TW202248273A - 熱硬化性樹脂組成物、高頻裝置、介電體基板及微帶天線 - Google Patents
熱硬化性樹脂組成物、高頻裝置、介電體基板及微帶天線 Download PDFInfo
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- TW202248273A TW202248273A TW111111406A TW111111406A TW202248273A TW 202248273 A TW202248273 A TW 202248273A TW 111111406 A TW111111406 A TW 111111406A TW 111111406 A TW111111406 A TW 111111406A TW 202248273 A TW202248273 A TW 202248273A
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- Prior art keywords
- thermosetting resin
- resin composition
- group
- titanate
- active ester
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 150
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 146
- 239000000758 substrate Substances 0.000 title claims description 71
- -1 ester compound Chemical class 0.000 claims abstract description 122
- 239000003822 epoxy resin Substances 0.000 claims abstract description 118
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 118
- 229920005989 resin Polymers 0.000 claims abstract description 75
- 239000011347 resin Substances 0.000 claims abstract description 75
- 239000000945 filler Substances 0.000 claims abstract description 69
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 61
- 150000002148 esters Chemical class 0.000 claims abstract description 53
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 48
- 239000004305 biphenyl Substances 0.000 claims abstract description 34
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 34
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 28
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 15
- 239000011777 magnesium Substances 0.000 claims abstract description 15
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 claims abstract description 10
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims abstract description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910002113 barium titanate Inorganic materials 0.000 claims abstract description 8
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 8
- FFQALBCXGPYQGT-UHFFFAOYSA-N 2,4-difluoro-5-(trifluoromethyl)aniline Chemical compound NC1=CC(C(F)(F)F)=C(F)C=C1F FFQALBCXGPYQGT-UHFFFAOYSA-N 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 6
- IJBYNGRZBZDSDK-UHFFFAOYSA-N barium magnesium Chemical compound [Mg].[Ba] IJBYNGRZBZDSDK-UHFFFAOYSA-N 0.000 claims abstract description 6
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052451 lead zirconate titanate Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 239000011701 zinc Substances 0.000 claims abstract description 6
- 229910002115 bismuth titanate Inorganic materials 0.000 claims abstract description 5
- 239000004848 polyfunctional curative Substances 0.000 claims description 63
- 239000004020 conductor Substances 0.000 claims description 46
- 125000003118 aryl group Chemical group 0.000 claims description 29
- 239000003054 catalyst Substances 0.000 claims description 26
- 230000005855 radiation Effects 0.000 claims description 24
- 238000012360 testing method Methods 0.000 claims description 24
- 230000009477 glass transition Effects 0.000 claims description 20
- 229920003986 novolac Polymers 0.000 claims description 19
- 125000001624 naphthyl group Chemical group 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- 238000000465 moulding Methods 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 13
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- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 12
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- 125000002947 alkylene group Chemical group 0.000 claims description 7
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical group OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- 125000005708 carbonyloxy group Chemical group [*:2]OC([*:1])=O 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000000101 thioether group Chemical group 0.000 claims description 3
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 101150091203 Acot1 gene Proteins 0.000 claims 1
- 102100025854 Acyl-coenzyme A thioesterase 1 Human genes 0.000 claims 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 claims 1
- WZEOVABZJGGUML-UHFFFAOYSA-N oxathiiran-3-one Chemical group O=C1OS1 WZEOVABZJGGUML-UHFFFAOYSA-N 0.000 claims 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract description 25
- 229910021523 barium zirconate Inorganic materials 0.000 abstract description 4
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 abstract description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
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- 239000011575 calcium Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 49
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- 150000001875 compounds Chemical class 0.000 description 31
- 239000011256 inorganic filler Substances 0.000 description 27
- 229910003475 inorganic filler Inorganic materials 0.000 description 27
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 25
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 25
- 125000000217 alkyl group Chemical group 0.000 description 22
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 17
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 14
- 150000003003 phosphines Chemical class 0.000 description 14
- 125000003545 alkoxy group Chemical group 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000005452 bending Methods 0.000 description 12
- 238000005259 measurement Methods 0.000 description 12
- 125000000962 organic group Chemical group 0.000 description 12
- 150000002989 phenols Chemical class 0.000 description 12
- 239000006087 Silane Coupling Agent Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
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- 125000004437 phosphorous atom Chemical group 0.000 description 10
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- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 10
- 125000003710 aryl alkyl group Chemical group 0.000 description 9
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- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 9
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
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- 125000000524 functional group Chemical group 0.000 description 6
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- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 5
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
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- JRNGUTKWMSBIBF-UHFFFAOYSA-N naphthalene-2,3-diol Chemical compound C1=CC=C2C=C(O)C(O)=CC2=C1 JRNGUTKWMSBIBF-UHFFFAOYSA-N 0.000 description 4
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- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 4
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
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JPH07241853A (ja) * | 1994-03-08 | 1995-09-19 | Kinugawa Rubber Ind Co Ltd | 誘電加熱成形型 |
JP2004124066A (ja) * | 2002-08-07 | 2004-04-22 | Toray Ind Inc | 高誘電体組成物 |
JP3680854B2 (ja) * | 2003-04-04 | 2005-08-10 | 東レ株式会社 | ペースト組成物およびこれを用いた誘電体組成物 |
JP2004315653A (ja) | 2003-04-16 | 2004-11-11 | Hitachi Chem Co Ltd | 樹脂組成物とその利用 |
JP2008106106A (ja) | 2006-10-24 | 2008-05-08 | Hitachi Chem Co Ltd | 高誘電率樹脂組成物,プリプレグ及びプリント配線板用積層板 |
CN103351578B (zh) * | 2013-07-19 | 2015-08-19 | 广东生益科技股份有限公司 | 一种用于形成天线用的介质基板的介质层的树脂组合物及其用途 |
JP6066865B2 (ja) * | 2013-08-15 | 2017-01-25 | 信越化学工業株式会社 | 高誘電率エポキシ樹脂組成物および半導体装置 |
TWI506077B (zh) * | 2013-12-31 | 2015-11-01 | Taiwan Union Technology Corp | 樹脂組合物及其應用 |
JP2018041998A (ja) | 2015-01-28 | 2018-03-15 | 日本化薬株式会社 | アンテナ、およびアンテナを有する電子装置 |
JP7067576B2 (ja) | 2020-02-21 | 2022-05-16 | 味の素株式会社 | 樹脂組成物 |
JP6870778B1 (ja) * | 2020-12-11 | 2021-05-12 | 昭和電工マテリアルズ株式会社 | 成形用樹脂組成物及び電子部品装置 |
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2022
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JP2024014929A (ja) | 2024-02-01 |
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JPWO2022202792A1 (ja) | 2022-09-29 |
WO2022202804A1 (ja) | 2022-09-29 |
WO2022202781A1 (ja) | 2022-09-29 |
KR20230160342A (ko) | 2023-11-23 |
TW202248340A (zh) | 2022-12-16 |
TW202248274A (zh) | 2022-12-16 |
JP7396534B2 (ja) | 2023-12-12 |
JP7347713B2 (ja) | 2023-09-20 |
JP7351434B2 (ja) | 2023-09-27 |
JPWO2022202781A1 (ja) | 2022-09-29 |
JP2023164926A (ja) | 2023-11-14 |
KR20230160869A (ko) | 2023-11-24 |
KR20230161473A (ko) | 2023-11-27 |
JP2023179419A (ja) | 2023-12-19 |
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