TWI261061B

TWI261061B - Polymer composition of nano-scaled fillers and hindered amine light stabilizers

Polymer composition of nano-scaled fillers and hindered amine light stabilizers Download PDF

Info

Publication number: TWI261061B
Authority: TW; Taiwan
Prior art keywords: tert; butyl; bis; tetra; hydroxy
Prior art date: 2001-06-29

Application number

TW091114129A

Other languages

English (en)

Chinese (zh)

Inventor

Hui Chin

Peter Shelsey Solera

Douglas Wayne Horsey

Nikolas Kaprinidis

Eugene Valentine Sitzmann

Original Assignee

Ciba Sc Holding Ag

Priority date

2001-06-29

Filing date

2002-06-27

Publication date

2006-09-01

2002-06-27 Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag

2006-09-01 Application granted granted Critical

2006-09-01 Publication of TWI261061B publication Critical patent/TWI261061B/zh

Links

239000000203 mixture Substances 0.000 title claims abstract description 123
229920000642 polymer Polymers 0.000 title claims abstract description 97
150000001412 amines Chemical class 0.000 title claims abstract description 95
239000004611 light stabiliser Substances 0.000 title claims abstract description 19
239000000945 filler Substances 0.000 title claims abstract description 6
239000000654 additive Substances 0.000 claims abstract description 53
230000000996 additive effect Effects 0.000 claims abstract description 26
230000000087 stabilizing effect Effects 0.000 claims abstract description 11
230000015556 catabolic process Effects 0.000 claims abstract description 10
238000006731 degradation reaction Methods 0.000 claims abstract description 10
230000001590 oxidative effect Effects 0.000 claims abstract description 3
-1 amine amines Chemical class 0.000 claims description 185
239000003381 stabilizer Substances 0.000 claims description 58
150000001875 compounds Chemical class 0.000 claims description 47
239000002738 chelating agent Substances 0.000 claims description 30
239000002105 nanoparticle Substances 0.000 claims description 30
239000011159 matrix material Substances 0.000 claims description 27
239000006096 absorbing agent Substances 0.000 claims description 17
206010036790 Productive cough Diseases 0.000 claims description 16
210000003802 sputum Anatomy 0.000 claims description 16
208000024794 sputum Diseases 0.000 claims description 16
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238000000034 method Methods 0.000 claims description 14
239000003795 chemical substances by application Substances 0.000 claims description 12
239000000126 substance Substances 0.000 claims description 11
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 7
125000002091 cationic group Chemical group 0.000 claims description 7
SQDFHQJTAWCFIB-UHFFFAOYSA-N n-methylidenehydroxylamine Chemical compound ON=C SQDFHQJTAWCFIB-UHFFFAOYSA-N 0.000 claims description 7
ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 6
239000002530 phenolic antioxidant Substances 0.000 claims description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
238000011049 filling Methods 0.000 claims description 3
229910052684 Cerium Inorganic materials 0.000 claims description 2
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
239000007800 oxidant agent Substances 0.000 claims description 2
PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
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125000003545 alkoxy group Chemical group 0.000 description 9
239000003963 antioxidant agent Substances 0.000 description 9
235000006708 antioxidants Nutrition 0.000 description 9
125000006309 butyl amino group Chemical group 0.000 description 9
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NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 9
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125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
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239000011347 resin Substances 0.000 description 8
DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 7
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ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
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JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 6
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XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
239000011686 zinc sulphate Substances 0.000 description 1
235000009529 zinc sulphate Nutrition 0.000 description 1
239000002076 α-tocopherol Substances 0.000 description 1
235000004835 α-tocopherol Nutrition 0.000 description 1
239000011590 β-tocopherol Substances 0.000 description 1
235000007680 β-tocopherol Nutrition 0.000 description 1
239000002478 γ-tocopherol Substances 0.000 description 1
QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
QUEDXNHFTDJVIY-DQCZWYHMSA-N γ-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-DQCZWYHMSA-N 0.000 description 1
239000002446 δ-tocopherol Substances 0.000 description 1