TW305742B - - Google Patents
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- Publication number
- TW305742B TW305742B TW084106191A TW84106191A TW305742B TW 305742 B TW305742 B TW 305742B TW 084106191 A TW084106191 A TW 084106191A TW 84106191 A TW84106191 A TW 84106191A TW 305742 B TW305742 B TW 305742B
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- Taiwan
- Prior art keywords
- formula
- patent application
- compound
- harmful fungi
- plants
- Prior art date
Links
- 239000000203 mixture Substances 0.000 claims abstract description 27
- -1 oxime ether carboxylic acid ester Chemical class 0.000 claims abstract description 13
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 7
- 241000233866 Fungi Species 0.000 claims description 20
- 238000011049 filling Methods 0.000 claims description 8
- 239000002689 soil Substances 0.000 claims description 6
- 241000894006 Bacteria Species 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- GKXVJHDEWHKBFH-UHFFFAOYSA-N xylylenediamine group Chemical class C=1(C(=CC=CC1)CN)CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 4
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims 2
- PCTMTFRHKVHKIS-BMFZQQSSSA-N (1s,3r,4e,6e,8e,10e,12e,14e,16e,18s,19r,20r,21s,25r,27r,30r,31r,33s,35r,37s,38r)-3-[(2r,3s,4s,5s,6r)-4-amino-3,5-dihydroxy-6-methyloxan-2-yl]oxy-19,25,27,30,31,33,35,37-octahydroxy-18,20,21-trimethyl-23-oxo-22,39-dioxabicyclo[33.3.1]nonatriaconta-4,6,8,10 Chemical compound C1C=C2C[C@@H](OS(O)(=O)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2.O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C=C/C=C/C=C/[C@H](C)[C@@H](O)[C@@H](C)[C@H](C)OC(=O)C[C@H](O)C[C@H](O)CC[C@@H](O)[C@H](O)C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 PCTMTFRHKVHKIS-BMFZQQSSSA-N 0.000 claims 1
- 241000252234 Hypophthalmichthys nobilis Species 0.000 claims 1
- SRBFZHDQGSBBOR-IOVATXLUSA-N Xylose Natural products O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 claims 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 150000001733 carboxylic acid esters Chemical class 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 44
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 12
- 239000000843 powder Substances 0.000 description 9
- 239000004480 active ingredient Substances 0.000 description 5
- 241000123650 Botrytis cinerea Species 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 241000221785 Erysiphales Species 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
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- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 2
- VZWGRQBCURJOMT-UHFFFAOYSA-N Dodecyl acetate Chemical compound CCCCCCCCCCCCOC(C)=O VZWGRQBCURJOMT-UHFFFAOYSA-N 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
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- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
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- 238000009472 formulation Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000015136 pumpkin Nutrition 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
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- 239000002023 wood Substances 0.000 description 2
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- QZEDXQFZACVDJE-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 QZEDXQFZACVDJE-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- KWVPFECTOKLOBL-KTKRTIGZSA-N 2-[(z)-octadec-9-enoxy]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCO KWVPFECTOKLOBL-KTKRTIGZSA-N 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 241000223600 Alternaria Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 235000003276 Apios tuberosa Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000010744 Arachis villosulicarpa Nutrition 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 241000221198 Basidiomycota Species 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 235000007862 Capsicum baccatum Nutrition 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 240000007154 Coffea arabica Species 0.000 description 1
- 241000219122 Cucurbita Species 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 241000371644 Curvularia ravenelii Species 0.000 description 1
- 206010011732 Cyst Diseases 0.000 description 1
- 239000005698 Dodecyl acetate Substances 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
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- 208000001613 Gambling Diseases 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- 241001417534 Lutjanidae Species 0.000 description 1
- 241001344131 Magnaporthe grisea Species 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 241000233622 Phytophthora infestans Species 0.000 description 1
- 244000295760 Piper arborescens Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 241000899394 Pseudocercospora Species 0.000 description 1
- 241001361634 Rhizoctonia Species 0.000 description 1
- 244000113877 Rubus saxatilis Species 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- 241000082085 Verticillium <Phyllachorales> Species 0.000 description 1
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- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000001217 buttock Anatomy 0.000 description 1
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- 239000004202 carbamide Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- LGASAICTCFRDSN-UHFFFAOYSA-L magnesium;tellurate Chemical compound [Mg+2].[O-][Te]([O-])(=O)=O LGASAICTCFRDSN-UHFFFAOYSA-L 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
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- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
A7 B7 五、發明説明（ 其本發明係有藺一種殺真菌琨合物，包含 Λ a ) 式I之肟醚羧酸酯 ， CS3
c=noch3 I co2CH3
K及 b) 協同有效量之選自化合物1[與JI之苯二甲醸亞' 胺衍生 物 〇
〇
II
SCC13 工工工 ---.丨_!·---> .衣------訂-----八 (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本發明另外係有關使用化合物I (即I a或I b )與I之混合 物抑或化合物I與JI之混合物控制有害真菌之方法，以及 有關化合物I 、化合物I[及化合物1B供製造此形態混合物 之用途。 式I化合物，其等之製備Μ及對抗有害真菌之作用揭示 于文獻ΕΡ-Α 253 21 3中。 一 4 本紙張尺度適用中國國家標準（CNS ) Α4规格（210 X 297公釐） 3C5742 A7 經濟部中央標準局員工消費合作社印製 B7五、發明説明（2 ) 苯二甲醯亞胺衍生物I與ffl(US-A ΐδδΙΉϋ; 2,553,77 1 ; 2,553,776 ) ’其等之製侮及對抗有害真菌之 作用同樣屬已知。 有關降低施用率及改菩已知化合物之作用範圍，本II明 係奠基於使活性化合物之施用總最下降，具有對抗；有害真 菌之改良作用的混合物（協同混合物）。 據此，頃發現關始即予界定之混合物。另外亦發現 '，化 合物I及化合物I或化合物m之同時共用或分開施用于有 害真菌上’抑或化合物I與化合物I或化合物ffl接> 縝施用 于有害真菌上比起®別化合物可作較佳之& _。 式I化合物就C = X雙鍵（相對于羧酸官能基）而言可从E 或Z姐態存在。因此’其等每一可从純E或純z的異構物 ，抑或E/Z異構物混合物用于根據本發明之混合物中。使 用E/Z異搆物混合物或E異構物為較佳，e異構物為尤佳 ‘者。 該混合物製備中較佳係使用純活性姐分I與]I或U ,如 有需要，可將另外對k有害真菌或其它害農，瞽如昆晶、 蜘蛛或線蟲之活性化合物，抑或其它除草或生長調節活性 化合物或肥料摻合于其中。 化合物I與I或I與m之琨合物，μ及化合物I與I或 I與ϋ之同時共用或分開使用係κ前者具有對抗大範圍植 物病害真菌（特別是子囊菌及擔子菌網類別者 > 之優良作 用相區別。某些情況下，其等具有内吸活性，因此亦可使 用作為葉Η及土壊殺具菌劑。 (請先閲讀背面之注意事項再填寫本頁) 哀. 、-° t -5 - 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 經濟部中央標準局員工消費合作社印製 A7 _B7_ 五、發明説明（3 ) , 于各種作物植物（臀如棉花、蔬菜植物（例如胡瓜、豆類 及南瓜）、大麥、青草、燕麥、咖啡、，玉蜀柰、水果植物 、稻米、黑麥、大豆、葡萄樹、小麥、裝飾植物、甘蔗） 及多數種子上控制許多真菌為尤其重要者。 其等特別適合控制下列植物病害真菌：毅類上之禾白粉 菌（粉狀霉）、南瓜上之二孢白粉菌及單絲殻、蘋果上之白 叉絲單囊殻、穀類上之柄銹菌種、棉花及草地上之絲核菌 種*殺類及蔗糖上之黑粉菌種、藕果上之蘋果黑星菌（斑 點病）、毅類上之長蠕孢種、小麥上之頴祜殼针孢'箄莓 及匍萄樹上之灰葡萄孢（灰霉）、落花生上之落花生尾孢、 小麥及大麥上之假小尾孢herpotricho丨des 、稻米上之稻 瘟病菌、馬鈐薯及蕃茄上之致病疫霉、葡萄樹上之葡萄生 單軸霉、蔬菜及水果上之鍵格孢物種，Μ及蠊孢物種和輪 枝孢物棰。 其另外可應用於材料之保護（例如木頭保謭），臀如對抗 擬音霉。 化合物I與Π或I齒Β[可同時、一齊或分別，抑或接鑛 施用，而分開施用的順序通常對控制结果無任何影響。 化合物I與Π或I與Β[通常Μ重量比率為1:1至1:1000 ，較佳為1:1至1:500，尤佳為1:3至1:300施用。 根撺本發明*混合物之施用速率視所希效果之類型而定 ，為0 . 0 2至5公斤/公頃，較佳為0.0 5至3.5公斤/公頃， 特別是0.]至3.5公斤/公頃。此處就化合物I而言，施用 速率為0 . 005至0 . 5公斤/公頃，較佳為〇 . 01至0 . 5公斤/ -6- ^紙張尺度適用中國國家榡準（CNS ) Α4规格（2丨〇'乂297公釐） ----------> ,衣------訂-----气 . -- - (請先閱讀背面之注意事項再填寫本頁) A7 B7 五、發明説明（& 公頃，特別是〇 · 〇1至〇. 3公斤/公頃。就化合物I或化合 物II而言，施用速率相當於〇 .】至5公斤，/公頃，較佳為 0 . 1至3 . 5公斤/公頃。 種子處理當中，一般所用混合物之施用速率為每公斤棰 子0.001至50克，較佳為〇.〇1至10克/公斤，特別是〇.〇1 至5克/公斤。 于對植物為病原之有害興菌待控制處，藉對種子、植物 或土壤嗔霧或撒粉方式，在植物播種前或後，或是植物盟 穿前或後行化合物I與Π或I與m ，抑或化合物 I與Η[之混合物之各別或共用施用。 根撺本發明之殺真菌協同混合物及化合物I與1或1與 15可以，例如，直接可噴霧溶液、粉末及懸浮液之形式製 備，抑或Μ高百分比的水性、油狀或其它懋浮液、分散液 、乳液、油狀分散液、漿液、撖粉姐合物、撤施姐合物或 顆粒形式製備，並旦藉噴霧、霧化、撤粉、撖_或漏水方 式使用。施用形式視預期用途而定；而每一情況皆應保證 根據本發明之混合物i分敗液需儘可能的微细且均一。 經濟部中央標準局員工消費合作杜印製 (請先閱讀背面之注意事項再填寫本頁) •1Τ 該配方以本身已知之方式，例如藉添加溶劑和/或載賭 製成。譬如乳化劑或分散劑之憤性添加劑一般與該配方相 摻合。 適當的表面活性物質有芳族磺酸（例如木質素確酸、笨 齡磺酸、萘磺酸及二丁基萘磺酸）及脂肪酸之驗金屬翔、 齡土金靨鹽、銨鹽，烷基-及烷基芳基磺酸鹽，烷基、十 二基醚及脂肪酵硫酸鹽，Μ及硫酸化之六_、七-與八癸 A7 3(55742 五、發明説明（5) 酵的鹽類或丨0肪酵乙一酵®、經確化萘及其衍生物與甲酸 的縮合產物，萘或萘磺酸與酚及甲醛的縮合產物、聚氧伸 乙基辛基酚醚、乙氧基化之興辛基―，辛基-或壬基酚， 烷基酚或二丁基苯基聚一酵_、烷基芳基聚醚酵、異三癸 基酵、脂肪酵-環氧乙烷縮合物、乙氧基化篦麻油、聚氧 伸乙基或聚氧伸丙基烧基酸、聚二酵酸乙酸十二烷基醇酯 、山梨酵酯、木質素-亞疏酸醺廢液或甲基纖維素。 粉末、撖施和撒粉姐合物可利用將化合物χ與E或^與 I裩合或共同研磨，抑或令化合物〗與π或j與]^之混合 物與一固體載體混合或共同研磨而製|得。 顆粒物（例如經塗覆、經浸漬或均勻粒子）—般由將活性 化合物粘合于固賭載髑上而製得。 所用填料及固體載鸦例如有礪物土，譬如矽膠.、矽石、 砂酸鹽、滑石、高嶺土、石灰石、石灰、白堊、紅玄武土 、黃土、粘土、白雲石、矽藻土、硫酸鈣及碲酸鎂、氧化 鎂、磨碎塑膠，及肥料，譬如硫酸銨、磷酸銨、硝酸銨、 脲及蔬菜產品，罾如象類粉末、樹皮粉、木粉填料及堅果 毅粉、纖維素粉末或其它固鵂載體。 該配方通常包含0.1至95重量％，較佳為0.5至90重量％ 化合物I與I或I與Β之一，或是化合物I與I[或I與I 之混合物。該情況下所用活性化合物之純度為90%至100 %，較佳為95%至100% (根據NMR光譜或HPLC)。 化合物I與II或I與Μ ，及混合物抑或相當之配方經施 用Μ處理有害真菌，或Κ殺真菌具活性量之該混合物或各 -8 - 本紙張尺度適用中國國家橾準（CNS ) Α4規格（210X297公釐） (請先閱讀背面之注意事項再填寫本1) 訂 1 經濟部中央標準局員工消费合作杜印製 經濟部中央橾準局員工消費合作社印製 A7 B7__ 五、發明説明（6 ) . 別施用化合物I與Π或I與1H處理保持免受真菌危害之植 物、棰子、土壤、表面、物質或空間°·可于通有害真菌侵 襲之前或之後進行施用。
說明根據本發明之化合物對抗有害真菌之協同作用的實 例C 該等化合物及其混合物之殺真菌作用Μ下列實驗證明： 于70重最％瑁己嗣、20重量％ Nekanil® LN (Lutensol4® AP6 ，M乙氧基化烷基酚為主成分、具乳化 和分散作用之鋪展劑-固著劑）及重量％ Emulphor® EL (Eraulan*® EL，K乙氧基化脂肪醇為主成份之乳化劑 )混合物中，該等活性組分被調配成20%強度的乳液•並 用水稀釋成所要的濟度。 Μ百分比計評估遭真菌侵襄之樹葉面積。然後將數字轉 換為作用程度。活性組分混合物之預期作用程度MCol by 公式（Co丨by , S . R .， ”計算除草姐合物之協同及反協同回 應”，Weeds ϋ, 20-22 (1967)]決定，並與觀察作用程 度作比較。
Co 1 by公式： E= X + y - x. y/100 E= 預期作用程度，當使用濃度為m與n之活性成分A與 B時，Μ未處理對照姐之％表示 省请用 χ= Α灞度為β之活性成分Α時，Μ未處理對照組之％表示 之作用程度 、 y= 當使用濃度為η之活性成分B時，以未處理對照 -9- 本紙張尺度適用中國國家標準（C:NS ) A4規格（2丨0 X 2S»7公釐） (請先閱讀背面之注意事項再填寫本頁) 衮. 訂 A7 B7 305742 五、發明説明（7 ) 表示之作用程度 闞於作用程度為〇乃經處理植物的葉片侵襄情況相當于 未處理對照植物者；作用程度為1〇〇意謂纆處理植物未有 任何葉片逋侵襄。 對抗灰葡萄孢之作用 1固 Μ該活性姐分配方噴洒具有4到葉片” Neusiedler I d e a 1 E 1 i t e ”品種的乾紅椒小樹達溢出情況。待嗔灑.會乾 煉後，K真菌，灰葡萄孢’之分生孢子懸浮液處理該植物 •22-24 T：及高濕度下維持5天。然後以目視方式> 評定葉 片遭侵襲情況。 , I. ^ ''衣 訂 ί \ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消费合作社印製 -10- 活性姐分 施用速率 [ppm] 作用程度 親察值 計算值 -/- 0 la 125 15 III 125 80 la + III 125+125 95 83 本紙張尺度適用中國國家榡準（CNS ) Α·4規格（210'X 297公釐）
Claims (1)
- 305 7¾¾由讀專利範園修正太（86年2月） ABCD 申請專利範圍 種殺I菌混合物，包含 a ) 式I a之肟鰱羧酸酯〇 C-NOCH3I co2ch3 τ ： 請 先 閲 ,讀 背 之 •注 意 事 項 再 本 頁 ) 協同有效量之式II之茏二甲釀亞胺衍生物 〇2U III 經濟部中央揉準局貝工消费合作社印裝 2. 根據申請專利篛第]項之殺真菌混合物，其中式 la之眄醚羧酸酯相對式51之茏二甲醢亞胺衍生物之重 最比率為1:1至1:1000。 3. —種控制有害舆菌之方法*其包括使用式la之肟醚羧 酸酯 CHic*noch3I C02CH3 本紙張尺度適用中國國家揉準（CNS ) A4規格（2!〇Χ297公釐） τ、申請專利範圍 UO C8 D8 及式®之苯二甲齷亞胺衍生物 0III (請先閎讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消费合作社印裂 离理有害真菌，其等之環境或保持免受有害興菌危害 之植物、種子、土塯、表面、物霣或空間。 4·根據申請專利範園第3項之方法，其中la之肟醚羧酸 酷輿式Μ之苯二甲醣亞胺衍生物係同時合併施用，或 分闢抑或接續施用。 5· 根據申謫專利範園第3項之方法，其中有害輿菌，其 等之環境或保捋免受有害真菌危客之植物、種子、土 填、表面、物質或空間以每公頃0.0 0 5至0 . 5公斤之式 la之眄1¾羧酸酯麾理之。 6 · 根撺申謫專利範鬮第3項之方法，其中有害真菌、其 等之環境或保持免受有害興菌危害之植物、種子、土 壤、表面、物霣或空間K每公頃0 . 1至5公斤之式1Π之 茏二甲釀亞胺衍生物逋理之。 本紙伕尺度適用中國國家揉率（CNS ) A4規格（210 X 297公釐）
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| DE4421041A DE4421041A1 (de) | 1994-06-17 | 1994-06-17 | Fungizide Mischungen |
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| EP1201126B1 (de) * | 1997-12-18 | 2005-04-06 | Basf Aktiengesellschaft | Fungizide Mischungen auf der Basis von Pyridincarboxamidverbindungen |
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| US6121197A (en) * | 1999-05-24 | 2000-09-19 | Creanova Inc. | Biocidal composition |
| DE102005060281A1 (de) * | 2005-12-16 | 2007-06-21 | Bayer Cropscience Ag | Fungizide Wirkstoffkombination |
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| US2553771A (en) * | 1948-09-23 | 1951-05-22 | Standard Oil Dev Co | Method of preparing n-trichloromethylthioimides |
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| DE3623921A1 (de) * | 1986-07-16 | 1988-01-21 | Basf Ag | Oximether und diese enthaltende fungizide |
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- 1995-06-08 CZ CZ19963688A patent/CZ288370B6/cs not_active IP Right Cessation
- 1995-06-08 DE DE59501997T patent/DE59501997D1/de not_active Expired - Lifetime
- 1995-06-08 NZ NZ288602A patent/NZ288602A/en not_active IP Right Cessation
- 1995-06-08 PL PL95317832A patent/PL180958B1/pl unknown
- 1995-06-08 AU AU27889/95A patent/AU692273B2/en not_active Expired
- 1995-06-08 CN CN2007101536139A patent/CN101129139B/zh not_active Expired - Lifetime
- 1995-06-08 EP EP95923264A patent/EP0765118B1/de not_active Expired - Lifetime
- 1995-06-13 IL IL11412695A patent/IL114126A/xx not_active IP Right Cessation
- 1995-06-15 ZA ZA954971A patent/ZA954971B/xx unknown
- 1995-06-16 TW TW084106191A patent/TW305742B/zh not_active IP Right Cessation
- 1995-08-06 UA UA97010165A patent/UA51626C2/uk unknown
-
1996
- 1996-12-13 BG BG101054A patent/BG63185B1/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2788995A (en) | 1996-01-15 |
| IL114126A0 (en) | 1995-10-31 |
| DE59501997D1 (de) | 1998-05-28 |
| NZ288602A (en) | 1998-05-27 |
| CZ368896A3 (en) | 1997-04-16 |
| EP0765118A1 (de) | 1997-04-02 |
| ZA954971B (en) | 1996-12-17 |
| PL180958B1 (pl) | 2001-05-31 |
| SK162196A3 (en) | 1997-09-10 |
| CN101129139A (zh) | 2008-02-27 |
| KR970703703A (ko) | 1997-08-09 |
| BR9508056A (pt) | 1997-08-12 |
| AU692273B2 (en) | 1998-06-04 |
| US5877201A (en) | 1999-03-02 |
| RU2152720C1 (ru) | 2000-07-20 |
| ES2115385T3 (es) | 1998-06-16 |
| KR100392870B1 (ko) | 2003-10-22 |
| DE4421041A1 (de) | 1995-12-21 |
| CN101129139B (zh) | 2011-01-26 |
| WO1995035033A1 (de) | 1995-12-28 |
| CZ288370B6 (en) | 2001-06-13 |
| IL114126A (en) | 2000-09-28 |
| MX9606520A (es) | 1997-06-28 |
| HU9603473D0 (en) | 1997-02-28 |
| HU215212B (hu) | 1998-10-28 |
| ATE165210T1 (de) | 1998-05-15 |
| BG101054A (en) | 1998-04-30 |
| UA51626C2 (uk) | 2002-12-16 |
| JPH10502909A (ja) | 1998-03-17 |
| BG63185B1 (bg) | 2001-06-29 |
| HUT75996A (en) | 1997-06-30 |
| DK0765118T3 (da) | 1998-10-07 |
| SK281658B6 (sk) | 2001-06-11 |
| PL317832A1 (en) | 1997-04-28 |
| EP0765118B1 (de) | 1998-04-22 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |