TWI322035B - A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers - Google Patents
A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers Download PDFInfo
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- TWI322035B TWI322035B TW095117094A TW95117094A TWI322035B TW I322035 B TWI322035 B TW I322035B TW 095117094 A TW095117094 A TW 095117094A TW 95117094 A TW95117094 A TW 95117094A TW I322035 B TWI322035 B TW I322035B
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- 239000000178 monomer Substances 0.000 title claims description 105
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- 239000000203 mixture Substances 0.000 title claims description 27
- 230000003197 catalytic effect Effects 0.000 title claims description 21
- 238000002360 preparation method Methods 0.000 title description 13
- 229910052751 metal Inorganic materials 0.000 claims description 238
- 239000002184 metal Substances 0.000 claims description 238
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- 239000002243 precursor Substances 0.000 claims description 56
- -1 anionic hydrocarbon Chemical class 0.000 claims description 52
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- 150000004696 coordination complex Chemical class 0.000 claims description 43
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- 238000000034 method Methods 0.000 claims description 39
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Classifications
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
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US7968487B2 (en) * | 2003-02-28 | 2011-06-28 | The Regents Of The University Of California | Single component, phosphine-free, initiators for ethylene homopolymerization and copolymerization with functionalized co-monomers |
JP5016512B2 (ja) | 2007-02-28 | 2012-09-05 | ローム アンド ハース カンパニー | 実質的に線状のコポリマーおよびその製造方法 |
JP5292059B2 (ja) * | 2007-10-30 | 2013-09-18 | 日本ポリプロ株式会社 | α−オレフィン・(メタ)アクリル酸エステル共重合体の製造方法ならびにα−オレフィン・(メタ)アクリル酸エステル共重合体 |
US8080681B2 (en) * | 2007-12-28 | 2011-12-20 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US7863210B2 (en) | 2007-12-28 | 2011-01-04 | Chevron Phillips Chemical Company Lp | Nano-linked metallocene catalyst compositions and their polymer products |
US8012900B2 (en) * | 2007-12-28 | 2011-09-06 | Chevron Phillips Chemical Company, L.P. | Nano-linked metallocene catalyst compositions and their polymer products |
US8236907B2 (en) * | 2008-10-14 | 2012-08-07 | Northwestern University | Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods |
FR2937643B1 (fr) * | 2008-10-27 | 2011-10-14 | Arkema France | Nouveaux copolymeres a blocs d'olefines polaires et apolaires |
US10190030B2 (en) | 2009-04-24 | 2019-01-29 | Alger Alternative Energy, Llc | Treated geothermal brine compositions with reduced concentrations of silica, iron and lithium |
US9034294B1 (en) | 2009-04-24 | 2015-05-19 | Simbol, Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
US8637428B1 (en) | 2009-12-18 | 2014-01-28 | Simbol Inc. | Lithium extraction composition and method of preparation thereof |
US8741256B1 (en) | 2009-04-24 | 2014-06-03 | Simbol Inc. | Preparation of lithium carbonate from lithium chloride containing brines |
US7919639B2 (en) | 2009-06-23 | 2011-04-05 | Chevron Phillips Chemical Company Lp | Nano-linked heteronuclear metallocene catalyst compositions and their polymer products |
WO2011025053A2 (en) | 2009-08-28 | 2011-03-03 | The University Of Tokyo | Production method of copolymer of allyl monomer containing polar group |
CN102127116B (zh) * | 2010-11-26 | 2013-11-20 | 吉林大学 | 钳型铬配合物及其制备方法和应用 |
US8809221B2 (en) | 2011-05-09 | 2014-08-19 | Reliance Industries Limited | Nitrogen containing external donor system for propylene polymerization |
US9296836B2 (en) | 2011-05-12 | 2016-03-29 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
US9233996B2 (en) * | 2011-09-13 | 2016-01-12 | California Institute Of Technology | Multi-metallic organometallic complexes, and related polymers, compositions, methods and systems |
EP2738187B1 (en) * | 2012-11-29 | 2016-05-04 | Solvay SA | Process for the manufacture of vinyl chloride-containing copolymers |
KR101680776B1 (ko) | 2015-03-24 | 2016-12-12 | 고재덕 | 초절전 축열식 전열 온수관 |
KR101582665B1 (ko) | 2015-10-08 | 2016-01-06 | 고재덕 | 초절전 축열식 전열 온수관 및 이를 포함하는 온수관 시스템 |
JP7175741B2 (ja) * | 2017-12-25 | 2022-11-21 | 日本ポリエチレン株式会社 | 多元系極性基含有オレフィン共重合体 |
KR102409622B1 (ko) * | 2020-04-29 | 2022-06-16 | 아주대학교산학협력단 | 크롬 화합물 및 이의 제조 방법 |
CN113559928A (zh) * | 2021-07-30 | 2021-10-29 | 四川信乙化工有限公司 | 一种苯乙酸可循环合成催化剂 |
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DE1292854B (de) | 1965-03-06 | 1969-04-17 | Hoechst Ag | Verfahren zur Herstellung von Homo- und Mischpolymerisaten von Mono- und Diolefinen |
US4906754A (en) | 1985-10-15 | 1990-03-06 | E. I. Du Pont De Nemours And Company | Nickel catalysts for copolymerization of ethylene |
US5131918A (en) * | 1990-12-13 | 1992-07-21 | Hoechst Celanese Corporation | Process for dyeing mixed anionic/cationic polyamide substrates with a specific type of vinyl sulfone dye |
DE19503119A1 (de) | 1995-02-01 | 1996-08-08 | Hoechst Ag | Verfahren zur Herstellung von aromatischen Olefinen unter Katalyse von Palladacyclen |
JPH1029994A (ja) * | 1996-07-15 | 1998-02-03 | Chichibu Onoda Cement Corp | ポルフィリン二量化化合物 |
US6174975B1 (en) | 1998-01-13 | 2001-01-16 | E.I. Du Pont De Nemours And Company | Polymerization of olefins |
US5929181A (en) * | 1997-06-09 | 1999-07-27 | The B.F.Goodrich Co. | Method for preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts |
US6511936B1 (en) | 1998-02-12 | 2003-01-28 | University Of Delaware | Catalyst compounds with β-diminate anionic ligands and processes for polymerizing olefins |
WO1999047474A1 (en) | 1998-03-18 | 1999-09-23 | Ciba Specialty Chemicals Holding Inc. | Coupling reactions with palladium catalysts |
US6410660B1 (en) * | 1998-03-27 | 2002-06-25 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
FR2784110B1 (fr) | 1998-10-06 | 2003-08-01 | Atochem Elf Sa | Procede de polymerisation des olefines en presence d'eau |
US6544919B1 (en) | 1999-10-06 | 2003-04-08 | Sri International | Multinuclear transition metal catalysts for preparation of multimodal polymer compositions |
FR2814169B1 (fr) | 2000-09-19 | 2005-07-08 | Atofina | Catalyseur pour la polymerisation des olefines |
US6919292B2 (en) | 2000-12-20 | 2005-07-19 | Tosoh Corporation | Transition metal compound, coordinative compound, catalyst for polymerization of olefin, and process for polymerization of olefin using the catalyst |
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US6864210B2 (en) * | 2003-02-06 | 2005-03-08 | Equistar Chemicals, Lp | Bimetallic olefin polymerization catalysts containing indigoid ligands |
US7094898B2 (en) | 2003-05-29 | 2006-08-22 | University Of Ottawa | Ruthenium compounds, their production and use |
US7087687B2 (en) * | 2003-08-21 | 2006-08-08 | Rohm And Haas Company | Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers |
US7172986B2 (en) | 2004-06-14 | 2007-02-06 | Rohm And Haas Company | Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers |
US7199074B2 (en) | 2004-06-14 | 2007-04-03 | Rohm And Haas Company | Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers |
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US20060270811A1 (en) | 2006-11-30 |
EP1728553A3 (en) | 2006-12-20 |
KR100882891B1 (ko) | 2009-02-10 |
KR20070118060A (ko) | 2007-12-13 |
US7435701B2 (en) | 2008-10-14 |
JP5173932B2 (ja) | 2013-04-03 |
CN100558756C (zh) | 2009-11-11 |
CA2547094C (en) | 2011-08-02 |
KR20060122768A (ko) | 2006-11-30 |
JP2006328402A (ja) | 2006-12-07 |
JP2009203479A (ja) | 2009-09-10 |
JP4410774B2 (ja) | 2010-02-03 |
TW200700445A (en) | 2007-01-01 |
CN1891721A (zh) | 2007-01-10 |
EP1728553A2 (en) | 2006-12-06 |
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