TWI625165B - 提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法 - Google Patents

提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法 Download PDF

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Publication number
TWI625165B
TWI625165B TW104130084A TW104130084A TWI625165B TW I625165 B TWI625165 B TW I625165B TW 104130084 A TW104130084 A TW 104130084A TW 104130084 A TW104130084 A TW 104130084A TW I625165 B TWI625165 B TW I625165B
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Taiwan
Prior art keywords
catalyst
epoxidation
promoter
temperature
concentration
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TW104130084A
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English (en)
Chinese (zh)
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TW201601837A (zh
Inventor
亞伯特Ｃ 劉
張麗萍
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陶氏科技投資公司
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
TW104130084A 2009-04-21 2010-04-20 提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法 TWI625165B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US17120709P 2009-04-21 2009-04-21
US61/171,207 2009-04-21

Publications (2)

Publication Number Publication Date
TW201601837A TW201601837A (zh) 2016-01-16
TWI625165B true TWI625165B (zh) 2018-06-01

Family

ID=42551515

Family Applications (2)

Application Number Title Priority Date Filing Date
TW104130084A TWI625165B (zh) 2009-04-21 2010-04-20 提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法
TW099112253A TWI504440B (zh) 2009-04-21 2010-04-20 提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
TW099112253A TWI504440B (zh) 2009-04-21 2010-04-20 提高錸促進環氧化催化劑效率之方法及利用該等之環氧化方法

Country Status (9)

Country Link
US (1) US8084632B2 (enExample)
EP (1) EP2421839B1 (enExample)
JP (1) JP5584284B2 (enExample)
KR (1) KR101704079B1 (enExample)
CN (1) CN102421766B (enExample)
CA (1) CA2759390C (enExample)
SG (1) SG175762A1 (enExample)
TW (2) TWI625165B (enExample)
WO (1) WO2010123675A1 (enExample)

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CN102458651B (zh) * 2009-04-21 2015-06-10 陶氏技术投资有限公司 铼助催化的环氧化催化剂及其制造和使用方法
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) * 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
KR101886462B1 (ko) 2010-12-10 2018-08-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법
WO2012082389A1 (en) 2010-12-15 2012-06-21 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
JP6104888B2 (ja) * 2011-04-29 2017-03-29 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Ｅｏ触媒の選択率を改善する方法
TW201335143A (zh) 2011-10-18 2013-09-01 Scient Design Co 添加緩和劑之環氧化方法
US9181207B2 (en) 2011-12-09 2015-11-10 Dow Technology Investments Llc Method of reducing or maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
EP2920159B1 (en) 2012-12-31 2020-02-12 Scientific Design Company Inc. Start-up process for high selectivity ethylene oxide catalysts
EP2943477B1 (en) * 2013-01-11 2018-03-07 Scientific Design Company Inc. Epoxidation process with post-conditioning step
RU2017144427A (ru) 2015-06-02 2019-07-09 Сайентифик Дизайн Компани, Инк. Пористые тела с улучшенной архитектурой пор
CN106311234B (zh) * 2015-07-02 2018-11-30 中国石油化工股份有限公司 复合型银催化剂的制备方法、该催化剂及其应用
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
CN110357836B (zh) * 2018-03-26 2021-04-13 中国石油化工股份有限公司 一种环氧乙烷生产方法

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Also Published As

Publication number Publication date
WO2010123675A1 (en) 2010-10-28
TW201601837A (zh) 2016-01-16
US8084632B2 (en) 2011-12-27
TW201041652A (en) 2010-12-01
EP2421839A1 (en) 2012-02-29
JP5584284B2 (ja) 2014-09-03
EP2421839B1 (en) 2014-05-07
JP2012524656A (ja) 2012-10-18
CA2759390C (en) 2017-08-22
CN102421766A (zh) 2012-04-18
CN102421766B (zh) 2015-03-25
SG175762A1 (en) 2011-12-29
CA2759390A1 (en) 2010-10-28
KR101704079B1 (ko) 2017-02-07
KR20120006551A (ko) 2012-01-18
US20100267973A1 (en) 2010-10-21
TWI504440B (zh) 2015-10-21

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