TWI523884B - 以交替式供體受體共聚物為主之高效溶液可加工半傳導性聚合物 - Google Patents

以交替式供體受體共聚物為主之高效溶液可加工半傳導性聚合物 Download PDF

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TWI523884B
TWI523884B TW098122448A TW98122448A TWI523884B TW I523884 B TWI523884 B TW I523884B TW 098122448 A TW098122448 A TW 098122448A TW 98122448 A TW98122448 A TW 98122448A TW I523884 B TWI523884 B TW I523884B
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semiconductor
thin film
copolymer
composite material
solution
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TW098122448A
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Chinese (zh)
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TW201008977A (en
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馬可 凱斯特勤
席克 庫勤
克勞斯 慕爾連
崔東
荷 尼可 陶
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巴地斯顏料化工廠
馬克斯 普蘭克科學促進公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent materials, e.g. electroluminescent or chemiluminescent
    • C09K11/06—Luminescent materials, e.g. electroluminescent or chemiluminescent containing organic luminescent materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
    • H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10—Organic polymers or oligomers
    • H10K85/151—Copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C08G2261/124—Copolymers alternating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3243—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more sulfur atoms as the only heteroatom, e.g. benzothiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
    • C08G2261/3246—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing nitrogen and sulfur as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/90—Applications
    • C08G2261/92—TFT applications
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1458—Heterocyclic containing sulfur as the only heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
    • C09K2211/14—Macromolecular compounds
    • C09K2211/1441—Heterocyclic
    • C09K2211/1483—Heterocyclic containing nitrogen and sulfur as heteroatoms
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/40—Organic transistors
    • H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
    • H10K10/462—Insulated gate field-effect transistors [IGFETs]
    • H10K10/466—Lateral bottom-gate IGFETs comprising only a single gate
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14—Carrier transporting layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Thin Film Transistor (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Photoreceptors In Electrophotography (AREA)
  • Hybrid Cells (AREA)
  • Electroluminescent Light Sources (AREA)
TW098122448A 2008-07-02 2009-07-02 以交替式供體受體共聚物為主之高效溶液可加工半傳導性聚合物 TWI523884B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP08159534 2008-07-02

Publications (2)

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TW201008977A TW201008977A (en) 2010-03-01
TWI523884B true TWI523884B (zh) 2016-03-01

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TW098122448A TWI523884B (zh) 2008-07-02 2009-07-02 以交替式供體受體共聚物為主之高效溶液可加工半傳導性聚合物

Country Status (8)

Country Link
US (1) US20110101329A1 (https=)
EP (1) EP2297223B1 (https=)
JP (1) JP5650108B2 (https=)
KR (1) KR101561322B1 (https=)
CN (1) CN102083883B (https=)
CA (1) CA2729714A1 (https=)
TW (1) TWI523884B (https=)
WO (1) WO2010000755A1 (https=)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010057984A2 (en) * 2008-11-24 2010-05-27 Basf Se Photocurable polymeric dielectrics and methods of preparation and use thereof
WO2010079064A2 (en) 2008-12-18 2010-07-15 Basf Se Semiconductor materials prepared from dithienylvinylene copolymers
WO2010125011A2 (de) 2009-04-28 2010-11-04 Basf Se Verfahren zur herstellung von halbleitenden schichten
US8343382B2 (en) * 2009-05-22 2013-01-01 The Regents Of The University Of California Band gap control in conjugated oligomers and polymers via Lewis acids
JP5782703B2 (ja) * 2009-10-29 2015-09-24 住友化学株式会社 高分子化合物及びそれを用いた電子素子
GB2492305B (en) 2010-04-19 2019-06-12 Merck Patent Gmbh Polymers of benzodithiophene and their use as organic semiconductors
JP5533258B2 (ja) * 2010-05-25 2014-06-25 富士ゼロックス株式会社 画像形成装置用像保持体、プロセスカートリッジ、及び画像形成装置
US8394918B2 (en) 2011-02-28 2013-03-12 Corning Incorporated Five-ring fused heteroaromatic compounds and conjugated polymers thereof
KR101282062B1 (ko) * 2011-04-21 2013-07-04 한국화학연구원 페릴렌 단위를 포함하는 반도체성 고분자
US8940411B2 (en) 2011-04-25 2015-01-27 General Electric Company Materials for optoelectronic devices
JP5751100B2 (ja) * 2011-09-05 2015-07-22 コニカミノルタ株式会社 色素増感型太陽電池及び製造方法
KR101259865B1 (ko) * 2011-11-21 2013-05-02 광주과학기술원 저밴드갭의 공중합체 및 이의 제조방법
CN103159918A (zh) * 2011-12-09 2013-06-19 海洋王照明科技股份有限公司 二噻吩蒽醌基共聚物太阳能电池材料及其制备方法和应用
CN104364292B (zh) * 2012-04-13 2018-02-02 韦克森林大学 低带隙结合聚合组合物及其应用
JP6057364B2 (ja) * 2012-04-26 2017-01-11 国立大学法人広島大学 ナフトビスチアジアゾール誘導体
JP6111552B2 (ja) * 2012-08-07 2017-04-12 株式会社リコー 光電変換素子、及び光電変換素子の製造方法
CN103833977B (zh) * 2012-11-27 2016-01-27 海洋王照明科技股份有限公司 一种含苯并二噻吩-噻咯并二(苯并噻二唑)共聚物及其制备与应用
CN103833976B (zh) * 2012-11-27 2016-01-27 海洋王照明科技股份有限公司 一种含苯并噻吩-噻咯并二(苯并噻二唑)共聚物及其制备和应用
CN103833987B (zh) * 2012-11-27 2016-01-13 海洋王照明科技股份有限公司 环戊二烯二噻吩-噻咯并二(苯并噻二唑)共聚物及其制备方法和应用
CN103848960A (zh) * 2012-11-28 2014-06-11 海洋王照明科技股份有限公司 含噻吩-苯-噻吩单元的聚合物及其制备方法和太阳能电池器件
GB201317966D0 (en) * 2013-10-10 2013-11-27 Univ Manchester Nanoparticles
WO2015092909A1 (ja) * 2013-12-19 2015-06-25 リンテック株式会社 高分子化合物、有機光電変換素子、及び該素子の製造方法
JP6274417B2 (ja) * 2014-03-11 2018-02-07 国立大学法人京都大学 ポリマー、光吸収材料、光電変換材料、電荷輸送材料、有機太陽電池用材料および化合物
CN104558531B (zh) * 2015-01-12 2017-02-01 华南理工大学 一种共轭聚合物的合成方法及应用
JP6536940B2 (ja) * 2015-03-13 2019-07-03 リンテック株式会社 高分子化合物、有機光電変換素子、及び該素子の製造方法
WO2017038948A1 (ja) * 2015-09-02 2017-03-09 富士フイルム株式会社 有機薄膜トランジスタ、有機薄膜トランジスタの製造方法、有機半導体組成物、有機半導体膜および有機半導体膜の製造方法
EP3762979A1 (en) 2018-03-07 2021-01-13 Clap Co., Ltd. Patterning method for preparing top-gate, bottom-contact organic field effect transistors
US20200411781A1 (en) 2018-03-08 2020-12-31 Clap Co., Ltd. Organic field effect transistor comprising semiconducting single-walled carbon nanotubes and organic semiconducting material
EP3735430B1 (en) 2018-06-26 2023-09-13 Clap Co., Ltd. Vinylether-based polymer as dielectric
CN110372848A (zh) * 2019-06-18 2019-10-25 东华大学 一种含氟代2,1,3-苯并硒二唑与二噻吩并环戊二烯的聚合物及其制备与应用
US11898000B2 (en) * 2019-07-03 2024-02-13 University Of Connecticut High dielectric breakdown polymers; compositions; methods of making; and use thereof
KR102457457B1 (ko) 2020-10-08 2022-10-20 부산대학교 산학협력단 전-고분자 태양전지용 공액 고분자, 이를 포함하는 전-고분자 태양전지용 활성층 조성물 및 이의 용도
CN113971943B (zh) * 2021-11-17 2022-11-01 京东方科技集团股份有限公司 一种显示驱动方法及其装置、显示装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198153A (en) * 1989-05-26 1993-03-30 International Business Machines Corporation Electrically conductive polymeric
US5274058A (en) * 1991-09-12 1993-12-28 Board Of Regents, The University Of Texas System Low bandgap polymers rf fused bithiophenes
JPH0821718B2 (ja) * 1992-07-30 1996-03-04 日本電気株式会社 電界効果型トランジスタおよびその製造方法
KR100354500B1 (ko) * 2000-09-05 2002-09-30 한화석유화학 주식회사 플로렌계 중합체 및 이를 이용한 전기발광 소자
DE602004024629D1 (de) * 2003-10-15 2010-01-28 Merck Patent Gmbh Polybenzodithiophene
GB0400997D0 (en) * 2004-01-16 2004-02-18 Univ Cambridge Tech N-channel transistor
US7351606B2 (en) * 2004-06-24 2008-04-01 Palo Alto Research Center Incorporated Method for forming a bottom gate thin film transistor using a blend solution to form a semiconducting layer and an insulating layer
US7781673B2 (en) * 2005-07-14 2010-08-24 Konarka Technologies, Inc. Polymers with low band gaps and high charge mobility
US7772485B2 (en) * 2005-07-14 2010-08-10 Konarka Technologies, Inc. Polymers with low band gaps and high charge mobility
US8075943B2 (en) * 2005-12-27 2011-12-13 Hitachi Chemical Co., Ltd. Purification process for organic electronics material
WO2007121252A2 (en) * 2006-04-11 2007-10-25 Konarka Technologies, Inc. Tandem photovoltaic cells
TW200813111A (en) * 2006-08-01 2008-03-16 Sumitomo Chemical Co Polymer compound and polymer illuminating element

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CN102083883B (zh) 2016-01-20
EP2297223A1 (en) 2011-03-23
WO2010000755A1 (en) 2010-01-07
EP2297223B1 (en) 2013-11-13
KR101561322B1 (ko) 2015-10-16
CN102083883A (zh) 2011-06-01
US20110101329A1 (en) 2011-05-05
KR20110038043A (ko) 2011-04-13
JP5650108B2 (ja) 2015-01-07
JP2011528383A (ja) 2011-11-17
CA2729714A1 (en) 2010-01-07
TW201008977A (en) 2010-03-01

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