TW205038B - - Google Patents
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- TW205038B TW205038B TW081105185A TW81105185A TW205038B TW 205038 B TW205038 B TW 205038B TW 081105185 A TW081105185 A TW 081105185A TW 81105185 A TW81105185 A TW 81105185A TW 205038 B TW205038 B TW 205038B
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- -1 Radical cation salts Chemical class 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 229920000642 polymer Polymers 0.000 claims abstract description 38
- 239000011159 matrix material Substances 0.000 claims abstract description 8
- 238000000576 coating method Methods 0.000 claims description 26
- 239000002904 solvent Substances 0.000 claims description 26
- 239000011248 coating agent Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 13
- 238000011049 filling Methods 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 12
- 150000003254 radicals Chemical class 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- 239000011593 sulfur Substances 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 229920001187 thermosetting polymer Polymers 0.000 claims description 9
- 229920000728 polyester Polymers 0.000 claims description 8
- 229920001169 thermoplastic Polymers 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000004634 thermosetting polymer Substances 0.000 claims description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 238000002309 gasification Methods 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229920000131 polyvinylidene Polymers 0.000 claims description 2
- IOOGPFMMGKCAGU-UHFFFAOYSA-N tetrasulfur Chemical compound S=S=S=S IOOGPFMMGKCAGU-UHFFFAOYSA-N 0.000 claims description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims 4
- 229910021592 Copper(II) chloride Inorganic materials 0.000 claims 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims 1
- GWFWOQAOJGMBLK-UHFFFAOYSA-N [C-]#N.[Dy+3].[C-]#N.[C-]#N Chemical compound [C-]#N.[Dy+3].[C-]#N.[C-]#N GWFWOQAOJGMBLK-UHFFFAOYSA-N 0.000 claims 1
- 229960003280 cupric chloride Drugs 0.000 claims 1
- 229920000193 polymethacrylate Polymers 0.000 claims 1
- 239000013078 crystal Substances 0.000 abstract description 12
- 238000000465 moulding Methods 0.000 abstract description 2
- 239000004020 conductor Substances 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 38
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 29
- 239000000243 solution Substances 0.000 description 24
- 239000002253 acid Substances 0.000 description 19
- 150000002148 esters Chemical class 0.000 description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 13
- 239000005977 Ethylene Substances 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 11
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- 102000004190 Enzymes Human genes 0.000 description 8
- 108090000790 Enzymes Proteins 0.000 description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 8
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- 150000001993 dienes Chemical class 0.000 description 8
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- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 150000008064 anhydrides Chemical class 0.000 description 5
- 150000002596 lactones Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 5
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- 239000000123 paper Substances 0.000 description 5
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- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 description 4
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 4
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 4
- 230000004151 fermentation Effects 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 229920000768 polyamine Polymers 0.000 description 4
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- 150000008442 polyphenolic compounds Chemical class 0.000 description 4
- 235000013824 polyphenols Nutrition 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 229920001897 terpolymer Polymers 0.000 description 4
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 3
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 229930188620 butyrolactone Natural products 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 3
- 229920006037 cross link polymer Polymers 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 3
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
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- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
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- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- 230000015572 biosynthetic process Effects 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
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- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
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- 150000008282 halocarbons Chemical class 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
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- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
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- YHHHHJCAVQSFMJ-FNORWQNLSA-N (3e)-deca-1,3-diene Chemical compound CCCCCC\C=C\C=C YHHHHJCAVQSFMJ-FNORWQNLSA-N 0.000 description 1
- BSSNZUFKXJJCBG-UPHRSURJSA-N (z)-but-2-enediamide Chemical compound NC(=O)\C=C/C(N)=O BSSNZUFKXJJCBG-UPHRSURJSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
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- SXWIAEOZZQADEY-UHFFFAOYSA-N 1,3,5-triphenylbenzene Chemical compound C1=CC=CC=C1C1=CC(C=2C=CC=CC=2)=CC(C=2C=CC=CC=2)=C1 SXWIAEOZZQADEY-UHFFFAOYSA-N 0.000 description 1
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- 239000003586 protic polar solvent Substances 0.000 description 1
- UBQKCCHYAOITMY-UHFFFAOYSA-N pyridin-2-ol Chemical compound OC1=CC=CC=N1 UBQKCCHYAOITMY-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical group [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 235000021092 sugar substitutes Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000006158 tetracarboxylic acid group Chemical group 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- AGZFYBDSGLYSGN-UHFFFAOYSA-N triazanium triphenoxide Chemical compound [NH4+].[NH4+].[NH4+].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 AGZFYBDSGLYSGN-UHFFFAOYSA-N 0.000 description 1
- YFNKIDBQEZZDLK-UHFFFAOYSA-N triglyme Chemical compound COCCOCCOCCOC YFNKIDBQEZZDLK-UHFFFAOYSA-N 0.000 description 1
- 125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
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- 229920001567 vinyl ester resin Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D495/06—Peri-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/121—Charge-transfer complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/15—Antistatic agents not otherwise provided for
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
五、發明説明(1 ) 本發明係翻於四硫四Ψ (以下簡稱τττ)及之自 由基陽離子鹽.及蘭於在有機溶劑中用無水CuC丨2、 CuClz水錯合物或CuCl2溶劑錯合物使TTT氣化而製得 其之方法,和開於使用其當作電堪體,典型上使聚合物 具抗靜電塗傭或製造導電膜、η、塗層或模製物。 在「延伸之線型鍵化合物j (Extended. Linear Chain
Compounds)第2冊,编輯為j.s.MnUr,充實販 ) (Plenum Press)紐約•第 393 及 394頁),I F Shchegder 等人說明TTT和CuBr以及四硒四早和“㈡^之自由基錯 合物。造些錯合物的専霣性相笛低,即使在單晶體狀態 。在300° !(之比導菜度^為10-2至1〇,3 。若陰 進子含有澳或碘,則逋常可觀測到這種自由基陽雔子錯 合物有高導電性❶然而該錯合物之熱阻低。 驚異地,發現TTT及以以^之自由基陽離子鹽之導電 度高至二等大小高,且這些鹽實質上具有熱安定性,因 此甚至可在較高溫加工。這些鹽结晶成針狀可用於構成 聚合物基質(aartrix)中结晶針之網狀組鏃。這些鹽之 組成顯箸地與上述已知之鍺合物不同。 請 先 閲 背 之 注 意 事 項 再 填 寫 本 頁 裝 ΤΓ 經濟部中央標準局員工消費合作社印製
0- 式 具 鹽 子 離 限 基 成 组 § 本紙張凡度遑用中國國家#flt(CNS)甲4規格(210x297公*) 81. 5 . 20.000(B) A 6 B6 ^05〇〇3 五、發明説明(2 ) 其中X之值為-0.1至+0.2。 (請先閱讀背面之.注意事項再填寫本頁) X之值本質上僳視合成條件而定,主要在於所用溶爾 、起始物質之種類及其比率。較佳X之值為-0.05至 + 0.15,尤其是-0.05至+0.5,更佳是-0.05至+0.05。特 佳者為式I之自由基陽離子鹽其中X之值為-0.002。 本發明之另一戡黠偽關於製備式I自由基颺離子鹽之 方法,其包括使無水CuCl2、CuCl2水錯合物或CuCl2 溶劑錯合物於有機溶劑中舆四硫四¥反醢。 氮化銅、二氯化銅水合物或二氮化銅溶劑錯合物相對 於每莫耳四硫四¥之使用量較佳為0.3至0.8契耳,更佳 為0.35至0.6莫耳。 當使用無水二氣化銅時,水可加入反應混合物内,方 便上以水溶劑狀。 經濟部中央標準局員工消費合作社印製 很多的二氣化銅及極性非質子性或質子性溶劑之溶劑 錯合物樣已知者。可使用單聚、二聚及多聚合錯合物。 適合之溶劑主要為含雜原子,典型上氣、硫、磷及氮。 代表性之例子為醚(乙黼、丁 *、二甘酵二甲或二乙醚) 、酯及内酯(醑酸乙酯、7— 丁内酷)、破(二甲隳、四 亞甲W)及胺(毗啶、α —吡啶酮、α —甲基毗啶、乙 二胺、Ν,Ν—二甲基乙二胺、1-(/3-胺乙基)毗啶、1-( yS -甲基胺乙基)毗啶。 反應係於情性溶劑存在下進行。適合之溶劑,其可單 播或為溶劑混合物,例子為脂族或芳族烴,典型上為己 -4- 本紙張尺度遑用中國困家標毕(CNS)T4規格(210X297公*) 81. 5. 20,000〇〇 Π50〇8 A 6 Β6 經濟部中央標準局员工消費合作社印製 五、發明説明(3 ) 烷、琛己烷、甲基琛己烷、苯、硝苯、甲苯、二甲苯及 聯苯;酵如甲酵、乙酵、丙酵及丁酵;醚如乙醚、二甘 酵二乙醚、乙二酵二甲醚、二苯醚、四氫呋喃及二《烷 ;鹵化烴如二氱甲烷、《仿、1,1,2.2 -四《乙烷及《苯 ;酯及内酯如醴酸乙酯、丁内酸、戊内酯;羧睡胺及内 醯胺如二甲基甲醯胺、二甲基乙醯胺及H -甲基毗咯啶酮 。若反應物係撇溶的,則其可用為懸浮於溶_中形式。 本發明方法方便上於高溫實行,典型上於30至300 1C . 較佳50至250C。程序包括:將鏑化合物溶液加入熱四 硫四¥溶液中,然後使反匾混合物冷卻。藉過濾分離结 晶沈澱物,若須要,水洗純化並乾燥。若欲較大之结晶 ,則進行擴散控制反應,係將各固髓反應物於反應器健 存容器中分離,然後覆以溶_。所得之自由基陽離子鹽 為高純度。 此自由基陽離子鹽非常熱安定,且可於高溫中摻入塑 謬材料中。因為棋製物品之离導霣度故可得到良好抗靜 霄加工(壓縮粉之江=0.4至2.02-1<:»-1)〇逭些自由 基陽離子鹽形成針狀結晶的能力使其可得到之棋製部分 如塗層或自撐膜具高導霣度,可高至新穎结晶自由基限 離子鹽之40X 。可用籣單方式達成製備,將四硫四¥及 銅化合物加入熔化之聚合物中,此聚合物在成形後被冷 卻,或加入該聚合物之溶液中,而在加工後藉蒸發將溶 剤除去。所得在於聚合物基霣中之結晶針緊密細目網狀 -5- (請先閲讀背面之注意事項再填寫本頁) 裝- 訂· 線- 本紙》尺度逍用中國國家榣準(CNS)甲4規格(210x297公釐) 81. 5. 20.000(H) A6 B6 05038 五、發明説明(4 ) 结構産生离導霣性。 本發明之再一觀點你鬭於一種組成物,包括:a)熱固 性、熱塑性或結構交聯聚合物,及b)自由基鵰離子·, 其在聚合物基質中為结晶針網狀结構狀。 此組成可含有自由基陽離子,量為0·01至30重量X, 較佳0.01至20Χ·尤其0.01至10重ΛΧ,最佳0.1至0.5重 悬X 〇 熱塑性聚合物可選自下列聚合物、共聚物或其混合物 « « 1.單烯或二烯聚合物,例如,聚丙烯、聚異丁烯、聚丁 烯、聚甲基戊-1-烯、聚異平或聚丁二烯、及璨烯,例 如,璨戊烯或正在烯、聚乙烯(可交聯或未交聯),例如 ,髙密度聚乙烯(HOPE)、低密度聚乙烯(LDPE及線型低 密度聚乙烯(LLDPE)。 2.1)下所述聚合物之混合物,例如聚丙烯混合聚異丁烯 、聚丙烯混合聚乙烯(例如PP/HDPE, PP/LDPE)及不同種 類聚乙烯(例如LDPE/HDPE)之混合物。 3.單烯輿二烯互相或輿其它乙烯單《之共聚物,例如乙 烯/丙烯共聚物線型低霣度聚乙烯(LLDPE)及其混合物舆 低密度聚乙烯(LDPE)、聚丙烯/丁 -1-烯共聚物、乙烯/ 己烯共聚物、乙烯/甲基戊烯共聚物、乙烯/庚烯共聚物 、乙烯/辛烯共聚物、丙烯/ 丁二烯共聚物、異丁烯/異 平共聚物、乙烯/丙烯酸烷酸共聚物、乙烯/甲基丙烯酸 -6- (請先閲讀背面之注意事項再填窝本頁) 裝· 線· 經濟部中央標準局貝工消費合作社印製 本紙張尺度遑用中家樣準(CNS)甲4規格(210X297公*) 81. 5· 20,000(H) Α6 Β6 經濟部中央標準局員工消費合作社印製 五、發明説明(5 ) 烷酯共聚物、乙烯/醋酸乙烯®共聚物或乙烯/丙烯酸共 聚物及其鹽(_子體).以及乙烯與丙烯及二烯如己二烯 、二琢戊二烯或亞乙基正存烯之三聚物:且亦是該共聚 物互相間或輿上述1)中所述聚合物之共聚物,例如聚丙 烯 / 乙嫌丙嫌共聚物、LDPE/EVA、LDPE/EAA、LLDPE/EVA 及 LLDPE/EAAo 3a.烴樹脂(例如Cs -C9 >包括其之氫化變匾(例如®黏 爾)。 . 4. 聚苯乙烯、聚(對甲基苯乙烯)、聚(《_甲基苯乙烯) Ο 5. 苯乙烯或α-甲基苯乙烯與二烯或丙烯酸衍生物之共 聚物,例如苯乙烯/ 丁二烯、苯乙烯/丙烯腈、苯乙烯/ 甲基丙烯酸烷酯、苯乙烯/ 丁二烯/丙烯酸烷酯、苯乙烯 /順丁烯二酸酐,苯乙烯/丙烯脯/丙烯酸甲酯;從苯乙 烯共聚物及另一聚合物而來之离衝擊強度混合物,例如 從聚丙烯酸酯、二烯聚合物或乙烯/丙烯/二烯三聚物而 來;及苯乙烯之嵌段聚合物,例如苯乙烯/ 丁二烯/苯乙 烯、苯乙烯/異平/苯乙烯、苯乙烯/乙烯/ 丁烯/苯乙烯 或苯乙烯/乙烯/丙烯/苯乙烯。 6. 苯乙烯或α-甲基苯乙烯之接枝聚合物,例如苯乙烯 對聚丁二烯,苯乙烯對聚丁二烯/苯乙烯、或聚丁二烯/ 丙烯脯;苯乙烯及丙烯腈(或甲基丙烯腈)對聚丁二烯; 苯乙嫌及顒丁烯二酸酐或順丁烯二醯亞胺對聚丁二烯; (請先閲讀背面之.注意事項再填寫本頁) 裝· 訂- 線- 本紙張尺度遑用中Β 家樣準(CNS)甲4規格(210x297公*) 81. 5 . 20.000(H) £ώ050〇8 A 6 Β6 經濟部中央標準局貝工消費合作社印製 五、發明説明(6 ) 苯乙烯、丙烯脯及甲基丙烯酸甲酯對聚丁二烯,笨乙烯 及丙烯酸烷酯或丙烯酸甲酯對聚丁二嫌·苯乙嫌及丙烯 腈對乙烯/丙烯/二烯三聚物,苯乙烯及丙烯腈對聚丙烯 酸烷酯或聚甲基丙烯酸烷酯,苯乙烯及丙烯腈對丙烯酸 酯/ 丁;:烯共聚物,以及其輿5)下所列共聚物之混合物 。例如,已知ABS、MBS、ASA或AES聚合物之混合物。 7. 氫化聚合物,如聚《平、氰化橡膠、氯化或磺酸氱化 聚乙烯、乙烯及氯化乙烯之共聚物、表氮酵均一及共聚 物;較佳為鹵化乙烯化合物之聚合物,例如聚一氯乙烯 、聚二氮亞乙烯、聚«乙烯、聚镉二氬乙烯,以及其共 聚物,例如氮乙烯/二氮亞乙烯、氯乙烯/醑酸乙烯酯或 二氛亞乙烯/醋酸乙烯酯共聚物。 8. α, /3-未飽和酸衍生之聚合物及其衍生物,如聚丙烯 酸酯及聚丙烯酸甲酯、聚丙烯醯胺及聚丙烯脯。 9.8)下所述單體互相間或舆其它未飽和單龌之共聚物, 例如丙烯脯/ 丁二烯共聚物、丙烯腈/丙烯酸烷酯共聚物 、丙烯請/烷基丙烯酸烷《酯或丙烯腈/鹵乙烯共聚物或 丙烯脯/甲基丙烯酸烷酯/ 丁二烯三聚物。 10.衍生自未飽和酵及胺或其之酵基衍生物或縮S之聚 合物,如聚乙烯酵、聚醣酸乙烯酯、聚硬脂酸乙烯酯、 聚苯氣酸乙烯酯、聚顆丁烯二酸乙烯酯、聚丁酸乙烯酯 、聚酞酸烯丙酯、或聚烯丙基三聚氱胺;及其輿1)中所 述烯之共聚物。 -8- (請先閱讀背面之"意事項再填寫本頁) 裝· -訂- 線- 本紙張尺度遑用中《國家樣準(CNS)甲4規格(210X297公釐) 81. 5 . 20.000(H) L050〇8 A6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(7 ) 11. 琢醚之均聚物及共聚物,如聚烷二酵、聚琛氣乙烷 、聚_氣丙烷或其與雙縮水甘油基醚之共聚物。 12. 聚縮醛,如聚氣甲烯及含有琛«乙烷當共單體之聚 氣甲烯和以熱塑性聚胺甲酸酯、丙烯酸酯或MBS修飾之 聚縮醛。 13. 聚環氧化苯撐及其硫化物或舆聚苯乙烯或聚S胺之 混合物。 14. 聚按甲酸酯,你衍生自聚醚、聚酯或聚丁二烯,帶 有終端Μ基在一邊,而帶有脂族或芳族聚異《酸·在另一 邊.及其共驅物。 15. 聚醏胺及共聚醯肢,其後衍生自二胺及二羧酸及/或 自胺基羧酸或相應之内醯胺,如聚醯胺4、聚醯胺6 、 聚醏胺6/6、6/10、6/9、6/12及4/6、聚醯胺11、聚蘼 胺12、縮合間二甲苯而得之芳族聚酵胺、二胺及己二酸 ;從六亞甲基二胺及異酞酸及/或對酞酸製得之聚胺, 含或不含笛修飾劑之»性醱,例如聚-2,4,4,-三甲基六 亞甲基對酞酸醯胺或聚間伸苯基異酞醏胺;上述聚醯胺 與聚烯之共聚物、烯共聚物、離子聚合物或化學鍵结或 接枝彈性體;或與聚醚,例如與聚乙二酵、聚丙二酵或 聚四亞甲二酵;及亦是以EPDM或ABS修飾之聚醯胺或共 聚睡胺,及在加工中縮合之聚醯胺UIM聚醣胺条统)。 1 6 .聚酥、聚醯亞胺及聚醯胺-醯亞胺和聚苯咪唑。 17.聚酯,葆衍生自二羧酸及二酵及/或自羥羧酸或相應 -9- ·(請先閲讀背面之•注意事項再填窝本頁) 裝· 訂· 線- 本紙張尺度逡用中國國家楳準(CHS)甲4規格(210X297公*) 81. 5. 20.000(H)
L050〇B A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(8 ) 之内酯,如聚乙烯對酞酸酯、聚丁烯對酞酸酯、聚-1,4 -二羥甲基琛己烷對酞酸酯、聚羥苄酸酯和衍生自羥基 終端聚酺之嵌段共聚醚酯;及亦是以聚硪酸酯或MBS修 飾之聚酯。 18. 聚硪酸酯及聚酯磺酸酯。 19. 聚礁、聚醚确及聚醚酮。 20. 二缩水甘油基化合物之聚醚,包括二縮水甘油基醚 及二酵,例如靨於雙酚A二缩水甘油基醚及雙酚A。 21. 天然聚合物,如雄維素、橡謬、明謬及其化學修飾 同条衍生物如鑛錐r描酸盡、鑛維素丙酸酯和纖維素丁 酸酯、或纖維素醚,如甲基纖雄素;及松脂和其衍生物 〇 22. 上述聚合物之混合物(聚摻和),例如PP/EPDM、聚釀 胺 6/Ei>DH或 ABS、PVC/EVA、PVS/ABS、PVC/MBS、PC/ABS 、PBTP/ABS、 PC/ASA、 PC/PBT、 PVC/CPE、 PVC/丙烯酸 酯、Ρ0Μ/熱塑性PUR、PC/熱塑性PUR、Ρ0Μ/丙烯酸酯、 POM/MBS、 PPE/HIPS、 PPE/PA6.6及共聚物、PA/HDPE、 PA/PP、 PA/PPOo 較佳之熱塑性聚合物你聚烯、聚苯乙烯、聚《乙烯、 聚氯亞乙烯、聚«亞乙烯、聚丙烯酸酯、聚甲基丙烯酸 酗、聚醯胺、聚酯、聚硪酸酯、芳族聚隳、芳族聚醚、 芳族聚醚S1、聚醯亞胺及聚乙烯咔唑。 熱固性及結構交聯聚合物典型上可為以下聚合物: -10- (請先閲讀背面之注意事項再填寫本頁) 裝- 訂- 線. 本紙張尺度遑用中國家榡準(CNS)甲4規格(210x297公*) 81. 5. 20,000(fl) 0b0〇8 五、發明説明(9 ) 物胺 合« 聚聚 聯三 交及胺 1.麻氱 脂 樹 0 甲 、聚 酚三 傺及 面脂 方樹 一 0 B 甲 / 除 酱 自 、 二r:甲 方酚 一如 其例 元 多 輿 酸 羧 二 和 飽 未 輿 和 鉋 自 C生 脂衍 樹係 酸其 酵 之酯 乾聚 非和 及飽 乾未 • · 2 3 素 鹵 含 其 是 亦 及 t 酯 聚 共 之 劑 聯 交 作 當 。 物fll 合變 化性 烯燒 乙燃 和低 酵之 酸 烯 丙酸脂樹 聯烯樹解 交丙酸、 可基酵脂 4 氣 5 樹 琛。 如酯 ,酸 酯烯 酸丙 嫌酯 丙聚 之或 代醣 取酸 自烯 生丙 衍酯 傈乙 ,酸 脂甲 樹胺 胺 氱 聚 三 輿 其 > 0 bn 賭 lU·! PH 樹樹 酯氧 酸琛 烯或 丙酯 或酸 脂気 樹異 酯聚 、聚 、 酷、脂 矽 • f 平 異 或 烯二 丁 如 例 烯二 聚 聯 交 自 生 衍 傜 醪 。 橡騮 6 橡 水當 缩 0 雙化 白硬 如有 例含 ,可 物其 化且 « 璨物 聚化 白氣 生琢 衍二 其族 ,脂 脂琛 樹自 氧或 璨醚 聯基 交油 7.甘 (請先閲讀背面之注意事項再填窝本頁) 裝· 訂· 線. 經濟部中央標準局貝工消費合作社印製 作交聯劑,或其可用硬化加速劑或照射而熱交聯。 在遒些交聯聚合物中,較佳為交迪琛《樹脂,如聚環 氧化物較佳係衍生自含有平均二值琛氡基在分子中之縮 水甘油基化合物。特別適合之编水甘油基化合物傺為連 有雜原子者(例如,硫,較佳為氣或《),尤其«(2,3-璨氧基琛戊基)_;多元脂族酵之二缠水甘油醚,如1,4 -丁二酵、或聚烷二酵,例如2, 2-«(4-羥環己基)丙烷; 多元酚之二縮水甘油基》,如間苯二酚、雙(對羥苯基) 本紙張尺度逍用中國國家#準(CNS)甲4規格(210x297公救) 81. 5. 20,000(H) 經濟部中央標準局员工消費合作社印製 __ 五、發明説明(10) 甲烷、2,2-雙(對羥苯基)丙烷、2,2-雙(4’-羥基-3',5’ -二溴苯基)丙烷、1,3-雙(對羥苯基)乙烷;以上二多元 酵式二多元酚之雙(/9-甲基縮水甘油基)醚;二羧酸之 二縮水甘油基酯,如酞酸、對肽酸、四氫酞酸及六 氫酞酸;含有二傾N原子之雜琛氮齡及一级胺及醯胺之 N,N-二縮水甘油基衍生物,及雙二级二醯胺及二胺之N, K1-二缩水甘油基衍生物,如二縮水甘油基苯胺· 如Ν,Ν -二縮水甘油基甲苯胺、Η ,Ν -二縮水甘油基對按苯 基甲基醚、Η , (Γ -二甲基-Ν , Ν ·-二縮水甘油基雙(對按苯 基)甲烷;Ν,,Ν’-二縮水甘油基-Μ-苯基異三聚*酸明; Ν’-二缩水甘油基伸乙脲;Ν,Ν* -二缩水甘油基-5, 5-二甲乙内醒脲、Ν,Ν’-二缩水甘油基-5-異丙基乙内醯解 、队許亞甲基雙(《*,厂-二缩水甘油基-5,5-二甲乙内醯 胺,1,3-雙(Ν-缠水甘油基-5,5-二甲乙内醯酾)-2-羥丙 烷;N,Η二縮水甘油基-5,5-二甲基-6-異丙基-5,6-二 氫尿嘧啶、三縮水甘油基異三聚«酸酯。 較佳之琛氣樹脂族群包括縮水甘油化酚醛樹脂、乙内 醯翮、肢酚、雙酚及芳族二胺或琢脂族琛氣化物。待佳 之琛氣樹脂傜缩水甘油化甲苯酚酚醛樹脂、雙酚Α及雙 酚F二缠水甘油醚、乙内醏解-N,Ν’-雙缩水甘油化物、 寺胺酚三縮水甘油化物、二胺二苯甲烷四縮水甘油化物 、乙烯琛己烯二氣化物、3 ,4 -琛氧基琛己基甲基- 3,4-琢氣基琛己烷羧酸酯或其混合物。 -12- -(請先閲讀背面之.注意事項再填寫本頁) 裝< -訂_ 線· 本紙張尺度遑用中Β Β家樣毕(CNS) Τ4規格(210X297公*) 81. 5 . 20.000(H) 五、發明説明(11) Μ 尚適合之琛«樹脂為該環氧化合物輿琛氣硬化_之預 反應加成物,例如雙酚Α二縮水甘油基醚輿雙酚Α之加 成物。或已經與帶有兩侮終躺羧基及琢氣化物之低聚明 預反應的加成物。 適合作琛氣樹脂之硬化劑為酸或_化合物。缠1合硬化 劑之例子··多元酚(間苯二酚、2,2-雙(4-羥苯基)丙烧) 或酚-甲醛樹脂;多元羧酸及其W,如肽酐、六肚酸 、4-甲基六氳Ife酸、3.6-内亞甲基四氫K酐、4-甲基-3 ,6 -内亞甲基四氫酞酐、3,4,5,6,7,7 -六氮内亞甲基四 氫肽酐、琥珀酐、己二酐、三甲基己二酐、癸二辭、順 丁烯二酐、十二基琥珀酐1,2,4,5-苯四甲酸酐、僱苯三 甲酸酐、二苯基酮四羧酸二酐,或該酐之混合物。 較佳之硬化劑的族群包括酚醛樹脂及聚羧酸鼾。 琛氣樹脂可另用固化加速劑固化,或僅用熱固化_媒 。固化加速劑及觴媒的例子為3-乙基-4-甲眯唑、三戊 銨酚鹽;單-或多酚(酚、二氣甲烷、柳酸);三氬化硼 及其輿有檐化合物的錯合物,如三《化硎醚錯合物及三 氟化硼胺錯合物(BF2/單乙胺錯合物);磷酸及三苯亞 先 閲 背 面 之 注 意 事 •項 再 填 寫 本 頁 裝 訂 線 經濟部中央標準局貝工消費合作社印製 量係 K 3 # 之量 脂耳 樹契 氣.等 琛用 佔使 傜常 量通 入剤 加化 之硬 常之 通脂 媒樹 觸氧 及琛 阐 〇 i X so 。加l 蟹化 酸固0. 磷的 至 安 光 及 質 性 面 表 ' 質 性 熱 。及 基霄 能 、 官械 之機 劑、 化性 硬特 及工 基加 氣強 琢增 其 本紙張尺度逍用中B國家楳準(CNS)甲4規格(210X297公釐) 81. 5 . 20,000(H) L050〇8 A 6 B6 經濟部中央標準局貝工消費合作社印製 五、發明説明(12) 定性之進一步的添加劑可摻合入此新穎配方中。該添加 劑之例子如細粒«充劑。加強缜充劑、助塑劑、潤》劑 及脱棋蘭、黏着促進劑、抗靜電劑、抗氣化两、熱及光 安定性顔料及染料。 在一較佳實施例中,此新穎组成物被成形成棋製物、 膜、Η、鐵維、或底材之至少一表面上之塗層。 此新穎组成物可由塑醪技術中已知之方法而製得。在 聚合物之成形技術中,如»製、壓棋、射出成形及擠製 中,將該自由基陽離子鹽加入以形成懸浮液,或將ΤΤΤ 輿網化合物聯合加至聚合物熔體,至少一熱固性塑膠之 起始物質,或分別地至各起始物質(例如至琛氧樹脂及 硬化劑)以形成溶液或想浮液,如,在成形後此自由基 陽離子鹽結晶或沈澱。在冷卻成針狀而於聚合物基質中 形成網狀結構之間。 在一特佳實施例中,此新穎組成物僳為膜或片狀或為 底材之至少一表面上之塗層。該實施例之製得方便上係 經由溶解或懸浮一熱塑性聚合物或熱固性聚合物或结構 及聯聚合物之至少一起始物質於溶劑或惰性溶劑中,然 後用已知塗覆方法將此溶液或懸浮液塗於一可能預熱之 底材上,其後加熱除去溶剤,而然後可交聯之混合物可 被固化。自身支撐之膜及片係将塗膜剝離底材或經由擠 製而得。 適合之底材的例子為:玻璃、金屬、塑膠、礦物及陶 _ 1 4 一 (請先閲讀背面之注意事項再填寫本頁) 裝. 訂- 線· 本紙張尺度边用中家樣準(CNS)甲4規格(210X 297公#) 81. 5 . 20.000(H) 經濟部中央標準局貝工消費合作社印製 ^〇5〇〇8 五、發明説明(li) 瓷材料、木及紙。底材可為任何外形,且典型上傺模製 物、絲、纖維、嫌物、棒、管、絲帶、片、板、简或鑄 製物。 適合之塗佈技術典型上傜刷、辊壓、刮塗、鑄、旋塗 、簾塗佈、噴霧。噴蓀方法像特佳者,一方面非常薄且 均勻之層,具有實質上各向同性、非常細目及均勻網狀 組嫌,傜可得自由基陽離子鹽之結晶針,而另一方面, 結晶針之大小及網狀組嫌之筛目寛度可由液滴大小加以 控制,即使用懸浮液噴霧。 適合聚合物及其起始物之惰性溶剤典型上係極性且較 佳傺非質子性溶劑,其可單獨或為至少二溶劑之混合液 以使用。該溶劑之代表性例子如:醚(二丁醮、四氫呋 喃、二噁烷、乙二酵單甲基或二甲基醚、乙二酵單乙基 或二乙基醚、二乙二酵二乙基醚、三乙二酵二甲醚), 鹵化烴(二氣甲烷、氯仿、1,2 -二氣乙烷、1,1,1-三氛 乙烷、1,1,2,2-四氣乙烷),羧酸酯及内_ (醋酸乙酯 、丙酸酯、苯甲酸乙酯、2-甲氣乙基醋酸酯、7-丁内 酯、δ-戊内酯、三甲基乙酵内酯),羧醯胺及内醛胺(N ,Η-二甲基甲醯胺、Ν,Ν-二乙基甲酵胺、Ν,Η-二甲基乙 醛胺、四甲脲、六甲基瞵酸三酵胺、7-丁内醏胺、e-己内醛胺、N -甲基吡咯啶酮、H -乙醯基吡咯啶酮、N -甲 基己内醛胺),亞碘(二甲亞碩),(二甲蜞、二乙M、 三亞甲基砚、四亞甲基砠),三级胺(N -甲基六氫吡啶、 -15- A 6 B6 •(請先閲讀背面之注意事項再填寫本頁) 裝· -線· 本紙張尺度逍用中國國家標毕(CNS)甲4規格(210X297公*) 81. 5. 20.000(H) A 6 B6 L〇50〇8
五、發明説明(lJ (請先閲讀背面之注意事項再填窝本頁) N-甲基鴫啉)取代之苯 < 苯甲腈、氦苯、鄰二氰苯、1·2, 4-三氯苯、硝苯、甲苯、二甲苯)及腈(乙腈、丙膪)。 塗佈技術之進行方便上可經由分別溶劑各播立成分然 後在應用所邐擇的技法之前使其结合。然而,製備兩種 成分溶液亦可行的,例如聚合物及ΤΤΤ或銅化合物•及 鋦化合物或ΤΤΤ ,或使這些成分结合於一溶掖中。在最 後狀況中,在塗佈前自由基限離子鹽可已經结晶出,但 是此實際上對塗層之所欲品質並無彩響。 溶液較佳為受熱過,方便上至50-250Τ。加熱底材以 加速溶劑之除去係有效的,其通常在溫度範困50至200 υ進行,直到塗層乾為止。若欲分離塗層而得到自身支 掙之膜或Η,則底材在塗佈前可以抗結塊劑處理。 經濟部中央標準局貝工消費合作社印製 一種選擇性的塗佈方法,包括:使針狀結晶之新穎的 自由基陽離子《懸浮於聚合物或熱固性聚合物之起欧物 質中,然後塗佈底材,其後除去溶劑,且若適合時,之 後進行固化以形成熱固性聚合物。亦可行的為從聚合物 粉或熱固性樹脂之固態起始物質及自由基m離子鹽而製 備乾燥粉混合物,然後用塗佈或靜霣塗佈方法將逭些混 合物加工至底材之層上。聚合物基質中之網狀組鐵亦以 逭些選擇性.方法製得。 製造底材上之CT錯合物的結晶針網狀.組嫌之純層,藉 由將底材溶液或於溶液中之CT錯合物懸浮液,且随後蒸 發溶_,傜亦可行的。該層可被霣化學金颶化以增加導 -1 6 - 81. 5. 20.000(H) 本紙張尺度逍用中家標毕(CNS)甲4規格(210x297公 經濟部中央標準局員工消費合作社印製 五、發明説明I (15) 電性,方便上用Cu、Pt或Pd。使該纯曆具有聚合物之保 護塗靥你可為有用的。 靥之厚度範圍可變化廣泛,傺視苗擇之塗佈方法而定 。噴霧法得到非常薄的膜,然而用刷或»製方法可得較 厚之層。靥的厚度典型上為0.01至5000 /i·,較佳0.1至 1000m·,最佳 0.1 至 500« 〇 視所選擇之聚合物而定,此新潁组成物是為不透明或 透明且具有顯著特性。因此,驚異地,塗層及棋製物具 有棰佳之放電能力,對不均物質這僳困難逹成或不能逹 成的。該組成物因此特別適用於製造靜«屏蔽成分之抗 靜電處理模製零件,及製造抗靜霣處理模製物。此高導 電性亦允許使用此新潁組成物當霉導腰,例如當顯示元 件或霣子構件之霄棰。此組成亦具極佳之機械強度及工 作性質。 以下實例詳細說明本發明。 A)斛備白由甚I»驢芊韉S_fiL6_L· 攪拌及浴粗180t!中,於氬氣下,將60毫克(TTT)溶於 33克7-丁内酯中(綠溶液)。將於5克7-丁内酯中之 15.3毫克(:11(:12*2112〇黄溶液加入之。两掉攪拌及油 浴加熱,使反應溶液於油浴中冷卻,於是針狀結晶(産 量:57毫克)。結晶之霉阻率為0.5至1Ω · CB。X射線 結構分析顯示産物傺為組成物TTT(CuCl2 之自由 -17- ·(請先閲讀背面之.注意事項再填寫本頁) 裝· 訂- -線, 本紙張尺度遑用中困國家標準(CNS)甲4規格(210X297公*) 81. 5 . 20.000(H) A6 B6 050S8 五、發明説明(ie) 基陽離子鹽。 審例A2至A8 : 重覆實例A1之程序,但是没有惰氣,且用無水CuCl2 或溶劑錯合物代替CuCl2 ·2Η20。 奮俐Α2 : 溶劑錯合物:CuCl2 (二甲亞碩),組成物TTT(CuCl2 0.44 ,ρ =0.7273Ω * c·'1 〇 窨锎A 3 : 溶劑錯合物:[CuCl2 (α-吡咯啶酮)]2 ,組成物ΤΤΤ (CuC 1 2 ) _ .., σ = 1.629Ω·* ♦ c _1 〇 0.43 竇例A4 : 溶劑錯合物:[CuCl 2 (四亞甲基碘)](聚合物),組成 物 TTT(CuCl2) , σ = 1.238Ω'1 «cm^o 0.44 奮例A5 溶劑錯合物:CuCl2 (α-甲毗啶)2 ,組成物ΤΤΤ (CuC 1 2 )〇42, σ' = 1 - 〇2 Ω -1 · car1。 窗例Α6 溶雨錯合物:[CuCl 2 (丁内酯)],(聚合物),組成物 TTT (CuC 1 2 )〇 59 * σ = 1 · 577 Ω -1 · cm·1 〇 審锎A7 溶劑錯合物:[CuCl2 (丁内酯)(聚合物),此溶液含 0.5¾水,組成物 TTT(CuC12)a£;1 , σ = 0.6954Ω·1 · O.bl c ffl 〇 -18- 本紙張尺度逍用中國困家«準(CNS)甲4規格(210X297公*) (請先閲讀背面之注意事項再填寫本頁) 裝. -線. 經濟部中央標準局員工消費合作社印製 81. 5. 20.000(H) 經濟部中央標準局貝工消費合作社印製 五、發明説明(17) 弯例Α8 用無水CuCl2代替溶劑錯合物;組成物TTT(CuCl 2 )λ ^ 0.44 ,σ - 1 . 1 Ω 'ι ·<:-*〇 宭锎R1 : 將9.0毫克ΤΤΤ及0.6克聚硪酸酯溶於160TC之18克 <r-丁内酯中,然後使此溶液舆於2克7-丁内酯中之 2.1毫克CuCl2 ·2Η20溶液相混合。將反應混合物噴 霧於預熱之玻璃板上(喷霧條件:玻璃噴嘴之直徑為1 毫米,推進氣體為氣•噴》至玻璃板距離約15公分。於 130¾蒸發溶劑,得到8橄米毫靥,具有於聚碩酸酯基 質中之TTT(CuCl2 )的導電針狀結晶之撤細針狀網狀組 嫌。電阻率為2.4· 103 Ω · cn。 啻期I B2: 於150t:將9.0毫克四硫四¥及0.6克聚磺酸酯溶於16 克甲氣苯中。再將2.0毫克CuCl2 ·2Η2〇於2克7-丁 内酯之溶液加至該溶液中。自由基陽離子鹽之小針結晶 立即發生。將此反應混合物噴霧於預熱之玻璃板上(噴 霧條件同Β1),然後於100Ρ蒸發溶_。此聚硪酸酯膜為 一透明、撖細、緊密、導電性針狀網狀組嫌。霣阻率為 6· 10 3 Ω · cb〇 表面放電之測試: 藉助直徑50撤米之負有電壓約3.4KV之鍍金的鎢線而 -19- ·(請先閲讀背面之注意項再填寫本頁) 裝. 訂- 線< 本紙張尺度逍用中B國家«準(CNS)甲4規格(210X297公*) 81. 5. 20.000(H) A6 B6 ^050〇8 五、發明説明(1浍 形成約200V之表面張力。控制電應以使每公分之線長的 轚流保持恆定20nA。用銀糊將此樣品黏結於玻體支撐體 及連接於支撐邊.緣之接«黏。在測試中,支撐體於電翬 放霣線下以約50公分/秒速度移動8 «米,然後停於浸 入接地導罨泡沫中之接觸點«。之後將樣本置於電場強 度計下(Isoprobe靜霣伏特計2 44, Monroe霣子公司)。 表面張力之減少用數位示波器健存。實例B1及B2之Η於 試驗中測試。在電晕放電充電後5秒鐘後,測表面張力 〇 結果: 實例Β1: 2 土 1伏特;實例Β2: 2 土伏特。 窨例Β3 : 將1毫克ΤΤΤ及2.5克聚硪酸酯於180*〇溶於14.5克之 7-丁内酯中。將5.5毫克CuCl2 *2Η20於1.5克含 0.5Χ水之7-丁内酯之溶液加至該溶液中。30秒鐘後, 用塗佈刀布玻璃板上將此配方作成270毫米厚度之濕膜 。於ιοου蒸發溶劑,随後於150t:乾燥此膜。此膜之電 阻率為500至800 Ω ♦ cm,且膜厚20毫米。 啻例B4 : 於1 5 0 t:將1 5 . 2 7毫克四硫四¥及3.7 5克雙酚A及雙酚 A之二縮水甘油基醚之聚醚溶於60甲氣苯中。約30分鐘 後,將2.5克由3.75毫克(:11(:12*2!120及2*;水在2.5克 7 -丁内酯之溶液及750撖升之含有聚胺甲酸酯低聚物 -2 0 - 本紙張尺度遑用中 家樣準(CNS)T4規格(210x297公*) (tr先閲讀背面之注意事項再填窝本頁) 裝. -線· 經濟部中央標準局貝工消費合作社印製 81. 5. 20.000(H) A6 B6 五、發明説明(19) (潤濕劑)於二甲苯中之甲氣苯溶液加入並混合。將反應 混合物噴霧於玻璃板上(噴霧條件:網雙流醱噴霧,推 進氣偽氬,噴嘴至玻璃板距離約20公分,噴霧速率4公 分/秒。於50它蒸發溶雨,得到一 5微米厚之於聚醚基 質中之ttt(Cuci 2 ) ^43的導電性結晶針之緊密網狀組 織的靥。電阻率為2· 103 Qcb。 奮例B 5 : 實例B1及B3之塗層保持於85X3, 85S!相對濕度600小 時。用四點方法測得電阻。此電阻實質上仍然不變。 ·(請先閲讀背面之注意事項再填寫本頁) 裝- 訂_ 線. 經濟部中央標準局員工消費合作社印製 -21- 本紙》尺度通用中B困家樣毕(CHS)甲4規格(210X297公*) 81. 5. 20.000(H)
Claims (1)
- ,:代+ * . ' < D7 第81105185號「四硫四革及氛化鏑之自由基 陽離子鹽,其製法及用途J專利案 (82年1月修正) .一種自由基陽離子鹽,具式(I)之組成 六、中請專-列範ffl+ X (I) 短汫部屮央橾準局Β工消«·合作社印¾ 其中X之值為-0.1至+0.2。 2. 如申請專利範圍第1項之自由基陽離子鹽 值為-0.05至 +0.15。 3. 如申請專利範圍第1項之自由基陽離子鹽 值為0.05至+ 0.1。 4. 如申諳專利範圍第1項之自由基陽離子鹽 值為-0.05至 +0.05。 5. 如申請專利範圍第1項之自由基陽離子鹽 值為-0.02。 6. —種裂備式(I )自由基陽離子鹽之方法, 水CuCl2、CuCl2水性錯合物—CUC12溶 有機溶劑中與四硫四¥反應。 7. 如申請專利範圍第6項之方法,其中無水 二氣化銅水性錯合物或二氣化銅溶劑錯合 四硫四¥之用量為0.3至0.8莫耳。 8. 如申諳專利範圍第7項之方法,其中無水 二氣化銅水性錯合物或二氛化銅溶劑錯合 ,其中X之 ,其中X之 ,其中X之 ,其中X之 其包运使無 劑錯合物於 二氣化銅、 物對每莫耳 二氛化銅、 物對每莫耳 請 先 Μ η 背.之 注 意.事 項 再 填 寫 本 1Γ 打 η. 22 表紙》尺度適用中BR家標準(CNS)甲4規格(2丨0x297公釐)經濟部屮央標準局貝工消贽合作社印製 六'申請專則苑ffl 四硫四¥之用量為0.35至0.6契耳。 9.如申諸專利範圉第6項之方法,其中二氛化銅之溶 劑錯合物含有溶劑含雜原子選自氣、硫、磷及氰所 構成之族群。 10. 如申請專利範圍第6項之方法,其係在高溫下進行 〇 11. 如申請專利範圔第10項之方法,其中溫度範圍傺30m 3〇ov 〇 12. —種组成物,包括: a) 熱固性、熱塑性或结構交聪之聚合物,及‘ b) 式(I )自由基陽雜子鹽,傜為在聚合物基質中之 结晶針網狀組黧形狀》 13. 如申請專利範圍第12項之组成物,其中含有佔該组 成物0.01至30重量X的自由基陽離子鹽。 14. 如申諸專利範圍第12項之组成物,其中熱塑性聚合 物换遘自族群包括:聚烯炫、聚苯乙烯、聚氬乙烯、聚'氯亞乙 烯、聚«亞乙烯、聚丙烯酸酯、聚甲基丙烯酸酯、聚酵胺、聚 酯、聚磺酸酯、芳族聚W、芳族聚醚、芳族聚醚5JS 、聚醯亞胺及聚畦。 15·如申請專利範圍第12項之組成物,其中熱固性聚合 物傜環氣樹脂。 16.如申請專利範圍第12項之组成物,其在底材之至少 一表面上成形為模製物、膜、K、纖維或塗層。 -23- (請先叫請背面之注意事項再填寫本百) .^* .訂· .綠· 本紙張尺度適用中B Η家樣準(CHS) «Μ規格P10X297公蝥) C7 D7 六、中^專利死IB 17. 如申請專利範圍第16項之組成物,其中塗靥厚0.01 至5000徹米。 18. 如申請專利範圍第16項之組成物,其中塗層厚0.1 至1000徹米。 19. 如申請專利.範圍第12項之組成物,其中式(I)之X值 為-0.05至 +0 . 15。 20. 如申請專利範圔第12項之组成物,其中式(I)之X值 為 0.05至 +0.1。 21. 如申請專利範圍第12項之組成物,其中式⑴之X 值 為-0.05至 +0.05。 22. 如申請專利範圍第12項之組成物,其中式(υ之X值 -0.0 2 〇 (請先聞讀背面之注意事項再填寫本百) ·«· 經濟部屮央標準局貝工消费合作社印製 •線· -24- 本紙*尺度適用中因Η家«準(CNS)T4規格(210x297公龙)
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US (3) | US5284600A (zh) |
EP (1) | EP0523003B1 (zh) |
JP (1) | JPH05194536A (zh) |
KR (1) | KR930002359A (zh) |
AT (1) | ATE127121T1 (zh) |
CA (1) | CA2072858A1 (zh) |
DE (1) | DE59203441D1 (zh) |
ES (1) | ES2076732T3 (zh) |
IE (1) | IE67553B1 (zh) |
MX (1) | MX9203841A (zh) |
TW (1) | TW205038B (zh) |
Cited By (5)
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US5639847A (en) * | 1995-05-25 | 1997-06-17 | Mearthane Products Corp. | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6063499A (en) * | 1992-04-16 | 2000-05-16 | Mearthane Products Corp. | Electrically conductive and semi-conductive polymers |
US6111051A (en) * | 1998-08-07 | 2000-08-29 | Mearthane Products Corporation | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6451438B1 (en) | 2000-11-30 | 2002-09-17 | Mearthane Products Corporation | Copolymerization of reactive silicone and urethane precursors for use in conductive, soft urethane rollers |
US8222341B2 (en) | 2009-03-17 | 2012-07-17 | Mearthane Products Corporation | Semi-conductive silicone polymers |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2696470B1 (fr) * | 1992-10-07 | 1994-11-04 | Rhone Poulenc Films | Compositions de polymères contenant des composés organiques amphiphiles électroactifs de la famille des complexes à transfert de charge et/ou des sels d'ions radicaux, leur obtention et leur utilisation. |
EP0523003B1 (de) * | 1991-07-02 | 1995-08-30 | Ciba-Geigy Ag | Radikalkationensalze von Tetrathiotetracen und Kupferchlorid, deren Herstellung und deren Verwendung |
US5441815A (en) * | 1994-08-29 | 1995-08-15 | Industrial Technology Research Institute | Process for producing easily removable polyimide resin film |
GB9418955D0 (en) * | 1994-09-21 | 1994-11-09 | Ciba Geigy Ag | Novel electroconductive composition |
GB2295351B (en) * | 1994-11-25 | 1998-12-16 | Tenmat Ltd | Composite articles |
US6939484B2 (en) * | 2003-12-04 | 2005-09-06 | E. I. Du Pont De Nemours And Company | Thick film conductor compositions for use in membrane switch applications |
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US3403165A (en) * | 1963-11-19 | 1968-09-24 | American Cyanamid Co | Tetrathiotetracene ion-radical salts |
CH612964A5 (zh) * | 1975-09-19 | 1979-08-31 | Ciba Geigy Ag | |
CH662567A5 (de) * | 1984-03-23 | 1987-10-15 | Ciba Geigy Ag | In 2-stellung substituiertes 5,6,11,12-tetrathio- und 5,6,11,12-tetraselenotetracene, verfahren zu ihrer herstellung und ihre verwendung. |
DE3870012D1 (de) * | 1987-04-03 | 1992-05-21 | Ciba Geigy Ag | Antistatische und elektrisch leitende polymere und formmassen. |
EP0344108A3 (de) * | 1988-05-27 | 1991-03-27 | Ciba-Geigy Ag | Elektroaktive ultradünne Schichten |
EP0504113A1 (de) * | 1991-03-15 | 1992-09-16 | Ciba-Geigy Ag | Verfahren zur Herstellung von peridichalkogenierten Aromaten |
JPH05202058A (ja) * | 1991-04-25 | 1993-08-10 | Ciba Geigy Ag | 5,6,11,12−テトラチオテトラセンの製造方法 |
EP0523003B1 (de) * | 1991-07-02 | 1995-08-30 | Ciba-Geigy Ag | Radikalkationensalze von Tetrathiotetracen und Kupferchlorid, deren Herstellung und deren Verwendung |
-
1992
- 1992-06-25 EP EP92810488A patent/EP0523003B1/de not_active Expired - Lifetime
- 1992-06-25 ES ES92810488T patent/ES2076732T3/es not_active Expired - Lifetime
- 1992-06-25 DE DE59203441T patent/DE59203441D1/de not_active Expired - Fee Related
- 1992-06-25 AT AT92810488T patent/ATE127121T1/de not_active IP Right Cessation
- 1992-06-29 US US07/906,074 patent/US5284600A/en not_active Expired - Fee Related
- 1992-06-30 TW TW081105185A patent/TW205038B/zh active
- 1992-06-30 CA CA002072858A patent/CA2072858A1/en not_active Abandoned
- 1992-06-30 MX MX9203841A patent/MX9203841A/es unknown
- 1992-07-01 KR KR1019920011661A patent/KR930002359A/ko not_active Application Discontinuation
- 1992-07-01 IE IE922149A patent/IE67553B1/en not_active IP Right Cessation
- 1992-07-02 JP JP4197465A patent/JPH05194536A/ja active Pending
-
1993
- 1993-11-16 US US08/153,247 patent/US5387627A/en not_active Expired - Fee Related
-
1994
- 1994-10-31 US US08/331,821 patent/US5504217A/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6063499A (en) * | 1992-04-16 | 2000-05-16 | Mearthane Products Corp. | Electrically conductive and semi-conductive polymers |
US6361484B1 (en) | 1992-04-16 | 2002-03-26 | Mearthane Products Corporation | Electrically conductive and semi-conductive polymers |
US5639847A (en) * | 1995-05-25 | 1997-06-17 | Mearthane Products Corp. | Preparation of conductive polyurethanes using a conductive quasi-solution |
US5898057A (en) * | 1995-05-25 | 1999-04-27 | Mearthane Products Corp. | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6184331B1 (en) | 1995-05-25 | 2001-02-06 | Mearthane Products Corporation | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6417315B2 (en) | 1995-05-25 | 2002-07-09 | Mearthane Products Corporation | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6111051A (en) * | 1998-08-07 | 2000-08-29 | Mearthane Products Corporation | Preparation of conductive polyurethanes using a conductive quasi-solution |
US6451438B1 (en) | 2000-11-30 | 2002-09-17 | Mearthane Products Corporation | Copolymerization of reactive silicone and urethane precursors for use in conductive, soft urethane rollers |
US8222341B2 (en) | 2009-03-17 | 2012-07-17 | Mearthane Products Corporation | Semi-conductive silicone polymers |
Also Published As
Publication number | Publication date |
---|---|
ATE127121T1 (de) | 1995-09-15 |
IE67553B1 (en) | 1996-04-17 |
EP0523003B1 (de) | 1995-08-30 |
MX9203841A (es) | 1993-01-01 |
EP0523003A1 (de) | 1993-01-13 |
US5504217A (en) | 1996-04-02 |
US5387627A (en) | 1995-02-07 |
US5284600A (en) | 1994-02-08 |
KR930002359A (ko) | 1993-02-23 |
JPH05194536A (ja) | 1993-08-03 |
ES2076732T3 (es) | 1995-11-01 |
CA2072858A1 (en) | 1993-01-03 |
DE59203441D1 (de) | 1995-10-05 |
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