TWI375344B - Electrolyte composition - Google Patents
Electrolyte composition Download PDFInfo
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- TWI375344B TWI375344B TW095131911A TW95131911A TWI375344B TW I375344 B TWI375344 B TW I375344B TW 095131911 A TW095131911 A TW 095131911A TW 95131911 A TW95131911 A TW 95131911A TW I375344 B TWI375344 B TW I375344B
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- 239000000203 mixture Substances 0.000 title claims description 156
- 239000003792 electrolyte Substances 0.000 title claims description 119
- 150000001875 compounds Chemical group 0.000 claims description 69
- 239000002904 solvent Substances 0.000 claims description 60
- -1 octa-methylene group Chemical group 0.000 claims description 50
- 229910052744 lithium Inorganic materials 0.000 claims description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 32
- 150000003839 salts Chemical class 0.000 claims description 29
- 229910052799 carbon Inorganic materials 0.000 claims description 28
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 26
- 150000001450 anions Chemical class 0.000 claims description 26
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 24
- 125000005842 heteroatom Chemical group 0.000 claims description 24
- 229910052731 fluorine Inorganic materials 0.000 claims description 23
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 19
- 239000011737 fluorine Substances 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 125000004122 cyclic group Chemical group 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 10
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000001153 fluoro group Chemical group F* 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 239000000052 vinegar Substances 0.000 claims description 6
- 235000021419 vinegar Nutrition 0.000 claims description 6
- 150000002891 organic anions Chemical class 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 125000005704 oxymethylene group Chemical group [H]C([H])([*:2])O[*:1] 0.000 claims description 5
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 4
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 125000006342 heptafluoro i-propyl group Chemical group FC(F)(F)C(F)(*)C(F)(F)F 0.000 claims description 3
- 229910001412 inorganic anion Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 3
- 150000001449 anionic compounds Chemical class 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 230000002829 reductive effect Effects 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- WRVYTFPNFWWAPE-UHFFFAOYSA-N 1,1,2,2-tetrachlorohydrazine Chemical compound ClN(Cl)N(Cl)Cl WRVYTFPNFWWAPE-UHFFFAOYSA-N 0.000 claims 1
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 claims 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 229920001774 Perfluoroether Polymers 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims 1
- 230000037431 insertion Effects 0.000 claims 1
- 238000003780 insertion Methods 0.000 claims 1
- 125000002099 lactulose group Chemical group 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 75
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 57
- 230000000052 comparative effect Effects 0.000 description 52
- 239000000047 product Substances 0.000 description 45
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 36
- 238000006243 chemical reaction Methods 0.000 description 28
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 26
- 238000007600 charging Methods 0.000 description 23
- 238000012360 testing method Methods 0.000 description 23
- 238000002360 preparation method Methods 0.000 description 21
- 239000011541 reaction mixture Substances 0.000 description 20
- 239000011877 solvent mixture Substances 0.000 description 20
- 210000004027 cell Anatomy 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 18
- 229910000027 potassium carbonate Inorganic materials 0.000 description 18
- 235000011181 potassium carbonates Nutrition 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- 239000011521 glass Substances 0.000 description 15
- 150000003254 radicals Chemical class 0.000 description 15
- 238000002390 rotary evaporation Methods 0.000 description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 14
- 239000003999 initiator Substances 0.000 description 14
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 13
- 229910001416 lithium ion Inorganic materials 0.000 description 13
- 239000007858 starting material Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000007259 addition reaction Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 12
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 11
- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 150000001336 alkenes Chemical class 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 10
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 9
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
- 150000001298 alcohols Chemical class 0.000 description 9
- 238000009835 boiling Methods 0.000 description 9
- 239000000543 intermediate Substances 0.000 description 9
- 239000000956 alloy Substances 0.000 description 8
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 229910045601 alloy Inorganic materials 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 238000010280 constant potential charging Methods 0.000 description 7
- 238000004090 dissolution Methods 0.000 description 7
- 239000007772 electrode material Substances 0.000 description 7
- 239000010439 graphite Substances 0.000 description 7
- 229910002804 graphite Inorganic materials 0.000 description 7
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 238000005481 NMR spectroscopy Methods 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 150000001721 carbon Chemical group 0.000 description 6
- 239000004020 conductor Substances 0.000 description 6
- 238000000151 deposition Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 6
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 6
- AQYSYJUIMQTRMV-UHFFFAOYSA-N hypofluorous acid Chemical compound FO AQYSYJUIMQTRMV-UHFFFAOYSA-N 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 238000007342 radical addition reaction Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910001290 LiPF6 Inorganic materials 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 4
- 239000012254 powdered material Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000012264 purified product Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 238000001075 voltammogram Methods 0.000 description 4
- 229910001316 Ag alloy Inorganic materials 0.000 description 3
- 241000208340 Araliaceae Species 0.000 description 3
- 229910000733 Li alloy Inorganic materials 0.000 description 3
- 229910032387 LiCoO2 Inorganic materials 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 239000002033 PVDF binder Substances 0.000 description 3
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 3
- 235000003140 Panax quinquefolius Nutrition 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- LXABNYCXGUIOSN-UHFFFAOYSA-N decyl ethyl carbonate Chemical compound CCCCCCCCCCOC(=O)OCC LXABNYCXGUIOSN-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 235000008434 ginseng Nutrition 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000001989 lithium alloy Substances 0.000 description 3
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 3
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 3
- 239000011325 microbead Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 2
- RJBJXVAPYONTFE-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(C(F)(F)F)OC(F)(F)C(F)(F)C(F)(F)F RJBJXVAPYONTFE-UHFFFAOYSA-N 0.000 description 2
- YIHRGKXNJGKSOT-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluorobutan-1-ol Chemical compound CC(F)(F)C(F)(F)C(O)(F)F YIHRGKXNJGKSOT-UHFFFAOYSA-N 0.000 description 2
- PBVZTJDHQVIHFR-UHFFFAOYSA-N 1,1,2,3,3,3-hexafluoroprop-1-ene Chemical compound FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F PBVZTJDHQVIHFR-UHFFFAOYSA-N 0.000 description 2
- BZPCMSSQHRAJCC-UHFFFAOYSA-N 1,2,3,3,4,4,5,5,5-nonafluoro-1-(1,2,3,3,4,4,5,5,5-nonafluoropent-1-enoxy)pent-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)C(F)(F)F BZPCMSSQHRAJCC-UHFFFAOYSA-N 0.000 description 2
- YBMDPYAEZDJWNY-UHFFFAOYSA-N 1,2,3,3,4,4,5,5-octafluorocyclopentene Chemical compound FC1=C(F)C(F)(F)C(F)(F)C1(F)F YBMDPYAEZDJWNY-UHFFFAOYSA-N 0.000 description 2
- QVHWOZCZUNPZPW-UHFFFAOYSA-N 1,2,3,3,4,4-hexafluorocyclobutene Chemical compound FC1=C(F)C(F)(F)C1(F)F QVHWOZCZUNPZPW-UHFFFAOYSA-N 0.000 description 2
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- QLSSITLVZFHSJT-UHFFFAOYSA-N 1-(3-chlorophenyl)-n-methylpropan-2-amine Chemical compound CNC(C)CC1=CC=CC(Cl)=C1 QLSSITLVZFHSJT-UHFFFAOYSA-N 0.000 description 2
- LVFXLZRISXUAIL-UHFFFAOYSA-N 2,2,3,4,4,4-hexafluorobutan-1-ol Chemical compound OCC(F)(F)C(F)C(F)(F)F LVFXLZRISXUAIL-UHFFFAOYSA-N 0.000 description 2
- ZRPAUEVGEGEPFQ-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2 ZRPAUEVGEGEPFQ-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 101150113197 CMAH gene Proteins 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 229910052493 LiFePO4 Inorganic materials 0.000 description 2
- 229910014549 LiMn204 Inorganic materials 0.000 description 2
- 229910000668 LiMnPO4 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229930182558 Sterol Natural products 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229940125782 compound 2 Drugs 0.000 description 2
- 238000010277 constant-current charging Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- WSLQHGMJTGELSF-UHFFFAOYSA-L dipotassium;difluoride Chemical compound [F-].[F-].[K+].[K+] WSLQHGMJTGELSF-UHFFFAOYSA-L 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N ethylene glycol dimethyl ether Natural products COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
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- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Secondary Cells (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71529105P | 2005-09-08 | 2005-09-08 | |
| US11/381,862 US7790312B2 (en) | 2005-09-08 | 2006-05-05 | Electrolyte composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200722412A TW200722412A (en) | 2007-06-16 |
| TWI375344B true TWI375344B (en) | 2012-10-21 |
Family
ID=37667209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW095131911A TWI375344B (en) | 2005-09-08 | 2006-08-30 | Electrolyte composition |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7790312B2 (enExample) |
| EP (1) | EP1938418A2 (enExample) |
| JP (1) | JP2009508304A (enExample) |
| KR (1) | KR101347015B1 (enExample) |
| CN (1) | CN101258637B (enExample) |
| TW (1) | TWI375344B (enExample) |
| WO (1) | WO2007030297A2 (enExample) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006216361A (ja) * | 2005-02-03 | 2006-08-17 | Three M Innovative Properties Co | リチウム電池用電解液 |
| US7691282B2 (en) * | 2005-09-08 | 2010-04-06 | 3M Innovative Properties Company | Hydrofluoroether compounds and processes for their preparation and use |
| US7790312B2 (en) | 2005-09-08 | 2010-09-07 | 3M Innovative Properties Company | Electrolyte composition |
| TWI270994B (en) * | 2005-12-29 | 2007-01-11 | Ind Tech Res Inst | High rate capability design of lithium ion secondary battery |
| KR20090029835A (ko) * | 2006-07-13 | 2009-03-23 | 다이킨 고교 가부시키가이샤 | 전기 화학 디바이스 |
| JP5229527B2 (ja) * | 2006-08-25 | 2013-07-03 | ソニー株式会社 | 二次電池用電解液および二次電池 |
| RU2010148390A (ru) * | 2008-04-28 | 2012-06-10 | Асахи Гласс Компани, Лимитед (Jp) | Неводный электролит для вторичного элемента и вторичный элемент |
| JP5253905B2 (ja) * | 2008-06-30 | 2013-07-31 | パナソニック株式会社 | 非水電解液および非水電解液二次電池 |
| US20100028784A1 (en) * | 2008-07-29 | 2010-02-04 | 3M Innovative Properties Company | Electrolyte composition, lithium-containing electrochemical cell, battery pack, and device including the same |
| US20110195317A1 (en) * | 2008-07-30 | 2011-08-11 | Daikin Industries, Ltd. | Solvent for dissolving electrolyte salt of lithium secondary cell |
| US7988877B2 (en) | 2008-11-03 | 2011-08-02 | 3M Innovative Properties Company | Methods of making fluorinated ethers, fluorinated ethers, and uses thereof |
| JP2010123287A (ja) * | 2008-11-17 | 2010-06-03 | Panasonic Corp | 非水電解液および非水電解液二次電池 |
| JP2010226100A (ja) * | 2009-02-25 | 2010-10-07 | Daikin Ind Ltd | 電気二重層キャパシタ |
| EP2413418A4 (en) * | 2009-03-27 | 2013-08-14 | Asahi Glass Co Ltd | ELECTROLYTE SOLUTION FOR ELECTRICAL ENERGY STORAGE DEVICES AND DEVICES FOR STORING ELECTRICAL ENERGY |
| US20100263885A1 (en) * | 2009-04-21 | 2010-10-21 | 3M Innovative Properties Company | Protection systems and methods for electronic devices |
| CN102414873B (zh) * | 2009-07-30 | 2014-10-01 | 株式会社东芝 | 非水电解液二次电池 |
| US8323524B2 (en) * | 2009-10-01 | 2012-12-04 | 3M Innovative Properties Company | Apparatus including hydrofluoroether with high temperature stability and uses thereof |
| JPWO2011052605A1 (ja) * | 2009-10-27 | 2013-03-21 | 旭硝子株式会社 | 二次電池用非水電解液および二次電池 |
| WO2012029625A1 (ja) * | 2010-09-02 | 2012-03-08 | 日本電気株式会社 | 二次電池 |
| US8906549B1 (en) | 2010-09-24 | 2014-12-09 | Greatbatch Ltd. | Development of mixed binder system for primary cell cathodes |
| US8703329B2 (en) | 2011-03-25 | 2014-04-22 | Enerdel, Inc. | Redox shuttle for high voltage lithium battery |
| PL2693558T3 (pl) * | 2011-03-31 | 2021-10-18 | Daikin Industries, Ltd. | Litowo-jonowa bateria akumulatorowa i niewodny elektrolit do litowo-jonowej baterii akumulatorowej |
| WO2012147778A1 (ja) * | 2011-04-26 | 2012-11-01 | 株式会社日立製作所 | リチウムアルミ電池 |
| WO2013114946A1 (ja) * | 2012-02-03 | 2013-08-08 | 日本電気株式会社 | リチウム二次電池 |
| CN104737354A (zh) * | 2012-06-19 | 2015-06-24 | A123系统有限责任公司 | 用于电化学电池的具有氟化溶剂的电解质 |
| US9748604B2 (en) | 2012-10-19 | 2017-08-29 | The University Of North Carolina At Chapel Hill | Ion conducting polymers and polymer blends for alkali metal ion batteries |
| US9040203B2 (en) * | 2013-01-16 | 2015-05-26 | Samsung Sdi Co., Ltd. | Lithium battery |
| KR20150139827A (ko) | 2013-04-01 | 2015-12-14 | 더 유니버시티 오브 노쓰 캐롤라이나 엣 채플 힐 | 알칼리 금속 이온 배터리를 위한 이온 전도성 플루오로중합체 카르보네이트 |
| WO2015046174A1 (ja) * | 2013-09-24 | 2015-04-02 | 旭硝子株式会社 | 非水電解液二次電池 |
| WO2015046172A1 (ja) * | 2013-09-24 | 2015-04-02 | 旭硝子株式会社 | 非水電解液二次電池 |
| JP6131868B2 (ja) * | 2014-01-29 | 2017-05-24 | ソニー株式会社 | リチウム二次電池用非水電解液、リチウム二次電池、電池パック、電動車両、電力貯蔵システム、電動工具および電子機器 |
| EP2950380B1 (en) * | 2014-05-27 | 2017-04-12 | Samsung Electronics Co., Ltd | Electrolyte for lithium air battery and lithium air battery including the same |
| WO2015195595A1 (en) | 2014-06-17 | 2015-12-23 | Medtronic, Inc. | Semi-solid electrolytes for batteries |
| CN106663846A (zh) * | 2014-07-14 | 2017-05-10 | 科慕埃弗西有限公司 | 用于减缓锂离子电池燃烧的组合物 |
| EP3197945B1 (en) | 2014-09-23 | 2020-10-21 | 3M Innovative Properties Company | Nitrogen containing hydrofluoroethers and methods of using same |
| US9614229B2 (en) | 2014-09-30 | 2017-04-04 | Maxpower, Inc. | Functionalized short chain fluorinated polyether based electrolytes for safe lithium batteries and the cells having the same |
| US10333173B2 (en) | 2014-11-14 | 2019-06-25 | Medtronic, Inc. | Composite separator and electrolyte for solid state batteries |
| US10227288B2 (en) | 2015-02-03 | 2019-03-12 | Blue Current, Inc. | Functionalized fluoropolymers and electrolyte compositions |
| JP6680293B2 (ja) * | 2015-03-25 | 2020-04-15 | 日本電気株式会社 | ハイドロフルオロエーテル化合物、非水電解液およびリチウムイオン二次電池 |
| US10707526B2 (en) | 2015-03-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| US20190036167A1 (en) * | 2015-08-31 | 2019-01-31 | Lintec Corporation | Electrolyte composition, secondary battery, and method for using secondary battery |
| CN105186032A (zh) * | 2015-10-19 | 2015-12-23 | 东莞市凯欣电池材料有限公司 | 一种高电压锂离子电池电解液及使用该电解液的锂离子电池 |
| CN108713018B (zh) * | 2016-03-11 | 2022-07-05 | 3M创新有限公司 | 含胺环状氢氟醚及其使用方法 |
| US10587005B2 (en) | 2016-03-30 | 2020-03-10 | Wildcat Discovery Technologies, Inc. | Solid electrolyte compositions |
| KR101945434B1 (ko) * | 2016-04-25 | 2019-02-08 | 한국에너지기술연구원 | 리간드-금속산화물층을 포함하는 자기구동 전기변색소자 |
| US9997815B2 (en) | 2016-08-05 | 2018-06-12 | Toyota Motor Engineering & Manufacturing North America, Inc. | Non-aqueous magnesium-air battery |
| US10347943B2 (en) | 2016-09-14 | 2019-07-09 | Uchicago Argonne, Llc | Fluoro-substituted ethers and compositions |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| JP6674885B2 (ja) * | 2016-12-06 | 2020-04-01 | 株式会社日立製作所 | 二次電池、及び二次電池の製造方法 |
| CN109148959B (zh) * | 2017-06-28 | 2023-07-25 | 松下知识产权经营株式会社 | 锂二次电池 |
| US11233272B2 (en) * | 2018-10-30 | 2022-01-25 | Nio Usa, Inc. | Zero flammability electrolyte for lithium-ion cell |
| CN109713367B (zh) * | 2018-12-28 | 2022-02-22 | 安普瑞斯（南京）有限公司 | 一种含硅的高能量密度锂离子电池 |
| US10868333B2 (en) | 2019-01-23 | 2020-12-15 | Uchicago Argonne, Llc | Electrolytes for lithium batteries |
| CN112210034B (zh) * | 2020-09-30 | 2022-06-24 | 氟金(上海)新材料有限公司 | 面向锂电池应用的聚合电解质材料及其制备方法 |
| EP4260397A1 (en) | 2020-12-11 | 2023-10-18 | Mexichem Fluor S.A. de C.V. | Composition |
| PL4264709T3 (pl) | 2020-12-16 | 2025-08-04 | Syensqo Sa | Kompozycja elektrolitu do baterii z metalicznym litem |
| KR20230154905A (ko) * | 2021-03-05 | 2023-11-09 | 에이지씨 가부시키가이샤 | 함불소 화합물의 제조 방법 및 함불소 화합물 |
| JP7698980B2 (ja) | 2021-05-26 | 2025-06-26 | Tdk株式会社 | リチウムイオン二次電池 |
| JP7724637B2 (ja) | 2021-05-26 | 2025-08-18 | Tdk株式会社 | リチウムイオン二次電池 |
| JP7698471B2 (ja) | 2021-05-26 | 2025-06-25 | Tdk株式会社 | リチウムイオン二次電池 |
| JP2024540743A (ja) | 2021-11-04 | 2024-11-01 | サイエンスコ エスアー | （パー）フルオロエラストマーを含む保護層を有する二次電池 |
| US12651775B2 (en) | 2022-04-11 | 2026-06-09 | Uchicago Argonne, Llc | Electrolytes for lithium batteries |
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| US3351495A (en) * | 1966-11-22 | 1967-11-07 | Grace W R & Co | Battery separator |
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| US3962328A (en) * | 1974-05-01 | 1976-06-08 | Kao Soap Co., Ltd. | Adamantyl thioamides |
| US4539256A (en) * | 1982-09-09 | 1985-09-03 | Minnesota Mining And Manufacturing Co. | Microporous sheet material, method of making and articles made therewith |
| GB8301506D0 (en) | 1983-01-20 | 1983-02-23 | Electricity Council | Fluorinated ethers |
| US4650730A (en) * | 1985-05-16 | 1987-03-17 | W. R. Grace & Co. | Battery separator |
| GB9023370D0 (en) | 1990-10-26 | 1990-12-05 | Rhone Poulenc Chemicals | Synthesis of fluorinated substituted ethanes |
| US5539008A (en) * | 1993-12-29 | 1996-07-23 | Minnesota Mining And Manufacturing Company | Foamable composition containing unsaturated perfluorochemical blowing agent |
| JP3304187B2 (ja) | 1994-03-14 | 2002-07-22 | 日本電信電話株式会社 | リチウム２次電池用電解液 |
| US5565281A (en) * | 1994-12-02 | 1996-10-15 | Hoechst Celanese Corporation | Shutdown, bilayer battery separator |
| JP3218982B2 (ja) * | 1995-07-25 | 2001-10-15 | 住友化学工業株式会社 | 非水電解液とリチウム二次電池 |
| DE19619233A1 (de) | 1996-05-13 | 1997-11-20 | Hoechst Ag | Fluorhaltige Lösungsmittel für Lithiumbatterien mit erhöhter Sicherheit |
| US6203944B1 (en) * | 1998-03-26 | 2001-03-20 | 3M Innovative Properties Company | Electrode for a lithium battery |
| US6080448A (en) * | 1998-04-03 | 2000-06-27 | Preservation Technologies Lp | Deacidification of cellulose based materials using hydrofluoroether carriers |
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| JP4780833B2 (ja) | 1998-09-11 | 2011-09-28 | 三井化学株式会社 | 非水電解液および非水電解液二次電池 |
| EP1141047B1 (en) * | 1998-11-30 | 2009-03-11 | E.I. Du Pont De Nemours And Company | Fluoromonomer polymerization |
| US6699336B2 (en) * | 2000-01-13 | 2004-03-02 | 3M Innovative Properties Company | Amorphous electrode compositions |
| US20030211390A1 (en) * | 2000-12-22 | 2003-11-13 | Dahn Jeffrey R. | Grain boundary materials as electrodes for lithium ion cells |
| JP3482488B2 (ja) | 2000-12-28 | 2003-12-22 | 独立行政法人産業技術総合研究所 | 含フッ素エーテル化合物の製造方法 |
| US6534220B2 (en) * | 2000-12-29 | 2003-03-18 | 3M Innovative Properties Company | High-boiling electrolyte solvent |
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| US6680145B2 (en) * | 2001-08-07 | 2004-01-20 | 3M Innovative Properties Company | Lithium-ion batteries |
| US6759374B2 (en) * | 2001-09-19 | 2004-07-06 | 3M Innovative Properties Company | Composition comprising lubricious additive for cutting or abrasive working and a method therefor |
| JP4269137B2 (ja) * | 2002-07-19 | 2009-05-27 | ダイキン工業株式会社 | 電極表面被膜形成剤。 |
| US7229718B2 (en) * | 2002-08-22 | 2007-06-12 | Samsung Sdi Co., Ltd. | Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same |
| US20040117918A1 (en) * | 2002-12-11 | 2004-06-24 | The Procter & Gamble Company | Fluorine-containing solvents and compositions and methods employing same |
| JP2004345967A (ja) | 2003-05-20 | 2004-12-09 | Daikin Ind Ltd | 含フッ素エーテル化合物の製造方法 |
| JP4431941B2 (ja) | 2003-06-06 | 2010-03-17 | 株式会社ジーエス・ユアサコーポレーション | 非水電解質二次電池 |
| US7498100B2 (en) * | 2003-08-08 | 2009-03-03 | 3M Innovative Properties Company | Multi-phase, silicon-containing electrode for a lithium-ion battery |
| US7128133B2 (en) * | 2003-12-16 | 2006-10-31 | 3M Innovative Properties Company | Hydrofluoroether as a heat-transfer fluid |
| JP4660104B2 (ja) | 2004-03-23 | 2011-03-30 | スリーエム イノベイティブ プロパティズ カンパニー | 非水性混合溶媒及びそれを含む非水性電解液 |
| US20060046144A1 (en) * | 2004-09-01 | 2006-03-02 | 3M Innovative Properties Company | Anode composition for lithium ion battery |
| JP2006216361A (ja) | 2005-02-03 | 2006-08-17 | Three M Innovative Properties Co | リチウム電池用電解液 |
| US7790312B2 (en) | 2005-09-08 | 2010-09-07 | 3M Innovative Properties Company | Electrolyte composition |
-
2006
- 2006-05-05 US US11/381,862 patent/US7790312B2/en not_active Expired - Fee Related
- 2006-08-21 JP JP2008530068A patent/JP2009508304A/ja active Pending
- 2006-08-21 KR KR1020087005605A patent/KR101347015B1/ko not_active Expired - Fee Related
- 2006-08-21 WO PCT/US2006/032439 patent/WO2007030297A2/en not_active Ceased
- 2006-08-21 CN CN2006800328819A patent/CN101258637B/zh not_active Expired - Fee Related
- 2006-08-21 EP EP06801908A patent/EP1938418A2/en not_active Withdrawn
- 2006-08-30 TW TW095131911A patent/TWI375344B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR101347015B1 (ko) | 2014-01-02 |
| TW200722412A (en) | 2007-06-16 |
| JP2009508304A (ja) | 2009-02-26 |
| US7790312B2 (en) | 2010-09-07 |
| KR20080042119A (ko) | 2008-05-14 |
| EP1938418A2 (en) | 2008-07-02 |
| CN101258637B (zh) | 2011-08-24 |
| WO2007030297A3 (en) | 2007-05-10 |
| US20070054186A1 (en) | 2007-03-08 |
| CN101258637A (zh) | 2008-09-03 |
| WO2007030297A2 (en) | 2007-03-15 |
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