TWI595030B - 高模數纖維強化聚合物複合物及其製造方法 - Google Patents
高模數纖維強化聚合物複合物及其製造方法 Download PDFInfo
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- TWI595030B TWI595030B TW102136906A TW102136906A TWI595030B TW I595030 B TWI595030 B TW I595030B TW 102136906 A TW102136906 A TW 102136906A TW 102136906 A TW102136906 A TW 102136906A TW I595030 B TWI595030 B TW I595030B
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- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
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- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
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- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/248—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using pre-treated fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2363/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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Landscapes
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- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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| US9498922B2 (en) | 2014-06-26 | 2016-11-22 | Vertera, Inc. | Apparatus and process for producing porous devices |
| US9504550B2 (en) | 2014-06-26 | 2016-11-29 | Vertera, Inc. | Porous devices and processes for producing same |
| US10072126B2 (en) * | 2014-09-23 | 2018-09-11 | The Boeing Company | Soluble nanoparticles for composite performance enhancement |
| USD815281S1 (en) | 2015-06-23 | 2018-04-10 | Vertera, Inc. | Cervical interbody fusion device |
| JP6555006B2 (ja) * | 2015-08-21 | 2019-08-07 | 東レ株式会社 | エポキシ樹脂組成物、樹脂硬化物、プリプレグおよび繊維強化複合材料 |
| US20180229407A1 (en) * | 2017-02-03 | 2018-08-16 | Marhaygue, Llc | Structural Composition and Method |
| JP6843443B2 (ja) * | 2015-11-17 | 2021-03-17 | マーハイグ エルエルシー | 構造物用組成物および方法 |
| CN106189074A (zh) * | 2016-08-15 | 2016-12-07 | 合肥万向钱潮汽车零部件有限公司 | 汽车传动轴的轴管材料配方 |
| KR102050362B1 (ko) * | 2017-05-22 | 2019-12-02 | 재단법인 한국탄소융합기술원 | 탄소섬유를 이용한 3d 프린터용 고분자 복합재 제조방법 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242792A (zh) * | 1997-10-14 | 2000-01-26 | 东丽株式会社 | 纤维强化复合材料用环氧树脂组合物、预浸料坯及纤维强化复合材料 |
| WO2012116261A1 (en) * | 2011-02-24 | 2012-08-30 | Toray Industries, Inc. | Reinforced interphase and bonded structures thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5599629A (en) | 1984-03-01 | 1997-02-04 | Amoco Corporation | High modulus prepregable epoxy resin systems |
| JPH02135218A (ja) * | 1988-11-16 | 1990-05-24 | Mitsubishi Heavy Ind Ltd | エポキシ樹脂用硬化剤 |
| JPH10266066A (ja) * | 1997-03-27 | 1998-10-06 | Toray Ind Inc | 炭素繊維トウおよびその製造方法 |
| US6399199B1 (en) | 1999-12-28 | 2002-06-04 | Toray Industries Inc. | Prepeg and carbon fiber reinforced composite materials |
| JP4969363B2 (ja) * | 2006-08-07 | 2012-07-04 | 東レ株式会社 | プリプレグおよび炭素繊維強化複合材料 |
| JP5061813B2 (ja) * | 2007-09-25 | 2012-10-31 | 東レ株式会社 | プリプレグおよびゴルフクラブシャフト |
| US7897703B2 (en) * | 2009-05-20 | 2011-03-01 | Hexcel Corporation | Epoxy resin and 4,4′-diaminobenzanilide powder |
| WO2012102201A1 (ja) * | 2011-01-28 | 2012-08-02 | 東レ株式会社 | 繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料 |
| US20150259580A1 (en) * | 2012-10-15 | 2015-09-17 | Toray Industries, Inc. | Fiber reinforced high modulus polymer composite with a reinforced interphase |
-
2013
- 2013-10-10 KR KR1020157006839A patent/KR20150070104A/ko not_active Withdrawn
- 2013-10-10 EP EP13847241.0A patent/EP2906620A4/en not_active Withdrawn
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- 2013-10-10 WO PCT/IB2013/002275 patent/WO2014060815A1/en not_active Ceased
- 2013-10-10 US US14/435,577 patent/US20150240042A1/en not_active Abandoned
- 2013-10-10 CN CN201380053981.XA patent/CN104718245A/zh active Pending
- 2013-10-14 TW TW102136906A patent/TWI595030B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242792A (zh) * | 1997-10-14 | 2000-01-26 | 东丽株式会社 | 纤维强化复合材料用环氧树脂组合物、预浸料坯及纤维强化复合材料 |
| WO2012116261A1 (en) * | 2011-02-24 | 2012-08-30 | Toray Industries, Inc. | Reinforced interphase and bonded structures thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104718245A (zh) | 2015-06-17 |
| JP2015531425A (ja) | 2015-11-02 |
| JP6418161B2 (ja) | 2018-11-07 |
| KR20150070104A (ko) | 2015-06-24 |
| US20150240042A1 (en) | 2015-08-27 |
| TW201425402A (zh) | 2014-07-01 |
| EP2906620A4 (en) | 2016-09-14 |
| WO2014060815A1 (en) | 2014-04-24 |
| EP2906620A1 (en) | 2015-08-19 |
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