TW496876B - Encapsulated hydrophilic polymers and their preparation - Google Patents
Encapsulated hydrophilic polymers and their preparation Download PDFInfo
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- TW496876B TW496876B TW084108776A TW84108776A TW496876B TW 496876 B TW496876 B TW 496876B TW 084108776 A TW084108776 A TW 084108776A TW 84108776 A TW84108776 A TW 84108776A TW 496876 B TW496876 B TW 496876B
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- acid
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- 229920001477 hydrophilic polymer Polymers 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 159
- 239000000178 monomer Substances 0.000 claims abstract description 143
- 239000002245 particle Substances 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 43
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 22
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims description 41
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 22
- -1 Alkenyl ester Chemical class 0.000 claims description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 21
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 19
- 230000008961 swelling Effects 0.000 claims description 18
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 17
- 239000000123 paper Substances 0.000 claims description 17
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- 239000003795 chemical substances by application Substances 0.000 claims description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
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- 238000000576 coating method Methods 0.000 claims description 11
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
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- NKHAVTQWNUWKEO-UHFFFAOYSA-N fumaric acid monomethyl ester Natural products COC(=O)C=CC(O)=O NKHAVTQWNUWKEO-UHFFFAOYSA-N 0.000 claims description 5
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- OIYTYGOUZOARSH-UHFFFAOYSA-N 4-methoxy-2-methylidene-4-oxobutanoic acid Chemical compound COC(=O)CC(=C)C(O)=O OIYTYGOUZOARSH-UHFFFAOYSA-N 0.000 claims description 4
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- NKHAVTQWNUWKEO-NSCUHMNNSA-N monomethyl fumarate Chemical compound COC(=O)\C=C\C(O)=O NKHAVTQWNUWKEO-NSCUHMNNSA-N 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 claims description 2
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- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 claims 3
- CFGGNXFNDNQZKD-UHFFFAOYSA-N 2-(9H-fluoren-1-yl)prop-2-enoic acid Chemical compound C1C2=CC=CC=C2C2=C1C(C(=C)C(=O)O)=CC=C2 CFGGNXFNDNQZKD-UHFFFAOYSA-N 0.000 claims 2
- CUTWSDAQYCQTGD-UHFFFAOYSA-N 2-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)C(C)OC(=O)C=C CUTWSDAQYCQTGD-UHFFFAOYSA-N 0.000 claims 2
- 125000005907 alkyl ester group Chemical group 0.000 claims 2
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 claims 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims 1
- 241001448862 Croton Species 0.000 claims 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N Methyl butyrate Chemical compound CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 claims 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- JDTXSWGCYBOHDZ-UHFFFAOYSA-N n-(9h-fluoren-1-yl)prop-2-enamide Chemical compound C1C2=CC=CC=C2C2=C1C(NC(=O)C=C)=CC=C2 JDTXSWGCYBOHDZ-UHFFFAOYSA-N 0.000 claims 1
- 230000002028 premature Effects 0.000 claims 1
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- 239000000463 material Substances 0.000 description 15
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- MVLVMROFTAUDAG-UHFFFAOYSA-N octadecanoic acid ethyl ester Natural products CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
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- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
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- ZFACJPAPCXRZMQ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C(O)=O ZFACJPAPCXRZMQ-UHFFFAOYSA-N 0.000 description 1
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- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
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- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
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- BHAROVLESINHSM-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1.CC1=CC=CC=C1 BHAROVLESINHSM-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/126—Polymer particles coated by polymer, e.g. core shell structures
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
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|---|---|---|---|
| US08/289,736 US5494971A (en) | 1994-08-12 | 1994-08-12 | Encapsulated hydrophilic polymers and their preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW496876B true TW496876B (en) | 2002-08-01 |
Family
ID=23112851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW084108776A TW496876B (en) | 1994-08-12 | 1995-08-23 | Encapsulated hydrophilic polymers and their preparation |
Country Status (15)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI421284B (zh) * | 2006-01-27 | 2014-01-01 | Jsr Corp | 多晶型粒子、多晶型粒子組成物及其製造方法、以及光擴散成形品 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19521663A1 (de) * | 1995-06-14 | 1996-12-19 | Philips Patentverwaltung | Integrierter Schaltkreis mit Spannungsregelschaltung |
| US6413011B1 (en) | 1997-02-26 | 2002-07-02 | Rohm And Haas Company | Method for producing fast-drying multi-component waterborne coating compositions |
| US6020435A (en) * | 1997-11-05 | 2000-02-01 | Rohm And Haas Company | Process for preparing polymer core shell type emulsions and polymers formed therefrom |
| ZA989623B (en) * | 1997-11-05 | 1999-04-26 | Rohm & Haas | Process for preparing polymer emulsions and polymers formed therefrom |
| US5932515A (en) * | 1997-11-25 | 1999-08-03 | The Mead Corporation | Recording paper incorporating hollow spherical plastic pigment |
| EP0959176B1 (en) * | 1998-05-18 | 2012-09-05 | Rohm And Haas Company | Hollow sphere organic pigment for paper or paper coatings |
| DE19833062A1 (de) | 1998-07-22 | 2000-02-03 | Elotex Ag Sempach Station | Redispergierbares Pulver und dessen wäßrige Dispersion, Verfahren zur Herstellung sowie Verwendung |
| DE19833061A1 (de) * | 1998-07-22 | 2000-02-03 | Elotex Ag Sempach Station | Verfahren zur Herstellung wäßriger Dispersionen von Latexteilchen mit heterogener Morphologie, die mit dem Verfahren erhältlichen Latexteilchen, die Dispersionen und redispergierbaren Pulver sowie deren Verwendung |
| KR100286471B1 (ko) | 1998-08-25 | 2001-04-16 | 김충세 | 중공구조를 갖는 유화 중합체 및 그 제조방법 |
| US6235344B1 (en) * | 1999-02-05 | 2001-05-22 | Rohm And Haas Company | Method of improving an adhesive article |
| US6531183B1 (en) * | 1999-07-28 | 2003-03-11 | Meadwestvaco Corporation | Method of producing high gloss paper |
| US6475556B1 (en) | 1999-11-25 | 2002-11-05 | Rohm And Haas Company | Method for producing fast drying multi-component waterborne coating compositions |
| MXPA01001665A (es) | 2000-02-18 | 2002-04-01 | John Michael Friel | Pinturas para el marcado de caminos,preparadas a partir de prepinturas; metodo y aparato para formar zonas y lineas marcadas en los caminos, con dichas pinturas y dispositivo para aplicar dichas pinturas |
| JP2002030113A (ja) * | 2000-05-09 | 2002-01-31 | Jsr Corp | 中空ポリマー粒子の製造方法 |
| WO2002055563A2 (en) | 2000-09-21 | 2002-07-18 | Rohm And Haas Company | Methods and compositions involving polar monomers and multivalent cations |
| AU782902B2 (en) | 2000-09-29 | 2005-09-08 | Rohm And Haas Company | Processes for chemically-modifying the surface of emulsion polymer particles |
| US6673451B2 (en) * | 2000-10-12 | 2004-01-06 | Rohn And Haas Company | Process for forming an aqueous polymeric dispersion |
| JP4843850B2 (ja) * | 2001-02-21 | 2011-12-21 | Ｊｓｒ株式会社 | 中空ポリマー粒子の製造方法 |
| AU2127902A (en) * | 2001-03-16 | 2002-09-19 | Rohm And Haas Company | Method for preparing fracture-resistant multi-component coatings at low temperature |
| US20050059748A1 (en) * | 2003-09-15 | 2005-03-17 | Blankenship Robert Mitchell | Aqueous emulsion polymerization process for preparing voided polymer particles |
| EP1602783B1 (en) | 2004-04-23 | 2014-02-26 | Rohm And Haas Company | Method of preparing paper |
| ES2351869T3 (es) * | 2004-04-23 | 2011-02-11 | Rohm And Haas Company | Procedimiento para preparar un material laminado decorativo. |
| US20050236125A1 (en) * | 2004-04-23 | 2005-10-27 | Brown James T | Method of preparing paper |
| KR100564807B1 (ko) * | 2004-07-06 | 2006-03-27 | 주식회사 엘지화학 | 중공 구조의 유화 중합체의 제조 방법 |
| US20060042768A1 (en) * | 2004-08-27 | 2006-03-02 | Brown James T | Coated paper product and the method for producing the same |
| US7939572B2 (en) * | 2004-08-31 | 2011-05-10 | Rohm And Haas Company | Aqueous dispersion of polymeric particles |
| RU2278872C1 (ru) * | 2005-05-13 | 2006-06-27 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения катионного латекса с полыми полимерными частицами |
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| US5157084A (en) * | 1990-10-12 | 1992-10-20 | The Dow Chemical Company | Process of making hollow polymer latex particles |
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1994
- 1994-08-12 US US08/289,736 patent/US5494971A/en not_active Expired - Lifetime
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1995
- 1995-06-06 US US08/467,687 patent/US5545695A/en not_active Expired - Lifetime
- 1995-08-01 IL IL11480095A patent/IL114800A/xx not_active IP Right Cessation
- 1995-08-04 FI FI953718A patent/FI953718A7/fi unknown
- 1995-08-04 EP EP95305474A patent/EP0696602B1/en not_active Expired - Lifetime
- 1995-08-04 DE DE69515570T patent/DE69515570T2/de not_active Expired - Lifetime
- 1995-08-04 ES ES95305474T patent/ES2143592T3/es not_active Expired - Lifetime
- 1995-08-07 AU AU28423/95A patent/AU706410B2/en not_active Expired
- 1995-08-09 KR KR1019950024606A patent/KR100389100B1/ko not_active Expired - Lifetime
- 1995-08-10 BR BR9503621A patent/BR9503621A/pt not_active IP Right Cessation
- 1995-08-10 JP JP22455295A patent/JP3727980B2/ja not_active Expired - Lifetime
- 1995-08-10 MX MX9503437A patent/MX186028B/es unknown
- 1995-08-10 CA CA002155808A patent/CA2155808C/en not_active Expired - Fee Related
- 1995-08-11 SG SG1995001107A patent/SG47351A1/en unknown
- 1995-08-11 CN CN95115344A patent/CN1079799C/zh not_active Expired - Lifetime
- 1995-08-23 TW TW084108776A patent/TW496876B/zh not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI421284B (zh) * | 2006-01-27 | 2014-01-01 | Jsr Corp | 多晶型粒子、多晶型粒子組成物及其製造方法、以及光擴散成形品 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2155808A1 (en) | 1996-02-13 |
| IL114800A (en) | 1999-09-22 |
| CN1079799C (zh) | 2002-02-27 |
| US5545695A (en) | 1996-08-13 |
| KR960007657A (ko) | 1996-03-22 |
| FI953718A7 (fi) | 1996-02-13 |
| AU2842395A (en) | 1996-02-22 |
| EP0696602A1 (en) | 1996-02-14 |
| BR9503621A (pt) | 1996-04-30 |
| ES2143592T3 (es) | 2000-05-16 |
| KR100389100B1 (ko) | 2004-03-06 |
| US5494971A (en) | 1996-02-27 |
| IL114800A0 (en) | 1995-12-08 |
| JP3727980B2 (ja) | 2005-12-21 |
| CN1130634A (zh) | 1996-09-11 |
| DE69515570D1 (de) | 2000-04-20 |
| SG47351A1 (en) | 1998-04-17 |
| AU706410B2 (en) | 1999-06-17 |
| CA2155808C (en) | 2005-05-17 |
| EP0696602B1 (en) | 2000-03-15 |
| DE69515570T2 (de) | 2000-12-14 |
| FI953718A0 (fi) | 1995-08-04 |
| MX186028B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1997-09-18 |
| JPH0881506A (ja) | 1996-03-26 |
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