Solid acids as catalysts for the preparation of hydrocarbon resins Download PDFInfo
- Publication number
- US6310154B1 US6310154B1 US09/003,596 US359698A US6310154B1 US 6310154 B1 US6310154 B1 US 6310154B1 US 359698 A US359698 A US 359698A US 6310154 B1 US6310154 B1 US 6310154B1
- Authority
- US
- United States
- Prior art keywords
- acid
- catalyst
- alumina
- solid acid
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 430
- 239000011973 solid acid Substances 0.000 title claims abstract description 134
- 239000013032 Hydrocarbon resin Substances 0.000 title claims abstract description 73
- 229920006270 hydrocarbon resin Polymers 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title description 14
- 239000000178 monomer Substances 0.000 claims abstract description 295
- 229920005989 resin Polymers 0.000 claims abstract description 224
- 239000011347 resin Substances 0.000 claims abstract description 224
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 105
- 239000002253 acid Substances 0.000 claims abstract description 96
- 238000006243 chemical reaction Methods 0.000 claims description 225
- 239000004927 clay Substances 0.000 claims description 113
- 238000000034 method Methods 0.000 claims description 101
- 239000002904 solvent Substances 0.000 claims description 89
- 230000008569 process Effects 0.000 claims description 87
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 78
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 71
- 239000007848 Bronsted acid Substances 0.000 claims description 59
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 48
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 40
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 37
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 32
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 32
- 239000011959 amorphous silica alumina Substances 0.000 claims description 26
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 25
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 25
- 238000001354 calcination Methods 0.000 claims description 25
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 25
- 239000000377 silicon dioxide Substances 0.000 claims description 24
- 239000010457 zeolite Substances 0.000 claims description 23
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical compound CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 claims description 22
- 238000001542 size-exclusion chromatography Methods 0.000 claims description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 19
- 239000002002 slurry Substances 0.000 claims description 18
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 16
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 16
- 229910017604 nitric acid Inorganic materials 0.000 claims description 16
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 13
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 13
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 claims description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 12
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 12
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 12
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 12
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 10
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 claims description 10
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 10
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 10
- QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims description 10
- 230000000379 polymerizing effect Effects 0.000 claims description 7
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- 150000004706 metal oxides Chemical class 0.000 claims description 6
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 6
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 claims description 5
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 5
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002734 clay mineral Substances 0.000 claims description 5
- -1 isoperene Chemical compound 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- QROGIFZRVHSFLM-QHHAFSJGSA-N [(e)-prop-1-enyl]benzene Chemical compound C\C=C\C1=CC=CC=C1 QROGIFZRVHSFLM-QHHAFSJGSA-N 0.000 claims description 4
- 229960000892 attapulgite Drugs 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 claims description 4
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 4
- 239000012013 faujasite Substances 0.000 claims description 4
- 229910000271 hectorite Inorganic materials 0.000 claims description 4
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 4
- 229960001545 hydrotalcite Drugs 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052622 kaolinite Inorganic materials 0.000 claims description 4
- 229910052680 mordenite Inorganic materials 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- 229910000275 saponite Inorganic materials 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 229940032330 sulfuric acid Drugs 0.000 claims 10
- 239000000047 product Substances 0.000 abstract description 50
- 238000006116 polymerization reaction Methods 0.000 abstract description 49
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract description 12
- 239000007787 solid Substances 0.000 abstract description 6
- 239000002685 polymerization catalyst Substances 0.000 abstract description 5
- 239000006227 byproduct Substances 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 173
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 102
- 239000000243 solution Substances 0.000 description 87
- 238000010926 purge Methods 0.000 description 81
- 239000003921 oil Substances 0.000 description 56
- 229910052757 nitrogen Inorganic materials 0.000 description 51
- 238000011068 loading method Methods 0.000 description 39
- 230000035484 reaction time Effects 0.000 description 33
- 239000003153 chemical reaction reagent Substances 0.000 description 32
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 30
- 230000000694 effects Effects 0.000 description 29
- 238000001914 filtration Methods 0.000 description 22
- 238000004821 distillation Methods 0.000 description 19
- 239000000203 mixture Substances 0.000 description 19
- 239000007789 gas Substances 0.000 description 18
- 239000002808 molecular sieve Substances 0.000 description 18
- 238000010992 reflux Methods 0.000 description 18
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 18
- 230000004044 response Effects 0.000 description 17
- 229910015900 BF3 Inorganic materials 0.000 description 15
- 150000001336 alkenes Chemical class 0.000 description 15
- 238000001816 cooling Methods 0.000 description 15
- 239000003208 petroleum Substances 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- 239000002841 Lewis acid Substances 0.000 description 14
- 150000007517 lewis acids Chemical class 0.000 description 14
- 125000003118 aryl group Chemical group 0.000 description 13
- 239000012065 filter cake Substances 0.000 description 13
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 12
- 239000012141 concentrate Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 10
- 239000012298 atmosphere Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000005984 hydrogenation reaction Methods 0.000 description 8
- 238000001256 steam distillation Methods 0.000 description 8
- 238000010538 cationic polymerization reaction Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000000539 dimer Substances 0.000 description 7
- 239000003348 petrochemical agent Substances 0.000 description 7
- 239000011949 solid catalyst Substances 0.000 description 7
- 150000003505 terpenes Chemical class 0.000 description 7
- 235000007586 terpenes Nutrition 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 239000003849 aromatic solvent Substances 0.000 description 6
- FKOASGGZYSYPBI-UHFFFAOYSA-K bis(trifluoromethylsulfonyloxy)alumanyl trifluoromethanesulfonate Chemical compound [Al+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F FKOASGGZYSYPBI-UHFFFAOYSA-K 0.000 description 6
- 239000012986 chain transfer agent Substances 0.000 description 6
- 239000011968 lewis acid catalyst Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 150000003839 salts Chemical group 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 5
- 238000000611 regression analysis Methods 0.000 description 5
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 239000003209 petroleum derivative Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 150000003738 xylenes Chemical class 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- 229920006272 aromatic hydrocarbon resin Polymers 0.000 description 3
- 238000010923 batch production Methods 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910001507 metal halide Inorganic materials 0.000 description 3
- 150000005309 metal halides Chemical class 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- FIPKSKMDTAQBDJ-UHFFFAOYSA-N 1-methyl-2,3-dihydro-1h-indene Chemical compound C1=CC=C2C(C)CCC2=C1 FIPKSKMDTAQBDJ-UHFFFAOYSA-N 0.000 description 2
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000005804 alkylation reaction Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000011280 coal tar Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 2
- PQNFLJBBNBOBRQ-UHFFFAOYSA-N indane Chemical compound C1=CC=C2CCCC2=C1 PQNFLJBBNBOBRQ-UHFFFAOYSA-N 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- NFWSQSCIDYBUOU-UHFFFAOYSA-N methylcyclopentadiene Chemical compound CC1=CC=CC1 NFWSQSCIDYBUOU-UHFFFAOYSA-N 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229930195734 saturated hydrocarbon Natural products 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- VCGRFBXVSFAGGA-UHFFFAOYSA-N (1,1-dioxo-1,4-thiazinan-4-yl)-[6-[[3-(4-fluorophenyl)-5-methyl-1,2-oxazol-4-yl]methoxy]pyridin-3-yl]methanone Chemical compound CC=1ON=C(C=2C=CC(F)=CC=2)C=1COC(N=C1)=CC=C1C(=O)N1CCS(=O)(=O)CC1 VCGRFBXVSFAGGA-UHFFFAOYSA-N 0.000 description 1
- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- CYJRNFFLTBEQSQ-UHFFFAOYSA-N 8-(3-methyl-1-benzothiophen-5-yl)-N-(4-methylsulfonylpyridin-3-yl)quinoxalin-6-amine Chemical compound CS(=O)(=O)C1=C(C=NC=C1)NC=1C=C2N=CC=NC2=C(C=1)C=1C=CC2=C(C(=CS2)C)C=1 CYJRNFFLTBEQSQ-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZQISRDCJNBUVMM-YFKPBYRVSA-N L-histidinol Chemical compound OC[C@@H](N)CC1=CNC=N1 ZQISRDCJNBUVMM-YFKPBYRVSA-N 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 241000779819 Syncarpia glomulifera Species 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- PHSMPGGNMIPKTH-UHFFFAOYSA-K cerium(3+);trifluoromethanesulfonate Chemical compound [Ce+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F PHSMPGGNMIPKTH-UHFFFAOYSA-K 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000007757 hot melt coating Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- XGVXKJKTISMIOW-ZDUSSCGKSA-N simurosertib Chemical compound N1N=CC(C=2SC=3C(=O)NC(=NC=3C=2)[C@H]2N3CCC(CC3)C2)=C1C XGVXKJKTISMIOW-ZDUSSCGKSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000009997 thermal pre-treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
- C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/003,596 US6310154B1 (en) | 1997-01-08 | 1998-01-07 | Solid acids as catalysts for the preparation of hydrocarbon resins |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3521797P | 1997-01-08 | 1997-01-08 | |
US3457997P | 1997-01-09 | 1997-01-09 | |
US3579797P | 1997-01-10 | 1997-01-10 | |
US09/003,596 US6310154B1 (en) | 1997-01-08 | 1998-01-07 | Solid acids as catalysts for the preparation of hydrocarbon resins |
Publications (1)
Publication Number | Publication Date |
---|---|
US6310154B1 true US6310154B1 (en) | 2001-10-30 |
Family
ID=27364695
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/003,594 Expired - Fee Related US6281309B1 (en) | 1997-01-08 | 1998-01-07 | Flourinated solid acids as catalysts for the preparation of hydrocarbon resins |
US09/003,596 Expired - Fee Related US6310154B1 (en) | 1997-01-08 | 1998-01-07 | Solid acids as catalysts for the preparation of hydrocarbon resins |
US09/003,879 Expired - Fee Related US6608155B2 (en) | 1997-01-08 | 1998-01-07 | Metal halide solid acids and supported metal halides as catalysts for the preparation of hydrocarbon resins |
US09/003,888 Expired - Fee Related US6133386A (en) | 1997-01-08 | 1998-01-07 | Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/003,594 Expired - Fee Related US6281309B1 (en) | 1997-01-08 | 1998-01-07 | Flourinated solid acids as catalysts for the preparation of hydrocarbon resins |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/003,879 Expired - Fee Related US6608155B2 (en) | 1997-01-08 | 1998-01-07 | Metal halide solid acids and supported metal halides as catalysts for the preparation of hydrocarbon resins |
US09/003,888 Expired - Fee Related US6133386A (en) | 1997-01-08 | 1998-01-07 | Metal oxide solid acids as catalysts for the preparation of hydrocarbon resins |
Country Status (9)
Country | Link |
---|---|
US (4) | US6281309B1 (de) |
EP (4) | EP0964844B1 (de) |
JP (4) | JP2001508102A (de) |
KR (4) | KR20000070007A (de) |
CN (4) | CN1249733A (de) |
AU (4) | AU5813398A (de) |
CA (4) | CA2277294A1 (de) |
DE (2) | DE69818018T2 (de) |
WO (4) | WO1998030519A1 (de) |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030069446A1 (en) * | 2000-03-27 | 2003-04-10 | Mohammed Belbachir | Composition and method for catalysis using bentonites |
US20060167434A1 (en) * | 2005-01-26 | 2006-07-27 | The Procter & Gamble Company | Disposable pull-on diaper having a low force, slow recovery elastic waist |
JP2006326469A (ja) * | 2005-05-25 | 2006-12-07 | Nippon Petrochemicals Co Ltd | 固体リン酸触媒およびそれを用いたオレフィンの二量化反応方法 |
WO2006135357A1 (en) * | 2005-06-08 | 2006-12-21 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
EP1882704A1 (de) * | 2006-07-26 | 2008-01-30 | Total Petrochemicals France | Verfahren zum Verringern von Rückständen in aromatische Polymere |
US20090157036A1 (en) * | 2007-12-13 | 2009-06-18 | Ekaterina Anatolyevna Ponomarenko | Absorbent Article With Composite Sheet Comprising Elastic Material |
US20090157035A1 (en) * | 2007-12-13 | 2009-06-18 | The Protect & Gamble Company | Absorbent Article with Composite Sheet Comprising Elastic Material |
US20090318884A1 (en) * | 2008-06-20 | 2009-12-24 | Axel Meyer | Absorbent structures with immobilized absorbent material |
US7717893B2 (en) | 2004-06-04 | 2010-05-18 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
US20100318049A1 (en) * | 2009-06-16 | 2010-12-16 | Axel Meyer | Absorbent Structures Including Coated Absorbent Material |
US7905872B2 (en) | 2004-06-04 | 2011-03-15 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate |
WO2012064908A1 (en) | 2010-11-12 | 2012-05-18 | The Procter & Gamble Company | Elastomeric compositions that resist force loss |
WO2012064909A1 (en) | 2010-11-12 | 2012-05-18 | The Procter & Gamble Company | Elastomeric compositions that resist disintegration |
US8323257B2 (en) | 2007-11-21 | 2012-12-04 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate and method for making the same |
US8419701B2 (en) | 2005-01-10 | 2013-04-16 | The Procter & Gamble Company | Absorbent articles with stretch zones comprising slow recovery elastic materials |
WO2013109673A2 (en) | 2012-01-18 | 2013-07-25 | Eastman Chemical Company | Low molecular weight polystyrene resin and methods of making and using the same |
US8828916B2 (en) | 2006-12-28 | 2014-09-09 | Chevron Oronite Company Llc | Method to prepare nonylated diphenylamine using recycle sequential temperatures |
EP2799606A1 (de) | 2013-05-03 | 2014-11-05 | Mondi Gronau GmbH | Elastisches Laminat |
WO2014179429A1 (en) | 2013-05-03 | 2014-11-06 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US9017305B2 (en) | 2010-11-12 | 2015-04-28 | The Procter Gamble Company | Elastomeric compositions that resist force loss and disintegration |
US9533067B2 (en) | 2013-05-03 | 2017-01-03 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US9687580B2 (en) | 2013-05-03 | 2017-06-27 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US10010645B2 (en) | 2013-05-03 | 2018-07-03 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US10851270B2 (en) | 2016-12-19 | 2020-12-01 | Eastman Chemical Company | Adhesives comprising polyindane resins |
US10959887B2 (en) | 2016-08-12 | 2021-03-30 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11008444B2 (en) | 2016-12-19 | 2021-05-18 | Eastman Chemical Company | Tires comprising polyindane resins and uses thereof |
US11944522B2 (en) | 2019-07-01 | 2024-04-02 | The Procter & Gamble Company | Absorbent article with ear portion |
Families Citing this family (66)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19704482A1 (de) * | 1997-02-06 | 1998-08-13 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
US6025534A (en) * | 1998-04-07 | 2000-02-15 | Bp Amoco Corporation | Olefin polymerization process |
DE19915108A1 (de) | 1999-04-01 | 2000-10-05 | Bayer Ag | Geträgerte Katalysatoren mit einer Donor-Akzeptor-Wechselwirkung |
US6346585B1 (en) * | 1999-06-24 | 2002-02-12 | The Lubrizol Corporation | Ammonium heteropolyacid catalized polymerization of olefins |
US6479598B1 (en) | 1999-07-20 | 2002-11-12 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with BF3 catalyst |
BR0013177A (pt) * | 1999-07-20 | 2002-04-02 | Exxonmobil Chem Patents Inc | Resinas de petróleo e sua produção com catalisador suportado |
US6265478B1 (en) | 1999-08-18 | 2001-07-24 | The Goodyear Tire & Rubber Company | Polymeric resinous material derived from limonene dicyclopentadiene indene and alpha-methyl styrene |
US6403743B1 (en) | 1999-09-14 | 2002-06-11 | Exxonmobil Chemical Patents Inc. | Petroleum resins and their production with supported catalyst |
JP3389176B2 (ja) * | 1999-11-17 | 2003-03-24 | 科学技術振興事業団 | 高分子担持ルイス酸触媒 |
US8168178B2 (en) | 1999-11-30 | 2012-05-01 | Curis, Inc. | Methods and compositions for regulating lymphocyte activity |
AU1935801A (en) * | 1999-11-30 | 2001-06-12 | Curis, Inc. | Methods and compositions for regulating lymphocyte activity |
SG97842A1 (en) * | 2000-02-02 | 2003-08-20 | Bp Amoco Corp | Olefin polymerization process |
JP2002079089A (ja) * | 2000-09-07 | 2002-03-19 | Showa Denko Kk | 低級脂肪族カルボン酸エステル製造用触媒、該触媒の製造方法、及び該触媒を用いた低級脂肪族カルボン酸エステルの製造方法 |
JP2002079088A (ja) * | 2000-09-07 | 2002-03-19 | Showa Denko Kk | 低級脂肪族カルボン酸エステル製造用触媒、該触媒の製造方法、及び該触媒を用いた低級脂肪族カルボン酸エステルの製造方法 |
US6677269B2 (en) * | 2001-05-17 | 2004-01-13 | George A Olah | Environmentally safe alkylation of aliphatic and aromatic hydrocarbons with olefins using solid HF-equivalent catalysts |
US6872692B2 (en) | 2001-09-21 | 2005-03-29 | Exxonmobil Research And Engineering Company | Synthetic hydrocarbon fluid |
US7145051B2 (en) * | 2002-03-22 | 2006-12-05 | Exxonmobil Chemical Patents Inc. | Combined oxydehydrogenation and cracking catalyst for production of olefins |
US7087803B2 (en) * | 2002-10-25 | 2006-08-08 | Haldor Topsoe A/S | Method for the recovery of perfluorinated sulphonic acid |
JP4041409B2 (ja) * | 2003-02-05 | 2008-01-30 | 独立行政法人科学技術振興機構 | 多環式芳香族炭素系固体強酸 |
WO2004071656A1 (en) * | 2003-02-05 | 2004-08-26 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
US7122492B2 (en) * | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
US7125817B2 (en) * | 2003-02-20 | 2006-10-24 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
US7122494B2 (en) * | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
US7122493B2 (en) * | 2003-02-05 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Combined cracking and selective hydrogen combustion for catalytic cracking |
US7119153B2 (en) | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
DE102005055818A1 (de) * | 2005-11-21 | 2007-05-24 | Basf Ag | Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe |
DE102006061204A1 (de) * | 2006-12-22 | 2008-06-26 | BSH Bosch und Siemens Hausgeräte GmbH | Bodendüse für Hartböden |
EP1900763A1 (de) * | 2006-09-15 | 2008-03-19 | Rütgers Chemicals GmbH | Verfahren zur Herstellung eines Kohlenwasserstoffharzes |
EP1900762A1 (de) * | 2006-09-15 | 2008-03-19 | Rütgers Chemicals GmbH | Verfahren zur Herstellung eines Kohlenwasserstoffharzes |
MX2009013178A (es) * | 2007-06-07 | 2010-02-17 | Albemarle Corp | Aductos, aductos y oligomeros o aductos, oligomeros y polimeros de bajo peso molecular asi como su preparacion. |
CN101743215A (zh) * | 2007-07-13 | 2010-06-16 | 皮拉莫医疗保健有限公司 | 1,2,2,2-四氟乙基二氟甲基醚(地氟烷)的制备方法 |
US8309780B2 (en) * | 2007-12-21 | 2012-11-13 | Exxonmobil Research And Engineering Company | Process for making olefin oligomers and alkyl benzenes in the presence of mixed metal oxide catalysts |
US8993684B2 (en) * | 2008-06-06 | 2015-03-31 | Albemarle Corporation | Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations |
US8642821B2 (en) * | 2008-12-02 | 2014-02-04 | Albemarle Corporation | Bromination of telomer mixtures derived from toluene and styrene |
EP2361269A1 (de) * | 2008-12-02 | 2011-08-31 | Albemarle Corporation | Verzweigte und sternverzweigte styrolpolymere, telomere und addukte, ihre synthese, bromierung und verwendung |
JO3423B1 (ar) * | 2008-12-02 | 2019-10-20 | Albemarle Corp | مؤخرات لهب معالجة بالبروم و مواد مشتقه منها |
WO2010065462A2 (en) * | 2008-12-02 | 2010-06-10 | Albemarle Corporation | Toluene and styrene derived telomer distributions and brominated flame retardants produced therefrom |
JO3059B1 (ar) | 2009-05-01 | 2017-03-15 | Albemarle Corp | معالجة بالبروم لتراكيب بوليمرات عطرية ذات وزن جزيئي منخفض |
WO2010127087A1 (en) | 2009-05-01 | 2010-11-04 | Albemarle Corporation | Pelletized low molecular weight brominated aromatic polymer compositions |
US8455415B2 (en) * | 2009-10-23 | 2013-06-04 | Exxonmobil Research And Engineering Company | Poly(alpha-olefin/alkylene glycol) copolymer, process for making, and a lubricant formulation therefor |
WO2011114707A1 (ja) * | 2010-03-17 | 2011-09-22 | 出光興産株式会社 | オレフィンのオリゴマー化反応用触媒 |
JP5838546B2 (ja) * | 2010-11-19 | 2016-01-06 | 東ソー株式会社 | 石油樹脂製造用ルイス酸性固体酸触媒の製造方法 |
JP2012107158A (ja) * | 2010-11-19 | 2012-06-07 | Tosoh Corp | 石油樹脂の製造方法 |
WO2012143281A1 (en) * | 2011-04-18 | 2012-10-26 | Solvay Specialty Polymers Usa, Llc | Process for the manufacture of dihalodiphenylsulfones |
US9388128B2 (en) | 2011-04-18 | 2016-07-12 | Solvay Speciality Polymers Usa, Llc | Process for the manufacture of dihalodiphenylsulfones starting from organic acids |
CN102399346A (zh) * | 2011-07-29 | 2012-04-04 | 长春工业大学 | 一种用于制备间戊二烯石油树脂的催化体系及制法 |
CN106311284A (zh) * | 2015-06-17 | 2017-01-11 | 江苏国立化工科技有限公司 | 一种固体酸催化剂及在合成橡胶防老剂dtpd中的应用 |
CN105482039B (zh) * | 2015-12-29 | 2017-10-24 | 广东工业大学 | 一种以c9馏分为原料制备石油树脂的方法 |
CN107022051B (zh) * | 2016-02-01 | 2019-07-09 | 江西福安路润滑材料有限公司 | 一种聚烯烃琥珀酰亚胺无灰分散剂及其制备方法与应用 |
CN106008817B (zh) * | 2016-06-26 | 2018-06-05 | 广西众昌树脂有限公司 | 石油树脂的改性方法 |
KR101959112B1 (ko) * | 2016-10-27 | 2019-03-15 | 한화토탈 주식회사 | 이소부텐을 포함한 c4 탄화수소 스트림으로부터 이소부텐 올리고머 제조방법 |
US10328422B2 (en) | 2017-04-21 | 2019-06-25 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Acidic catalyst |
WO2019158638A1 (de) * | 2018-02-14 | 2019-08-22 | Rütgers Germany GmbH | Verfahren zur herstellung von kohlenwasserstoffharzen und deren hydrierungsprodukte |
US11952319B2 (en) * | 2018-03-26 | 2024-04-09 | Phospholutions Inc. | Selecting and applying metal oxides and clays for plant growth |
CN108503743A (zh) * | 2018-04-11 | 2018-09-07 | 青岛海佳助剂有限公司 | 复合橡胶及其制备方法与用途 |
CN109180851B (zh) * | 2018-11-13 | 2020-08-14 | 南京工程学院 | 一种耐高温胍基强碱树脂及其制备方法 |
CN109553714B (zh) * | 2018-12-05 | 2022-01-11 | 江苏麒祥高新材料有限公司 | 一种用于提高橡胶抗湿滑性能的低聚物的制备方法 |
CN109824811A (zh) * | 2018-12-08 | 2019-05-31 | 濮阳班德路化学有限公司 | 一种α-甲基苯乙稀液体树脂的制备方法 |
CN109851715B (zh) * | 2019-01-26 | 2019-12-27 | 乐清市智格电子科技有限公司 | 一种加氢石油树脂及其制备方法 |
CN111234106A (zh) * | 2020-03-11 | 2020-06-05 | 恒河材料科技股份有限公司 | 一种液态改性芳烃石油树脂的制备方法 |
CN111548806B (zh) * | 2020-05-12 | 2021-06-01 | 天津大学 | 一种两段式处理碳氢燃料裂解炉内表面积碳的方法 |
US20230279194A1 (en) * | 2020-07-15 | 2023-09-07 | The Regents Of The University Of California | Process for catalytic upcycling of hydrocarbon polymers to alkylaromatic compounds |
CN114433229B (zh) * | 2020-10-20 | 2024-01-30 | 中国石油化工股份有限公司 | 一种用于制备碳酸亚烷酯的催化剂及其制备方法和应用 |
CN112279964A (zh) * | 2020-10-29 | 2021-01-29 | 遂川海州树脂有限公司 | 一种利用复合催化剂制备改性间戊二烯石油树脂的方法 |
WO2022235860A1 (en) * | 2021-05-06 | 2022-11-10 | Eastman Chemical Company | Recycle content c5 hydrocarbon resins and methods of making and using the same |
CN114289042B (zh) * | 2022-01-10 | 2023-05-30 | 万华化学集团股份有限公司 | 一种介孔固体酸催化剂、制备方法及其应用 |
Citations (332)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2301966A (en) | 1936-04-02 | 1942-11-17 | Michel Richard | Process for the manufacture of valuable products from olefins |
US2455225A (en) * | 1944-08-15 | 1948-11-30 | Pennsyivania Ind Chemical Corp | Method of making styrene resin |
US2460692A (en) * | 1943-06-24 | 1949-02-01 | Allied Chem & Dye Corp | Polymerization of resin oils with mixed clay and organic acid catalyst |
US2507864A (en) | 1947-03-25 | 1950-05-16 | Texas Co | Polymerization of olefins |
US2559576A (en) | 1947-06-25 | 1951-07-03 | Universal Oil Prod Co | Process for polymerization with tetraborohypophosphoric acid catalyst |
US2626291A (en) | 1950-10-19 | 1953-01-20 | Standard Oil Dev Co | Solid phosphoric acid slurry polymerization process |
US2626290A (en) | 1950-03-30 | 1953-01-20 | Standard Oil Dev Co | Process for polymerizing olefins with a phosphoric acid slurry catalyst |
US2632777A (en) | 1949-01-06 | 1953-03-24 | Universal Oil Prod Co | Production of hydrocarbon conjunct polymers |
US2642402A (en) | 1950-04-27 | 1953-06-16 | Standard Oil Dev Co | Olefin polymerization catalyst and its preparation |
US2694686A (en) | 1950-12-01 | 1954-11-16 | Standard Oil Dev Co | Phosphoric acid catalysts comprising a calcined silicon phosphoric base |
US2721889A (en) | 1950-07-28 | 1955-10-25 | Exxon Research Engineering Co | Olefin polymerization process |
US2728804A (en) | 1952-11-01 | 1955-12-27 | Exxon Research Engineering Co | Multi-stage polymerization process |
US2732398A (en) | 1953-01-29 | 1956-01-24 | cafiicfzsojk | |
US2734046A (en) | 1956-02-07 | Steam or | ||
US2739143A (en) | 1952-12-29 | 1956-03-20 | Exxon Research Engineering Co | Process for the preparation of polyisobutylene with a slurry catalyst |
US2744084A (en) | 1952-09-26 | 1956-05-01 | Exxon Research Engineering Co | Olefin polymerization process using hydrogenated naphtha solvent |
US2745890A (en) | 1952-03-29 | 1956-05-15 | Exxon Research Engineering Co | Process for production of polymer hydrocarbons |
US2748090A (en) | 1955-02-28 | 1956-05-29 | Universal Oil Prod Co | Manufacture of solid polymerization catalysts |
US2751331A (en) | 1951-11-13 | 1956-06-19 | Texas Co | Process for selectively polymerizing diolefins |
US2753382A (en) | 1952-12-01 | 1956-07-03 | Exxon Research Engineering Co | Polymers from piperylene concentrates |
US2753325A (en) | 1952-12-22 | 1956-07-03 | Exxon Research Engineering Co | Resins from selected distillates |
US2758143A (en) | 1951-10-01 | 1956-08-07 | Exxon Research Engineering Co | Olefin polymerization process |
US2766312A (en) | 1952-08-19 | 1956-10-09 | Exxon Research Engineering Co | Process for polymerizing olefins |
US2766311A (en) | 1952-08-28 | 1956-10-09 | Exxon Research Engineering Co | Combination catalytic polymerization process |
US2767234A (en) | 1952-11-01 | 1956-10-16 | Exxon Research Engineering Co | Multi-stage polymerization of olefins with suspended catalyst |
US2772317A (en) | 1952-03-28 | 1956-11-27 | Exxon Research Engineering Co | Polymerization catalyst and processes |
US2773051A (en) | 1953-07-03 | 1956-12-04 | Exxon Research Engineering Co | Preparation of resins from c5 fractions and cyclopentadiene dimers |
US2775577A (en) | 1952-12-23 | 1956-12-25 | Exxon Research Engineering Co | Controlled isobutylene polymerization |
US2778804A (en) | 1951-07-31 | 1957-01-22 | Exxon Research Engineering Co | Olefin polymerization catalyst and process |
US2779753A (en) | 1952-12-29 | 1957-01-29 | Exxon Research Engineering Co | Process for preparing high molecular polymers from isobutylene |
US2786878A (en) | 1954-06-08 | 1957-03-26 | Exxon Research Engineering Co | Olefin polymerization process |
US2816944A (en) | 1954-05-14 | 1957-12-17 | Exxon Research Engineering Co | Polymerization of liquid olefins in the presence of a boron fluoride-phosphoric acidcatalyst |
US2831037A (en) | 1954-06-01 | 1958-04-15 | Universal Oil Prod Co | Conversion of bicyclo-olefins |
US2833746A (en) | 1953-12-23 | 1958-05-06 | Ethyl Corp | Acrylonitrile-isobutylene-styrene interpolymer |
US2849428A (en) | 1953-06-24 | 1958-08-26 | Exxon Research Engineering Co | Process for the preparation of a dissolved aluminum chloride catalyst |
US2852580A (en) | 1955-09-26 | 1958-09-16 | Universal Oil Prod Co | Preparation of polyisoolefins |
US2878240A (en) | 1956-12-24 | 1959-03-17 | Universal Oil Prod Co | Polymerization of olefins to solid polymers |
US2887472A (en) * | 1954-09-30 | 1959-05-19 | Standard Oil Co | Production of solid polyethylene by a catalyst consisting essentially of an alkali metal and an adsorbent alumina-containing material |
US2906793A (en) | 1956-03-08 | 1959-09-29 | Exxon Research Engineering Co | Polymerization of isoolefins |
US2914517A (en) | 1956-12-24 | 1959-11-24 | Universal Oil Prod Co | Polymerization of olefins to solid polymers |
US2931792A (en) | 1956-02-02 | 1960-04-05 | Robert S Aries | Pyrophoric catalytic systems |
US2938018A (en) | 1957-11-22 | 1960-05-24 | Universal Oil Prod Co | Production of hard olefin polymers |
US2945845A (en) | 1958-04-28 | 1960-07-19 | Universal Oil Prod Co | Polymerization of olefins with complex catalyst comprising platinum or palladium |
US2976338A (en) | 1958-12-08 | 1961-03-21 | Exxon Research Engineering Co | Process and catalyst for polymerization |
US2987511A (en) | 1958-07-10 | 1961-06-06 | Universal Oil Prod Co | Process for polymerizing olefinic hydrocarbons |
US3000868A (en) | 1959-12-30 | 1961-09-19 | Pennsylvania Ind Chemical Corp | Vinyl toluene-alpha methyl styrene polymers |
US3006905A (en) | 1959-02-16 | 1961-10-31 | Universal Oil Prod Co | Preparation of copolymers |
US3006906A (en) | 1958-07-21 | 1961-10-31 | Universal Oil Prod Co | Preparation of polymers of isobutylene and an alkylene diamine |
US3017400A (en) | 1956-11-02 | 1962-01-16 | Universal Oil Prod Co | Polymerization of olefins |
US3024226A (en) | 1959-11-23 | 1962-03-06 | Texaco Inc | Polymerization process |
US3037970A (en) | 1959-02-16 | 1962-06-05 | Universal Oil Prod Co | Copolymer of an unsaturated side chain aromatic compound and an alkylene diamine |
US3054787A (en) | 1958-03-17 | 1962-09-18 | Dal Mon Research Co | Catalytic process |
US3109041A (en) | 1961-02-16 | 1963-10-29 | Texaco Inc | Polymerization of isobutylene |
US3112350A (en) | 1961-06-12 | 1963-11-26 | Universal Oil Prod Co | Polymerization of olefins using a solid phosphoric acid catalyst |
US3113165A (en) | 1960-09-01 | 1963-12-03 | Universal Oil Prod Co | Polymerization of unsaturated organic compounds |
US3128318A (en) | 1962-06-18 | 1964-04-07 | Universal Oil Prod Co | Alkali metal amide catalysts and their use in polymerizing olefins |
US3133127A (en) | 1961-11-10 | 1964-05-12 | Texaco Inc | Polymerization process |
US3136729A (en) * | 1960-06-16 | 1964-06-09 | Phillips Petroleum Co | Catalyst compositions and process of preparation |
US3154595A (en) | 1960-09-29 | 1964-10-27 | Universal Oil Prod Co | Olefin polymerization catalyzed by aminated alkali metal |
US3166545A (en) | 1961-04-06 | 1965-01-19 | Texaco Inc | Polymerization of isobutylene with an aluminum-titanium dioxide-titanium tetrachloride catalyst |
US3179649A (en) | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
US3190938A (en) | 1962-11-01 | 1965-06-22 | Exxon Research Engineering Co | Polymerization of olefins |
US3190936A (en) | 1961-02-16 | 1965-06-22 | Texaco Inc | Process for regenerating an adsorbent and a catalyst support in a polymerization operation |
US3221001A (en) | 1962-02-12 | 1965-11-30 | Exxon Research Engineering Co | Polymerization of ethylene in the presence of inorganic salt hydrates |
US3244768A (en) | 1964-10-19 | 1966-04-05 | Texaco Inc | Catalytic polymerization of propylene |
US3244767A (en) | 1964-01-24 | 1966-04-05 | Universal Oil Prod Co | Polymerization process using oxygenated sulfur-phosphoric acid catalyst |
US3248341A (en) | 1963-02-13 | 1966-04-26 | Universal Oil Prod Co | Method of admixing a phosphoric acid and an absorbent and precipitating with ammonia |
DE1963684U (de) | 1967-02-25 | 1967-07-06 | Agfa Gevaert Ag | Grundplatte fuer ein fotografisches vergroesserungsgeraet. |
US3347676A (en) | 1964-04-30 | 1967-10-17 | Du Pont | Photopolymerizable compositions and process |
US3364191A (en) | 1964-11-03 | 1968-01-16 | Universal Oil Prod Co | Olefin-aromatic hydrocarbon copolymers |
US3374285A (en) | 1964-12-29 | 1968-03-19 | Gulf Research Development Co | Process for the polymerization of propylene |
US3383378A (en) | 1964-04-22 | 1968-05-14 | Universal Oil Prod Co | Polymerization of ethylene |
US3418304A (en) | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
US3420809A (en) | 1966-08-12 | 1969-01-07 | Exxon Research Engineering Co | Catalyst for ethylene polymerization |
US3426007A (en) | 1965-10-21 | 1969-02-04 | Exxon Research Engineering Co | Polymerization catalyst system |
US3426089A (en) | 1966-08-30 | 1969-02-04 | Universal Oil Prod Co | Polymerization process |
US3427275A (en) | 1967-08-16 | 1969-02-11 | Reichhold Chemicals Inc | Vinyl aromatic-acrylic copolymers and process of producing the same |
US3457189A (en) | 1966-08-30 | 1969-07-22 | Universal Oil Prod Co | Fluorided refractory oxide catalyst and preparation thereof |
US3463744A (en) | 1968-06-03 | 1969-08-26 | Universal Oil Prod Co | Control of acid activity of a hydrocarbon conversion catalyst comprising a halogen component combined with a support containing alumina and crystalline aluminosilicate particles |
US3464929A (en) | 1968-05-09 | 1969-09-02 | Universal Oil Prod Co | Hydrocarbon conversion catalyst comprising a halogen component combined with a support containing alumina and finely divided crystalline aluminosilicate particles |
US3472791A (en) | 1966-09-12 | 1969-10-14 | Universal Oil Prod Co | Method of spherical catalyst preparation |
US3497568A (en) | 1967-09-29 | 1970-02-24 | Texaco Inc | Continuous process for polymerizing olefins |
US3499877A (en) | 1966-09-19 | 1970-03-10 | Standard Oil Co | Dimethyl alpha-methyl styrene polymers |
US3515769A (en) | 1967-06-30 | 1970-06-02 | Universal Oil Prod Co | Polymerization process |
US3555107A (en) | 1965-01-27 | 1971-01-12 | Texaco Inc | Hydrocarbon conversion process with a catalyst activated with an organic chloride and oxygen |
US3577400A (en) | 1968-08-26 | 1971-05-04 | Goodyear Tire & Rubber | Novel catalysts for the polymerization of alicyclic olefins |
US3586616A (en) | 1969-03-14 | 1971-06-22 | Minnesota Mining & Mfg | Bis(perfluoroalkylsulfonyl)methane metal salts in cationic polymerization |
US3597403A (en) | 1969-10-27 | 1971-08-03 | Goodyear Tire & Rubber | Novel catalysts for the ring-opening polymerization of unsaturated alicyclic compounds |
US3597406A (en) | 1969-04-30 | 1971-08-03 | Goodyear Tire & Rubber | Polymers of hydrocarbon substituted 1,5-cyclooctadienes and methods for their polymerization |
US3607959A (en) | 1967-06-16 | 1971-09-21 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3609098A (en) | 1969-08-21 | 1971-09-28 | Phillips Petroleum Co | Haloester and cuprous salt polymerization catalyst systems |
US3624060A (en) | 1969-01-31 | 1971-11-30 | Goodyear Tire & Rubber | Binary catalyst systems for the polymerization of unsaturated alicyclic monomers |
US3630981A (en) | 1969-06-09 | 1971-12-28 | Pennsylvania Ind Chemical Corp | Copolymers of alpha methyl styrene and vinyl toluene and process of preparation |
US3631212A (en) | 1970-04-20 | 1971-12-28 | Universal Oil Prod Co | Preparation of polyarylpolyalkanes |
US3640981A (en) | 1969-04-23 | 1972-02-08 | Reichhold Chemicals Inc | Vinyl toluene-alpha methyl styrene co-polymers and method of preparing the same |
US3644220A (en) | 1969-11-13 | 1972-02-22 | Exxon Research Engineering Co | Metal halide containing zeolites and method for their preparation |
US3652487A (en) | 1970-02-05 | 1972-03-28 | Goodyear Tire & Rubber | Process for the polymerization of alicyclic monomer masterbatches |
US3652706A (en) | 1969-09-16 | 1972-03-28 | Texaco Inc | Polymerization of olefins |
US3652707A (en) | 1969-09-16 | 1972-03-28 | Texaco Inc | Process for the polymerization of olefin hydrocarbons |
US3657208A (en) | 1970-11-02 | 1972-04-18 | Goodyear Tire & Rubber | Ternary catalyst systems for the polymerization of cyclic olefins |
US3657205A (en) | 1970-09-03 | 1972-04-18 | Goodyear Tire & Rubber | Preparation of high 1 4-polypentadienes |
US3661870A (en) | 1969-11-24 | 1972-05-09 | Goodyear Tire & Rubber | Isobutylene,1,3-butadiene,methyl butene copolymers |
US3669947A (en) | 1970-02-02 | 1972-06-13 | Velsicol Chemical Corp | Process for the production of alpha-methylstyrene polymer |
US3689434A (en) | 1968-07-29 | 1972-09-05 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3689471A (en) | 1968-08-26 | 1972-09-05 | Goodyear Tire & Rubber | Ternary catalyst systems for the polymerization of cycle olefins |
US3692695A (en) | 1970-06-25 | 1972-09-19 | Texaco Inc | Fluorided composite alumina catalysts |
US3692872A (en) | 1969-12-04 | 1972-09-19 | Goodyear Tire & Rubber | Preparation of graft, block and crosslinked unsaturated polymers and copolymers by olefin metathesis |
US3711425A (en) | 1970-06-25 | 1973-01-16 | Texaco Inc | Fluorided metal alumina catalysts |
US3717586A (en) | 1970-06-25 | 1973-02-20 | Texaco Inc | Fluorided composite alumina catalysts |
US3734866A (en) | 1967-06-26 | 1973-05-22 | Goodyear Tire & Rubber | Preparation of polymeric aromatic compositions |
US3746696A (en) | 1971-03-25 | 1973-07-17 | Goodyear Tire & Rubber | Catalyst systems for polymerizing alicyclic olefins |
US3753961A (en) | 1971-12-03 | 1973-08-21 | Goodyear Tire & Rubber | Resinous composition |
US3753962A (en) | 1970-03-16 | 1973-08-21 | Atlas Chem Ind | Recovery of a water soluble polymer powder from an aqueous gel of said polymer |
US3772255A (en) | 1972-06-07 | 1973-11-13 | Goodyear Tire & Rubber | Ring-opening polymerization of cycloolefins |
US3772401A (en) | 1971-10-27 | 1973-11-13 | Texaco Inc | Continuous 2-methyl-1-alkene polymerization process |
US3799913A (en) | 1971-12-30 | 1974-03-26 | Neville Chemical Co | Production of hydrocarbon resin compositions from alpha-methyl styrene,indene and vinyl toluene |
US3801559A (en) | 1965-04-16 | 1974-04-02 | Goodyear Tire & Rubber | Poly-1-chloro cyclooctadiene |
US3842019A (en) | 1969-04-04 | 1974-10-15 | Minnesota Mining & Mfg | Use of sulfonic acid salts in cationic polymerization |
US3867361A (en) | 1966-03-28 | 1975-02-18 | Goodyear Tire & Rubber | A process for the polymerization of cyclic olefins |
US3888789A (en) | 1972-12-15 | 1975-06-10 | Universal Oil Prod Co | Preparation of polymerization catalyst systems |
US3926882A (en) | 1973-11-23 | 1975-12-16 | Standard Oil Co | Alpha-methyl styrene/tertiary butyl styrene/olefin terepolymer resins and hot melt adhesives containing the same |
US3929737A (en) | 1974-09-30 | 1975-12-30 | Goodyear Tire & Rubber | Maleic anhydride-modified resin backbone |
US3932553A (en) | 1974-07-26 | 1976-01-13 | Exxon Research And Engineering Company | Oligomerization of propylene |
US3932332A (en) | 1973-02-16 | 1976-01-13 | Hercules Incorporated | Copolymers of alpha-methylstyrene and styrene and uses thereof |
US3935179A (en) | 1974-04-01 | 1976-01-27 | The Goodyear Tire & Rubber Company | Cycloolefin metathesis |
US3943116A (en) | 1974-06-21 | 1976-03-09 | The Goodyear Tire & Rubber Company | Method for preparing high cis polyalkenamers |
US3945986A (en) | 1974-04-01 | 1976-03-23 | The Goodyear Tire & Rubber Company | Metathesis of cycloolefins |
US3956250A (en) | 1969-06-09 | 1976-05-11 | Hercules Incorporated | Alpha methyl styrene and vinyl toluene and processes of preparation |
US3956180A (en) | 1970-12-28 | 1976-05-11 | Texaco Development Corporation | Hydrocarbon soluble molybdenum catalysts |
US3975336A (en) | 1973-05-14 | 1976-08-17 | The Goodyear Tire & Rubber Company | Polymers of nonconjugated 1,4-dienes |
US3980577A (en) | 1972-10-21 | 1976-09-14 | Sumitomo Chemical Company, Limited | Diphenylmethane electrophotographic liquid developer |
US3987109A (en) | 1972-12-27 | 1976-10-19 | Universal Oil Products Company | Polymerization of polyfunctional phenols |
US3992322A (en) | 1975-04-11 | 1976-11-16 | Universal Oil Products Company | Preparation of polymerization catalyst systems |
US3997471A (en) | 1974-04-01 | 1976-12-14 | The Goodyear Tire & Rubber Company | Cycloolefin metathesis catalyst |
US4009228A (en) | 1975-05-12 | 1977-02-22 | The Goodyear Tire & Rubber Company | Primary amine-modified anhydride resin |
US4010113A (en) | 1974-04-01 | 1977-03-01 | The Goodyear Tire & Rubber Company | Catalyst for metathesis of cycloolefins |
US4013736A (en) | 1975-07-16 | 1977-03-22 | Exxon Research And Engineering Company | Synthesis of low viscosity low pour point hydrocarbon lubricating oils |
US4020254A (en) | 1974-09-30 | 1977-04-26 | The Goodyear Tire & Rubber Company | Metathesis polymerization of cycloolefins |
US4028272A (en) | 1974-11-22 | 1977-06-07 | The Goodyear Tire & Rubber Company | Process of polymerization of conjugated diolefins using iron catalysts and sulfur ligands |
US4038471A (en) | 1976-10-29 | 1977-07-26 | The Goodyear Tire & Rubber Company | Method for preparing high-cis polyalkenamers |
US4048262A (en) | 1975-01-02 | 1977-09-13 | Chemische Werke Huls Aktiengesellschaft | Polydodecenamers as reinforcing resins for elastomers |
US4062801A (en) | 1975-08-11 | 1977-12-13 | Vop Inc. | Catalyst regeneration method |
US4063011A (en) | 1969-06-09 | 1977-12-13 | Hercules Incorporated | Alpha methyl styrene and vinyl toluene and processes of preparation |
US4064335A (en) | 1974-11-11 | 1977-12-20 | The Goodyear Tire & Rubber Company | Polymers of nonconjugated 1,4-dienes |
US4068062A (en) | 1975-07-30 | 1978-01-10 | Exxon Research And Engineering Company | Polymerizing C5 and C6 olefins and diolefins with 3° hydrocarbyl halide to produce narrow molecular weight petroleum resins having low softening points |
US4105843A (en) | 1976-04-15 | 1978-08-08 | Mitsui Petrochemical Industries Ltd. | Process for producing hydrocarbon resins having improved color and thermal stability by heat treatment with an α,βunsaturated anhydride |
US4108944A (en) | 1976-06-24 | 1978-08-22 | The Goodyear Tire & Rubber Company | Metal salts of modified anhydride resin |
US4127710A (en) | 1974-10-02 | 1978-11-28 | Phillips Petroleum Company | Copolymerization of a 1,3-cyclodiene and a linear conjugated diene |
US4130701A (en) | 1976-10-19 | 1978-12-19 | Exxon Research & Engineering Co. | Petroleum resins containing vinyl norbornene or tetrahydroindene |
US4133801A (en) | 1977-01-26 | 1979-01-09 | Teijin Limited | Process for the preparation of polyesters |
US4137390A (en) | 1977-09-07 | 1979-01-30 | The Goodyear Tire & Rubber Company | Process for the polymerization of cycloolefins |
DE2836982A1 (de) | 1977-08-25 | 1979-03-08 | Exxon Research Engineering Co | Elastomere co- oder terpolymere und verfahren zu ihrer herstellung |
US4153771A (en) | 1975-01-15 | 1979-05-08 | The Goodyear Tire & Rubber Company | Hydrocarbon resin prepared from antimony pentafluoride or ferric chloride |
US4168357A (en) | 1978-04-05 | 1979-09-18 | The Goodyear Tire & Rubber Company | Preparation of high cis-1,4-polypentadiene |
US4171414A (en) | 1977-08-25 | 1979-10-16 | Exxon Research & Engineering Co. | Catalyst composition for an improved polymerization process of isoolefins and multiolefins |
US4172932A (en) | 1977-09-07 | 1979-10-30 | The Goodyear Tire & Rubber Company | Process for the preparation of polymers of cyclopentene or copolymers of cyclopentene with unsaturated alicyclic compounds |
US4205160A (en) | 1976-03-11 | 1980-05-27 | The Goodyear Tire & Rubber Company | Indane containing polymers |
US4217409A (en) | 1977-05-12 | 1980-08-12 | Dai Nippon Insatsu Kabushiki Kaisha | Image forming material comprising polyacids of Mo or W or their salts or complexes |
US4230840A (en) | 1977-12-26 | 1980-10-28 | Mitsui Petrochemical Industries Ltd. | Process for producing hydrocarbon resins having improved color and thermal stability |
US4233139A (en) | 1978-07-25 | 1980-11-11 | Exxon Research & Engineering Co. | Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support |
US4239874A (en) | 1979-02-21 | 1980-12-16 | The Goodyear Tire & Rubber Company | Cyclopentene copolymerization process |
US4245075A (en) | 1978-06-27 | 1981-01-13 | Exxon Research & Engineering Co. | Carene modified petroleum resins |
US4248735A (en) | 1979-06-01 | 1981-02-03 | Phillips Petroleum Company | Treatment of silica |
SU859391A1 (ru) | 1976-02-24 | 1981-08-30 | Институт Химии Башкирского Филиала Ан Ссср | Способ получени окрашенного полимерного материала-полиметилметакрилата,полистирола или поливинилацетата |
US4294724A (en) | 1980-02-06 | 1981-10-13 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4296001A (en) | 1980-02-06 | 1981-10-20 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4299731A (en) | 1980-02-06 | 1981-11-10 | Phillips Petroleum Company | Large pore volume olefin polymerization catalysts |
US4301227A (en) | 1973-03-29 | 1981-11-17 | Sumitomo Chemical Company, Limited | Electrophotographic liquid developer |
US4301034A (en) | 1980-05-21 | 1981-11-17 | Phillips Petroleum Company | Silica from single phase controlled hydrolysis of silicate ester |
US4328090A (en) | 1980-07-31 | 1982-05-04 | Exxon Research & Engineering Co. | Process for production of hydrogenated hydrocarbon polymers and catalyst useful therefore |
US4339559A (en) | 1980-05-21 | 1982-07-13 | Phillips Petroleum Company | Polymerization using silica from single phase controlled hydrolysis of silicate ester |
US4345055A (en) | 1980-02-06 | 1982-08-17 | Phillips Petroleum Company | Polymerization with titanium impregnated silica-chromium catalysts |
US4347158A (en) | 1980-05-02 | 1982-08-31 | Dart Industries, Inc. | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4359406A (en) | 1977-06-17 | 1982-11-16 | Exxon Research And Engineering Co. | Highly dispersed supported group VIII metal-phosphorus compounds, and highly dispersed, supported group VIII metal-arsenic and a process for making said compounds |
US4363746A (en) | 1979-05-29 | 1982-12-14 | Phillips Petroleum Company | Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst |
US4364840A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Phosphated silica-chromium catalyst with boron-containing cocatalyst |
US4364841A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Phosphate containing support with zerovalent chromium |
US4364854A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Acid gelling aluminum phosphate from concentrated mass and catalyst containing same |
US4367352A (en) | 1980-12-22 | 1983-01-04 | Texaco Inc. | Oligomerized olefins for lubricant stock |
US4368303A (en) | 1980-02-06 | 1983-01-11 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4378306A (en) | 1981-09-17 | 1983-03-29 | Phillips Petroleum Company | Surface heat treatment of silica-containing catalyst base |
US4382022A (en) | 1981-11-25 | 1983-05-03 | Phillips Petroleum Company | Silica having titanium incorporated through use of peroxide |
US4384086A (en) | 1980-02-06 | 1983-05-17 | Phillips Petroleum Company | Large pore volume olefin polymerization catalysts |
US4391737A (en) | 1981-06-11 | 1983-07-05 | The Goodyear Tire & Rubber Company | Catalysts for ring-opening copolymerization of cycloolefins |
US4395578A (en) | 1982-06-18 | 1983-07-26 | Texaco, Inc. | Oligomerization of olefins over boron trifluoride in the presence of a transition metal cation-containing promoter |
US4397765A (en) | 1980-12-31 | 1983-08-09 | Phillips Petroleum Company | Phosphated alumina or aluminum phosphate chromium catalyst |
US4403088A (en) | 1982-08-05 | 1983-09-06 | The Goodyear Tire & Rubber Company | Plastic resin prepared from meta or para-diisopropenylbenzene and method of preparation |
USRE31443E (en) | 1977-12-05 | 1983-11-15 | Phillips Petroleum Company | Treatment of silica |
US4415715A (en) | 1981-06-11 | 1983-11-15 | The Goodyear Tire & Rubber Company | Catalysts for ring-opening copolymerization of cycloolefins |
US4419268A (en) | 1981-11-20 | 1983-12-06 | Phillips Petroleum Company | Partially hydrolyzed silicate treatment of catalyst support |
US4422957A (en) | 1980-05-02 | 1983-12-27 | Phillips Petroleum Company | Methods of producing polyolefins using supported high efficiency polyolefin catalyst components |
US4424320A (en) | 1981-11-25 | 1984-01-03 | Phillips Petroleum Company | Polymerization with a silica base catalyst having titanium incorporated through use of peroxide |
US4424139A (en) | 1982-03-30 | 1984-01-03 | Phillips Petroleum Company | Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
US4425257A (en) | 1980-05-02 | 1984-01-10 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4425226A (en) | 1982-12-10 | 1984-01-10 | Phillips Petroleum Company | Polymerization catalyst and deodorizing agent |
US4434243A (en) | 1982-03-09 | 1984-02-28 | Phillips Petroleum Company | Aqueous titanation of catalyst support containing chromium with solubilized Ti(OR)4 |
US4434280A (en) | 1981-09-17 | 1984-02-28 | Phillips Petroleum Company | Polymerization process using surface heat treated silica-containing catalyst base |
US4436948A (en) | 1982-09-07 | 1984-03-13 | Phillips Petroleum Company | Catalyst compositions |
US4439543A (en) | 1982-08-05 | 1984-03-27 | Phillips Petroleum Company | Co Reduced chromyl halide on silica catalyst |
US4442274A (en) | 1980-12-31 | 1984-04-10 | Phillips Petroleum Company | Polymerization process using a phosphate containing support for vanadium catalyst |
US4442275A (en) | 1982-03-09 | 1984-04-10 | Phillips Petroleum Company | Polymerization process using catalyst having aqueous titanation of support with solubilized Ti(OR)4 |
US4444966A (en) | 1982-05-05 | 1984-04-24 | Phillips Petroleum Company | Polymerization using phosphated alumina or aluminum phosphate chromium catalyst |
US4444968A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Olefin polymerization with phosphate supported zerovalent chromium |
US4444904A (en) | 1983-05-26 | 1984-04-24 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
US4444962A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Polymerization process using catalysts with acid gelled aluminum phosphate base |
US4454367A (en) | 1982-03-23 | 1984-06-12 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the low polymerization of isobutene |
US4520222A (en) | 1982-12-10 | 1985-05-28 | Phillips Petroleum Company | Polymerization catalyst and deodorizing agent and process of use |
US4520121A (en) | 1983-10-28 | 1985-05-28 | Inkrott Kenneth E | Magnesium halide hydrates and polymerization catalysts prepared therefrom |
US4536358A (en) | 1982-06-17 | 1985-08-20 | Uop Inc. | Process for the production of high surface area catalyst supports |
US4547474A (en) | 1979-03-26 | 1985-10-15 | Atochem | Supported superacidic catalysts based on C10 to C18 perfluorinated alkanesulfonic acids |
US4547479A (en) | 1984-07-02 | 1985-10-15 | Phillips Petroleum Company | Polyphosphate in chromium catalyst support |
US4555496A (en) | 1982-08-20 | 1985-11-26 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using the same |
US4558170A (en) | 1983-06-29 | 1985-12-10 | Exxon Research & Engineering Co. | Polyisobutylene process |
US4565795A (en) | 1979-12-07 | 1986-01-21 | Phillips Petroleum Company | Polymerization and catalysts |
US4567153A (en) | 1984-08-13 | 1986-01-28 | Exxon Research & Engineering Co. | Polymerization catalyst comprising copulverized solid magnesium compound and solid halide of scandium |
US4575538A (en) | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
US4588703A (en) | 1984-07-18 | 1986-05-13 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
US4596862A (en) | 1984-12-24 | 1986-06-24 | Phillips Petroleum Company | Olefin polymerization using chromium on fluorided aluminophosphate |
US4604438A (en) | 1985-08-12 | 1986-08-05 | Uop Inc. | High temperature thermoset terpolymers |
US4618661A (en) | 1980-05-02 | 1986-10-21 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4618595A (en) | 1984-12-12 | 1986-10-21 | Phillips Petrolem Company | Polymerization of olefins |
US4619980A (en) | 1985-04-01 | 1986-10-28 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
US4626519A (en) | 1985-09-06 | 1986-12-02 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using same |
EP0101205B1 (de) | 1982-08-13 | 1987-01-07 | Exxon Research And Engineering Company | Verfahren zur Herstellung von Polyisobutylen |
US4677174A (en) | 1986-04-21 | 1987-06-30 | American Colloid Company | Water absorbent styrene-acrylic acid copolymers |
US4680351A (en) | 1985-09-06 | 1987-07-14 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using same |
US4681866A (en) | 1985-04-01 | 1987-07-21 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
US4684707A (en) | 1986-02-10 | 1987-08-04 | Exxon Chemical Patents Inc. | Low color, high softening point aromatic resin and method for its production |
US4686092A (en) | 1984-04-13 | 1987-08-11 | Union Carbide Corporation | Manganese-aluminum-phosphorus-silicon-oxide molecular sieves |
US4689436A (en) | 1985-05-13 | 1987-08-25 | Idemitsu Kosan Company Limited | Process for producing alkenyl-aromatic hydrocarbon derivatives |
US4699962A (en) | 1984-01-30 | 1987-10-13 | Phillips Petroleum Company | Olefin polymerization |
US4711866A (en) | 1986-02-05 | 1987-12-08 | Exxon Chemical Patents Inc. | Adamantane polymerization catalyst |
US4719190A (en) | 1986-10-22 | 1988-01-12 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
US4719271A (en) | 1982-05-21 | 1988-01-12 | Phillips Petroleum Company | Polymerization of olefins |
US4721559A (en) | 1986-10-17 | 1988-01-26 | Olah George A | Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US4732936A (en) | 1984-11-20 | 1988-03-22 | Hercules Incorporated | Alpha methylstyrene and para methylstyrene copolymers |
US4744970A (en) | 1984-04-13 | 1988-05-17 | Union Carbide Corporation | Cobalt-aluminum-phosphorus-silicon-oxide molecular sieves |
US4757044A (en) | 1985-04-17 | 1988-07-12 | The Standard Oil Company | Lanthanide metal salts of heteropolyanions as catalysts for alcohol conversion |
US4780513A (en) | 1982-09-30 | 1988-10-25 | Exxon Research & Engineering Co. | Modified Lewis acid catalyzed polymerization |
US4788171A (en) | 1987-02-02 | 1988-11-29 | Philips Petroleum Company | Phosphated calcined alumina |
US4791086A (en) | 1984-01-30 | 1988-12-13 | Phillips Petroleum Company | Olefin polymerization |
US4793833A (en) | 1984-04-13 | 1988-12-27 | Uop | Manganese-aluminum-phosphorus-silicon-oxide molecular sieves |
US4801364A (en) | 1983-07-15 | 1989-01-31 | Uop | Separation and conversion processes using metal aluminophosphates |
US4814308A (en) | 1986-10-21 | 1989-03-21 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
US4822707A (en) | 1984-07-30 | 1989-04-18 | Ricoh Co., Ltd. | Positively chargeable toners for use in dry type electrophotography comprising a blue dye lake charge control agent |
US4824554A (en) | 1984-04-13 | 1989-04-25 | Uop | Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions |
US4824921A (en) | 1983-06-28 | 1989-04-25 | Exxon Research & Engineering Company | Petroleum resins and their production |
US4843133A (en) | 1979-12-07 | 1989-06-27 | Phillips Petroleum Company | Polymerization and catalysts |
US4846956A (en) | 1984-04-13 | 1989-07-11 | Uop | Manganese-aluminum-phosphorus-silicon-oxide Molecular sieves |
US4846066A (en) | 1986-08-29 | 1989-07-11 | Ici Australia Operations Proprietary Limited | Detonator system |
US4849572A (en) | 1987-12-22 | 1989-07-18 | Exxon Chemical Patents Inc. | Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647) |
US4868343A (en) | 1986-04-16 | 1989-09-19 | Catalytica Inc. | Acid catalyzed process |
EP0202965B1 (de) | 1985-04-09 | 1989-09-27 | Kawasaki Steel Corporation | Oligomere Harze und Verfahren zu deren Herstellung |
US4879425A (en) | 1988-05-26 | 1989-11-07 | Phillips Petroleum Company | Oligomerization of olefins |
US4894213A (en) | 1984-04-13 | 1990-01-16 | Uop | Arsenic-aluminum-phosphorus-silicon-oxide molecular sieve compositions |
US4900704A (en) | 1988-09-29 | 1990-02-13 | Phillips Petroleum Company | Peptized and phosphated inorganic oxides and catalysts supported on said oxides |
US4912279A (en) | 1988-12-29 | 1990-03-27 | Uop | Solid phosphoric acid catalyst |
US4929800A (en) | 1986-10-22 | 1990-05-29 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
US4935576A (en) | 1988-11-25 | 1990-06-19 | Exxon Chemical Patents Inc. | Polybutene process |
US4948768A (en) | 1988-05-26 | 1990-08-14 | Phillips Petroleum Company | Catalyst composition for oligomerization of olefins |
US4952544A (en) | 1987-03-05 | 1990-08-28 | Uop | Stable intercalated clays and preparation method |
US4952739A (en) | 1988-10-26 | 1990-08-28 | Exxon Chemical Patents Inc. | Organo-Al-chloride catalyzed poly-n-butenes process |
US4954562A (en) | 1986-04-21 | 1990-09-04 | American Colloid Company | Water absorbent resins |
US4956420A (en) | 1988-09-15 | 1990-09-11 | Exxon Chemical Patents Inc. | Selective catalytic process for controlled modification of ethylene-(alpha-olefin)-diene monomer terpolymer with halothisulfonamide |
US4957889A (en) | 1987-03-05 | 1990-09-18 | Uop | Stable intercalated clays and preparation method |
US4982045A (en) | 1986-12-12 | 1991-01-01 | Exxon Chemical Patents Inc. | Fixed bed process for polymerizing liquid butenes |
US4987200A (en) | 1987-06-08 | 1991-01-22 | Exxon Chemical Patents Inc. | Preparation of polymer incorporating masked functional group-containing monomers |
US5008468A (en) | 1986-04-16 | 1991-04-16 | Catalytica, Inc. | Acid catalyzed process |
US5017662A (en) | 1988-09-15 | 1991-05-21 | Exxon Chemical Patents, Inc. | Selective catalytic process for preparing N-halothiosulfonamide modified EPDM terpolymers |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5073531A (en) | 1990-05-07 | 1991-12-17 | Phillips Petroleum Company | Olefin polymerization catalysts and preparation method |
US5075394A (en) | 1990-06-07 | 1991-12-24 | Phillips Petroleum Company | Olefin polymerization using supported pentadienyl derivative-transition metal complexes |
US5081086A (en) | 1988-12-29 | 1992-01-14 | Uop | Solid phosphoric acid catalyst |
US5110778A (en) | 1986-10-17 | 1992-05-05 | Olah George A | Boron aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US5113034A (en) | 1991-08-05 | 1992-05-12 | Exxon Research And Engineering Company | Dimerization catalyst and process therefor |
US5139761A (en) | 1990-12-17 | 1992-08-18 | Uop | Modified zeolite omega and processes for preparing and using same |
US5171791A (en) | 1989-03-13 | 1992-12-15 | The Dow Chemical Company | Anionic polymerization process |
US5177288A (en) | 1988-11-25 | 1993-01-05 | Exxon Chemical Patents Inc. | Polybutene process |
US5191140A (en) | 1990-09-20 | 1993-03-02 | Idemitsu Petrochemical Co., Ltd. | Process for producing olefin oligomer |
US5190844A (en) | 1990-12-07 | 1993-03-02 | Nippon Paint Co., Ltd. | Production of surface-modified organic particles |
US5191132A (en) | 1991-05-09 | 1993-03-02 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5198512A (en) | 1991-12-16 | 1993-03-30 | Phillips Petroleum Company | Polymerization catalyst and process |
US5198563A (en) | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5200379A (en) | 1990-06-07 | 1993-04-06 | Phillips Petroleum Company | Olefin polymerization using supported pentadienyl derivative-transition metal complexes |
US5206314A (en) | 1992-08-31 | 1993-04-27 | Phillips Petroleum Company | Polyolefin polymerization process, process of producing catalyst, and catalyst |
US5225493A (en) | 1989-03-13 | 1993-07-06 | The Dow Chemical Company | Anionic polymerization process |
US5272124A (en) | 1992-11-20 | 1993-12-21 | Phillips Petroleum Company | Ethylene polymerization catalyst comprising a nickel compound and an aromatic carboxylic acid compound |
US5283301A (en) | 1991-08-23 | 1994-02-01 | Phillips Petroleum Company | Olefin polymerization with particulate gel-containing catalyst |
US5284811A (en) | 1990-05-14 | 1994-02-08 | Phillips Petroleum Company | Polymerization catalysts and processes |
US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
US5288677A (en) | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5321106A (en) | 1990-07-03 | 1994-06-14 | The Dow Chemical Company | Addition polymerization catalyst with oxidative activation |
EP0273627B1 (de) | 1986-12-12 | 1994-06-22 | Exxon Chemical Patents Inc. | Festbettverfahren für die Polymerisation von flüssigen Butenen |
US5324881A (en) | 1992-12-22 | 1994-06-28 | Mobil Oil Corp. | Supported heteropoly acid catalysts for isoparaffin-olefin alkylation reactions |
US5326923A (en) | 1990-09-26 | 1994-07-05 | Catalytica, Inc. | Method for regenerating certain acidic hydrocarbon conversion catalysts by solvent extraction |
US5326921A (en) | 1988-10-26 | 1994-07-05 | Exxon Chemical Patents Inc. | AlCl3 -catalyzed process for preparing poly-N-butenes from mixed butenes |
US5328956A (en) | 1990-11-13 | 1994-07-12 | Kao Corporation | Propylene (co)polymer and process for the preparation of the same |
EP0391697B1 (de) | 1989-04-04 | 1994-07-13 | Exxon Chemical Patents Inc. | Ozonbeständige Butyl-Elastomere |
US5330949A (en) | 1985-06-17 | 1994-07-19 | Idemitsu Petrochemical Company, Ltd. | Method for producing polyolefin |
US5331104A (en) | 1989-08-10 | 1994-07-19 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5332708A (en) | 1992-11-23 | 1994-07-26 | Phillips Petroleum Company | Catalyst compositions and catalytic processes |
US5338812A (en) | 1991-12-24 | 1994-08-16 | Phillips Petroleum Company | Olefin polymerization |
US5347026A (en) | 1993-06-11 | 1994-09-13 | Phillips Petroleum Company | Fluorene compounds and methods for making |
US5350726A (en) | 1993-09-03 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
US5350819A (en) | 1993-02-19 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
US5354721A (en) | 1993-06-22 | 1994-10-11 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5362825A (en) | 1992-07-13 | 1994-11-08 | Phillips Petroleum Company | Catalysts for polymerizing olefins and methods |
US5365010A (en) | 1990-09-26 | 1994-11-15 | Catalytica, Inc. | Method for regenerating Lewis acid-promoted transition alumina catalysts used for isoparaffin alkylation by calcination |
US5366945A (en) | 1992-12-22 | 1994-11-22 | Mobil Oil Corp. | Supported heteropoly acid catalysts |
US5371154A (en) | 1993-11-09 | 1994-12-06 | Uop | Process for forming acid functionalized organically-bridged polysilsesquioxanes |
US5382420A (en) | 1992-09-25 | 1995-01-17 | Exxon Research & Engineering Company | ECR-33: a stabilized rare-earth exchanged Q type zeolite |
US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5393911A (en) | 1991-05-09 | 1995-02-28 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5401817A (en) | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
US5403803A (en) | 1993-09-28 | 1995-04-04 | Exxon Chemical Patents Inc. | Carbocationic catalyst and process for its use |
US5412024A (en) | 1991-04-09 | 1995-05-02 | Idemitsu Kosan Co., Ltd. | Thermoplastic resin composition |
US5414180A (en) | 1993-07-14 | 1995-05-09 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5414187A (en) | 1992-10-30 | 1995-05-09 | Catalytica, Inc. | Acid catalyst and use thereof in alkylation of olefins with tertiary alkanes |
EP0367386B1 (de) | 1988-10-26 | 1995-07-05 | Exxon Chemical Patents Inc. | Verfahren zur Herstellung von Poly-n-Butylenen aus einer Butylenschnitte mittels Aluminiumchloridkatalysatoren |
US5436305A (en) | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5446102A (en) | 1994-08-10 | 1995-08-29 | Bridgeston, Corporation | Olefin metathesis catalysts for degelling polymerization reactors |
US5453410A (en) | 1992-01-06 | 1995-09-26 | The Dow Chemical Company | Catalyst composition |
US5461127A (en) | 1992-09-22 | 1995-10-24 | Idemitsu Kosan Co., Ltd. | Polymerization catalysts and process for producing polymers |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5475162A (en) | 1993-11-09 | 1995-12-12 | Uop | Acid functionalized organically-bridged polysilsesquioxanes as catalysts for acid catalyzed reactions |
US5491214A (en) | 1993-03-26 | 1996-02-13 | Hercules Incorporated | Process for hydrotreating resins to lighten color |
US5561095A (en) | 1994-03-31 | 1996-10-01 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
US5633419A (en) | 1994-08-12 | 1997-05-27 | The Dow Chemical Company | Polymerization of olefins in the presence of a supported catalyst |
US5710225A (en) | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
EP0575866B1 (de) | 1992-06-16 | 1999-08-04 | Phillips Petroleum Company | Olefinpolymerisation, Katalysator und Vorprodukt |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US31443A (en) * | 1861-02-19 | Felly-machine | ||
US3347678A (en) * | 1961-12-27 | 1967-10-17 | Grindstedvaerket As | Processing citrus fruits |
US3721632A (en) * | 1970-12-30 | 1973-03-20 | Cities Service Co | Method of catalyst preparation |
JPS5017231B2 (de) * | 1971-10-26 | 1975-06-19 | ||
JPS57102825A (en) * | 1980-12-19 | 1982-06-26 | Nippon Oil & Fats Co Ltd | Preparation of isobutylene oligomer |
JPS57149233A (en) * | 1981-03-11 | 1982-09-14 | Showa Denko Kk | Preparation of isobutene oligomer |
US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
US4463212A (en) * | 1982-12-10 | 1984-07-31 | Uop Inc. | Selective oligomerization of olefins |
US5073351A (en) | 1984-06-01 | 1991-12-17 | Mobil Oil Corporation | Production of middle distillate range hydrocarbons by light olefin upgrading |
IT1226550B (it) * | 1988-07-29 | 1991-01-24 | Enichem Anic Spa | Processo di oligomerizzazione selettiva di olefine e nuovo catalizzatore per tale processo. |
US4845066A (en) | 1988-08-25 | 1989-07-04 | Phillips Petroleum Company | Preparation of pillared clay |
WO1994028036A1 (en) * | 1993-05-20 | 1994-12-08 | Exxon Chemical Patents Inc. | Heterogeneous lewis acid-type catalysts |
EP0920909A1 (de) * | 1994-03-31 | 1999-06-09 | Exxon Chemical Patents Inc. | Lewis-Säure enthaltende Trägerkatalysatoren für Umwandlungsreaktionen von Kohlenwasserstoffen |
JPH0812601A (ja) * | 1994-07-01 | 1996-01-16 | Cosmo Sogo Kenkyusho:Kk | α−アルキルスチレン類多量体の製造法 |
-
1998
- 1998-01-07 WO PCT/US1998/000009 patent/WO1998030519A1/en not_active Application Discontinuation
- 1998-01-07 CN CN98803007A patent/CN1249733A/zh active Pending
- 1998-01-07 EP EP98901669A patent/EP0964844B1/de not_active Expired - Lifetime
- 1998-01-07 EP EP98901667A patent/EP0963365B1/de not_active Expired - Lifetime
- 1998-01-07 US US09/003,594 patent/US6281309B1/en not_active Expired - Fee Related
- 1998-01-07 CN CN98803201A patent/CN1249734A/zh active Pending
- 1998-01-07 DE DE69818018T patent/DE69818018T2/de not_active Expired - Fee Related
- 1998-01-07 EP EP98901163A patent/EP0970117A2/de not_active Withdrawn
- 1998-01-07 CA CA002277294A patent/CA2277294A1/en not_active Abandoned
- 1998-01-07 KR KR1019997006222A patent/KR20000070007A/ko not_active Application Discontinuation
- 1998-01-07 AU AU58133/98A patent/AU5813398A/en not_active Abandoned
- 1998-01-07 CA CA002277297A patent/CA2277297A1/en not_active Abandoned
- 1998-01-07 JP JP53096598A patent/JP2001508102A/ja active Pending
- 1998-01-07 US US09/003,596 patent/US6310154B1/en not_active Expired - Fee Related
- 1998-01-07 CA CA002277295A patent/CA2277295A1/en not_active Abandoned
- 1998-01-07 JP JP53096498A patent/JP2001509185A/ja active Pending
- 1998-01-07 AU AU57309/98A patent/AU5730998A/en not_active Abandoned
- 1998-01-07 CA CA002277292A patent/CA2277292A1/en not_active Abandoned
- 1998-01-07 WO PCT/US1998/000012 patent/WO1998030587A2/en not_active Application Discontinuation
- 1998-01-07 CN CN98802978A patent/CN1249732A/zh active Pending
- 1998-01-07 EP EP98901668A patent/EP0954516A1/de not_active Withdrawn
- 1998-01-07 US US09/003,879 patent/US6608155B2/en not_active Expired - Fee Related
- 1998-01-07 AU AU58134/98A patent/AU5813498A/en not_active Abandoned
- 1998-01-07 KR KR1019997006219A patent/KR20000070004A/ko not_active Application Discontinuation
- 1998-01-07 WO PCT/US1998/000010 patent/WO1998030520A1/en not_active Application Discontinuation
- 1998-01-07 US US09/003,888 patent/US6133386A/en not_active Expired - Fee Related
- 1998-01-07 CN CN98803202A patent/CN1249735A/zh active Pending
- 1998-01-07 KR KR1019997006224A patent/KR20000070009A/ko not_active Application Discontinuation
- 1998-01-07 JP JP53096698A patent/JP2001511194A/ja active Pending
- 1998-01-07 KR KR1019997006221A patent/KR20000070006A/ko not_active Application Discontinuation
- 1998-01-07 JP JP53096798A patent/JP2001508103A/ja active Pending
- 1998-01-07 WO PCT/US1998/000011 patent/WO1998030521A1/en not_active Application Discontinuation
- 1998-01-07 DE DE69815301T patent/DE69815301T2/de not_active Expired - Fee Related
- 1998-01-07 AU AU58132/98A patent/AU5813298A/en not_active Abandoned
Patent Citations (349)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2734046A (en) | 1956-02-07 | Steam or | ||
US2301966A (en) | 1936-04-02 | 1942-11-17 | Michel Richard | Process for the manufacture of valuable products from olefins |
US2460692A (en) * | 1943-06-24 | 1949-02-01 | Allied Chem & Dye Corp | Polymerization of resin oils with mixed clay and organic acid catalyst |
US2455225A (en) * | 1944-08-15 | 1948-11-30 | Pennsyivania Ind Chemical Corp | Method of making styrene resin |
US2507864A (en) | 1947-03-25 | 1950-05-16 | Texas Co | Polymerization of olefins |
US2559576A (en) | 1947-06-25 | 1951-07-03 | Universal Oil Prod Co | Process for polymerization with tetraborohypophosphoric acid catalyst |
US2632777A (en) | 1949-01-06 | 1953-03-24 | Universal Oil Prod Co | Production of hydrocarbon conjunct polymers |
US2626290A (en) | 1950-03-30 | 1953-01-20 | Standard Oil Dev Co | Process for polymerizing olefins with a phosphoric acid slurry catalyst |
US2642402A (en) | 1950-04-27 | 1953-06-16 | Standard Oil Dev Co | Olefin polymerization catalyst and its preparation |
US2721889A (en) | 1950-07-28 | 1955-10-25 | Exxon Research Engineering Co | Olefin polymerization process |
US2626291A (en) | 1950-10-19 | 1953-01-20 | Standard Oil Dev Co | Solid phosphoric acid slurry polymerization process |
US2694686A (en) | 1950-12-01 | 1954-11-16 | Standard Oil Dev Co | Phosphoric acid catalysts comprising a calcined silicon phosphoric base |
US2778804A (en) | 1951-07-31 | 1957-01-22 | Exxon Research Engineering Co | Olefin polymerization catalyst and process |
US2758143A (en) | 1951-10-01 | 1956-08-07 | Exxon Research Engineering Co | Olefin polymerization process |
US2751331A (en) | 1951-11-13 | 1956-06-19 | Texas Co | Process for selectively polymerizing diolefins |
US2772317A (en) | 1952-03-28 | 1956-11-27 | Exxon Research Engineering Co | Polymerization catalyst and processes |
US2745890A (en) | 1952-03-29 | 1956-05-15 | Exxon Research Engineering Co | Process for production of polymer hydrocarbons |
US2766312A (en) | 1952-08-19 | 1956-10-09 | Exxon Research Engineering Co | Process for polymerizing olefins |
US2766311A (en) | 1952-08-28 | 1956-10-09 | Exxon Research Engineering Co | Combination catalytic polymerization process |
US2744084A (en) | 1952-09-26 | 1956-05-01 | Exxon Research Engineering Co | Olefin polymerization process using hydrogenated naphtha solvent |
US2728804A (en) | 1952-11-01 | 1955-12-27 | Exxon Research Engineering Co | Multi-stage polymerization process |
US2767234A (en) | 1952-11-01 | 1956-10-16 | Exxon Research Engineering Co | Multi-stage polymerization of olefins with suspended catalyst |
US2753382A (en) | 1952-12-01 | 1956-07-03 | Exxon Research Engineering Co | Polymers from piperylene concentrates |
US2753325A (en) | 1952-12-22 | 1956-07-03 | Exxon Research Engineering Co | Resins from selected distillates |
US2775577A (en) | 1952-12-23 | 1956-12-25 | Exxon Research Engineering Co | Controlled isobutylene polymerization |
US2739143A (en) | 1952-12-29 | 1956-03-20 | Exxon Research Engineering Co | Process for the preparation of polyisobutylene with a slurry catalyst |
US2779753A (en) | 1952-12-29 | 1957-01-29 | Exxon Research Engineering Co | Process for preparing high molecular polymers from isobutylene |
US2732398A (en) | 1953-01-29 | 1956-01-24 | cafiicfzsojk | |
US2849428A (en) | 1953-06-24 | 1958-08-26 | Exxon Research Engineering Co | Process for the preparation of a dissolved aluminum chloride catalyst |
US2773051A (en) | 1953-07-03 | 1956-12-04 | Exxon Research Engineering Co | Preparation of resins from c5 fractions and cyclopentadiene dimers |
US2833746A (en) | 1953-12-23 | 1958-05-06 | Ethyl Corp | Acrylonitrile-isobutylene-styrene interpolymer |
US2816944A (en) | 1954-05-14 | 1957-12-17 | Exxon Research Engineering Co | Polymerization of liquid olefins in the presence of a boron fluoride-phosphoric acidcatalyst |
US2831037A (en) | 1954-06-01 | 1958-04-15 | Universal Oil Prod Co | Conversion of bicyclo-olefins |
US2786878A (en) | 1954-06-08 | 1957-03-26 | Exxon Research Engineering Co | Olefin polymerization process |
US2887472A (en) * | 1954-09-30 | 1959-05-19 | Standard Oil Co | Production of solid polyethylene by a catalyst consisting essentially of an alkali metal and an adsorbent alumina-containing material |
US2748090A (en) | 1955-02-28 | 1956-05-29 | Universal Oil Prod Co | Manufacture of solid polymerization catalysts |
US2852580A (en) | 1955-09-26 | 1958-09-16 | Universal Oil Prod Co | Preparation of polyisoolefins |
US2931792A (en) | 1956-02-02 | 1960-04-05 | Robert S Aries | Pyrophoric catalytic systems |
US2906793A (en) | 1956-03-08 | 1959-09-29 | Exxon Research Engineering Co | Polymerization of isoolefins |
US3017400A (en) | 1956-11-02 | 1962-01-16 | Universal Oil Prod Co | Polymerization of olefins |
US2878240A (en) | 1956-12-24 | 1959-03-17 | Universal Oil Prod Co | Polymerization of olefins to solid polymers |
US2914517A (en) | 1956-12-24 | 1959-11-24 | Universal Oil Prod Co | Polymerization of olefins to solid polymers |
US2938018A (en) | 1957-11-22 | 1960-05-24 | Universal Oil Prod Co | Production of hard olefin polymers |
US3054787A (en) | 1958-03-17 | 1962-09-18 | Dal Mon Research Co | Catalytic process |
US2945845A (en) | 1958-04-28 | 1960-07-19 | Universal Oil Prod Co | Polymerization of olefins with complex catalyst comprising platinum or palladium |
US2987511A (en) | 1958-07-10 | 1961-06-06 | Universal Oil Prod Co | Process for polymerizing olefinic hydrocarbons |
US3006906A (en) | 1958-07-21 | 1961-10-31 | Universal Oil Prod Co | Preparation of polymers of isobutylene and an alkylene diamine |
US2976338A (en) | 1958-12-08 | 1961-03-21 | Exxon Research Engineering Co | Process and catalyst for polymerization |
US3006905A (en) | 1959-02-16 | 1961-10-31 | Universal Oil Prod Co | Preparation of copolymers |
US3037970A (en) | 1959-02-16 | 1962-06-05 | Universal Oil Prod Co | Copolymer of an unsaturated side chain aromatic compound and an alkylene diamine |
US3024226A (en) | 1959-11-23 | 1962-03-06 | Texaco Inc | Polymerization process |
US3000868A (en) | 1959-12-30 | 1961-09-19 | Pennsylvania Ind Chemical Corp | Vinyl toluene-alpha methyl styrene polymers |
US3136729A (en) * | 1960-06-16 | 1964-06-09 | Phillips Petroleum Co | Catalyst compositions and process of preparation |
US3113165A (en) | 1960-09-01 | 1963-12-03 | Universal Oil Prod Co | Polymerization of unsaturated organic compounds |
US3154595A (en) | 1960-09-29 | 1964-10-27 | Universal Oil Prod Co | Olefin polymerization catalyzed by aminated alkali metal |
US3109041A (en) | 1961-02-16 | 1963-10-29 | Texaco Inc | Polymerization of isobutylene |
US3190936A (en) | 1961-02-16 | 1965-06-22 | Texaco Inc | Process for regenerating an adsorbent and a catalyst support in a polymerization operation |
US3166545A (en) | 1961-04-06 | 1965-01-19 | Texaco Inc | Polymerization of isobutylene with an aluminum-titanium dioxide-titanium tetrachloride catalyst |
US3112350A (en) | 1961-06-12 | 1963-11-26 | Universal Oil Prod Co | Polymerization of olefins using a solid phosphoric acid catalyst |
US3133127A (en) | 1961-11-10 | 1964-05-12 | Texaco Inc | Polymerization process |
US3179649A (en) | 1961-12-11 | 1965-04-20 | Dow Chemical Co | Polymerization catalyst mixture of a bismuthine, a cuprous salt, and a lewis acid |
US3221001A (en) | 1962-02-12 | 1965-11-30 | Exxon Research Engineering Co | Polymerization of ethylene in the presence of inorganic salt hydrates |
US3128318A (en) | 1962-06-18 | 1964-04-07 | Universal Oil Prod Co | Alkali metal amide catalysts and their use in polymerizing olefins |
US3190938A (en) | 1962-11-01 | 1965-06-22 | Exxon Research Engineering Co | Polymerization of olefins |
US3248341A (en) | 1963-02-13 | 1966-04-26 | Universal Oil Prod Co | Method of admixing a phosphoric acid and an absorbent and precipitating with ammonia |
US3418304A (en) | 1963-09-13 | 1968-12-24 | Exxon Research Engineering Co | Polymerization catalyst |
US3244767A (en) | 1964-01-24 | 1966-04-05 | Universal Oil Prod Co | Polymerization process using oxygenated sulfur-phosphoric acid catalyst |
US3383378A (en) | 1964-04-22 | 1968-05-14 | Universal Oil Prod Co | Polymerization of ethylene |
US3347676A (en) | 1964-04-30 | 1967-10-17 | Du Pont | Photopolymerizable compositions and process |
US3244768A (en) | 1964-10-19 | 1966-04-05 | Texaco Inc | Catalytic polymerization of propylene |
US3364191A (en) | 1964-11-03 | 1968-01-16 | Universal Oil Prod Co | Olefin-aromatic hydrocarbon copolymers |
US3374285A (en) | 1964-12-29 | 1968-03-19 | Gulf Research Development Co | Process for the polymerization of propylene |
US3555107A (en) | 1965-01-27 | 1971-01-12 | Texaco Inc | Hydrocarbon conversion process with a catalyst activated with an organic chloride and oxygen |
US3801559A (en) | 1965-04-16 | 1974-04-02 | Goodyear Tire & Rubber | Poly-1-chloro cyclooctadiene |
US3426007A (en) | 1965-10-21 | 1969-02-04 | Exxon Research Engineering Co | Polymerization catalyst system |
US3867361A (en) | 1966-03-28 | 1975-02-18 | Goodyear Tire & Rubber | A process for the polymerization of cyclic olefins |
US3420809A (en) | 1966-08-12 | 1969-01-07 | Exxon Research Engineering Co | Catalyst for ethylene polymerization |
US3426089A (en) | 1966-08-30 | 1969-02-04 | Universal Oil Prod Co | Polymerization process |
US3457189A (en) | 1966-08-30 | 1969-07-22 | Universal Oil Prod Co | Fluorided refractory oxide catalyst and preparation thereof |
US3472791A (en) | 1966-09-12 | 1969-10-14 | Universal Oil Prod Co | Method of spherical catalyst preparation |
US3499877A (en) | 1966-09-19 | 1970-03-10 | Standard Oil Co | Dimethyl alpha-methyl styrene polymers |
DE1963684U (de) | 1967-02-25 | 1967-07-06 | Agfa Gevaert Ag | Grundplatte fuer ein fotografisches vergroesserungsgeraet. |
US3607959A (en) | 1967-06-16 | 1971-09-21 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3734866A (en) | 1967-06-26 | 1973-05-22 | Goodyear Tire & Rubber | Preparation of polymeric aromatic compositions |
US3515769A (en) | 1967-06-30 | 1970-06-02 | Universal Oil Prod Co | Polymerization process |
US3427275A (en) | 1967-08-16 | 1969-02-11 | Reichhold Chemicals Inc | Vinyl aromatic-acrylic copolymers and process of producing the same |
US3497568A (en) | 1967-09-29 | 1970-02-24 | Texaco Inc | Continuous process for polymerizing olefins |
US3464929A (en) | 1968-05-09 | 1969-09-02 | Universal Oil Prod Co | Hydrocarbon conversion catalyst comprising a halogen component combined with a support containing alumina and finely divided crystalline aluminosilicate particles |
US3463744A (en) | 1968-06-03 | 1969-08-26 | Universal Oil Prod Co | Control of acid activity of a hydrocarbon conversion catalyst comprising a halogen component combined with a support containing alumina and crystalline aluminosilicate particles |
US3689434A (en) | 1968-07-29 | 1972-09-05 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3577400A (en) | 1968-08-26 | 1971-05-04 | Goodyear Tire & Rubber | Novel catalysts for the polymerization of alicyclic olefins |
US3689471A (en) | 1968-08-26 | 1972-09-05 | Goodyear Tire & Rubber | Ternary catalyst systems for the polymerization of cycle olefins |
US3624060A (en) | 1969-01-31 | 1971-11-30 | Goodyear Tire & Rubber | Binary catalyst systems for the polymerization of unsaturated alicyclic monomers |
US3586616A (en) | 1969-03-14 | 1971-06-22 | Minnesota Mining & Mfg | Bis(perfluoroalkylsulfonyl)methane metal salts in cationic polymerization |
US3842019A (en) | 1969-04-04 | 1974-10-15 | Minnesota Mining & Mfg | Use of sulfonic acid salts in cationic polymerization |
US3640981A (en) | 1969-04-23 | 1972-02-08 | Reichhold Chemicals Inc | Vinyl toluene-alpha methyl styrene co-polymers and method of preparing the same |
US3597406A (en) | 1969-04-30 | 1971-08-03 | Goodyear Tire & Rubber | Polymers of hydrocarbon substituted 1,5-cyclooctadienes and methods for their polymerization |
US3630981A (en) | 1969-06-09 | 1971-12-28 | Pennsylvania Ind Chemical Corp | Copolymers of alpha methyl styrene and vinyl toluene and process of preparation |
US3956250A (en) | 1969-06-09 | 1976-05-11 | Hercules Incorporated | Alpha methyl styrene and vinyl toluene and processes of preparation |
US4063011A (en) | 1969-06-09 | 1977-12-13 | Hercules Incorporated | Alpha methyl styrene and vinyl toluene and processes of preparation |
US3609098A (en) | 1969-08-21 | 1971-09-28 | Phillips Petroleum Co | Haloester and cuprous salt polymerization catalyst systems |
US3652707A (en) | 1969-09-16 | 1972-03-28 | Texaco Inc | Process for the polymerization of olefin hydrocarbons |
US3652706A (en) | 1969-09-16 | 1972-03-28 | Texaco Inc | Polymerization of olefins |
US3597403A (en) | 1969-10-27 | 1971-08-03 | Goodyear Tire & Rubber | Novel catalysts for the ring-opening polymerization of unsaturated alicyclic compounds |
US3644220A (en) | 1969-11-13 | 1972-02-22 | Exxon Research Engineering Co | Metal halide containing zeolites and method for their preparation |
US3661870A (en) | 1969-11-24 | 1972-05-09 | Goodyear Tire & Rubber | Isobutylene,1,3-butadiene,methyl butene copolymers |
US3692872A (en) | 1969-12-04 | 1972-09-19 | Goodyear Tire & Rubber | Preparation of graft, block and crosslinked unsaturated polymers and copolymers by olefin metathesis |
US3669947A (en) | 1970-02-02 | 1972-06-13 | Velsicol Chemical Corp | Process for the production of alpha-methylstyrene polymer |
US3652487A (en) | 1970-02-05 | 1972-03-28 | Goodyear Tire & Rubber | Process for the polymerization of alicyclic monomer masterbatches |
US3753962A (en) | 1970-03-16 | 1973-08-21 | Atlas Chem Ind | Recovery of a water soluble polymer powder from an aqueous gel of said polymer |
US3631212A (en) | 1970-04-20 | 1971-12-28 | Universal Oil Prod Co | Preparation of polyarylpolyalkanes |
US3692697A (en) | 1970-06-25 | 1972-09-19 | Texaco Inc | Fluorided metal-alumina catalysts |
US3692695A (en) | 1970-06-25 | 1972-09-19 | Texaco Inc | Fluorided composite alumina catalysts |
US3717586A (en) | 1970-06-25 | 1973-02-20 | Texaco Inc | Fluorided composite alumina catalysts |
US3692696A (en) | 1970-06-25 | 1972-09-19 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3711425A (en) | 1970-06-25 | 1973-01-16 | Texaco Inc | Fluorided metal alumina catalysts |
US3692694A (en) | 1970-06-25 | 1972-09-19 | Texaco Inc | Catalyst for hydrocarbon conversion |
US3657205A (en) | 1970-09-03 | 1972-04-18 | Goodyear Tire & Rubber | Preparation of high 1 4-polypentadienes |
US3657208A (en) | 1970-11-02 | 1972-04-18 | Goodyear Tire & Rubber | Ternary catalyst systems for the polymerization of cyclic olefins |
US3956180A (en) | 1970-12-28 | 1976-05-11 | Texaco Development Corporation | Hydrocarbon soluble molybdenum catalysts |
US3746696A (en) | 1971-03-25 | 1973-07-17 | Goodyear Tire & Rubber | Catalyst systems for polymerizing alicyclic olefins |
US3772401A (en) | 1971-10-27 | 1973-11-13 | Texaco Inc | Continuous 2-methyl-1-alkene polymerization process |
US3753961A (en) | 1971-12-03 | 1973-08-21 | Goodyear Tire & Rubber | Resinous composition |
US3799913A (en) | 1971-12-30 | 1974-03-26 | Neville Chemical Co | Production of hydrocarbon resin compositions from alpha-methyl styrene,indene and vinyl toluene |
US3772255A (en) | 1972-06-07 | 1973-11-13 | Goodyear Tire & Rubber | Ring-opening polymerization of cycloolefins |
US3980577A (en) | 1972-10-21 | 1976-09-14 | Sumitomo Chemical Company, Limited | Diphenylmethane electrophotographic liquid developer |
US3888789A (en) | 1972-12-15 | 1975-06-10 | Universal Oil Prod Co | Preparation of polymerization catalyst systems |
US3987109A (en) | 1972-12-27 | 1976-10-19 | Universal Oil Products Company | Polymerization of polyfunctional phenols |
US4075404A (en) | 1973-02-16 | 1978-02-21 | Hercules Incorporated | Copolymers of alpha-methylstyrene and styrene and uses thereof |
US3932332A (en) | 1973-02-16 | 1976-01-13 | Hercules Incorporated | Copolymers of alpha-methylstyrene and styrene and uses thereof |
US4301227A (en) | 1973-03-29 | 1981-11-17 | Sumitomo Chemical Company, Limited | Electrophotographic liquid developer |
US3975336A (en) | 1973-05-14 | 1976-08-17 | The Goodyear Tire & Rubber Company | Polymers of nonconjugated 1,4-dienes |
US3926882A (en) | 1973-11-23 | 1975-12-16 | Standard Oil Co | Alpha-methyl styrene/tertiary butyl styrene/olefin terepolymer resins and hot melt adhesives containing the same |
US4010113A (en) | 1974-04-01 | 1977-03-01 | The Goodyear Tire & Rubber Company | Catalyst for metathesis of cycloolefins |
US3997471A (en) | 1974-04-01 | 1976-12-14 | The Goodyear Tire & Rubber Company | Cycloolefin metathesis catalyst |
US3945986A (en) | 1974-04-01 | 1976-03-23 | The Goodyear Tire & Rubber Company | Metathesis of cycloolefins |
US3935179A (en) | 1974-04-01 | 1976-01-27 | The Goodyear Tire & Rubber Company | Cycloolefin metathesis |
US3943116A (en) | 1974-06-21 | 1976-03-09 | The Goodyear Tire & Rubber Company | Method for preparing high cis polyalkenamers |
US3932553A (en) | 1974-07-26 | 1976-01-13 | Exxon Research And Engineering Company | Oligomerization of propylene |
US3929737A (en) | 1974-09-30 | 1975-12-30 | Goodyear Tire & Rubber | Maleic anhydride-modified resin backbone |
US4020254A (en) | 1974-09-30 | 1977-04-26 | The Goodyear Tire & Rubber Company | Metathesis polymerization of cycloolefins |
US4127710A (en) | 1974-10-02 | 1978-11-28 | Phillips Petroleum Company | Copolymerization of a 1,3-cyclodiene and a linear conjugated diene |
US4064335A (en) | 1974-11-11 | 1977-12-20 | The Goodyear Tire & Rubber Company | Polymers of nonconjugated 1,4-dienes |
US4028272A (en) | 1974-11-22 | 1977-06-07 | The Goodyear Tire & Rubber Company | Process of polymerization of conjugated diolefins using iron catalysts and sulfur ligands |
US4048262A (en) | 1975-01-02 | 1977-09-13 | Chemische Werke Huls Aktiengesellschaft | Polydodecenamers as reinforcing resins for elastomers |
US4153771A (en) | 1975-01-15 | 1979-05-08 | The Goodyear Tire & Rubber Company | Hydrocarbon resin prepared from antimony pentafluoride or ferric chloride |
US3992322A (en) | 1975-04-11 | 1976-11-16 | Universal Oil Products Company | Preparation of polymerization catalyst systems |
US4009228A (en) | 1975-05-12 | 1977-02-22 | The Goodyear Tire & Rubber Company | Primary amine-modified anhydride resin |
US4013736A (en) | 1975-07-16 | 1977-03-22 | Exxon Research And Engineering Company | Synthesis of low viscosity low pour point hydrocarbon lubricating oils |
US4068062A (en) | 1975-07-30 | 1978-01-10 | Exxon Research And Engineering Company | Polymerizing C5 and C6 olefins and diolefins with 3° hydrocarbyl halide to produce narrow molecular weight petroleum resins having low softening points |
US4062801A (en) | 1975-08-11 | 1977-12-13 | Vop Inc. | Catalyst regeneration method |
SU859391A1 (ru) | 1976-02-24 | 1981-08-30 | Институт Химии Башкирского Филиала Ан Ссср | Способ получени окрашенного полимерного материала-полиметилметакрилата,полистирола или поливинилацетата |
US4205160A (en) | 1976-03-11 | 1980-05-27 | The Goodyear Tire & Rubber Company | Indane containing polymers |
US4105843A (en) | 1976-04-15 | 1978-08-08 | Mitsui Petrochemical Industries Ltd. | Process for producing hydrocarbon resins having improved color and thermal stability by heat treatment with an α,βunsaturated anhydride |
US4108944A (en) | 1976-06-24 | 1978-08-22 | The Goodyear Tire & Rubber Company | Metal salts of modified anhydride resin |
US4130701A (en) | 1976-10-19 | 1978-12-19 | Exxon Research & Engineering Co. | Petroleum resins containing vinyl norbornene or tetrahydroindene |
US4038471A (en) | 1976-10-29 | 1977-07-26 | The Goodyear Tire & Rubber Company | Method for preparing high-cis polyalkenamers |
US4133801A (en) | 1977-01-26 | 1979-01-09 | Teijin Limited | Process for the preparation of polyesters |
US4217409A (en) | 1977-05-12 | 1980-08-12 | Dai Nippon Insatsu Kabushiki Kaisha | Image forming material comprising polyacids of Mo or W or their salts or complexes |
US4359406A (en) | 1977-06-17 | 1982-11-16 | Exxon Research And Engineering Co. | Highly dispersed supported group VIII metal-phosphorus compounds, and highly dispersed, supported group VIII metal-arsenic and a process for making said compounds |
US4171414A (en) | 1977-08-25 | 1979-10-16 | Exxon Research & Engineering Co. | Catalyst composition for an improved polymerization process of isoolefins and multiolefins |
DE2836982A1 (de) | 1977-08-25 | 1979-03-08 | Exxon Research Engineering Co | Elastomere co- oder terpolymere und verfahren zu ihrer herstellung |
US4172932A (en) | 1977-09-07 | 1979-10-30 | The Goodyear Tire & Rubber Company | Process for the preparation of polymers of cyclopentene or copolymers of cyclopentene with unsaturated alicyclic compounds |
US4137390A (en) | 1977-09-07 | 1979-01-30 | The Goodyear Tire & Rubber Company | Process for the polymerization of cycloolefins |
USRE31443E (en) | 1977-12-05 | 1983-11-15 | Phillips Petroleum Company | Treatment of silica |
US4230840A (en) | 1977-12-26 | 1980-10-28 | Mitsui Petrochemical Industries Ltd. | Process for producing hydrocarbon resins having improved color and thermal stability |
US4168357A (en) | 1978-04-05 | 1979-09-18 | The Goodyear Tire & Rubber Company | Preparation of high cis-1,4-polypentadiene |
US4245075A (en) | 1978-06-27 | 1981-01-13 | Exxon Research & Engineering Co. | Carene modified petroleum resins |
US4233139A (en) | 1978-07-25 | 1980-11-11 | Exxon Research & Engineering Co. | Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support |
US4239874A (en) | 1979-02-21 | 1980-12-16 | The Goodyear Tire & Rubber Company | Cyclopentene copolymerization process |
US4547474A (en) | 1979-03-26 | 1985-10-15 | Atochem | Supported superacidic catalysts based on C10 to C18 perfluorinated alkanesulfonic acids |
US4363746A (en) | 1979-05-29 | 1982-12-14 | Phillips Petroleum Company | Composition of matter and method of preparing same, catalyst, method of producing the catalyst and polymerization process employing the catalyst |
US4248735A (en) | 1979-06-01 | 1981-02-03 | Phillips Petroleum Company | Treatment of silica |
US4843133A (en) | 1979-12-07 | 1989-06-27 | Phillips Petroleum Company | Polymerization and catalysts |
US4565795A (en) | 1979-12-07 | 1986-01-21 | Phillips Petroleum Company | Polymerization and catalysts |
US4368303A (en) | 1980-02-06 | 1983-01-11 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4296001A (en) | 1980-02-06 | 1981-10-20 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4299731A (en) | 1980-02-06 | 1981-11-10 | Phillips Petroleum Company | Large pore volume olefin polymerization catalysts |
US4384086A (en) | 1980-02-06 | 1983-05-17 | Phillips Petroleum Company | Large pore volume olefin polymerization catalysts |
US4345055A (en) | 1980-02-06 | 1982-08-17 | Phillips Petroleum Company | Polymerization with titanium impregnated silica-chromium catalysts |
US4294724A (en) | 1980-02-06 | 1981-10-13 | Phillips Petroleum Company | Titanium impregnated silica-chromium catalysts |
US4618661A (en) | 1980-05-02 | 1986-10-21 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4422957A (en) | 1980-05-02 | 1983-12-27 | Phillips Petroleum Company | Methods of producing polyolefins using supported high efficiency polyolefin catalyst components |
US4425257A (en) | 1980-05-02 | 1984-01-10 | Phillips Petroleum Company | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4347158A (en) | 1980-05-02 | 1982-08-31 | Dart Industries, Inc. | Supported high efficiency polyolefin catalyst component and methods of making and using the same |
US4339559A (en) | 1980-05-21 | 1982-07-13 | Phillips Petroleum Company | Polymerization using silica from single phase controlled hydrolysis of silicate ester |
US4301034A (en) | 1980-05-21 | 1981-11-17 | Phillips Petroleum Company | Silica from single phase controlled hydrolysis of silicate ester |
US4328090A (en) | 1980-07-31 | 1982-05-04 | Exxon Research & Engineering Co. | Process for production of hydrogenated hydrocarbon polymers and catalyst useful therefore |
US4367352A (en) | 1980-12-22 | 1983-01-04 | Texaco Inc. | Oligomerized olefins for lubricant stock |
US4364841A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Phosphate containing support with zerovalent chromium |
US4397765A (en) | 1980-12-31 | 1983-08-09 | Phillips Petroleum Company | Phosphated alumina or aluminum phosphate chromium catalyst |
US4364854A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Acid gelling aluminum phosphate from concentrated mass and catalyst containing same |
US4444968A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Olefin polymerization with phosphate supported zerovalent chromium |
US4442274A (en) | 1980-12-31 | 1984-04-10 | Phillips Petroleum Company | Polymerization process using a phosphate containing support for vanadium catalyst |
US4364840A (en) | 1980-12-31 | 1982-12-21 | Phillips Petroleum Company | Phosphated silica-chromium catalyst with boron-containing cocatalyst |
US4444962A (en) | 1980-12-31 | 1984-04-24 | Phillips Petroleum Company | Polymerization process using catalysts with acid gelled aluminum phosphate base |
US4415715A (en) | 1981-06-11 | 1983-11-15 | The Goodyear Tire & Rubber Company | Catalysts for ring-opening copolymerization of cycloolefins |
US4391737A (en) | 1981-06-11 | 1983-07-05 | The Goodyear Tire & Rubber Company | Catalysts for ring-opening copolymerization of cycloolefins |
US4378306A (en) | 1981-09-17 | 1983-03-29 | Phillips Petroleum Company | Surface heat treatment of silica-containing catalyst base |
US4434280A (en) | 1981-09-17 | 1984-02-28 | Phillips Petroleum Company | Polymerization process using surface heat treated silica-containing catalyst base |
US4419268A (en) | 1981-11-20 | 1983-12-06 | Phillips Petroleum Company | Partially hydrolyzed silicate treatment of catalyst support |
US4424320A (en) | 1981-11-25 | 1984-01-03 | Phillips Petroleum Company | Polymerization with a silica base catalyst having titanium incorporated through use of peroxide |
US4382022A (en) | 1981-11-25 | 1983-05-03 | Phillips Petroleum Company | Silica having titanium incorporated through use of peroxide |
US4434243A (en) | 1982-03-09 | 1984-02-28 | Phillips Petroleum Company | Aqueous titanation of catalyst support containing chromium with solubilized Ti(OR)4 |
US4442275A (en) | 1982-03-09 | 1984-04-10 | Phillips Petroleum Company | Polymerization process using catalyst having aqueous titanation of support with solubilized Ti(OR)4 |
US4513166A (en) | 1982-03-23 | 1985-04-23 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the low polymerization of isobutene |
US4454367A (en) | 1982-03-23 | 1984-06-12 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the low polymerization of isobutene |
EP0090569B1 (de) | 1982-03-23 | 1986-01-08 | Toa Nenryo Kogyo Kabushiki Kaisha | Verfahren zur Oligomerisierung von Isobuten |
US4424139A (en) | 1982-03-30 | 1984-01-03 | Phillips Petroleum Company | Catalyst comprising a phosphate and with a bis-(cyclopentadienyl)chromium(II) compound |
US4444966A (en) | 1982-05-05 | 1984-04-24 | Phillips Petroleum Company | Polymerization using phosphated alumina or aluminum phosphate chromium catalyst |
US4719271A (en) | 1982-05-21 | 1988-01-12 | Phillips Petroleum Company | Polymerization of olefins |
US4536358A (en) | 1982-06-17 | 1985-08-20 | Uop Inc. | Process for the production of high surface area catalyst supports |
US4395578A (en) | 1982-06-18 | 1983-07-26 | Texaco, Inc. | Oligomerization of olefins over boron trifluoride in the presence of a transition metal cation-containing promoter |
US4403088A (en) | 1982-08-05 | 1983-09-06 | The Goodyear Tire & Rubber Company | Plastic resin prepared from meta or para-diisopropenylbenzene and method of preparation |
US4439543A (en) | 1982-08-05 | 1984-03-27 | Phillips Petroleum Company | Co Reduced chromyl halide on silica catalyst |
EP0101205B1 (de) | 1982-08-13 | 1987-01-07 | Exxon Research And Engineering Company | Verfahren zur Herstellung von Polyisobutylen |
US4555496A (en) | 1982-08-20 | 1985-11-26 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using the same |
US4436948A (en) | 1982-09-07 | 1984-03-13 | Phillips Petroleum Company | Catalyst compositions |
US4780513A (en) | 1982-09-30 | 1988-10-25 | Exxon Research & Engineering Co. | Modified Lewis acid catalyzed polymerization |
US4520222A (en) | 1982-12-10 | 1985-05-28 | Phillips Petroleum Company | Polymerization catalyst and deodorizing agent and process of use |
US4425226A (en) | 1982-12-10 | 1984-01-10 | Phillips Petroleum Company | Polymerization catalyst and deodorizing agent |
US4444904A (en) | 1983-05-26 | 1984-04-24 | Exxon Research & Engineering Co. | Process for synthesizing a multicomponent acidic catalyst composition containing zirconium by an organic solution method |
US4824921A (en) | 1983-06-28 | 1989-04-25 | Exxon Research & Engineering Company | Petroleum resins and their production |
US4558170A (en) | 1983-06-29 | 1985-12-10 | Exxon Research & Engineering Co. | Polyisobutylene process |
US4801364A (en) | 1983-07-15 | 1989-01-31 | Uop | Separation and conversion processes using metal aluminophosphates |
US4520121A (en) | 1983-10-28 | 1985-05-28 | Inkrott Kenneth E | Magnesium halide hydrates and polymerization catalysts prepared therefrom |
US4699962A (en) | 1984-01-30 | 1987-10-13 | Phillips Petroleum Company | Olefin polymerization |
US4791086A (en) | 1984-01-30 | 1988-12-13 | Phillips Petroleum Company | Olefin polymerization |
US4824554A (en) | 1984-04-13 | 1989-04-25 | Uop | Processes for the use of cobalt-aluminum-phosphorus-silicon-oxide molecular sieve compositions |
US4846956A (en) | 1984-04-13 | 1989-07-11 | Uop | Manganese-aluminum-phosphorus-silicon-oxide Molecular sieves |
US4793833A (en) | 1984-04-13 | 1988-12-27 | Uop | Manganese-aluminum-phosphorus-silicon-oxide molecular sieves |
US4894213A (en) | 1984-04-13 | 1990-01-16 | Uop | Arsenic-aluminum-phosphorus-silicon-oxide molecular sieve compositions |
US4744970A (en) | 1984-04-13 | 1988-05-17 | Union Carbide Corporation | Cobalt-aluminum-phosphorus-silicon-oxide molecular sieves |
US4686092A (en) | 1984-04-13 | 1987-08-11 | Union Carbide Corporation | Manganese-aluminum-phosphorus-silicon-oxide molecular sieves |
US4547479A (en) | 1984-07-02 | 1985-10-15 | Phillips Petroleum Company | Polyphosphate in chromium catalyst support |
US4588703A (en) | 1984-07-18 | 1986-05-13 | Phillips Petroleum Company | Polyolefin polymerization process and catalyst |
US4822707A (en) | 1984-07-30 | 1989-04-18 | Ricoh Co., Ltd. | Positively chargeable toners for use in dry type electrophotography comprising a blue dye lake charge control agent |
US4567153A (en) | 1984-08-13 | 1986-01-28 | Exxon Research & Engineering Co. | Polymerization catalyst comprising copulverized solid magnesium compound and solid halide of scandium |
US4732936A (en) | 1984-11-20 | 1988-03-22 | Hercules Incorporated | Alpha methylstyrene and para methylstyrene copolymers |
US4618595A (en) | 1984-12-12 | 1986-10-21 | Phillips Petrolem Company | Polymerization of olefins |
US4575538A (en) | 1984-12-20 | 1986-03-11 | Phillips Petroleum Company | Olefin polymerization |
US4596862A (en) | 1984-12-24 | 1986-06-24 | Phillips Petroleum Company | Olefin polymerization using chromium on fluorided aluminophosphate |
US4619980A (en) | 1985-04-01 | 1986-10-28 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
US4681866A (en) | 1985-04-01 | 1987-07-21 | Phillips Petroleum Company | Polymerization catalyst, method of making and use therefor |
EP0202965B1 (de) | 1985-04-09 | 1989-09-27 | Kawasaki Steel Corporation | Oligomere Harze und Verfahren zu deren Herstellung |
US4757044A (en) | 1985-04-17 | 1988-07-12 | The Standard Oil Company | Lanthanide metal salts of heteropolyanions as catalysts for alcohol conversion |
US4689436A (en) | 1985-05-13 | 1987-08-25 | Idemitsu Kosan Company Limited | Process for producing alkenyl-aromatic hydrocarbon derivatives |
US5330949A (en) | 1985-06-17 | 1994-07-19 | Idemitsu Petrochemical Company, Ltd. | Method for producing polyolefin |
US4604438A (en) | 1985-08-12 | 1986-08-05 | Uop Inc. | High temperature thermoset terpolymers |
US4626519A (en) | 1985-09-06 | 1986-12-02 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using same |
US4680351A (en) | 1985-09-06 | 1987-07-14 | Phillips Petroleum Company | Supported polyolefin catalyst components and methods of making and using same |
US4711866A (en) | 1986-02-05 | 1987-12-08 | Exxon Chemical Patents Inc. | Adamantane polymerization catalyst |
US4684707A (en) | 1986-02-10 | 1987-08-04 | Exxon Chemical Patents Inc. | Low color, high softening point aromatic resin and method for its production |
US5008468A (en) | 1986-04-16 | 1991-04-16 | Catalytica, Inc. | Acid catalyzed process |
US4868343A (en) | 1986-04-16 | 1989-09-19 | Catalytica Inc. | Acid catalyzed process |
US4954562A (en) | 1986-04-21 | 1990-09-04 | American Colloid Company | Water absorbent resins |
US4677174A (en) | 1986-04-21 | 1987-06-30 | American Colloid Company | Water absorbent styrene-acrylic acid copolymers |
US4846066A (en) | 1986-08-29 | 1989-07-11 | Ici Australia Operations Proprietary Limited | Detonator system |
US5110778A (en) | 1986-10-17 | 1992-05-05 | Olah George A | Boron aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US4721559A (en) | 1986-10-17 | 1988-01-26 | Olah George A | Boron, aluminum and gallium perfluoro alkanesulfonate and resinsulfonate catalysts |
US4814308A (en) | 1986-10-21 | 1989-03-21 | Basf Aktiengesellschaft | Preparation of homopolymers and copolymers of ethene by Phillips catalysis |
US4929800A (en) | 1986-10-22 | 1990-05-29 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
US4719190A (en) | 1986-10-22 | 1988-01-12 | University Of Florida | Hydrocarbon conversion and polymerization catalyst and method of making and using same |
EP0273627B1 (de) | 1986-12-12 | 1994-06-22 | Exxon Chemical Patents Inc. | Festbettverfahren für die Polymerisation von flüssigen Butenen |
US4982045A (en) | 1986-12-12 | 1991-01-01 | Exxon Chemical Patents Inc. | Fixed bed process for polymerizing liquid butenes |
US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US4788171A (en) | 1987-02-02 | 1988-11-29 | Philips Petroleum Company | Phosphated calcined alumina |
US4952544A (en) | 1987-03-05 | 1990-08-28 | Uop | Stable intercalated clays and preparation method |
US4957889A (en) | 1987-03-05 | 1990-09-18 | Uop | Stable intercalated clays and preparation method |
US4987200A (en) | 1987-06-08 | 1991-01-22 | Exxon Chemical Patents Inc. | Preparation of polymer incorporating masked functional group-containing monomers |
US4849572A (en) | 1987-12-22 | 1989-07-18 | Exxon Chemical Patents Inc. | Process for preparing polybutenes having enhanced reactivity using boron trifluoride catalysts (PT-647) |
US4948768A (en) | 1988-05-26 | 1990-08-14 | Phillips Petroleum Company | Catalyst composition for oligomerization of olefins |
US4879425A (en) | 1988-05-26 | 1989-11-07 | Phillips Petroleum Company | Oligomerization of olefins |
US5017662A (en) | 1988-09-15 | 1991-05-21 | Exxon Chemical Patents, Inc. | Selective catalytic process for preparing N-halothiosulfonamide modified EPDM terpolymers |
US4956420A (en) | 1988-09-15 | 1990-09-11 | Exxon Chemical Patents Inc. | Selective catalytic process for controlled modification of ethylene-(alpha-olefin)-diene monomer terpolymer with halothisulfonamide |
US4900704A (en) | 1988-09-29 | 1990-02-13 | Phillips Petroleum Company | Peptized and phosphated inorganic oxides and catalysts supported on said oxides |
US4952739A (en) | 1988-10-26 | 1990-08-28 | Exxon Chemical Patents Inc. | Organo-Al-chloride catalyzed poly-n-butenes process |
EP0367386B1 (de) | 1988-10-26 | 1995-07-05 | Exxon Chemical Patents Inc. | Verfahren zur Herstellung von Poly-n-Butylenen aus einer Butylenschnitte mittels Aluminiumchloridkatalysatoren |
EP0367385B1 (de) | 1988-10-26 | 1995-11-15 | Exxon Chemical Patents Inc. | Verfahren zur Herstellung von Poly-n-Butylenen mittels Organo-Aluminium-Halogenidkatalysatoren |
US5326921A (en) | 1988-10-26 | 1994-07-05 | Exxon Chemical Patents Inc. | AlCl3 -catalyzed process for preparing poly-N-butenes from mixed butenes |
US5177288A (en) | 1988-11-25 | 1993-01-05 | Exxon Chemical Patents Inc. | Polybutene process |
US4935576A (en) | 1988-11-25 | 1990-06-19 | Exxon Chemical Patents Inc. | Polybutene process |
US4912279A (en) | 1988-12-29 | 1990-03-27 | Uop | Solid phosphoric acid catalyst |
US5081086A (en) | 1988-12-29 | 1992-01-14 | Uop | Solid phosphoric acid catalyst |
US5171791A (en) | 1989-03-13 | 1992-12-15 | The Dow Chemical Company | Anionic polymerization process |
US5225493A (en) | 1989-03-13 | 1993-07-06 | The Dow Chemical Company | Anionic polymerization process |
EP0391697B1 (de) | 1989-04-04 | 1994-07-13 | Exxon Chemical Patents Inc. | Ozonbeständige Butyl-Elastomere |
US5198563A (en) | 1989-08-10 | 1993-03-30 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5331104A (en) | 1989-08-10 | 1994-07-19 | Phillips Petroleum Company | Chromium compounds and uses thereof |
US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
US5073531A (en) | 1990-05-07 | 1991-12-17 | Phillips Petroleum Company | Olefin polymerization catalysts and preparation method |
US5284811A (en) | 1990-05-14 | 1994-02-08 | Phillips Petroleum Company | Polymerization catalysts and processes |
US5444132A (en) | 1990-05-14 | 1995-08-22 | Phillips Petroleum Company | Controlled addition of alkali or alkaline earth salts to a chromium oxide catalyst |
US5075394A (en) | 1990-06-07 | 1991-12-24 | Phillips Petroleum Company | Olefin polymerization using supported pentadienyl derivative-transition metal complexes |
US5200379A (en) | 1990-06-07 | 1993-04-06 | Phillips Petroleum Company | Olefin polymerization using supported pentadienyl derivative-transition metal complexes |
US5321106A (en) | 1990-07-03 | 1994-06-14 | The Dow Chemical Company | Addition polymerization catalyst with oxidative activation |
US5191140A (en) | 1990-09-20 | 1993-03-02 | Idemitsu Petrochemical Co., Ltd. | Process for producing olefin oligomer |
US5326923A (en) | 1990-09-26 | 1994-07-05 | Catalytica, Inc. | Method for regenerating certain acidic hydrocarbon conversion catalysts by solvent extraction |
US5365010A (en) | 1990-09-26 | 1994-11-15 | Catalytica, Inc. | Method for regenerating Lewis acid-promoted transition alumina catalysts used for isoparaffin alkylation by calcination |
US5328956A (en) | 1990-11-13 | 1994-07-12 | Kao Corporation | Propylene (co)polymer and process for the preparation of the same |
US5190844A (en) | 1990-12-07 | 1993-03-02 | Nippon Paint Co., Ltd. | Production of surface-modified organic particles |
US5139761A (en) | 1990-12-17 | 1992-08-18 | Uop | Modified zeolite omega and processes for preparing and using same |
US5412024A (en) | 1991-04-09 | 1995-05-02 | Idemitsu Kosan Co., Ltd. | Thermoplastic resin composition |
US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5191132A (en) | 1991-05-09 | 1993-03-02 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5459218A (en) | 1991-05-09 | 1995-10-17 | Phillips Petroleum Company | Syndiotactic polypropylene prepared using silyl bridged metallocenes |
US5401817A (en) | 1991-05-09 | 1995-03-28 | Phillips Petroleum Company | Olefin polymerization using silyl-bridged metallocenes |
US5393911A (en) | 1991-05-09 | 1995-02-28 | Phillips Petroleum Company | Cyclopentadiene type compounds and method for making |
US5436305A (en) | 1991-05-09 | 1995-07-25 | Phillips Petroleum Company | Organometallic fluorenyl compounds, preparation, and use |
US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
US5288677A (en) | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5409873A (en) | 1991-06-28 | 1995-04-25 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5414177A (en) | 1991-06-28 | 1995-05-09 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
US5113034A (en) | 1991-08-05 | 1992-05-12 | Exxon Research And Engineering Company | Dimerization catalyst and process therefor |
US5283301A (en) | 1991-08-23 | 1994-02-01 | Phillips Petroleum Company | Olefin polymerization with particulate gel-containing catalyst |
US5198512A (en) | 1991-12-16 | 1993-03-30 | Phillips Petroleum Company | Polymerization catalyst and process |
US5328881A (en) | 1991-12-16 | 1994-07-12 | Phillips Petroleum Company | Polymerization catalyst and process |
US5338812A (en) | 1991-12-24 | 1994-08-16 | Phillips Petroleum Company | Olefin polymerization |
US5426080A (en) | 1991-12-24 | 1995-06-20 | Phillips Petroleum Company | Olefin polymerization |
US5453410A (en) | 1992-01-06 | 1995-09-26 | The Dow Chemical Company | Catalyst composition |
US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
US5399635A (en) | 1992-05-15 | 1995-03-21 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
EP0575866B1 (de) | 1992-06-16 | 1999-08-04 | Phillips Petroleum Company | Olefinpolymerisation, Katalysator und Vorprodukt |
US5362825A (en) | 1992-07-13 | 1994-11-08 | Phillips Petroleum Company | Catalysts for polymerizing olefins and methods |
US5206314A (en) | 1992-08-31 | 1993-04-27 | Phillips Petroleum Company | Polyolefin polymerization process, process of producing catalyst, and catalyst |
US5461127A (en) | 1992-09-22 | 1995-10-24 | Idemitsu Kosan Co., Ltd. | Polymerization catalysts and process for producing polymers |
US5382420A (en) | 1992-09-25 | 1995-01-17 | Exxon Research & Engineering Company | ECR-33: a stabilized rare-earth exchanged Q type zeolite |
US5414187A (en) | 1992-10-30 | 1995-05-09 | Catalytica, Inc. | Acid catalyst and use thereof in alkylation of olefins with tertiary alkanes |
US5272124A (en) | 1992-11-20 | 1993-12-21 | Phillips Petroleum Company | Ethylene polymerization catalyst comprising a nickel compound and an aromatic carboxylic acid compound |
US5322910A (en) | 1992-11-20 | 1994-06-21 | Phillips Petroleum Company | Ethylene polymerization |
US5332708A (en) | 1992-11-23 | 1994-07-26 | Phillips Petroleum Company | Catalyst compositions and catalytic processes |
US5324881A (en) | 1992-12-22 | 1994-06-28 | Mobil Oil Corp. | Supported heteropoly acid catalysts for isoparaffin-olefin alkylation reactions |
US5366945A (en) | 1992-12-22 | 1994-11-22 | Mobil Oil Corp. | Supported heteropoly acid catalysts |
US5350819A (en) | 1993-02-19 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
US5491214A (en) | 1993-03-26 | 1996-02-13 | Hercules Incorporated | Process for hydrotreating resins to lighten color |
US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
US5347026A (en) | 1993-06-11 | 1994-09-13 | Phillips Petroleum Company | Fluorene compounds and methods for making |
US5354721A (en) | 1993-06-22 | 1994-10-11 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5414180A (en) | 1993-07-14 | 1995-05-09 | Phillips Petroleum Company | Organo-aluminoxy product and use |
US5418303A (en) | 1993-09-03 | 1995-05-23 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
US5350726A (en) | 1993-09-03 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
US5403803A (en) | 1993-09-28 | 1995-04-04 | Exxon Chemical Patents Inc. | Carbocationic catalyst and process for its use |
US5371154A (en) | 1993-11-09 | 1994-12-06 | Uop | Process for forming acid functionalized organically-bridged polysilsesquioxanes |
US5475162A (en) | 1993-11-09 | 1995-12-12 | Uop | Acid functionalized organically-bridged polysilsesquioxanes as catalysts for acid catalyzed reactions |
US5561095A (en) | 1994-03-31 | 1996-10-01 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
US5648580A (en) | 1994-03-31 | 1997-07-15 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
US5446102A (en) | 1994-08-10 | 1995-08-29 | Bridgeston, Corporation | Olefin metathesis catalysts for degelling polymerization reactors |
US5633419A (en) | 1994-08-12 | 1997-05-27 | The Dow Chemical Company | Polymerization of olefins in the presence of a supported catalyst |
US5710225A (en) | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
Non-Patent Citations (86)
Cited By (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7094823B2 (en) * | 2000-03-27 | 2006-08-22 | Mohammed Belbachir | Composition and method for catalysis using bentonites |
US20030069446A1 (en) * | 2000-03-27 | 2003-04-10 | Mohammed Belbachir | Composition and method for catalysis using bentonites |
US7717893B2 (en) | 2004-06-04 | 2010-05-18 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
US7905872B2 (en) | 2004-06-04 | 2011-03-15 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate |
US8419701B2 (en) | 2005-01-10 | 2013-04-16 | The Procter & Gamble Company | Absorbent articles with stretch zones comprising slow recovery elastic materials |
US20060167434A1 (en) * | 2005-01-26 | 2006-07-27 | The Procter & Gamble Company | Disposable pull-on diaper having a low force, slow recovery elastic waist |
US8029488B2 (en) | 2005-01-26 | 2011-10-04 | The Procter & Gamble Company | Disposable pull-on diaper having a low force, slow recovery elastic waist |
JP2006326469A (ja) * | 2005-05-25 | 2006-12-07 | Nippon Petrochemicals Co Ltd | 固体リン酸触媒およびそれを用いたオレフィンの二量化反応方法 |
US8203025B2 (en) * | 2005-05-25 | 2012-06-19 | Nippon Oil Corporation | Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same |
US20090099400A1 (en) * | 2005-05-25 | 2009-04-16 | Nippon Oil Corporation | Solid phosphoric acid catalyst and methods of olefin dimerization reaction with the same |
WO2006135357A1 (en) * | 2005-06-08 | 2006-12-21 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
CN101198303B (zh) * | 2005-06-08 | 2011-12-28 | 宝洁公司 | 包括缓慢恢复的弹性体的吸收制品 |
WO2008012217A3 (en) * | 2006-07-26 | 2008-03-06 | Total Petrochemicals France | Process for reducing residuals content in vinyl aromatic polymers |
US20100113707A1 (en) * | 2006-07-26 | 2010-05-06 | Total Petrochemicals Research Feluy | Process for Reducing Residuals Content in Vinyl Aromatic Polymers |
CN101511883B (zh) * | 2006-07-26 | 2012-02-01 | 道达尔石化法国公司 | 减少乙烯基芳族聚合物中残留物含量的方法 |
US8541542B2 (en) | 2006-07-26 | 2013-09-24 | Total Research & Technology Feluy | Process for reducing residuals content in vinyl aromatic polymers |
EP1882704A1 (de) * | 2006-07-26 | 2008-01-30 | Total Petrochemicals France | Verfahren zum Verringern von Rückständen in aromatische Polymere |
EA017071B1 (ru) * | 2006-07-26 | 2012-09-28 | Тотал Петрокемикалс Франс | Способ снижения содержания остаточных веществ в стирольном полимере |
US8828916B2 (en) | 2006-12-28 | 2014-09-09 | Chevron Oronite Company Llc | Method to prepare nonylated diphenylamine using recycle sequential temperatures |
US8323257B2 (en) | 2007-11-21 | 2012-12-04 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate and method for making the same |
US20090157035A1 (en) * | 2007-12-13 | 2009-06-18 | The Protect & Gamble Company | Absorbent Article with Composite Sheet Comprising Elastic Material |
US20090157036A1 (en) * | 2007-12-13 | 2009-06-18 | Ekaterina Anatolyevna Ponomarenko | Absorbent Article With Composite Sheet Comprising Elastic Material |
US8235959B2 (en) | 2007-12-13 | 2012-08-07 | The Procter Gamble Company | Absorbent article with composite sheet comprising elastic material |
US20090318884A1 (en) * | 2008-06-20 | 2009-12-24 | Axel Meyer | Absorbent structures with immobilized absorbent material |
US8502012B2 (en) | 2009-06-16 | 2013-08-06 | The Procter & Gamble Company | Absorbent structures including coated absorbent material |
US20100318049A1 (en) * | 2009-06-16 | 2010-12-16 | Axel Meyer | Absorbent Structures Including Coated Absorbent Material |
WO2012064909A1 (en) | 2010-11-12 | 2012-05-18 | The Procter & Gamble Company | Elastomeric compositions that resist disintegration |
WO2012064908A1 (en) | 2010-11-12 | 2012-05-18 | The Procter & Gamble Company | Elastomeric compositions that resist force loss |
US9017305B2 (en) | 2010-11-12 | 2015-04-28 | The Procter Gamble Company | Elastomeric compositions that resist force loss and disintegration |
US8946365B2 (en) | 2012-01-18 | 2015-02-03 | Eastman Chemical Company | Low molecular weight polystyrene resin and methods of making and using the same |
US8829105B2 (en) | 2012-01-18 | 2014-09-09 | Eastman Chemical Company | Low molecular weight polystyrene resin and methods of making and using the same |
WO2013109673A2 (en) | 2012-01-18 | 2013-07-25 | Eastman Chemical Company | Low molecular weight polystyrene resin and methods of making and using the same |
US11590033B2 (en) | 2013-05-03 | 2023-02-28 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US11135100B2 (en) | 2013-05-03 | 2021-10-05 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US9533067B2 (en) | 2013-05-03 | 2017-01-03 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US9561299B2 (en) | 2013-05-03 | 2017-02-07 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US9687580B2 (en) | 2013-05-03 | 2017-06-27 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US10010645B2 (en) | 2013-05-03 | 2018-07-03 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
US10485713B2 (en) | 2013-05-03 | 2019-11-26 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
EP2799606A1 (de) | 2013-05-03 | 2014-11-05 | Mondi Gronau GmbH | Elastisches Laminat |
US11179278B2 (en) | 2013-05-03 | 2021-11-23 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
WO2014179429A1 (en) | 2013-05-03 | 2014-11-06 | The Procter & Gamble Company | Absorbent articles comprising stretch laminates |
DE202014011486U1 (de) | 2013-05-03 | 2021-06-10 | The Procter & Gamble Company | Absorptionsartikel, die Stretch-Laminate umfassen |
US10959887B2 (en) | 2016-08-12 | 2021-03-30 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11382798B2 (en) | 2016-08-12 | 2022-07-12 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11596557B2 (en) | 2016-08-12 | 2023-03-07 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11617687B2 (en) | 2016-08-12 | 2023-04-04 | The Procter & Gamble Company | Methods and apparatuses for assembling elastic laminates with different bond densities for absorbent articles |
US11642250B2 (en) | 2016-08-12 | 2023-05-09 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11872113B2 (en) | 2016-08-12 | 2024-01-16 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US11877914B2 (en) | 2016-08-12 | 2024-01-23 | The Procter & Gamble Company | Method and apparatus for assembling absorbent articles |
US12070378B2 (en) | 2016-08-12 | 2024-08-27 | The Procter And Gamble Company | Elastic laminates and methods for assembling elastic laminates for absorbent articles |
US11008444B2 (en) | 2016-12-19 | 2021-05-18 | Eastman Chemical Company | Tires comprising polyindane resins and uses thereof |
US10851270B2 (en) | 2016-12-19 | 2020-12-01 | Eastman Chemical Company | Adhesives comprising polyindane resins |
US11944522B2 (en) | 2019-07-01 | 2024-04-02 | The Procter & Gamble Company | Absorbent article with ear portion |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6310154B1 (en) | Solid acids as catalysts for the preparation of hydrocarbon resins | |
US5561095A (en) | Supported lewis acid catalysts for hydrocarbon conversion reactions | |
DE69521990T2 (de) | Aus supersäuren hergestellte lewissäure enthaltende trägerkatalysatoren, die für umwandlungsreaktionen von kohlenwasserstoffen verwendbar sind. | |
US6646067B2 (en) | Petroleum resins and their production with BF3 catalyst | |
GB1581199A (en) | Preparation of oligomers of alpha-olefins | |
US5932778A (en) | Shutdown process for olefin polymerization reactor | |
EP1208125A1 (de) | Petroleumharze und ihre herstellung mit bf3 katalysator | |
JPS6217566B2 (de) | ||
JPS6136005B2 (de) | ||
MXPA96004507A (en) | Lewis acid catalysts supported for hydrocarbon conversion reactions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: HERCULES INCORPORATED, DELAWARE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BABCOCK, LAURA M.;MORRELL, DENNIS C.;REEL/FRAME:009220/0971 Effective date: 19980415 |
|
AS | Assignment |
Owner name: BANK OF AMERICA, N.A., AS COLLATERAL AGENT, NORTH Free format text: NOTICE OF GRANT OF SECURITY INTEREST;ASSIGNORS:HERCULES INCORPORATED, A DELAWARE CORPORATION;HERCULES CREDIT, INC., A DELAWARE CORPORAION;HERCULES FLAVOR, INC., A DELAWAARE CORPORATION;AND OTHERS;REEL/FRAME:011437/0438 Effective date: 20001114 |
|
AS | Assignment |
Owner name: EASTMAN CHEMICAL RESING, INC., TENNESSEE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:HERCULES INCORPORATED;REEL/FRAME:011822/0393 Effective date: 20010501 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
CC | Certificate of correction | ||
LAPS | Lapse for failure to pay maintenance fees | ||
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20051030 |
|
AS | Assignment |
Owner name: HERCULES INCORPORATED, DELAWARE Free format text: PATENT TERMINATION BA-011437-0438;ASSIGNOR:BANK OF AMERICA, N.A., AS COLLATERAL AGENT;REEL/FRAME:021901/0627 Effective date: 20081113 |