TWI592221B - 使用含經靜電穩定的銀奈米粒子之分散體製造導電表面塗層之方法，分散體及其製造方法 - Google Patents
使用含經靜電穩定的銀奈米粒子之分散體製造導電表面塗層之方法，分散體及其製造方法 Download PDFInfo
- Publication number
- TWI592221B TWI592221B TW100108208A TW100108208A TWI592221B TW I592221 B TWI592221 B TW I592221B TW 100108208 A TW100108208 A TW 100108208A TW 100108208 A TW100108208 A TW 100108208A TW I592221 B TWI592221 B TW I592221B
- Authority
- TW
- Taiwan
- Prior art keywords
- dispersion
- dispersant
- silver
- water
- silver nanoparticles
- Prior art date
Links
- 239000006185 dispersion Substances 0.000 title claims description 153
- 238000000034 method Methods 0.000 title claims description 57
- 238000000576 coating method Methods 0.000 title claims description 46
- 239000011248 coating agent Substances 0.000 title claims description 43
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 title claims description 42
- 230000008569 process Effects 0.000 title claims description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 59
- 239000002270 dispersing agent Substances 0.000 claims description 56
- 239000002245 particle Substances 0.000 claims description 24
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 22
- 229910052709 silver Inorganic materials 0.000 claims description 22
- 239000004332 silver Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000009835 boiling Methods 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 229920003023 plastic Polymers 0.000 claims description 16
- 239000004033 plastic Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000003960 organic solvent Substances 0.000 claims description 5
- 230000003068 static effect Effects 0.000 claims description 5
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 239000002985 plastic film Substances 0.000 claims description 4
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 239000002345 surface coating layer Substances 0.000 claims description 3
- 239000002318 adhesion promoter Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000001035 drying Methods 0.000 description 20
- 238000005245 sintering Methods 0.000 description 18
- 238000005259 measurement Methods 0.000 description 13
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 238000007639 printing Methods 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 238000004220 aggregation Methods 0.000 description 7
- 230000002776 aggregation Effects 0.000 description 7
- 239000000976 ink Substances 0.000 description 7
- -1 poly(vinylpyrrolidone) Polymers 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000006641 stabilisation Effects 0.000 description 6
- 238000011105 stabilization Methods 0.000 description 6
- 238000011026 diafiltration Methods 0.000 description 5
- 229910001961 silver nitrate Inorganic materials 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000004815 dispersion polymer Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 238000005374 membrane filtration Methods 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VYQMXBMNWDFBHM-UHFFFAOYSA-K 2-hydroxypropane-1,2,3-tricarboxylate tetramethylazanium Chemical compound C[N+](C)(C)C.C[N+](C)(C)C.C[N+](C)(C)C.OC(CC([O-])=O)(CC([O-])=O)C([O-])=O VYQMXBMNWDFBHM-UHFFFAOYSA-K 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 238000005411 Van der Waals force Methods 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002338 electrophoretic light scattering Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- XLSMFKSTNGKWQX-UHFFFAOYSA-N hydroxyacetone Chemical compound CC(=O)CO XLSMFKSTNGKWQX-UHFFFAOYSA-N 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920006289 polycarbonate film Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 2
- 229940071536 silver acetate Drugs 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000004425 Makrolon Substances 0.000 description 1
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 description 1
- OKIZCWYLBDKLSU-UHFFFAOYSA-M N,N,N-Trimethylmethanaminium chloride Chemical group [Cl-].C[N+](C)(C)C OKIZCWYLBDKLSU-UHFFFAOYSA-M 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 108010039918 Polylysine Proteins 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- FRHBOQMZUOWXQL-UHFFFAOYSA-L ammonium ferric citrate Chemical compound [NH4+].[Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FRHBOQMZUOWXQL-UHFFFAOYSA-L 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 1
- 229910010277 boron hydride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005100 correlation spectroscopy Methods 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000001962 electrophoresis Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229960004337 hydroquinone Drugs 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004313 iron ammonium citrate Substances 0.000 description 1
- 235000000011 iron ammonium citrate Nutrition 0.000 description 1
- 238000000707 layer-by-layer assembly Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000083 poly(allylamine) Polymers 0.000 description 1
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000656 polylysine Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000001314 profilometry Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 1
- 229910001958 silver carbonate Inorganic materials 0.000 description 1
- 229940071575 silver citrate Drugs 0.000 description 1
- 229960001516 silver nitrate Drugs 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- CSABAZBYIWDIDE-UHFFFAOYSA-N sulfino hydrogen sulfite Chemical class OS(=O)OS(O)=O CSABAZBYIWDIDE-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical group CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical class CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 description 1
- QUTYHQJYVDNJJA-UHFFFAOYSA-K trisilver;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ag+].[Ag+].[Ag+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QUTYHQJYVDNJJA-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/84—Manufacture, treatment, or detection of nanostructure
- Y10S977/89—Deposition of materials, e.g. coating, cvd, or ald
- Y10S977/892—Liquid phase deposition
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Conductive Materials (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Paints Or Removers (AREA)
- Powder Metallurgy (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10002605.3A EP2369597B1 (de) | 2010-03-12 | 2010-03-12 | Herstellung leitfähiger Oberflächenbeschichtungen mit Dispersion mit elektrostatisch stabilisierten Silbernanopartikeln |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201217070A TW201217070A (en) | 2012-05-01 |
| TWI592221B true TWI592221B (zh) | 2017-07-21 |
Family
ID=42111845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100108208A TWI592221B (zh) | 2010-03-12 | 2011-03-11 | 使用含經靜電穩定的銀奈米粒子之分散體製造導電表面塗層之方法，分散體及其製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8834960B2 (enExample) |
| EP (2) | EP2369597B1 (enExample) |
| JP (1) | JP2011190535A (enExample) |
| KR (1) | KR20110103351A (enExample) |
| CN (1) | CN102189072B (enExample) |
| CA (1) | CA2733600A1 (enExample) |
| DK (1) | DK2369597T3 (enExample) |
| ES (1) | ES2495390T3 (enExample) |
| PL (1) | PL2369597T3 (enExample) |
| PT (1) | PT2369597E (enExample) |
| TW (1) | TWI592221B (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2562766A1 (de) * | 2011-08-22 | 2013-02-27 | Bayer MaterialScience AG | Kohlenstoffnanoröhren und Graphenplättchen umfassende Dispersionen |
| DE102011085642A1 (de) * | 2011-11-03 | 2013-05-08 | Bayer Materialscience Aktiengesellschaft | Verfahren zur Herstellung einer Metallnanopartikeldispersion, Metallnanopartikeldispersion sowie deren Verwendung |
| CN103421970B (zh) * | 2012-03-30 | 2017-11-17 | 施耐德电器工业公司 | 一种银基电接触材料的制备方法 |
| US9872916B2 (en) | 2012-04-06 | 2018-01-23 | University of North Texas Office of Economic Development and Technology Transfer | Facile method for making non-toxic biomedical compositions comprising hybrid metal-polymer microparticles |
| JP2016507893A (ja) * | 2012-12-21 | 2016-03-10 | ベネルギー エルエルシー | 太陽エネルギーを収集して変換するための、装置、システム及び方法 |
| JPWO2015068478A1 (ja) * | 2013-11-07 | 2017-03-09 | 富士電機株式会社 | 放射線の測定方法およびこれに使用する金属ナノ粒子複合体 |
| JP2017511820A (ja) * | 2014-02-03 | 2017-04-27 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 電子回路部品タイプの適用のための導電材料の高速印刷用の組成物、および関連する方法 |
| WO2017071949A1 (de) * | 2015-10-30 | 2017-05-04 | Clariant International Ltd | Metalldispersion mit erhöhter stabilität |
| JP6939025B2 (ja) * | 2017-03-31 | 2021-09-22 | 東洋インキＳｃホールディングス株式会社 | 光輝性呈色樹脂組成物、光輝性呈色物品およびその製造方法 |
| CN110573577B (zh) | 2017-04-28 | 2021-10-08 | 日本板硝子株式会社 | 光亮性颜料、含颜料的组合物和含颜料的涂装体 |
| JP7019996B2 (ja) * | 2017-08-23 | 2022-02-16 | コニカミノルタ株式会社 | 水系インクおよび画像形成方法 |
| CN108976914B (zh) * | 2018-08-14 | 2021-06-22 | 重庆文理学院 | 一种高分散的铜纳米线导电墨水、导电薄膜及其制备方法 |
| CN112300430B (zh) * | 2020-10-23 | 2023-01-24 | 东莞市东森光电科技有限公司 | 一种抗静电耐刮钢化膜 |
| CN112589093B (zh) * | 2020-12-15 | 2022-05-27 | 深圳艾利佳材料科技有限公司 | 纳米银抗菌剂、制备方法、及抗菌不锈钢的制备方法 |
| CN112864269A (zh) * | 2021-01-20 | 2021-05-28 | 沈阳师范大学 | 一种基于电场分布调控的高增益紫外雪崩探测器及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2465124A1 (en) * | 2001-11-01 | 2003-05-08 | Yissum Research Development Company Of The Hebrew University In Jerusalem | Ink-jet inks containing metal nanoparticles |
| TWI251018B (en) | 2002-04-10 | 2006-03-11 | Fujikura Ltd | Electroconductive composition, electroconductive coating and method of producing the electroconductive coating |
| CN1961381A (zh) * | 2004-02-18 | 2007-05-09 | 弗吉尼亚科技知识产权公司 | 用于连接的纳米级金属糊及其使用方法 |
| US7919015B2 (en) * | 2006-10-05 | 2011-04-05 | Xerox Corporation | Silver-containing nanoparticles with replacement stabilizer |
| US20100224026A1 (en) * | 2007-10-04 | 2010-09-09 | Margaret Elizabeth Brennan Fournet | A process for synthesising silver nanoparticles |
| US20090104437A1 (en) * | 2007-10-17 | 2009-04-23 | Michael Jeremiah Bortner | Scalable silver nano-particle colloid |
| JP4911003B2 (ja) * | 2007-12-10 | 2012-04-04 | セイコーエプソン株式会社 | 導体パターン形成用インク、導体パターンおよび配線基板 |
| JP5332624B2 (ja) * | 2008-01-22 | 2013-11-06 | 三菱マテリアル株式会社 | 金属ナノ粒子分散液及びその製造方法 |
-
2010
- 2010-03-12 EP EP10002605.3A patent/EP2369597B1/de not_active Not-in-force
- 2010-03-12 PT PT100026053T patent/PT2369597E/pt unknown
- 2010-03-12 PL PL10002605T patent/PL2369597T3/pl unknown
- 2010-03-12 ES ES10002605.3T patent/ES2495390T3/es active Active
- 2010-03-12 DK DK10002605.3T patent/DK2369597T3/da active
-
2011
- 2011-03-08 EP EP11157252A patent/EP2369598A1/de not_active Withdrawn
- 2011-03-09 US US13/044,129 patent/US8834960B2/en not_active Expired - Fee Related
- 2011-03-09 CA CA2733600A patent/CA2733600A1/en not_active Abandoned
- 2011-03-11 CN CN201110058677.7A patent/CN102189072B/zh not_active Expired - Fee Related
- 2011-03-11 JP JP2011054046A patent/JP2011190535A/ja active Pending
- 2011-03-11 KR KR1020110021860A patent/KR20110103351A/ko not_active Withdrawn
- 2011-03-11 TW TW100108208A patent/TWI592221B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2495390T3 (es) | 2014-09-17 |
| TW201217070A (en) | 2012-05-01 |
| PL2369597T3 (pl) | 2015-03-31 |
| DK2369597T3 (da) | 2014-10-06 |
| US20110223322A1 (en) | 2011-09-15 |
| CN102189072B (zh) | 2016-02-10 |
| HK1162395A1 (zh) | 2012-08-31 |
| JP2011190535A (ja) | 2011-09-29 |
| EP2369597B1 (de) | 2014-06-25 |
| CA2733600A1 (en) | 2011-09-12 |
| KR20110103351A (ko) | 2011-09-20 |
| EP2369597A1 (de) | 2011-09-28 |
| US8834960B2 (en) | 2014-09-16 |
| CN102189072A (zh) | 2011-09-21 |
| EP2369598A1 (de) | 2011-09-28 |
| PT2369597E (pt) | 2014-09-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8834960B2 (en) | Production of conductive surface coatings using a dispersion containing electrostatically stabilised silver nanoparticles | |
| CN101232963B (zh) | 铜微粒分散液及其制造方法 | |
| JP2025142096A (ja) | 基材上に形成されたローラーボールペンおよび導電性トレースのための導電性インク | |
| EP2610023A1 (en) | Low-temperature sinterable silver nanoparticle composition and electronic component formed using that composition | |
| KR101802458B1 (ko) | 금속 나노입자 분산액 | |
| CN105340370B (zh) | 制备导电金属层或图案的方法 | |
| KR20110108272A (ko) | 저온 소결성 금속 나노 입자 조성물 및 상기 조성물을 이용하여 형성된 전자 물품 | |
| JP2014505969A (ja) | 導電性被膜の製造用のピッカリングエマルジョン及びピッカリングエマルジョンの製造方法 | |
| KR20080007310A (ko) | 금속 나노 입자의 수계 분산액 | |
| CN113421695B (zh) | 一种水性碳纳米管分散液、导电浆料及其制备方法 | |
| KR20150099595A (ko) | 금속 나노입자 분산액의 제조 방법 | |
| CN105802344A (zh) | 一种抗氧化纳米铜导电油墨 | |
| TWI629319B (zh) | 以（半）導體奈米粒子為主之墨水調配物 | |
| WO2020127676A1 (en) | Conductive ink jet printing ink composition | |
| CN121001838A (zh) | 高负载银纳米线、分散体及膏状物、导电材料、以及对应的方法 | |
| CN108610743A (zh) | 一种导电墨水组合物及其制备方法 | |
| HK1162395B (en) | Production of conductive surface coatings using a dispersion containing electrostatically stabilised silver nanoparticles | |
| TWI504693B (zh) | 低溫燒結性銀奈米粒子組成物及使用該組成物所形成之電子物品 | |
| CN119794325A (zh) | 纳米银颗粒及其制备方法、导电油墨 | |
| KR101836407B1 (ko) | 고주파 분산 스프레이를 이용한 은 나노와이어 균일코팅방법 | |
| HK1161613A (en) | Low-temperature sinterable metal nanoparticle composition and electronic article formed using the composition | |
| HK1191664A (en) | Pickering emulsion for producing electrically conductive coating and process for producing a pickering emulsion |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |