TWI791795B - 熱塑性樹脂組成物 - Google Patents
熱塑性樹脂組成物 Download PDFInfo
- Publication number
- TWI791795B TWI791795B TW108109376A TW108109376A TWI791795B TW I791795 B TWI791795 B TW I791795B TW 108109376 A TW108109376 A TW 108109376A TW 108109376 A TW108109376 A TW 108109376A TW I791795 B TWI791795 B TW I791795B
- Authority
- TW
- Taiwan
- Prior art keywords
- copolymer
- weight
- thermoplastic resin
- monomer
- resin composition
- Prior art date
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 74
- 239000011342 resin composition Substances 0.000 title claims abstract description 57
- 229920001577 copolymer Polymers 0.000 claims abstract description 114
- 239000000178 monomer Substances 0.000 claims abstract description 96
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 42
- 229920000642 polymer Polymers 0.000 claims abstract description 30
- 150000001993 dienes Chemical class 0.000 claims abstract description 25
- 239000002245 particle Substances 0.000 claims abstract description 25
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 19
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 43
- 239000011159 matrix material Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 8
- 239000012963 UV stabilizer Substances 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 238000002834 transmittance Methods 0.000 abstract description 31
- 230000000052 comparative effect Effects 0.000 description 18
- 239000000463 material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
- 229920000578 graft copolymer Polymers 0.000 description 11
- 238000012662 bulk polymerization Methods 0.000 description 10
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- 239000005062 Polybutadiene Substances 0.000 description 6
- -1 ethylhexyl Chemical group 0.000 description 6
- 229920002857 polybutadiene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 229920006352 transparent thermoplastic Polymers 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- RLFXJQPKMZNLMP-UHFFFAOYSA-N 2-phenylprop-2-enenitrile Chemical compound N#CC(=C)C1=CC=CC=C1 RLFXJQPKMZNLMP-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- SQHOHKQMTHROSF-UHFFFAOYSA-N but-1-en-2-ylbenzene Chemical compound CCC(=C)C1=CC=CC=C1 SQHOHKQMTHROSF-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- NECLQTPQJZSWOE-UHFFFAOYSA-N spiro[5.5]undecane Chemical compound C1CCCCC21CCCCC2 NECLQTPQJZSWOE-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20180032286 | 2018-03-20 | ||
| KR10-2018-0032286 | 2018-03-20 | ||
| KR1020190030765A KR102183999B1 (ko) | 2018-03-20 | 2019-03-18 | 열가소성 수지 조성물 |
| KR10-2019-0030765 | 2019-03-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201940579A TW201940579A (zh) | 2019-10-16 |
| TWI791795B true TWI791795B (zh) | 2023-02-11 |
Family
ID=68098758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108109376A TWI791795B (zh) | 2018-03-20 | 2019-03-19 | 熱塑性樹脂組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US11104785B2 (enExample) |
| EP (1) | EP3623421B1 (enExample) |
| JP (1) | JP6821065B2 (enExample) |
| KR (1) | KR102183999B1 (enExample) |
| CN (1) | CN110753727B (enExample) |
| TW (1) | TWI791795B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102707172B1 (ko) * | 2020-10-29 | 2024-09-20 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이로부터 제조된 성형품 |
| EP4029915B1 (en) * | 2020-10-29 | 2024-04-17 | LG Chem, Ltd. | Thermoplastic resin composition, preparation method thereof, and molded article manufactured therefrom |
| KR102707170B1 (ko) * | 2021-01-22 | 2024-09-20 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품 |
| KR102687068B1 (ko) * | 2021-01-22 | 2024-07-23 | 주식회사 엘지화학 | 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품 |
| US20250340729A1 (en) * | 2021-10-01 | 2025-11-06 | Lg Chem, Ltd. | Transparent resin composition and molded article |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080112842A (ko) * | 2007-06-22 | 2008-12-26 | 제일모직주식회사 | 내후성이 향상된 열가소성 수지 조성물 |
| CN103910948A (zh) * | 2012-12-31 | 2014-07-09 | 第一毛织株式会社 | 透明热塑性树脂组合物和由该组合物生产的模制品 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3090942B2 (ja) | 1990-11-02 | 2000-09-25 | 三菱化学株式会社 | 冷蔵庫内箱用熱可塑性樹脂組成物及びそれを成形して得られた冷蔵庫内箱 |
| JP3538491B2 (ja) | 1995-11-24 | 2004-06-14 | 三菱化学株式会社 | 熱可塑性樹脂組成物 |
| US6883938B1 (en) * | 1998-02-20 | 2005-04-26 | Nippon Zeon Co., Ltd. | Lighting equipment |
| JP2002020438A (ja) * | 2000-07-06 | 2002-01-23 | Mitsubishi Rayon Co Ltd | グラフト共重合体およびこれを含む熱可塑性樹脂組成物ならびにその成形品 |
| JP2003138091A (ja) * | 2001-10-31 | 2003-05-14 | Nippon A & L Kk | 光ディスク基板用材料および光ディスク |
| JP4849857B2 (ja) * | 2005-09-27 | 2012-01-11 | 旭化成ケミカルズ株式会社 | 熱可塑性樹脂組成物 |
| KR100645260B1 (ko) | 2005-11-25 | 2006-11-14 | 제일모직주식회사 | 내화학성 및 전사성과 진공성형성이 우수한 냉장고용열가소성 수지 조성물 |
| US20090269531A1 (en) | 2007-10-26 | 2009-10-29 | Dominique Arnould | Resinous compositions, articles made therefrom and process |
| KR101020054B1 (ko) | 2008-08-19 | 2011-03-09 | 주식회사 엘지화학 | 이형성 및 착색성이 우수한 열가소성 수지 조성물 |
| JP2010070646A (ja) * | 2008-09-18 | 2010-04-02 | Asahi Kasei Chemicals Corp | 光学材料用樹脂組成物 |
| JP5742076B2 (ja) * | 2010-01-07 | 2015-07-01 | テクノポリマー株式会社 | 透明熱可塑性樹脂組成物および樹脂成形品 |
| JPWO2011115253A1 (ja) * | 2010-03-19 | 2013-07-04 | 旭化成ケミカルズ株式会社 | スチレン系樹脂組成物及びそれからなる樹脂成形体 |
| KR101409599B1 (ko) * | 2010-08-11 | 2014-06-27 | 주식회사 엘지화학 | 내스크래치성과 내열성이 우수한 내광성 열가소성 수지 조성물 |
| JP2012062409A (ja) * | 2010-09-16 | 2012-03-29 | Asahi Kasei Chemicals Corp | スチレン系熱可塑性樹脂組成物及びそれからなる成形品 |
| KR101469263B1 (ko) * | 2011-12-22 | 2014-12-05 | 제일모직주식회사 | 열가소성 수지 조성물 및 그 성형품 |
| US8927631B2 (en) | 2013-03-29 | 2015-01-06 | Lg Chem, Ltd. | Transparent thermoplastic resin composition and molded article prepared therefrom |
| EP3037474B1 (en) | 2014-09-16 | 2019-06-26 | LG Chem, Ltd. | Thermoplastic resin composition and thermoplastic resin molded article prepared therefrom |
| KR101886482B1 (ko) * | 2014-11-21 | 2018-09-07 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
| KR20160067675A (ko) | 2014-12-04 | 2016-06-14 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 이를 적용한 성형품 |
| KR102007976B1 (ko) * | 2015-11-30 | 2019-08-06 | 주식회사 엘지화학 | 열가소성 수지의 제조방법, 열가소성 수지 및 이를 포함하는 열가소성 수지 조성물 |
| WO2017178075A1 (en) | 2016-04-15 | 2017-10-19 | Huawei Technologies Co., Ltd. | Method for generating pulse shapes with adjustable length, orthogonality and localization properties |
-
2019
- 2019-03-18 KR KR1020190030765A patent/KR102183999B1/ko active Active
- 2019-03-19 US US16/626,247 patent/US11104785B2/en active Active
- 2019-03-19 JP JP2019570439A patent/JP6821065B2/ja active Active
- 2019-03-19 CN CN201980003072.2A patent/CN110753727B/zh active Active
- 2019-03-19 TW TW108109376A patent/TWI791795B/zh active
- 2019-03-19 EP EP19771730.9A patent/EP3623421B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20080112842A (ko) * | 2007-06-22 | 2008-12-26 | 제일모직주식회사 | 내후성이 향상된 열가소성 수지 조성물 |
| CN103910948A (zh) * | 2012-12-31 | 2014-07-09 | 第一毛织株式会社 | 透明热塑性树脂组合物和由该组合物生产的模制品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3623421A4 (en) | 2020-04-15 |
| US11104785B2 (en) | 2021-08-31 |
| KR102183999B1 (ko) | 2020-11-30 |
| TW201940579A (zh) | 2019-10-16 |
| KR20190110454A (ko) | 2019-09-30 |
| JP6821065B2 (ja) | 2021-01-27 |
| CN110753727B (zh) | 2022-06-14 |
| CN110753727A (zh) | 2020-02-04 |
| EP3623421A1 (en) | 2020-03-18 |
| EP3623421B1 (en) | 2022-09-21 |
| JP2020524206A (ja) | 2020-08-13 |
| US20200216653A1 (en) | 2020-07-09 |
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