TW299226B - - Google Patents
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- TW299226B TW299226B TW084112157A TW84112157A TW299226B TW 299226 B TW299226 B TW 299226B TW 084112157 A TW084112157 A TW 084112157A TW 84112157 A TW84112157 A TW 84112157A TW 299226 B TW299226 B TW 299226B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/48—Surfactants
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4993—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/34—Oils, fats, waxes or natural resins
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
- A61F2013/51117—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control the lotion having skin care properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Hematology (AREA)
- Materials Engineering (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Emergency Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dermatology (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Materials For Medical Uses (AREA)
- Cosmetics (AREA)
- Laminated Bodies (AREA)
Description
A7 A7 經濟部中央慄準局β:工消费合作杜印製 B7 五、發明説明( 技術領域 本申請案係關吸收物件如尿片、訓練短褲、成人失禁装 置之類。較詳言之本發明係關頂片外表面上有洗劑塗i的 吸收物件能經正常接觸及穿者動作與/或體溫轉移至穿者皮 膚。本發明洗劑屬之至發穿煮支底二J^參羞 炎於..清.除、9,. 發明之背景 «•午夕型可棄式吸收製如尿片能得有吸尿之大容量。此 型可棄式製品一般含幾種能透流體的應芡、界嚷蘇與不透 ♦獎H_.片教質.。此等型態之吸收結構雖可高效吸收流體 而不能吸收大便(即後文稱作"By")。:61^典型留在能透流 體的頂片外表面與穿者的皮膚之間,大多附著殄穿者皮膚 〇 曼哼為B Μ附、著於穿者皮膚起見照料者常在屁股上及肛門 辱塗敷保乘或"防止用巧如凡士林或礦油後放置吸收物件 '於穿者。此一程序通常涉及照料者傾倒油或洗劑於例如手 中,雙手一起抹擦分布手上後抹於婴兒膚上。爲免此浪費 及麻煩之需要與易於忘懷的手續、以往曾有不少嘗試製備 頂片上含保護或治療的護膚物質之吸收物件。 5塗在尿片製品上作洗劑授予撫慰護層的一種物質爲礦 油。礦油(亦稱液態礦脂)係石油内高沸點(即3〇〇。_ 39(rc. 館份态得的多種液烴之混合物。礦油在常溫如2 〇。_ 2 5 馬液體。因此即使塗敷於尿布頂片時亦係流體而較活動。 4 - (請先閱讀背而之注意事項再填寫本f)
木.錄尺度朗 家縣(CNs')~W^( 21〇Χ2';7^Ι-' 經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(2 ) 礦油因在常溫係流體活動故不易保持局限於頂片表面而 知過頂片入尿布内邵。於是須要塗敷較高度礦油於頂片以 供應所須治療或保護塗層洗劑利益。如此不僅導致此等加 洗劑的尿片製品增加成本,亦有其他不利影響。 此等不利影響之一爲高度礦油易堵塞頂片孔隙而降低流 體處理性質。褒油曼進尿片内部’易於作用成疏水^ 加劑,若其下方用吸收芯時逐減少其吸收能力。礦油塗熬 量加多時吸收能力上此項降低將更顯著。 ’ 縱不增加用量’礦油一旦塗敷即有其他不利影響。舉例 所塗礦油能移轉進入並通過加洗劑尿片產品的包裹或封裝 材料。於是產生障壁型包裹或封裝膜之需 片製品中塗污或其他淺漏。 、自尿 ,此可能要求提供帶洗劑的尿片製品:⑴具所須治療或 保遵塗覆洗劑的利益;⑵不必要高度室溫時呈液態(如礦油 的塗層、⑶對尿片製品的吸收能力無不利影響;及⑷矣須 特殊包裹或封裝之障護材料。 ....... 美國專利3,585,998中海福特(Hayf〇rd)等指出一種可棄式嬰 :尿片,其内襯附帶_排含婴兒油的能壓碎膠囊。其專利 用則s用家庭用具如旋轉銷、手熨斗等施壓破 =囊。加壓能破的膠囊同一原理在戈得發(Goldfard)等美 =3的4Γ,413内用以製作能投送藥物至傷處之端帶。二專 刊揭TF的物侔路古 S3 ‘ Τ 施壓破壞膠囊:囊::缺陷。即除非使用尿片或端帶前 f ^濩膚物質或者根本不交遞或者移 运不均勾而遺留某些皮膚區域未塗覆。 Μ U U) 乂 297公釐) {請先閲讀背面之注意事項再填寫本頁}
B7 五、發明説明(3 ) 不哈特(Buchalter)之美國專利3 896 8〇7指出一種以固態y 相乳油配方浸清的物件其上添加水分後形成乳膏。此資剩 所透珞物件之主要缺點爲有益物質自吸收底質至皮膚之移 轉經遲延而僅於釋出體液時實現。 鄧肯(Duncan)等的美國專利3 489 148指出一種含一疏水及 由的頂片之嬰兒尿片,其中一部分頂片塗覆不連續的含 油物質膜。鄧肯等資料内發表尿片之主要缺點爲疏水與疏 油頂片推動尿液至其下方吸收芯之移轉緩慢。 因此本發明疋目的在提供有優越流體輸送性質的親水頂 片之可棄式尿片。 :發明另-目的在提供頂片外表面上有洗劑塗層之親水 ,布,片能移轉洗劑至穿者的皮膚而有效減輕峨附著於皮 膚,楮以改進使B Μ易於清除。 本發明又-目的可望貢獻加洗劑的尿片製品:⑴有適宜 脱、清除 '治療或保護的洗劑塗層利益;⑵不須相各 南农度的礦油;⑶對尿片的流體輸送性質無不利Ί ⑷不須要包裝用特殊封裹或障壁材料。 抑, 用本發明達致此等與其他標 彰顯。 知於閲印以下發表後將易於 經濟部中央標準局員工消費合作杜印製 發明之概要 本發明係關-種可棄式尿片,其 劑塗層在常溫(即2。。〇時爲半固體或固*:,=上有-者的皮膚,作心減少㈣附著於穿〜膚1移轉至
又h 楮改吾B IV 太紙:尺度適用中國國家操準( ) Λ4規格(2ΐ〇χ 297‘Γ^ 6 - 經濟部中央標準扃員工消费4作社印裝 A7 B7 五、發明説明.(4 ) 於清除。 簡言之,本發明可棄式尿片含: ㈧一不透液體的背片; (B) —透液體的親水頂片連接該背片,該頂片有一朝向該尿 片内部的内表面與穿著該尿片時朝向穿者皮膚之外表面 ,其中孩頂片外表面的至少一部分含有效量之洗劑塗層 於2 0 C時係半固態或固體,且部分能轉移至穿者皮膚, 該洗劑塗層包括: (〇自約1 0至約9 5 %的實質無水潤膚劑,2 〇»c時有柔軟 或流體稠度,含有選自石油基潤膚劑、脂肪酸酯潤膚 劑、烷基乙氧酯潤膚劑、聚矽氧烷潤膚劑,及其混合 物等; ' 口 (11)自約5至約90%之用劑能固定該潤膚劑於頂片的該外 表面上’該固定劑有至少約3 5。匸之熔點;及 (C) 一吸收芯位於該頂片與該背片之間。 本發明尿布頂片的至少一部分上洗劑塗層量範圍宜自約 0.1 mg/in2至約25 mg/in2,較佳自約i mg/in2至約叫如2。 根據本發明之帶洗劑尿布頂片提供所須BM清除、治療或 保護洗劑塗層利益。由於潤膚劑實質固定於頂片表面,須 要較少洗劑組合物給予所須皮膚保護利益。而且包裝本發 明帶洗劑的尿片製品時不必要特殊障壁或封裹材料。 後文將討論本發明洗劑組合物宜有熔點分佈使其於室溫 時比較固定而集中在巷布頂片上,能於體溫時移轉予穿= 但在非常貯存情況下_仍非完全液體。! -7· ( CNS ) Λ4^ I 2!OX 297^:¾ ) (請先閱讀背面之注意事項再填转本頁)
AT AT 經濟部中央標準局員工消費合作社印製 五、發明説明( 要點爲本發明洗劑组合物經常能 吊恐接觸、穿者動作及/哎 姐溫易#轉至皮膚。不受理論約束、 相彳s洗劑組合物改變 皮膚的表面能量及/或形成"障壁,,而降低BM2皮膚親 力。因此B Μ對皮膚降低黏著傾向而較易脱除。 圖之簡述 圖1爲一示意描繪説明塗敷本發明洗劑組合物於尿 片之較佳方法。 〃 圖2爲一示意描繪説明塗敷本發明洗劑组合物於尿布頂 片之另一方法。 圖3係根據本發明尿片形式之—種吸收物件。 發明之詳細説明 又内使用"包含"一辭意謂各種组份、成分、或步驟能此 同採用以實現本發明。因此"包含"之辭涵蓋較狹義的用語 "主要組成"及"組成··。 文内所用一切百分率、比率與比例除另行指定外均係重 量計。 A.吸收物件 文内用吸收物件之辭指吸收並容留身體分泌液之裝置 ,更明確言之指放置靠穿者皮膚以吸收並容留由身體排出 的各種分泌液之裝置。”可棄式"一辭在文内用以說明吸收 物件一次使用後不計劃經洗濯或別的方式復原或再作吸收 -8- 本呔張尺度適用中國S家標隼(CNS ) A4規格(21ϋΧ29/公缓) (請先閱讀背面之注意事項再填寫本筲) 訂 2^^22e
五、發明説明( 頂 棄 經濟部中央標準局員工消費合作社印製 物件用。可棄式吸收物件實例包括婦女衛生衣著如衛生棉 與短褲襯、尿片、&禁短褲、尿片夾、及訓練短褲之類。 可棄式吸收物件典型含—透液體頂片、連接頂片的不透 液3片#卩居頂片及背片間之吸收芯。可棄式吸收物 件及其組件等包括頂>t、背片 '吸收芯與此等組件之一切 個別層均有一身體面與-衣服面。文内所用"身體面"意謂 預備穿著朝向或鄰近穿者身體的物件或組件之表面,而" 衣服面"係在反面預備於穿著可棄式吸收物件時朝向或鄰 近穿者的内衣。 以下説明大概討論可棄式吸收物件中適用的吸收芯、 片與背片材料。須知此概述除適用於文内概述的其他可采 式吸收物件外,更及於後文說明圖3所示特定吸收物件組件 吸收芯一般能吸收或保持液體(如月經、尿與/或其他身體 分泌液)。吸收芯宜能壓縮、能順應並不刺激穿者皮膚。吸 收芯可製成多種大小與形狀(如矩形、印形、砂漏、"τ"形 '犬骨、不料等)。㈣發明吸收複合物外吸收芯可含多 種中任-種吸收物件内通用之液體.吸收材料如粉碎木漿通 常稱作氣鋪…及收芯内所用其他適宜吸收材料實例包括皺 纖維素填料;溶吹聚合物包括共成㈣;化學強化、改良 或交聯的纖維素纖維;合成纖維如捲縮的聚g§纖維;泥煤 苔:薄紙包括薄包裹紙與薄紙#$;吸收泡沫:吸收海綿 :超吸收聚合物;吸收膠凝材料;或任何同類材料或材料 之組合’或此等混合物。 本紙張尺度適片1中國國家橾隼(CNS ) Λ4規格(210 X29·:. ---- (請先閱讀背1&之注意事項再填寫本筲)
經濟部中央螵準局6貝工消費合作衽印製 帶態與構造亦可變化(例如吸收芯可有變異厚廣 S刀P使中央車父厚:親水梯度;本發明吸 度,超吸收劑梯彦.式把τ t 反口物梯 度,或低平均密度及低平均基重帶,例如 攝取帶寺:或者可含—層或多層或。但 收能量應配合設計g丼„ „ 〜成 ^ f,、何及吸收物件之預計用途。此外、吸 收〜之大j與吸收能量可變動以配合不同用途如尿片' 禁整、短褲襯、正規的衛生棉及過夜衛生棉,並適應自幼 兒至成人範圍穿者。 吸收芯能含吸收物件中常用的其他吸收組件,例如撒粉 層、芯吸或攝取層’或輔助頂片以增加穿者舒適。 頂片宜順應、柔感且對穿者皮膚無刺激性。而且頂片能 透液體,容許液體(如月經與/或尿)順利渗穿其厚度。適用 頂片可由廣範圍材料製造如織造或非織材料(如非織的纖維 網構);聚合材料如穿孔成形熱塑膜,穿孔塑膠膜及加氣重 整的熱塑膜;多孔泡沫’·網狀泡沫;網狀熱塑M;及熱塑 襯布等。適宜織造與非織材料能由天然纖維(如木材或棉纖 維),合成纖維(如聚合物纖維如聚酯、聚丙烯或聚乙烯纖 維)或由天然與合成纖維合併組成,頂片含非織網構時網構 可用許多已知技術製造。舉例、網構可係噴絲結合'杭毛 、濕鋪、溶吹、水力糾纏,及以上组合等。 背片不透液體(如月經與/或尿),雖亦可用其他柔勒不透 液材料製造,但以薄塑膠膜爲佳。文内用"柔勒"之辭指材 料順應且能輕易適合人體的一般形狀與曲線。背片防止吸 收芯内所吸收與容納的分泌液弄濕接觸吸收物件的物件如 -10- 本A張尺度適用t國國家標準(CNS)A4規格(2丨公釐) (-•tT先S?讀背而之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 29822β at ~ _Β7 五、發明説明(8 ) 床單、短褲、睡衣及内衣等。背片因此可含織造或非織材 料’聚合物膜如聚乙烯或聚丙晞之熱塑膜,或複合材料如 膜覆的非織材料。適宜背片爲厚度自約〇 〇12 mm (〇 5爪⑴至 約0.051 mm (2.0 mil)之聚乙晞膜。模範聚乙晞膜係俄亥俄州 新新那提之Clopay公司製P18-1401與印第安那州Terre Haute 之屈第加Tredegar膜產品的XP-39385。背片宜經壓紋及/或複 光處理製成較似布外觀。另外,背片可容蒸汽逸出吸收芯( 即背片能呼吸)同時仍阻止分泌液通過背片。背片大小由所 選吸收芯的大小與正確吸收物件設計決定。 背片與頂片位置分別鄰近吸收芯的衣服面及身體面。吸 收芯宜以附件機構已知的任何方式與頂片、背片或二者連 接(圖3中未繪出)。但想像本發明之具體例其中全部吸收芯 的各部分不歸屬頂片、背片或二者。 舉例、背片與/或頂片可固定於吸收芯或用均勻連續膠 黏層、圖案膠黏層或分離的膠黏劑線、螺線或斑點排列相 互固疋。已發現滿意的膠黏劑爲明尼蘇達州聖保祿富勒公 司(118111以1'(:〇.)製之肛-1258或小2031。附件機構較佳含 一種膠黏劑纖絲之開放圖案網絡如1986年3月4日頒予明尼 陀拉(Minetola)等之美國專利4,573,986,本文引用參考。開 放圖案的纖絲網絡之一標準附件機構含幾條膠黏纖絲蝸捲 成螺旋圖案如1975年10月7日頒予小史普雷格(Sprague,Jr)之 美國專利3,911,173 ; 1978年11月22日頌予渠克(zwieker)等之 美國專利4,785,996 ;及I%9年6月27日頒予魏命尺茨 (Werenicz)之美國專利4,842,666中表現的設備與方法。各專 -11 - 本紙浪尺度i?.用中國國家標準(CNS〉A.4現格(2丨0 X 297公楚) (請先閒讀背而之注意事項再填寫本頁)
經濟部中夬標準局員工消費合作社印製 A7 B7 五、發明説明(9 ) 利在此引用參考。或者附件機構可包括加熱結合、加壓結 合、超音波結合、動力機械結合、或任何其他適宜附件機 構或此等技術上所知的附屬機構合併。 其中可用本發明帶洗劑頂片之較佳可棄式吸收物件爲尿 片。文内所用"尿片"之辭指一種通常由嬰兒與失禁人在穿 者較低軀幹周圍穿著的吸收物件。換言之"尿片辭包括 嬰兒尿片、訓練短褲及成人失禁裝置等。 圖3爲本發明尿片5〇於其攤開無收縮狀態(即拔出彈性誘 起的收縮)之平面圖,部分結構切除以更清楚顯示尿片分 <結構’自穿者朝外的尿片50部分即外表面定向對閱者。 如圖3所tf尿片宜包括一透液體頂片52〇 不透液體的背 片530與頂片52〇連接;一吸收芯54〇位居頂片52〇與背片5邛 之間,吸收芯54〇有朝衣服面M2,朝身體面5料,側邊5牝 ’腰邊548,與耳549。尿片50宜另含鬆緊腿褶55〇 ;彈性腰 邵特徵多層稱作560 ;與一稱作57〇一般多重的繫結系統。 圖3内所不尿片50有外表面52,第一腰區56,第二腰區μ =外緣51由尿片5G之外邊界定,其中縱邊稱料而端邊 稱爲57。(熟練技工可認知尿片普通用辭説明有一對腰區 及腰區中間之腿叉區,本申請書中爲簡化名詞説明尿片二 僅有腰區包括一部分尿片典型可稱爲腿又區部分)。尿 的内表面54包括尿片50在使用期間放置 Π(即内表面54-般由頂片-的至少-部分及其 :=520的組件形成)。外表面52包括位置離開 胆的尿片50部分(即外表面52_般由背片53〇之至少一部分 4、紙張尺度適用中國國家標準(CNS ) (請先閱讀背面之注意事項再填寫本I}
經濟部中央標準局員工消費合作社印裝 A7 -------- 五、發明説明(10) ~ ~ 及其他可連接至背片530的組件形成)。(文内所用尿片5岬 分或其面對穿者之組件亦稱作朝身體表面。同樣朝向離開 穿者的邵分文内亦稱作朝衣服面。)第—腰區56及第二腰 區58分別自外緣51的端邊57延伸至尿片5〇之橫中線”。圖3 亦顯示縱中線59。 圖3表現尿片50之較佳具體例,其中頂片52〇及背片有 長度及寬度尺寸一般大於吸收芯54〇者。鬆緊腿褶55〇及背 片530伸出吸收芯540邊外於是形成尿片%的外緣51。 本發明尿片能有許多熟知形態,其吸收芯配合本發明。 標準形態大致説明見1975年1月14日頒予畢耳(Buell)之美國 專利3,860,003 ; 1992年9月29曰頒予畢耳之美國專利 5’151,〇92 ’ 1993年6月22日頒予畢耳等的美國專利5 221 274 。文内引用此等各專利參考。本發明能順利適應之另一尿 片形態説明見1994年2月28日提出的待審美國專利申請案 〇8/203,456號,文内引用參考。此等專利内所述尿片的吸收 心Bt*按文内指示配合本發明含吸收複合物作其中所述之吸 收膠凝材料。 尿片50内特別適用的頂片520用紡織界技術者週知的梳 毛及加熱結合。本發明完善的頂片含丁尼爾約2 2之定長 聚丙烯纖維。此處所用,,定長纖維”之辭係指其纖維有至少 約15.9 mm (0.625吋)之長度。頂片宜有每方公尺約14至約乃 公克的基重。一種適當頂片爲麻州瓦波耳國際紙公司分支 Veratec Inc.製之 P-8。 尿片50的頂片520宜用親水材料製以促進液體(如展)快速 _______13- 本紙張尺度適用中國國家標準(CNS ) A4規格(2!0X^7公慶) (請先閱讀背面之注意事項再填寫本頁) 訂
A 經濟部中央標準局員工消費合作社印製 A7 _____B7 五、發明説明(11 ) 移過頂片。若頂片係疏水材料製,至少頂片之最上表面經 處理成親水使液體犯較快移過頂片。於是減少身體分泌液 流出頂片而不吸經頂片被吸收芯吸收之可能。頂片能以界 面活性劑處理使其親水。用界面活化劑處理頂片之適宜方 法包括以界面活化劑喷霧頂片材料及將材料浸入界面活化 劑内。此項處理與疏水性之更詳討論包含在丨991年丨月29 曰頒予雷新(Reising)等題爲’,有多層吸收層的吸收物件,,之美 國專利4,988,344 ;及1991年1月29日頒予雷新題爲"有快速 攝取吸收芯的吸收物件",文内引用各專利參考。 文内所述尿片一較佳具體例内背片530有一改良砂漏形 伸出吸收芯外圍繞整體尿片邊緣約1.3 cm至約6.4 cm(約0.5 至約2.5吋)之最低距離。 吸收芯540可採取能與尿片50相容的任何大小或形狀。尿 片50之一較佳具體例有一不對稱改良T_形吸收芯54〇 ,其第 一腰區内有耳,但第二腰區中一般成矩形。本發明已獲廣 泛接受及商業成功作吸收芯用之標準吸收結構,説明見 1986年9月9日頒予韋司曼(Weisman)等題爲"高密度吸收結構 "的美國專利4,610,678 ; 1987年6月16曰頒予韋司曼等題爲" 有雙層芯的吸收物件••之美國專利4,673,402 ; 1989年12月19 曰頒予安斯達(Angstadt)题爲,,有撒粉層的吸收芯"之美國專 利4,888,231 ;及1989年5月30日頒予奥厘滿尼(Alemany)等題 爲"有低密度低基重攝取帶的高密度吸收構件"之美國專利 4,834,735。吸收芯可在吸收貯存芯上設置另一種含化學強 化纖維的攝取/分配芯之雙重芯系統,如1993年8月10日頒 ________-14- 本紙張尺度適用中國國家樣:隼(CNS ) A4規格(2丨0'/ 297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 屢! 經濟部中央樣準局員工消費合作杜印製 15- A7 B7 五、發明説明(l2 ) 予奥厘滿尼等題爲"有彈性腰邵特色與加強吸收本領的吸 收物件|,之美國專利5,234,423 ;及1992年9月15日頒予楊等 (Young,Lavon & Taylor)題爲"失禁處理用高效吸收物件,,之美 國專利5,147,345。此等專利皆在此引用參考。 一較佳具體例中尿片50又含鬆緊腿褶55〇提供液體及其 他身體分泌液之改善圍堵;一彈性腰部特徵56〇提供改良 貼身與圍堵;及一繫結系統570形成側封保持第一腰區% 與第二腰區58成重疊形態使尿片周邊保留橫向張力保持尿 片於穿者上。尿片50亦可含鬆緊側片(未繪出)在腰區56與 58内製備能彈性伸張的特色提供尿片5〇更舒適及輪廓貼合 與更有效運用。 ° 鬆緊腿稽550能構造成許多不同形態包括仍專利 3,86〇,〇〇3號;1"0年3月20日頒予阿濟茲(Αζιζ)等的美國專 利4,9〇9,8〇3號;1987年9月22日頒予勞生(Uws〇n)的美國專 利4,695,278號;及1989年1月3日頒予厥拉戈(以叫〇〇)的美國 4,795,454號内説明者:各在文内引用參考。 鬆緊腰部特徵宜含一鬆緊腰帶(未繪出),可構成許多不 同形態包括1985年5月7日頒予祁維(Kievit)等的美國專利 4,515,595號;!991年6月25日射羅勃生(R〇ber_)的美國 專利5,026,364號;及前引資料1992年9月29日頒予畢耳等的 美國專利5,151,092號中所説明者,此等各資料均引用參考 〇 鬆緊側條片可構成許多形態。尿片的耳(耳翼)内設置鬆 緊側片的尿片實㈣表在⑼9年8月丨5日頒予伍德(w〇〇d)等 木紙張尺度適用中國國家標準(CNS )戍4規格(2丨〇^7^" (請先閱讀背面之注意事項再填寫本頁) -訂 Λ ! 經濟部中央標準局負工消費合作杜印裝 A7 B7 五、發明説明(l3 ) 的美國專利4,857,067號;1983年5月3日頒予夏拉法(Sciaraffa) 等的美國專利4,381,781號;1990年7月3日頒予范岡沛(Van
Gompel)等的美國專利4,938,753號;與1992年9月29日頒予畢 耳(Buell)等的美國專利5,151,092號内;各在此引用參考。 標準繫結系統570發表在1989年7月11曰頒予史克力 (8〇1^?8)的美國專利4,846,815號;1990年1月16日頒予内思 特軋(Nestegard)的美國專利4,894,060號;1990年8月7日頒予 巴屈耳(Battrell)的美國專利4,946,527號;1974年11月19曰頒 予畢耳的美國專利3,848 594號;1987年5月5曰頒予廣津 (Hirotsu)的美國專利B1 4,662,875號;及1992年9月29日頒予 畢耳等之美國專利5,151,092號等内;文内引用各專利參考 〇 尿片50用於穿者宜將尿片的腰區之一較佳第二脹區咒放 在穿者背下,尿片其餘部分拉在穿者腿間使另—腰區較佳 第一腰區56放置越過穿者正面。随後運用繫結系統完成側 封。 本發明加洗劑的頂片亦適用於訓練短褲。文内所用,,訓 練短褲"係指有固定側邊與腿孔的可棄式衣裳。訓練短褲 在穿者上放置位置係將穿者的腿插進腿孔,滑動訓練短褲 進入靠穿者下部軀幹就位。適當訓練短褲發表在1993年9 月2丨曰頒予哈西(Hasse)等的美國專利5,246,433號内。 適用本發明加洗劑頂片的另一可棄式吸收物件爲失禁物 件。’•失禁物件"一辭指襯墊、貼身衣(由同一型懸吊系統如 帶子類定位之襯墊等),吸收物件之插入物,吸收物件之 (請先閱讀背面之注意事項再填寫本頁) 訂 4! 私紙張尺度和fifi家標準(,CNS) 16- (210X297公釐) A7 ___ B7 五、發明説明(Μ ) 容量增補器、短褲、床墊及不管由成人或其他失禁人穿著 之類。適宜失禁物件發表在1981年3月3日頒予史屈克命 (Strickland)等的美國專利4,253,461號;頒予畢耳的美國專利 4,597,760與4,597,761 ;前述美國專利4,704,115 ;頒予艾爾 (Ahr)等的美國專利4,9〇9,8〇2號:1990年10月2;3曰頒予吉卜 生(Gipson)的美國專利4,964,860 ;及1991年1月3日諾耳(Noel) 等提出的美國專利申請案07/637,090號(PCT刊物1992年1月 23日出版的WO 92/11830號)。 B .洗劑組合物 本發明洗劑組合物在2 0。(:即室溫時爲固體或較常半固態 。”半固態”意謂洗劑組合物有假塑性或塑性流體之典型流 動性。不施剪力時洗劑組合物能有半固態外觀,但當增高 剪率時能使之流動。此乃由於事實上洗劑組合物雖主要含 固態組份’其中亦含若干次要液態組份。 本發明洗劑組合物在室溫至少爲半固態以減少洗劑移動 。而且洗劑組合物宜有最後熔點(丨0 0 %液體)在可能"充 壓"貯存條件以上能高於4 5。(:(例如在亞里桑那倉庫及佛 維里達車廂等)。明確言之本發明洗劑組合物應有如下炫 (請先閱讀背面之注意事項再填寫本萸) 訂 Λ! 經濟部中央標隼局貝工消費合作社印製 點分佈: 特徵 較佳範圍 最好 室溫(20°C )時液體% 2-50 3-25 體溫(37°C)時液體% 25-95 30-90 最後熔點(°C ) ^ 38 s 45 ** -17- 本紙張尺度適用中國國家標準(CNS ) A4規格(2!0:< 297公釐) • J— 經濟部中央標準局員工消费合作社印製 A7 五、發明説~ ' 由於玄溫時爲固體或半固體,此等洗劑組合物並無越向 流動及移徒入其所塗尿布頂片内部。如此意謂需要較少洗 劑組合物賦予期望的治療或保護塗層洗劑利益。 本發明洗劑組合物塗敷於尿布頂片的外表面時能經正常 接觸、穿者動作及/或體溫轉移至穿者皮膚。本發明揭示 (洗劑重量在減少B Μ附著於穿者皮膚從而改善易於清除 ΒΜ。 ‘、 本發明尿布頂片含有效量的洗劑組合物。文内所用"有 效量洗劑塗層之辭指特別洗劑組合物量塗敷於尿布頂片時 能有效減少Β Μ附著於穿者皮膚《當然洗劑塗層之有效量 極大程度須視所用明確洗劑组合物定奪。 本發明的洗劑組合物含:⑴一種潤膚劑(等);⑵潤膚劑 之固足劑(等);⑶随意地親水性界面活化劑(等);及⑷其 他隨意組份等。 配方的洗劑组合物包括潤膚劑、固定劑、與随意組份之 黏度應儘可能高以保持洗劑不流進尿片内部。不幸,高黏 度亦能導致洗劑組合物難以塗敷而無處理問題。因此務必 獲得平衡使黏度之高足以保持洗劑組合物局限於尿布頂片 表面,但不過高致發生加工困難。6(rc時測量洗劑組合物 之適宜黏度典型範圍自約5至約2 0 〇厘泊,較佳自約t 5至 約1 0 0厘泊。 1 .潤膚劑 此等洗劑組合物内關鍵活性成分爲—種或數種潤膚劑。 -13
本纸珉尺度適用中國國家橾準(CNS ) A4規格(210/297公釐I f請先閲讀背面之注意事項再填寫本頁) *•11 五、發明説明() 此處所用潤膚劑係柔化、撫慰、順從、泠帝 愛覆、潤滑、渴潤 或洗淨皮膚的物質。一種潤膚劑典型達成 一热阀 撫慰 '濕潤與潤滑皮膚。本發明用涂夕lU μ, $ 。 、此等潤膚劑於2 0 c即室内溫度有柔軟或流體稠度。此特殊 ' 组合物得以賦予柔軟光滑的似洗劑感覺。 ^ 本發明適用的潤膚劑實質上亦不含水。所謂"實質上益 水”意指不蓄意加水於潤膚劑。製備或使用本^明二 合物時不必加水於潤膚劑且需要外加乾燥步驟。不過由例 如周圍濕度結果吸取在潤膚劑中之少量或痕量水分能容忍 而無不利影響。本發明内所用潤膚劑典型含約5〇/。以下之 水,較佳約1%以下水,最好約0.5%以下之水。 本發明適用之潤膚劑可係石油基的脂防酸醋型、院基乙 氧酯型、脂肪酸酯乙氧酯、脂肪族醇型、聚矽氧烷型、或 此等潤膚劑之混合物。適用石油基潤膚劑包括鏈長自t 6 至3 2碳原子的鏈烴類或鏈烴混合物等。有此等鏈長的石 油基鏈烴包括礦油(亦稱"液體礦脂")及礦脂(亦稱"地蠟" ’石油/東"與”礦物凉’’)。礦油泛指含1 6至2 0個碳原子键 fe之黏性較低混合物。礦脂常指含1 6至3 2個碳原子鏈熳 的較黏混合物。礦脂與礦油爲本發明洗劑組合物之特佳潤 經濟部中央標準局員工消費合作社印裝 膚劑。 適宜脂肪酸酯型潤膚劑包括自C12-c28脂肪酸、較佳cl6-C:22飽和脂肪酸與短鏈(CpCg,較佳crC3)單羥醇類衍生着 。此項酯類之代表實例包括十六烷酸甲酯、十八烷酸甲酯 、十一坑酸異丙酯、十四燒•酸異丙酯、十六燒酸異丙酯、 -19 本紙年尺度適用中國國家標準(CNS) A4規格(210x 經濟部中央標準局員工消費合作社印製 A7 ____B7 五、發明説明(l7 ) 十六燒酸乙基己醋及其混合物等。適宜脂肪酸酯潤膚劑亦 月匕自較長鏈醇(CfC^8、較佳c12-c16)與較短鏈脂肪酸如乳 酸之酯類如乳酸十二烷酯及乳酸十六境醋。' 適宜燒基乙氧醋型潤膚劑包括有約2至約3〇平均乙氧化 耘度之C i2_C22脂肪族醇乙氧酯。較佳脂肪醇乙氧酯潤膚劑 係選自平均乙氧化程度範圍自約2至約23的十二烷基、十 六燒基及十八烷基乙氧酯與其混合物等。此等烷基乙氧酯 (代表例包括laureth-3(平均乙氧化程度3之十二烷基乙氧 醋)’ laureth-23(平均乙氧化程度23之十二烷基乙氧酯), ceteth-l〇(平均乙氧化程度1〇之十六烷醇乙氧酯)及咖似心 10(平均乙氧化程度1〇之十八烷醇乙氧酯此等烷基乙氧 醋潤膚劑典型與石油基潤膚劑如礦脂合併使用,烷基乙氧 酉曰谓膚劑對石油基潤膚劑之重量比自约1 : 1至約1 : 5,較 佳自約1 : 2至約1 : 4。 適宜脂防醇型潤膚劑包括c12-c22脂肪醇,較佳(:16-(:18脂 肪醇。代表性例包括十六烷醇、十八烷醇及其混合物等。 此等脂膀酸潤膚劑典型與石油基潤膚劑如礦脂合併使用, 脂肪醇潤摩劑對石油基潤膚劑之重量比自約1 : 1至約1 : 5 ’較佳自约1 : 1至約1 : 2。 本發明用之其他適宜型潤膚劑包括聚矽氧烷化合物。本 發月用適立聚秒氧燒物質一般包括其有以下結構的單體石夕 氧纪單位者: (請先閱讀背面之注意事項再填寫本頁) 訂 Λ s992S6 A7 B7 五、發明説明(18 ) ⑴ -Si- 〇 經濟部中央標準局員工消費合作社印製 I R2 式内各獨立矽氧烷單體單位之心及心能自由係氫或任—烷 基万基、烯基、烷芳基、芳烷基、環烷基、画化烴或其 他,團。任何此等基團能經取代或未取代。任何特別單體 型單位的\與&基團可與次一毗鄰的單體單位相當官能度 不同。此外、聚矽氧烷能隨意爲直鏈、支鏈或有環狀結構 。基團尺丨與&能另係獨立的其他含矽官能基例如但非限於 矽氧烷、聚矽氧烷、矽烷及聚矽烷。基團心與心可含多種 有機T能基之任一種包括例如醇、羧酸、苯基及胺官能基 〇 標準燒基團爲甲、乙、丙、丁、戊、己、辛、癸及十八 ’烷基等。標準晞基團爲乙烯基及烯丙基等。標準芳基團爲 苯、聯苯、及莕基之類。標準烷芳基團爲甲苯基、二甲苯 基及乙苯基之類。標準芳烷基圏爲苄基、苯乙基、点_ 苯乙基及苯丁基之類。標準環烷基團爲環丁、環戊及 環己等基。標準鹵化烴基團爲氣曱、溴乙、四氟乙 '氟乙 、三氟乙、三氟甲苯、六氟二甲苯基之類。 適用聚矽氧烷的黏度可大致如聚矽氧烷之黏度同樣廣泛 變化’衹要聚矽氧烷能流動或能使其流動供塗敷於尿布頂 片。此黏度包括但不限於低至5厘泊(37°C時用玻璃黏度計 測量)至約20,〇〇〇,〇〇〇厘泊。聚矽氧烷在37。(3宜有黏度範圍 -21 - 私紙張尺度適用中國國家樣丰(CNS〉Α4规格(2i〇X297公釐) (請先閲讀背面之注意事項再填寫本頁) 訂 -為! 1. 經濟部中央標準局貝工消費合作社印製 A7 五、發明説明(l9 ) 自約5至約5,000厘泊,較佳自約5至約2,_厘泊,最好自約 1〇〇至約麵厘泊。高黏度聚秒氧燒本身抗拒流動者能用 各種万法附著於尿布頂片例如將聚矽氧烷乳化於界面活化 劑内或藉溶劑如己烷之助製成聚矽氧烷溶液提供,列舉僅 作不範用。塗敷聚矽氧烷潤膚劑於尿布頂片之特別方法後 文更詳研討。 本發明所用較佳聚矽氧烷化合物發表在1991年1〇月22日 頒予安波斯基(Ampulski)等的美國專利5 059 282内,此處引 用參考。本發明洗劑組合物中作潤膚劑用之特佳聚矽氧烷 化合物包括苯官能性聚甲基矽氧烷化合物(例如道康寧556 化妝品級流體:聚苯基甲基矽氧烷)及十六烷或十八烷基 二甲碎_ (dimethicones)分別如Dow 2502及Dow 2503聚矽氧烷 流•體。除用苯官能或燒基之此項取代作用外、可用胺基、 羧基、羥基、醚、聚醚、醛、酮、醯胺、酯及硫醇基作有 效取代。此等有效取代基群中含苯基、胺基、烷基、羧基 及經基族比其他更佳;以苯官能基最好。 除石油基潤膚劑、脂肪酸S旨潤膚劑、脂肪酸S旨乙氧能潤 膚劑、烷棊乙氧酯潤膚劑、脂肪醇潤膚劑及聚矽氧烷外, 本發明適用的潤膚劑能含少量(例如最多總計潤膚劑之約 10%)其他習用潤膚劑。此等其他習用潤膚劑包括丙二醇、 甘油、三甘醇、鯨墩或其他蝮、脂肪酸、及脂肪鏈内有12 至2 8碳原子的脂肪醇酸等,如十八燒酸、丙氧化脂肪醇: 甘油酯 '乙醯甘油酯及(:12-(:28脂肪酸之乙氧化甘油酯,多 羥基醇之其他脂肪酯;羊毛脂及其衍生物等。此等其他潤 -22- 本紙張又度適用中國國家榡準cNsTA4^i«- ( 2!0X29?公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 Λ 經濟部中央樣準局負工消費合作社印製 A7 -------B7 五、發明説明(2〇 ) 膚劑應以一種方式包含使保持洗劑組合物之固態或半固態 特徵。 洗劑組合物中能含的潤膚劑量將視多種因素而定,包括 1 ^特殊潤膚劑,所期似洗劑利益,洗劑組合物内其他組 伤等颏因素。洗劑組合物能含約丨〇至約9 5 y❶之潤膚劑。 較佳洗劑組合物含約2 〇至約8 〇 %,最好約4 〇至約7 5 %之 潤膚劑。 2 :固定劑 本發明洗劑組合物之特別重要组份爲能在其塗敷的洗劑 組合物的尿布頂片上使潤膚劑固定之用劑。因爲組合物内 捫膚μ〗在2 0 C時有柔軟或泥體稠度,縱受輕微剪力亦易 流動或私徙。塗敷於尿布頂片、尤其呈軟化或溶融狀態時 潤膚劑將不主要留在頂片表面上而潤膚劑將易移動流入尿 布的内部。 潤膚劑如此移動入尿片内部由於本發明洗劑組合物中所 用"午夕/閏膚劑之疏水特性能引起對尿片芯吸收本領上不良 影響。亦即意謂必須在尿布頂片塗敷更多潤膚劑俾得所期 盼的療效或護膚洗劑利益。提高潤膚劑量不僅加多成本, 且亦惡化對尿片芯吸收本領之不良影響。 固疋劑藉保持護膚劑主要局限於塗敷洗劑組合物的尿布 頂片表面上而抵消護膚劑移徒或流動之此趨勢。此點相信 邛刀係由於固定劑提升洗劑組合物熔點高過護膚劑熔點之 事實。因爲固定劑亦能與潤膚劑溶混(或藉助特定乳化劑 本紙張尺(刺巾家縣(CNS ; Λ4^Τ1Τ〇χΐ97^»7 (请先Μ讀背面之注意事項存填寫本頁) 訂 典!
五、發明説明(21) 而増落於護膚劑中)’亦捕促潤膚劑在尿布頂片表面上 鎖疋固疋劑在尿布頂片表面上亦有利。如此可用在頂 片面上快速結晶(即凝固)的固定劑達成。此外已處理的尿 布頂片經鼓風機'風扇等外在冷卻能加速固定劑之結晶作 用。 除旎與(或増溶於)潤膚劑溶混外、固定劑須有熔點至少 ’”勺3 5 C如此可使固足劑本身無移徒或流動之趨向。較佳 固定劑有熔點至少約4(rc。固定劑典型可有熔點在約5〇。 至約150°C之範圍内。 本發明的適當固定劑能含—種選自CwCu脂肪族醇、 circ:22脂肪酸,有平均乙氧化程度範圍自2至約3〇的 脂族醇乙^酯、及其混合物等之份子。較佳固定劑包括 C16 曰知醇,最好選自十六燒醇、十八燒醇,與其;昆合 物等。十六烷醇與十八烷醇的混合物特佳。其他較佳固定 佳包括Cw-C^8脂肪酸,最好選自十六烷酸、十八烷酸、及 其混合物等。十六烷酸與十八烷酸的混合物特佳。尚有其 他較佳,定劑包^括有平均乙氧化程度範圍自約5至約2〇的 Cl6-Cl8〗曰族醇乙氧酯。脂族醇、脂肪酸爲直鏈較佳。 此等較佳固疋劑如c w c 18脂族醇重大增加洗劑結晶速 度使洗劑快速結晶在底質表面上。因此能用較低洗劑量或 者能給予更高超的洗劑觸覺。慣例必要較大量洗劑產生柔 性’由於此等液體流進尿片芯。 其他土固足劑把随意單獨或與前述脂族醇脂肪酸及脂族 醇乙氧酯合併使用。此等其他型固定劑實例包括多羥基脂 ----τ'---—----- - 24 - 本紙張尺度遗用中國國家樣準(CNS ) A4j£i7Ti〇^297^^ )----- (請先閱讀背面之注意事項再填寫本頁) 、1Τ 典 經濟部中央標準局員工消費合作社印製 A7 A7 經濟部中夬標準局員工消費合作社印製 _____B7_ 五、發明説明(22 ) 肪酸酯多羥基脂肪酸醯胺及其混合物等。較佳酯及醯胺之 多#空基部分上可有三個以上自由經基,典型非離子性。因 爲使用其他塗敷洗劑組合物的尿布頂片之可能皮膚過敏性 、此等酯與酿胺亦應比較溫和且不刺激皮膚。 本發明用的適宜多羥基脂肪酸酯可有化學式: 「 -〇 R-C-O-i—γ 式内R係Cs-Cm烴基,較佳直鏈C7-C19烷基或烯基,更佳直鏈 基或締基’最好直鏈cu-C17坑基或缔基或其混合物 ;丫爲多羥基烴基部分有一帶至少2自由羥基直接連接鏈上 的烴鏈;η最小爲1。適宜γ基能自多元醇如甘油、季戊四 醇;糖類如棉子糖、麥芽右旋糖、半乳糖、蔗糖、葡萄糖 、木糖、果糖、麥芽糖、甘露糖、及赤蘚糖;糖醇類如丁 四醇、木糖醇、malitol、甘露糖醇與山梨糖醇;及糖醇之奸 如山梨糖醇酐等衍生。 本發明用一類適宜多超基脂膀酸酯含某些山梨糖醇奸醋 ’較佳山梨糖醇酐之C^C:22飽和脂肪酸酯。由於其典型製 造方式之故此等山梨糖醇酐酯常含單、二、三等酿的混合 物。適宜山梨糖醇酐酯之代表例包括山梨糖醇酐十六坑酸 酯(如SPAN 40),十八烷酸酯(如SPAN 60),及廿二燒酸醋, 其中含一或多種此等山梨糖醇辭酯之單-、二_、與三-醋则 -25- 本纸張尺度適用中®國家械準(CNS〉Λ4規格(210X 297公釐) (請先閒讀背面之/'1Φ?事項再填寫本頁)
經濟部中央標隼局員工消费合作社印製 A7 __________B7 五、發明説明(23 ) 例如山梨糖醇酐單、二、及三(十六燒酸)酷,山梨糖醇酐 單、二、及三(十八烷酸)酯,山梨糖醇酐單、二及三(廿二 烷酸)酐,以及混合的牛油脂肪酸山梨糖醇酐單、二及三酯 亦flb用不同山梨糖醇肝g旨之混合物如山梨糖醇肝十六燒 酸酯與山梨糖醇酐十八烷酸酯。特佳山梨糖醇酐酯爲山梨 糖醇酐十八烷酸酯,典型呈單、二、與三酯(加若干四酯)之 混合物如SPAN60,及龍茶公司(Lonza,Inc)商標名 GLYC〇MUL_S下所售的山梨糖醇酐十八烷酸酯等。雖然此等 山梨糖醇酐酯典型含單、二與三,加若干四酯的混合物, 此等漏合物内常以單及二醋爲多數型類。 本發明用另一類適宜多羥基脂肪酸酯含某些甘油單能, 較佳c^c:22飽和脂肪酸之甘油單酯如甘油單十八烷酸騎、 甘油單十六烷酸酯及甘油單廿二烷酸酯。再者與山梨糠醇 酐酯相似、甘油單酯混合物典型含多少二酯與三醋。不過 此等混合物主要應含本發明適用的甘油單醋類型。 本發明用另一類適宜多羥基脂肪酸酯包括某些蔗糖脂妝 fe· S旨’較佳薦糖之C u-C;22飽和脂肪·酸醋。薦糖單醋與二妒 特別可取’包括無糖早與一(十八垸《酸)醋及薦糖單與二( 十二烷酸)酯。 本發明用適宜多經基脂肪酸醯胺有化學式 (請先閱讀背面之注意事項再填寫本頁j 訂 Μ !
經濟部中央樣準局舅工消费合作社印製 A7 ________B7 五、發明説明(24 ) 式内R 1係Η,(:丨-(:4烴基,2-羥乙基,2-¾丙基,甲氧乙基, 甲氧丙基或其混合物;較佳燒基、甲氧乙基或甲氧丙 基,更佳(:丨或^烷基或甲氧丙基;最好(:丨烷基(即甲基)或曱 氧丙基;R2爲C5-C31烴基,較佳直鏈(:7-(:19烷或烯基,更佳 直鏈c9-c17烷或晞基’最好直鏈C^-C^烷或烯基或其混合物 ;Z係有線型烴鏈的多超基烴部分其中至少3經基直接連接 於鏈。見1992年12月29日頒予杭沙(Honsa)的美國專利 5,174,927(此處引用參考),其中發表此等多羥基脂肪酸醯胺 及其製法。 Z部分較佳能自還原糖在還原胺化反應;最好甘糖醯基 (glycityl)中衍生。適宜還原糖包括葡萄糖、果糖、麥芽糖 、乳糖、半乳糖、甘露糖與木糖。能用高右旋糖玉米糖漿 、南果糖玉米糖漿及而麥芽糖玉米糖漿,以及上文所列之 個別糖。此等玉米糖漿能產生Z部分糖組份之混合物。 z 部分宜選自-CH2-(CH0H)n-CH20H,-C^Ci^OHHCCHOHU-CH2〇H,-(:Η20Η-(:Η2-((:Η0Η)2((:Η0Κ·3Χ(:Η0Η)-(:Η20Η,其中 η爲 自3至5整數,R3係Η或環狀或脂屬單糖。最好爲其中η係4 之甘糖醯基,特別-ch2-(choh)4-ch2oh。 上式内R1能係例如N -甲,N -乙,N -丙,N -異丙,N - 丁 ’ N - 2-#至乙,N -甲氧丙或N - 2 -羥丙基。R2能選擇以提供 例如古柯醯胺,十八燒醯胺,油醯胺,十二烷醯胺,十四 垸酿胺,癸醯胺,十六烷醯胺,牛脂醯胺等。z部分能係 1-脱氧甘糖酿基,2-脱氧果糖酿基(fructityl),1-脱氧麥芽糖 醯基m altityl ’ 1-脱氧乳糖醯基(iactityi),卜脱氧半乳糖醯基 ___-______________-_Γ_ 木紙張尺度遴用中國國家標隼(CNS ) Α4规格( 1ί〇Χ291:^釐〉 (請先閱讀背面之注意事項再填寫本頁) 訂 .^! 0Η I CH—CH2—0Η 經濟部中央標準局員工消費合作社印製 A7 ________ B7 五、發明説明(25 ) (galactityl) ’ 1-脱氧甘露糖酿基(mannityl) ’ 1-脱氧麥芽糖三 S备基(maltotriotityl)等基。 最佳多經基脂肪酸醯胺有通式: 0 R1
II I R2—C-N-CH2 式内Rl係曱基或甲氧丙基;r2爲Cll_C17直鏈烷或晞基。此 等包括N-十一燒•基-N-甲替葡糖酿胺,N-十二境基-N-曱 氧丙替葡糖醯胺’ N-椰基-N -曱氧丙替葡糖醯胺,N- + ττ燒基-N-甲乳丙替葡糖酿胺,N -牛脂基-N -甲替葡糖酿 胺’或Ν -牛脂基-Ν -甲氧丙替葡糖酿胺。 前文提述有些固定劑須要乳化劑供增溶於潤膚劑内。某 些葡糖醯胺如HLB値至少約7的Ν-烷基-Ν-曱氧丙替葡糖 醯胺之情況特別如此。適宜乳化劑典型包括其有Η ^ Β値 在約7以下者。在此方面前述的山梨糖醇奸酯如山梨糖醇 酐十八烷酸酯有H L· Β値約4 _ 9或更低者經發現有效增溶此 等葡糖醯胺固定劑於礦脂内。其他適宜乳化劑包括 steareth-2(符合化學式 CH/CHA/OCH/H^Oi^ ^ 平均値 2的十八烷醇之聚乙二醇醚),山梨糖醇酐三(十八境酸)酉匕 ,異山梨糖醇十二烷酸酯,與甘油單十八烷酸酯。可含乳 化劑量足以增溶固定劑於潤膚劑内而得實質均勻的混合物 。舉例普通不能熔化成單相混合物的N -椰基_ N •甲替葡糖 28- 木紙張尺^適用中國国家標準(CNS ) Λ4規格(2Ίΰ7ΐ97公瘦"Γ" (請先閱讀背而之注意事項再填寫本頁)
經濟部中央標準局員工消费合作社印製 A7 ——_ ___ B7 五、發明説明(26) 酿胺與礦脂之約b 1混合物於添加2 〇 %的steareth_2與山裂 糖醇酐三(十八烷酸)酯之丨:丨混合物後截溶成單相混合物。 能單獨或與前述固定劑合併作固定劑用的其他型組成分 包括壞類如巴西棕摘壤、蜂堞、小濁樹蟻、石蠛、地蟻、 西班牙草蠛、小冠椰子蠛、雷佐壌及其他已知蠘。較佳壤 爲石蠟。特佳石蠟之一例爲來自史察-匹區公司(Strahl &
Pitsch Inc_,P. 0· Box 1098 West Babylon, NY 11704)之石蠟 S. P 434 = 洗劑組合物内應含之固定劑量將視多項因素而定,包括 所含明確潤膚劑、所含特別固定劑,是否須要乳化劑增溶 固定劑於潤膚劑内’洗劑組合物中其他组物等類因素。洗 劑组合物能含約5至約90%之固定劑。較佳洗劑組合物含 約5至約5 0 %、最好約〗〇至約4 〇 %之固定劑。 3 .隨意的親水界面活化#丨 如如所述極紛尿布頂片用親水材料製作以促進液體(如 尿)快速傳過頂片。同樣重要洗劑組合物亦能充分潤濕以 確保液體迅速移經頂片。如此使身體分泌液流離洗劑塗層 而不被吸過頂片爲吸收芯吸收之可能性降低。視本發明洗 劑組合物内所用的特別固定劑如何、可能或可不須要外加 親水界面活化劑(或親水界面活化劑之混合物)以增進潤濕 性。舉例有些固定劑如N-椰基-N_甲氧丙替葡糖醯胺有/至 少約7之HLB値者無須添加親水界面活化劑能充分潤濕。 其他固定劑如HLB値低於約7之Cl6_Ci8脂族%則於塗敷=劑 __________-29 - 本紙張尺度中國國家標準(CNS > A4,i7110X297公董厂 (請先閲讀背面之注意事項再填寫本頁)
經濟部中央標準局員工消费合作社印製 A7 B7 五、發明説明(27 ) 至尿布頂片時須要加親水界面活化劑。同樣地疏水性潤膚 劑如礦脂則必須添加親水界面活化劑。 適宜親水界面活化劑能與潤膚劑及固定劑相溶混製成均 勻混合物。由於使用塗有洗劑組合物的可棄式吸收製品者 之可能皮膚敏感,此等界面活化劑亦應相當溫和且不刺激 皮膚。此等親水界面活化劑典型係非離子型不僅不刺激皮 膚,且亦避免對任何下方薄紙疊層結構有其他不合宜影響 如降低抗張強度等。 洗劑組合物塗於尿布頂片後適宜的非離子型界面活化劑 可實質地不遷移,將典型地有HLB値在約4至約2 0範圍内 ’較佳自約7至約2 0。欲使其不遷移,此等非離子型界面 活化劑典型須有溶點高於貯存、運輸、售賣及使用可棄式 吸收製品期間通常遭遇的溫度,即至少約3 〇。關於此 點、此等非離子型界面活化劑宜有與前述固定劑類似之熔 點。 本發明洗劑組合物内適用的非離子型界面活化劑包括烷 基配糖物;1977年3月8日頒予郎登(Langdon)等美國專利 4,011,3 89内.所述之貌基卷謎;紀基多乙氧化自旨如peg〇Sperse 1000MS(可件自龍余公司 Lon'za, Inc.,Fair Lawn, New Jersey)乙 氧化山梨糖醇酐單、二及/或三c l2_c 18脂肪酸酯,有平均乙 氧化程度自約2至約2 0較佳自約2至純1 〇者,如TWEEN 60( 平均乙氧化度約20之十八烷酸山梨糖醇酐酯)及TWEEN 61( 平均乙氧化度約4之十八烷酸山梨糖醇酐酯),及脂族醇與 約1至約54莫耳乙烯化氧之縮合產物。脂族醇的烷鏈典型成 ______— -30- 本紙張尺度賴巾ϋ®家鮮(⑽)^見格1210χ29ν公董了 (請先閲讀背面之注意事項再填寫本頁) 訂 Λ ! 經濟部中央標準局負工消費合作社印製 A7 B7 五、發明説明(28 ) 直鏈(線型)構態並含約8至約22個碳原子。特佳爲含約丨1至 約22碳原子的烷基醇與每莫耳醇約2至約30莫耳乙烯化氧的 縮合產物。此項乙氧化醇實例包括十四燒醇與每莫耳醇7莫 耳乙缔化氧之縮合產物,椰子醇(有長度變化自1〇至14碳原 子的烷基鏈之脂肪族醇混合物)與約6莫耳乙烯化氧之縮合產 物。商品可得許多適用的乙氧化醇,包括聯合碳化物公司 供售的TERGITOL 15-S-9 (CirC15線形醇與9莫耳乙烯化氧之 縮合產物);寶鹼公司供售的KYRO EOB (<:13-(:15線形醇與9 莫耳乙晞化氧之縮合產物);蜆音化學廠供售的NEODOL牌 界面活化劑,尤其NEODOL 25-12((:12-(:25線形醇與12莫耳乙 晞化氧之縮合產物)與NEODOL 2〗-6.5T(C12_C13線形醇與曾經 蒸餾(拔頂)除脱某些雜質的6.5莫耳乙烯化氧之縮合產物); 與特別由BASF公司供售的PLURAFAC牌界面活化劑,尤其 PLURAFAC Α·38((:18直鍵醇與27莫耳乙晞化氧之縮合產物)。 (某些親水界面活化劑特別乙氧化醇如NEODOL 25-12亦能作 燒基乙氧酯潤膚劑用)。其他較佳乙氧化醇界面活化劑實例 包括卜内門的Brij類界面活化劑及其混合物等,以Brij 72(即 Steareth-2)與Brij 76(即Steareth-ΙΟ)爲較佳。又乙氧化至平均 乙氧化程度自約1〇至約2〇的十六烷醇與十八烷醇之混合物 亦可用作親水界面活化劑。 本發明用另一型適宜界面活化劑包括Aerosol OT,乃美國 氰胺公司供售的績基丁二酸鈉之二辛酯。 本發明用再一型適宜界面活化劑包括矽酮共聚物如通用 電氣SF 1188(聚二甲基矽氧烷與聚氧化烯醚之共聚物)及通 —_________—" 31 - 本紙張尺度賴t ®目家榡準yCNS) A4規'& (;〉< 297公釐) (請先閱讀背面之注意事項再填寫本頁) 訂 ^-! Μ _____ Β7 五、發明説明(29 ) 用電乳SF 1228(-種碎網聚醚共聚物此等碎輞界面活化 劑能與前文研討的其他型親水界面活化劑如乙氧化醇類混 合。經發現此等矽酮界面活化劑在洗劑組合物重量比低至 01%,較佳自約0.25至約1.0%之濃度有效。 提高洗劑組合物可濕性至所須程度必要的親水界面活化 劑用量視所用固定劑的HLB値與量、所用界面活化劑之 H L B値與量及類似因素而定。洗劑组合物於需要提升組合 物的可潤濕性質時能含自約1至約5 〇 %之親水界面活化劑 。當必要增加可濕性時較佳洗劑組合物含約丨至約2 5 %之 親水界面活化劑,最好自約丨0至約2 〇 %。 4 ·其他隨意組份 洗劑組合物能含潤膚劑、乳膏及此型洗劑中典型存在的 其他随意組份。此等隨意組份包括水、黏度修正劑、香料 、消毒殺菌活性劑、藥物活性劑 '薄膜形成劑、除臭劑、 遮光劑、收歛劑及溶劑等❶此外,能加穩定劑如纖維素衍 生物、蛋白質及卵磷脂以增加洗劑組合物之適用期。所有 此等物質均爲技術上週知作此等配方之添加劑,能在本發 明洗劑組合物内適量採用。 經濟部中央標準局貝工消費合作杜印製 c · 先劑組合物處理尿布頂片 製備根據本發明的加洗劑尿片製品時將洗劑組合物塗於 尿布頂片的外表面(即向身體面)。能用多種均句分佈有溶 化或液體稠度的光滑物質塗敷方法之任—種。適宜方法包 _ -----— - _____ · 32 · 本祆張尺度適用中同國家標芈(CNS ) A4規格(--- A7 B7 29^22β 五、發明説明(3〇) 括嘴霧、印刷(例如凸版印刷)、塗覆(如凹版塗覆)、擠恩 或此等應用技術合併例如將洗劑組合物喷霧於旋轉表面如 砑光輥上然後轉移組合物至尿布頂片的外表面。 洗劑组合物塗敷尿布頂片之方式應使頂片不爲洗劑組合 物飽和。若頂片以洗劑組合物飽和、洗劑將有較大趨勢堵 π員片孔療’踔弱頂片傳遞流體至下方吸收芯的能力。欲 侍冶療與/或保護的洗劑利益亦不需要頂片飽和。特別適 宜施用法爲主要塗敷洗劑組合物於尿布頂片之外表面。 尿布頂片上洗劑之最低塗敷量爲減輕Β Μ附著於穿者皮 膚之有效量。本發明尿布頂片上塗敷洗劑組合物量範圍宜 自約〇^mg/in2至約25 mg/in2,較佳自約i呵/一至約1〇 mg/in (每方吋塗敷頂片之洗劑m g)。由於潤膚劑實質上固 疋在頂片表面上,須要較少洗劑組合物賦予所期護膚利益 。此項較低量洗劑組合物足夠給予頂片所期療效與/或保護 的洗劑利ϋ,但並不飽和頂片的吸收能力及/或可潤濕性質 〇 洗劑组合物可塗敷頂片的全體表面或其部分。較佳塗敷 洗劑組合物成一條對齊並集中於可棄式吸收物件的縱長中 線上。最好如以下實例内説明、洗劑組合物塗敷成頂片上 不連續型’例如3.75吋寬(尿片橫向)與7吋長(尿片縱向)墊大 致排列對第二腰區。 土 洗劑組合物亦能不均勻地塗於尿布頂片的外表面。所謂 "不均勻”意指洗劑組合物之量及分佈圖案等能在全頂片表 面變化。舉例頂片已處理表面的有些部分能有較多或較少 Μ氏張尺度適用中0國家標準(CNS ) Α4規格ί (請先閱讀背面之注意事項再填寫本頁) 、\s° Μ ! 經濟部中央標準局員工消費合作社印製 33 A7 經濟部中央標準局員工消费合作社印裝 五、發明説明(31 量之洗劑組合物,包括其上全無洗劑組合物的表面部分。 洗劑組合物能於組集期間在任—點處塗敷於頂片。例如 洗劑組合物能於包裝前塗於完成的可棄式吸收製品之頂片 。洗劑组合物亦能與其他原料合併作成完備可棄式吸收製 品前塗於頂片。 洗劑组合物典型自其熔化物塗於尿布頂片。洗劑組合物 因熔點高過室溫甚多,通常作加熱塗層塗於頂片。洗劑組 合物典型加熱至約35。至約1〇0。(:、較佳自4〇。至約9〇χ: 範圍内溫度後塗於尿布頂片。熔融洗劑組合物己塗於尿布 頂片後遂任其冷凝在頂片上形成固化塗層或薄膜。塗敷製 程宜設計以助洗劑之冷卻/固定。 塗敷本發明洗劑組合物於尿布頂片時以噴霧、凹版塗覆 及擠壓塗層等法爲佳。圖丨説明此一較佳方法包括嘴霧塗料 於尿布頂片上然後與其他原材料組集爲成品。參考圖i, 頂片母輥2(按箭2a指示方向旋轉)放開非織頂片網構1前 至噴霧站6,在此以熱熔的洗劑組合物(例如6 5 t )噴霧網π 的一面。離開噴霧站6後非織頂片網構1變爲3所指的加洗劑 頂片網構。加洗劑的頂片網構3於是繞轉折輥4及轉折輥8前 進’而捲繞於加洗劑頂片的母輥丨〇上(旋轉方向按箭l 〇 a指 示)。 圖2例示另一較佳方法包括在轉化作業期間連續或間歇 噴霧洗劑組合物於尿布頂片上。參考圖2、輸送帶丨按轉折 擦3與4上箭示方向前進並變成回轉輸送帶2。輸送帶^ 帶未塗洗劑的尿片5至噴霧站6,頂片墊7在此處經熱溶 白 進 布 1摘 (請先閲讀背面之注意事項再填寫本頁) 訂 -34- 經濟部中央標準局員工消費合作社印製 A7 ________B7 ___ 五、發明説明(32 ) (例如6 5 °C )洗劑組合物噴霧。離開噴霧站6後無洗劑的尿 片5變爲有加洗劑頂片之尿片8。移轉至頂片墊7之洗劑組 合物量由:⑴自噴霧站6所噴熔化洗劑組合物量;與/或⑵ 輸送帶1在噴霧站6下移行的速度控制。 加洗劑的尿布頂片製法之特別例解 以下爲用根據本發明洗劑组合物處理尿布頂片之特別例 解: 實例1 A · 1劑組合物方率法 }昆合以下溶化的(即液態)組份一起作一無水洗劑組合物( 洗劑 A):礦油(Witco Corp•製 Carnation白礦油,USP); Cetearyl醇(寶鹼公司製TA-1618名下之混合線形cl6-C18伯醇) ;Steareth-2(美國ICI製有平均乙氧化程度2之Ci8漆形轉乙氧 S曰’ Bnj 72)。此等組份之重量百分比如下表〗所示:
表I 組份 重量% 礦油 50 Cetearyl 醇 35 Steareth-2 15 B · 頂片用執烷喷霧之製法 置洗劑組合物八在125下溫度作業的加熱槽内。組合物隨 __ -35- 未纸張尺度適用中· (請先閲讀背而之注意事項再填ϊϊ-r本頁}
五、發明説明(33 ) A7 B7 經濟部中央橾準局負工消費合作社印製 後(用Dynatec E84B1758噴霧頭於1ό5Τ溫度及2 4〇 psig喷霧 壓力作業)喷於3.75吋寬(尿片橫向)及7吋長(尿片縱向)區内 的尿布頂片上,小塊在橫中線前1吋開始而向製品後方延 伸。累計量=0.006 g/in2 (9.3 g/m2)。 實例2 根據實例1程序所製之洗劑組合物A随後噴霧在尿布頂 片上的3_75吋寬(尿片橫向)條内集中於縱向中線上而延伸 至製品之全長。累計量=0.006 g/in2 (9.3 g/m^。 實例3 根據實例1程序所製之洗劑組合物A隨後噴霧在尿布頂 片上在3.75吋寬(尿片橫向)條内集中於縱向中線上與7吋長 (尿片縱向)區,小塊在橫中線前i吋開始而向製品後方延 伸。累計量=0.003 g/in2 (4.65 g/m2)。 實例4 A .洗劑組合物之製法 混合以下熔化的(即液態)组份一起作— .., F 热水洗劑組合物( 洗劑B):礦油(Witco Corp·製Carnation白礦油,仍 Cete^丨醇(寶驗公司製TA_1618名下之遇合線形Cels伯醇) 。此等組份之重量百分比如下表11所示: 、 本紙張尺度適用巾1[國家標準(CNS ) M規格(21〇χ297公羞 •36- (請先閲讀背面之注意事項再填寫本頁) 訂 -滅! 經濟部中央標準局員工消費合作杜印$1 A7 B7 五、發明説明(34 )
表II 組份 重量% 礦油 65 Cetearyl 醇 35 B .加洗劑的薄紙用熱熔噴霧之製法 置洗劑組合物B在125T溫度作業的加熱槽内。組合物隨 後(用Dynatec E84B1758噴霧頭於165°F溫度及2.40 psig噴霧 壓力作業)噴於3.75吋寬(尿片橫向)及7吋長(尿片縱向)區内 的尿布頂片上,小塊在橫中線前1吋開始而向製品後方延 伸。累計量=0.006 g/in2 (9.3 g/m2)。 實例5 A .洗劑組合物之製法 混合以下溶化的(即液態)組份一起作一無水洗劑組合物( 洗劑 C):白 Protopet® lS(Witco Corp.製白礦脂);Cetearyl 醇( 寶鹼公司製TA-1618名下之混合線形C16-C18伯醇);Steareth-2(美國ICI製有平均乙氧化程度2之C18線形醇乙氧酯,Brij 762)。此等組份之重量百分比如下表III所示: -37 本紙張尺度適用中國國家標準(CNS ) A4規格210X 297公釐) (請先閱讀背面之注意事項再填寫本頁)
五、發明説明(35 ) A7B7
表III 組份 重量% 白 Protopet® IS 50 Cetearyl 醇 35 Steareth 2 15 經濟部中央標準局員工消費合作社印製 B .加洗劑的薄紙用熱熔噴霧之製法 置洗劑組合物C在125°F溫度作業的加熱槽内。組合物隨 後(用Dynatec E84B1758噴霧頭於165T溫度及2.40 psig噴霧 壓力作業)噴於3.75吋寬(尿片橫向)及7吋長(尿片縱向)區内 的尿布頂片上,小塊在橫中線前1吋開始而向製品後方延 伸。累計量=0.006 g/in2 (9.3 g/m2)。 實例6 A ·洗劑組合物之製法 混合以下熔化的(即液態)組份一起作一無水洗劑組合物( 洗劑D ):白Protopet® lS(Witco Corp.製白礦脂);道康寧556 化妝品級流體(道康寧製聚苯基甲基矽氧烷);特佳石蠟之 一例爲石蠟 S.P.434(Strahl & Pitsch Inc.製之一種石蠟); Cetearyl醇(寶鹼公司製TA-1618名下之混合線形C16-C18伯醇) ;PEG 2000(Sigma-Aldrich Corp.製 My 2000之聚乙二醇)。此 等組份之重量百分比如下表IV所示: ______58- 本紙張尺度適用中國围家標率(CNS ) A4規柊(210 X:!97公釐) (請先閱讀背面之注意事項再填寫本頁) 歧! A7 B7 五、發明説明(36 )
表IV 組份 重量% 白 Protopet® 1 S 52 聚苯基甲基矽氧烷 20 石蠟 15 Cetearyl 醇 10 PEG 2000 3 (請先閱讀背面之注意事項再填寫本頁) B .加洗劑的薄紙用熱熔喷霧之製法 置洗劑組合物D在150下溫度作業的加熱槽内。組合物隨 後(用Dynatec E84B1758喷霧頭於170T溫度及2.40 psig噴霧 壓力作業)噴於3.75吋寬(尿片橫向)及7吋長(尿片縱向)區内 的尿布頂片上,小塊在橫中線前1吋開始而向製品後方延 伸。累計量=0.006 g/in2 (9_3 g/m2)。
,1T Μ ! 經濟部中央標準局員工消費合作社印製 ____-59- 本纸張尺度適用中國國家標準(CNS〉A4規格(210X197公釐)
Claims (1)
- 第84112157號專利申請案 中文申請專利範圍條正太年7 E| ) A8 B8 C8 D8 六、申請專利範圍一種可棄式尿片,含 (A) —不透液體的背片; (B) —能透液體的親水頂片連接該背片,當穿著該尿片 時該頂片有一定向該尿片内部的内表面與_定向穿 者皮膚的外表面,其中該頂片外表面之至少一部分 含有效量的洗劑塗層在20»c時係半固態或固體且能 邵分移轉至穿者的皮膚,該洗劑塗層含: (1)自10至95%實質無水之潤膚劑在2〇β(:時有柔軟 或流體稠度並含一種選自具鏈長爲16至32個碳 原子之石油基碳氫化合物、衍生自(:12_〇:28脂 肪酸及crc8—元醇之脂肪酸酯 '具平均乙氧 化度爲2至30之C12-C22脂肪醇乙氧酯 '及其 混合物等之成分; (ii)自5至90%能固定該潤膚劑於該頂片外表面上 之用劑,該固定劑有3 5。(:至1 5 0。(:之炫點;及 (C) 一吸收芯位於該頂片與該背片之間。 2 經濟部中央橾準局月工消費合作社印製 (請先閲讀背面之注意事項再填寫本頁) 、1T 根據申請專利範園第1項之可棄式尿片,其中該固定劑 係選自多經基C6-C32脂肪酸酯,多羥基c6_c32脂肪 酸醯胺’ C14-C22脂肪族醇,Cl4-c22脂肪酸、具平 均乙氧化度爲2至30之Ci4_C22脂肪醇乙氧g旨及其混 合物等。 3 .根據申請專利範園第2項之可棄式尿片,其中該潤膚劑 含0至5 %的水並包括選自礦油、礦脂及其混合物等之 一種石油基潤膚劑。 本紙張尺度適用中囷國家標隼(CNS ) A4規格(210X297公瘦)申請專利範圍 經濟部中央標準局負工消费合作社印製 4.根據申請專利範固第3項之可棄式尿片 係礦脂。 5 ·根據申請專利範固第4項之可棄式尿片 係礦油。 6 .根據申請專利範固第丨項之可棄式尿片 表面之該部分上洗劑塗覆量 T 2^^ mg/in2〇 固自 〇] mg/W 至 25 根據申請專利範園第6項之可杳彳抚 卑貝了棄式尿片,其中該頂片外 之該部分上洗劑塗覆量範固自i „^/42至1〇 mg/i η 2 ° 8 ·根據申請專利範圍第1項之可查或 闽珩m j案式尿片,其中該潤膚劑 含一種脂肪酸酯潤膚劑選自十六烷酸甲酯,十八烷酸甲 酯,十二烷酸異丙酯,十四烷酸異丙酯,十六烷酸異丙 醋’十六烷酸乙基己醋,乳酸十二烷醋與乳酸十六烷醋 ,及其混合物等。 9. 根據申請專利範圍第i項之可棄式尿片其中該潤膚劑 含—種燒基乙氧醋潤膚劑選自c12“Ci8脂肪族醇乙氧 醋有平均乙氧化程度範圍自2至30。 10. 根據申請專利範圍第1項之可棄式尿片,其中該洗劑塗 料含自5至50%之該固定劑,該固定劑有4〇β(:至15〇τ 之熔點》 11. 根據申請專利範圍第10項之可棄式尿片其中該固定 劑含c M - C 2 2脂肪族醇。 12. 根據申請專利範圍第1 1項之可棄式尿片,其中該固定 -2 - 、 其中该潤膚劑 其中該潤膚劑 其中該頂片外 (請先Μ讀背面之注意事項再填寫本I) 本紙張尺度適用中囷囷家標準(CNS ) Α4規格(210Χ297公釐) 申請專利範圍 劑令^ ΓΛ —C16-C18脂肪族醇 丰 及其混合物等。 選自十-垸醇’十八坑醇, 根據申請專利範圍第J 〇項之可 劑含—多經基脂防酸醋有化學式/ ,其中該固定 請 « 2 装 Π 式内R爲Cj-Cqi煙基;γγ家之a计 5 31 丞,Y係多羥基烴部分有一至少 2自由經基直接連接鏈上之烴鏈;^最小爲!。 地根據申請專利範圍第丨3 淹丨丨▲ * 月<'1業式尿片,其中該固定 制含-多經基脂脉酸酿選自c16.c22飽和脂肪酸之山 梨糖醇肝醋,c16-c22飽和脂肪酸之甘油單酿,與 C12-C22飽和脂肪酸之蔗糖酯。 15. 根據申請專利範園第14項之可棄式尿片,其中該固定 劑含—多羥基脂肪酸酯選自十六烷酸山梨糖醇酐酯,十 八燒酸山梨糖醇酐酯’廿二烷酸山梨糖醇酐酯,單十八 垸酸甘油酯,單十六烷酸甘油酯,單廿二燒酸甘油酯, 單-及二-(十八烷酸)蔗糖酯,與單·及二_(十二烷酸)蔗 糖酿。 16. 根據申請專利範圍第! 5項之可棄式尿片,其中該固定 劑含十八烷酸山梨糖醇酐酯。 17. 根據申請專利範圍第1 〇項之可棄式尿片,其中該固定 -3 · 訂 經濟部中央揉率爲貝工消费合作社印製 I - 〇 · 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐 申請專利範圍 劑含 有下式 之多羥基脂肪酸醯胺 Ζ R丨Ν ο = C I 2 R 經濟部中央標準局負工消费合作社印製 式内R 1 & LT Λ ’C1_C4烴基’2 -羥乙基,2_羥丙基, 乙基’甲氧丙基或其等混合物;r、C5_C3i烴 基;爲多題基烴部分有至少3個題基直接連接鍵上 I一線形烴鏈。 1δ.根據申請專利範圍第17項之可棄式尿片,其中rUN_ I 二?、丙、N-異丙、Ν· 丁、N_2_羥乙、N-甲 2_羥丙等基;R2係直鍵CU-C17貌基或晞 基,或其混合物;及Z爲甘糖醯基。 19. 根據申請專利範圍第"項之可棄式尿片,其中該固定 劑含-多經基脂肪酸酿胺選㈣·十二燒替_n_甲替葡糖 酿胺,N·十二垸替·Ν_甲氧丙替葡糖酿胺,n_挪替·n_ :替葡糖酿胺’ N_椰替_N_甲氧丙替葡糖酿胺,ν·十 ^替_Ν-甲&丙替葡糖酿胺,Ν-牛脂替_Ν•甲替葡糖 醯胺與Ν•牛脂替-Ν-曱氧丙替葡糖醯胺。 20. 根據申請專利範圍第1〇項之可棄式尿片,其中該固定 劑含石蠟。 21. 根據申請專利範圍第4之可棄式尿片,其中該洗劑塗 層另含1至50%之親水界面活性劑,該親水界面活性劑 有4至20之HLB値》 4- 本紙張尺度適用中國國家標準(CNS ) M規格(210X297公釐) (請先閲讀背面之注f項再填寫本頁) 、1Τ X A8 B8 C8 D8 、申請專利範圍 22. 根據申請專利範圍第2 1項之可棄式尿片,其中該洗劑 塗層另含1至2 5 %之該親水界面活性劑,該親水界面活 性劑爲非離子型,有4至2 0之H L B値。 23. 根據申請專利範圍第22項之可棄式尿片,其中該親水 界面活性劑含一有8至22碳原子烷鏈之乙氧化醇,其平 均乙氧化程度範圍自1至5 4。 24根據申請專利範圍第2 3項之可棄式尿片,其中該乙氧 化醇有-U至22碳原子㈣,其平均乙氧化程^範圍 自2至30。 25.根據申請專利範圍第24項之可棄式尿片,其中該親水 界面活化劑含一 CI2-C 18脂肪酸的乙氧化山梨=醇酐 醋,有平均乙氧化程度自2至2 0。 ---r------------ir (請先閲讀背面之注意事項存填寫本筲) 經濟部中央標準局β:工消費合作社印製 -5 本紙張尺度逍用中國國家標準(CNS > A4規格(210><297公着)
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1994
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1995
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- 1995-10-26 CN CN95196627A patent/CN1127987C/zh not_active Expired - Lifetime
- 1995-10-26 JP JP51877696A patent/JP3222470B2/ja not_active Expired - Lifetime
- 1995-10-26 ES ES95939598T patent/ES2164783T3/es not_active Expired - Lifetime
- 1995-10-26 AU AU41354/96A patent/AU4135496A/en not_active Abandoned
- 1995-10-26 CZ CZ0161197A patent/CZ297874B6/cs not_active IP Right Cessation
- 1995-10-26 DE DE69524630T patent/DE69524630T2/de not_active Revoked
- 1995-10-26 CA CA002205027A patent/CA2205027C/en not_active Expired - Lifetime
- 1995-10-26 HU HU9800546A patent/HU226312B1/hu not_active IP Right Cessation
- 1995-10-26 MX MX9703881A patent/MX9703881A/es unknown
- 1995-10-26 WO PCT/US1995/013809 patent/WO1996016682A1/en not_active Application Discontinuation
- 1995-10-26 BR BR9509774A patent/BR9509774A/pt not_active IP Right Cessation
- 1995-11-10 MY MYPI95003418A patent/MY114905A/en unknown
- 1995-11-16 TW TW084112157A patent/TW299226B/zh active
- 1995-11-24 AR AR33438295A patent/AR000203A1/es unknown
- 1995-11-27 TR TR95/01494A patent/TR199501494A2/xx unknown
- 1995-11-27 ZA ZA9510061A patent/ZA9510061B/xx unknown
- 1995-11-27 PE PE1995285720A patent/PE1897A1/es not_active Application Discontinuation
-
1996
- 1996-01-16 SA SA96160533A patent/SA96160533B1/ar unknown
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1997
- 1997-05-26 NO NO972394A patent/NO972394L/no unknown
- 1997-05-27 FI FI972237A patent/FI972237A/fi unknown
- 1997-06-27 US US08/884,069 patent/US6118041A/en not_active Expired - Lifetime
- 1997-06-27 US US08/884,575 patent/US5968025A/en not_active Expired - Lifetime
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1998
- 1998-03-17 HK HK98102242A patent/HK1005654A1/xx not_active IP Right Cessation
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1999
- 1999-06-24 US US09/339,144 patent/US6586652B1/en not_active Expired - Fee Related
- 1999-07-20 US US09/358,007 patent/US6627787B1/en not_active Expired - Fee Related
-
2001
- 2001-05-28 JP JP2001158986A patent/JP4083395B2/ja not_active Expired - Lifetime
-
2003
- 2003-03-12 US US10/386,959 patent/US6825393B2/en not_active Expired - Fee Related
-
2004
- 2004-06-07 JP JP2004168848A patent/JP4255883B2/ja not_active Expired - Lifetime
-
2007
- 2007-06-25 US US11/821,612 patent/US20080249491A1/en not_active Abandoned
-
2008
- 2008-12-05 JP JP2008310942A patent/JP2009137964A/ja active Pending
-
2009
- 2009-12-21 JP JP2009289641A patent/JP2010063921A/ja active Pending
- 2009-12-21 JP JP2009289666A patent/JP2010075733A/ja active Pending
- 2009-12-21 JP JP2009289656A patent/JP2010075732A/ja not_active Withdrawn
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