TW516203B - Chromium adhesion layer for copper vias in low-k technology - Google Patents

Chromium adhesion layer for copper vias in low-k technology Download PDF

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TW516203B
TW516203B TW091100147A TW91100147A TW516203B TW 516203 B TW516203 B TW 516203B TW 091100147 A TW091100147 A TW 091100147A TW 91100147 A TW91100147 A TW 91100147A TW 516203 B TW516203 B TW 516203B
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layer
depositing
copper wire
patent application
forming
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Brett H Engel
Mark Hoinkis
John A Miller
Soon-Cheon Seo
Yun-Yu Wang
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Ibm
Infineon Technologies Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76841Barrier, adhesion or liner layers
    • H01L21/76843Barrier, adhesion or liner layers formed in openings in a dielectric
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76841Barrier, adhesion or liner layers
    • H01L21/76843Barrier, adhesion or liner layers formed in openings in a dielectric
    • H01L21/76846Layer combinations
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    • H01ELECTRIC ELEMENTS
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    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/52Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames
    • H01L23/522Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
    • H01L23/532Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
    • H01L23/53204Conductive materials
    • H01L23/53209Conductive materials based on metals, e.g. alloys, metal silicides
    • H01L23/53228Conductive materials based on metals, e.g. alloys, metal silicides the principal metal being copper
    • H01L23/53238Additional layers associated with copper layers, e.g. adhesion, barrier, cladding layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/0001Technical content checked by a classifier
    • H01L2924/0002Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing
    • Y10T29/49124On flat or curved insulated base, e.g., printed circuit, etc.
    • Y10T29/49126Assembling bases
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing
    • Y10T29/49124On flat or curved insulated base, e.g., printed circuit, etc.
    • Y10T29/49128Assembling formed circuit to base
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing
    • Y10T29/49124On flat or curved insulated base, e.g., printed circuit, etc.
    • Y10T29/49155Manufacturing circuit on or in base
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing
    • Y10T29/49124On flat or curved insulated base, e.g., printed circuit, etc.
    • Y10T29/49155Manufacturing circuit on or in base
    • Y10T29/49156Manufacturing circuit on or in base with selective destruction of conductive paths
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing
    • Y10T29/49124On flat or curved insulated base, e.g., printed circuit, etc.
    • Y10T29/49155Manufacturing circuit on or in base
    • Y10T29/49165Manufacturing circuit on or in base by forming conductive walled aperture in base

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
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  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Description

516203
發明領域 本發明之領域為形成具有銅金屬化和低k介電質的積體 電路。 發明背景 在銅與氧化物的領域中,該技藝己開發出_組相容材 料,以鑲襯含銅的溝渠和通孔。鑲襯物必須黏附於介電質 •上’並阻止擴散和電致遷移。 傳統上,在氧化物介電質電路中,將連接至下層的通孔 與一水平導線構件組合在一起的雙鑲嵌結構包含由丁&或
TaN構成的黏附層、·由TaN構成,以防止銅擴散的障礙 裝 層,以及在Cu種子沈積之前,由Ta4lraN構成的頂層。 、當半導體裝置的尺寸持續縮小時,其金屬導線的^延 遲變成裝置速率的主要限制因素。為解決此問題,在一低 訂 k介電材料(降低金屬導線之間的電容值c)内實作銅導線 (降低電阻值H) ’成為半導體工業將裝置縮小至深次微米 尺寸時的關鍵性問題。 實現銅低k金屬化製程最經濟的方式為使用一雙鑲嵌結 構,並於某-製程步驟中姓刻金屬通孔和金屬導線,並填 以Cu金屬。多餘的Cu#CMp(化學機械研磨)法除去。 =嵌結構中,對於金屬通孔和金屬導線而言,U金^ 2材枓之間需要一層(或多層)障礙層。此障礙層亦稱為 ’㈣物。報襯物有兩個功能:t*Cu擴散的障礙物,可防 ‘政5丨1私材料内,也是C u金屬通孔與下層金屬導 、”(可由Cu或W製成)之間的接觸層。 才 芘張尺度適用格(21〇χ297公着) 516203 A7 B7 五、發明説明( 在「31〇2介負内的C u雙鑲嵌金屬化結構」的領域中(吾 人並不將此介電質視為低k介電材料),以往技藝已開發出 一組用於鑲襯物的相容材料,例如T a、τ aN和CVD T i N。 吾人也已發現T a對C u金屬的黏附性很好,而CVD 丁 i N在 導線和通孔側壁上的覆蓋性較佳,特別是對高寬比很大的 結構。 .然而’ 「在低k介電材料内形成c u金屬導線」領域中已 產生了新的問題,這些問題在「&〇2介質内的c u金屬導 線」中並無對應的問題。例如某一種低k介電質(例如SiLK) 有一些在Si02中並不存在的材料性質。siLK為一聚合物材 料主要疋由C構成。SiLK也是一種軟材料,其熱膨脹係 數非常南。由於SiLK材料的這些獨特性質,該材料中之c u 金屬導線的要求,例如通孔側壁的覆蓋性,以及鑲襯層與 下層金屬(―Cu或W金屬)之”間的黏附性,與Si〇2介電材料内 C u金屬化的對應要求不同。 此外,通孔及金屬導線的尺寸正在縮小,且通孔的高寬 比相對增加的事實,也對雙鑲嵌結構的鑲襯物增加了額外 的要求。 本I明係關於一種材料與結構的組合,此組合係針對使 用低k介電質的銅導線電路’它提供通孔底部與下方銅導 線構件之間所需的黏附性,並提供足夠低的電阻值。 本發明的特色之一為通孔底部的C r鑲襯層與下方銅導線 構件之間的黏附性足以抵抗熱循環造成的應力。 516203 A7 B7
五、發明説明( 本發明的另一特色為吾人藉由一 Cr層的吸氣作用而減少 通孔底部上的碳污染。 圖式簡述 圖1顯示根據本發明之導線的一部分。 圖2顯示根據以往技藝之導線的一部分。 k j圭具體复例的詳細描述 .在測武將銅金屬化與低k介電質(例如D 〇 w出品的SiLK) 組合的積體電路時,吾人發現一意料之外的問題。 相較於在「銅導線與氧化物層間介電質」方面的以往技 r 藝工作,通孔在熱循環後發生了開路現象,其失敗率高得 令人不能接受。 吾人已發現問題的原因為通孔底部與下層鋼構件之間的 機械分離。 當通孔橫向尺寸縮小(以及其高寬比增加)時,此問題 只會更嚴重。 現在參閱圖2,其中顯示一根據以往技藝的典型通孔。 下方介電層20置於矽基板10上。第一銅層3〇從左邊延伸 到右邊。一傳統的障礙層3 2,亦稱為覆蓋層(例如s iN), 已沉積於銅層30上。 在圖的中央,一通孔從銅層50向下延伸,並與層3〇接 觸。吾人以一傳統的CVD TiN鑲襯物62和丁a(及/STaN)鑲 襯物6 4的組合將銅鑲襯。在一示範性具體實施例中,對一 名義上的接線規則為2〇〇奈米的製程而言,層4〇的厚度名 義上為300奈米,通孔的尺寸名義上為2〇〇奈米χ2〇〇奈米,高 本紙張尺度適用中國國家標準(CNS) Α4規格(210 X 297公釐) I比名義上為3.5。當尺寸縮小時,高寬比(以及通孔底部 之鍵結上的張力)會增加。 ^人已喬現此一組合在產生任何熱應力之前很理想,然 而當其在介於_65。(:與2〇〇它之間的重覆熱循環之後,會造 成鬲得不能接受的失敗率。吾人已發現失敗率的原因為通 =展部的機械分離。SiLK的熱膨脹係數比銅大五倍,因此 ‘田電路的溫度上升時,層間·介電質會對通孔底部的人 施加很大的應力。 造成分離的可疑原因之-是因為在先前#刻與清潔通孔 的製程中,碳從低1^介電質放出(逸出)。傳統的清潔過程 (例如噴滅清潔法)並未將這些碳完全除去’它們會干擾_ 的上表面及鑲襯物下方表面之間良好鍵結的形成。此外, 當晶圓暴露於空氣中時,氧會吸附在暴露出來的通孔底部 上ϋ匕效應的組合,+Ta及/或丁aN與銅之間的鍵結變 弱’並產生在熱應力下造成電路開路的現象。《已造成組 合銅導線與低k介電質之優良特性時的難題。 / 現在參閱圖1 ’顯示本發明的一具體實施例,其中在诵 ::的底部’鑲襯物62和64已被取代為由賤鍍的C:構成的 ^ .襄襯物4 2厚度名義上為j 〇〜2 〇奈米。c r在側邊的覆 蓋率將較底部為低,因為濺鍵的對垂直表面的ρ性^ 佳。以往在電路封裝領域中,〇已被使用為銅上:黏附 層’其中並未使用有機材料’且其尺寸及應力與積體電路 技蟄完全不同。 其次, 吾人在標準狀態下沉積一 名義上為5奈米到1 〇奈 516203
米厚的CVD ΤιΝ(以化學氣相沉積法沉積)$。此層具有保形 7並可彌補第一層缺少的覆蓋性。TiN對SiLK的黏附性也 很予口此即使通孔壁上有任何敞開的SiLK表面,壁上的 黏附性仍然很好。 €襯物的最後一層為_丁 &層,名義上為奈米厚, ,、功用為增進丁 lN鑲襯物與C u導線構件之間的鍵結。亦 可使用TaN。 貝驗〜果_ 7F ·根據本發明建造的通孔,其失敗率已劇 降。 在铋作時,第一層銅導線照常沉積與製作圖案(最好在 :鑲嵌結構内)。第一層介電質亦照常沉積。纟次,吾人 最好在雙鑲肷製程内蝕刻層間介電質,將其貫穿而產生 一組通孔。一組三層鑲襯層已放下,且若吾人希望的話, 並以傳統的CMP方法除去通道外的鑲襯層,俾供第二銅層 之用。 3 吾人放下第二層銅,並製作圖案。製程將視需要而重 複,直到所有的銅層都被放下。 !一種具體f 瓦面的討論係針對三層的鑲襯物。吾人亦可使用本發明 的其他具體實施例。例如,吾人可使用單一的C r層4 2,而 不使用TiN或丁a。此具體實施例放棄了 TiN的保形性覆蓋 及其身為擴散障礙層的品質。此具體實施例具有成本較低 的優點’但其保形性不如CVD TiN。 另一具體實施例係以另一濺鍍C r層取代T a頂端鑲襯層 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐)
裝 訂
)1()203
48。這樣可以提供對導線上層銅層的良好黏附性,且使用 的材料較少。 另一種層不使用TiN層46 ,並保留Ta(或TaN)層48。 其保形性不如第一具體實施例,但可略去cv〇步驟。 在每-具體實施例中’通常會有一傳統的濺鍍銅種子 層,以改進黏附性。 .雖然本|明係針對單-較佳具體實施例而描㉛,熟悉本 技藝的人士將理解吾人可在下列申纟杳森 仏P〜肀叫寻利軏圍的精神與範 寿 < 内,以任何版本來實行本發明。

Claims (1)

  1. 516203 A8 B8 C8 D8 六、 申請專利範圍 1· 一種在積體電路中形成鋼導線的方法,包含下列步驟: (a) 沉積並圖案化一第—鋼導線層; (b) 沉積一第一層低介電常數的層間介電質; (c) 經由該第一層低介電常數的層間介電質形成/麵 通孔,並止於該銅導線的第一層上; (d) 在该組通孔内沉積一第一 Cr鑲襯層,·以及 (e) 沉積並圖案化一第二銅導線層。 2。如申請專利範圍第1項在積體電路中形成銅導線的方 法,包含額外步驟: (d- 1)在該組通孔中沉積由cv〇 丁沉構成的第二鑲襯 層。 3·如申請專利範圍第2項在積體電路中形成銅導線的方 法,包含額外步驟: (d-2)_沉積一從Ta*TaN構成的群組中選出之第三鑲 襯層。 *·如申請專利範圍第2項在積體電路中形成銅導線的方 法,包含額外步驟: (d-2)沉積一由以構成的第三鑲襯層。 方 5.如申請專利範圍第η在積體電路中形成銅導線的 法,包含額外步驟: 鑲 (d-Ι)沉積一&Ta和丁 aN構成的群組中選出之第二 襯層。 ~ 5· -種在積體電路中形成銅導線的方法,包含下列步驟 (a)沉積並圖案化一第一銅導線層; ίΑ -11 - 本紙張尺歧財® β家標準(c^ii^_X297公爱) 516203
    (b ) /儿積一弟一層低介電常數的層間介電質· (c) 經由該第一層低介電常數的層間介電質形成一組 通孔,並止於該銅導線的第一層上; (d) 在該組通孔内沉積一第一 c r鑲襯層; (e) 在該組通孔内沉積一第二cvd TiN鑲襯層; (f) 沉積一從T a和T aN構成的群組中選出之第三镶觀 層;以及 (g) 沉積一第二銅導線層,並製作圖案。 7.如申請專利範圍第6項的方法,尚包含重複該步驟(b)到 (g)至少一次。 8·如申請專利範圍第6項的方法,其中該低介電常數的層 間介電質含有SiLK。 9·如申請專利範圍第7項的方法,其中該低介電常數的層 間介電質含有SiLK。 -12 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐)
TW091100147A 2001-01-11 2002-01-08 Chromium adhesion layer for copper vias in low-k technology TW516203B (en)

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CN1486504A (zh) 2004-03-31
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JP2004523891A (ja) 2004-08-05
JP4558272B2 (ja) 2010-10-06

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