TWI491565B - 多孔球形二氧化鈦 - Google Patents
多孔球形二氧化鈦 Download PDFInfo
- Publication number
- TWI491565B TWI491565B TW100133857A TW100133857A TWI491565B TW I491565 B TWI491565 B TW I491565B TW 100133857 A TW100133857 A TW 100133857A TW 100133857 A TW100133857 A TW 100133857A TW I491565 B TWI491565 B TW I491565B
- Authority
- TW
- Taiwan
- Prior art keywords
- titanium oxide
- porous spherical
- spherical titanium
- range
- surface area
- Prior art date
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims description 44
- 239000004408 titanium dioxide Substances 0.000 title claims description 14
- 239000002245 particle Substances 0.000 claims description 51
- 239000007921 spray Substances 0.000 claims description 30
- 239000011148 porous material Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 17
- 239000000725 suspension Substances 0.000 claims description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 239000007900 aqueous suspension Substances 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000011149 active material Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 35
- 239000010419 fine particle Substances 0.000 description 10
- 229910044991 metal oxide Inorganic materials 0.000 description 7
- 150000004706 metal oxides Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000011362 coarse particle Substances 0.000 description 6
- 239000011236 particulate material Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000010335 hydrothermal treatment Methods 0.000 description 4
- 238000001354 calcination Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- UAMZXLIURMNTHD-UHFFFAOYSA-N dialuminum;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Al+3] UAMZXLIURMNTHD-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
- B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/50—Producing shaped prefabricated articles from the material specially adapted for producing articles of expanded material, e.g. cellular concrete
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/08—Drying; Calcining ; After treatment of titanium oxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Analytical Chemistry (AREA)
- Mechanical Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Glanulating (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010041189 | 2010-09-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201223873A TW201223873A (en) | 2012-06-16 |
| TWI491565B true TWI491565B (zh) | 2015-07-11 |
Family
ID=45478043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100133857A TWI491565B (zh) | 2010-09-22 | 2011-09-21 | 多孔球形二氧化鈦 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8715827B2 (enExample) |
| EP (1) | EP2619138B1 (enExample) |
| JP (1) | JP6234816B2 (enExample) |
| KR (1) | KR101774296B1 (enExample) |
| CN (1) | CN103153867B (enExample) |
| DE (1) | DE102011053753A1 (enExample) |
| TW (1) | TWI491565B (enExample) |
| WO (1) | WO2012062303A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SI2588232T1 (sl) | 2010-06-29 | 2020-09-30 | Venator Germany Gmbh | Katalitski material in postpoek za njegovo izdelavo |
| EP2465605A3 (en) | 2010-12-20 | 2014-04-30 | Sachtleben Chemie GmbH | Titania-supported hydrotreating catalysts |
| TWI651269B (zh) * | 2013-09-23 | 2019-02-21 | Tioxide Europe Limited | 二氧化鈦粒子及其製備方法 |
| WO2015124149A1 (de) * | 2014-02-21 | 2015-08-27 | Sachtleben Chemie Gmbh | Katalysatorprecursormaterial auf TiO2-Basis, dessen Herstellung und dessen Verwendung |
| KR102618310B1 (ko) * | 2016-09-19 | 2023-12-26 | 한양대학교 산학협력단 | 타이타늄 복합체 분말 및 이의 제조방법 |
| CN112174197B (zh) * | 2020-09-29 | 2022-05-24 | 攀钢集团研究院有限公司 | 以四氯化钛为原料制备锂电负极材料钛酸锂的方法 |
| CN116654978A (zh) * | 2023-06-05 | 2023-08-29 | 厦门大学 | 一种通过喷雾水解制备二氧化钛微球的方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1176046A (en) * | 1966-12-19 | 1970-01-01 | Grace W R & Co | Preparation of Microspheroidal Titanium Dioxide. |
| WO2008076082A1 (en) * | 2006-12-20 | 2008-06-26 | Nanyang Technological University | Microspheric tio2 photocatalyst |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS601056B2 (ja) | 1980-02-19 | 1985-01-11 | 千代田化工建設株式会社 | アスファルテンを含む重質炭化水素油の水素化処理 |
| JPS6065725A (ja) * | 1983-09-20 | 1985-04-15 | Fuji Titan Kogyo Kk | チタニヤ球状粒子の製造法 |
| US5128291A (en) * | 1990-12-11 | 1992-07-07 | Wax Michael J | Porous titania or zirconia spheres |
| JP3653112B2 (ja) * | 1994-12-15 | 2005-05-25 | チタン工業株式会社 | 顆粒状二酸化チタン及びその製造方法 |
| US6613234B2 (en) * | 1998-04-06 | 2003-09-02 | Ciphergen Biosystems, Inc. | Large pore volume composite mineral oxide beads, their preparation and their applications for adsorption and chromatography |
| JP4731053B2 (ja) * | 2001-06-28 | 2011-07-20 | 日揮触媒化成株式会社 | 樹脂被覆球状多孔質粒子、その製造方法、および該粒子を配合した化粧料 |
| CN1210101C (zh) * | 2002-03-07 | 2005-07-13 | 江苏苏净集团有限公司 | 纳米二氧化钛多孔微球及其制造方法 |
| JP4105971B2 (ja) * | 2003-03-27 | 2008-06-25 | 株式会社資生堂 | 多孔質酸化チタン粉体及びその製造方法 |
| US20060263291A1 (en) | 2004-11-23 | 2006-11-23 | Carmine Torardi | Mesoporous amorphous oxide of titanium |
| KR100615781B1 (ko) * | 2004-12-31 | 2006-08-25 | 주식회사 효성 | 차광성 및 난연성이 우수한 폴리에스터 섬유 및 이를이용한 섬유 제품 |
| JP5046389B2 (ja) * | 2005-04-08 | 2012-10-10 | 協和化学工業株式会社 | アルナイト型化合物粒子、その製造方法およびその利用 |
| JP5400607B2 (ja) * | 2007-03-16 | 2014-01-29 | 石原産業株式会社 | 電極活物質及びそれを用いてなるリチウム電池 |
-
2011
- 2011-09-19 KR KR1020137008444A patent/KR101774296B1/ko active Active
- 2011-09-19 US US13/822,313 patent/US8715827B2/en not_active Expired - Fee Related
- 2011-09-19 WO PCT/DE2011/075226 patent/WO2012062303A1/de not_active Ceased
- 2011-09-19 EP EP20110808157 patent/EP2619138B1/de active Active
- 2011-09-19 CN CN201180045481.2A patent/CN103153867B/zh active Active
- 2011-09-19 DE DE201110053753 patent/DE102011053753A1/de not_active Withdrawn
- 2011-09-19 JP JP2013528514A patent/JP6234816B2/ja not_active Expired - Fee Related
- 2011-09-21 TW TW100133857A patent/TWI491565B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1176046A (en) * | 1966-12-19 | 1970-01-01 | Grace W R & Co | Preparation of Microspheroidal Titanium Dioxide. |
| WO2008076082A1 (en) * | 2006-12-20 | 2008-06-26 | Nanyang Technological University | Microspheric tio2 photocatalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6234816B2 (ja) | 2017-11-22 |
| CN103153867B (zh) | 2017-07-28 |
| KR101774296B1 (ko) | 2017-09-04 |
| WO2012062303A1 (de) | 2012-05-18 |
| DE102011053753A1 (de) | 2012-04-26 |
| JP2013542160A (ja) | 2013-11-21 |
| EP2619138B1 (de) | 2014-11-12 |
| EP2619138A1 (de) | 2013-07-31 |
| US8715827B2 (en) | 2014-05-06 |
| US20130189520A1 (en) | 2013-07-25 |
| KR20130140656A (ko) | 2013-12-24 |
| CN103153867A (zh) | 2013-06-12 |
| TW201223873A (en) | 2012-06-16 |
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| Date | Code | Title | Description |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |