TW201350785A - Device for measuring film thickness and device for forming film - Google Patents

Device for measuring film thickness and device for forming film Download PDF

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TW201350785A
TW201350785A TW102106106A TW102106106A TW201350785A TW 201350785 A TW201350785 A TW 201350785A TW 102106106 A TW102106106 A TW 102106106A TW 102106106 A TW102106106 A TW 102106106A TW 201350785 A TW201350785 A TW 201350785A
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substrate
light
film thickness
film
optical
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TWI489080B (en
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Kyokuyo Sai
Yohei Hinata
Yoshiyuki Otaki
you-song Jiang
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Shincron Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/52Means for observation of the coating process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/542Controlling the film thickness or evaporation rate
    • C23C14/545Controlling the film thickness or evaporation rate using measurement on deposited material
    • C23C14/547Controlling the film thickness or evaporation rate using measurement on deposited material using optical methods
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0616Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating
    • G01B11/0625Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating with measurement of absorption or reflection

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Length Measuring Devices By Optical Means (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

Provided is a device for measuring film thickness capable of measuring optical film thickness with good precision. A device for measuring film thickness (6) comprising a projector (11) that projects light toward a monitor board (Sm) via a projector-side fiber (f1), an optical receiver (22) that receives, via a light receptor-side fiber (f2), light that is reflected by the monitor board (Sm) after being projected from the projector (11), and an optical sensing probe (13) formed by bundling a plurality of projector-side fibers (f1) and a plurality of light receptor-side fibers (f2), wherein a plurality of projector-side fiber (f1) end faces and a plurality of light receptor-side fiber (f2) end faces are disposed in the distal end face of the optical sensing probe (13) facing the monitor board (Sm). Each projector-side fiber (f1) end face is adjacent to a light receptor-side fiber (f2) end face and is arranged in an arcuate or annular shape, and each light receptor-side fiber (f2) end face is adjacent to a projector-side fiber (f1) end face and is arranged in an arcuate or annular shape.

Description

膜厚測定裝置及成膜裝置 Film thickness measuring device and film forming device

本發明係關於一種膜厚測定裝置及搭載有該膜厚測定裝置之成膜裝置,尤其係關於為了測定形成於被測定用基板之光學膜厚,而通過光纖向被測定用基板照射光,通過光纖接受由被測定用基板所反射之反射光的膜厚測定裝置及搭載有該膜厚測定裝置之成膜裝置。 The present invention relates to a film thickness measuring device and a film forming device equipped with the film thickness measuring device, and in particular, for measuring the optical film thickness formed on the substrate to be measured, the light is applied to the substrate to be measured through the optical fiber, and the light is passed through the optical fiber. A film thickness measuring device that receives reflected light reflected by a substrate to be measured, and a film forming device on which the film thickness measuring device is mounted.

在利用光學薄膜之各領域中,希望以良好的精度來形成光學薄膜以達成特定膜厚。另一方面,對於光學薄膜之高精度之膜厚控制而言,準確的膜厚測定不可或缺。再者,此處所謂之膜厚為光學膜厚,其係由物理膜厚及薄膜之折射率而決定之值。 In various fields in which optical films are utilized, it is desirable to form an optical film with good precision to achieve a specific film thickness. On the other hand, accurate film thickness measurement is indispensable for high-precision film thickness control of optical films. Here, the film thickness referred to herein is an optical film thickness which is determined by the physical film thickness and the refractive index of the film.

作為膜厚之測定方法,已知有反射式測定法,該方法係利用因光學薄膜之表面上被反射之光線、與於基板與光學薄膜之界面被反射之光線的路徑不同而產生相位差從而產生干涉的現象來測定膜厚,關於採用該測定法之膜厚測定裝置,提出有各種裝置。 As a method for measuring the film thickness, a reflection type measuring method is known in which a phase difference is generated by a light reflected from a surface of an optical film and a path of light reflected at an interface between the substrate and the optical film. The film thickness was measured by the phenomenon of interference, and various apparatuses were proposed regarding the film thickness measuring apparatus using this measuring method.

作為先前之膜厚測定裝置之一例,可列舉專利文獻1中所記載之搭載於成膜裝置之膜厚測定裝置。於該裝置中,投射至光學薄膜之光通過光纖而自光源傳輸,於基板與光學薄膜之界面被反射之光通過光纖而傳輸至分光器。 An example of the film thickness measuring apparatus described in Patent Document 1 is a film thickness measuring device mounted in a film forming apparatus. In the device, light projected onto the optical film is transmitted from the light source through the optical fiber, and light reflected at the interface between the substrate and the optical film is transmitted through the optical fiber to the optical splitter.

又,於膜厚測定裝置搭載於真空成膜裝置內之情況下,在裝 置內一併設置最終成為多層膜製品之基板與監測玻璃,以與基板相同之條件亦於監測玻璃形成薄膜。而且,成膜步驟中,測定形成於監測玻璃側之薄膜的光學膜厚,而監測成膜狀況。藉此,可測定形成於基板側之多層膜之各層的光學膜厚。再者,於先前之真空成膜裝置中,在成膜步驟中,當每次使形成於基板之多層膜之各層成膜時,監測玻璃自完成成膜之玻璃更換為新玻璃、即成膜前之監測玻璃。 Moreover, when the film thickness measuring device is mounted in a vacuum film forming apparatus, it is mounted. The substrate and the monitoring glass which finally become the multilayer film product are disposed together, and the film is formed by monitoring the glass under the same conditions as the substrate. Further, in the film forming step, the optical film thickness of the film formed on the side of the monitoring glass was measured, and the film formation condition was monitored. Thereby, the optical film thickness of each layer of the multilayer film formed on the substrate side can be measured. Further, in the prior vacuum film forming apparatus, in the film forming step, each time the layers of the multilayer film formed on the substrate are formed into a film, the glass is replaced with a new glass, that is, a film is formed. Pre-monitoring glass.

[專利文獻1]日本專利3866933號公報 [Patent Document 1] Japanese Patent No. 3866693

然而,於反射式之膜厚測定中,於光線相對於基板之光學薄膜成角度地入射之情況下,膜厚之測定值薄於光線相對於光學薄膜垂直地照射之情況的膜厚、即本來之膜厚。若具體地說明,則將光線相對於基板之光學膜之入射角度設為θ,將光學膜之折射率設為n,將本來之膜厚設為d0,則膜厚之測定值d成為滿足下述式(1)之值。 However, in the measurement of the film thickness of the reflective type, when the light is incident at an angle with respect to the optical film of the substrate, the measured value of the film thickness is thinner than the film thickness of the light when the light is perpendicularly irradiated to the optical film, that is, originally The film thickness. Specifically, when the incident angle of the light with respect to the optical film of the substrate is θ, the refractive index of the optical film is n, and the original film thickness is d0, the measured value d of the film thickness is satisfied. The value of the formula (1).

d=(d0/n2)×√{n2-(sin θ)2} (1) d=(d0/n 2 )×√{n 2 -(sin θ) 2 } (1)

因此,入射角度θ越大,膜厚之測定誤差△d(=d0-d)越大,膜厚之測定精度越低。 Therefore, the larger the incident angle θ, the larger the measurement error Δd (=d0-d) of the film thickness, and the lower the measurement accuracy of the film thickness.

再者,如圖9所示,入射角度θ相當於朝向基板入射之光之光路、與於基板側被反射之光之光路所成之角度的一半。圖9係關於入射角度之說明圖。 Further, as shown in FIG. 9, the incident angle θ corresponds to half the angle between the optical path of the light incident on the substrate and the optical path of the light reflected on the substrate side. Fig. 9 is an explanatory diagram regarding an incident angle.

若考慮此種入射角度θ與膜厚之測定誤差△d之關係,則較理想為,對於對光學薄膜照射之投光器,使實際照射光之部分的面積(有效投光範圍)儘可能小,而使入射角度θ減小。 In consideration of the relationship between the incident angle θ and the measurement error Δd of the film thickness, it is preferable that the area (effective emission range) of the portion of the actual irradiation light is as small as possible for the light projector that irradiates the optical film. The incident angle θ is decreased.

又,為了對光學薄膜之特定位置以良好的精度照射光,有時會於投光器與光學薄膜之間設置集光透鏡,隔著該集光透鏡對光學薄膜照射光。同樣地,為了確實地接受自光學薄膜反射之反射光,有時會於受光器與光學薄膜之間設置受光透鏡,隔著該受光透鏡而接受來自光學薄膜之反射光。於此情況下,對應於光通過透鏡之量,照度有所衰減,有對膜厚之測定精度造成影響之虞。 Further, in order to irradiate light with a high precision at a specific position of the optical film, a collecting lens may be provided between the light projector and the optical film, and the optical film may be irradiated with light through the collecting lens. Similarly, in order to reliably receive the reflected light reflected from the optical film, a light receiving lens may be disposed between the light receiver and the optical film, and the reflected light from the optical film may be received through the light receiving lens. In this case, the illuminance is attenuated corresponding to the amount of light passing through the lens, which has an effect on the measurement accuracy of the film thickness.

進而,若於每次於形成有多層膜之基板形成各層時更換監測玻璃,則於尺寸、表面狀態及加工精度之方面,於監測玻璃間會產生不均,有該不均對薄膜測定精度造成影響之虞。 Further, if the monitoring glass is replaced every time the respective layers are formed on the substrate on which the multilayer film is formed, unevenness occurs between the monitoring glasses in terms of size, surface state, and processing accuracy, and the unevenness causes measurement accuracy of the film. The impact of the impact.

而且,若因如上理由而無法準確地進行光學膜厚之測定,則反映該測定結果而執行之膜厚控制之精度亦降低,不易獲得成為所期望之膜厚之薄膜。 In addition, if the measurement of the optical film thickness cannot be accurately performed for the above reasons, the accuracy of the film thickness control performed by reflecting the measurement result is also lowered, and it is difficult to obtain a film having a desired film thickness.

因此,本發明之目的在於提供一種能以良好的精度來測定光學膜厚之膜厚測定裝置。而且,本發明之另一目的在於提供一種可基於光學膜厚之準確之測定結果,而以良好的精度來控制形成於基板之薄膜之膜厚的成膜裝置。 Accordingly, an object of the present invention is to provide a film thickness measuring device capable of measuring an optical film thickness with good precision. Further, another object of the present invention is to provide a film forming apparatus which can control the film thickness of a film formed on a substrate with good precision based on an accurate measurement result of an optical film thickness.

只要利用本發明之膜厚測定裝置,則上述問題藉由下述方式而得以解決:具備:照射裝置:其係為了測定形成於被測定用基板之膜的光學膜厚,而通過由光纖構成之照射側纖維向上述被測定用基板照射光;受光裝置:其係為了測定上述光學膜厚,而通過由光纖構成之受光側纖維,接受於自上述照射裝置照射後由上述被測定用基板反射之光;及探針:其係捆束複數根上述照射側纖維及複數根上述受光側纖維而形成;於該探針 之作為端面而設於與上述被測定用基板相對向之側的對向面,分別配置有複數個上述照射側纖維之端面及上述受光側纖維之端面;於上述對向面,複數個配置之上述照射側纖維之端面的各者均係於與至少1個上述受光側纖維之端面相鄰的狀態下排列成圓弧狀或圓環狀,且複數個配置之上述受光側纖維之端面的各者均係於與至少1個上述照射側纖維之端面之各者相鄰的狀態下排列成圓弧狀或圓環狀。 According to the film thickness measuring apparatus of the present invention, the above problem can be solved by providing an irradiation apparatus which is formed of an optical fiber in order to measure the optical film thickness of the film formed on the substrate to be measured. The irradiation-side fiber is irradiated with light to the substrate to be measured, and the light-receiving device receives the light-receiving fiber made of an optical fiber and is reflected by the substrate for measurement after being irradiated from the irradiation device. And a probe which is formed by binding a plurality of the above-mentioned irradiation side fibers and a plurality of the above-mentioned light-receiving side fibers; An end surface of the plurality of the irradiation-side fibers and an end surface of the light-receiving side fiber are disposed on the opposite surface of the opposite side of the substrate to be measured, and the plurality of the opposite surfaces are disposed on the opposite surface. Each of the end faces of the irradiation-side fibers is arranged in an arc shape or an annular shape in a state of being adjacent to an end surface of at least one of the light-receiving-side fibers, and each of the end faces of the light-receiving side fibers disposed in a plurality of positions Each of them is arranged in an arc shape or an annular shape in a state adjacent to each of the end faces of at least one of the irradiation-side fibers.

於上述薄膜測定裝置中,於探針之作為端面而設於與被測定用基板相對向之側的對向面,若照射側纖維之端面與受光側纖維之端面彼此相鄰,則自照射裝置對薄膜照射之光之入射角度進一步減小。 In the above-mentioned film measuring apparatus, the opposite surface of the probe which is provided on the side opposite to the substrate to be measured is the self-irradiating device when the end faces of the irradiation-side fibers and the end faces of the light-receiving fibers are adjacent to each other. The angle of incidence of the light that illuminates the film is further reduced.

若具體地說明,則於照射側纖維之端面與受光側纖維之端面彼此相鄰的情況下,與兩光纖之端面不相鄰之情況相比,自照射側纖維之端面照射之光去往薄膜時之光路、與該光由被測定用基板反射而去往受光側纖維之端面時之光路所成的角度進一步減小。另一方面,入射角度為上述2條光路所成之角度之大小的1/2,因此,於照射側纖維之端面與受光側纖維之端面彼此相鄰之情況時,入射角度亦進一步減小。如此,若入射角度減小,則根據上述入射角度與膜厚之測定誤差△d之關係(具體而言為上述式(1)),測定誤差△d減小。 Specifically, when the end faces of the irradiation-side fibers and the end faces of the light-receiving fibers are adjacent to each other, the light irradiated from the end faces of the irradiation-side fibers is transferred to the film as compared with the case where the end faces of the two fibers are not adjacent to each other. The angle of the light path and the optical path when the light is reflected by the substrate for measurement and goes to the end surface of the light-receiving side fiber is further reduced. On the other hand, since the incident angle is 1/2 of the angle formed by the two optical paths, the incident angle is further reduced when the end faces of the irradiation-side fibers and the end faces of the light-receiving fibers are adjacent to each other. As described above, when the incident angle is decreased, the measurement error Δd is reduced in accordance with the relationship between the incident angle and the measurement error Δd of the film thickness (specifically, the above formula (1)).

又,若照射側纖維之端面與受光側纖維之端面彼此相鄰,則可通過受光側纖維而有效率地接受反射光。 Further, when the end faces of the irradiation side fibers and the end faces of the light receiving side fibers are adjacent to each other, the reflected light can be efficiently received by the light receiving side fibers.

進而,探針之端面之光纖之填充率越高,膜厚測定之精度越高,因此通常於探針之端面內,光纖之端面以密集狀態配置。另一方面,光纖之端面越密集,照射側纖維之端面彼此及受光側纖維之端面彼此越容 易密集。相對於此,若於探針之端面以使照射側纖維之端面與受光側纖維之端面分別排列成圓弧狀或圓環狀之方式配置各光纖,則可有效率地實現如照射側纖維與受光側纖維彼此相鄰之光纖配置。 Further, the higher the filling rate of the optical fiber of the end face of the probe, the higher the accuracy of the film thickness measurement. Therefore, the end face of the optical fiber is usually arranged in a dense state in the end face of the probe. On the other hand, the denser the end faces of the optical fibers, the end faces of the fibers on the irradiation side and the end faces of the fibers on the light receiving side are more distant from each other. Easy to intensive. On the other hand, when the end faces of the probes are arranged such that the end faces of the irradiation-side fibers and the end faces of the light-receiving fibers are arranged in an arc shape or an annular shape, the fibers on the irradiation side can be efficiently realized. The fibers on the light-receiving side are disposed adjacent to each other.

藉由如上之作用,請求項1所記載之膜厚測定裝置與先前之裝置相比,可以更佳的精度來測定光學膜厚。 As described above, the film thickness measuring device described in claim 1 can measure the optical film thickness with higher accuracy than the prior art device.

又,於上述膜厚測定裝置中,較佳為,上述探針係於上述對向面與上述被測定用基板之間未設置有光學零件的狀態下,以上述對向面與上述被測定用基板中位於形成有上述膜之側相反側的非成膜面相對向。 Further, in the film thickness measuring device, it is preferable that the probe is in a state in which the optical component is not provided between the opposite surface and the substrate to be measured, and the opposite surface and the measurement target are used. The non-film formation faces on the opposite side of the substrate on the side where the film is formed are opposed to each other.

於以上之構成中,未使用集光透鏡或受光透鏡,因此可抑制光損失,於通過受光側纖維而接受反射光時,能以相對較大之照度接受反射光。而且,相應於通過受光側纖維而接受之光之光量變大的程度,為了算出膜厚而對該光進行分光分析時之S/N比提昇。因此,根據請求項2所記載之構成,可以更良好的精度來測定光學膜厚。 In the above configuration, since the collecting lens or the light receiving lens is not used, light loss can be suppressed, and when the reflected light is received by the light receiving side fiber, the reflected light can be received with a relatively large illuminance. Further, in accordance with the extent to which the amount of light received by the light-receiving side fibers is increased, the S/N ratio at the time of spectroscopic analysis of the light is increased in order to calculate the film thickness. Therefore, according to the configuration described in the claim 2, the optical film thickness can be measured with higher precision.

又,於上述薄膜測定裝置中,更佳為,構成上述探針之複數根上述照射側纖維及複數根上述受光側纖維係形成為端面於上述對向面對齊之束狀光纖,上述對向面與上述成膜面之間的距離為上述束狀光纖之直徑的2倍以上。 Further, in the film measuring device, it is preferable that the plurality of the irradiation side fibers and the plurality of light receiving side fibers constituting the probe are formed as bundle fibers having end faces aligned on the opposite faces, and the opposite direction The distance between the surface and the film formation surface is twice or more the diameter of the bundled optical fiber.

於以上之構成中,光對於薄膜之入射角度、換言之為由薄膜所反射之光之反射角度係受光側纖維之數值孔徑NA以下。於此情況下,通過受光側纖維而接受光時之受光效率進一步提高。因此,根據請求項3所記載之構成,能以更佳的精度來測定光學膜厚。 In the above configuration, the incident angle of light to the film, in other words, the angle of reflection of the light reflected by the film, is equal to or less than the numerical aperture NA of the light-receiving fiber. In this case, the light-receiving efficiency when light is received by the light-receiving side fiber is further improved. Therefore, according to the configuration described in the claim 3, the optical film thickness can be measured with better accuracy.

又,於上述薄膜測定裝置中,上述被測定用基板亦可為圓盤 狀或圓環狀之基板。即,於請求項4所記載之構成中,能以良好的精度來測定形成於圓盤狀或圓環狀之被測定用基板之薄膜的光學膜厚。進而,於可進行膜厚之多點監測之膜厚測定裝置中,若使用圓盤狀或圓環狀之基板,則與例如矩形狀之基板相比,可使監測點數進一步增多。 Further, in the film measuring device, the substrate to be measured may be a disk Shaped or annular substrate. In other words, in the configuration described in the claim 4, the optical film thickness of the film formed on the disk-shaped or annular substrate to be measured can be measured with good precision. Further, in the film thickness measuring device capable of performing multi-point monitoring of the film thickness, when a disk-shaped or annular substrate is used, the number of monitoring points can be further increased as compared with, for example, a rectangular substrate.

又,於上述薄膜測定裝置中,亦可具有:上述照射裝置;直流穩定化電源:其對設置於上述照射裝置之光源供給直流電流;上述探針;分光器:其具備上述受光裝置,輸出與上述受光裝置接受由上述被測定用基板所反射之光時之受光強度對應的類比訊號;放大器:其放大自該分光器所輸出之上述類比訊號;A/D轉換器:其將藉由該放大器所放大之上述類比訊號轉換為數位訊號;電子計算機:其基於上述數位訊號而運算上述光學膜厚;及訊號處理電路:其介於上述A/D轉換器與上述電子計算機之間,於上述電子計算機運算上述光學膜厚時用以對上述數位訊號執行特定之訊號處理。即,於請求項5所記載之構成中,具備與通常之薄膜測定裝置所具備之構成機器同樣的機器,並且能以良好的精度來測定薄膜之光學膜厚。 Further, the film measuring device may further include: the irradiation device; a DC stabilized power supply that supplies a direct current to a light source provided in the irradiation device; and the probe; the spectroscope includes the light receiving device, and outputs The light receiving device receives an analog signal corresponding to the received light intensity when the light reflected by the substrate to be measured is received; the amplifier: amplifies the analog signal outputted from the optical splitter; and the A/D converter: which is to be used by the amplifier Converting the above analog signal into a digital signal; an electronic computer: calculating the optical film thickness based on the digital signal; and a signal processing circuit: between the A/D converter and the electronic computer, the electronic The computer calculates the optical film thickness to perform specific signal processing on the digital signal. In other words, the configuration described in the claim 5 includes the same equipment as that of the conventional thin film measuring device, and the optical film thickness of the film can be measured with good precision.

又,只要是本發明之成膜裝置,則上述問題藉由下述方式而得以解決:一種藉由在真空容器內使蒸鍍材料蒸鍍於基板之表面而在上述基板形成膜的成膜裝置,且具備:蒸發機構:其用以使上述蒸鍍材料蒸發;開閉構件:其為了阻斷該蒸發機構所蒸發之上述蒸鍍材料往上述基板表面時的路線而進行開閉動作;控制機構:其控制該開閉構件之開閉;及請求項1至5中任一項之膜厚測定裝置;且,於上述基板及上述被測定用基板之兩者被收容於上述真空容器內的狀態下,上述蒸發機構使上述蒸鍍材料 蒸發,以使上述蒸鍍材料蒸鍍於該兩者之表面,上述膜厚測定裝置測定形成於上述被測定用基板之膜的上述光學膜厚,上述控制機構根據由上述膜厚測定裝置所得之上述光學膜厚之測定結果來控制上述開閉構件之開閉。 Further, as long as it is the film forming apparatus of the present invention, the above problem can be solved by a film forming apparatus for forming a film on the substrate by vapor-depositing a vapor deposition material on the surface of the substrate in a vacuum vessel. And an evaporation mechanism for evaporating the vapor deposition material, and an opening and closing member for opening and closing the route for blocking the vapor deposition material evaporated by the evaporation mechanism to the surface of the substrate; and a control mechanism: The opening and closing of the opening and closing member; and the film thickness measuring device according to any one of claims 1 to 5; wherein the evaporation is performed in a state in which both the substrate and the substrate to be measured are housed in the vacuum container The mechanism makes the above vapor deposition material Evaporating to deposit the vapor deposition material on the surfaces of the both, wherein the film thickness measuring device measures the optical film thickness of the film formed on the substrate to be measured, and the control means is obtained by the film thickness measuring device. The opening and closing of the opening and closing member is controlled as a result of measurement of the optical film thickness.

以如上方式構成之成膜裝置具備發揮上述效果之膜厚測定裝置,因此能以良好的精度來測定膜厚,進而,根據該測定結果進行膜厚控制。因此,若為請求項6所記載之成膜裝置,則可基於光學膜厚之準確之測定結果,而以良好的精度來控制形成於基板之薄膜之膜厚。 Since the film forming apparatus configured as described above includes the film thickness measuring device that exhibits the above-described effects, the film thickness can be measured with good precision, and the film thickness can be controlled based on the measurement result. Therefore, in the film forming apparatus described in the claim 6, the film thickness of the film formed on the substrate can be controlled with good precision based on the accurate measurement result of the optical film thickness.

又,於上述成膜裝置中,更佳為,於將多層膜形成於上述基板之期間,於上述真空容器內配置相同之上述被測定用基板,亦於上述被測定用基板形成上述多層膜,上述膜厚測定裝置係測定形成於上述被測定用基板之上述多層膜中每一層膜的上述光學膜厚。 Further, in the film forming apparatus, it is preferable that the same substrate to be measured is disposed in the vacuum container while the multilayer film is formed on the substrate, and the multilayer film is formed on the substrate to be measured. The film thickness measuring device measures the optical film thickness of each of the multilayer films formed on the substrate to be measured.

若為以上之構成,則於在基板形成多層膜期間,不更換被測定用基板,而於每次在被測定用基板形成多層膜之各層時,測定該各層之膜的光學膜厚,因此可抑制每次測定各層之膜厚時因被測定用基板變化而產生之影響。因此,若為請求項7所記載之成膜裝置,則能以良好的精度來測定形成於基板之多層膜之各層的膜厚,且能基於該測定結果以更佳的精度來進行膜厚控制。 According to the above configuration, when the multilayer film is formed on the substrate, the substrate for measurement is not replaced, and the optical film thickness of the film of each layer is measured each time the respective layers of the multilayer film are formed on the substrate to be measured. It is suppressed that the influence of the substrate to be measured changes when the film thickness of each layer is measured each time. Therefore, in the film forming apparatus described in the claim 7, the film thickness of each layer of the multilayer film formed on the substrate can be measured with good precision, and the film thickness control can be performed with better precision based on the measurement result. .

請求項1所記載之膜厚測定裝置與先前之裝置相比,能以更佳的精度來測定光學膜厚。 The film thickness measuring device described in claim 1 can measure the optical film thickness with higher precision than the prior art device.

請求項2所記載之膜厚測定裝置能對應於分光分析之S/N比提昇之程度,而以更佳的精度來測定光學膜厚。 The film thickness measuring device described in claim 2 can measure the optical film thickness with better accuracy in accordance with the degree of improvement in the S/N ratio of the spectroscopic analysis.

請求項3所記載之膜厚測定裝置中,由薄膜反射之光之反射角度為受 光側纖維之數值孔徑NA以下,因此能以更佳的精度來測定光學膜厚。 In the film thickness measuring device described in claim 3, the reflection angle of the light reflected by the film is affected by Since the optical side fiber has a numerical aperture NA or less, the optical film thickness can be measured with better precision.

請求項4所記載之膜厚測定裝置能以良好的精度來測定形成於圓盤狀或圓環狀之被測定用基板之薄膜之光學膜厚。進而,於可進行膜厚之多點監測的膜厚測定裝置中,若使用圓盤狀或圓環狀之基板,則與矩形狀之基板相比,可使監測點數進一步增多。 The film thickness measuring device described in the claim 4 can measure the optical film thickness of the film formed on the disk-shaped or annular substrate to be measured with good precision. Further, in the film thickness measuring device capable of performing multi-point monitoring of the film thickness, when a disk-shaped or annular substrate is used, the number of monitoring points can be further increased as compared with the rectangular substrate.

請求項5所記載之膜厚測定裝置具備與通常之薄膜測定裝置所具備之構成機器同樣的機器,並且能以良好的精度來測定薄膜之光學膜厚。 The film thickness measuring device described in claim 5 has the same equipment as that of the conventional film measuring device, and the optical film thickness of the film can be measured with good precision.

請求項6所記載之成膜裝置能以良好的精度來測定膜厚,且根據該測定結果而以良好的精度來進行膜厚控制。 The film forming apparatus described in claim 6 can measure the film thickness with good precision, and based on the measurement result, the film thickness control can be performed with good precision.

請求項7所記載之成膜裝置中,於測定形成於基板之多層膜之各層的光學膜厚時能抑制於每層因被測定用基板變更而產生之影響,相應於此,能以良好的精度來測定形成於基板之多層膜之各層的膜厚,且能基於該測定結果而以更佳的精度來進行膜厚控制。 In the film forming apparatus of the seventh aspect, when the optical film thickness of each layer of the multilayer film formed on the substrate is measured, it is possible to suppress the influence of each substrate on the substrate to be measured, and accordingly, it is possible to obtain a favorable effect. The film thickness of each layer of the multilayer film formed on the substrate is measured with accuracy, and film thickness control can be performed with better precision based on the measurement result.

1‧‧‧真空容器 1‧‧‧vacuum container

2‧‧‧基板保持器 2‧‧‧Substrate holder

2a‧‧‧開口 2a‧‧‧ openings

3‧‧‧蒸發機構 3‧‧‧Evaporation mechanism

4‧‧‧擋閘 4‧‧‧ blocking

5‧‧‧擋閘控制單元 5‧‧‧Block control unit

6‧‧‧膜厚測定裝置 6‧‧‧ Film thickness measuring device

11‧‧‧投光器 11‧‧‧Light projector

12‧‧‧直流穩定化電源 12‧‧‧DC stabilized power supply

13‧‧‧光學感測器用探針 13‧‧‧Probes for optical sensors

14‧‧‧分光器 14‧‧‧ Spectroscope

15‧‧‧放大器 15‧‧‧Amplifier

16‧‧‧A/D轉換器 16‧‧‧A/D converter

17‧‧‧訊號處理電路 17‧‧‧Signal Processing Circuit

21‧‧‧光源 21‧‧‧Light source

22‧‧‧受光裝置 22‧‧‧Light receiving device

23‧‧‧軟管 23‧‧‧Hose

24A‧‧‧接合連接器 24A‧‧‧ joint connector

24B‧‧‧接合連接器 24B‧‧‧ joint connector

24C‧‧‧中間連接器 24C‧‧‧Intermediate connector

25‧‧‧保護筒 25‧‧‧protection cylinder

25a‧‧‧大徑部 25a‧‧‧The Great Trails Department

25b‧‧‧小徑部 25b‧‧‧Little Trails Department

100‧‧‧真空蒸鍍裝置 100‧‧‧Vacuum evaporation device

f1‧‧‧照射側纖維 F1‧‧‧illuminated side fiber

f2‧‧‧受光側纖維 F2‧‧‧light-receiving fiber

PC1‧‧‧第1電腦 PC1‧‧‧1st computer

PC2‧‧‧第2電腦 PC2‧‧‧2nd computer

PLC‧‧‧可程式邏輯控制器 PLC‧‧‧programmable logic controller

S‧‧‧實際基板 S‧‧‧ actual substrate

Sm‧‧‧監測基板 Sm‧‧‧ monitoring substrate

θ‧‧‧入射角度 Θ‧‧‧incidence angle

圖1係表示本實施形態之成膜裝置之概略構成之圖。 Fig. 1 is a view showing a schematic configuration of a film forming apparatus of the embodiment.

圖2係本實施形態之探針之模式側視圖。 Fig. 2 is a schematic side view of the probe of the embodiment.

圖3(A)及(B)係表示第1例中之光纖之配置位置之圖。 3(A) and 3(B) are views showing the arrangement positions of the optical fibers in the first example.

圖4係表示比較例中之光纖之配置位置之圖。 Fig. 4 is a view showing the arrangement position of the optical fibers in the comparative example.

圖5(A)及(B)係表示第2例中之光纖之配置位置之圖。 5(A) and 5(B) are views showing the arrangement positions of the optical fibers in the second example.

圖6係關於本實施形態中之光纖之配置位置之有效性的說明圖。 Fig. 6 is an explanatory diagram showing the effectiveness of the arrangement position of the optical fibers in the present embodiment.

圖7(A)及(B)係表示關於第2例之其他變化之圖。 7(A) and (B) are diagrams showing other changes in the second example.

圖8(A)及(B)係表示第3例中之光纖之配置位置之圖。 8(A) and 8(B) are views showing the arrangement positions of the optical fibers in the third example.

圖9係關於入射角度之說明圖。 Fig. 9 is an explanatory diagram regarding an incident angle.

以下,參照圖式而對本發明之實施形態(以下稱為本實施形態)進行說明。 Hereinafter, an embodiment (hereinafter referred to as the present embodiment) of the present invention will be described with reference to the drawings.

首先,一面參照圖1一面對本實施形態之成膜構成之概略構成進行說明。圖1係表示本實施形態之成膜裝置之概略構成之圖。 First, a schematic configuration of a film formation structure of the present embodiment will be described with reference to Fig. 1 . Fig. 1 is a view showing a schematic configuration of a film forming apparatus of the embodiment.

本實施形態之成膜裝置係藉由在真空容器內使蒸鍍材料蒸鍍於基板之表面而在基板上形成多層膜的裝置,尤其係藉由真空蒸鍍法而形成膜之真空蒸鍍裝置100。又,本實施形態之真空蒸鍍裝置100中,於真空容器1內設置基板(以下稱為實際基板S)與膜厚測定用之監測基板Sm,能一面測定形成於監測基板Sm側之薄膜之光學膜厚,一面基於該測定結果來控制形成於實際基板S側之薄膜之膜厚。 The film forming apparatus of the present embodiment is a device for forming a multilayer film on a substrate by vapor-depositing a vapor deposition material on a surface of a substrate in a vacuum container, in particular, a vacuum vapor deposition device for forming a film by a vacuum evaporation method. 100. In the vacuum vapor deposition apparatus 100 of the present embodiment, a substrate (hereinafter referred to as an actual substrate S) and a monitoring substrate Sm for measuring a film thickness are provided in the vacuum chamber 1, and the film formed on the side of the monitoring substrate Sm can be measured. The film thickness of the film formed on the actual substrate S side is controlled based on the measurement result based on the optical film thickness.

此處,所謂實際基板S,係指實際安裝於薄膜利用機器之基板,例如由玻璃構成。另一方面,監測基板Sm相當於被測定用基板,且係僅用於膜厚監測者,其係由與實際基板S同樣之材料、例如玻璃構成。尤其是,本實施形態之監測基板Sm於俯視時成為圓環狀之基板,其較佳之厚度為1.0~2.0 mm。 Here, the actual substrate S refers to a substrate that is actually mounted on a film utilization device, and is made of, for example, glass. On the other hand, the monitoring substrate Sm corresponds to the substrate to be measured, and is used only for the film thickness monitor, and is made of the same material as the actual substrate S, for example, glass. In particular, the monitoring substrate Sm of the present embodiment has an annular substrate in a plan view, and preferably has a thickness of 1.0 to 2.0 mm.

而且,本實施形態中,於監測基板Sm,以與實際基板S相同之條件形成多層膜。即,本實施形態中,一併觀察形成於實際基板S側之薄膜之光學膜厚、與形成於監測基板Sm側之薄膜之光學膜厚,藉由對監測基板Sm側之薄膜之光學膜厚進行監測,而管理實際基板S側之薄膜之光 學膜厚。 Further, in the present embodiment, the multilayer substrate is formed under the same conditions as the actual substrate S on the substrate Sm. In other words, in the present embodiment, the optical film thickness of the film formed on the actual substrate S side and the optical film thickness of the film formed on the side of the monitoring substrate Sm are observed together, and the optical film thickness of the film on the side of the monitoring substrate Sm is observed. Monitoring, and managing the light of the film on the side of the actual substrate S Learn to thicken the film.

若對真空蒸鍍裝置100之構成進行說明,則如圖1所示,具備真空容器1、基板保持器2、蒸發機構3、擋閘4、擋閘控制單元5、膜厚測定裝置6。 When the configuration of the vacuum vapor deposition apparatus 100 is described, as shown in FIG. 1, the vacuum container 1, the substrate holder 2, the evaporation mechanism 3, the shutter 4, the shutter control unit 5, and the film thickness measuring device 6 are provided.

於真空容器1之內空間中之上方之空間內收容有圓頂狀之基板保持器2,於該基板保持器2之內表面安裝有複數個實際基板S。又,於基板保持器2之內表面之中心位置形成有開口2a,於該開口2a之正下方位置配置有1個監測基板Sm。配置於該位置之監測基板Sm成為其一部分通過上述開口2a而露出於圓頂之外側的狀態。 A dome-shaped substrate holder 2 is housed in a space above the inner space of the vacuum container 1, and a plurality of actual substrates S are mounted on the inner surface of the substrate holder 2. Further, an opening 2a is formed at a center position of the inner surface of the substrate holder 2, and one monitoring substrate Sm is disposed at a position directly below the opening 2a. The monitoring substrate Sm disposed at this position is in a state in which a part thereof is exposed to the outside of the dome through the opening 2a.

進而,就使實際基板S間之成膜量均勻化之目的而言,基板保持器2係於成膜期間以沿著鉛垂方向之旋轉軸為中心旋轉。其間,監測基板Sm相對於基板保持器2而進行相對旋轉。即,本實施形態中,監測基板Sm由與基板保持器2分體形成之未圖示之監測基板保持器保持,基板保持器2與監測基板保持器可相互獨立地旋轉。 Further, for the purpose of uniformizing the amount of film formation between the actual substrates S, the substrate holder 2 is rotated about the rotation axis in the vertical direction during the film formation period. In the meantime, the monitoring substrate Sm is relatively rotated with respect to the substrate holder 2. That is, in the present embodiment, the monitoring substrate Sm is held by a monitoring substrate holder (not shown) which is formed separately from the substrate holder 2, and the substrate holder 2 and the monitoring substrate holder are rotatable independently of each other.

另一方面,於真空容器1之內空間中之下方之空間設置有蒸發機構3。該蒸發機構3係用以使為了形成薄膜而蒸鍍於實際基板S或監測基板Sm之蒸鍍材料蒸發者。若具體地說明,則本實施形態之蒸發機構3係與真空蒸鍍裝置通常所具備之蒸發機構為同種類者,例如可列舉藉由電子束對由未圖示之坩堝保持的蒸鍍材料進行加熱而使其蒸發之電子束裝置等。 On the other hand, an evaporation mechanism 3 is provided in a space below the space inside the vacuum vessel 1. The evaporation mechanism 3 is for evaporating a vapor deposition material which is vapor-deposited on the actual substrate S or the monitoring substrate Sm in order to form a thin film. Specifically, the evaporation mechanism 3 of the present embodiment is of the same type as the evaporation mechanism normally provided in the vacuum vapor deposition apparatus, and for example, a vapor deposition material held by a crucible (not shown) by an electron beam is used. An electron beam device or the like that is heated to evaporate.

於基板保持器2與蒸發機構3之間設置有擋閘4。該擋閘4為開閉構件之一例,為了阻斷蒸發機構3所蒸發之蒸鍍材料往實際基板S 或監測基板Sm之表面時之路線,而藉由未圖示之驅動機構進行開閉移動。若具體地說明,則於擋閘4位於打開位置(圖1中,以實線表示之擋閘4之位置)時,蒸發機構3所蒸發之蒸鍍材料飛散而可供給至實際基板S或監測基板Sm。反之,於擋閘4位於關閉位置(圖1中,以虛線表示之擋閘4之位置)時,藉由擋閘4而防止蒸鍍材料之飛散,結果無法對實際基板S或監測基板Sm供給蒸鍍材料。 A shutter 4 is provided between the substrate holder 2 and the evaporation mechanism 3. The shutter 4 is an example of an opening and closing member, and the vapor deposition material evaporated by the evaporation mechanism 3 is blocked to the actual substrate S. Alternatively, the route when the surface of the substrate Sm is monitored is opened and closed by a drive mechanism (not shown). Specifically, when the shutter 4 is in the open position (the position of the shutter 4 indicated by the solid line in FIG. 1), the evaporation material evaporated by the evaporation mechanism 3 is scattered and can be supplied to the actual substrate S or monitored. Substrate Sm. On the other hand, when the shutter 4 is in the closed position (the position of the shutter 4 indicated by a broken line in FIG. 1), the evaporation of the vapor deposition material is prevented by the shutter 4, and as a result, the actual substrate S or the monitoring substrate Sm cannot be supplied. Evaporation material.

擋閘控制單元5相當於控制上述擋閘4之開閉之控制機構,本實施形態中,藉由下述之第2電腦PC2而構成。若具體地說明,則第2電腦PC2經由未圖示之介面而與擋閘4連接,藉由執行安裝於第2電腦PC2之控制程式,而向擋閘4輸出控制訊號。而且,若擋閘4自第2電腦PC2接收控制訊號,則按照控制訊號進行開閉動作。 The shutter control unit 5 corresponds to a control unit that controls opening and closing of the shutter 4, and is configured by the second computer PC2 described below in the present embodiment. Specifically, the second computer PC2 is connected to the shutter 4 via a interface (not shown), and the control program attached to the second computer PC2 is executed to output a control signal to the shutter 4. Further, when the shutter 4 receives the control signal from the second computer PC2, the opening and closing operation is performed in accordance with the control signal.

膜厚測定裝置6係測定形成於監測基板Sm之薄膜之光學膜厚的裝置,尤其是,於本實施形態中,其係藉由反射法而測定膜厚者。即,本實施形態之膜厚測定裝置6中,對形成於監測基板Sm之薄膜入射光,接受由監測基板Sm反射之光後,將該反射光分光,檢測每一波長下之光強度(光譜)。繼而,基於檢測到之光強度,而算出形成於監測基板Sm之薄膜之光學膜厚。 The film thickness measuring device 6 is a device for measuring the optical film thickness of the film formed on the monitoring substrate Sm. In particular, in the present embodiment, the film thickness is measured by a reflection method. In the film thickness measuring device 6 of the present embodiment, the light incident on the monitoring substrate Sm receives the light reflected by the monitoring substrate Sm, and then splits the reflected light to detect the light intensity at each wavelength (spectrum ). Then, based on the detected light intensity, the optical film thickness of the film formed on the monitoring substrate Sm is calculated.

進而,本實施形態之膜厚測定裝置6係測定形成於監測基板Sm之多層膜中每一層膜的光學膜厚者。若更具體地說明,則如上所述般,監測基板Sm係獨立於基板保持器2而旋轉,另一方面,於監測基板Sm之正下方位置配置有未圖示之監測基板遮罩。該監測基板遮罩為圓盤狀構件,於其中央部形成有開口。監測基板Sm之一部分通過該開口而對蒸發機 構3露出。 Further, the film thickness measuring device 6 of the present embodiment measures the optical film thickness of each film formed in the multilayer film of the monitoring substrate Sm. More specifically, as described above, the monitoring substrate Sm is rotated independently of the substrate holder 2, and a monitoring substrate mask (not shown) is disposed directly under the monitoring substrate Sm. The monitoring substrate mask is a disk-shaped member, and an opening is formed in a central portion thereof. Monitoring a portion of the substrate Sm through the opening to the evaporator Structure 3 is exposed.

另一方面,於真空容器1內收容有實際基板S及監測基板Sm之兩者的狀態下,蒸發機構3使蒸鍍材料蒸發,以使蒸鍍材料蒸鍍於該兩者之表面。藉此,於實際基板S及監測基板Sm之各者之成膜面,以大致相同之條件形成薄膜。此時,監測基板Sm之成膜面中的形成有薄膜之區域僅為通過形成於監測基板遮罩之開口而露出之區域。 On the other hand, in a state in which both the actual substrate S and the monitoring substrate Sm are accommodated in the vacuum chamber 1, the evaporation mechanism 3 evaporates the vapor deposition material to vapor-deposit the vapor deposition material on both surfaces. Thereby, a film is formed on substantially the same condition on the film formation surface of each of the actual substrate S and the monitor substrate Sm. At this time, the region where the thin film is formed in the film formation surface of the monitoring substrate Sm is only the region exposed by the opening formed in the monitor substrate mask.

又,如上所述,本實施形態中,於實際基板S形成多層膜,每次形成各層之薄膜時,蒸鍍材料及成膜條件替換為用以形成下一層之薄膜之材料及條件。另一方面,以與基板大致相同之條件亦於監測基板Sm形成多層膜,本實施形態中,於完成一層薄膜而替換蒸鍍材料及成膜條件之時間點,監測基板Sm相對於靜止之監測基板遮罩而僅以特定之旋動角度進行相對旋動。如此,因監測基板Sm相對於監測基板遮罩進行相對旋動,使得監測基板Sm中的通過形成於監測基板遮罩之開口而露出之區域僅以上述之旋動角度偏移,結果,形成有薄膜之區域僅以上述之旋動角度偏移。 Further, as described above, in the present embodiment, the multilayer film is formed on the actual substrate S, and each time a thin film of each layer is formed, the vapor deposition material and the film formation conditions are replaced with materials and conditions for forming the film of the next layer. On the other hand, the multilayer film is formed on the monitoring substrate Sm under substantially the same conditions as the substrate. In the present embodiment, the monitoring of the substrate Sm with respect to the stationary state is monitored at the time when the vapor deposition material and the film forming conditions are replaced by the completion of one film. The substrate is masked and the relative rotation is only performed at a specific rotation angle. In this manner, since the monitoring substrate Sm is relatively rotated with respect to the monitoring substrate mask, the area exposed by the opening formed in the monitoring substrate mask in the monitoring substrate Sm is only shifted by the above-described rotation angle, and as a result, formed The area of the film is only offset by the above-described rotational angle.

繼而,於其後之成膜處理中,在監測基板Sm中之旋動前露出之區域(以下稱為旋動前之露出區域)與旋動後露出之區域(以下稱為旋動後之露出區域)之重複範圍,形成新層之薄膜。另一方面,於旋動前之露出區域中不與旋動後之露出區域重複之範圍,不形成新層之薄膜。因此,以各成膜處理而形成之部份之薄膜的膜厚,係藉由對監測基板Sm中於即將執行成膜處理之前之旋轉動作之前後露出的區域、與於旋轉動作後不露出的區域之間所形成的薄膜之光學膜厚進行比較而求出。 Then, in the film forming process thereafter, the region exposed before the rotation in the monitoring substrate Sm (hereinafter referred to as the exposed region before the rotation) and the region exposed after the rotation (hereinafter referred to as the exposure after the rotation) The repeating range of the area) forms a film of the new layer. On the other hand, in the exposed area before the rotation, the film does not form a new layer without overlapping the exposed area after the rotation. Therefore, the film thickness of the film formed by each film formation process is not exposed to the region after the rotation of the substrate Sm immediately before the film formation process is performed, and after the rotation operation. The optical film thickness of the film formed between the regions was determined and compared.

其次,一面參照圖1及圖2一面對本實施形態之膜厚測定裝 置6之構成進行說明。圖2係本實施形態之探針之模式側視圖。 Next, the film thickness measuring device of the present embodiment is faced with reference to FIGS. 1 and 2 The configuration of the sixth is explained. Fig. 2 is a schematic side view of the probe of the embodiment.

如圖1所示,膜厚測定裝置6中,具有投光器11、直流穩定化電源12、光學感測器用探針13、分光器14、放大器15、A/D轉換器16、訊號處理電路17、2個電腦PC1、PC2作為主要構成要素。 As shown in FIG. 1, the film thickness measuring device 6 includes a light projector 11, a DC stabilized power supply 12, an optical sensor probe 13, a beam splitter 14, an amplifier 15, an A/D converter 16, and a signal processing circuit 17, Two computers PC1 and PC2 are main components.

投光器11係照射裝置之一例,為了測定形成於監測基板Sm之膜的光學膜厚,通過由光纖構成之照射側纖維f1向監測基板Sm照射光。若具體地說明,則投光器11具有由鹵素燈等構成之光源21,自配置有照射側纖維f1之端面的光學感測器用探針13之前端面照射自光源21發出之白色光。此處,投光器11與分光器14同步,與分光器14中之入射光強度之輸出週期同步地反覆進行光源21之熄燈與亮燈。再者,對於投光器11具備之光源21,自直流穩定化電源12供給直流電流。 The light projector 11 is an example of an irradiation device. In order to measure the optical film thickness of the film formed on the monitoring substrate Sm, the irradiation substrate fiber f1 composed of an optical fiber is irradiated with light to the monitoring substrate Sm. Specifically, the light projector 11 has a light source 21 composed of a halogen lamp or the like, and the white light emitted from the light source 21 is irradiated from the front end surface of the probe 13 for the optical sensor in which the end surface of the irradiation side fiber f1 is disposed. Here, the light projector 11 is synchronized with the spectroscope 14, and the light source 21 is turned off and on in synchronization with the output period of the incident light intensity in the spectroscope 14. Further, a direct current is supplied from the DC stabilized power source 12 to the light source 21 included in the light projector 11.

分光器14具備受光裝置22,並輸出與受光裝置22接受由監測基板Sm反射之光時之受光強度對應的類比訊號。若更若具體地說明,則分光器14具備之受光裝置22係藉由例如CCD(Charge Coupled Device,電荷耦合裝置)而構成,並且,為了測定光學膜厚,通過由光纖構成之受光側纖維f2,接受自投光器11照射後由監測基板Sm反射之光。分光器14將受光裝置22所接受之光分光後,檢測各波長下之光強度(光譜),輸出對應於檢測結果之電氣訊號。此處,自分光器14輸出之電氣訊號相當於與受光裝置22接受反射光時之受光強度對應的類比訊號。 The spectroscope 14 includes a light receiving device 22, and outputs an analog signal corresponding to the received light intensity when the light receiving device 22 receives the light reflected by the monitoring substrate Sm. More specifically, the light-receiving device 22 included in the spectroscope 14 is configured by, for example, a CCD (Charge Coupled Device), and the light-receiving side fiber f2 composed of an optical fiber is measured for measuring the optical film thickness. The light reflected by the monitoring substrate Sm after being irradiated from the light projector 11 is received. The spectroscope 14 splits the light received by the light receiving device 22, detects the light intensity (spectrum) at each wavelength, and outputs an electrical signal corresponding to the detection result. Here, the electrical signal output from the optical splitter 14 corresponds to an analog signal corresponding to the received light intensity when the light receiving device 22 receives the reflected light.

又,分光器14將自投光器11照射之光分光,輸出表示入射光之各波長下之光強度、即入射光強度的電氣訊號。如上所述,分光器14分別輸出表示入射光強度之電氣訊號、與表示反射光強度之電氣訊號。自 分光器14輸出之上述2種電氣訊號分別藉由放大器15而放大,其後藉由A/D轉換器16轉換為數位訊號。其後,數位訊號被輸入至第2電腦19。 Further, the spectroscope 14 splits the light irradiated from the light projector 11 and outputs an electric signal indicating the intensity of light at each wavelength of the incident light, that is, the intensity of the incident light. As described above, the spectroscope 14 outputs an electrical signal indicating the intensity of the incident light and an electrical signal indicating the intensity of the reflected light. from The above two types of electrical signals output by the beam splitter 14 are amplified by the amplifier 15, respectively, and then converted into digital signals by the A/D converter 16. Thereafter, the digital signal is input to the second computer 19.

光學感測器用探針13係探針之一例,係捆束複數根照射側纖維f1及複數根受光側纖維f2而形成。若具體地說明,則如圖2所示般,連接於投光器11之複數根照射側纖維f1及連接於受光裝置22之複數根受光側纖維f2分別形成束(bundle),並收容於軟管23內。 An example of the probe 13-series probe for an optical sensor is formed by bundling a plurality of irradiation-side fibers f1 and a plurality of light-receiving fibers f2. Specifically, as shown in FIG. 2, the plurality of irradiation-side fibers f1 connected to the light projector 11 and the plurality of light-receiving side fibers f2 connected to the light-receiving device 22 respectively form bundles and are housed in the hose 23 Inside.

再者,照射側纖維f1及受光側纖維f2分別具有芯與覆蓋芯之被覆,本實施形態中,芯徑為約200μm,含被覆之光纖徑為約235μm。 Further, each of the irradiation-side fiber f1 and the light-receiving-side fiber f2 has a core and a cover core. In the present embodiment, the core diameter is about 200 μm, and the coated fiber diameter is about 235 μm.

又,於照射側纖維f1所形成之束中,在連接於投光器11之側之端安裝有接合連接器24A。同樣地,於受光側纖維f2所形成之束中,在連接於受光裝置22之側之端安裝有接合連接器24B。 Further, in the bundle formed by the irradiation side fiber f1, the joint connector 24A is attached to the end connected to the side of the light projector 11. Similarly, in the bundle formed by the light-receiving side fiber f2, the joint connector 24B is attached to the end connected to the side of the light-receiving device 22.

繼而,成束之照射側纖維f1及受光側纖維f2於其自由端側匯合成一束而形成為光學感測器用探針13。即,構成光學感測器用探針13之複數根照射側纖維f1與複數根受光側纖維f2係形成為端面於光學感測器用探針13之自由端側之面對齊的束狀光纖。 Then, the bundled irradiation-side fiber f1 and the light-receiving-side fiber f2 are combined at the free end side to form a probe 13 for an optical sensor. In other words, the plurality of irradiation side fibers f1 and the plurality of light receiving side fibers f2 constituting the optical sensor probe 13 are formed into bundle optical fibers whose end faces are aligned on the free end side of the optical sensor probe 13.

若更具體地說明,則如圖2所示,各光纖f1、f2之束係於中間連接器24C合流而匯合成一束,收容於相同之軟管23內。進而,在處於匯合成一束之狀態的照射側纖維f1及受光側纖維f2中,於成為自由端之側之端部安裝有圓筒狀之保護筒25,該保護筒25及收容於其內部之光纖f1、f2配設於真空容器1內。 More specifically, as shown in FIG. 2, the bundles of the optical fibers f1 and f2 are joined to the intermediate connector 24C to be combined and bundled, and housed in the same hose 23. Further, in the irradiation-side fiber f1 and the light-receiving-side fiber f2 which are in a state of being combined, a cylindrical protective cylinder 25 is attached to the end portion on the side which is the free end, and the protective cylinder 25 is housed therein. The optical fibers f1 and f2 are disposed in the vacuum container 1.

保護筒25係由直徑彼此不同之大徑部25a及小徑部25b構成,小徑部25b形成為光學感測器用探針13之前端部。而且,光學感測器 用探針13係設置為:作為其前端面之小徑部25b之一端面於監測基板Sm之正上方位置與監測基板Sm相對向。即,形成光學感測器用探針13之前端面的小徑部25b之一端面相當於設在光學感測器用探針13與監測基板Sm相對向之側的對向面。 The protective cylinder 25 is composed of a large diameter portion 25a and a small diameter portion 25b having different diameters, and the small diameter portion 25b is formed as a front end portion of the optical sensor probe 13. Moreover, optical sensor The probe 13 is provided such that one end surface of the small diameter portion 25b as the front end surface faces the monitoring substrate Sm at a position directly above the monitoring substrate Sm. In other words, one end surface of the small diameter portion 25b on the front end surface of the probe 13 for forming the optical sensor corresponds to the opposite surface provided on the side opposite to the optical probe 13 and the monitoring substrate Sm.

又,小徑部25b中,以照射側纖維f1及受光側纖維f2成為同一平面之方式使端面對齊。因此,於小徑部25b之一端面,分別配置有複數個照射側纖維f1之端面及受光側纖維f2之端面。此處,本實施形態中,於小徑部25b之一端面,規則地配置有照射側纖維f1之端面及受光側纖維f2之端面。下文,對小徑部25b之一端面上的各光纖f1、f2之配置位置進行詳細敍述。 In the small-diameter portion 25b, the end faces are aligned so that the irradiation-side fiber f1 and the light-receiving-side fiber f2 are flush with each other. Therefore, the end faces of the plurality of irradiation side fibers f1 and the end faces of the light receiving side fibers f2 are disposed on one end surface of the small diameter portion 25b. In the present embodiment, the end surface of the irradiation-side fiber f1 and the end surface of the light-receiving side fiber f2 are regularly arranged on one end surface of the small-diameter portion 25b. Hereinafter, the arrangement positions of the optical fibers f1 and f2 on one end surface of the small diameter portion 25b will be described in detail.

如上所述,本實施形態之光學感測器用探針13係藉由將複數根照射側纖維f1及受光側纖維f2匯合成一束而成之束狀光纖而構成。再者,本實施形態中,構成光學感測器用探針13之照射側纖維f1及受光側纖維f2各者之根數為20根以上。藉此,本實施形態之膜厚測定裝置6可進行膜厚之多點監測。 As described above, the probe 13 for an optical sensor of the present embodiment is configured by combining bundles of the plurality of irradiation-side fibers f1 and the light-receiving-side fibers f2 into a bundle of optical fibers. In the present embodiment, the number of each of the irradiation-side fiber f1 and the light-receiving-side fiber f2 constituting the optical sensor probe 13 is 20 or more. Thereby, the film thickness measuring device 6 of the present embodiment can perform multi-point monitoring of the film thickness.

2台電腦PC1、PC2可經由乙太網路(註冊商標)而相互通信,作為一電腦之第1電腦PC1係控制投光器11者。本實施形態中,第1電腦PC1為了進行通信協定轉換而經由可程式邏輯控制器PLC(Programmable Logic Controller)控制投光器11之光照射動作。作為另一電腦之第2電腦PC2係電子計算機之一例,基於藉由A/D轉換器16將自分光器14輸出之電氣訊號加以轉換而生成之數位訊號,運算形成於監測基板Sm之薄膜之光學膜厚。 The two computers PC1 and PC2 can communicate with each other via Ethernet (registered trademark), and the first computer PC1 as one computer controls the light projector 11. In the present embodiment, the first computer PC1 controls the light irradiation operation of the light projector 11 via a programmable logic controller PLC (Programmable Logic Controller) in order to perform communication protocol conversion. As an example of the second computer PC2 electronic computer of another computer, the digital signal generated by converting the electric signal output from the optical splitter 14 by the A/D converter 16 is used to calculate the film formed on the monitoring substrate Sm. Optical film thickness.

再者,於A/D轉換器16與第2電腦PC2之間介有訊號處理電路17。該訊號處理電路17係於第2電腦PC2運算光學膜厚時對上述數位訊號執行特定之訊號處理。此處,所謂特定之訊號處理,係指將上述之數位訊號轉換為對用於利用第2電腦PC2進行之光學膜厚運算而言形式較佳之訊號的處理,例如去除干涉訊號以外之成分的小波(wavelet)處理或頻率解析處理等。 Further, a signal processing circuit 17 is interposed between the A/D converter 16 and the second computer PC2. The signal processing circuit 17 performs a specific signal processing on the digital signal when the second computer PC2 calculates the optical film thickness. Here, the specific signal processing refers to a process of converting the above-mentioned digital signal into a signal of a better form for the optical film thickness calculation by the second computer PC2, for example, removing a wavelet of a component other than the interference signal. (wavelet) processing or frequency analysis processing.

進而,第2電腦PC2係如上所述般相當於控制擋閘4之開閉的控制機構,根據光學膜厚之運算值而控制擋閘4之開閉。此處,第2電腦PC2所運算出之光學膜厚之運算值係利用膜厚測定裝置6而得出的光學膜厚之測定結果。 Further, the second computer PC2 corresponds to a control unit that controls opening and closing of the shutter 4 as described above, and controls opening and closing of the shutter 4 based on the calculated value of the optical film thickness. Here, the calculated value of the optical film thickness calculated by the second computer PC2 is the measurement result of the optical film thickness obtained by the film thickness measuring device 6.

關於上文所說明之本實施形態之膜厚測定裝置6的構成,其大部分與先前之反射式膜厚測定裝置之構成共通,但於以下說明之4個方面與先前之裝置不同。 The configuration of the film thickness measuring device 6 of the present embodiment described above is common to the configuration of the conventional reflective film thickness measuring device, but is different from the prior devices in the four aspects described below.

第1不同點係:於光學感測器用探針13之前端面與監測基板Sm之間未設置集光透鏡或受光透鏡等光學零件。即,本實施形態中,光學感測器用探針13如圖1所示般,於在形成為其前端面之小徑部25b之一端面與監測基板Sm之間未設置有光學零件的狀態下,以小徑部25b之一端面與監測基板Sm之非成膜面相對向。此處,所謂非成膜面,係指監測基板Sm中位於形成有膜之側相反側的面。 The first difference is that an optical component such as a collecting lens or a light receiving lens is not provided between the end surface of the optical sensor probe 13 and the monitoring substrate Sm. In the present embodiment, the optical sensor probe 13 is in a state where no optical component is provided between one end surface of the small-diameter portion 25b formed as the distal end surface and the monitoring substrate Sm, as shown in FIG. One end surface of the small diameter portion 25b faces the non-film formation surface of the monitoring substrate Sm. Here, the non-film formation surface refers to a surface of the substrate Sm on the side opposite to the side on which the film is formed.

如此,藉由在光學感測器用探針13之前端面與監測基板Sm之間不設置光學零件,本實施形態中,可抑制因通過光學零件而產生之光損失。其結果為,受光側纖維f2能以相對較大之照度接受反射光。而且, 相應於受光側纖維f2所接受之光之光量變大的程度,為了算出膜厚而對該光進行分光分析時之S/N比提昇。因此,本實施形態之膜厚測定裝置6能以良好的精度來測定光學膜厚。 As described above, by providing no optical component between the end surface of the optical sensor probe 13 and the monitoring substrate Sm, in the present embodiment, light loss due to the optical component can be suppressed. As a result, the light-receiving side fiber f2 can receive the reflected light with a relatively large illuminance. and, Corresponding to the extent to which the amount of light received by the light-receiving side fiber f2 is increased, the S/N ratio at the time of spectroscopic analysis of the light is increased in order to calculate the film thickness. Therefore, the film thickness measuring device 6 of the present embodiment can measure the optical film thickness with good precision.

再者,於在光學感測器用探針13之前端面與監測基板Sm之間未設置有光學零件之情況下,關於有效投光點之直徑,可視為相當於照射側纖維f1與受光側纖維f2所形成之束狀光纖之直徑、即束狀光纖徑者。此處,所謂束狀光纖徑,係指根據配置在光學感測器用探針13之前端面的複數個照射側纖維f1之端面及複數個受光側纖維f2之端面中相隔最遠之2個端面所規定之長度,本實施形態中為約1.8 mm。 In the case where the optical component is not provided between the end surface of the optical sensor probe 13 and the monitoring substrate Sm, the diameter of the effective light-emitting point can be regarded as equivalent to the irradiation-side fiber f1 and the light-receiving side fiber f2. The diameter of the bundled fiber formed, that is, the diameter of the bundled fiber. Here, the bundle fiber diameter refers to the two end faces which are the farthest apart from the end faces of the plurality of irradiation side fibers f1 disposed on the end surface of the optical sensor probe 13 and the end faces of the plurality of light receiving side fibers f2. The predetermined length is about 1.8 mm in this embodiment.

第2不同點係:光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離為束狀光纖徑之2倍以上。若成為此種構成,則光相對於薄膜之入射角度、換言之為由薄膜反射之光之反射角度成為受光側纖維f2之數值孔徑NA以下。本實施形態中,利用以上之性質,將光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離確保為束狀光纖徑之2倍以上。其結果為,通過受光側纖維f2而接受光時之受光效率進一步提高,可進一步以良好的精度來測定光學膜厚。 The second difference is that the distance between the front end surface of the optical sensor probe 13 and the film formation surface of the monitoring substrate Sm is twice or more the diameter of the bundle fiber. With such a configuration, the angle of incidence of the light with respect to the film, in other words, the angle of reflection of the light reflected by the film, becomes equal to or less than the numerical aperture NA of the light-receiving side fiber f2. In the present embodiment, the distance between the front end surface of the optical sensor probe 13 and the film formation surface of the monitor substrate Sm is ensured to be twice or more the diameter of the bundle fiber by the above properties. As a result, the light receiving efficiency when light is received by the light-receiving side fiber f2 is further improved, and the optical film thickness can be further measured with good precision.

又,若光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離過度地變短,則光相對於薄膜之入射角度及由薄膜反射之光之反射角度變大,因此光學感測器用探針13之受光效率(以光學感測器用探針13接受之光量相對於被反射之光量的比率)降低,因此測定精度降低。另一方面,若光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離過度地變長,則自光由薄膜反射起至藉由光學感測器用探針13 接受為止的期間內之衰減程度變大,因此測定精度降低。相對於此,若光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離為束狀光纖徑之2倍以上、較理想為2倍~3倍之範圍內,則可達成較佳之測定精度。 Further, when the distance between the front end surface of the probe 13 for the optical sensor and the film formation surface of the monitor substrate Sm is excessively shortened, the incident angle of the light with respect to the film and the reflection angle of the light reflected by the film become large. The light receiving efficiency of the probe 13 for the optical sensor (the ratio of the amount of light received by the optical sensor probe 13 to the amount of reflected light) is lowered, so that the measurement accuracy is lowered. On the other hand, if the distance between the front end surface of the probe 13 for the optical sensor and the film formation surface of the monitor substrate Sm is excessively long, the self-light is reflected from the film to the probe 13 by the optical sensor. The degree of attenuation in the period until acceptance is increased, so the measurement accuracy is lowered. On the other hand, if the distance between the front end surface of the probe 13 for the optical sensor and the film formation surface of the monitor substrate Sm is twice or more, preferably 2 to 3 times the diameter of the bundle fiber, Achieve better measurement accuracy.

再者,以下,為方便說明,將光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離稱為動作距離WD。 In the following, for convenience of explanation, the distance between the front end surface of the optical sensor probe 13 and the film formation surface of the monitoring substrate Sm is referred to as an operation distance WD.

第3不同點係:於在實際基板S形成多層膜期間,在真空容器1內配置相同之監測基板Sm,且亦於監測基板Sm形成上述多層膜。即,本實施形態中,於在實際基板S形成多層膜之中途並不更換監測基板Sm。而且,膜厚測定裝置6係測定形成於監測基板Sm之多層膜中每一層膜的光學膜厚。其結果為,於按層來測定多層膜之各層之光學膜厚時,可抑制每次測定時因監測基板Sm變化而產生之影響。 The third difference is that the same monitoring substrate Sm is disposed in the vacuum vessel 1 during the formation of the multilayer film on the actual substrate S, and the multilayer film is also formed on the monitoring substrate Sm. That is, in the present embodiment, the monitoring substrate Sm is not replaced in the middle of forming the multilayer film on the actual substrate S. Further, the film thickness measuring device 6 measures the optical film thickness of each of the films formed on the multilayer film of the monitoring substrate Sm. As a result, when the optical film thickness of each layer of the multilayer film is measured in layers, the influence of the change in the monitoring substrate Sm at each measurement can be suppressed.

若具體地說明,則於形成多層膜之先前之成膜裝置中,存在搭載有監測基板變換器(未圖示)者,該裝置中,當每次於實際基板S形成多層膜之各層時,監測基板變換器會更換監測基板Sm。然而,於監測基板間,尺寸、表面狀態及加工精度存在不均,存在因該不均而對薄膜測定精度造成影響之情況。即,於膜厚測定之再現性之方面,在多層膜形成中途更換監測基板存在問題。 Specifically, in the film forming apparatus of the prior art in which the multilayer film is formed, there is a monitor substrate converter (not shown) in which the layers of the multilayer film are formed each time on the actual substrate S. Monitoring the substrate converter replaces the monitoring substrate Sm. However, there is a problem in size, surface state, and processing accuracy between the substrates to be monitored, and there is a case where the measurement accuracy of the film is affected by the unevenness. That is, in terms of reproducibility of film thickness measurement, there is a problem in replacing the monitoring substrate in the middle of formation of the multilayer film.

相對於此,本實施形態中,於在實際基板S形成多層膜之期間,在真空容器1內連續地配置相同之監測基板Sm,因此,因監測基板Sm間之不均而產生之影響不會波及薄膜測定之精度。相應地,能以良好的精度來測定形成於監測基板Sm之多層膜之各層的膜厚,進而,可基於該測定結果以更佳的精度來控制形成於實際基板S側之膜的光學膜厚。 On the other hand, in the present embodiment, the same monitoring substrate Sm is continuously disposed in the vacuum chamber 1 during the formation of the multilayer film on the actual substrate S. Therefore, the influence of the unevenness between the monitoring substrates Sm does not occur. The accuracy of the measurement of the film is affected. Accordingly, the film thickness of each layer of the multilayer film formed on the monitoring substrate Sm can be measured with good precision, and further, the optical film thickness of the film formed on the actual substrate S side can be controlled with better precision based on the measurement result. .

再者,本實施形態中,如上所述,使用圓環狀之基板作為監測基板Sm,另一方面,可於膜厚測定裝置6側進行膜厚之多點監測。進而,本實施形態中,束狀光纖徑為約1.8 mm,光學感測器用探針13藉由20根以上之照射側纖維f1及受光側纖維f2而構成。其結果為,本實施形態之膜厚測定裝置6可使監測點數(測定點數)為80點。一般,就使光量感度提高之目的而言,於監測基板Sm上形成高折射率之蒸鍍材料與低折射率之蒸鍍材料的2種蒸鍍層,因此,若為80點之監測點數,則亦可應對形成有由例如160層(80×2)構成之多層膜之情況。 Further, in the present embodiment, as described above, the annular substrate is used as the monitoring substrate Sm, and on the other hand, the film thickness monitoring device 6 can perform multi-point monitoring. Furthermore, in the present embodiment, the beam-shaped optical fiber has a diameter of about 1.8 mm, and the optical probe 13 is composed of 20 or more irradiation-side fibers f1 and light-receiving fibers f2. As a result, the film thickness measuring device 6 of the present embodiment can set the number of monitoring points (measurement points) to 80 points. In general, for the purpose of improving the light amount sensitivity, two kinds of vapor deposition materials of a high refractive index vapor deposition material and a low refractive index vapor deposition material are formed on the monitoring substrate Sm. Therefore, if the number of monitoring points is 80 points, It is also possible to cope with the case where a multilayer film composed of, for example, 160 layers (80 × 2) is formed.

第4不同點係:於作為光學感測器用探針13之前端面之小徑部25b之一端面,配置有照射側纖維f1及受光側纖維f2之各者之端面之位置。若具體地說明,則本實施形態中,於光學感測器用探針13之前端面,複數個配置之照射側纖維f1之端面的各者均於與至少1個受光側纖維f2之端面相鄰的狀態下配置成圓弧狀或圓環狀。同樣地,於上述一端面,複數個配置之受光側纖維f2之端面的各者均於與至少1個照射側纖維f1之端面之各者相鄰的狀態下配置成圓弧狀或圓環狀。 The fourth difference is that the end surface of each of the irradiation-side fiber f1 and the light-receiving side fiber f2 is disposed on one end surface of the small-diameter portion 25b which is the end surface of the probe 13 for the optical sensor. Specifically, in the present embodiment, each of the end faces of the plurality of irradiation-side fibers f1 disposed on the front end surface of the probe 13 for the optical sensor is adjacent to the end surface of the at least one light-receiving side fiber f2. In the state, it is arranged in an arc shape or an annular shape. In the same manner, each of the end faces of the plurality of light-receiving side fibers f2 is disposed in an arc shape or an annular shape in a state adjacent to each of the end faces of at least one of the irradiation-side fibers f1. .

如上所述,於光學感測器用探針13之前端面,若照射側纖維f1之端面與受光側纖維f2之端面彼此相鄰,則自投光器11對薄膜照射之光之入射角度進一步減小。此處,入射角度之大小係自照射側纖維f1之端面照射之光去往薄膜時之光路、與該光由薄膜之表面或監測基板Sm與薄膜之分界面反射而去往受光側纖維f2之端面時之光路所成之角度的1/2。 As described above, when the end surface of the irradiation side fiber f1 and the end surface of the light receiving side fiber f2 are adjacent to each other on the front end surface of the probe 13 for the optical sensor, the incident angle of the light irradiated from the light projector 11 to the film is further reduced. Here, the incident angle is the optical path when the light irradiated from the end surface of the irradiation-side fiber f1 goes to the film, and the light is reflected from the surface of the film or the interface between the substrate Sm and the film to the light-receiving side fiber f2. 1/2 of the angle formed by the light path at the end face.

另一方面,入射角度θ與膜厚之測定值d之間,上述式(1)所示之關係成立,因此入射角度θ越大,膜厚之測定誤差△d越大。若具 體地說明,則於將成膜材料之折射率設為n=1.47之情況下,當入射角度θ為3°、5°、8°、10°、12°時,測定誤差△d分別為0.07%、0.2%、0.5%、0.7%、1.0%。反之,入射角度θ越小,膜厚之測定誤差△d越小。 On the other hand, the relationship shown by the above formula (1) is established between the incident angle θ and the measured value d of the film thickness. Therefore, the larger the incident angle θ, the larger the measurement error Δd of the film thickness. If Physically, when the refractive index of the film-forming material is n=1.47, when the incident angle θ is 3°, 5°, 8°, 10°, and 12°, the measurement error Δd is 0.07. %, 0.2%, 0.5%, 0.7%, 1.0%. On the other hand, the smaller the incident angle θ, the smaller the measurement error Δd of the film thickness.

如上所述,照射側纖維f1之端面與受光側纖維f2之端面越分離,由薄膜反射之光量中通過受光側纖維f2而接受之光量所占的比率、即受光效率越低。反之,若照射側纖維f1之端面與受光側纖維f2之端面彼此相鄰,則受光效率提高。 As described above, the more the end surface of the irradiation-side fiber f1 and the end surface of the light-receiving side fiber f2 are separated, the ratio of the amount of light received by the light-receiving side fiber f2 in the amount of light reflected by the film, that is, the lower the light-receiving efficiency. On the other hand, when the end faces of the irradiation-side fibers f1 and the end faces of the light-receiving-side fibers f2 are adjacent to each other, the light-receiving efficiency is improved.

另外,由於光學感測器用探針13之前端面之光纖之填充率越高則膜厚測定之精度越高,因此通常於光學感測器用探針13之前端面內,以密集狀態配置光纖之端面。另一方面,光纖之端面越密集,照射側纖維f1之端面彼此及受光側纖維f2之端面彼此越容易密集。而且,若同種類光纖之端面彼此密集地配置成塊狀,則照射側纖維f1之端面與受光側纖維f2之端面容易分離。 In addition, since the film thickness measurement accuracy is higher as the filling rate of the optical fiber of the front end surface of the probe 13 for the optical sensor is higher, the end face of the optical fiber is usually disposed in a dense state in the front end surface of the probe 13 for the optical sensor. On the other hand, the denser the end faces of the optical fibers, the more closely the end faces of the irradiation side fibers f1 and the end faces of the light receiving side fibers f2 are denser. In addition, when the end faces of the same type of optical fibers are densely arranged in a block shape, the end faces of the irradiation side fibers f1 and the end faces of the light receiving side fibers f2 are easily separated.

相對於此,若於光學感測器用探針13之前端面,以照射側纖維f1之端面與受光側纖維f2之端面分別排列成圓弧狀或圓環狀之方式配置各光纖,則可有效率地實現如照射側纖維f1與受光側纖維f2彼此相鄰之光纖配置。 On the other hand, when the end faces of the probes 13 for the optical sensor are arranged such that the end faces of the irradiation-side fibers f1 and the end faces of the light-receiving fibers f2 are arranged in an arc shape or an annular shape, the optical fibers can be efficiently arranged. An optical fiber arrangement in which the irradiation-side fiber f1 and the light-receiving-side fiber f2 are adjacent to each other is realized.

再者,作為如照射側纖維f1與受光側纖維f2彼此相鄰之光纖配置,亦可考慮到如下之配置:於光學感測器用探針13之前端面,照射側纖維f1之端面與受光側纖維f2之端面分別形成行,且各種類光纖之行交替排列。然而,根據上述理由而於光學感測器用探針13之前端面內以密集狀態配置光纖之端面之狀況下,如照射側纖維f1之端面與受光側纖維f2之端面分別形 成為行且各種類光纖之行交替排列般之光纖配置難以於物理上實現。因此,如本實施形態般以各種類光纖之端面排列成圓弧狀或圓環狀之方式配置各光纖者更有效率,故而較佳。 In addition, as the optical fiber arrangement in which the irradiation-side fiber f1 and the light-receiving-side fiber f2 are adjacent to each other, an arrangement may be considered in which the end face of the optical sensor probe 13 and the end face of the irradiation-side fiber f1 and the light-receiving side fiber are disposed. The end faces of f2 are respectively formed into rows, and the rows of various types of optical fibers are alternately arranged. However, in the case where the end faces of the optical fibers are arranged in a dense state in the front end surface of the optical sensor probe 13 in the above-described reason, the end faces of the irradiation side fibers f1 and the end faces of the light receiving side fibers f2 are respectively formed. It is difficult to physically implement a fiber arrangement that is alternately arranged in a row and various types of optical fibers. Therefore, it is preferable to arrange the optical fibers in such a manner that the end faces of the various types of optical fibers are arranged in an arc shape or an annular shape as in the present embodiment.

藉由如上之作用,與先前之裝置相比,本實施形態之膜厚測定裝置6能以更佳的精度來測定光學膜厚。 By the above action, the film thickness measuring device 6 of the present embodiment can measure the optical film thickness with better precision than the conventional device.

其次,一面參照圖3至8一面對關於光學感測器用探針13之前端面之照射側纖維f1及受光側纖維f2之各者之端面之配置位置的具體例(第1例~第3例)進行說明。 Next, a specific example of the arrangement positions of the end faces of the respective sides of the irradiation side fiber f1 and the light receiving side fiber f2 of the front end surface of the probe 13 for the optical sensor will be described with reference to FIGS. 3 to 8 (first to third examples). )Be explained.

圖3(A)及(B)係表示第1例中之光纖之配置位置之圖。圖4係表示比較例中之光纖之配置位置之圖。圖5(A)及(B)係表示第2例中之光纖之配置位置之圖。圖6係關於本實施形態之光纖之配置位置之有效性之說明圖,圖中,實線之曲線表示第1例之資料,虛線之曲線表示比較例之資料。圖7(A)及(B)係表示關於第2例之其他變化之圖。圖8(A)及(B)係表示第3例中之光纖之配置位置之圖。圖3、4、6、7及8中,黑圓表示照射側纖維f1之配置位置,白圓表示受光側纖維f2之配置位置。 3(A) and 3(B) are views showing the arrangement positions of the optical fibers in the first example. Fig. 4 is a view showing the arrangement position of the optical fibers in the comparative example. 5(A) and 5(B) are views showing the arrangement positions of the optical fibers in the second example. Fig. 6 is an explanatory view showing the effectiveness of the arrangement position of the optical fiber of the present embodiment, in which the solid line curve indicates the data of the first example, and the broken line curve indicates the data of the comparative example. 7(A) and (B) are diagrams showing other changes in the second example. 8(A) and 8(B) are views showing the arrangement positions of the optical fibers in the third example. In Figs. 3, 4, 6, 7, and 8, the black circle indicates the arrangement position of the irradiation side fiber f1, and the white circle indicates the arrangement position of the light receiving side fiber f2.

首先,若對第1例中光纖之配置位置進行說明,則如圖3(A)及(B)所示,照射側纖維f1及受光側纖維f2係以照射側纖維f1及受光側纖維f2形成為相互反向之螺旋之方式排列,束整體上成為圓狀之配置。再者,圖3(A)及(B)表示使照射側纖維f1之配置位置與受光側纖維f2之配置位置相互反轉之構成,因此以下僅說明圖3(A)所圖示之構成。 First, as shown in FIGS. 3(A) and (B), the irradiation side fiber f1 and the light receiving side fiber f2 are formed by the irradiation side fiber f1 and the light receiving side fiber f2. Arranged in such a manner that they are arranged in a spiral shape, the bundle is arranged in a circular shape as a whole. In addition, in FIGS. 3(A) and (B), the arrangement position of the irradiation-side fiber f1 and the arrangement position of the light-receiving-side fiber f2 are reversed. Therefore, only the configuration shown in FIG. 3(A) will be described below.

第1例中,如上所述,照射側纖維f1及受光側纖維f2分別 排列成圓弧狀、更具體而言排列為螺旋狀而配置。藉此,第1例中,能以均勻之光量對監測基板Sm中有效投光範圍之各部分照射光,進而,能以均勻之條件接受由監測基板Sm反射之光。 In the first example, as described above, the irradiation side fiber f1 and the light receiving side fiber f2 are respectively Arranged in an arc shape, more specifically in a spiral shape. As a result, in the first example, it is possible to irradiate light to each portion of the effective light-emitting range of the monitoring substrate Sm with a uniform amount of light, and further, it is possible to receive light reflected by the monitoring substrate Sm under uniform conditions.

又,第1例中,最大入射角度約為8.4°,實效入射角度約為1.5°。此處,最大入射角度相當於在光學感測器用探針13之前端面相互相隔最遠的照射側纖維f1與受光側纖維f2之間之角度的一半,圖3(A)中,相當於自位於最外側之照射側纖維f1照射之光之光路、與去往位於束中央之受光側纖維f2之光之光路所成之角度的一半。又,所謂實效入射角度,相當於自照射側纖維f1照射之光之光路、與去往鄰接於該光纖f1之受光側纖維f2之光之光路所成之角度的一半。 Further, in the first example, the maximum incident angle is about 8.4°, and the effective incident angle is about 1.5°. Here, the maximum incident angle corresponds to half the angle between the irradiation-side fiber f1 and the light-receiving-side fiber f2 which are farthest from each other before the end face of the optical sensor probe 13, and in FIG. 3(A), it is equivalent to self-positioning The optical path of the light irradiated to the outermost side of the irradiation side fiber f1 is half the angle formed by the optical path of the light to the light-receiving side fiber f2 located at the center of the beam. Further, the effective incident angle corresponds to half the angle between the optical path of the light irradiated from the irradiation side fiber f1 and the optical path of the light that is adjacent to the light receiving side fiber f2 of the optical fiber f1.

若對第1例之光纖之配置位置之有效性進行說明,則第1例中,與圖4所圖示之比較例相比,最大入射角度及實效入射角度變小。若更具體地說明,則比較例中,複數根照射側纖維f1集合成半圓狀,且複數根受光側纖維f2集合成半圓狀,束整體上成為圓狀之配置。 When the effectiveness of the arrangement position of the optical fiber of the first example is described, in the first example, the maximum incident angle and the effective incident angle are smaller than those of the comparative example shown in FIG. 4 . More specifically, in the comparative example, the plurality of irradiation-side fibers f1 are arranged in a semicircular shape, and the plurality of light-receiving fibers f2 are arranged in a semicircular shape, and the bundles are arranged in a circular shape as a whole.

而且,比較例中,最大入射角度約為11.1°,實效入射角度約為6°。此處,比較例中之最大入射角度相當於自位於最外側之照射側纖維f1照射之光之光路、與去往與該光纖f1相隔最遠之受光側纖維f2之光之光路所成之角度的一半。又,比較例中之實效入射角度相當於自位於重心位置之照射側纖維f1照射之光之光路、與去往位於重心位置之受光側纖維f2之光之光路所成之角度的一半。再者,所謂重心位置,係指集合成半圓狀之光纖群之重心位置,於將光纖群所形成之半圓之直徑設為r時,重心相對於該半圓之中心之相對位置可由(0,2r/π)之座標表示。 Moreover, in the comparative example, the maximum incident angle was about 11.1°, and the effective incident angle was about 6°. Here, the maximum incident angle in the comparative example corresponds to the angle between the optical path of the light irradiated from the outermost irradiation side fiber f1 and the light path to the light of the light receiving side fiber f2 farthest from the optical fiber f1. Half of it. Further, the effective incident angle in the comparative example corresponds to half the angle between the optical path of the light irradiated from the irradiation side fiber f1 at the position of the center of gravity and the light path to the light of the light receiving side fiber f2 located at the center of gravity. Furthermore, the position of the center of gravity refers to the position of the center of gravity of the group of fibers that are semicircular, and when the diameter of the semicircle formed by the group of fibers is r, the relative position of the center of gravity with respect to the center of the semicircle can be (0, 2r). The coordinates of /π) are indicated.

如上所述,第1例中,與比較例相比,最大入射角度及實效入射角度變小。其原因為,第1例中,相對於比較例而言,照射側纖維f1及受光側纖維f2各者之散亂程度較大,照射側纖維f1中鄰接於受光側纖維f2者之比率及受光側纖維f2中鄰接於照射側纖維f1者之比率進一步提高。藉此,第1例中,相對於比較例而言,有效投光範圍變小,光學膜厚之測定誤差亦變小。 As described above, in the first example, the maximum incident angle and the effective incident angle are smaller than in the comparative example. The reason for this is that in the first example, the degree of scattering of each of the irradiation-side fiber f1 and the light-receiving-side fiber f2 is large, and the ratio of the irradiation-side fiber f1 adjacent to the light-receiving-side fiber f2 and the light receiving is large. The ratio of the side fibers f2 adjacent to the irradiation side fibers f1 is further increased. Therefore, in the first example, the effective light-emitting range is small and the measurement error of the optical film thickness is also small as compared with the comparative example.

又,第1例中,相對於比較例而言,動作距離WD為0~7 mm之範圍內之相對反射光量(反射光之光量相對於入射光之光量的比率)進一步增大。因此,於動作距離WD為0~7 mm之範圍內之情況下,在第1例中,與比較例相比,能以更高的光量接受反射光。藉此,分光器14之分光分析之精度提高,結果,光學膜厚之測定精度提高。 Further, in the first example, the relative amount of reflected light (the ratio of the amount of reflected light to the amount of incident light) in the range of 0 to 7 mm in the operating distance WD is further increased with respect to the comparative example. Therefore, in the case where the operating distance WD is in the range of 0 to 7 mm, in the first example, the reflected light can be received with a higher amount of light than in the comparative example. Thereby, the accuracy of the spectroscopic analysis of the spectroscope 14 is improved, and as a result, the measurement accuracy of the optical film thickness is improved.

其次,若對第2例中之光纖之配置位置進行說明,則如圖5(A)及(B)所示,照射側纖維f1及受光側纖維f2分別排列成圓環狀,各光纖f1、f2所形成之圓環以同心圓狀交替地配置。再者,圖5(A)及(B)表示使照射側纖維f1之配置位置與受光側纖維f2之配置位置相互反轉之構成,以下僅說明圖5(A)所圖示之構成。 Next, when the arrangement position of the optical fibers in the second example is described, as shown in FIGS. 5(A) and (B), the irradiation-side fiber f1 and the light-receiving-side fiber f2 are arranged in a ring shape, and the respective optical fibers f1 are arranged. The rings formed by f2 are alternately arranged in a concentric manner. In addition, FIG. 5 (A) and (B) show a configuration in which the arrangement position of the irradiation-side fiber f1 and the arrangement position of the light-receiving-side fiber f2 are reversed, and only the configuration shown in FIG. 5(A) will be described below.

第2例中,如上所述,照射側纖維f1及受光側纖維f2分別排列成圓環狀而配置,藉此,能以均勻之光量對監測基板Sm中有效投光範圍之各部分照射光,進而,能以均勻之條件接受由監測基板Sm反射之光。 In the second example, as described above, the irradiation-side fiber f1 and the light-receiving-side fiber f2 are arranged in an annular shape, whereby light can be irradiated to each portion of the effective projection range of the monitor substrate Sm with a uniform amount of light. Further, the light reflected by the monitoring substrate Sm can be received under uniform conditions.

又,第2例中,最大入射角度約為4.2°,實效入射角度約為1.5°。進而,如圖6所示,第2例中,與比較例相比,動作距離WD為0~7 mm之範圍內之相對反射光量進一步增大。因此,於動作距離WD為0~7 mm 之範圍內之情況下,第2例中,與比較例相比,能以更高光量接受反射光,結果,分光器14之分光分析之精度提高,光學膜厚之測定精度提高。 Further, in the second example, the maximum incident angle is about 4.2 and the effective incident angle is about 1.5. Further, as shown in FIG. 6, in the second example, the amount of relative reflected light in the range of the operation distance WD of 0 to 7 mm is further increased as compared with the comparative example. Therefore, the action distance WD is 0~7 mm In the case of the second example, the reflected light can be received at a higher light amount than in the comparative example. As a result, the accuracy of the spectroscopic analysis of the spectroscope 14 is improved, and the measurement accuracy of the optical film thickness is improved.

再者,作為將各光纖配置成圓環狀之其他變化,亦可考慮如下構成:如圖7(A)及(B)所示,於照射側纖維f1所形成之圓環中位於最外側之圓環中,以約90°之間隔將照射側纖維f1置換為受光側纖維f2。藉由此種配置,第2例中,與第1例相比,束中之光纖數中受光側纖維f2所占之比率與照射側纖維f1所占之比率之差進一步減小。即,於探針之功能方面,較理想的是照射側纖維f1之數量與受光側纖維f2之數量接近,就該理由而言,亦可採用如圖7(A)或(B)之光纖配置。 Further, as another variation in which the respective optical fibers are arranged in a ring shape, a configuration may be considered as shown in FIGS. 7(A) and (B), which is located at the outermost side in the ring formed by the irradiation-side fiber f1. In the ring, the irradiation side fiber f1 is replaced with the light receiving side fiber f2 at intervals of about 90°. With this arrangement, in the second example, the difference between the ratio of the ratio of the light-receiving side fibers f2 and the ratio of the irradiation-side fibers f1 in the number of fibers in the bundle is further reduced as compared with the first example. That is, in terms of the function of the probe, it is preferable that the number of the irradiation-side fibers f1 is close to the number of the light-receiving-side fibers f2, and for this reason, the fiber configuration as shown in Fig. 7(A) or (B) may be employed. .

其次,對第3例中之光纖之配置位置進行說明。第3例中,照射側纖維f1及受光側纖維f2之各者並不排列成圓弧狀或圓環狀,該方面與上述之第1例及第2例不同。若具體地說明,則第3例中,如圖8(A)及(B)所示,大致排列成V字狀之照射側纖維f1係沿束之外周以每隔一定間隔而配置於5個部位,且以埋入其間隙及束中央之方式配置受光側纖維f2,束整體上成為圓狀之配置。而且,第3例中,最大入射角度約為8.4°,實效入射角度約為1.5°。因此,第3例中,與比較例相比,最大入射角度及實效入射角度亦變小,有效投光範圍亦變小。再者,圖8(A)及(B)表示使照射側纖維f1之配置位置與受光側纖維f2之配置位置相互反轉之構成。 Next, the arrangement position of the optical fiber in the third example will be described. In the third example, each of the irradiation-side fiber f1 and the light-receiving-side fiber f2 is not arranged in an arc shape or an annular shape, and is different from the first and second examples described above. Specifically, in the third example, as shown in FIGS. 8(A) and 8(B), the irradiation-side fibers f1 arranged substantially in a V shape are arranged at five intervals at regular intervals along the outer circumference of the bundle. The light-receiving side fiber f2 is disposed so as to be embedded in the gap and the center of the bundle, and the bundle is arranged in a circular shape as a whole. Moreover, in the third example, the maximum incident angle is about 8.4°, and the effective incident angle is about 1.5°. Therefore, in the third example, compared with the comparative example, the maximum incident angle and the effective incident angle are also small, and the effective projection range is also small. In addition, FIGS. 8(A) and 8(B) show a configuration in which the arrangement position of the irradiation-side fiber f1 and the arrangement position of the light-receiving-side fiber f2 are reversed.

以上已對本實施形態之膜厚測定裝置及成膜裝置進行了說明,但本實施形態僅僅係為了使本發明容易理解之一例,上述構件、配置等並非限定本發明者,當然可根據本發明之宗旨而進行各種改變、改良, 並且,本發明中包含其等價物。例如,作為構成薄膜測定裝置之各機器之尺寸或大小、形狀、材質,上述內容僅僅係用以發揮本發明之效果之一例,並不限定本發明。 The film thickness measuring device and the film forming device of the present embodiment have been described above. However, the present embodiment is merely an example for facilitating understanding of the present invention, and the members, the arrangement, and the like are not limited to the present invention, and of course, according to the present invention. Various changes and improvements, Further, the equivalents are included in the present invention. For example, the size, size, shape, and material of each device constituting the film measuring device are merely examples for exerting the effects of the present invention, and are not intended to limit the present invention.

又,上述實施形態中,作為成膜裝置之一例,對藉由真空蒸鍍法而成膜之真空蒸鍍裝置100進行了說明,但對於藉由離子電鍍法而成膜之成膜裝置、藉由離子束蒸鍍法而成膜之成膜裝置,亦可應用本發明。又,本發明亦可應用於採用使離子與靶碰撞而成膜之濺鍍法的成膜裝置中。 Further, in the above-described embodiment, the vacuum deposition apparatus 100 formed by the vacuum deposition method has been described as an example of the film formation apparatus. However, the film formation apparatus formed by the ion plating method and the film formation apparatus are used. The present invention can also be applied to a film forming apparatus formed by ion beam evaporation. Further, the present invention can also be applied to a film forming apparatus using a sputtering method in which ions are collided with a target to form a film.

又,上述實施形態中,為了提高反射光之受光效率,而將光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離、即動作距離WD設為束狀光纖徑之2倍以上。但是,並不限定於此,光學感測器用探針13之前端面與監測基板Sm之成膜面之間的距離亦可未達束狀光纖徑之2倍。 Further, in the above-described embodiment, in order to improve the light receiving efficiency of the reflected light, the distance between the front end surface of the optical sensor probe 13 and the film formation surface of the monitor substrate Sm, that is, the operation distance WD is set as the bundle fiber diameter. More than 2 times. However, the distance between the front end surface of the probe 13 for the optical sensor and the film formation surface of the monitor substrate Sm may not be twice as large as the diameter of the bundle fiber.

又,上述實施形態中,使用圓環狀之基板作為監測基板Sm。圓環狀之基板例如於進行光學膜厚之測定並且利用水晶膜厚計進行膜厚測定之情況下較為有效。其原因為,一般,於使用圓環狀之監測基板Sm之成膜裝置中,就裝置構造上之理由而言,可將水晶膜厚計配置於裝置中央、具體為相當於基板保持器2之中央的位置。但是,監測基板Sm並不限定於圓環狀之基板,亦可為其他形狀之基板、例如圓盤狀之基板。 Further, in the above embodiment, an annular substrate is used as the monitoring substrate Sm. The annular substrate is effective, for example, when the measurement of the optical film thickness is performed and the film thickness is measured by a crystal film thickness meter. The reason for this is that, in general, in the film forming apparatus using the annular monitoring substrate Sm, the crystal film thickness gauge can be disposed at the center of the device, specifically equivalent to the substrate holder 2, for the reason of the device structure. Central location. However, the monitoring substrate Sm is not limited to the annular substrate, and may be a substrate of another shape, for example, a disk-shaped substrate.

又,上述實施形態中,於在實際基板S形成多層膜期間內,未更換監測基板Sm,而亦於監測基板Sm側形成多層膜,但並不限定於此。即,亦可於每次形成多層膜中之各層膜時,更換監測基板Sm。但是,如上所述,於監測基板間,尺寸、表面狀態及加工精度存在不均,若於每次測 定各層之膜厚時更換監測基板Sm,則上述不均會對測定精度造成影響。於該方面,較理想的是於在實際基板S形成多層膜之期間不更換監測基板Sm。 Further, in the above-described embodiment, the multilayer substrate is formed on the side of the monitoring substrate Sm without changing the monitoring substrate Sm during the formation of the multilayer film of the actual substrate S, but the invention is not limited thereto. That is, the monitoring substrate Sm may be replaced every time each layer of the multilayer film is formed. However, as described above, there is unevenness in size, surface state, and processing accuracy between the substrates to be monitored. When the monitoring substrate Sm is replaced when the film thickness of each layer is changed, the above unevenness affects the measurement accuracy. In this regard, it is desirable that the monitoring substrate Sm is not replaced during the formation of the multilayer film of the actual substrate S.

再者,上述實施形態中,列舉於實際基板S形成多層膜之成膜裝置作為例子進行了說明,但本發明亦可應用於在實際基板S形成單層膜之裝置。 Further, in the above embodiment, the film forming apparatus for forming a multilayer film on the actual substrate S has been described as an example. However, the present invention is also applicable to an apparatus for forming a single layer film on the actual substrate S.

13‧‧‧光學感測器用探針 13‧‧‧Probes for optical sensors

25b‧‧‧小徑部 25b‧‧‧Little Trails Department

f1‧‧‧照射側纖維 F1‧‧‧illuminated side fiber

f2‧‧‧受光側纖維 F2‧‧‧light-receiving fiber

Claims (7)

一種膜厚測定裝置,具備:照射裝置:其係為了測定形成於被測定用基板之膜的光學膜厚,而通過由光纖構成之照射側纖維向該被測定用基板照射光;受光裝置:其係為了測定該光學膜厚,而通過由光纖構成之受光側纖維,接受於自該照射裝置照射後由該被測定用基板反射之光;及探針:其係捆束複數根該照射側纖維及複數根該受光側纖維而形成;於該探針之作為端面而設於與該被測定用基板相對向之側的對向面,分別配置有複數個該照射側纖維之端面及該受光側纖維之端面,於該對向面,複數個配置之該照射側纖維之端面的各者均係於與至少1個該受光側纖維之端面相鄰的狀態下排列成圓弧狀或圓環狀,且複數個配置之該受光側纖維之端面的各者均係於與至少1個該照射側纖維之端面之各者相鄰的狀態下排列成圓弧狀或圓環狀。 A film thickness measuring device includes: an irradiation device that measures light of an optical film thickness of a film formed on a substrate to be measured, and irradiates light to the substrate to be measured by an optical fiber made of an optical fiber; and a light receiving device: In order to measure the thickness of the optical film, the light-receiving side fiber composed of an optical fiber is received by the substrate to be measured after being irradiated from the irradiation device; and the probe is bundled with the plurality of the irradiation-side fibers. And a plurality of the light-receiving fibers are formed, and an end surface of the plurality of the irradiation-side fibers and the light-receiving side are disposed on a facing surface of the probe that is disposed on a side facing the substrate to be measured The end surface of the fiber is arranged in an arc shape or an annular shape in a state in which the end faces of the plurality of the irradiation side fibers are adjacent to the end faces of the at least one of the light receiving side fibers. Further, each of the end faces of the light-receiving side fibers arranged in a plurality of rows is arranged in an arc shape or an annular shape in a state of being adjacent to each of the end faces of at least one of the irradiation-side fibers. 如申請專利範圍第1項之膜厚測定裝置,其中,該探針係於在該對向面與該被測定用基板之間未設置有光學零件的狀態下,以該對向面與該被測定用基板中位於形成有該膜之側相反側的非成膜面相對向。 The film thickness measuring device according to the first aspect of the invention, wherein the probe is in a state in which an optical component is not provided between the opposite surface and the substrate to be measured, and the opposite surface and the quilt are The non-film formation surface on the side opposite to the side on which the film was formed in the measurement substrate was opposed to each other. 如申請專利範圍第2項之膜厚測定裝置,其中,構成該探針之複數根該照射側纖維及複數根該受光側纖維係形成為端面於該對向面對齊之束狀光纖,該對向面與該成膜面之間的距離為該束狀光纖之直徑的2倍以上。 The film thickness measuring device according to claim 2, wherein the plurality of the irradiation side fibers and the plurality of light receiving side fibers constituting the probe are formed as bundle fibers having end faces aligned on the opposite faces, The distance between the opposing surface and the film forming surface is twice or more the diameter of the bundled optical fiber. 如申請專利範圍第3項之膜厚測定裝置,其中,該被測定用基板為圓盤 狀或圓環狀之基板。 The film thickness measuring device of claim 3, wherein the substrate to be measured is a disk Shaped or annular substrate. 如申請專利範圍第1至4項中任一項之膜厚測定裝置,其具有:該照射裝置;直流穩定化電源:其對設置於該照射裝置之光源供給直流電流;該探針;分光器:其具備該受光裝置,輸出與該受光裝置接受由該被測定用基板反射之光時之受光強度對應的類比訊號;放大器:其放大自該分光器輸出之該類比訊號;A/D轉換器:其將藉由該放大器放大之該類比訊號轉換為數位訊號;電子計算機:其基於該數位訊號而運算該光學膜厚;及訊號處理電路:其介於該A/D轉換器與該電子計算機之間,於該電子計算機運算該光學膜厚時用以對該數位訊號執行特定之訊號處理。 The film thickness measuring device according to any one of claims 1 to 4, further comprising: the illuminating device; a DC stabilized power source: supplying a direct current to a light source provided in the illuminating device; the probe; the beam splitter Providing the light receiving device, and outputting an analog signal corresponding to the received light intensity when the light receiving device receives the light reflected by the substrate for measurement; the amplifier: amplifying the analog signal output from the optical splitter; and the A/D converter : converting the analog signal amplified by the amplifier into a digital signal; the computer: calculating the optical film thickness based on the digital signal; and the signal processing circuit: the A/D converter and the electronic computer When the optical film thickness is calculated by the computer, a specific signal processing is performed on the digital signal. 一種成膜裝置,其係藉由在真空容器內使蒸鍍材料蒸鍍於基板之表面而在該基板形成膜,其特徵在於具備:蒸發機構:其用以使該蒸鍍材料蒸發;開閉構件:其為了阻斷該蒸發機構蒸發之該蒸鍍材料往該基板表面時的路線而進行開閉動作;控制機構:其控制該開閉構件之開閉;及申請專利範圍第1至5項中任一項之膜厚測定裝置;於該基板及該被測定用基板之兩者被收容於該真空容器內的狀態 下,該蒸發機構使該蒸鍍材料蒸發,以使該蒸鍍材料蒸鍍於該兩者之表面,該膜厚測定裝置測定形成於該被測定用基板之膜的該光學膜厚,該控制機構根據由該膜厚測定裝置所得之該光學膜厚的測定結果來控制該開閉構件之開閉。 A film forming apparatus for forming a film on a substrate by vapor-depositing a vapor deposition material on a surface of a substrate in a vacuum vessel, comprising: an evaporation mechanism for evaporating the vapor deposition material; and an opening and closing member Opening and closing operations for blocking the evaporation of the evaporation material onto the surface of the substrate; the control mechanism: controlling the opening and closing of the opening and closing member; and claiming any one of items 1 to 5 of the patent scope The film thickness measuring device is in a state in which both the substrate and the substrate to be measured are housed in the vacuum container The evaporation mechanism evaporates the vapor deposition material to vapor-deposit the vapor deposition material on the surfaces of the two, and the film thickness measuring device measures the optical film thickness of the film formed on the substrate for measurement. The mechanism controls opening and closing of the opening and closing member based on the measurement result of the optical film thickness obtained by the film thickness measuring device. 如申請專利範圍第6項之成膜裝置,其中,於將多層膜形成於該基板之期間,於該真空容器內配置相同之該被測定用基板,亦將該多層膜形成於該被測定用基板,該膜厚測定裝置係測定形成於該被測定用基板之該多層膜中每一層膜的該光學膜厚。 The film forming apparatus of the sixth aspect of the invention, wherein the substrate for measurement is disposed in the vacuum container while the multilayer film is formed on the substrate, and the multilayer film is formed on the substrate for measurement The substrate thickness measuring device measures the optical film thickness of each of the multilayer films formed on the substrate for measurement.
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