TW562694B - Catalytic composition and a process for oligomerising ethylene, in particular to 1-hexene - Google Patents
Catalytic composition and a process for oligomerising ethylene, in particular to 1-hexene Download PDFInfo
- Publication number
- TW562694B TW562694B TW089127720A TW89127720A TW562694B TW 562694 B TW562694 B TW 562694B TW 089127720 A TW089127720 A TW 089127720A TW 89127720 A TW89127720 A TW 89127720A TW 562694 B TW562694 B TW 562694B
- Authority
- TW
- Taiwan
- Prior art keywords
- compound
- patent application
- aryloxy
- scope
- composition according
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/69—Chromium, molybdenum, tungsten or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9916509A FR2802833B1 (fr) | 1999-12-24 | 1999-12-24 | Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en hexene-1 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW562694B true TW562694B (en) | 2003-11-21 |
Family
ID=9553853
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW089127720A TW562694B (en) | 1999-12-24 | 2000-12-22 | Catalytic composition and a process for oligomerising ethylene, in particular to 1-hexene |
Country Status (8)
Country | Link |
---|---|
US (1) | US6828269B2 (ko) |
EP (1) | EP1110930B1 (ko) |
JP (1) | JP4747416B2 (ko) |
KR (1) | KR100805753B1 (ko) |
DE (1) | DE60005123T2 (ko) |
ES (1) | ES2207473T3 (ko) |
FR (1) | FR2802833B1 (ko) |
TW (1) | TW562694B (ko) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104941682A (zh) * | 2014-03-25 | 2015-09-30 | Ifp新能源公司 | 新型催化组合物及用于使乙烯低聚成1-己烯的方法 |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2833191B1 (fr) * | 2001-12-10 | 2004-08-20 | Inst Francais Du Petrole | Composition catalytique et procede ameliores pour l'oligomerisation de l'ethylene, en particulier en hexene-1 |
US6897276B2 (en) | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
US7091292B2 (en) | 2002-04-24 | 2006-08-15 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
US7060848B2 (en) | 2002-04-24 | 2006-06-13 | Symyx Technologies, Inc. | Bridged bi-aromatic catalysts, complexes, and methods of using the same |
TW200502038A (en) | 2003-03-14 | 2005-01-16 | Chevron Phillips Chemical Co | Process to decrease or eliminate corrosion from the decomposition of halide containing olefin catalysts |
FR2857964B1 (fr) * | 2003-07-25 | 2008-02-15 | Inst Francais Du Petrole | Procede ameliore de production d'olefines-alpha legeres en particulier d'hexene-1, par oligomerisation de l'ethylene |
US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
US20050187098A1 (en) * | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US7384886B2 (en) | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
US7414006B2 (en) * | 2005-03-09 | 2008-08-19 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins |
JP5448142B2 (ja) * | 2005-03-09 | 2014-03-19 | エクソンモービル・ケミカル・パテンツ・インク | オレフィンのオリゴマー化 |
US7982085B2 (en) | 2006-02-03 | 2011-07-19 | Exxonmobil Chemical Patents Inc. | In-line process for generating comonomer |
US8003839B2 (en) | 2006-02-03 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Process for generating linear apha olefin comonomers |
US8076524B2 (en) | 2006-02-03 | 2011-12-13 | Exxonmobil Chemical Patents Inc. | Process for generating alpha olefin comonomers |
US8404915B2 (en) | 2006-08-30 | 2013-03-26 | Exxonmobil Chemical Patents Inc. | Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations |
EP2104679A1 (en) | 2007-01-08 | 2009-09-30 | ExxonMobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts |
WO2008085659A1 (en) | 2007-01-08 | 2008-07-17 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine ether catalysts |
WO2008085658A1 (en) | 2007-01-08 | 2008-07-17 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins with chromium pyridine thioether catalysts |
KR101445431B1 (ko) * | 2007-11-28 | 2014-09-26 | 린데 악티엔게젤샤프트 | 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 |
US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
EP2196444A1 (en) * | 2008-12-11 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to make alpha olefins from ethanol |
US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
AU2013207783B2 (en) | 2012-01-13 | 2017-07-13 | Lummus Technology Llc | Process for providing C2 hydrocarbons via oxidative coupling of methane and for separating hydrocarbon compounds |
KR101513145B1 (ko) | 2012-05-10 | 2015-04-17 | 주식회사 엘지화학 | 리간드 화합물, 크롬 화합물 및 이를 포함하는 촉매계 |
US9469577B2 (en) | 2012-05-24 | 2016-10-18 | Siluria Technologies, Inc. | Oxidative coupling of methane systems and methods |
US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
EP3074119B1 (en) | 2013-11-27 | 2019-01-09 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
WO2015105911A1 (en) | 2014-01-08 | 2015-07-16 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
EP3097068A4 (en) | 2014-01-09 | 2017-08-16 | Siluria Technologies, Inc. | Oxidative coupling of methane implementations for olefin production |
US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
US9601801B2 (en) * | 2014-07-18 | 2017-03-21 | Uchicago Argonne, Llc | Electrolytes comprising metal amide and metal chlorides for multivalent battery |
US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
WO2016205411A2 (en) | 2015-06-16 | 2016-12-22 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
WO2017065947A1 (en) | 2015-10-16 | 2017-04-20 | Siluria Technologies, Inc. | Separation methods and systems for oxidative coupling of methane |
CA3019396A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
US9707549B1 (en) | 2016-05-26 | 2017-07-18 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization catalyst systems using chemically-treated solid oxides |
EP3554672A4 (en) | 2016-12-19 | 2020-08-12 | Siluria Technologies, Inc. | PROCEDURES AND SYSTEMS FOR CHEMICAL DEPOSITION |
HUE064375T2 (hu) | 2017-05-23 | 2024-03-28 | Lummus Technology Inc | Metán oxidatív csatolási folyamatainak integrálása |
US10836689B2 (en) | 2017-07-07 | 2020-11-17 | Lummus Technology Llc | Systems and methods for the oxidative coupling of methane |
WO2020114745A1 (en) | 2018-12-04 | 2020-06-11 | Exxonmobil Chemical Patents Inc. | Methods for separating linear alpha olefins from combined product streams |
WO2020185426A1 (en) | 2019-03-13 | 2020-09-17 | Tpc Group Llc | Flexible manufacturing system for selectively producing different linear alpha olefins |
FR3112969B1 (fr) * | 2020-07-30 | 2022-08-05 | Ifp Energies Now | Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
FR2093306A6 (fr) * | 1970-06-09 | 1972-01-28 | Solvay | Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines |
US4024050A (en) * | 1975-01-07 | 1977-05-17 | Nalco Chemical Company | Phosphorous ester antifoulants in crude oil refining |
JPS5952166B2 (ja) * | 1976-06-29 | 1984-12-18 | 三井化学株式会社 | ポリオレフインの製造方法 |
US4422957A (en) * | 1980-05-02 | 1983-12-27 | Phillips Petroleum Company | Methods of producing polyolefins using supported high efficiency polyolefin catalyst components |
US4547475A (en) * | 1984-09-07 | 1985-10-15 | The Dow Chemical Company | Magnesium halide catalyst support and transition metal catalyst prepared thereon |
US5543375A (en) * | 1994-02-18 | 1996-08-06 | Phillips Petroleum Company | Olefin production |
US5506184A (en) * | 1994-06-22 | 1996-04-09 | Mobil Oil Corporation | Olefin polymerization catalyst system |
JP3153850B2 (ja) * | 1996-05-20 | 2001-04-09 | 昭和電工株式会社 | エチレン系重合体の製造方法 |
US6011127A (en) * | 1996-05-20 | 2000-01-04 | Showa Denko K.K. | Process for the production of ethylenic polymers |
JP3572811B2 (ja) * | 1996-06-17 | 2004-10-06 | 東ソー株式会社 | クロムを含有する廃触媒の処理方法 |
JP3823429B2 (ja) * | 1996-06-28 | 2006-09-20 | 住友化学株式会社 | 触媒系及びオレフィンの反応方法 |
JPH1119158A (ja) * | 1997-07-01 | 1999-01-26 | Sakai Medical Co Ltd | 入浴用車椅子 |
JP4352513B2 (ja) * | 1998-12-11 | 2009-10-28 | 東ソー株式会社 | エチレンの三量化触媒及びその触媒を用いたエチレンの三量化方法 |
-
1999
- 1999-12-24 FR FR9916509A patent/FR2802833B1/fr not_active Expired - Lifetime
-
2000
- 2000-12-11 DE DE60005123T patent/DE60005123T2/de not_active Expired - Lifetime
- 2000-12-11 ES ES00403477T patent/ES2207473T3/es not_active Expired - Lifetime
- 2000-12-11 EP EP00403477A patent/EP1110930B1/fr not_active Expired - Lifetime
- 2000-12-22 KR KR1020000080167A patent/KR100805753B1/ko active IP Right Grant
- 2000-12-22 TW TW089127720A patent/TW562694B/zh not_active IP Right Cessation
- 2000-12-25 JP JP2000392368A patent/JP4747416B2/ja not_active Expired - Lifetime
- 2000-12-26 US US09/745,441 patent/US6828269B2/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104941682A (zh) * | 2014-03-25 | 2015-09-30 | Ifp新能源公司 | 新型催化组合物及用于使乙烯低聚成1-己烯的方法 |
CN104941682B (zh) * | 2014-03-25 | 2019-07-30 | Ifp 新能源公司 | 催化组合物及用于使乙烯低聚成1-己烯的方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1110930A1 (fr) | 2001-06-27 |
KR100805753B1 (ko) | 2008-02-21 |
FR2802833A1 (fr) | 2001-06-29 |
ES2207473T3 (es) | 2004-06-01 |
EP1110930B1 (fr) | 2003-09-10 |
DE60005123T2 (de) | 2004-03-25 |
DE60005123D1 (de) | 2003-10-16 |
JP4747416B2 (ja) | 2011-08-17 |
JP2001219071A (ja) | 2001-08-14 |
KR20010062617A (ko) | 2001-07-07 |
FR2802833B1 (fr) | 2002-05-10 |
US20010023281A1 (en) | 2001-09-20 |
US6828269B2 (en) | 2004-12-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW562694B (en) | Catalytic composition and a process for oligomerising ethylene, in particular to 1-hexene | |
JP4189703B2 (ja) | 触媒組成物、並びにエチレンの特に1−ブテンおよび/または1−ヘキセンへのオリゴマー化方法 | |
US6903042B2 (en) | Catalytic composition and process for oligomerizing ethylene, in particular to 1-hexene | |
RU2682334C2 (ru) | Новая каталитическая композиция и способ олигомеризации этилена с получением гексена-1 | |
JPS643534B2 (ko) | ||
JP6574599B2 (ja) | 新規ニッケルベースの組成物、およびオレフィンのオリゴマー化のための該組成物の使用 | |
JPH0425936B2 (ko) | ||
US20200331823A1 (en) | Normal Alpha Olefin Synthesis Using Dehydroformylation or Dehydroxymethylation | |
FR2710280A1 (fr) | Composition catalytique et procédé pour la dimérisation des oléfines. | |
WO2002083306A2 (en) | Oligomerisation process and catalyst system | |
JP2015209429A (ja) | 新規ニッケルベース錯体、およびオレフィンの変換方法における害錯体の使用 | |
JP4454090B2 (ja) | 芳香族炭化水素のアルキル化方法及びそれに用いる触媒 | |
JP4395638B2 (ja) | 含窒素複素環をアルコールと結合させた二座キレート配位子を含む有機金属錯体及びオレフィンのオリゴマー化の触媒として作用するためのそれらの使用 | |
Zimmermann et al. | Biphasic dimerisation of methylacrylate—immobilisation and stabilisation of cationic Pd-catalysts in ionic liquids by an ammoniumphosphine ligand | |
JP2009504578A (ja) | 線状アルファオレフィンの調製方法およびそのための反応装置系 | |
JPS5934685B2 (ja) | 2,6− ジメチル −1,3,6− オクタトリエン ノ セイゾウホウ | |
JPS6330293B2 (ko) | ||
JPS62158225A (ja) | 低級α−オレフインの二量化方法 | |
US6294687B1 (en) | Process for the preparation of saturated carboxylic acids and their esters | |
JPH06293670A (ja) | エチレン低重合体の製造方法 | |
JPH0730095B2 (ja) | 2,1,3―ベンゾアザジシロリジン誘導体の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GD4A | Issue of patent certificate for granted invention patent | ||
MK4A | Expiration of patent term of an invention patent |