TWI378970B - Organic resin composition, solution of the same and shaped article of the same - Google Patents
Organic resin composition, solution of the same and shaped article of the same Download PDFInfo
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- TWI378970B TWI378970B TW94110532A TW94110532A TWI378970B TW I378970 B TWI378970 B TW I378970B TW 94110532 A TW94110532 A TW 94110532A TW 94110532 A TW94110532 A TW 94110532A TW I378970 B TWI378970 B TW I378970B
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- organic resin
- resin composition
- group
- patent application
- liquid crystal
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- 239000011342 resin composition Substances 0.000 title claims 8
- 229920000728 polyester Polymers 0.000 claims description 22
- 239000004973 liquid crystal related substance Substances 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 8
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 229910052909 inorganic silicate Inorganic materials 0.000 claims description 3
- 238000005266 casting Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims 2
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims 1
- KAUQJMHLAFIZDU-UHFFFAOYSA-N 6-Hydroxy-2-naphthoic acid Chemical compound C1=C(O)C=CC2=CC(C(=O)O)=CC=C21 KAUQJMHLAFIZDU-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 229920001169 thermoplastic Polymers 0.000 claims 1
- -1 phenol compound Chemical class 0.000 description 16
- 125000003118 aryl group Chemical group 0.000 description 14
- 229910052801 chlorine Inorganic materials 0.000 description 10
- 125000001309 chloro group Chemical group Cl* 0.000 description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 125000001153 fluoro group Chemical group F* 0.000 description 6
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 5
- 229910052740 iodine Inorganic materials 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 4
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- HFZWRUODUSTPEG-UHFFFAOYSA-N 2,4-dichlorophenol Chemical compound OC1=CC=C(Cl)C=C1Cl HFZWRUODUSTPEG-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- QFJZMVJDDBTJHB-UHFFFAOYSA-N (2,4,5-trichlorophenyl)hydrazine Chemical compound NNC1=CC(Cl)=C(Cl)C=C1Cl QFJZMVJDDBTJHB-UHFFFAOYSA-N 0.000 description 1
- LHJGJYXLEPZJPM-UHFFFAOYSA-N 2,4,5-trichlorophenol Chemical compound OC1=CC(Cl)=C(Cl)C=C1Cl LHJGJYXLEPZJPM-UHFFFAOYSA-N 0.000 description 1
- LINPIYWFGCPVIE-UHFFFAOYSA-N 2,4,6-trichlorophenol Chemical compound OC1=C(Cl)C=C(Cl)C=C1Cl LINPIYWFGCPVIE-UHFFFAOYSA-N 0.000 description 1
- ZIYRDJLAJYTELF-UHFFFAOYSA-N 2-bromo-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1Br ZIYRDJLAJYTELF-UHFFFAOYSA-N 0.000 description 1
- WDNBURPWRNALGP-UHFFFAOYSA-N 3,4-Dichlorophenol Chemical compound OC1=CC=C(Cl)C(Cl)=C1 WDNBURPWRNALGP-UHFFFAOYSA-N 0.000 description 1
- HVSZOPBXNGXRFF-UHFFFAOYSA-N 4-chloro-2-(1,1,2,2,2-pentafluoroethyl)phenol Chemical compound OC1=CC=C(Cl)C=C1C(F)(F)C(F)(F)F HVSZOPBXNGXRFF-UHFFFAOYSA-N 0.000 description 1
- LUYVFIYUQPJQOJ-UHFFFAOYSA-N 4-chloro-2-(trifluoromethyl)phenol Chemical compound OC1=CC=C(Cl)C=C1C(F)(F)F LUYVFIYUQPJQOJ-UHFFFAOYSA-N 0.000 description 1
- ZKMUKBBWORLNLA-UHFFFAOYSA-N 4-chloro-2-fluorophenol Chemical compound OC1=CC=C(Cl)C=C1F ZKMUKBBWORLNLA-UHFFFAOYSA-N 0.000 description 1
- JKPLMQJLGBBFLO-UHFFFAOYSA-N 4-chloro-2-iodophenol Chemical compound OC1=CC=C(Cl)C=C1I JKPLMQJLGBBFLO-UHFFFAOYSA-N 0.000 description 1
- XLHYAEBESNFTCA-UHFFFAOYSA-N 4-chloro-3-fluorophenol Chemical compound OC1=CC=C(Cl)C(F)=C1 XLHYAEBESNFTCA-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004974 Thermotropic liquid crystal Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001621 bismuth Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical group ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 125000001142 dicarboxylic acid group Chemical group 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/263—Frames with special provision for insulation
- E06B3/267—Frames with special provision for insulation with insulating elements formed in situ
- E06B3/2675—Frames with special provision for insulation with insulating elements formed in situ combined with prefabricated insulating elements
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/04—Wing frames not characterised by the manner of movement
- E06B3/263—Frames with special provision for insulation
- E06B3/2632—Frames with special provision for insulation with arrangements reducing the heat transmission, other than an interruption in a metal section
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B7/00—Special arrangements or measures in connection with doors or windows
- E06B7/12—Measures preventing the formation of condensed water
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/06—Substrate layer characterised by chemical composition
-
- E—FIXED CONSTRUCTIONS
- E05—LOCKS; KEYS; WINDOW OR DOOR FITTINGS; SAFES
- E05Y—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES E05D AND E05F, RELATING TO CONSTRUCTION ELEMENTS, ELECTRIC CONTROL, POWER SUPPLY, POWER SIGNAL OR TRANSMISSION, USER INTERFACES, MOUNTING OR COUPLING, DETAILS, ACCESSORIES, AUXILIARY OPERATIONS NOT OTHERWISE PROVIDED FOR, APPLICATION THEREOF
- E05Y2800/00—Details, accessories and auxiliary operations not otherwise provided for
- E05Y2800/40—Physical or chemical protection
- E05Y2800/428—Physical or chemical protection against water or ice
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
- E06B3/30—Coverings, e.g. protecting against weather, for decorative purposes
- E06B3/301—Coverings, e.g. protecting against weather, for decorative purposes consisting of prefabricated profiled members or glass
- E06B3/306—Covering plastic frames with metal or plastic profiled members
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Chemical & Material Sciences (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Description
(3) 1378970 特別者’從高耐熱性及對近代電子材料所需高頻率有 回應之觀點來看’最佳者爲使用液晶聚酯作爲樹脂（a) 。有關液晶聚酯’較佳者爲可溶於含有至少30重量。/。下 面式（I)所表鹵素取代苯酚化合物的溶劑內之聚酯，因 爲其具有小的各向異性且可以用較大量的無機矽酸鹽予以 塡充之故。
OH
(I) (A)i 其中A爲鹵素原子或鹵化院基，例如三氟甲基，且i 爲A的數目且爲1至5的整數’但其限制條件爲當丨爲2 至5'的整數時，取代基A可相同或不同。 溶解該液晶聚酯所用溶劑較佳者爲含有至少5〇重量 %，更佳者至少60重量％的鹵素取代苯酚化合物（丨）。 .9 最佳者’該溶劑爲純（1〇〇重量％ )鹵素取代苯酚化合物 (I)。 較佳者，式（I)中的i爲1' 2或3,更佳者爲1或 2。當i爲1時，A較佳者係在4-位置，且當丨爲至少2 時’至少一個取代基A較佳地存在於4_位置，經基取代 基位置係在1 -位置。 ’式（I)中A的鹵素原子爲氟原子、氯原子、溴原子 或碘原子。彼等之中，從樹脂在化合物（1)中的溶解度 觀點來看，氣原子和氯原子爲較佳者，且更丨圭者爲氯^原子 1378970
，因爲a爲氯原子的化合物（η在其價格與樹脂溶解度 上具有良好協調之故^ 式（I)中Α爲氯原子的化合物之特定例子包括4-氯 苯酚，2,4-二氯苯酚，3,4-二氯苯酚，2,4,5-三氯苯酚， 2，4,6-三氯苯酚，五氯苯酚，等。式（I)中諸A中之一者 爲氟原子的化合物之特定例子包括4-氯-2-氟苯酚，4-氯· 3 -氟苯酚，等。式（I)中諸A中之一者爲溴原子的化合 -φ 物之特定例子包括4-氯-2-溴苯酚，等。式（I)中諸Α中 . 之一者爲碘原子的化合物之特定例子包括4-氯-2-碘苯酚 ，等。 式（I)中諸A中之一者爲鹵化烷基的化合物之特定 例子包括4-氯-2-三氟甲基苯酚，4-氯-2-五氟乙基苯酚， 等。 更佳者，式（I)中的A爲氯原子。所以，式（I)化 合物的較佳例子包括4-氯苯酚，2,4-二氯苯酚，3,4-二氯 ,φ 苯酚，2,4,5-三氯苯酹，2，4,6-三氯苯酚和五氯苯酚。特別 者，4-氯苯酚爲較佳。 除了式（I)苯酚化合物之外，該溶劑可包含其他成 分，只要該其他成分不在溶液的貯存中沈澱液晶聚酯即可 。較佳者，該其他成分爲氯烴類例如鄰-二氯苯，氯仿， 二氯甲烷，四氯乙烷，等，係由於其不會干擾液晶聚酯的 溶解度之故。 用於本發明中的液晶聚酯可爲向熱性液晶聚酯且可形 成在450 °C或更低溫度下展現光學各向異性的熔融體。 -8 - ⑧ (5) (5)
1378970 液晶聚酯的例子包括下列聚酯： (1) 包括衍生自羥基羧酸的重複單位，衍 二羧酸的重複單位和衍生自芳族二醇的重複單位 (2) 包括衍生自二或更多種不同芳族羥基 複單位之聚酯； (3)包括衍生自芳族二羧酸的重複單位和 族二醇的重複單位之聚酯； (4 )經由用芳族羥基羧酸與結晶型聚酯例 芳族羥基羧酸，芳族二羧酸或芳族二醇可用 衍生物形式來使用。芳族羥基羧酸或芳族二羧酸 性衍生物可爲高反應性衍生物例如氯化物或酸酐 基羧酸或芳族二羧酸與醇或乙二醇的酯類，其可 化形成聚酯。芳族二醇的酯形成性衍生物可爲芳 其苯酚羥基與一羧酸形成一酯，而可經由轉酯形 芳族羥基羧酸，芳族二羧酸及/或芳族二醇 少一個取代基只要不使酯形成性質劣化即可。取 子包括鹵素原子（如氯原子、氟原子，等），烷 基、乙基，等），芳基（如苯基，等）。 液晶聚酯所含重複單位之非限制性例如包括 單位： 衍生自芳族羥基羧酸的重複單位： 生自芳族 之聚酯； 羧酸的重 衍生自芳 如聚對苯 酯形成性 的酯形成 ，芳族羥 經由轉酯 族二醇， 成聚酯。 可含有至 代基的例 基（如甲 下列重複 1378970
ο (A,) 〆·
(Α2)
上述諸重複單位可含鹵素原子（如，氯原子，氟原子 ，溴原子，碘原子，等）或烷基等取代基。 衍生自芳族二羧酸的重複單位 -10- ⑧ (7)1378970
•o(ch2>2o.
上述諸重複單位可含鹵素原子（如：氯原子，氟原子 ，溴原子，碘原子，等），烷基或芳基等取代基。 衍生自芳族二醇的重複單位 ⑧ -11 1378970
上述諸重複單位可含鹵素原子（如，氯原子，氟原子 ，溴原子，碘原子，等），烷基或芳基等取代基。 -12- ⑧ (18) 1378970 實施例2 將實施例1中所製組成物溶液澆鑄在一玻璃板上且在 120°C熱空氣乾燥器內加熱以移除溶劑，然後在250°C下 加熱而得液晶聚醋膜。用TMA ( TA Instrument所製熱機 械分析儀）測量所得膜的熱膨脹係數。該熱膨脹係數爲 3 Ο X 1 0 6 / 〇C。 .φ 比較例1 . 將合成實施例2中所製液晶聚酯溶液（100克）與合 成實施例3中用爲原料的市售無機矽酸鹽（微晶高嶺石， 含有以ICP光譜術測得總量爲3 5,000ppm的鈉，鉀，鈣和 鎂）（1克）混合且在1 30°C回流4小時而得含該液晶聚 酯和無機矽酸鹽的組成物之溶液。 比較例2
將比較例1所製組成物溶液在一玻璃板上澆鑄，於 1 2 0 °C下加熱1小時使澆鑄溶液半乾，然後在2 5 0 °C下加 熱而得液晶聚酯膜。用TMA測量所得膜之熱膨脹係數。 該熱膨脹係數爲40xl0_6/ °C。 -22- ⑧
Claims (1)
- Γ378970 第〇94110532號專利申請案中文申請專利範圍修正本 民國101年9月12日修正 十、申請專利範圍 1·—種有機樹脂組成物，包括（a)有機樹脂，和（b )含有總量爲l，000ppm或更少的鹼金屬和鹼土金屬之無 機矽酸鹽，其中該有機樹脂爲液晶聚酯，該液晶聚酯包含 30至80莫耳％衍生自至少一種選自對—羥基苯甲酸和2_羥 基-6-萘甲酸所構成的群組中之化合物的重複單位，1〇至 35莫耳％衍生自至少一種選自氫醌和4,4，-二羥基聯苯所 構成的群組中的化合物之重複單位，及1 〇至3 5莫耳％衍 生自至少一種選自對苯二甲酸和異苯二甲酸所構成的群組 中的化合物之重複單位。 2.如申請專利範圍第1項之有機樹脂組成物，其中該 有機樹脂（a)包括一液晶熱塑性聚合物，其熔融體展現 出光學各向異性。 3 ·如申請專利範圍第1項之有機樹脂組成物，其中該 有機樹脂（a)包括一液晶聚酯，其可溶於包含至少30重 量％的式（I )所表之經鹵素取代之苯酚化合物之溶劑中： OH(I) (A)i 其中A爲鹵素原子和鹵化烷基，且i爲A的數目且 爲1至5之整數，但其限制條件爲當i爲2至5的整數時 1378970 ，取代基A可相同或相異。 4. 一種樹脂組成物之溶液，其包括如申請專利範圍第 1項之有機樹脂組成物，及溶劑。 5. —種包括如申請專利範圍第1項之有機樹脂組成物 之成型物件。 6. 如申請專利範圍第5項之成型物件，其爲一薄膜。 7. —種薄膜，其係藉由將如申請專利範圍第4項之樹 脂組成物之溶液澆鑄在一基板上且蒸發掉該溶劑而得到的 -2- S
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| EP2360754B1 (en) * | 2010-01-26 | 2013-11-13 | Samsung SDI Co., Ltd. | Battery assembly |
| EP2407505A1 (de) * | 2010-07-12 | 2012-01-18 | Bayer MaterialScience AG | Polymermaterial mit organisch modifizierten Schichtsilikaten |
| US20130171391A1 (en) * | 2010-09-29 | 2013-07-04 | E I Du Pont De Nemours And Company | Polyimide resins for high temperature applications |
| CN105907058B (zh) * | 2016-04-13 | 2018-06-15 | 珠海万通特种工程塑料有限公司 | 一种液晶聚酯组合物 |
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| Publication number | Publication date |
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| KR101146958B1 (ko) | 2012-05-22 |
| US8071221B2 (en) | 2011-12-06 |
| US20050227102A1 (en) | 2005-10-13 |
| KR20050097781A (ko) | 2005-10-10 |
| CN1680486B (zh) | 2013-03-27 |
| CN1680486A (zh) | 2005-10-12 |
| TW200604286A (en) | 2006-02-01 |
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