US20150292070A1 - Nanocarbon-reinforced aluminium composite materials and method for manufacturing the same - Google Patents

Nanocarbon-reinforced aluminium composite materials and method for manufacturing the same Download PDF

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US20150292070A1
US20150292070A1 US14/490,481 US201414490481A US2015292070A1 US 20150292070 A1 US20150292070 A1 US 20150292070A1 US 201414490481 A US201414490481 A US 201414490481A US 2015292070 A1 US2015292070 A1 US 2015292070A1
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nanocarbon
aluminum
ceramic
powder
coated
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Dong Hoon Nam
Jong Kook Lee
Byung Ho Min
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Hyundai Motor Co
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Hyundai Motor Co
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0084Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ carbon or graphite as the main non-metallic constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C49/00Alloys containing metallic or non-metallic fibres or filaments
    • C22C49/02Alloys containing metallic or non-metallic fibres or filaments characterised by the matrix material
    • C22C49/04Light metals
    • C22C49/06Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/06Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/0081Casting in, on, or around objects which form part of the product pretreatment of the insert, e.g. for enhancing the bonding between insert and surrounding cast metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/14Casting in, on, or around objects which form part of the product the objects being filamentary or particulate in form
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82BNANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1005Pretreatment of the non-metallic additives
    • C22C1/101Pretreatment of the non-metallic additives by coating
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • C22C1/1042Alloys containing non-metals starting from a melt by atomising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/001Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0052Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0068Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only nitrides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0047Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
    • C22C32/0073Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only borides
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/02Pretreatment of the fibres or filaments
    • C22C47/04Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C47/00Making alloys containing metallic or non-metallic fibres or filaments
    • C22C47/08Making alloys containing metallic or non-metallic fibres or filaments by contacting the fibres or filaments with molten metal, e.g. by infiltrating the fibres or filaments placed in a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • C22C2026/002Carbon nanotubes

Definitions

  • the present disclosure relates to a nanocarbon-reinforced aluminum composite material and a method of manufacturing the same. More particularly, the present disclosure relates to a nanocarbon-reinforced aluminum composite material, wherein the reaction between nanocarbon and liquid aluminum is controlled and the dispersibility of nanocarbon in aluminum is improved, and to a method of manufacturing the same.
  • a carbon nanotube is a tubular carbon nanomaterial having a diameter of several nanometers (nm) to several tens of nanometers (nm).
  • a carbon nanotube has excellent mechanical properties, such as high strength, a high elastic modulus, low density, a high aspect ratio, etc. Therefore, research into the application of carbon nanotubes to structural materials, that is, reinforcing materials, such as polymer-metal matrix composite materials and the like, has been actively conducted.
  • a powder metallurgy process of mixing carbon nanotubes with metal powder to prepare carbon nanotube-metal composite powder and then sintering this composite powder is generally used.
  • carbon nanotubes are mixed with metal powder by ball milling or the like, and then the mixture is sintered.
  • carbon nanotubes are strongly agglomerated by the Van der Waals force acting therebetween, and thus it is very difficult to uniformly disperse them in a metal matrix material. Further, the difference in density between carbon nanotubes and a metal matrix material makes the dispersion of carbon nanotubes difficult.
  • agglomerated carbon nanotubes are not easily sintered, the density is low, and the characteristics of a composite material are poor. Further, when carbon nanotubes are mixed with metal powder, such as titanium powder, and then sintered, carbide, such as titanium carbide (TiC), is produced, and thus excellent reinforcing effects attributable to original carbon nanotubes are not achieved.
  • metal powder such as titanium powder
  • TiC titanium carbide
  • the present disclosure has been devised to solve the above-mentioned problems.
  • the present disclosure provides a nanocarbon-reinforced aluminum composite material, wherein the reaction between nanocarbon and liquid aluminum is controlled and the dispersibility of nanocarbon in aluminum is improved, and a method of manufacturing the same.
  • An aspect of the present disclosure provides a method of manufacturing a nanocarbon-reinforced aluminum composite material comprising adding composite powder, in which ceramic-coated nanocarbon is surrounded by metal powder, to molten aluminum and then casting the molten aluminum with the added composite powder.
  • the method may include the steps of: coating nanocarbon with ceramic; mixing the ceramic-coated nanocarbon with metal powder to prepare composite powder such that the ceramic-coated nanocarbon is surrounded by the metal powder; adding the composite powder to molten aluminum; and casting the molten aluminum with the added composite powder.
  • the nanocarbon may include at least one selected from the group consisting of carbon nanotubes, carbon nanofiber, and graphene.
  • the ceramic may include at least one selected from the group consisting of oxide, carbide, nitride, and boride.
  • the metal powder may be aluminum or a metal alloyed with the aluminum or reacted with the aluminum to form an intermetallic compound.
  • the ceramic-coated nanocarbon may be mixed with the metal powder by ball milling such that the ceramic-coated nanocarbon is surrounded by the metal powder.
  • Another aspect of the present disclosure provides a nanocarbon-reinforced aluminum composite material, manufactured by adding composite powder, in which ceramic-coated nanocarbon is surrounded by metal powder, to molten aluminum and then casting the molten aluminum with the added composite powder.
  • FIG. 1 is a schematic view showing a process of manufacturing a nanocarbon-reinforced aluminum composite material according to an embodiment of the present disclosure
  • FIG. 2 is a photograph showing carbon nanotubes coated with titanium oxide (TiO 2 ).
  • FIG. 3 is a photograph showing a nanocarbon-reinforced aluminum composite material according to an embodiment of the present disclosure.
  • FIG. 4 is a photograph showing a nanocarbon-reinforced aluminum composite material of Comparative Example 1.
  • FIG. 5 is a photograph showing TiO 2 -coated carbon nanotube-aluminum composite powder prepared by ball milling.
  • FIG. 6 is a graph showing a graphene coated with Al 2 O 3 .
  • the method of manufacturing a nanocarbon-reinforced aluminum composite material according to the present invention is characterized in that composite powder, in which ceramic-coated nanocarbon is surrounded by metal powder, is added to molten aluminum and then the molten aluminum with the added composite powder is casted.
  • ceramic applied on nanocarbon controls the reaction between liquid aluminum and the nanocarbon, and the metal powder improves the wettability of liquid aluminum, thereby improving both thermal stability and dispersibility of nanocarbon in molten aluminum.
  • Nanocarbon can greatly contribute to the realization of high-functionalization, weight reduction, and miniaturization in the fields of electric and electronic appliances, automobiles, and the like in combination with existing metal materials because it has high electrical conductivity, high thermal conductivity and excellent mechanical properties. Therefore, in the present invention, the above advantages are realized by surrounding ceramic-coated nanocarbon with metal powder to prepare composite powder, adding the composite powder to molten metal and then casting the molten metal added with the composite powder.
  • the method of manufacturing a nanocarbon-reinforced aluminum composite material can be embodied by the steps of: coating nanocarbon with ceramic; mixing the ceramic-coated nanocarbon with metal powder to prepare composite powder such that the ceramic-coated nanocarbon is surrounded by the metal powder; adding the composite powder to molten aluminum; and casting the molten aluminum added with the composite powder.
  • Nanocarbon includes at least one selected from the group consisting of carbon nanotubes, carbon nanofiber, and graphene.
  • the ceramic includes at least one selected from among oxide, carbide, nitride, and boride.
  • nanocarbon may be coated with metal powder by applying metal particles, such as copper, nickel or the like, and heat-treating them under an oxygen atmosphere.
  • a ceramic coating layer may be adjusted in a range of 10 nm to 1 ⁇ m. Further, ceramic coating may be performed by various methods, such as electroless plating, sputtering, deposition, chemical vapor deposition, and the like.
  • the ceramic coating may be performed such that ceramic particles are uniformly distributed on the nanocarbon. This uniformly ceramic-coated nanocarbon is surrounded by metal powder to prepare composite powder.
  • the composite powder in which ceramic-coated nanocarbon is surrounded by metal powder, is mixed with molten aluminum, and then this mixture is cast, to manufacture a nanocarbon-reinforced aluminum composite material.
  • the metal powder may be aluminum or a metal alloyed with the aluminum or reacted with the aluminum to form an intermetallic compound.
  • the ceramic-coated nanocarbon may be mixed with the metal powder by ball milling.
  • CNTs carbon nanotubes
  • a nanocarbon-reinforced aluminum composite material was manufactured in the same manner as in Example 1, after graphene was coated with Al 2 O 3 using a sol-gel process.
  • a nanocarbon-reinforced aluminum composite material was manufactured in the same manner as in Example 1, except that carbon nanotubes coated with TiO 2 were used.
  • ceramic-coated nanocarbon is mixed with metal powder to prepare composite powder, thus improving the dispersibility of nanocarbon in aluminum while controlling the reaction between nanocarbon and liquid aluminum.
  • the nanocarbon-reinforced aluminum composite material of the present disclosure is advantageous in that the reaction between nanocarbon and liquid aluminum can be controlled, and the dispersibility of nanocarbon in aluminum can be improved.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
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  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Nanotechnology (AREA)
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  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)
US14/490,481 2014-04-14 2014-09-18 Nanocarbon-reinforced aluminium composite materials and method for manufacturing the same Abandoned US20150292070A1 (en)

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KR1020140044439A KR101583916B1 (ko) 2014-04-14 2014-04-14 나노카본 강화 알루미늄 복합재 및 그 제조방법

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CN111057897A (zh) * 2019-12-27 2020-04-24 中北大学 一种石墨烯增强铝基复合材料的深过冷制备方法
CN112846198A (zh) * 2021-01-05 2021-05-28 中冶赛迪技术研究中心有限公司 一种纳米颗粒增强金属基复合材料及其制备方法
US20220093286A1 (en) * 2019-06-05 2022-03-24 Yazaki Corporation Aluminum carbon nanotube (al-cnt) wires in transmission or distribution line cables
CN114959359A (zh) * 2022-05-11 2022-08-30 河南科技大学 高致密化定向排列Ti2AlC/TiAl仿生复合材料及其制备方法

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CN106636992B (zh) * 2016-10-11 2018-06-12 西南交通大学 一种CNTs和CNFs协同增强铜基复合材料及制备方法
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CN109022955A (zh) * 2018-08-24 2018-12-18 山东创新金属科技有限公司 一种高耐腐蚀性铝合金复合材料及其制备方法
KR102219180B1 (ko) * 2019-03-22 2021-02-23 부경대학교 산학협력단 알루미늄계 클래드 형재의 제조 방법 및 이를 이용하여 제조된 알루미늄계 클래드 형재
KR102266847B1 (ko) * 2019-04-15 2021-06-21 부경대학교 산학협력단 복합재료 제조를 위한 소성 가공용 빌렛의 제조방법 및 이에 의해 제조된 빌렛
CN110453113B (zh) * 2019-09-16 2020-10-27 宜春学院 一种氧化铯改性石墨烯增强铝合金复合材料的方法
KR102324737B1 (ko) * 2020-03-31 2021-11-10 재단법인 한국탄소산업진흥원 탄소섬유 강화 금속 복합재의 제조방법 및 그로부터 제조된 탄소섬유 강화 알루미늄 복합재
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US20220093286A1 (en) * 2019-06-05 2022-03-24 Yazaki Corporation Aluminum carbon nanotube (al-cnt) wires in transmission or distribution line cables
CN111057897A (zh) * 2019-12-27 2020-04-24 中北大学 一种石墨烯增强铝基复合材料的深过冷制备方法
CN112846198A (zh) * 2021-01-05 2021-05-28 中冶赛迪技术研究中心有限公司 一种纳米颗粒增强金属基复合材料及其制备方法
CN114959359A (zh) * 2022-05-11 2022-08-30 河南科技大学 高致密化定向排列Ti2AlC/TiAl仿生复合材料及其制备方法

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