TWI380442B - Semiconductor device and method of making semiconductor device comprising multiple stacked hybrid orientation layers - Google Patents
Semiconductor device and method of making semiconductor device comprising multiple stacked hybrid orientation layers Download PDFInfo
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- TWI380442B TWI380442B TW094141672A TW94141672A TWI380442B TW I380442 B TWI380442 B TW I380442B TW 094141672 A TW094141672 A TW 094141672A TW 94141672 A TW94141672 A TW 94141672A TW I380442 B TWI380442 B TW I380442B
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- Prior art keywords
- layer
- semiconductor device
- insulating layer
- germanium
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- 239000004065 semiconductor Substances 0.000 title claims description 45
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000013078 crystal Substances 0.000 claims description 42
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 39
- 229910052732 germanium Inorganic materials 0.000 claims description 34
- 239000000758 substrate Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 24
- -1 hydrogen ions Chemical class 0.000 claims description 5
- 230000007547 defect Effects 0.000 claims description 4
- 125000006850 spacer group Chemical group 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 229910000420 cerium oxide Inorganic materials 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- 239000012634 fragment Substances 0.000 claims 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 claims 1
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 52
- 150000002500 ions Chemical class 0.000 description 10
- 239000007943 implant Substances 0.000 description 9
- 239000002019 doping agent Substances 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 4
- 229910052715 tantalum Inorganic materials 0.000 description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical class [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 2
- 230000003071 parasitic effect Effects 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- SCCCLDWUZODEKG-UHFFFAOYSA-N germanide Chemical compound [GeH3-] SCCCLDWUZODEKG-UHFFFAOYSA-N 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 125000001475 halogen functional group Chemical group 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
- 230000035922 thirst Effects 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/84—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being other than a semiconductor body, e.g. being an insulating body
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
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- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
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- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
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- H01L21/823807—Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the channel structures, e.g. channel implants, halo or pocket implants, or channel materials
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- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
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- H01L21/7624—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology
- H01L21/76251—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology using bonding techniques
- H01L21/76254—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology using bonding techniques with separation/delamination along an ion implanted layer, e.g. Smart-cut, Unibond
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- H01L21/76264—SOI together with lateral isolation, e.g. using local oxidation of silicon, or dielectric or polycristalline material refilled trench or air gap isolation regions, e.g. completely isolated semiconductor islands
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- H01L21/76264—SOI together with lateral isolation, e.g. using local oxidation of silicon, or dielectric or polycristalline material refilled trench or air gap isolation regions, e.g. completely isolated semiconductor islands
- H01L21/76283—Lateral isolation by refilling of trenches with dielectric material
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- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/823481—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type isolation region manufacturing related aspects, e.g. to avoid interaction of isolation region with adjacent structure
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- H01L21/82—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
- H01L21/822—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
- H01L21/8232—Field-effect technology
- H01L21/8234—MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
- H01L21/8238—Complementary field-effect transistors, e.g. CMOS
- H01L21/823878—Complementary field-effect transistors, e.g. CMOS isolation region manufacturing related aspects, e.g. to avoid interaction of isolation region with adjacent structure
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
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- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1203—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI
- H01L27/1207—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body the substrate comprising an insulating body on a semiconductor body, e.g. SOI combined with devices in contact with the semiconductor body, i.e. bulk/SOI hybrid circuits
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/04—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their crystalline structure, e.g. polycrystalline, cubic or particular orientation of crystalline planes
- H01L29/045—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their crystalline structure, e.g. polycrystalline, cubic or particular orientation of crystalline planes by their particular orientation of crystalline planes
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thin Film Transistor (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Element Separation (AREA)
- Recrystallisation Techniques (AREA)
Description
1380442 九、發明說明: “ 【發明所屬之技術領域】 本發明係關於半導體裝置以及製造半導體裝置之方 法,更詳而言之’係關於包括絕緣層上覆矽(silicon_〇n_ insulator ’簡稱SOI)技術之改良半導體裝置。 【先前技術】 在半導體產業中持續研發之重要目標為在增加半導體 效能的同時減少半導體裝置之功率消耗。諸如金屬氧化物 •半導體場效電晶體(MOSFETs)之平面型電晶體(planar transistor)特別適合用於高密度積體電路。當M〇SFETs -以及其他裝置之尺寸減小時,該裝置之源極/汲極區域、通 .道(channel)區域、以及閘極電極之大小亦減小。 具有短通道長度之持續更小的平面型電晶體之設計需 要&供非常淺的源極/沒極接點(junct i〇ns)。淺接點需要 避免植入的摻雜物侧向擴散至通道内,因為此種擴散不利 _地造成漏電流(leakage current)以及不佳的擊穿 (breakdown)效能❶通常在短通道裝置中可接受的效能需要 深度為1 000埃(A )等級或更小之淺源極/汲極。 絕緣層上覆矽(SOI)技術允許形成高速、淺接點裝置。 此外,SOI裝置藉由減少寄生接點電容(parasitic junction capacitance)而改進效能。 在SOI基材中,由氧化矽製成之埋設氧化物(buried 〇xide)(B0X)膜係形成於單晶矽上,而單晶矽薄膜係形成於 其上各種製造此種SOI基材之方法為已知的。其甲一種 93305 6 1380442 4^M^^^^(Separati〇n_byimpianted 〇,:en)(s刪)之方法,其中 其 形成埋設氧化物(臟)膜。 m w基心 另一種形成S〇I基材之方法為晶圓接合(㈤打 同0將具有氧切表面層之兩個半導體基材共 二間 乳化石夕表面以形成B〇X層於該等兩個半導體基 另-種SOI技術為SmartCut®,其亦有關經由氧化物 曰而接合半導體基材。在Smartcut@方法中,在接合前以 ㈣子植人其t-財導縣材。錢料植人接著使經 氫離子植入之基材自接合的基材中分離,而留下石夕薄層在 表面上。 θ 可藉由選擇具有某晶面定向(crystal plane orientations)之矽層而進一步提升半導體裝置效能,該晶 面疋向有利於電洞或電子流動。例如,若將p型m〇sfeTs 籲(PMOSFETs)製造於(11 〇 )矽表面上,且將閘極定向使電洞於 (ιιο)/<ιιο>的方向流動,則可改良PM0SFETs的效能。在 (ιιο)/<ιιο>方向流動的電洞的遷移率(mobility)比在習 知(100)/<11〇>方向流動的電洞的遷移率的兩倍還高。不幸 地,在(no)表面上以對(110)/<110>方向之成直角(right angles)移動之電洞在(11〇)/<100>方向流動。在(11〇)/ <100〉方向的電洞的遷移率只有在(110)/<110>方向流動的 電洞的遷移率的2/3。此外,在(11 〇)面的電子遷移率比在 習知(100)面的電子遷移率低很多。 93305 7 1380442 —此處所應用之術語「半導體裝置」不限於特定揭露之 實施例在匕處所應用之半導體裝置包含種類廣泛的電子褒 置’其包含覆晶⑴ip chips)、覆晶/封裝組合(package assemblies)电日日體、電容器、微處理器、隨機存取記憶 體等通吊’半導體襄置係指任何包括半導體之電子裳置。 【發明内容】 在半導體裝置技藝中存在結合SOI技術之效能改良以 及理想石夕晶向(crystal orientation)之需求。在此技藝中 進一步存在包括MOSFETs之半導體裝置之需求,其中 PMOSFETs和_SFETs分別製造於對於電洞(hQle)和電子 -遷移率而言為理想的石夕表面上。在此技藝中亦存在形成包 括SOI技術及理想石夕晶向之半導體裝置之方法之需求。此 外,在此技藝中存在形成包括M〇SFETs之半導體裝置之方 法之需求’其中P贿ETs和腦SFETs製造於對於電洞和 電子遷移率而言為理想的矽表面上。 ❿ 本發明之實施例符合這些及其他需求,其係提供包括 具有第一晶向之基材之半導體裝置。第一絕緣層應在該基 材上,且複數個矽層位在該第一絕緣層上。第一矽層包括 具有第二晶向和晶面之石夕。第二石夕層包括具有該第二晶向 及大體與第一矽層之晶面垂直之晶面之矽。 …本發明之實施例復符合這些及其他需求,其提供形成 半導體褒置之方法,包括:設置絕緣層上覆石夕結構,該絕 緣層上覆矽結構包括有第一絕緣層形成於其上之具有第一 晶向之第一矽基材,以及位於第一絕緣層上之具有第二晶 93305 8 1380442 向和晶面之第一矽層。提供第二矽基材,其具有該第二晶 向及晶面以及形成於該第二基材上之第二絕緣層。第二矽 基材包括藉由植入氫離子至該第二矽基材所產生之缺陷線 (a line of defects)。經由該第二絕緣層及該第一矽層而 接合該第二矽基材至該絕緣層上覆矽結構,以使該第二矽 基材之晶面定向為大體垂直於該第一矽層之晶面。該第二 矽基材沿缺陷線分裂和移除,而留下該第二絕緣層及第二 矽層於該絕緣層上覆矽結構上。 本發明滿足具有改良電子特性之改良高速半導體裝置 之需求。 本發明之上述及其他特點、方面、以及優點將在以下 本發明之詳細說明配合所附圖式而更為清楚。 【實施方式】 本發明能夠製造具有s〇i技術之優點以及形成於一般 矽基材上具有不同晶向之矽層上之M0SFET之改良的高速 半導體裝置。本發明復以S〇 I技術之減少的寄生接點電容 優點提供藉由形成於具有(110)/<110>晶向之矽層上之 PM0SFET所提供之更高電洞遷移率。 為了使從在(11 〇 )面上製造裝置獲得之完全效能最佳 化’必須定向所有PM0SFET閘極以使電洞可在(11〇)/<11〇> 方向流動。在習知電路佈局中製造M0SFET閘極電極以致許 多閘極與其他閘極成直角。 根據本發明某些實施例,多堆疊混合定向(hybrid oirientation)層提供複數個矽層,該等矽層具有形成於一 9 93305 1380442 曝光及圖案化光阻、非等向性蝕刻、以及移除剩下的光阻 以形成溝44,如第13圖所示。溝44位於氮化物側壁38 周圍’以使當進行非等向性蝕刻時,從結構27移除氮化物 側壁38。 如第14圖所示,溝44接著藉由習知CVD製程以適合 的絕緣材料48填充。適合的絕緣材料48包括氮化矽及氧 化石夕。在本發明之某些實施例中’溝區域44以氧化矽48 填充以隔離第一區域52、第二區域54、以及第三區域56。 一些習知以氧化矽填充溝區域44之方法包含: (a) 四乙氧基石夕(tetraethylorthosi 1 icate)低壓化 學氣相沉積(TEOS LPCVD), (b) 非表面敏感TE0S臭氧大氣壓(non-surface sensitive TEOS ozone atmosphere)或次大氣壓 (sub-atmospheric pressure)化學氣相沉積 (APCVD 或 SACVD),以及 (c) 矽烷氧化高密度電漿CVD。 以氧化石夕48填充溝44前,熱氧化物襯料(1丨ners)(圖 中未顯示)係照慣例沿溝44之壁49成長,例如藉由在溫度 約950t至約ll〇〇t:暴露結構27於氧氣環境。接著藉由又 CMP平坦化結構27以移除延伸在溝〇上之氧化矽4/。平 垣化之後,接著移除氮化矽層28及氧化矽層26,如第15 圓所示,以暴露第二矽層25之上表面5〇。典型藉由渴式 _移除氮化㈣28及氧切層26。習知利用㈣酸二 刻虱化矽以及利用氫氟酸或氫氟酸和氟化銨的混合物(緩 93305 15 1380442 « 衝氧化物蝕刻)移除氧化矽。於所得之結構 層42與第三區域56之第二他二 = 石夕層4°隔離。第—區域52之第三石夕層40 亦/、第二區域56之第二矽層25隔離。 如第16圖所示,形成NM〇SFET58於第—區域μ ::〇ΓΓ:ΕΤ60於第二區域54中,以及形成PM0SFET62 構27之第三區域56中。該形成於第三區域56 =二石夕層25之PM贿62定向為大體與形成於第二區 域54之第一矽層42之PMOSFET 60垂直。 形成閘極氡化物層64及閘極電極層66於結構π上。 在本發明之某些實施例中,閘極電極層 山咖)且形成至厚度約⑽奈米至約_奈米。間 ,氧化物層64典型形成至厚度約1()埃⑷至約彻埃。 错由習知的微影和飯刻技術圖案化閘極氧化物層64及閉 極電極層6 6。 藉由習知的離子植入技術形成源極和沒極延伸區 7〇。植入至源極和汲極延伸區7G之摻雜物 NM0SFET或PM〇SFET而定。例如,若電曰,Λ裝置為 J 右逼日日體為簡0SFET,則 將N型摻雜物植入至源極和沒極延伸區7〇。在本發明之某 些實施例中,例如砷之Μ摻雜物以植入量約心〇)4離; 二方::分U㈣㈤至約 千電子伏㈣eV)W5千電子伏特植入至源極和 沒極延伸區70。若電晶體為PM0SFET,則將p型摻雜物植 入至源極和沒極延伸區70。在本發明之某些實施例中,例 93305 16 丄細442 如二氟化蝴(BF2)之p型摻雜物以植入量約1χ 1〇14離子/平 ♦刀至約2x 1〇離子/平方公分以及植入能量約〇 5千 a子伏特至約5千電子伏特植人至源極和汲極延伸區。 而要幵v成環形植入物(halo implants)72於通道區 一、4中接近M〇SFET 58 ' 6〇、之汲極和源極區域μ。 :與沒極和源極區域68之導電型式(conductivity type) 令。捧雜物形成環开)植入⑯72。在本發明之某些實施例 • 可以角度植入(angled implant)形成環形植入物72。 本發月之某些實施例中,環形植入物72可以植入量約8 X 1—〇12離子/平方公分至約2χ 10“離子/公分平方以及植入 能量約7千電子伏特至約5()千電子伏特植人。環形植入物 α +避免在通道區域74中源極和汲汲區域之合併。此外, 可藉由调整壤形劑量(hal〇 dose)而修改M0SFET 58、60、 62之臨界電壓。 接著形成源極和汲極區域68之重濃度摻雜(heaviiy d〇Ped_)部,78(下文中亦稱重濃度摻雜區域78)。如第i 7 圖所不’藉由習知方法在閘極電極66周圍形成侧壁間隔件 ^例如沉積絕緣材料層例如氮化發或氧化⑪,接著藉由 性蝕刻以形成側壁間隔件7 6。在本發明之某實“ ,右電晶體為NM0SFET,則以植入量約1χ 1〇丨5離子/平 方公分至約4Χ 1015離子/平方公分以及植人能量約20千電 子伏特至約50千電子伏特植人~至重濃度摻㈣域 在,發明之某些實施例中,若電晶體為pm〇sfet,則以植 入罝約1X 1〇15離子/平方公分至約4x 1〇15離子/平方公分 93305 17 1380442 以及植入能量約2千電子伏特至約1G千電子伏特植入蝴至 '重濃度摻雜區域78。 由於在具有<110〉晶向之矽上製造PM0SFET可大幅提 昇PM0SFET之效能,包括<11〇〉晶向石夕之石夕層以卩型摻雜物 摻雜於汲極和源極區域68。包括<1〇〇>晶向矽之矽層以N 型摻雜物摻雜於汲極和源極區域68以形成nm〇sfet。 接著沉積金屬層於SOI結構27上。加熱S0I結構27 使金屬層與下面的源極和汲極區域68及閘極電極中之 矽反應而形成在源極和汲極區域68中及閘極電極上之 金屬矽化物接點80,如第18圖所示。 在本發明之某些實施例中,S0I結構91形成有絕緣β〇χ 層84,以使第一區域86中之第三矽層4〇、第二區域88 中之第一矽層42、以及第三區域90中之第二矽層25各為 SOI矽層,如第19圖所示。藉由SIM〇x製程而形成Β〇χ層 84。在SIM0X製程中’植入氧離子82至S0I結構91。在 φ本發明之某些實施例中,以能量範圍為從約7〇千電子伏特 至約200千電子伏特以及劑量範圍為從約1〇χ 1〇π離子/ 平方公分至約1. 〇χ 1〇18離子/平方公分植入氧離子82至 SOI結構91。離子植入後,在溫度範圍從約125{rc至約 C中退火SOI結構91約4至約6小時。如第20圖所示, 接著形成複數個M0SFET 92、94、96於第一區域86、第二 區域88、以及第三區域90,如上所述。 在本發明之替代實施例中,BOX層84未延伸至第三區 域90下。在第一區域86和第二區域88植入氧離子82期 93305 18
Claims (1)
- 第料141672號專利申請案 101年6月4日修正替換頁 十、申請專利範圍: 丨.一種半導體裝置,包括: 具有第一晶向之基材; 在該基材上之第一絕緣層· ,以及 、卜在第絕緣層上且包含第一石夕層和第二石夕層 ,複數個矽層’其中’該第-矽層包括具有第二晶向和 之矽而該第二矽層包括具有該第二晶向及大體與 h第一矽層之晶面垂直之晶面之矽, ’、 9 1 +八中該第一和第二矽層由絕緣區域所隔開。 .專利範圍第1項之半導體裝置,其中,該第一絕 緣層包括氧化矽。 3.=請專利範圍第Μ之半導體裝置,復包括位於該基 材上之第二發層。 A.=料利範圍第3項之半導體裝置,其中,該第三石夕 θ Μ由絕緣區域而與該第—和第二碎層隔開。 •二申範圍第4項之半導體裝置,復包括插置於該 第—夕層與該基材之間之第二絕緣層。 δ.::::利範圍第5項之半導體裝置,其中,該第二絕 7 復插置於該第二♦層與該第-絕緣層之間。 .緩:::利範圍第6項之半導體裝置,其中,該第二絕 緣層包括氧化矽。 s 8. 如申請專利範圍第&項之丰遙 形成於該第-、第二及第三石夕層之:二’SFET 9. 如申請專利範圍第4項之半導體裝置,曰其中,該基材和 93305(修正版) 21 1380442 第94141672號專利申請案 兮帑一_ r π L 101年6月4日修正替換頁 孩弟二妙層包括具有<1〇〇>晶向之石夕- 10·:申請專利範圍第9項之半導體裝置,其中,該第一和 第一石夕層包括具有<110〉晶向之矽。 U·:申請專利範圍第6項之半導體裝置,復包括形成於該 第一和第二石夕層之酬SFET以及形成 NMOSFET。 矛一 /層乏 請專利範圍第^之半導體裝置,其中,形成於 ^二石夕層之該·圓^向為大體垂直於形成於該 弟一石夕層之該PMOSFET。 13·—種形成半導體裝置之方法,包括下列步驟: 材,以及位在該第一絕緣層上之具有第 第一矽層 提供絕緣層上覆縣構,該絕緣層上覆㈣構包括 有第一絕緣層形成於其上之具有第—晶向之第一石夕其 晶向和晶面之 提供第二梦基材,該第二石夕基材具有該第二晶向和 晶面以及形成於該第二矽基材上之第二絕緣層,Α中, 該第二石夕基材包括藉由植人氫離子至該第二♦基 產生之缺陷線; 二石夕 晶面 經由該第二絕緣層和該第一矽層而接合該第 基材至該絕緣層上覆矽結構,以使該第二矽基材之 疋向為大體與該第一碎層之晶面垂直; 沿該缺陷線分裂及移除該第二矽基材而留下該第 二絕緣層及第二矽層於該絕緣層上覆矽結構上;χ 移除部分之該第二矽層、第二絕緣層、第一梦層及 93305(修正版) 22 1380442 壤 * . I---- 第94141672號專利申請案 101年6月4日修正替換頁 第一絕緣層以形成第一開口於該絕緣層上覆矽結構之 • 第一區域中而暴露部分之該第一矽基材;以及 於該絕緣層上覆矽結構之第二區域中移除部分之 该第二矽層和第二絕緣層以形成第二開口而暴露部分 之該第一梦層。 14. 如申請專利範圍第13項之形成半導體裝置之方法,復 包括形成側壁間隔件於該第一和第二開口之侧壁上。 15. 如申請專利範圍第U項之形成半導體裝置之方法,復 包括成長磊晶矽在該第一和第二開口中以提供絕緣層 上覆矽結構’其具有在該絕緣層上覆矽結構之該第一區 域中具有該第一晶向之第三矽層、在該絕緣層上覆矽結 構之該第二區域中具有該第二晶向與晶面之第一矽 層、以及在該絕緣層上覆矽結構之第三區域中具有該第 一晶向以及大體與該第一矽層之晶面垂直之晶面之該 第二矽層。 16·如申請專利範圍第15項之形成半導體裝置之方法,復 包括·形成複數個絕緣區域在該絕緣層上覆矽結構中以 使該第-區域與該第二和第三區域絕緣,以及使該第二 區域與該第三區域絕緣。 Π.如申請專㈣16項之形成半導體裝置之方法,其 中該开成該複數個絕緣區域之步驟包括移除該側壁間 隔件。 18.如申請專利範圍第16項之形成半導體裝置之方法,復 包括.形成埋設氧化物層於該絕緣層上覆矽結構之該第 93305(修正版) 23 1380442 秦lq」 使該第三@層與該基材絕緣。 tr專圍第18項之形成半導體裝置之方法,復 ^括^成該埋設氧化物層於該絕緣層上詩結構之該 弟—Εΐ域中β 2〇·如申請專利範圍第18項之形成半導體裝置之方法,復 包括形成MOSFET於該絕緣層上覆石夕結構之該第一、第 一及第三區域中。 21·如申請專利範圍第16項之形成半導體裝置之方法,其 中該第一石夕層具有<1〇〇>晶向而該第一和第二石夕層具 有〈110>晶向。 22.如申請專利範圍第21項之形成半導體裝置之方法,復 包括形成NMOSFET於該第三矽層以及形成PM〇SFET於該 第一和第二石夕層。 23·如申請專利範圍第丨5項之形成半導體裝置之方法,其 中’該沉積的矽層係藉由選擇性磊晶沉積而沉積。 93305(修正版) 24 14 14 1380442 ^ 鵪 外年//月2?日修正替換I12第2圖17<第3圖 (Amended) 齊
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US6815278B1 (en) * | 2003-08-25 | 2004-11-09 | International Business Machines Corporation | Ultra-thin silicon-on-insulator and strained-silicon-direct-on-insulator with hybrid crystal orientations |
JP4419147B2 (ja) * | 2003-09-08 | 2010-02-24 | 株式会社Sumco | 貼り合わせウェーハの製造方法 |
US20050116290A1 (en) * | 2003-12-02 | 2005-06-02 | De Souza Joel P. | Planar substrate with selected semiconductor crystal orientations formed by localized amorphization and recrystallization of stacked template layers |
JP5113999B2 (ja) * | 2004-09-28 | 2013-01-09 | シャープ株式会社 | 水素イオン注入剥離方法 |
US7102166B1 (en) * | 2005-04-21 | 2006-09-05 | International Business Machines Corporation | Hybrid orientation field effect transistors (FETs) |
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2005
- 2005-11-28 TW TW094141672A patent/TWI380442B/zh not_active IP Right Cessation
- 2005-11-29 CN CN200580040188A patent/CN100578751C/zh not_active Expired - Fee Related
- 2005-11-29 WO PCT/US2005/043398 patent/WO2006062796A2/en active Application Filing
- 2005-11-29 JP JP2007545518A patent/JP2008523620A/ja active Pending
- 2005-11-29 KR KR1020077013621A patent/KR101175342B1/ko not_active IP Right Cessation
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Also Published As
Publication number | Publication date |
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KR101175342B1 (ko) | 2012-08-21 |
US20060118918A1 (en) | 2006-06-08 |
CN101065840A (zh) | 2007-10-31 |
WO2006062796A2 (en) | 2006-06-15 |
GB2434034B (en) | 2010-02-17 |
CN100578751C (zh) | 2010-01-06 |
DE112005003123B4 (de) | 2011-11-10 |
TW200625635A (en) | 2006-07-16 |
KR20070086303A (ko) | 2007-08-27 |
DE112005003123T5 (de) | 2008-04-17 |
GB2434034A (en) | 2007-07-11 |
WO2006062796A3 (en) | 2006-08-03 |
GB0707665D0 (en) | 2007-05-30 |
JP2008523620A (ja) | 2008-07-03 |
US7422956B2 (en) | 2008-09-09 |
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