US3860457A - A ductile iron and method of making it - Google Patents
A ductile iron and method of making it Download PDFInfo
- Publication number
- US3860457A US3860457A US377035A US37703573A US3860457A US 3860457 A US3860457 A US 3860457A US 377035 A US377035 A US 377035A US 37703573 A US37703573 A US 37703573A US 3860457 A US3860457 A US 3860457A
- Authority
- US
- United States
- Prior art keywords
- ductile iron
- weight
- molybdenium
- iron
- bainite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001141 Ductile iron Inorganic materials 0.000 title claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 title description 3
- 238000005275 alloying Methods 0.000 claims abstract description 18
- 229910001566 austenite Inorganic materials 0.000 claims abstract description 14
- 229910001563 bainite Inorganic materials 0.000 claims abstract description 13
- 239000010949 copper Substances 0.000 claims abstract description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052718 tin Inorganic materials 0.000 claims abstract description 9
- 238000010791 quenching Methods 0.000 claims abstract description 6
- 230000000171 quenching effect Effects 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 13
- 239000011572 manganese Substances 0.000 claims description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000003754 machining Methods 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 230000000717 retained effect Effects 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract description 14
- 238000005266 casting Methods 0.000 abstract description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052759 nickel Inorganic materials 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 229910001562 pearlite Inorganic materials 0.000 abstract description 4
- 238000009661 fatigue test Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910000760 Hardened steel Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 229920001074 Tenite Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- -1 ferritepearlite Inorganic materials 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C37/00—Cast-iron alloys
- C22C37/04—Cast-iron alloys containing spheroidal graphite
Definitions
- said iron UNITED STATES PATENTS contains molybdenium 0.15 0.22 by weight and 2,324,322 7/1943 Reese et a1.
- 148/35 X less than 0.2 by weight of tin and/or less than 1.0 2,485,760 /1949 Millis et al across 75/123 CB by weight of copper.
- the present invention relates to a ductile iron alloyed with molybdenium and manganese and which has, after an isothermal heat treatment, a bainitic microstructure with a considerable amount of retained austenite.
- Ductile iron is generally used unalloyed or alloyed in various ways, and with, for example, a ferrite, ferritepearlite, pearlite, annealed martensite, or bainitic microstructure.
- the most essential characteristic of the ductile iron according to the present invention is its bainitic microstructure in combination with a considerable amount of retained austenite.
- FIG. 1 shows an example of such a ductile iron; the S-curves are indicated by solid lines and the curve which illustrates the cooling of the piece by a broken line in the time-temperature coordiate system.
- a bainitizing process in which pieces manufactured from unalloyed ductile iron are heattreated isothermally.
- the cast piece is reheated to the austenitization temperature after the casting process and is then cooled rapidly in a hot bath at an appropriate temperature.
- the piece is kept in the bath and thereby at a constant temperature until the bainite reaction has taken place, whereafter the piece is cooled to room temperature.
- the S-curves according to this process are indicated by solid lines and the curve illustrating the cooling of the piece by a broken line in a time-temperature coordiate system.
- the present invention provides a ductile iron of the character described, which comprises as alloying elements molybdenium 0.10 0.26 by weight and manganese 0.3 1.4 by weight and possibly also an alloying'element which promotes the formation of a pearlitic micro-structure during the casting and thereby accelerates the austenization and which consists of nickel in an amount of less than 2.5 by weight and at least one of the elements tin and copper.
- the ductile iron and its bainitization process according to the present invention can be applied to both thick and thin castings. In this process, the alloying ratios need not be changed according to the wall thickness of the casting.
- This ductile iron is rather mildly alloyed so that the alloying elements do not raise its price very much.
- the retained austenite present in this ductile iron in addition to bainite, gives it toughness and makes it capable of being hardened by machining.
- Hardening by machining creates a compression stress at the surface and thereby increases the fatigue strength. Its elongation at rupture is great.
- the ductile iron according to the invention contains the conventional amounts of carbon, silicon, phosphorus, sulphur, and magnesium, and as actual alloying elements, molybdenium 0.10 0.26 preferably 0.15 0.22 and manganese 0.3 1.4
- a ductile iron so alloyed is as such suitable for isothermal bainitization. If an amount of 0.03 0.2 of tin, 0.3 1.0 of copper, or 0.5 2.5 of nickel is also added to the alloy, a pearlitic micro-structure is obtained in the piece in as cast condition, and when this structure is reheated to the austenitization temperature, itbecomcs austenitized considerably faster than a micro-structure which contains free ferrite, and thereby the heattreatment period is shortened. Tin, copper and nickel have a similar effect on the pearlite formation and therefore they can entirely or partly replace each other; for example, a one-third batch of each of the three additives can be used.
- a ductile iron according to the invention, bainitized isothermally, is an excellent raw material for gears, especially when the teeth cannot be finishedor are not worth finishing by grinding.
- An example of such a case is gears with inside teeth. It is also applicable to all kinds of machine elements exposed to fatigue stress loads. Examples of such machine elements are, in addition to gears, gear shafts, sprockets, support wheels or rolls which are to roll against a hard surface, cams, crankshafts, support rings, and various parts subject to wear and tear, such as friction plates.
- FIG. 1 shows, in time-temperature diagram, some characteristical curves for a highly alloyed ductile iron belonging to the prior art
- FIG. 2 shows corresponding curves for a known unalloyed ductile iron
- FIG. 3 shows corresponding curves for a ductile iron according to the present invention.
- a ductile iron piece according to the invention is manufactured, for example, in the following manner: A disk-shaped blank with a diameter of 150 mm and a thickness of mm is cast from a melt which contains as alloying elements carbon (C) 3.5 3.7 silicon (Si) 2.1 2.4 manganese (Mn) 0.50 0.55 molybdenium (M0) 0.2 0.22 and copper (Cu) 0.7 0.8 and a conventional amount of magnesium.
- the blank is allowed to cool freely, or its treatment is continued while it is hot.
- the blank is transferred to a furnace with a temperature of 900C. In the furnace, the micro-structure of the blank is transformed into austenite.
- the blank After an austenitization of 2 hours, the blank is quenched into a salt bath at a temperature of 370C.
- the quantity of the bath is 200 kg and it contains 1 part of sodium nitrate (NaNO and 1 part of potassium nitrate (KNO).
- the bath has been provided with a agitation device and with a thermostat.
- the test piece is kept in the bath from minutes to 4 hours, depending on the desired amount of bainite.
- the blank is removed from the bath and allowed to cool freely. Thereafter, the blank contains, for example, bainite about 50 by vol., austenite about 40 by vol., and graphite about 10 by vol.
- a suitable amount of retained austenite is -50 by vol.
- a ductile iron containing less austenite is not capable of being work hardened by machining and a ductile iron containing more austenite is not strong enough.
- FIG. 3 The isothermal heat-treatment of a ductile iron according to the invention is illustrated in FIG. 3 in a time-temperature coordinate system.
- the solid lines indicate the S-curves of the ductile iron.
- the broken line indicates the cooling curve of the piece.
- An isothermally bainitized blank, cast from a ductile iron alloyed according to the invention, is of a very even qualityand suitable for machining. It has been verified by tensile strength tests that its elongation, when a tensile strength of 1 10 kp/mm is used, is about 10 which is high when compared to the respective value of a highly alloyed bainitic ductile iron or a quenched and tempered ductile iron of the same strength.
- the tensile strength and elongation of some bainitized ductile irons having an alloy ratio according to the present invention are as follows:
- the retained austenite in a ductile iron according to the invention makes it capable of being hardened by machining and thereby capable of enduring a very fatiguing load.
- a bending fatigue test with a turned and polished test bar of 12 mm gives a value of 50 kp/mm which is high compared to the respective values of other ductile iron.
- a bending fatigue test with a notch bar of 12 mm into which there has been turned a groove with an angle of 60 and with a bottom rounding radius of 1.0 mm gives a value of 40 kplmm which is high even when compared to steels.
- the ratio of the values obtained from fatigue tests with the same SG- iron i.e., the ratio of the smooth bar value 50 kp/mm to the value 40 kp/mm of the notched bar, namely, 1.25, called the notch effect, is very low.
- Rolling fatigue tests with a ductile iron according to the invention gave the following values.
- the composition of the SG-iron used in the test was: C 3.66 Si 2.24 Mn 0.54 Mo 0.22 Cu 0.78 P 0.02 and S 0.008 It was heat-treated so that the micro-structure contained bainite about 53 by vol., austenite about 37 by ml, and graphite about 10 by vol.
- the Hertzian contact stress was determined in a rotary fatigue test and was comparable to the values given in DIN 3990 El 9.
- the counter gear was case-hardened steel (DIN 1720, 15CrNi6) with surface hardeners 58-68 HRC.
- a ductile iron especially applicable to machine elements exposed to fatigue stresses containing as alloying elements molybdenium 0.10-0.26 per cent by weight and manganese 0.3-1.4 per cent by weight and having a microstructure of isothermal bainite and 20 to' 50% by volume of retained austenite enabling work hardening of the ductile iron in use when exposed to said fatigue stresses or by machining.
- a ductile iron as in claim 1 containing tin up to 0.2% by weight.
- a ductile iron as in claim 1 containing copper up to 1.0% by weight.
- a method of producing an austenitic-bainitic ductile iron comprising austenitizing a ductile iron containing as alloying elements molybdenium 0.10-0.26 per cent by weight and manganese 0.3-l.4 per cent by weight by heating it to the austenitization temperature and austenitizing it, then quenching it in a hot bath to form isothermal bainite, and cooling it further when the bainitic ductile iron so transformed still contains 20 to 50% by volume of retained austenite.
- a method as in claim 5 including machining the ductile iron before quenching it.
- a machine element constructed of the ductile iron ofclaiml.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI199772 | 1972-07-12 | ||
FI199672A FI49732C (fi) | 1972-07-12 | 1972-07-12 | Seostettu SG-rauta. |
Publications (1)
Publication Number | Publication Date |
---|---|
US3860457A true US3860457A (en) | 1975-01-14 |
Family
ID=26156551
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US377035A Expired - Lifetime US3860457A (en) | 1972-07-12 | 1973-07-06 | A ductile iron and method of making it |
Country Status (11)
Country | Link |
---|---|
US (1) | US3860457A (de) |
JP (1) | JPS553422B2 (de) |
CA (1) | CA1016372A (de) |
CH (1) | CH606461A5 (de) |
DE (1) | DE2334992C2 (de) |
DK (1) | DK143415C (de) |
FR (1) | FR2192184B1 (de) |
GB (1) | GB1417435A (de) |
NL (1) | NL7309637A (de) |
NO (1) | NO132764C (de) |
SE (1) | SE396093C (de) |
Cited By (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4018632A (en) * | 1976-03-12 | 1977-04-19 | Chrysler Corporation | Machinable powder metal parts |
US4096002A (en) * | 1974-09-25 | 1978-06-20 | Riken Piston Ring Industrial Co. Ltd. | High duty ductile cast iron with superplasticity and its heat treatment methods |
US4222793A (en) * | 1979-03-06 | 1980-09-16 | General Motors Corporation | High stress nodular iron gears and method of making same |
US4448610A (en) * | 1982-03-01 | 1984-05-15 | Pont-A-Mousson S.A. | Centrifugally cast tube of spheroidal graphite cast-iron and its method of manufacture |
US4541878A (en) * | 1982-12-02 | 1985-09-17 | Horst Muhlberger | Cast iron with spheroidal graphite and austenitic-bainitic mixed structure |
US4596606A (en) * | 1984-09-04 | 1986-06-24 | Ford Motor Company | Method of making CG iron |
US4619713A (en) * | 1983-02-25 | 1986-10-28 | Hitachi Metals, Ltd. | Method of producing nodular graphite cast iron |
US4737199A (en) * | 1985-12-23 | 1988-04-12 | Ford Motor Company | Machinable ductile or semiductile cast iron and method |
US4880477A (en) * | 1988-06-14 | 1989-11-14 | Textron, Inc. | Process of making an austempered ductile iron article |
EP0374116A1 (de) * | 1988-12-13 | 1990-06-20 | Sandvik Aktiebolag | Walzring aus Hartmetall und Gusseisen und Verfahren zur Herstellung |
US4964344A (en) * | 1989-04-28 | 1990-10-23 | Mid-West Conveyor Company, Inc. | Side link pusher dog with lubrication passage |
US4981081A (en) * | 1989-05-24 | 1991-01-01 | Mid-West Conveyor Company, Inc. | Center link pusher dog for power and free conveyors |
US5028281A (en) * | 1988-06-14 | 1991-07-02 | Textron, Inc. | Camshaft |
US5044056A (en) * | 1988-12-13 | 1991-09-03 | Sandvik Ab | Roll ring comprising a ring of cemented carbide metallurgically bonded to a cast iron body |
US5082507A (en) * | 1990-10-26 | 1992-01-21 | Curry Gregory T | Austempered ductile iron gear and method of making it |
US5167067A (en) * | 1988-12-13 | 1992-12-01 | Sandvik Ab | Method of making a roll with a composite roll ring of cemented carbide and cast iron |
US5246510A (en) * | 1992-06-01 | 1993-09-21 | Applied Process | Method for producing a selectively surface hardened cast iron part |
US5248289A (en) * | 1989-12-13 | 1993-09-28 | Sandvik Ab | Cast iron roll with one or more cemented carbide roll rings metallurgically bonded thereto |
US5359772A (en) * | 1989-12-13 | 1994-11-01 | Sandvik Ab | Method for manufacture of a roll ring comprising cemented carbide and cast iron |
US5865385A (en) * | 1997-02-21 | 1999-02-02 | Arnett; Charles R. | Comminuting media comprising martensitic/austenitic steel containing retained work-transformable austenite |
FR2800752A1 (fr) * | 1999-11-10 | 2001-05-11 | Mecanique Franc De | Procede de fabrication d'une fonte a graphite spheroidal brute de coulee bainitique |
EP1344839A1 (de) * | 2002-01-18 | 2003-09-17 | Ing.Firman Allan Persson HAB | Legiertes Sphärogusseisen |
US20040013219A1 (en) * | 2002-05-21 | 2004-01-22 | Duke University | Recirculating target and method for producing radionuclide |
US20040074460A1 (en) * | 2002-10-18 | 2004-04-22 | Dhruva Mandal | Valve lifter body |
US20040112173A1 (en) * | 2001-01-24 | 2004-06-17 | Paritosh Maulik | Sintered ferrous material contaning copper |
US20050000314A1 (en) * | 2002-10-18 | 2005-01-06 | Dhruva Mandal | Roller follower body |
US20050063852A1 (en) * | 2001-12-12 | 2005-03-24 | Takeshi Hida | Screw compressor and method of manufacturing rotor for the same |
CN100366758C (zh) * | 2004-12-02 | 2008-02-06 | 张志祥 | 球墨铸铁曲轴等温淬火的方法 |
US20090104367A1 (en) * | 2005-02-17 | 2009-04-23 | Tritron Gmbh & Co.Kg | Pretreatment and/or precoating of nonabsorbent substrates and/or nonabsorbent support materials |
US20100006189A1 (en) * | 2006-12-16 | 2010-01-14 | Indexator Ab | Austempered ductile iron, method for producing this and component compri |
US20100278293A1 (en) * | 2009-05-01 | 2010-11-04 | Matthew Hughes Stokely | Particle beam target with improved heat transfer and related apparatus and methods |
US20110247581A1 (en) * | 2008-11-19 | 2011-10-13 | Trieschmann Joerg | Gear and balance shaft for a piston engine |
CN111304525A (zh) * | 2018-12-11 | 2020-06-19 | 现代自动车株式会社 | 用于连续可变气门正时系统的凸轮件的制造方法及凸轮件 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI56699C (fi) * | 1976-10-05 | 1980-03-10 | Kymin Oy Kymmene Ab | Maskinelement av segjaern foer kraftoeverfoering medelst friktion |
FI780026A (fi) * | 1978-01-05 | 1979-07-06 | Ovako Oy | Kisellegerat staol |
DE2853870A1 (de) * | 1978-12-13 | 1980-07-03 | Schmidt Gmbh Karl | Gusseisen mit kugelgraphit mit austenitisch-bainitischem mischgefuege |
JPS55164055A (en) * | 1979-06-08 | 1980-12-20 | Toyota Motor Corp | Spherical graphite cast iron for surface quenching |
CH653706A5 (de) * | 1981-05-21 | 1986-01-15 | Fischer Ag Georg | Verfahren und vorrichtung zur abschnittsweisen waermebehandlung von bauteilen aus eisenwerkstoffen. |
CH648350A5 (de) * | 1981-12-03 | 1985-03-15 | Fischer Ag Georg | Verfahren zum isothermen bainitisieren von werkstuecken aus eisenwerkstoffen. |
JPS59129730A (ja) * | 1983-01-18 | 1984-07-26 | Toyota Motor Corp | 高強度クランクシャフトの製造方法 |
JPS60121253A (ja) * | 1983-12-05 | 1985-06-28 | Nissan Motor Co Ltd | 球状黒鉛鋳鉄 |
JPS60184659A (ja) * | 1984-03-02 | 1985-09-20 | Toyota Motor Corp | 高強度高靭性球状黒鉛鋳鉄 |
JPS60197841A (ja) * | 1984-03-19 | 1985-10-07 | Nissan Motor Co Ltd | 球状黒鉛鋳鉄 |
JP2672293B2 (ja) * | 1984-08-30 | 1997-11-05 | 日立金属株式会社 | 機械的性質に優れた球状黒鉛鋳鉄 |
JPS61136657A (ja) * | 1984-12-05 | 1986-06-24 | Ngk Insulators Ltd | プラスチツク成形用鋳造金型 |
US4666533A (en) * | 1985-09-05 | 1987-05-19 | Ford Motor Company | Hardenable cast iron and the method of making cast iron |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2324322A (en) * | 1940-05-30 | 1943-07-13 | Int Nickel Co | High quality cast iron |
US2485760A (en) * | 1947-03-22 | 1949-10-25 | Int Nickel Co | Cast ferrous alloy |
US3549431A (en) * | 1965-07-27 | 1970-12-22 | Renault | Method of production of cast-iron parts with a high coefficient of thermal expansion |
US3549430A (en) * | 1967-11-14 | 1970-12-22 | Int Nickel Co | Bainitic ductile iron having high strength and toughness |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1121639B (de) * | 1956-03-16 | 1962-01-11 | Renault | Verfahren zur Herstellung von in Kokille gegossenen, hoechstens 25 mm dicken Gusseisenstuecken sehr hoher Zaehigkeit |
DE1178451B (de) * | 1957-06-06 | 1964-09-24 | Goetzewerke | Verfahren zur Herstellung von Unrund-Kolben-ringen hoher Biege- und Verschleissfestigkeit |
FR1286077A (fr) * | 1961-01-20 | 1962-03-02 | Renault | Acier et traitement pour l'obtention de pièces à coefficient de dilatation thermique élevé |
-
1973
- 1973-07-06 US US377035A patent/US3860457A/en not_active Expired - Lifetime
- 1973-07-10 DE DE2334992A patent/DE2334992C2/de not_active Expired
- 1973-07-10 NO NO2828/73A patent/NO132764C/no unknown
- 1973-07-10 NL NL7309637A patent/NL7309637A/xx active Search and Examination
- 1973-07-11 CH CH1011173A patent/CH606461A5/xx not_active IP Right Cessation
- 1973-07-11 FR FR7325396A patent/FR2192184B1/fr not_active Expired
- 1973-07-11 DK DK384473A patent/DK143415C/da not_active IP Right Cessation
- 1973-07-11 CA CA176,179A patent/CA1016372A/en not_active Expired
- 1973-07-11 JP JP7759373A patent/JPS553422B2/ja not_active Expired
- 1973-07-11 GB GB3303573A patent/GB1417435A/en not_active Expired
- 1973-07-12 SE SE7309824A patent/SE396093C/xx unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2324322A (en) * | 1940-05-30 | 1943-07-13 | Int Nickel Co | High quality cast iron |
US2485760A (en) * | 1947-03-22 | 1949-10-25 | Int Nickel Co | Cast ferrous alloy |
US3549431A (en) * | 1965-07-27 | 1970-12-22 | Renault | Method of production of cast-iron parts with a high coefficient of thermal expansion |
US3549430A (en) * | 1967-11-14 | 1970-12-22 | Int Nickel Co | Bainitic ductile iron having high strength and toughness |
Cited By (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4096002A (en) * | 1974-09-25 | 1978-06-20 | Riken Piston Ring Industrial Co. Ltd. | High duty ductile cast iron with superplasticity and its heat treatment methods |
US4018632A (en) * | 1976-03-12 | 1977-04-19 | Chrysler Corporation | Machinable powder metal parts |
US4222793A (en) * | 1979-03-06 | 1980-09-16 | General Motors Corporation | High stress nodular iron gears and method of making same |
US4448610A (en) * | 1982-03-01 | 1984-05-15 | Pont-A-Mousson S.A. | Centrifugally cast tube of spheroidal graphite cast-iron and its method of manufacture |
US4541878A (en) * | 1982-12-02 | 1985-09-17 | Horst Muhlberger | Cast iron with spheroidal graphite and austenitic-bainitic mixed structure |
US4619713A (en) * | 1983-02-25 | 1986-10-28 | Hitachi Metals, Ltd. | Method of producing nodular graphite cast iron |
US4596606A (en) * | 1984-09-04 | 1986-06-24 | Ford Motor Company | Method of making CG iron |
US4737199A (en) * | 1985-12-23 | 1988-04-12 | Ford Motor Company | Machinable ductile or semiductile cast iron and method |
US4880477A (en) * | 1988-06-14 | 1989-11-14 | Textron, Inc. | Process of making an austempered ductile iron article |
US5028281A (en) * | 1988-06-14 | 1991-07-02 | Textron, Inc. | Camshaft |
AU615125B2 (en) * | 1988-12-13 | 1991-09-19 | Sandvik Ab | Roll ring, comprising cemented carbide and cast iron, and method for manufacture of the same. |
EP0374116A1 (de) * | 1988-12-13 | 1990-06-20 | Sandvik Aktiebolag | Walzring aus Hartmetall und Gusseisen und Verfahren zur Herstellung |
US5167067A (en) * | 1988-12-13 | 1992-12-01 | Sandvik Ab | Method of making a roll with a composite roll ring of cemented carbide and cast iron |
US5044056A (en) * | 1988-12-13 | 1991-09-03 | Sandvik Ab | Roll ring comprising a ring of cemented carbide metallurgically bonded to a cast iron body |
US4964344A (en) * | 1989-04-28 | 1990-10-23 | Mid-West Conveyor Company, Inc. | Side link pusher dog with lubrication passage |
US4981081A (en) * | 1989-05-24 | 1991-01-01 | Mid-West Conveyor Company, Inc. | Center link pusher dog for power and free conveyors |
US5248289A (en) * | 1989-12-13 | 1993-09-28 | Sandvik Ab | Cast iron roll with one or more cemented carbide roll rings metallurgically bonded thereto |
US5359772A (en) * | 1989-12-13 | 1994-11-01 | Sandvik Ab | Method for manufacture of a roll ring comprising cemented carbide and cast iron |
US5082507A (en) * | 1990-10-26 | 1992-01-21 | Curry Gregory T | Austempered ductile iron gear and method of making it |
US5246510A (en) * | 1992-06-01 | 1993-09-21 | Applied Process | Method for producing a selectively surface hardened cast iron part |
US5865385A (en) * | 1997-02-21 | 1999-02-02 | Arnett; Charles R. | Comminuting media comprising martensitic/austenitic steel containing retained work-transformable austenite |
US6080247A (en) * | 1997-02-21 | 2000-06-27 | Gs Technologies Operating Company | Comminuting media comprising martensitic/austenitic steel containing retained work-transformable austenite |
FR2800752A1 (fr) * | 1999-11-10 | 2001-05-11 | Mecanique Franc De | Procede de fabrication d'une fonte a graphite spheroidal brute de coulee bainitique |
EP1099768A1 (de) * | 1999-11-10 | 2001-05-16 | Françoise de Mécanique | Verfahren zur Herstellung von Gusseisen mit Kugelgraphit und bainitschen Gefüge in dem Gusszustand |
US20040112173A1 (en) * | 2001-01-24 | 2004-06-17 | Paritosh Maulik | Sintered ferrous material contaning copper |
US20050063852A1 (en) * | 2001-12-12 | 2005-03-24 | Takeshi Hida | Screw compressor and method of manufacturing rotor for the same |
EP1344839A1 (de) * | 2002-01-18 | 2003-09-17 | Ing.Firman Allan Persson HAB | Legiertes Sphärogusseisen |
US20040013219A1 (en) * | 2002-05-21 | 2004-01-22 | Duke University | Recirculating target and method for producing radionuclide |
US7200198B2 (en) * | 2002-05-21 | 2007-04-03 | Duke University | Recirculating target and method for producing radionuclide |
US20070217561A1 (en) * | 2002-05-21 | 2007-09-20 | Duke University | Recirculating target and method for producing radionuclide |
US20040074460A1 (en) * | 2002-10-18 | 2004-04-22 | Dhruva Mandal | Valve lifter body |
US20050000314A1 (en) * | 2002-10-18 | 2005-01-06 | Dhruva Mandal | Roller follower body |
CN100366758C (zh) * | 2004-12-02 | 2008-02-06 | 张志祥 | 球墨铸铁曲轴等温淬火的方法 |
US20090104367A1 (en) * | 2005-02-17 | 2009-04-23 | Tritron Gmbh & Co.Kg | Pretreatment and/or precoating of nonabsorbent substrates and/or nonabsorbent support materials |
US7758922B2 (en) | 2005-02-17 | 2010-07-20 | Tritron Gmbh & Co. Kg | Pretreatment and/or precoating of nonabsorbent substrates and/or nonabsorbent support materials |
US20100006189A1 (en) * | 2006-12-16 | 2010-01-14 | Indexator Ab | Austempered ductile iron, method for producing this and component compri |
US20100111662A1 (en) * | 2006-12-16 | 2010-05-06 | Indexator Ab | Method for manufacturing at least part of a device for an earthmoving or materials-handling machine using austempered ductile iron |
US8192561B2 (en) | 2006-12-16 | 2012-06-05 | Indexator Group Ab | Method for manufacturing at least part of a device for an earthmoving or materials-handling machine using austempered ductile iron and its named product |
US20110247581A1 (en) * | 2008-11-19 | 2011-10-13 | Trieschmann Joerg | Gear and balance shaft for a piston engine |
US8561589B2 (en) * | 2008-11-19 | 2013-10-22 | Mitec Automotive Ag | Gear and balance shaft for a piston engine |
US20100278293A1 (en) * | 2009-05-01 | 2010-11-04 | Matthew Hughes Stokely | Particle beam target with improved heat transfer and related apparatus and methods |
US8670513B2 (en) | 2009-05-01 | 2014-03-11 | Bti Targetry, Llc | Particle beam target with improved heat transfer and related apparatus and methods |
CN111304525A (zh) * | 2018-12-11 | 2020-06-19 | 现代自动车株式会社 | 用于连续可变气门正时系统的凸轮件的制造方法及凸轮件 |
US11441204B2 (en) * | 2018-12-11 | 2022-09-13 | Hyundai Motor Company | Method of manufacturing cam piece for continuously variable valve duration and cam piece manufactured therefrom |
CN111304525B (zh) * | 2018-12-11 | 2023-08-18 | 现代自动车株式会社 | 用于连续可变气门正时系统的凸轮件的制造方法及凸轮件 |
Also Published As
Publication number | Publication date |
---|---|
FR2192184B1 (de) | 1977-09-09 |
NL7309637A (de) | 1974-01-15 |
NO132764C (de) | 1975-12-29 |
CA1016372A (en) | 1977-08-30 |
DK143415C (da) | 1981-12-21 |
DK143415B (da) | 1981-08-17 |
CH606461A5 (de) | 1978-10-31 |
NO132764B (de) | 1975-09-22 |
FR2192184A1 (de) | 1974-02-08 |
DE2334992C2 (de) | 1984-08-16 |
JPS4953115A (de) | 1974-05-23 |
SE396093C (sv) | 1981-03-23 |
SE396093B (sv) | 1977-09-05 |
DE2334992A1 (de) | 1974-02-07 |
GB1417435A (en) | 1975-12-10 |
JPS553422B2 (de) | 1980-01-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3860457A (en) | A ductile iron and method of making it | |
CN100532887C (zh) | 齿轮构件及其制造方法 | |
US4415378A (en) | Case hardening method for steel parts | |
JPH0579742B2 (de) | ||
US4702778A (en) | Method for softening rolled medium carbon machine structural steels | |
US4225365A (en) | Lower bainite alloy steel article and method of making same | |
US2087764A (en) | Ferrous alloys and method of manufacture | |
US3893873A (en) | Method for manufacturing spheroidal graphite cast iron | |
EP1031631A2 (de) | Verfahren zum Glühen auf kugeligem Carbide von untereutektoidischen niedriglegierten Stählen | |
US3895972A (en) | Thermal treatment of steel | |
JP2000096185A (ja) | 軸受用鋼 | |
US12104234B2 (en) | Steel material | |
US3826694A (en) | Thermal treatment of steel | |
JPH0238645B2 (ja) | Kokyodokyujokokuenchutetsunoseizohoho | |
US3704183A (en) | Method for producing a low-cost hypereutectoid bearing steel | |
JPH04124217A (ja) | 焼鈍軟化性に優れた強靭歯車用鋼の製造方法 | |
US2585372A (en) | Method of making low-alloy steel | |
US3922181A (en) | Thermal treatment of steel | |
JPS569328A (en) | Forged roll for cold rolling mill | |
JPS62139812A (ja) | 高強度高靭性鋳鋼の製造法 | |
JP3607583B2 (ja) | 動力伝達部品用鋼および動力伝達部品 | |
CN101586207B (zh) | 一种1600MPa级机械结构用热轧线材及其制造方法 | |
US4396440A (en) | Crushing bodies forged from steel | |
JP2773523B2 (ja) | 鋼材の熱処理方法 | |
JPH0615687B2 (ja) | 表面強化方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCF | Information on status: patent grant |
Free format text: PATENTED FILE - (OLD CASE ADDED FOR FILE TRACKING PURPOSES) |