TWI462942B - 含有可固化的氟化共聚物之基材塗料 - Google Patents

含有可固化的氟化共聚物之基材塗料 Download PDF

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Publication number
TWI462942B
TWI462942B TW095147365A TW95147365A TWI462942B TW I462942 B TWI462942 B TW I462942B TW 095147365 A TW095147365 A TW 095147365A TW 95147365 A TW95147365 A TW 95147365A TW I462942 B TWI462942 B TW I462942B
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Taiwan
Prior art keywords
vinyl
coating
acid
group
copolymer
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TW095147365A
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English (en)
Chinese (zh)
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TW200736285A (en
Inventor
Juergen Reiners
Tillmann Hassel
Rodger Maier
Akihiko Ueda
Masaru Nagato
Masahiko Maeda
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Lanxess Deutschland Gmbh
Daikin Ind Ltd
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Priority claimed from EP05027728A external-priority patent/EP1801133A1/en
Priority claimed from EP06003301A external-priority patent/EP1820809A1/en
Application filed by Lanxess Deutschland Gmbh, Daikin Ind Ltd filed Critical Lanxess Deutschland Gmbh
Publication of TW200736285A publication Critical patent/TW200736285A/zh
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Publication of TWI462942B publication Critical patent/TWI462942B/zh

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/22Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02Homopolymers or copolymers of esters of monocarboxylic acids
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/10Acylation
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/46Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805Compounds having only one group containing active hydrogen
    • C08G18/2815Monohydroxy compounds
    • C08G18/283Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • CCHEMISTRY; METALLURGY
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6275Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6279Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705Dispersions of isocyanates or isothiocyanates in a liquid medium
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71Monoisocyanates or monoisothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/04Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08L79/08Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • C14C11/006Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Laminated Bodies (AREA)
TW095147365A 2005-12-19 2006-12-18 含有可固化的氟化共聚物之基材塗料 TWI462942B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05027728A EP1801133A1 (en) 2005-12-19 2005-12-19 Curable fluorinated copolymers and coatings and processes thereof
EP06003301A EP1820809A1 (en) 2006-02-17 2006-02-17 Coating of substrates with curable fluorinated copolymers

Publications (2)

Publication Number Publication Date
TW200736285A TW200736285A (en) 2007-10-01
TWI462942B true TWI462942B (zh) 2014-12-01

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US (2) US20090306284A1 (cg-RX-API-DMAC7.html)
EP (1) EP1966253B1 (cg-RX-API-DMAC7.html)
JP (2) JP5513742B2 (cg-RX-API-DMAC7.html)
KR (1) KR101393263B1 (cg-RX-API-DMAC7.html)
CN (1) CN101341173B (cg-RX-API-DMAC7.html)
AR (1) AR059562A1 (cg-RX-API-DMAC7.html)
AU (1) AU2006329052A1 (cg-RX-API-DMAC7.html)
BR (1) BRPI0620006A2 (cg-RX-API-DMAC7.html)
CA (1) CA2632399A1 (cg-RX-API-DMAC7.html)
TW (1) TWI462942B (cg-RX-API-DMAC7.html)
WO (1) WO2007071323A1 (cg-RX-API-DMAC7.html)

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BRPI0620006A2 (pt) * 2005-12-19 2011-10-25 Lanxess Deutschland Gmbh processo para revestir substratos flexìveis e rìgidos, composição de revestimento, processo para revestimento de substratos, copolìmeros a1 e a2 fluorados curáveis, dispersão aquosa, processo para fabricação do copolìmero a2, uso de copolìmero a fluorado curável, substrato obtido pelo processo, substrato revestido
CN101517017B (zh) * 2006-09-22 2012-09-26 旭硝子株式会社 水性涂料用组合物及其制造方法及二液固化型水性涂料盒
EP2188343B1 (en) 2007-08-24 2016-07-13 Vencorex France Two component waterborne polyurethane coatings for anti-graffiti application
GB0919014D0 (en) 2009-10-30 2009-12-16 3M Innovative Properties Co Soll and stain resistant coating composition for finished leather substrates
CN101798366B (zh) * 2010-03-12 2012-02-08 常州光辉化工有限公司 水性全氟烷基氟碳乳液和含有该乳液的水性电缆防结冰涂料及其制备方法
JP2012134464A (ja) * 2010-11-30 2012-07-12 Daikin Ind Ltd 太陽電池システム
WO2012133836A1 (ja) * 2011-03-31 2012-10-04 ダイキン工業株式会社 含フッ素共重合体
CN102348297B (zh) * 2011-10-19 2013-03-27 信阳市环宇针织服装有限公司 一种纳米碳纤维复合电热材料及其制备方法
CN102627899B (zh) * 2012-04-13 2014-04-16 阜新恒通氟化学有限公司 一种含氟高光漆的制备工艺
EP2838965A4 (en) * 2012-04-17 2015-05-20 Arkema Inc AQUEOUS FLUOROPOLYMER GLASS COATING
JP5914169B2 (ja) * 2012-05-28 2016-05-11 株式会社有沢製作所 フレキシブルプリント配線板用樹脂組成物
JP6247492B2 (ja) * 2012-11-06 2017-12-13 ダウ グローバル テクノロジーズ エルエルシー 水性皮革コーティング組成物および皮革をコーティングするための方法
CN103602764B (zh) * 2013-11-18 2015-10-21 海宁森德皮革有限公司 一种抗污型汽车内饰革的生产工艺
KR101947421B1 (ko) * 2014-10-20 2019-02-14 (주)엘지하우시스 표면코팅용 수성 조성물 및 이를 적용한 자동차용 시트
CN104356289B (zh) * 2014-12-02 2016-08-17 郭依依 一种太阳能背板专用四氟乙烯系氟碳涂料树脂及制备方法
BR112017026964B1 (pt) * 2015-06-16 2022-09-20 Novapharm Research (Australia) Pty Ltd Método para remoção de gorduras, óleos e efluentes de cozedura de um sistema de escape de exaustor, composição de revestimento destacável, película destacável contínua, e, sistema de escape de coifa
JP6033974B1 (ja) * 2016-01-18 2016-11-30 株式会社Sskプロテクト 二液型コーティング剤及び被覆体保護方法
CN108848670B (zh) * 2016-05-20 2021-11-19 三井化学株式会社 固化性组合物及其用途
JP6733329B2 (ja) * 2016-06-10 2020-07-29 株式会社ジェイテクト 転がり軸受、機械要素、及び固体膜形成方法
JPWO2018079774A1 (ja) * 2016-10-31 2019-09-19 Agc株式会社 車両内装部材用水性塗料、車両内装部材および車両内装部材の製造方法
KR102600965B1 (ko) * 2017-01-18 2023-11-13 다이킨 고교 가부시키가이샤 단백질 저흡착성을 갖는 단백질 혹은 단백질을 포함하는 조성물의 투여용, 보존용, 운반용 또는 수송용 용기 및 단백질 혹은 단백질 조성물의 제조용 기재
WO2018135394A1 (ja) * 2017-01-19 2018-07-26 パナソニックIpマネジメント株式会社 塗料組成物、光学部材及び照明装置
CN107383263A (zh) * 2017-08-04 2017-11-24 安徽博泰氟材料科技有限公司 水性氟树脂涂料及其制备工艺
US11214707B2 (en) * 2018-09-21 2022-01-04 The Boeing Company Compositions and methods for fabricating coatings
CN109825177A (zh) * 2018-12-28 2019-05-31 新纶复合材料科技(常州)有限公司 一种氟碳涂料
CN111410859A (zh) * 2020-01-16 2020-07-14 佛山市大幸新材料有限公司 一种瓷砖全氟防污防护材料
KR102145147B1 (ko) * 2020-03-27 2020-08-14 이흥수 친환경 피혁제품용 코팅제 조성물 및 이를 포함하는 피혁재료
CN114133516B (zh) * 2021-12-31 2023-05-26 广东美涂士建材股份有限公司 一种自清洁低表面能改性聚氨酯的制备方法
ES2988637T3 (es) * 2022-01-17 2024-11-21 Hermes Sellier Un método para producir un sustituto del cuero terminado
CN115010842B (zh) * 2022-05-20 2024-02-02 万华化学集团股份有限公司 一种含氟强碱性阴离子树脂催化剂、制备方法及一种(甲基)丙烯酸羟乙酯的制备方法
WO2024026053A1 (en) * 2022-07-28 2024-02-01 Arkema Inc. Crosslinkable fluoropolymer coating
CN116354907A (zh) * 2023-04-12 2023-06-30 智仑超纯环氧树脂(西安)有限公司 一种含氟环氧树脂及其制备方法、应用
CN120137517A (zh) * 2025-04-14 2025-06-13 佛山科建建筑科技有限公司 一种抗污聚氨酯涂料及其生产方法

Citations (4)

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CN101341173A (zh) 2009-01-07
JP2009520087A (ja) 2009-05-21
US20130184400A1 (en) 2013-07-18
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AR059562A1 (es) 2008-04-16
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