TWI580840B - A sheet and a method for producing the sheet - Google Patents
A sheet and a method for producing the sheet Download PDFInfo
- Publication number
- TWI580840B TWI580840B TW102143744A TW102143744A TWI580840B TW I580840 B TWI580840 B TW I580840B TW 102143744 A TW102143744 A TW 102143744A TW 102143744 A TW102143744 A TW 102143744A TW I580840 B TWI580840 B TW I580840B
- Authority
- TW
- Taiwan
- Prior art keywords
- pva
- sheet
- fiber
- polyurethane
- water
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 253
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 253
- 239000000835 fiber Substances 0.000 claims description 179
- 239000004814 polyurethane Substances 0.000 claims description 169
- 229920002635 polyurethane Polymers 0.000 claims description 169
- 239000000758 substrate Substances 0.000 claims description 91
- 239000000243 solution Substances 0.000 claims description 77
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 75
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 75
- 239000007864 aqueous solution Substances 0.000 claims description 74
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 239000000463 material Substances 0.000 claims description 44
- 229920001410 Microfiber Polymers 0.000 claims description 42
- 238000010438 heat treatment Methods 0.000 claims description 31
- 239000002585 base Substances 0.000 claims description 28
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 25
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 25
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- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 239000003513 alkali Substances 0.000 claims description 11
- 239000002759 woven fabric Substances 0.000 claims description 10
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- 238000000034 method Methods 0.000 description 38
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- 150000002009 diols Chemical class 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000003960 organic solvent Substances 0.000 description 15
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 14
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- 239000007787 solid Substances 0.000 description 10
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- 230000000052 comparative effect Effects 0.000 description 9
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
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- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 5
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 5
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
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- 238000004458 analytical method Methods 0.000 description 3
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- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/10—Conjugate fibres, e.g. core-sheath, side-by-side
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/105—Resistant to abrasion, scratch
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/14—Furniture, upholstery
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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Landscapes
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
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| JP2012261805 | 2012-11-30 |
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| TW (1) | TWI580840B (fr) |
| WO (1) | WO2014084253A1 (fr) |
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| WO2015129602A1 (fr) * | 2014-02-27 | 2015-09-03 | 東レ株式会社 | Matériau en forme de feuille et procédé de production associé |
| IT201700089038A1 (it) * | 2017-08-02 | 2019-02-02 | Alcantara Spa | Nuovo processo per la preparazione di un tessuto non tessuto micro-fibroso sintetico scamosciato |
| CN111918998A (zh) | 2018-04-12 | 2020-11-10 | 东丽株式会社 | 片状物及其制造方法 |
| JP7163959B2 (ja) * | 2018-06-20 | 2022-11-01 | 東レ株式会社 | シート状物の製造方法 |
| EP3951047A4 (fr) * | 2019-03-29 | 2022-12-28 | Toray Industries, Inc. | Article en forme de feuille et procédé de fabrication associé |
| JP7322573B2 (ja) * | 2019-07-30 | 2023-08-08 | 東レ株式会社 | シート状物およびその製造方法 |
| CN115075023B (zh) * | 2022-07-12 | 2024-02-06 | 百草边大生物科技(青岛)有限公司 | 一种含茶叶活性成分的大生物水性合成革的制备方法 |
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| JP2009293150A (ja) * | 2008-06-05 | 2009-12-17 | Toray Ind Inc | シート状物 |
| CN101725052A (zh) * | 2009-11-04 | 2010-06-09 | 烟台万华超纤股份有限公司 | 水性聚氨酯树脂超细纤维革及制造方法 |
| JP2010248683A (ja) * | 2009-03-26 | 2010-11-04 | Toray Ind Inc | 皮革様シート状物およびその製造方法 |
| WO2011114956A1 (fr) * | 2010-03-16 | 2011-09-22 | 東レ株式会社 | Matériau de type feuille et son procédé de fabrication |
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| JPH04240207A (ja) * | 1991-01-22 | 1992-08-27 | Unitika Ltd | ポリビニルアルコール系繊維及びその製造法 |
| JP2980261B2 (ja) * | 1991-07-23 | 1999-11-22 | 株式会社クラレ | 繊維シート状物の製造方法 |
| JP4644971B2 (ja) * | 2000-05-10 | 2011-03-09 | 東レ株式会社 | 皮革様シート状物の製造方法 |
| JP2002030579A (ja) | 2000-07-17 | 2002-01-31 | Toray Ind Inc | 立毛調皮革様シート状物およびその製造方法 |
| JP2002242083A (ja) * | 2001-02-16 | 2002-08-28 | Toray Ind Inc | 人工皮革の製造方法 |
| ITMI20010516A1 (it) * | 2001-03-12 | 2002-09-12 | Alcantara Spa | Processo per la produzione di un tessuto non tessuto microfibroso scamosciato senza l'uso di solventi organici |
| JP2003096676A (ja) | 2001-09-25 | 2003-04-03 | Toray Ind Inc | 皮革様シート状物の製造方法 |
| JP4087321B2 (ja) * | 2003-09-17 | 2008-05-21 | 株式会社クラレ | ポリビニルアルコール系重合体およびその製造方法 |
| US20050118394A1 (en) * | 2003-11-25 | 2005-06-02 | Kuraray Co., Ltd. | Artificial leather sheet substrate and production method thereof |
| KR20080075854A (ko) * | 2005-12-14 | 2008-08-19 | 가부시키가이샤 구라레 | 인공 피혁용 엉킴체의 제조 방법 |
| TWI429806B (zh) * | 2007-03-30 | 2014-03-11 | Kuraray Co | 粒面仿皮革片材及其製法 |
| CN101498106B (zh) * | 2009-02-14 | 2011-11-23 | 烟台万华超纤股份有限公司 | 一种镜面合成革及其制造方法 |
| JP5958060B2 (ja) * | 2012-05-10 | 2016-07-27 | 東レ株式会社 | シート状物およびその製造方法 |
| ITMI20121780A1 (it) * | 2012-10-22 | 2014-04-23 | Alcantara Spa | Nuovo processo per la preparazione di un tessuto non tessuto micro fibroso sintetico scamosciato |
-
2013
- 2013-11-27 US US14/647,923 patent/US20150315741A1/en not_active Abandoned
- 2013-11-27 EP EP13859092.2A patent/EP2927368B1/fr active Active
- 2013-11-27 JP JP2014549860A patent/JP6225917B2/ja active Active
- 2013-11-27 WO PCT/JP2013/081891 patent/WO2014084253A1/fr active Application Filing
- 2013-11-27 CN CN201380062155.1A patent/CN104838063B/zh active Active
- 2013-11-27 KR KR1020157015928A patent/KR102090355B1/ko active IP Right Grant
- 2013-11-29 TW TW102143744A patent/TWI580840B/zh not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009293150A (ja) * | 2008-06-05 | 2009-12-17 | Toray Ind Inc | シート状物 |
| JP2010248683A (ja) * | 2009-03-26 | 2010-11-04 | Toray Ind Inc | 皮革様シート状物およびその製造方法 |
| CN101725052A (zh) * | 2009-11-04 | 2010-06-09 | 烟台万华超纤股份有限公司 | 水性聚氨酯树脂超细纤维革及制造方法 |
| WO2011114956A1 (fr) * | 2010-03-16 | 2011-09-22 | 東レ株式会社 | Matériau de type feuille et son procédé de fabrication |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102090355B1 (ko) | 2020-03-17 |
| JP6225917B2 (ja) | 2017-11-08 |
| EP2927368A1 (fr) | 2015-10-07 |
| JPWO2014084253A1 (ja) | 2017-01-05 |
| EP2927368B1 (fr) | 2017-10-11 |
| KR20150090122A (ko) | 2015-08-05 |
| CN104838063A (zh) | 2015-08-12 |
| WO2014084253A1 (fr) | 2014-06-05 |
| EP2927368A4 (fr) | 2016-06-29 |
| US20150315741A1 (en) | 2015-11-05 |
| CN104838063B (zh) | 2016-09-28 |
| TW201439398A (zh) | 2014-10-16 |
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