WO2015004755A1 - Optical film thickness measurement device, thin film forming device, and method for measuring film thickness - Google Patents

Optical film thickness measurement device, thin film forming device, and method for measuring film thickness Download PDF

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Publication number
WO2015004755A1
WO2015004755A1 PCT/JP2013/068887 JP2013068887W WO2015004755A1 WO 2015004755 A1 WO2015004755 A1 WO 2015004755A1 JP 2013068887 W JP2013068887 W JP 2013068887W WO 2015004755 A1 WO2015004755 A1 WO 2015004755A1
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WO
WIPO (PCT)
Prior art keywords
light
lens
substrate
film thickness
projecting
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Application number
PCT/JP2013/068887
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French (fr)
Japanese (ja)
Inventor
旭陽 佐井
陽平 日向
芳幸 大瀧
Original Assignee
株式会社シンクロン
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Priority to PCT/JP2013/068887 priority Critical patent/WO2015004755A1/en
Priority to JP2013553183A priority patent/JPWO2015004755A1/en
Publication of WO2015004755A1 publication Critical patent/WO2015004755A1/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/542Controlling the film thickness or evaporation rate
    • C23C14/545Controlling the film thickness or evaporation rate using measurement on deposited material
    • C23C14/547Controlling the film thickness or evaporation rate using measurement on deposited material using optical methods
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/0021Reactive sputtering or evaporation
    • C23C14/0036Reactive sputtering
    • C23C14/0073Reactive sputtering by exposing the substrates to reactive gases intermittently
    • C23C14/0078Reactive sputtering by exposing the substrates to reactive gases intermittently by moving the substrates between spatially separate sputtering and reaction stations
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • C23C14/505Substrate holders for rotation of the substrates
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0616Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating
    • G01B11/0625Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material of coating with measurement of absorption or reflection

Definitions

  • the present invention relates to an optical film thickness meter, a thin film forming apparatus, and a film thickness measuring method for measuring the film thickness of an optical thin film formed on a substrate.
  • An optical thin film is formed on the substrate surface by physical vapor deposition such as sputtering to produce optical products such as interference filters, such as antireflection filters, half mirrors, various bandpass filters, dichroic filters, and coloring on the surface of various decorative products.
  • physical vapor deposition such as sputtering to produce optical products such as interference filters, such as antireflection filters, half mirrors, various bandpass filters, dichroic filters, and coloring on the surface of various decorative products.
  • the application of physical vapor deposition such as sputtering to precision optical products such as wide-angle lenses used in single-lens reflex digital cameras and projectors and precision optical filters for game machines is spreading.
  • a method of measuring the film thickness of a thin film formed on a substrate As a method of measuring the film thickness of a thin film formed on a substrate, a method using a crystal film thickness meter, or an indirect optical film that monitors a film thickness using a monitor substrate arranged at a position different from the film formation substrate There is a thickness monitor method.
  • precise film thickness measurement is difficult with a quartz film thickness meter or an indirect optical film thickness monitor system.
  • the indirect optical film thickness monitoring method is so-called indirect measurement, and there is a distance between the monitor substrate and the film formation substrate, and a physical space is separated.
  • there are unstable factors such as changes in the distribution of vapor deposition particles after electron beam irradiation and the influence of gas released from the wall surface of the vacuum system, and the density of the film material scattered in the vacuum system. Is not constant, and there is a scattering distribution of the film substance in the vacuum apparatus. Therefore, the film thickness to be formed varies depending on the position of the substrate disposed in the vacuum apparatus, and is not suitable for highly accurate film formation.
  • the film thickness accuracy required for precision optical parts is achieved even if the film thickness is controlled by a quartz film thickness meter or an indirect optical film thickness monitor method. This is difficult and causes a decrease in the production yield of precision optical components.
  • the indirect type optical film thickness monitoring method an error due to a physical space between the monitor glass and the film formation substrate is currently corrected with a parameter called tooling. Therefore, in recent years, measurement and monitoring of film thickness by a direct-viewing optical film thickness monitor method that directly measures the film thickness of a substrate whose optical characteristics are to be measured has come into practical use.
  • the direct-view type optical film thickness monitor method is widely used when a film is formed on a stationary substrate by a vacuum deposition method, a sputtering method, or the like.
  • a carousel type substrate holder in which a plurality of substrates are held on the outer peripheral surface of a rotating drum, a dome type rotating substrate holder, etc.
  • a film forming apparatus is known.
  • a carousel type or dome type rotary substrate holder rotates around a rotation axis while holding a plurality of substrates. The substrate revolves around the rotation axis, and there is no substrate that remains in one place while the substrate holder is rotating.
  • the direct-view type optical film thickness monitor method it is necessary to temporarily stop the rotation of the substrate holder and then perform an optical measurement or the like on the substrate.
  • the thin film forming process must be stopped every time the film thickness is measured, and thus the thin film forming process takes time.
  • the inventors of the present invention have used a direct-view optical film thickness monitor method to measure and monitor the film thickness in a film deposition apparatus equipped with a carousel-type substrate holder.
  • a direct-view optical film thickness monitor method to measure and monitor the film thickness in a film deposition apparatus equipped with a carousel-type substrate holder.
  • a reflection-type optical film thickness meter that projects light and calculates the film thickness by receiving and analyzing the reflected light (for example, Patent Document 1).
  • Patent No. 4800734 paragraphs 0092 to 0124, FIGS. 1, 2 and 6)
  • the film thickness meter of Patent Document 1 is provided on the wall of a vacuum chamber of a carousel-type sputtering apparatus, and includes a light source, a light projecting optical fiber, a light projecting photometric probe, a condensing lens, and a light receiving device.
  • a photometric probe for light projection and light reception is opposed to a substrate held on the outer peripheral surface of a rotary drum type substrate holder.
  • film thickness measurement using the film thickness meter of Patent Document 1 light from a light source is projected from an optical fiber, and is projected onto a rotating substrate through a light metering probe and a condenser lens.
  • the reflected light partially transmitted and reflected at the interface between the substrate surface and the deposited thin film is received by the optical fiber through the condensing lens and the photometric probe for light reception and guided to the optical measuring means.
  • the intensity of light is measured by an optical measuring means.
  • Patent Document 1 measures the film thickness of the thin film on the substrate attached to the side surface of the substrate holder that rotates at high speed, photometry for light projection and light reception during film formation.
  • the emission angle and incident angle of light onto the substrate surface by the probe are constantly changing. Therefore, it is difficult to control the emission angle and incidence angle of light on the substrate surface. If the substrate is inclined due to mounting error or rotation unevenness and the incident angle of the measurement light exceeds a certain angle, the reflected light is reflected from the condenser lens. It sometimes protrudes to the outside, making measurement difficult.
  • the present invention has been made in view of the above circumstances, and its purpose is to directly measure the thickness of an optical thin film on a rotating substrate attached to a substrate holder of a rotating optical thin film forming apparatus.
  • a reflective optical film thickness meter, a thin film forming apparatus, and a film thickness measuring method which are less affected by variations in the angle of a rotating substrate and have high measurement accuracy, a thin film forming apparatus, and a film It is to provide a thickness measuring method.
  • the object is to attach the optical thin film on the substrate which is attached to the substrate holder of the rotary optical thin film forming apparatus and rotates according to the rotation of the substrate holder.
  • a reflection-type optical film thickness meter for measuring a film thickness wherein a measurement light is projected toward the rotating substrate, and is disposed between the light projection unit and the substrate.
  • a projection-side lens unit comprising a projection-side lens that receives the measurement light emitted from the light projecting unit and guides the measurement light to the substrate, and the reflected light of the measurement light from the substrate.
  • the rotating measurement target substrate is measured by the substrate mounting error, the rotation unevenness of the substrate holder, etc. Even when tilted with respect to a plane perpendicular to the light axis, the reflected light reflected by the substrate is unlikely to deviate from the optical path of the light-receiving lens, and the amount of reflected light can be accurately detected. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
  • the film thickness of the thin film on the sample substrate is directly measured without providing a separate monitor substrate in a rotating optical thin film forming apparatus.
  • a direct-view optical film thickness meter can be provided. Therefore, when a mass-produced rotary optical thin film forming device is used, unlike a quartz oscillator thickness meter or an indirect type optical film thickness meter, it has a high accuracy as required for precision optical components. The film thickness can be controlled.
  • the light-projecting side lens and the light-receiving side lens are separate and independent lenses, and the effective diameter of the light-projecting side lens is preferably smaller than the effective diameter of the light-receiving side lens. is there.
  • the lens on the light projecting side and the lens on the light receiving side are separate lenses independent from each other, the optical paths of the measurement light and the reflected light can be separated into two with a simple configuration.
  • the effective diameter of the lens on the light emitting side is smaller than the effective diameter of the lens on the light receiving side, even when the substrate is tilted when measuring the film thickness, the light receiving having a larger effective diameter than the lens on the light projecting side is received.
  • the lens on the side can receive the reflected light.
  • the angle between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens is 3 ° to 10 °
  • the distance from the light-projecting lens to the substrate is:
  • the distance from the light projecting unit to the lens on the light projecting side may be longer, and the distance from the lens on the light receiving side to the substrate may be longer than the distance from the light receiving unit to the lens on the light receiving side.
  • the angle formed between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens passes through the intersection of the optical axis of the light-projecting lens and the optical axis of the light-receiving lens.
  • the lens on the light receiving side may be arranged at a position where the straight line passes.
  • the light-receiving side lens and the light-projecting side lens can be arranged close to each other.
  • the lens on the light-projecting side and the lens on the light-receiving side can be made up of lenses with a larger effective diameter while being compactly arranged in a narrow area, and the film thickness can be measured with high accuracy.
  • An optical film thickness meter suitable for measuring the film thickness of an optical thin film for precision optical components can be realized.
  • the effective diameter of the condensing lens may be larger than the sum of the effective diameter of the light-projecting side lens and the effective diameter of the light-receiving side lens.
  • the film thickness can be measured with high accuracy, and an optical film thickness meter suitable for measuring the film thickness of the optical thin film for precision optical components can be realized. Further, by further providing a condensing lens as described above, the optical film thickness meter can be configured compactly while keeping the incident angle of the measurement light small and improving the parallelism of the incident light.
  • the light projecting side lens and the light receiving side lens are formed as a single light projecting / receiving side combined lens, and the measurement light is interposed between the light projecting / receiving side lens and the light receiving unit.
  • a beam splitter may be disposed that reflects the reflected light at the same time as passing through and has a beam branching surface inclined with respect to the axis of the reflected light.
  • the optical path of the projected measurement light and the reflected light to be received can be obtained without configuring the light-projecting lens and the light-receiving lens as separate bodies. Can be separated. Even when the substrate to be measured is tilted with respect to a plane perpendicular to the axis of the measurement light due to substrate mounting error, rotation unevenness of the substrate holder, etc., the reflected light reflected by the substrate is projected. It becomes difficult to deviate from the optical path of the light-receiving side combined lens, and the amount of reflected light can be accurately detected.
  • An aperture for limiting the amount of measurement light emitted from the light projecting unit is provided between the light projecting and receiving side combined lens and the light projecting unit, and the light projecting side lens unit is provided on the light projecting and receiving side.
  • the reflected light is difficult to deviate from the optical path of the lens for the light projecting and receiving side, and the amount of the reflected light Can be detected accurately.
  • it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
  • the lens may be a combined lens in which a plurality of lenses are combined so as to remove aberration of a beam of light emitted from the lens. Since it is configured in this way, it is possible to prevent aberrations such as chromatic aberration and spherical aberration from occurring in the light beam emitted from the light projecting side lens, the light receiving side lens, the light projecting / receiving side lens or the condenser lens, The film thickness of the optical thin film can be measured more accurately.
  • the subject is a substrate holder that can rotate while supporting a substrate in a vacuum vessel, and a thin film disposed opposite to the substrate held by the substrate holder.
  • the optical film thickness meter comprises the optical film thickness meter according to any one of claims 1 to 8.
  • the substrate holder is hardly affected by variations in the substrate tilt angle due to substrate mounting errors, substrate holder rotation unevenness, etc. Accordingly, the thickness of the optical thin film on the rotating substrate can be measured accurately and stably.
  • the object is a reflective method for measuring the film thickness of an optical thin film formed on a rotating substrate according to the rotation of the substrate holder of the rotary optical thin film forming apparatus.
  • the method of measuring a film thickness of the method wherein the measurement light is projected from the light projecting unit toward the rotating substrate through a light projecting side lens unit including a lens on the light projecting side.
  • the reflected light of the measurement light is provided with a light-receiving side lens having an effective area larger than the effective area of the light-projecting side lens unit, and at least a part is separated from the optical path of the light-projecting side lens unit.
  • the light quantity of the reflected light that is guided to the light receiving unit through the light receiving side lens unit having an effective area larger than the effective area of the light projecting side lens unit and received by the light receiving unit.
  • the film thickness of an optical thin film can be measured accurately and stably.
  • the rotating measurement target substrate is caused by the substrate mounting error, the rotation unevenness of the substrate holder, and the like. Even when tilted with respect to a plane perpendicular to the axis of the measurement light, the reflected light reflected by the substrate is unlikely to deviate from the optical path of the lens on the light receiving side, and the amount of reflected light can be detected accurately. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
  • the film thickness of the thin film on the sample substrate is directly measured without providing a separate monitor substrate in a rotating optical thin film forming apparatus.
  • a direct-view optical film thickness meter can be provided. Therefore, when a mass-produced rotary optical thin film forming device is used, unlike a quartz oscillator thickness meter or an indirect type optical film thickness meter, it has a high accuracy as required for precision optical components. The film thickness can be controlled.
  • FIG. 6 is a perspective explanatory view of lens arrangement of the optical film thickness meter of FIG. 5.
  • Examples 1 and 2 using an optical film thickness meter having a lens arrangement according to Comparative Example 1, when measuring light is emitted from a substrate having an inclination angle of 0.0 to 2.0 ° from the substrate It is a graph which shows the result of having calculated the relative reflectance of the reflected light.
  • FIG. 3 shows the result of examining the variation in light quantity during thin film formation when the experiment of forming a multilayer AR film on the substrate S is repeated a plurality of times by controlling the film thickness with a film thickness meter having the lens arrangement of FIG. It is a graph to show.
  • FIG. 3 shows the result of examining the variation in light quantity during thin film formation when the experiment of forming a multilayer AR film on the substrate S is repeated a plurality of times by controlling the film thickness with a film thickness meter having the lens arrangement of FIG. It is a graph to show.
  • a thin film forming apparatus in which a film thickness meter 40 as an optical film thickness meter of the present embodiment is used includes a rotary substrate holder that rotates a substrate holder that holds a substrate.
  • the substrate holding surface of the substrate holder and the normal of the substrate held on the substrate holding surface with respect to the rotation axis of the substrate holder such as a dome-shaped substrate holder, a carousel type substrate holder with a rotating drum, etc.
  • the substrate holder is not limited to a dome type formed in a spherical shape or a cylindrical shape, but includes a polygonal pyramid shape or a polygonal column shape.
  • the optical film thickness meter according to the present invention is not limited to a thin film forming apparatus having a rotary substrate holder that revolves around the substrate, but also used in an in-line thin film forming apparatus in which the substrate moves in a linear direction. Can do.
  • FIG. 1 An example in which the film thickness meter 40 of this embodiment is used in the carousel type sputtering apparatus 1 will be described.
  • the present invention is not limited to the sputtering apparatus, and may be used for other thin film forming apparatuses such as a vacuum deposition apparatus and a CVD apparatus.
  • a sputtering apparatus 1 in which the film thickness meter 40 of the present embodiment is installed is shown in FIG. 1 includes a vacuum vessel 11, a rotating drum 12, a pair of sputtering sources 20A and 20B, and a plasma source 30 as main components.
  • the vacuum vessel 11 is a known rectangular vacuum vessel used in sputtering, and is divided into a thin film forming chamber 11A and a load lock chamber 11B by a door.
  • the rotating drum 12 is a substrate holder that holds the substrate S, and has a substantially cylindrical shape with a vertical rotation axis Z as the center, as shown in FIG. 1, and is configured to hold the substrate S on the outer peripheral surface. Yes.
  • the rotating drum 12 only needs to be rotatable about the rotation axis Z, and may be formed of a polygonal column or a conical hollow body.
  • a disc-shaped frame (not shown) is fixed to the lower end of the rotating drum 12 so as to close a hollow space in the rotating drum 12, and a rotating shaft of a motor (not shown) is connected to the center of the frame. ing.
  • the rotary drum 12 can be driven to rotate by driving a motor (not shown).
  • a timing detection reflecting plate 15 is attached to the upper end portion of the rotating drum 12, and the passage thereof can be detected by the timing sensor 16.
  • the sputtering sources 20A and 20B are means for depositing a metal or an incomplete compound thereof on the substrate S.
  • the sputtering sources 20A and 20B are each a known dual cathode type magnetron sputtering source, and a pair of targets are formed on the side walls of the thin film forming chamber 11A. 22A and 22B are provided to face the substrate S. As shown in FIG. 1, the sputtering sources 20A and 20B include a pair of magnetron sputtering electrodes 21A and 21B that hold a pair of targets 22A and 22B, respectively, and an AC power source 24A that supplies power to the magnetron sputtering electrodes 21A and 21B. 24B and transformers 23A and 23B as power control means.
  • film formation process regions 26A and 26B are formed on the front surfaces of the sputtering sources 20A and 20B, respectively.
  • the film forming process regions 26A and 26B are surrounded on four sides by a partition wall 13 protruding from the inner wall surface of the vacuum vessel 11 toward the rotary drum 12, so that each can secure an independent space inside the vacuum vessel 11. It is divided into.
  • the film forming process regions 26A and 26B are provided with piping so that the sputtering gas stored in the gas cylinders 25A and 25B can be supplied.
  • the plasma source 30 is a means for reacting a thin film formed on the substrate S by the sputtering sources 20A and 20B with a reactive gas to form a compound thin film, which is a known plasma source and is a side wall of the thin film forming chamber 11A. Is provided.
  • the plasma source 30 includes a case body 31 fixed so as to close an opening formed in the wall surface of the vacuum vessel 11, and a dielectric plate 32 fixed to the case body 31.
  • An area surrounded by the body plate 32 constitutes an antenna housing chamber configured to be evacuated by a vacuum pump.
  • An antenna (not shown) is disposed in the antenna housing chamber, and this antenna is connected to the high frequency power source 34 via the matching box 33 and receives an electric power from the high frequency power source 34 to generate an induction electric field in the reaction process region 36.
  • reaction process regions 36 are respectively formed on the front surface of the plasma source 30.
  • the reaction process region 36 is surrounded on all sides by a partition wall 14 projecting from the inner wall surface of the vacuum vessel 11 toward the rotary drum 12, and each is partitioned so as to ensure an independent space inside the vacuum vessel 11. ing.
  • the reaction process region 36 is provided with a pipe so that the reactive gas stored in the gas cylinder 35 can be supplied.
  • the film thickness meter 40 of this embodiment is attached to the sputtering apparatus 1.
  • the film thickness meter 40 includes a light source 41, an optical fiber 42, a light projecting photometric probe 43, a light projecting side lens 51, a light receiving side lens 52, and a light receiving photometric probe 44.
  • a control device 47 is provided as a main component.
  • the light source 41 is a device that emits white light by power supplied from a power source (not shown), and a known halogen lamp is used in this embodiment.
  • the light projecting photometric probe 43 has a structure in which the end of the optical fiber 42 is housed inside a cylindrical member, and the side wall of the vacuum container 11 is substantially perpendicular to the side surface of the rotary drum 12.
  • the photometering window 17 fitted in this hole is disposed outside the side wall of the vacuum vessel 11 with its end facing the photometric window 17.
  • a light projecting side lens 51 is disposed between the rotary drum 12 and the light projecting photometric probe 43.
  • the light projecting side lens 51 has a diameter of 10 to 20 mm and is a known achromatic lens used for an optical film thickness meter.
  • the light projecting side lens 51 is irradiated from the light projecting photometric probe 43 and converges the light spreading in a wide angle to irradiate the substrate S.
  • the light projecting photometric probe 43 is disposed in the vicinity of the focal point of the light projecting side lens 51.
  • a light receiving side lens 52 is disposed between the rotary drum 12 and the light receiving photometric probe 44.
  • the light-receiving side lens 52 has a diameter of 15 to 30 mm and is made of a known achromatic lens used in a general optical film thickness meter.
  • the light-receiving side lens 52 converges the reflected light from the substrate S spreading over a wide angle and irradiates the photometric probe 44 for light reception.
  • An achromatic lens is an achromatic lens in which chromatic aberration is corrected at two wavelengths, and is realized by combining two or more lenses.
  • the achromatic lens corresponds to the grouped lens in the claims.
  • the light projecting side lens 51 and the light receiving side lens 52 are arranged in parallel on the optical paths of the measurement light and the reflected light, as shown in FIGS.
  • the center 51C of the light projecting side lens 51 and the center 52C of the light receiving side lens 52 have substantially the same distance from the substrate S.
  • An angle ⁇ between the optical axis 51a of the light projecting side lens 51 and the optical axis 52a of the light receiving side lens 52 is 3 to 10 °.
  • a bisector B that bisects the angle between the optical axis 51a and the optical axis 52a passes through the substrate S and has a larger diameter among the light-receiving side lens 52 and the light-projecting side lens 51 provided adjacent to each other. It penetrates the light receiving side lens 52. That is, the large-diameter light receiving side lens 52 is arranged so as to protrude from the bisector B toward the light projecting side lens 51. Accordingly, the film thickness meter 40 can be configured compactly by making the light-projecting lens 51 and the light-receiving lens 52 the angle between the optical axes 51a and 52a as small as 3 to 10 °.
  • the effective diameters of the light projecting side lens 51 and the light receiving side lens 52 can be secured sufficiently large, and a more accurate film thickness meter can be obtained.
  • the effective diameter of the light receiving side lens 52 can be made sufficiently large, and even when the angle of the substrate is inclined with respect to the optical axis of the light projecting side lens 51, it is possible to make it difficult to come off from the light receiving lens 52. .
  • the distance WD between the light projecting side lens 51 and the light receiving side lens 52 and the substrate S is 75 to 350 mm.
  • the distance S1 between the light projecting side lens 51 and the light projecting photometric probe 43 and between the light receiving side lens 52 and the light receiving photometric probe 44 is 35 to 90 mm, and WD is larger than S1. By doing so, the light incident on the substrate becomes closer to parallel light, and the film thickness can be measured with higher accuracy.
  • the light-receiving photometric probe 44 is made of a cylindrical member and receives the reflected light guided from the light-receiving side lens 52.
  • the light-receiving photometric probe 44 is disposed in the vicinity of the focal point of the light-receiving side lens 52.
  • the light receiving photometric probe 44 is aligned with the light projecting photometric probe 43 on the side surface of the rotary drum 12. It is disposed outside the side wall of the vacuum vessel 11 with its end facing the photometric window 17 fitted in the hole on the side wall of the vacuum vessel 11 so as to face each other. As shown in FIG.
  • the optical detection device 46 is a known collimator made of a flat plate member having a thin slit, deflects reflected light, known grating for emitting only light of a predetermined wavelength out of light incident from the collimator, and grating It is a well-known optical detection device provided with a photodiode for detecting light emitted from.
  • the optical detection device 46 is connected to a control device 48 via an integration amplifier 47, and is configured such that the control device 48 can control the film thickness based on a light reception signal detected by the optical detection device 46.
  • the pair of targets 22A and 22B are held by the pair of magnetron sputtering electrodes 21A and 21B.
  • the thin film forming chamber 11A is brought into a vacuum state of about 10 ⁇ 2 Pa to 10 Pa by evacuating by operating the vacuum pump.
  • the substrate S is attached to the rotary drum 12 with the rotary drum 12 locked at the position of the load lock chamber 11B.
  • the load pump chamber 11B is evacuated by operating the vacuum pump, and a vacuum state of about 10 ⁇ 2 Pa to 10 Pa is set.
  • the door between the thin film forming chamber 11A and the load lock chamber 11B is opened, the rotating drum 12 is moved to the thin film forming chamber 11A, and the door is closed again.
  • the inside of the vacuum vessel 11 and the inside of the antenna housing chamber are depressurized to a predetermined pressure.
  • the pressure in the film forming process region 26A is adjusted to 1.0 ⁇ 10 ⁇ 1 Pa to 1.3 Pa.
  • the rotating drum 12 is rotated by operating a motor (not shown).
  • a motor not shown
  • the operator turns on a switch (not shown) of the light source 41 and starts projecting continuous light from the light source 41.
  • Light from the light source 41 is transmitted through the optical fiber 42 and irradiated onto the surface of the substrate S from the end of the light projecting photometric probe 43.
  • thin film formation processing is started in the film forming process area 26A and the reaction process area 36.
  • sputtering is performed on the pair of targets 22A, and a thin film made of metal or an incomplete reaction product of metal is formed on the surface of the substrate S.
  • an intermediate thin film mainly composed of a complete reaction product of metal is formed by introducing a reactive gas into the thin film formed in the film formation process region 26A.
  • the current address of the rotary drum 12 is detected by the timing sensor 16, and the control device 48 determines whether it is an address at which sampling of light amount data is started.
  • the current address is an address at which light quantity sampling is started
  • a sampling start signal is transmitted from the control device 48 to the optical detection device 46, and light quantity data sampling is started.
  • the measurement light When the measurement light is continuously irradiated from the light source 41 to the surface of the rotary drum 12 and the substrate S held by the rotary drum 12, the light is projected when reaching the address at which sampling of the light amount data is started.
  • the measurement light projected from the light metering probe 43 and converged by the light projecting side lens 51 irradiates the substrate S.
  • the measurement light is reflected by the substrate S, and the reflected light is received and converged by the light receiving side lens 52 and received by the optical detection device 46 from the light receiving photometric probe 44 through the optical fiber 45.
  • the optical detection device 46 detects the intensity of the received reflected light and transmits a received light signal to the integrating amplifier 47.
  • the integrating amplifier 47 converts this received light signal into a light amount signal and transmits it to the control device 48.
  • the control device 48 determines whether or not the current address detected by the timing sensor 16 is an address at which sampling of the light amount data is finished. If the current address is an address at which the sampling of the light amount data is finished, the sampling of the light amount data is ended. Thereafter, the control device 48 calculates the light amount by integrating the intensity of the light received between the address where the sampling of the light amount data is started and the address where the sampling is finished, and based on this light amount, the film thickness is determined by a known method. Perform the operation. The sampling of the light amount data and the film thickness calculation based on the light amount are performed until the obtained film thickness data matches the desired film thickness value set first.
  • the thin film forming process in the film forming process region 26A and the reaction process region 36 is terminated by a command from the control device 48.
  • thin film formation processing is started in the film formation process region 26B and the reaction process region 36.
  • the thin film forming process in the film forming process area 26A and the reaction process area 36 the same process as the sampling of the light amount data, and the film thickness calculation are performed, and when the film thickness data matches the desired film thickness value.
  • the thin film forming process in the film forming process region 26B and the reaction process region 36 is terminated by a command from the control device 48.
  • the light projecting side lens 51 and the light receiving side lens 52 are configured as separate lenses, but instead of the light projecting side lens 51 and the light receiving side lens 52, as shown in FIG.
  • the lens and the light-receiving side lens may be used together, and the lens may be configured as an integral light-receiving / light-receiving side lens 53 that guides both the measurement light applied to the substrate S and the reflected light from the substrate S.
  • the measurement light and the reflected light can be separated by providing a beam splitter 54 that transmits the measurement light and reflects the reflected light on the opposite side of the substrate S of the light emitting / receiving lens 53.
  • the light emitting / receiving lens 53 has a diameter of 15 to 40 mm and is a known achromatic lens used in a general optical film thickness meter.
  • the achromatic lens corresponds to the grouped lens in the claims.
  • the beam splitter 54 shown in FIG. 4 is composed of a known plate beam splitter, but measures a beam branch plane that transmits measurement light incident from the opposite side of the substrate S and reflects reflected light incident from the substrate S side. It suffices if it is provided at an angle of 45 ° with respect to the optical axis of the light and the optical axis of the reflected light, and it may be composed of a cube beam splitter and a pellicle beam splitter.
  • an aperture member 55 is provided between the beam splitter 54 and the light projecting photometric probe 43, and the aperture member 55 has an aperture 55a for shaping the shape of the light beam emitted from the light projecting photometric probe 43. Is formed.
  • the aperture 55a has a shape that can limit the amount of light projected at a position corresponding to the optical path of the reflected light from the substrate S by about 20 to 50%.
  • the aperture 55a is provided, even if the substrate S is slightly inclined with respect to the plane perpendicular to the optical axis of the measurement light and the incident angle of the measurement light is changed, the reflected light is rotated. Spreading along the rotation direction V of the drum 12 is suppressed. As a result, it is possible to suppress the reflected light from protruding from the light projecting / receiving lens 53, and to suppress an error in the film thickness measurement value due to variations in the substrate angle.
  • a silver film in which a hole having a shape capable of limiting the amount of light projected at a position corresponding to the optical path of the reflected light from the substrate S by about 20 to 50% is formed in the beam splitter 54.
  • a reflective metal such as may be attached.
  • the distance WD between the light projecting / receiving side lens 53 and the substrate S is 75 to 350 mm
  • the distance S2 between the light projecting / receiving side lens 53 and the light projecting photometric probe 43 is 35 to 35 mm. 90 mm.
  • the light-receiving photometric probe 44 is positioned closer to the substrate S than the light-projecting photometric probe 43 and the beam splitter 54, and to the position on the opposite side of the light-projecting photometric probe 43 with respect to the optical axis of the light-projecting / receiving-side lens 53.
  • the light projecting photometric probe 43 is installed at an angle.
  • the measurement light irradiated from the light projecting photometric probe 43 is projected by the aperture 55a at a position corresponding to the optical path of the reflected light from the substrate S.
  • the light is transmitted through the beam splitter 54, guided by the light projecting / receiving side lens 53, and irradiated onto the substrate S.
  • a part of the measurement light incident on the substrate S is reflected by the substrate S, guided by the light projecting / receiving lens 53 and incident on the beam splitter 54.
  • the reflected light is reflected in the vertical direction by the beam splitter 54 and received by the photometric probe 44 for light reception.
  • the aperture member 55, the beam splitter 54, and the light projecting / receiving side combined lens 53 are the light projecting side lens unit, the light projecting / receiving side combined lens 53, and the beam splitter 54 are within the scope of the claims. Corresponds to the light-receiving side lens unit.
  • FIG. 5 a light projecting side lens 56, a light receiving side lens 57, and a condensing lens 58 are disposed between the light projecting photometric probe 43 and the rotary drum 12.
  • a condensing lens 58 that is used both for guiding the measurement light passing through the light receiving side lens 57 and for guiding reflected light from the substrate S. It has been.
  • the diameter of the condensing lens 58 is 40 mm, which is larger than the sum of the diameters of the light projecting side lens 56 and the light receiving side lens 57.
  • the condensing lens 58 is disposed so that one surface thereof faces the light projecting side lens 56 and the light receiving side lens 57 and the other surface thereof faces the substrate S.
  • the distance WD between the condenser lens 58 and the substrate S is 75 to 350 mm, and the distances S3 and S4 between the light receiving side lens 57 and the light receiving photometric probe 44 are 35 to 90 mm. 5 and 6, the light receiving photometric probe 44 and the light projecting side lens 56 are arranged closer to the condenser lens 58 and the substrate S than the light projecting measuring probe 43 and the light receiving side lens 57, respectively. Has been. Therefore, the position where the light receiving measurement probe 44 and the light receiving side lens 57 are sandwiched between the light projecting measuring probe 43 and the light projecting side lens 56 in a direction substantially along the traveling direction of the measurement light and the reflected light. It has become a relationship.
  • the light projecting side lens 56 is a lens for guiding the measurement light from the light projecting photometric probe 43 and has a diameter of about 15 mm.
  • the light-receiving side lens 57 is a lens that guides reflected light from the substrate S, and has a diameter larger than that of the light-projecting side lens 56 and 20 mm.
  • Other configurations of the light projecting side lens 56 and the light receiving side lens 57 are the same as those of the light projecting side lens 51 and the light receiving side lens 52, respectively.
  • the light projecting side lens 56 and the light receiving side lens 57 are arranged such that the center 56C of the light projecting side lens 56 and the center 57C of the light receiving side lens 57 are located on both sides of the optical axis 58a of the condenser lens 58. Yes.
  • the optical axis 58 a of the condensing lens 58 is the end of the large-diameter light receiving side lens 57 among the light receiving side lens 56 and the light projecting side lens 57 provided adjacent to each other. It is arranged so that the parts are close.
  • the optical axis 58 a of the condenser lens 58 may be disposed so as to penetrate the large-diameter light-receiving side lens 57.
  • the light projecting photometric probe 43 is disposed in the vicinity of the focal point of the light projecting side lens 56
  • the light receiving photometric probe 44 is disposed in the vicinity of the focal point of the light receiving side lens 57.
  • the focal length of the light projecting side lens 56 is longer than the focal length of the light receiving side lens 57
  • the light receiving photometric probe 44 is larger than the light projecting photometric probe 43.
  • the measurement light projected from the light projecting photometric probe 43 is incident on the condensing lens 58 through the light projecting side lens 56, and converged by the condensing lens 58. S is irradiated. The measurement light is reflected by the substrate S, and the reflected light is guided to the condenser lens 58. The guided measurement light is converged by the light receiving side lens 57 and received by the light receiving photometric probe 44.
  • the lens arrangement of the proportional 1 is such that a single condensing lens (not shown) is placed between the substrate S and the light projecting photometric probe 43 and the light receiving photometric probe 44 as an axis of the light projecting photometric probe 43.
  • the lens arrangement of the prior art provided substantially perpendicularly is used. The distance WD between the condensing lens (not shown) of FIG. 3 and FIG.
  • the substrate S held on the rotary drum 12 is inclined at each angle within a range of 0.0 ° to 2.0 ° with respect to the surface facing the light projecting photometric probe 43 and the light receiving photometric probe 44.
  • Example 1 in FIG. 3 0.0 ° to 2.0 ° with respect to the plane perpendicular to the bisector B that bisects the angle between the optical axis 51a and the optical axis 52a.
  • the arrangement was inclined at each angle within the range of.
  • Example 2 and Comparative Example 1 in FIG. 4 0.0 ° to 2.0 ° with respect to a plane perpendicular to the optical axis of the light emitting / receiving lens 53 or a condensing lens (not shown).
  • the arrangement was inclined at each angle within the range of. In this state, the relative reflectance was calculated.
  • the relative reflectance was calculated by calculating the intensity of light projected from the light source and received by the optical detection device 46.
  • the relative reflectance at each tilt angle was calculated using the calculated value when the tilt angle of the substrate S was 0.0 ° as a standard value.
  • Table 1 and FIG. 7 show the calculation results of the relative reflectance (%) at each inclination angle of Examples 1 and 2 and Comparative Example 1.
  • the relative reflectance is 68.9% and the rate of change in the amount of reflected light is about 31%. That is, when the substrate S having an effective measurement range of 20 mm is mounted on the rotary drum 12 having a diameter of 500 mm, the substrate is measured during film thickness measurement due to uneven rotation of the rotary drum 12 or mounting errors of the substrate S to the rotary drum 12. Although S can be tilted up to about 1.2 °, in contrast 1, the amount of reflected light is reduced by about 30% due to the tilt of the substrate S that can generally occur as an error. As a total, it was found that there was no practical degree of accuracy.
  • Example 1 The film thickness is controlled by the film thickness meter 40 having the lens arrangement shown in FIG. 3 and the experiment for forming the multilayer AR film on the substrate S is repeated a plurality of times, and the light amount change during the thin film formation and the multilayer AR film The variation of spectral characteristics was examined.
  • the distance WD in FIG. 3 was 200 mm
  • the diameters of the light projecting side lens 51 and the light receiving side lens 52 in FIG. 3 were 30 mm and 20 mm.
  • silicon (Si) is used as the first target 22A
  • niobium (Nb) is used as the second target 22B
  • Argon gas is used as a reactive gas introduced into the reaction process region 36
  • silicon oxide (SiO 2 ) and niobium oxide (Nb 2 O) are formed on the plurality of substrates S held on the rotary drum 12.
  • An optical multilayer film in which three thin films are alternately laminated that is, a thin film of SiO 2 —Nb 2 O 5 —SiO 2 —Nb 2 O 5 —SiO 2 is laminated in the order closer to the substrate S.
  • a multilayer film having a five-layer structure was formed.
  • the film thickness of the first SiO 2 layer and the second Nb 2 O 5 layer was controlled by an absolute value control method. That is, using the film thickness meter 40 arranged in FIG. 3, the measurement light emitted from the light source 41 is irradiated from the light projecting photometric probe 43 toward the substrate S, and the reflected light received by the light receiving photometric probe 44 is reflected. The film thickness is monitored by detecting the intensity with the optical detection device 46, calculating the amount of light with the control device 48 based on the intensity data of the reflected light, and monitoring the fluctuation state of the light amount change curve in which the amount of light is plotted. did. The film formation was terminated when the film thickness reached a predetermined target value. Further, at the end of the second layer film formation, the film formation rate coefficient for time control was calculated by dividing the film thickness when the film formation was completed by the film formation time required for the film formation.
  • the film thickness of the third SiO 2 layer was controlled by the B / A control method using the film thickness meter 40 having the lens arrangement shown in FIG.
  • the B / A control method is to irradiate the generated thin film with monitor light, measure the change in transmittance of the monitor light transmitted / reflected from the thin film, and to express a certain amplitude, maximum value, This is a method of controlling a trajectory having a minimum value by using a ratio (B / A) of a change A from an extreme value of the stop light amount B with respect to an upper and lower width A of the trajectory.
  • the film formation rate coefficient for time control was calculated by dividing the film thickness at the end of film formation by the film formation time taken for film formation.
  • the film thicknesses of the fourth Nb 2 O 5 layer and the fifth SiO 2 layer were controlled by a time control method using the film formation rate coefficients calculated during the formation of the second and third layers.
  • the film formation times of the fourth layer and the fifth layer are calculated from the film formation rates of the second layer and the third layer and the desired film thicknesses formed by the fourth layer and the fifth layer, respectively.
  • the fourth layer and the fifth layer were formed by performing this step for forming the film.
  • FIG. 8 shows a graph of the change in light amount during film formation of samples 1 to 3. As shown in FIG. 8, in the three samples in which the same process was repeated, almost the same change in the amount of light was shown, indicating that the reproducibility was high.
  • FIG. 9 shows a graph of spectral characteristics of Samples 1 to 3 having a 5-layer AR film on the substrate S. As shown in FIG. 9, Samples 1 to 3 have almost the same spectral characteristics, and by controlling the film thickness using the film thickness meter of this example, a five-layer AR having substantially the same spectral characteristics. It was found that the film can be formed with good reproducibility.

Abstract

 Provided is a reflective optical-film-thickness-measurement device attached to a substrate holder of a rotary optical-thin-film-forming device, the optical-film-thickness-measurement device measuring the thickness of the optical thin film on a rotating substrate and not being readily affected by variation in angle of the rotating substrate. The present invention is provided with: a projection-side lens unit provided with a projection part (43) for projecting measurement light towards a rotating substrate (S), and projection-side lenses (51, 56) disposed between the substrate (S) and the projection part (43), the projection side lenses (51, 56) receiving the measurement light emitted from the projection part (43) and guiding the measurement light to the substrate (S); and a reception-side lens unit provided with a light reception part (44) for receiving light reflected by the substrate (S) from the measurement light, and reception-side lenses (52, 57) disposed between the substrate (S) and the reception part (44), the reception side lenses (52, 57) receiving the light reflected by the substrate (S) and guiding this reflected light to the reception unit (44). At least some of the optical path of the reception-side lens unit and the optical path of the projection-side lens unit are separate, and the active area of the projection-side lens unit is less than the active area of the reception-side lens unit.

Description

光学式膜厚計,薄膜形成装置及び膜厚測定方法Optical film thickness meter, thin film forming apparatus, and film thickness measuring method
 本発明は基板上に形成された光学薄膜の膜厚を測定する光学式膜厚計,薄膜形成装置及び膜厚測定方法に関する。 The present invention relates to an optical film thickness meter, a thin film forming apparatus, and a film thickness measuring method for measuring the film thickness of an optical thin film formed on a substrate.
 スパッタリング等の物理蒸着により、基板表面に光学薄膜を形成させて干渉フィルター、例えば反射防止フィルター、ハーフミラー、各種バンドパスフィルター、ダイクロイックフィルターなどの光学製品を製造したり、各種装飾品の表面に色付けコートを行ったりすることにより、特定の光学特性を有する装飾品等を製造することが一般的に行われている。
 その中でも、一眼レフデジタルカメラやプロジェクタに用いられる広角レンズやゲーム機用精密光学フィルター等、精密光学製品へのスパッタリング等の物理蒸着の応用が広がっている。
 基板上に成膜される薄膜の膜厚を測定する方法として、水晶膜厚計を使う方法や、成膜基板とは異なる位置に配置したモニタ基板を用いて膜厚モニタを行う間接型光学膜厚モニタ方式がある。
 しかし、水晶膜厚計や間接型光学膜厚モニタ方式では、精密な膜厚測定が難しい。
An optical thin film is formed on the substrate surface by physical vapor deposition such as sputtering to produce optical products such as interference filters, such as antireflection filters, half mirrors, various bandpass filters, dichroic filters, and coloring on the surface of various decorative products. In general, it is common to manufacture decorative articles having specific optical characteristics by coating.
Among them, the application of physical vapor deposition such as sputtering to precision optical products such as wide-angle lenses used in single-lens reflex digital cameras and projectors and precision optical filters for game machines is spreading.
As a method of measuring the film thickness of a thin film formed on a substrate, a method using a crystal film thickness meter, or an indirect optical film that monitors a film thickness using a monitor substrate arranged at a position different from the film formation substrate There is a thickness monitor method.
However, precise film thickness measurement is difficult with a quartz film thickness meter or an indirect optical film thickness monitor system.
 間接型光学膜厚モニタ方式は、いわゆる間接的な計測であって、モニタ基板と成膜基板との間には、距離があり、物理的な空間を隔てている。また、電子ビーム加熱蒸着装置では、電子ビーム照射後の蒸着粒子分布の変化や、真空装置の壁表面からの放出ガスの影響などの不安定要因があり、真空装置内で飛散する膜物質の密度は一定ではなく、真空装置内には膜物質の飛散分布が存在する。従って、真空装置内で配置される基板の位置に応じて、成膜される膜厚が異なり、高精度な成膜には、不向きである。
 従って、精密光学部品の薄膜を物理蒸着により成膜する場合、水晶膜厚計や間接型光学膜厚モニタ方式で膜厚を制御しても、精密光学部品に要求される膜厚精度を達成することは困難であり、精密光学部品の製造の歩留まりの低下の原因となっている。
 間接型光学膜厚モニタ方式において、モニタガラスと成膜基板との間の物理的な空間に起因する誤差は、toolingとよばれるパラメータで補正を行っているのが現状である。
 そこで、近年、光学特性を測定したい基板の膜厚を直接測定する直視型光学膜厚モニタ方式による膜厚の計測及び監視が、実用化されるようになった。直視型光学膜厚モニタ方式は、静止した基板に真空蒸着法やスパッタリング法等により成膜する場合に、広く用いられている。
The indirect optical film thickness monitoring method is so-called indirect measurement, and there is a distance between the monitor substrate and the film formation substrate, and a physical space is separated. In addition, in the electron beam heating vapor deposition system, there are unstable factors such as changes in the distribution of vapor deposition particles after electron beam irradiation and the influence of gas released from the wall surface of the vacuum system, and the density of the film material scattered in the vacuum system. Is not constant, and there is a scattering distribution of the film substance in the vacuum apparatus. Therefore, the film thickness to be formed varies depending on the position of the substrate disposed in the vacuum apparatus, and is not suitable for highly accurate film formation.
Therefore, when a thin film of precision optical parts is formed by physical vapor deposition, the film thickness accuracy required for precision optical parts is achieved even if the film thickness is controlled by a quartz film thickness meter or an indirect optical film thickness monitor method. This is difficult and causes a decrease in the production yield of precision optical components.
In the indirect type optical film thickness monitoring method, an error due to a physical space between the monitor glass and the film formation substrate is currently corrected with a parameter called tooling.
Therefore, in recent years, measurement and monitoring of film thickness by a direct-viewing optical film thickness monitor method that directly measures the film thickness of a substrate whose optical characteristics are to be measured has come into practical use. The direct-view type optical film thickness monitor method is widely used when a film is formed on a stationary substrate by a vacuum deposition method, a sputtering method, or the like.
 一方、多数の基板に成膜して光学フィルターを大量生産する装置として、回転ドラムの外周面に複数の基板が保持されるカルーセル式の基板ホルダや、ドーム型の回転式基板ホルダ等を備えた成膜装置が知られている。
 カルーセル式やドーム型の回転式基板ホルダは、複数の基板を保持した状態で、回転軸を中心に回転する。基板は、回転軸を中心に公転し、基板ホルダの回転中は、一箇所にとどまった状態の基板が存在しない。
 従って、直視型光学膜厚モニタ方式で膜厚等の物性値を測定するためには、基板ホルダの回転を一旦停止してから基板に対して光学測定等を行う必要があった。このような測定方法では、膜厚測定のたびに薄膜形成工程を停止しなければならないため、薄膜形成工程に時間がかかっていた。
On the other hand, as an apparatus for mass production of optical filters by forming a film on a large number of substrates, a carousel type substrate holder in which a plurality of substrates are held on the outer peripheral surface of a rotating drum, a dome type rotating substrate holder, etc. A film forming apparatus is known.
A carousel type or dome type rotary substrate holder rotates around a rotation axis while holding a plurality of substrates. The substrate revolves around the rotation axis, and there is no substrate that remains in one place while the substrate holder is rotating.
Therefore, in order to measure a physical property value such as a film thickness by the direct-view type optical film thickness monitor method, it is necessary to temporarily stop the rotation of the substrate holder and then perform an optical measurement or the like on the substrate. In such a measuring method, the thin film forming process must be stopped every time the film thickness is measured, and thus the thin film forming process takes time.
 そこで、本発明者らは、カルーセル式の基板ホルダを備えた成膜装置において、直視型光学膜厚モニタ方式で膜厚を計測、監視する装置として、回転している測定対象の膜に光源の光を投光し、その反射光を受光して解析することにより膜厚を算出する反射式の光学式膜厚計を利用するものを提案した(例えば、特許文献1)。 Therefore, the inventors of the present invention have used a direct-view optical film thickness monitor method to measure and monitor the film thickness in a film deposition apparatus equipped with a carousel-type substrate holder. There has been proposed one that uses a reflection-type optical film thickness meter that projects light and calculates the film thickness by receiving and analyzing the reflected light (for example, Patent Document 1).
特許第4800734号(段落0092~0124,図1,2,6)Patent No. 4800734 (paragraphs 0092 to 0124, FIGS. 1, 2 and 6)
 特許文献1の膜厚計は、カルーセル式のスパッタ装置の真空チャンバの壁部に設けられており、光源と、投光用の光ファイバと、投光用測光プローブと、集光レンズと、受光用測光プローブと、受光用の光ファイバと、光学測定手段と、を備えている。膜厚計は、回転ドラム式の基板ホルダの外周面に保持される基板に投光用及び受光用の測光プローブを対向させている。
 特許文献1の膜厚計を用いた膜厚測定は、光源からの光を光ファイバから投光し、投光用測光プローブ及び集光レンズを通して、回転中の基板に投光する。基板の表面と堆積された薄膜との間の界面で一部が透過して一部が反射した反射光を、集光レンズと、受光用測光プローブを通して光ファイバで受光して光学測定手段に導き、光学測定手段で、光の強度を測定する。
 特許文献1の膜厚計によれば、回転ドラム式の基板ホルダが高速で回転するカルーセル式の薄膜形成装置においても、モニタ用基板を別途設けずサンプル基板上の薄膜を直接膜厚測定する直視型の方式により、膜厚測定できるものであった。
The film thickness meter of Patent Document 1 is provided on the wall of a vacuum chamber of a carousel-type sputtering apparatus, and includes a light source, a light projecting optical fiber, a light projecting photometric probe, a condensing lens, and a light receiving device. A photometric probe, a light receiving optical fiber, and an optical measuring means. In the film thickness meter, a photometric probe for light projection and light reception is opposed to a substrate held on the outer peripheral surface of a rotary drum type substrate holder.
In film thickness measurement using the film thickness meter of Patent Document 1, light from a light source is projected from an optical fiber, and is projected onto a rotating substrate through a light metering probe and a condenser lens. The reflected light partially transmitted and reflected at the interface between the substrate surface and the deposited thin film is received by the optical fiber through the condensing lens and the photometric probe for light reception and guided to the optical measuring means. The intensity of light is measured by an optical measuring means.
According to the film thickness meter of Patent Document 1, even in a carousel type thin film forming apparatus in which a rotating drum type substrate holder rotates at a high speed, a direct view of directly measuring the thickness of a thin film on a sample substrate without providing a monitor substrate is provided. The film thickness could be measured by the mold method.
 しかし、この特許文献1の膜厚計は、高速で回転する基板ホルダの側面に取付けられた基板上の薄膜の膜厚を測定するものであるため、成膜中、投光用及び受光用測光プローブによる基板面への光の出射角及び入射角は、常に変化している。
 従って、基板面への光の出射角及び入射角の制御が難しく、取付誤差や回転むら等により基板が傾斜して測定光の入射角が一定の角度を超えると、反射光が集光レンズの外側まではみ出し、測定が困難になる場合があった。
However, since the film thickness meter of Patent Document 1 measures the film thickness of the thin film on the substrate attached to the side surface of the substrate holder that rotates at high speed, photometry for light projection and light reception during film formation. The emission angle and incident angle of light onto the substrate surface by the probe are constantly changing.
Therefore, it is difficult to control the emission angle and incidence angle of light on the substrate surface.If the substrate is inclined due to mounting error or rotation unevenness and the incident angle of the measurement light exceeds a certain angle, the reflected light is reflected from the condenser lens. It sometimes protrudes to the outside, making measurement difficult.
 本発明は、上記事情に鑑みてなされたものであり、その目的は、回転式の光学薄膜形成装置の基板ホルダに取付けられて、回転している基板上の光学薄膜の膜厚を直接測定する反射式の光学式膜厚計,薄膜形成装置及び膜厚測定方法であって、回転中の基板の角度のばらつきによる影響を受けにくく、測定精度の高い光学式膜厚計,薄膜形成装置及び膜厚測定方法を提供することにある。 The present invention has been made in view of the above circumstances, and its purpose is to directly measure the thickness of an optical thin film on a rotating substrate attached to a substrate holder of a rotating optical thin film forming apparatus. A reflective optical film thickness meter, a thin film forming apparatus, and a film thickness measuring method, which are less affected by variations in the angle of a rotating substrate and have high measurement accuracy, a thin film forming apparatus, and a film It is to provide a thickness measuring method.
 前記課題は、請求項1に係る光学式膜厚計によれば、回転式の光学薄膜形成装置の基板ホルダに取付けられ、該基板ホルダの回転に応じて回転している基板上の光学薄膜の膜厚を測定する反射式の光学式膜厚計であって、測定光を、前記回転している前記基板に向けて投光する投光部と、該投光部と前記基板の間に配置され、前記投光部から出射する前記測定光を受けて、該測定光を前記基板に導光する投光側のレンズを備えた投光側レンズユニットと、前記基板から前記測定光の反射光を受光する受光部と、該受光部と前記基板の間に配置され、前記基板からの反射光を受けて、該反射光を前記受光部に導光する受光側のレンズを備えた受光側レンズユニットと、を備え、該受光側レンズユニットの光路と前記投光側レンズユニットの光路とは、少なくとも一部が分離され、前記投光側レンズユニットの有効面積は、前記受光側レンズユニットの有効面積よりも小さいこと、により解決される。 According to the optical film thickness meter of the first aspect, the object is to attach the optical thin film on the substrate which is attached to the substrate holder of the rotary optical thin film forming apparatus and rotates according to the rotation of the substrate holder. A reflection-type optical film thickness meter for measuring a film thickness, wherein a measurement light is projected toward the rotating substrate, and is disposed between the light projection unit and the substrate. A projection-side lens unit comprising a projection-side lens that receives the measurement light emitted from the light projecting unit and guides the measurement light to the substrate, and the reflected light of the measurement light from the substrate. A light receiving side lens, and a light receiving side lens that is disposed between the light receiving unit and the substrate, receives light reflected from the substrate, and guides the reflected light to the light receiving unit. A light path of the light receiving side lens unit and light of the light projecting side lens unit. And it is at least partially separated, the effective area of the light projection-side lens unit is solved by a small fact, than the effective area of the light receiving side lens unit.
 このように、投光側レンズユニットの有効面積は、受光側レンズユニットの有効面積よりも小さいため、基板の取付誤差,基板ホルダの回転むら等により、回転している測定対象の基板が、測定光の軸に垂直な面に対して傾斜した場合であっても、基板で反射した反射光が受光側のレンズの光路から外れ難くなり、反射光の光量を正確に検知できる。その結果、基板の取付誤差や基板ホルダの回転むら等の影響による光量ノイズを最小限に抑えて、回転する基板上に形成された光学式薄膜の膜厚を正確に安定して測定することが可能となる。ひいては、成膜後に膜厚の補正を繰り返す工程が不要となる。 As described above, since the effective area of the light emitting side lens unit is smaller than the effective area of the light receiving side lens unit, the rotating measurement target substrate is measured by the substrate mounting error, the rotation unevenness of the substrate holder, etc. Even when tilted with respect to a plane perpendicular to the light axis, the reflected light reflected by the substrate is unlikely to deviate from the optical path of the light-receiving lens, and the amount of reflected light can be accurately detected. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
 また、回転中の基板上の薄膜に適用可能であるため、ドラム型,ドーム型の回転式の基板ホルダ等を備えた薄膜形成装置に適用可能となり、大量の基板に短時間で薄膜を形成する量産型の薄膜形成装置に適した光学式膜厚計を提供可能となる。
 更に、測定光を、回転している基板に向けて投光する投光部を備えるため、回転式の光学薄膜形成装置において、モニタ用基板を別途設けずサンプル基板上の薄膜を直接膜厚測定する直視型の光学式膜厚計を提供できる。従って、量産型の回転式の光学薄膜形成装置を用いた場合において、水晶振動子膜厚計や間接型光学式膜厚計とは異なり、精密光学部品等で要望されるような、高い精度での膜厚制御が可能となる。
In addition, since it can be applied to a thin film on a rotating substrate, it can be applied to a thin film forming apparatus equipped with a drum-type or dome-type rotary substrate holder, and forms a thin film on a large number of substrates in a short time. It is possible to provide an optical film thickness meter suitable for a mass production type thin film forming apparatus.
In addition, since it has a light projecting unit that projects measurement light toward the rotating substrate, the film thickness of the thin film on the sample substrate is directly measured without providing a separate monitor substrate in a rotating optical thin film forming apparatus. A direct-view optical film thickness meter can be provided. Therefore, when a mass-produced rotary optical thin film forming device is used, unlike a quartz oscillator thickness meter or an indirect type optical film thickness meter, it has a high accuracy as required for precision optical components. The film thickness can be controlled.
 前記投光側のレンズと前記受光側のレンズは、相互に独立した別体のレンズであり、前記投光側のレンズの有効径は、前記受光側のレンズの有効径よりも小さいと好適である。
 このように、前記投光側のレンズと前記受光側のレンズは、相互に独立した別体のレンズであるため、簡単な構成で測定光と反射光の光路を二つに分離することができる。
 また、前記投光側のレンズの有効径は、前記受光側のレンズの有効径よりも小さいため、膜厚測定時に基板が傾いていた場合でも、投光側のレンズよりも有効径の大きい受光側のレンズで、反射光を受光できる。
The light-projecting side lens and the light-receiving side lens are separate and independent lenses, and the effective diameter of the light-projecting side lens is preferably smaller than the effective diameter of the light-receiving side lens. is there.
As described above, since the lens on the light projecting side and the lens on the light receiving side are separate lenses independent from each other, the optical paths of the measurement light and the reflected light can be separated into two with a simple configuration. .
In addition, since the effective diameter of the lens on the light emitting side is smaller than the effective diameter of the lens on the light receiving side, even when the substrate is tilted when measuring the film thickness, the light receiving having a larger effective diameter than the lens on the light projecting side is received. The lens on the side can receive the reflected light.
 また、前記投光側のレンズの光軸と、前記受光側のレンズの光軸との角度は、3°以上10°以下であって、前記投光側のレンズから前記基板までの距離は、前記投光部から前記投光側のレンズまでの距離よりも長く、前記受光側のレンズから前記基板までの距離は、前記受光部から前記受光側のレンズまでの距離よりも長くてもよい。
 このように、投光側のレンズから基板までの距離及び受光側のレンズから基板までの距離を大きくとることにより、基板に入射する光をより平行光に近いものとして、膜厚測定の精度をより向上することが可能となる。
The angle between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens is 3 ° to 10 °, and the distance from the light-projecting lens to the substrate is: The distance from the light projecting unit to the lens on the light projecting side may be longer, and the distance from the lens on the light receiving side to the substrate may be longer than the distance from the light receiving unit to the lens on the light receiving side.
Thus, by increasing the distance from the lens on the light emitting side to the substrate and the distance from the lens on the light receiving side to the substrate, the light incident on the substrate is made closer to parallel light, and the film thickness measurement accuracy is improved. It becomes possible to improve further.
 前記投光側のレンズの光軸と前記受光側のレンズの光軸との交点を通り、前記投光側のレンズの光軸と前記受光側のレンズの光軸のなす角度を二等分する直線が、通過する位置に、前記受光側のレンズが配置されていてもよい。
 このように構成しているため、受光側のレンズと投光側のレンズを相互に近づけて配置可能となる。その結果、投光側のレンズと受光側のレンズとを、狭い領域にコンパクトに配置しつつ、より有効径の大きいレンズから構成することができ、高精度での膜厚測定が可能となって、精密光学部品用の光学薄膜の膜厚の測定に適した光学式膜厚計を実現できる。
The angle formed between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens passes through the intersection of the optical axis of the light-projecting lens and the optical axis of the light-receiving lens. The lens on the light receiving side may be arranged at a position where the straight line passes.
With this configuration, the light-receiving side lens and the light-projecting side lens can be arranged close to each other. As a result, the lens on the light-projecting side and the lens on the light-receiving side can be made up of lenses with a larger effective diameter while being compactly arranged in a narrow area, and the film thickness can be measured with high accuracy. An optical film thickness meter suitable for measuring the film thickness of an optical thin film for precision optical components can be realized.
 また、前記投光側のレンズ及び前記受光側のレンズと、測定対象の前記基板との間に、前記投光側のレンズ,前記受光側のレンズ及び前記基板に対向する集光レンズを備え、該集光レンズの有効径は、前記投光側のレンズの有効径と前記受光側のレンズの有効径の和より大きくてもよい。
 このように、投光側のレンズ及び受光側のレンズと、測定対象の基板との間に、投光側のレンズ,受光側のレンズ及び基板に対向する集光レンズを備えているため、基板に入射する光を、更に平行光に近いものとすることが可能となり、膜厚測定の精度をより向上することが可能となる。その結果、高精度での膜厚測定が可能となって、精密光学部品用の光学薄膜の膜厚の測定に適した光学式膜厚計を実現できる。
 また、このように更に集光レンズを設けることにより、測定光の入射角を小さく保って入射光の平行性を高めつつ、光学式膜厚計をコンパクトに構成可能となる。
In addition, between the lens on the light projecting side and the lens on the light receiving side, and the substrate to be measured, the lens on the light projecting side, the lens on the light receiving side, and a condensing lens facing the substrate, The effective diameter of the condensing lens may be larger than the sum of the effective diameter of the light-projecting side lens and the effective diameter of the light-receiving side lens.
As described above, since the light-projecting lens, the light-receiving lens, and the measurement target substrate are provided with the light-projecting lens, the light-receiving lens, and the condensing lens facing the substrate, the substrate It is possible to make the light incident on the light beam closer to parallel light, and to improve the accuracy of film thickness measurement. As a result, the film thickness can be measured with high accuracy, and an optical film thickness meter suitable for measuring the film thickness of the optical thin film for precision optical components can be realized.
Further, by further providing a condensing lens as described above, the optical film thickness meter can be configured compactly while keeping the incident angle of the measurement light small and improving the parallelism of the incident light.
 また、前記投光側のレンズと前記受光側のレンズは、一体に形成された単一の投受光側兼用レンズからなり、該投受光側兼用レンズと前記受光部との間に、前記測定光を透過すると同時に前記反射光を反射し、前記反射光の軸に対して傾斜したビーム分岐面を備えたビームスプリッタが配置されていてもよい。 In addition, the light projecting side lens and the light receiving side lens are formed as a single light projecting / receiving side combined lens, and the measurement light is interposed between the light projecting / receiving side lens and the light receiving unit. A beam splitter may be disposed that reflects the reflected light at the same time as passing through and has a beam branching surface inclined with respect to the axis of the reflected light.
 このように構成しているため、投光側のレンズと受光側のレンズとを別体として構成しなくても、投光された測定光の光路と受光される反射光の光路の少なくとも一部を分離することが可能となる。
 基板の取付誤差,基板ホルダの回転むら等により、回転している測定対象の基板が、測定光の軸に垂直な面に対して傾斜した場合であっても、基板で反射した反射光が投受光側兼用レンズの光路から外れ難くなり、反射光の光量を正確に検知できる。その結果、基板の取付誤差や基板ホルダの回転むら等の影響による光量ノイズを最小限に抑えて、回転する基板上に形成された光学式薄膜の膜厚を正確に安定して測定することが可能となる。ひいては、成膜後に膜厚の補正を繰り返す工程が不要となる。
Since it is configured in this manner, at least a part of the optical path of the projected measurement light and the reflected light to be received can be obtained without configuring the light-projecting lens and the light-receiving lens as separate bodies. Can be separated.
Even when the substrate to be measured is tilted with respect to a plane perpendicular to the axis of the measurement light due to substrate mounting error, rotation unevenness of the substrate holder, etc., the reflected light reflected by the substrate is projected. It becomes difficult to deviate from the optical path of the light-receiving side combined lens, and the amount of reflected light can be accurately detected. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
 また、前記投受光側兼用レンズと前記投光部との間に、前記投光部から出射される測定光の光量を制限するアパーチャが設けられ、前記投光側レンズユニットは、前記投受光側兼用レンズ,前記ビームスプリッタ及び前記アパーチャから構成されていてもよい。
 このように構成しているため、測定光のビームの有効面積を反射光のビームの有効面積よりも小さくすることが可能となり、基板の取付誤差,基板ホルダが回転式である場合の回転むら等により、回転している測定対象の基板が、測定光の軸に垂直な面に対して傾斜した場合であっても、反射光が投受光側兼用レンズの光路から外れ難くなり、反射光の光量を正確に検知できる。その結果、基板の取付誤差や基板ホルダの回転むら等の影響による光量ノイズを最小限に抑えて、回転する基板上に形成された光学式薄膜の膜厚を正確に安定して測定することが可能となる。ひいては、成膜後に膜厚の補正を繰り返す工程が不要となる。
An aperture for limiting the amount of measurement light emitted from the light projecting unit is provided between the light projecting and receiving side combined lens and the light projecting unit, and the light projecting side lens unit is provided on the light projecting and receiving side. You may comprise from a combined lens, the said beam splitter, and the said aperture.
With this configuration, it is possible to make the effective area of the measurement light beam smaller than the effective area of the reflected light beam, mounting errors of the substrate, uneven rotation when the substrate holder is a rotary type, etc. Therefore, even when the rotating substrate to be measured is tilted with respect to the plane perpendicular to the axis of the measurement light, the reflected light is difficult to deviate from the optical path of the lens for the light projecting and receiving side, and the amount of the reflected light Can be detected accurately. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
 また、前記レンズは、該レンズが出射する光のビームの収差を除去するよう複数枚のレンズを組み合わせた組レンズからなっていてもよい。
 このように構成しているため、投光側のレンズ,受光側のレンズ,投受光側兼用レンズ又は集光レンズから出射した光のビームに色収差や球面収差等の収差が生じることを防止でき、より正確な光学式薄膜の膜厚測定が可能となる。
The lens may be a combined lens in which a plurality of lenses are combined so as to remove aberration of a beam of light emitted from the lens.
Since it is configured in this way, it is possible to prevent aberrations such as chromatic aberration and spherical aberration from occurring in the light beam emitted from the light projecting side lens, the light receiving side lens, the light projecting / receiving side lens or the condenser lens, The film thickness of the optical thin film can be measured more accurately.
 前記課題は、請求項9に係る薄膜形成装置によれば、真空容器内に基板を支持して回転可能な基板ホルダと、該基板ホルダに保持された前記基板に対向して配設された薄膜形成手段と、前記基板が取付けられた前記基板ホルダが回転している状態で、前記基板に測定光を照射して前記基板上の光学薄膜の膜厚を測定する光学式膜厚計と、を備えた薄膜形成装置であって、前記光学式膜厚計は、請求項1乃至8いずれか記載の光学式膜厚計からなること、により解決される。 According to the thin film forming apparatus of the ninth aspect, the subject is a substrate holder that can rotate while supporting a substrate in a vacuum vessel, and a thin film disposed opposite to the substrate held by the substrate holder. Forming means, and an optical film thickness meter that measures the film thickness of the optical thin film on the substrate by irradiating the substrate with measurement light while the substrate holder to which the substrate is attached is rotating. A thin film forming apparatus provided, wherein the optical film thickness meter comprises the optical film thickness meter according to any one of claims 1 to 8.
 このように構成しているため、回転式の基板ホルダを備えた薄膜形成装置において、基板の取付誤差,基板ホルダの回転むら等による基板傾斜角度のばらつきの影響をほとんど受けずに、基板ホルダに伴って回転している基板上の光学薄膜の膜厚を正確に安定して測定できる。 With this configuration, in a thin film forming apparatus equipped with a rotary substrate holder, the substrate holder is hardly affected by variations in the substrate tilt angle due to substrate mounting errors, substrate holder rotation unevenness, etc. Accordingly, the thickness of the optical thin film on the rotating substrate can be measured accurately and stably.
 前記課題は、請求項10に係る膜厚測定方法によれば、回転式光学薄膜形成装置の基板ホルダの回転に応じて回転している基板に形成された光学薄膜の膜厚を測定する反射式の膜厚測定方法であって、測定光を投光部から、投光側のレンズを備えた投光側レンズユニットを介して、前記回転している基板に向けて投光し、前記基板で反射した前記測定光の反射光を、前記投光側レンズユニットの有効面積よりも大きい有効面積を備えた受光側のレンズを備え、前記投光側レンズユニットの光路とは、少なくとも一部が分離された光路を有し、前記投光側レンズユニットの有効面積よりも大きい有効面積を備えた受光側レンズユニットを介して、受光部に導光し、該受光部が受光した前記反射光の光量データを解析することにより、前記光学薄膜の膜厚を測定すること、により解決される。 According to the film thickness measuring method according to claim 10, the object is a reflective method for measuring the film thickness of an optical thin film formed on a rotating substrate according to the rotation of the substrate holder of the rotary optical thin film forming apparatus. The method of measuring a film thickness of the method, wherein the measurement light is projected from the light projecting unit toward the rotating substrate through a light projecting side lens unit including a lens on the light projecting side. The reflected light of the measurement light is provided with a light-receiving side lens having an effective area larger than the effective area of the light-projecting side lens unit, and at least a part is separated from the optical path of the light-projecting side lens unit The light quantity of the reflected light that is guided to the light receiving unit through the light receiving side lens unit having an effective area larger than the effective area of the light projecting side lens unit and received by the light receiving unit By analyzing the data, the optical Measuring the thickness of a film, it is solved by.
 このように構成しているため、基板の取付誤差,基板ホルダの回転むら等により、回転している測定対象の基板が、測定光の軸に垂直な面に対して傾斜した場合であっても、基板で反射した反射光が受光側のレンズの光路から外れ難くなり、反射光の光量を正確に検知できる。その結果、基板の取付誤差や基板ホルダの回転むら等の影響による光量ノイズを最小限に抑えて、回転する基板上に形成された光学式薄膜の膜厚を正確に安定して測定することが可能となる。ひいては、成膜後に膜厚の補正を繰り返す工程が不要となる。 Even if the substrate to be measured is tilted with respect to the plane perpendicular to the axis of the measurement light due to the mounting error of the substrate, the rotation unevenness of the substrate holder, etc. The reflected light reflected by the substrate is unlikely to deviate from the optical path of the lens on the light receiving side, and the amount of reflected light can be accurately detected. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
 また、回転中の基板上の薄膜に適用可能であるため、ドラム型,ドーム型の回転式の基板ホルダ等を備えた薄膜形成装置に適用可能となり、大量の基板に短時間で薄膜を形成する量産型の薄膜形成装置においても、光学式薄膜の膜厚を正確に安定して測定することが可能となる。 In addition, since it can be applied to a thin film on a rotating substrate, it can be applied to a thin film forming apparatus equipped with a drum-type or dome-type rotary substrate holder, and forms a thin film on a large number of substrates in a short time. Even in a mass production type thin film forming apparatus, the film thickness of an optical thin film can be measured accurately and stably.
 本発明によれば、投光側レンズユニットの有効面積は、受光側レンズユニットの有効面積よりも小さいため、基板の取付誤差,基板ホルダの回転むら等により、回転している測定対象の基板が、測定光の軸に垂直な面に対して傾斜した場合であっても、基板で反射した反射光が受光側のレンズの光路から外れ難くなり、反射光の光量を正確に検知できる。その結果、基板の取付誤差や基板ホルダの回転むら等の影響による光量ノイズを最小限に抑えて、回転する基板上に形成された光学式薄膜の膜厚を正確に安定して測定することが可能となる。ひいては、成膜後に膜厚の補正を繰り返す工程が不要となる。 According to the present invention, since the effective area of the light-projecting side lens unit is smaller than the effective area of the light-receiving side lens unit, the rotating measurement target substrate is caused by the substrate mounting error, the rotation unevenness of the substrate holder, and the like. Even when tilted with respect to a plane perpendicular to the axis of the measurement light, the reflected light reflected by the substrate is unlikely to deviate from the optical path of the lens on the light receiving side, and the amount of reflected light can be detected accurately. As a result, it is possible to accurately and stably measure the film thickness of the optical thin film formed on the rotating substrate while minimizing the light intensity noise due to the effects of substrate mounting errors and uneven rotation of the substrate holder. It becomes possible. As a result, the process of repeating the correction of the film thickness after the film formation becomes unnecessary.
 また、回転中の基板上の薄膜に適用可能であるため、ドラム型,ドーム型の回転式の基板ホルダ等を備えた薄膜形成装置に適用可能となり、大量の基板に短時間で薄膜を形成する量産型の薄膜形成装置に適した光学式膜厚計を提供可能となる。
 更に、測定光を、回転している基板に向けて投光する投光部を備えるため、回転式の光学薄膜形成装置において、モニタ用基板を別途設けずサンプル基板上の薄膜を直接膜厚測定する直視型の光学式膜厚計を提供できる。従って、量産型の回転式の光学薄膜形成装置を用いた場合において、水晶振動子膜厚計や間接型光学式膜厚計とは異なり、精密光学部品等で要望されるような、高い精度での膜厚制御が可能となる。
In addition, since it can be applied to a thin film on a rotating substrate, it can be applied to a thin film forming apparatus equipped with a drum-type or dome-type rotary substrate holder, and forms a thin film on a large number of substrates in a short time. It is possible to provide an optical film thickness meter suitable for a mass production type thin film forming apparatus.
In addition, since it has a light projecting unit that projects measurement light toward the rotating substrate, the film thickness of the thin film on the sample substrate is directly measured without providing a separate monitor substrate in a rotating optical thin film forming apparatus. A direct-view optical film thickness meter can be provided. Therefore, when a mass-produced rotary optical thin film forming device is used, unlike a quartz oscillator thickness meter or an indirect type optical film thickness meter, it has a high accuracy as required for precision optical components. The film thickness can be controlled.
本発明の一実施形態に係る薄膜形成装置を上面から見た部分断面説明図である。It is the fragmentary sectional view which looked at the thin film forming apparatus concerning one embodiment of the present invention from the upper surface. 本発明の一実施形態に係る光学式膜厚計の構成を示す機能ブロック図である。It is a functional block diagram which shows the structure of the optical film thickness meter which concerns on one Embodiment of this invention. 本発明の一実施形態に係る光学式膜厚計のレンズ配置を示す概略説明図である。It is a schematic explanatory drawing which shows lens arrangement | positioning of the optical film thickness meter which concerns on one Embodiment of this invention. 本発明の他の実施形態に係る光学式膜厚計のレンズユニット配置を示す概略説明図である。It is a schematic explanatory drawing which shows the lens unit arrangement | positioning of the optical film thickness meter which concerns on other embodiment of this invention. 本発明の更に他の実施形態に係る光学式膜厚計のレンズ配置を示す概略説明図である。It is a schematic explanatory drawing which shows the lens arrangement | positioning of the optical film thickness meter which concerns on other embodiment of this invention. 図5の光学式膜厚計のレンズ配置の斜視説明図である。FIG. 6 is a perspective explanatory view of lens arrangement of the optical film thickness meter of FIG. 5. 実施例1,2,対比例1に係るレンズ配置を備えた光学式膜厚計を用いて、傾斜角度が0.0~2.0°である基板に測定光を出射した場合の、基板からの反射光の相対的反射率を算出した結果を示すグラフである。Examples 1 and 2, using an optical film thickness meter having a lens arrangement according to Comparative Example 1, when measuring light is emitted from a substrate having an inclination angle of 0.0 to 2.0 ° from the substrate It is a graph which shows the result of having calculated the relative reflectance of the reflected light. 図3のレンズ配置を備えた膜厚計により膜厚を制御して、基板S上に多層AR膜を形成する実験を複数回繰返した場合における薄膜形成中の光量変化のばらつきについて検討した結果を示すグラフである。FIG. 3 shows the result of examining the variation in light quantity during thin film formation when the experiment of forming a multilayer AR film on the substrate S is repeated a plurality of times by controlling the film thickness with a film thickness meter having the lens arrangement of FIG. It is a graph to show. 図3のレンズ配置を備えた膜厚計により膜厚を制御して、基板S上に多層AR膜を形成する実験を複数回繰返した場合における多層AR膜の分光特性のばらつきについて検討した結果を示すグラフである。FIG. 3 shows the result of examining the dispersion of the spectral characteristics of the multilayer AR film when the experiment of forming the multilayer AR film on the substrate S is repeated a plurality of times by controlling the film thickness with the film thickness meter having the lens arrangement of FIG. It is a graph to show.
 以下、本発明の実施形態について、図を参照して説明する。なお、以下に説明する部材、配置等は、本発明を限定するものではなく、本発明の趣旨に沿って各種改変することができることは勿論である。
 本実施形態の光学式膜厚計としての膜厚計40が用いられる薄膜形成装置は、基板を保持する基板ホルダが回転する回転式の基板ホルダを備えてなる。
 例えば、ドーム型の基板ホルダ、回転ドラムを備えたカルーセル式の基板ホルダ等のように、基板ホルダの回転軸に対して、基板ホルダの基板保持面及び基板保持面に保持される基板の法線が傾斜するものに、特に好適に用いられる。
 一般に、ドーム状又はドラム型等の基板ホルダでは、基板ホルダの回転に応じて、基板へ出射される測定光と基板表面との間の角度が変化するため、回転むら等の影響による光量ノイズにより、膜厚測定精度を高精度に保つことは難しい。それに対し、本実施形態の光学式膜厚計では、基板傾斜角度のばらつきの影響をほとんど受けずに、基板ホルダに伴って回転している基板上の光学薄膜の膜厚を正確に安定して測定できる。
 但し、基板ホルダは、球面状に形成されたドーム式のものや、円筒形のものに限らず、多角錐形や多角柱形のもの等を含む。
 また、本発明の光学式膜厚計は、基板が公転する回転式の基板ホルダを備えた薄膜形成装置に限らず、基板が直線方向に移動するインライン式の薄膜形成装置等にも、用いることができる。
Hereinafter, embodiments of the present invention will be described with reference to the drawings. It should be noted that members, arrangements, and the like described below do not limit the present invention, and it goes without saying that various modifications can be made in accordance with the spirit of the present invention.
A thin film forming apparatus in which a film thickness meter 40 as an optical film thickness meter of the present embodiment is used includes a rotary substrate holder that rotates a substrate holder that holds a substrate.
For example, the substrate holding surface of the substrate holder and the normal of the substrate held on the substrate holding surface with respect to the rotation axis of the substrate holder, such as a dome-shaped substrate holder, a carousel type substrate holder with a rotating drum, etc. It is particularly preferably used for those in which the slope is inclined.
In general, in a dome-shaped or drum-type substrate holder, the angle between the measurement light emitted to the substrate and the substrate surface changes according to the rotation of the substrate holder. It is difficult to keep the film thickness measurement accuracy high. On the other hand, in the optical film thickness meter of the present embodiment, the film thickness of the optical thin film on the substrate rotating with the substrate holder can be accurately and stably hardly affected by variations in the substrate tilt angle. It can be measured.
However, the substrate holder is not limited to a dome type formed in a spherical shape or a cylindrical shape, but includes a polygonal pyramid shape or a polygonal column shape.
The optical film thickness meter according to the present invention is not limited to a thin film forming apparatus having a rotary substrate holder that revolves around the substrate, but also used in an in-line thin film forming apparatus in which the substrate moves in a linear direction. Can do.
(スパッタ装置1)
 本実施形態の膜厚計40を、カルーセル式のスパッタ装置1において用いた例について説明する。なお、スパッタ装置に限らず、真空蒸着装置,CVD装置等、他の薄膜形成装置に用いてもよいことは当然である。
 本実施形態の膜厚計40が設置されるスパッタ装置1を、図1に示す。
 図1のスパッタ装置1は、真空容器11と、回転ドラム12と、一対のスパッタ源20A,20Bと、プラズマ源30と、を主要な構成要素としている。
 真空容器11は、スパッタリングにおいて用いられる公知の矩形の真空容器からなり、扉によって薄膜形成室11Aとロードロック室11Bに分けられている。
 回転ドラム12は、基板Sを保持する基板ホルダであって、図1に示すように、鉛直の回転軸Zを中心とした略円筒形からなり、外周面に基板Sを保持可能に構成されている。なお、回転ドラム12は、回転軸Zを軸として回転可能であればよく、多角柱や円錐形の中空体から構成してもよい。
(Sputtering device 1)
An example in which the film thickness meter 40 of this embodiment is used in the carousel type sputtering apparatus 1 will be described. Of course, the present invention is not limited to the sputtering apparatus, and may be used for other thin film forming apparatuses such as a vacuum deposition apparatus and a CVD apparatus.
A sputtering apparatus 1 in which the film thickness meter 40 of the present embodiment is installed is shown in FIG.
1 includes a vacuum vessel 11, a rotating drum 12, a pair of sputtering sources 20A and 20B, and a plasma source 30 as main components.
The vacuum vessel 11 is a known rectangular vacuum vessel used in sputtering, and is divided into a thin film forming chamber 11A and a load lock chamber 11B by a door.
The rotating drum 12 is a substrate holder that holds the substrate S, and has a substantially cylindrical shape with a vertical rotation axis Z as the center, as shown in FIG. 1, and is configured to hold the substrate S on the outer peripheral surface. Yes. The rotating drum 12 only needs to be rotatable about the rotation axis Z, and may be formed of a polygonal column or a conical hollow body.
 回転ドラム12の下端には、回転ドラム12内の中空の空間を閉塞するように、不図示の円板状のフレームが固定され、このフレームの中心に、不図示のモータの回転軸が連結されている。不図示のモータを駆動することにより、回転ドラム12を回転駆動可能に構成されている。
 また、回転ドラム12の上方端部には、図2に示すように、タイミング検出用反射板15が取付けられ、タイミングセンサー16によってその通過が検出可能に構成されている。
 スパッタ源20A,20Bは、基板S上に金属又はその不完全化合物を成膜する手段であって、公知のデュアルカソードタイプのマグネトロンスパッタ源からなり、薄膜形成室11Aの側壁に、それぞれ一対のターゲット22A,22Bが基板Sと対向するように設けられている。
 スパッタ源20A,20Bは、図1に示すように、それぞれ一対のターゲット22A,22Bを保持するそれぞれ一対のマグネトロンスパッタ電極21A,21Bと、マグネトロンスパッタ電極21A,21Bに電力を供給する交流電源24A,24Bと、電力制御手段としてのトランス23A,23Bにより構成される。
A disc-shaped frame (not shown) is fixed to the lower end of the rotating drum 12 so as to close a hollow space in the rotating drum 12, and a rotating shaft of a motor (not shown) is connected to the center of the frame. ing. The rotary drum 12 can be driven to rotate by driving a motor (not shown).
Further, as shown in FIG. 2, a timing detection reflecting plate 15 is attached to the upper end portion of the rotating drum 12, and the passage thereof can be detected by the timing sensor 16.
The sputtering sources 20A and 20B are means for depositing a metal or an incomplete compound thereof on the substrate S. The sputtering sources 20A and 20B are each a known dual cathode type magnetron sputtering source, and a pair of targets are formed on the side walls of the thin film forming chamber 11A. 22A and 22B are provided to face the substrate S.
As shown in FIG. 1, the sputtering sources 20A and 20B include a pair of magnetron sputtering electrodes 21A and 21B that hold a pair of targets 22A and 22B, respectively, and an AC power source 24A that supplies power to the magnetron sputtering electrodes 21A and 21B. 24B and transformers 23A and 23B as power control means.
 図1に示すように、スパッタ源20A,20Bの前面には、それぞれ成膜プロセス領域26A,26Bが形成されている。成膜プロセス領域26A,26Bは、真空容器11の内壁面から回転ドラム12に向けて突出する仕切壁13により四方が取り囲まれており、それぞれが真空容器11の内部で独立した空間を確保できるように区画されている。
 成膜プロセス領域26A,26Bには、配管が設けられ、ガスボンベ25A,25Bに貯蔵されたスパッタガスを供給可能に構成されている。
As shown in FIG. 1, film formation process regions 26A and 26B are formed on the front surfaces of the sputtering sources 20A and 20B, respectively. The film forming process regions 26A and 26B are surrounded on four sides by a partition wall 13 protruding from the inner wall surface of the vacuum vessel 11 toward the rotary drum 12, so that each can secure an independent space inside the vacuum vessel 11. It is divided into.
The film forming process regions 26A and 26B are provided with piping so that the sputtering gas stored in the gas cylinders 25A and 25B can be supplied.
 プラズマ源30は、スパッタ源20A,20Bによって基板S上に成膜された薄膜を反応性ガスにより反応させて化合物薄膜とする手段であって、公知のプラズマ源からなり、薄膜形成室11Aの側壁に設けられている。
 プラズマ源30は、真空容器11の壁面に形成された開口を塞ぐように固定されたケース体31と、このケース体31に固定された誘電体板32とを有し、このケース体31と誘電体板32に囲まれる領域が、真空ポンプで真空引き可能に構成されたアンテナ収容室を構成している。アンテナ収容室内には、不図示のアンテナが配置され、このアンテナは、マッチングボックス33を介して高周波電源34に接続され、高周波電源34の電力の供給を受けて、反応プロセス領域36に誘導電界を発生させてプラズマを発生させる。
 図1に示すように、プラズマ源30の前面には、それぞれ反応プロセス領域36が形成されている。反応プロセス領域36は、真空容器11の内壁面から回転ドラム12に向けて突出する仕切壁14により四方が取り囲まれており、それぞれが真空容器11の内部で独立した空間を確保できるように区画されている。
 反応プロセス領域36には、配管が設けられ、ガスボンベ35に貯蔵された反応性ガスを供給可能に構成されている。
The plasma source 30 is a means for reacting a thin film formed on the substrate S by the sputtering sources 20A and 20B with a reactive gas to form a compound thin film, which is a known plasma source and is a side wall of the thin film forming chamber 11A. Is provided.
The plasma source 30 includes a case body 31 fixed so as to close an opening formed in the wall surface of the vacuum vessel 11, and a dielectric plate 32 fixed to the case body 31. An area surrounded by the body plate 32 constitutes an antenna housing chamber configured to be evacuated by a vacuum pump. An antenna (not shown) is disposed in the antenna housing chamber, and this antenna is connected to the high frequency power source 34 via the matching box 33 and receives an electric power from the high frequency power source 34 to generate an induction electric field in the reaction process region 36. To generate plasma.
As shown in FIG. 1, reaction process regions 36 are respectively formed on the front surface of the plasma source 30. The reaction process region 36 is surrounded on all sides by a partition wall 14 projecting from the inner wall surface of the vacuum vessel 11 toward the rotary drum 12, and each is partitioned so as to ensure an independent space inside the vacuum vessel 11. ing.
The reaction process region 36 is provided with a pipe so that the reactive gas stored in the gas cylinder 35 can be supplied.
(膜厚計40)
 スパッタ装置1には、図1に示すように、本実施形態の膜厚計40が取付けられている。
 図2,図3に示すように、膜厚計40は、光源41と、光ファイバ42と、投光用測光プローブ43と、投光側レンズ51,受光側レンズ52と、受光用測光プローブ44と、光ファイバ45と、光学検出装置46と、光学検出装置47で検出された受光信号を光量信号に変換する積分アンプ48と、積分アンプ48から光量信号を受信して膜厚制御等を行う制御装置47を主要な構成要素として備えている。
 光源41は、不図示の電源から供給される電力によって白色光を発する装置であり、本実施形態では公知のハロゲンランプを使用している。
(Film thickness meter 40)
As shown in FIG. 1, the film thickness meter 40 of this embodiment is attached to the sputtering apparatus 1.
As shown in FIGS. 2 and 3, the film thickness meter 40 includes a light source 41, an optical fiber 42, a light projecting photometric probe 43, a light projecting side lens 51, a light receiving side lens 52, and a light receiving photometric probe 44. An optical fiber 45, an optical detection device 46, an integration amplifier 48 for converting the received light signal detected by the optical detection device 47 into a light amount signal, and receiving the light amount signal from the integration amplifier 48 to perform film thickness control and the like. A control device 47 is provided as a main component.
The light source 41 is a device that emits white light by power supplied from a power source (not shown), and a known halogen lamp is used in this embodiment.
 光源41には、公知の光ファイバ42の一端が接続され、光ファイバ42の他端には投光用測光プローブ43が設けられている。投光用測光プローブ43は、円筒状部材の内部に光ファイバ42の端部が収納された構造をしており、回転ドラム12の側面に対して略垂直となるように、真空容器11の側壁の孔に嵌めこまれた測光用窓17に端部を対向させた状態で、真空容器11の側壁の外側に配設されている。 One end of a known optical fiber 42 is connected to the light source 41, and a light projecting photometric probe 43 is provided at the other end of the optical fiber 42. The light projecting photometric probe 43 has a structure in which the end of the optical fiber 42 is housed inside a cylindrical member, and the side wall of the vacuum container 11 is substantially perpendicular to the side surface of the rotary drum 12. The photometering window 17 fitted in this hole is disposed outside the side wall of the vacuum vessel 11 with its end facing the photometric window 17.
 回転ドラム12と投光用測光プローブ43との間には、投光側レンズ51が配置されている。投光側レンズ51は、径10~20mmで、光学膜厚計に用いられる公知のアクロマートレンズからなる。投光側レンズ51は、投光用測光プローブ43から照射され、広角に広がる光を収束して基板Sに照射する。
 投光用測光プローブ43は、投光側レンズ51の焦点近傍に配置されている。
 また、回転ドラム12と受光用測光プローブ44との間には、受光側レンズ52が配置されている。受光側レンズ52は、径15~30mmで、一般的な光学膜厚計に用いられる公知のアクロマートレンズからなる。受光側レンズ52は、広角に広がる基板Sからの反射光を収束して受光用測光プローブ44に照射する。
 アクロマートレンズとは、2波長で色収差が補正されている色消しレンズをいい、2枚以上のレンズを組み合わせて実現される。アクロマートレンズは、特許請求の範囲の組レンズに該当する。
A light projecting side lens 51 is disposed between the rotary drum 12 and the light projecting photometric probe 43. The light projecting side lens 51 has a diameter of 10 to 20 mm and is a known achromatic lens used for an optical film thickness meter. The light projecting side lens 51 is irradiated from the light projecting photometric probe 43 and converges the light spreading in a wide angle to irradiate the substrate S.
The light projecting photometric probe 43 is disposed in the vicinity of the focal point of the light projecting side lens 51.
A light receiving side lens 52 is disposed between the rotary drum 12 and the light receiving photometric probe 44. The light-receiving side lens 52 has a diameter of 15 to 30 mm and is made of a known achromatic lens used in a general optical film thickness meter. The light-receiving side lens 52 converges the reflected light from the substrate S spreading over a wide angle and irradiates the photometric probe 44 for light reception.
An achromatic lens is an achromatic lens in which chromatic aberration is corrected at two wavelengths, and is realized by combining two or more lenses. The achromatic lens corresponds to the grouped lens in the claims.
 投光側レンズ51及び受光側レンズ52は、図2,図3に示すように、測定光及び反射光の光路上に、並列に配置される。
 投光側レンズ51の中心51C及び受光側レンズ52の中心52Cは、基板Sからの距離が略同じである。
 投光側レンズ51の光軸51aと、受光側レンズ52の光軸52aとの角度αは、3~10°である。
The light projecting side lens 51 and the light receiving side lens 52 are arranged in parallel on the optical paths of the measurement light and the reflected light, as shown in FIGS.
The center 51C of the light projecting side lens 51 and the center 52C of the light receiving side lens 52 have substantially the same distance from the substrate S.
An angle α between the optical axis 51a of the light projecting side lens 51 and the optical axis 52a of the light receiving side lens 52 is 3 to 10 °.
 光軸51aと光軸52aとの角度を二等分する二等分線Bは、基板Sを通ると共に、隣り合って設けられた受光側レンズ52及び投光側レンズ51のうち、大径の受光側レンズ52を貫通している。
 つまり、大径の受光側レンズ52は、二等分線Bよりも投光側レンズ51側へ張り出して配置されている。従って、投光側レンズ51と受光側レンズ52を、それぞれの光軸51a,52a間の角度が3~10°という小さい角度になるようにして、膜厚計40をコンパクトに構成できると同時に、投光側レンズ51及び受光側レンズ52の有効径を十分大きく確保することができ、より高精度の膜厚計とすることができる。また、受光側レンズ52の有効径を十分大きくすることができ、基板の角度が、投光側レンズ51の光軸に対して傾斜した場合でも、受光レンズ52から外れ難くすることが可能となる。
 また、このとき、投光側レンズ51及び受光側レンズ52と基板Sとの間の距離WDは、75~350mmである。投光側レンズ51と投光用測光プローブ43及び受光側レンズ52と受光用測光プローブ44との間の距離S1は、35~90mmであって、WDは、S1よりも大きくなっている。
 このようにすることにより、基板に入射する投光が、より平行光に近くなり、より高精度の膜厚測定が可能となる。
A bisector B that bisects the angle between the optical axis 51a and the optical axis 52a passes through the substrate S and has a larger diameter among the light-receiving side lens 52 and the light-projecting side lens 51 provided adjacent to each other. It penetrates the light receiving side lens 52.
That is, the large-diameter light receiving side lens 52 is arranged so as to protrude from the bisector B toward the light projecting side lens 51. Accordingly, the film thickness meter 40 can be configured compactly by making the light-projecting lens 51 and the light-receiving lens 52 the angle between the optical axes 51a and 52a as small as 3 to 10 °. The effective diameters of the light projecting side lens 51 and the light receiving side lens 52 can be secured sufficiently large, and a more accurate film thickness meter can be obtained. In addition, the effective diameter of the light receiving side lens 52 can be made sufficiently large, and even when the angle of the substrate is inclined with respect to the optical axis of the light projecting side lens 51, it is possible to make it difficult to come off from the light receiving lens 52. .
At this time, the distance WD between the light projecting side lens 51 and the light receiving side lens 52 and the substrate S is 75 to 350 mm. The distance S1 between the light projecting side lens 51 and the light projecting photometric probe 43 and between the light receiving side lens 52 and the light receiving photometric probe 44 is 35 to 90 mm, and WD is larger than S1.
By doing so, the light incident on the substrate becomes closer to parallel light, and the film thickness can be measured with higher accuracy.
 受光用測光プローブ44は、円筒形部材からなり、受光側レンズ52から導光された反射光を受光する。
 受光用測光プローブ44は、受光側レンズ52の焦点近傍に配置されている。
 本実施形態では、投光側レンズ51と受光側レンズ52の焦点距離がほぼ同じであるため、受光用測光プローブ44は、投光用測光プローブ43と並ぶようにして、回転ドラム12の側面に対向するように、真空容器11の側壁の孔に嵌めこまれた測光用窓17に端部を対向させた状態で、真空容器11の側壁の外側に配設されている。
 図2に示すように、光ファイバ45は、一方の先端部が受光用測光プローブ44の一端に収納され、他方の先端部は光学検出装置46に接続している。
 光学検出装置46は、細いスリットを備えた平板状部材からなり反射光を偏向させる公知のコリメータと、コリメータから入射した光のうち所定の波長の光のみを出射する公知のグレイティングと、グレイティングから出射した光を検知するフォトダイオードとを備えた公知の光学検出装置である。
 光学検出装置46は、積分アンプ47を介して制御装置48に連結され、光学検出装置46で検出された受光信号に基づき、制御装置48で膜厚制御可能に構成されている。
The light-receiving photometric probe 44 is made of a cylindrical member and receives the reflected light guided from the light-receiving side lens 52.
The light-receiving photometric probe 44 is disposed in the vicinity of the focal point of the light-receiving side lens 52.
In the present embodiment, since the focal lengths of the light projecting side lens 51 and the light receiving side lens 52 are substantially the same, the light receiving photometric probe 44 is aligned with the light projecting photometric probe 43 on the side surface of the rotary drum 12. It is disposed outside the side wall of the vacuum vessel 11 with its end facing the photometric window 17 fitted in the hole on the side wall of the vacuum vessel 11 so as to face each other.
As shown in FIG. 2, one end of the optical fiber 45 is housed in one end of the light-receiving photometric probe 44, and the other tip is connected to the optical detection device 46.
The optical detection device 46 is a known collimator made of a flat plate member having a thin slit, deflects reflected light, known grating for emitting only light of a predetermined wavelength out of light incident from the collimator, and grating It is a well-known optical detection device provided with a photodiode for detecting light emitted from.
The optical detection device 46 is connected to a control device 48 via an integration amplifier 47, and is configured such that the control device 48 can control the film thickness based on a light reception signal detected by the optical detection device 46.
 次に、本実施形態の膜厚計40の動作について説明する。
 まず、スパッタ源20A,20Bそれぞれにおいて、一対のターゲット22A,22Bを一対のマグネトロンスパッタ電極21A,21Bに保持させる。真空ポンプを作動させて排気を行い、薄膜形成室11Aを10-2Pa~10Pa程度の真空状態にする。
Next, operation | movement of the film thickness meter 40 of this embodiment is demonstrated.
First, in each of the sputtering sources 20A and 20B, the pair of targets 22A and 22B are held by the pair of magnetron sputtering electrodes 21A and 21B. The thin film forming chamber 11A is brought into a vacuum state of about 10 −2 Pa to 10 Pa by evacuating by operating the vacuum pump.
 その後、回転ドラム12をロードロック室11Bの位置でロックした状態で、回転ドラム12に基板Sを取付ける。続いて、真空ポンプを作動させてロードロック室11Bを排気し、10-2Pa~10Pa程度の真空状態にする。次いで、薄膜形成室11Aとロードロック室11Bの間の扉を開いて回転ドラム12を薄膜形成室11Aへ移動させ、扉を再び閉じる。真空容器11の内部,アンテナ収容室の内部を所定の圧力に減圧する。
 その後、真空容器11の内部,アンテナ収容室の内部の圧力が安定した後に、成膜プロセス領域26Aの圧力を1.0×10-1Pa~1.3Paに調整する。
Thereafter, the substrate S is attached to the rotary drum 12 with the rotary drum 12 locked at the position of the load lock chamber 11B. Next, the load pump chamber 11B is evacuated by operating the vacuum pump, and a vacuum state of about 10 −2 Pa to 10 Pa is set. Next, the door between the thin film forming chamber 11A and the load lock chamber 11B is opened, the rotating drum 12 is moved to the thin film forming chamber 11A, and the door is closed again. The inside of the vacuum vessel 11 and the inside of the antenna housing chamber are depressurized to a predetermined pressure.
Thereafter, after the pressure inside the vacuum vessel 11 and the inside of the antenna housing chamber is stabilized, the pressure in the film forming process region 26A is adjusted to 1.0 × 10 −1 Pa to 1.3 Pa.
 次に、不図示のモータを作動させて回転ドラム12を回転させる。
 回転ドラム12の回転速度がほぼ一定になった段階で、光源41の図示しないスイッチをオペレータがオンにして、光源41からの連続光の投光が開始される。光源41からの光は光ファイバ42内を伝送して、投光用測光プローブ43端部より基板Sの表面に照射される。
Next, the rotating drum 12 is rotated by operating a motor (not shown).
When the rotational speed of the rotary drum 12 becomes substantially constant, the operator turns on a switch (not shown) of the light source 41 and starts projecting continuous light from the light source 41. Light from the light source 41 is transmitted through the optical fiber 42 and irradiated onto the surface of the substrate S from the end of the light projecting photometric probe 43.
 次いで、成膜プロセス領域26Aおよび反応プロセス領域36での薄膜形成処理を開始する。成膜プロセス領域26Aでは、一対のターゲット22Aに対してスパッタが行われて、基板Sの表面に金属や金属の不完全反応物からなる薄膜が形成される。続く反応プロセス領域36では、成膜プロセス領域26Aで形成された薄膜に反応性ガスを導入することにより、金属の完全反応物を主とした中間薄膜が形成される。 Next, thin film formation processing is started in the film forming process area 26A and the reaction process area 36. In the film forming process region 26A, sputtering is performed on the pair of targets 22A, and a thin film made of metal or an incomplete reaction product of metal is formed on the surface of the substrate S. In the subsequent reaction process region 36, an intermediate thin film mainly composed of a complete reaction product of metal is formed by introducing a reactive gas into the thin film formed in the film formation process region 26A.
 タイミングセンサー16で、回転ドラム12の現在の番地を検出し、制御装置48が、光量データのサンプリングを開始する番地であるかを判定する。現在の番地が光量のサンプリングを開始する番地である場合は、制御装置48から光学検出装置46にサンプリング開始信号が送信されて、光量データのサンプリングを開始する。 The current address of the rotary drum 12 is detected by the timing sensor 16, and the control device 48 determines whether it is an address at which sampling of light amount data is started. When the current address is an address at which light quantity sampling is started, a sampling start signal is transmitted from the control device 48 to the optical detection device 46, and light quantity data sampling is started.
 光源41からは、測定光が連続して回転ドラム12の表面及び回転ドラム12に保持された基板Sに照射されている状態にあり、光量データのサンプリングを開始する番地に到達したときには、投光用測光プローブ43から投光され投光側レンズ51で収束された測定光は、基板Sを照射している。
 この測定光は、基板Sで反射し、反射光が受光側レンズ52で受光され収束されて、受光用測光プローブ44から光ファイバ45を介して光学検出装置46で受光される。光学検出装置46では、受光された反射光の強度を検出し、受光信号を積分アンプ47に送信する。積分アンプ47は、この受光信号を光量信号に変換し、制御装置48に送信する。
When the measurement light is continuously irradiated from the light source 41 to the surface of the rotary drum 12 and the substrate S held by the rotary drum 12, the light is projected when reaching the address at which sampling of the light amount data is started. The measurement light projected from the light metering probe 43 and converged by the light projecting side lens 51 irradiates the substrate S.
The measurement light is reflected by the substrate S, and the reflected light is received and converged by the light receiving side lens 52 and received by the optical detection device 46 from the light receiving photometric probe 44 through the optical fiber 45. The optical detection device 46 detects the intensity of the received reflected light and transmits a received light signal to the integrating amplifier 47. The integrating amplifier 47 converts this received light signal into a light amount signal and transmits it to the control device 48.
 次いで、制御装置48が、タイミングセンサー16で検出した現在の番地が、光量データのサンプリングを終了する番地であるかを判定する。現在の番地が光量データのサンプリングを終了する番地である場合は、光量データのサンプリングを終了する。
 その後、制御装置48は、光量データのサンプリングを開始する番地から終了する番地までの間に受光した光の強度を積算して光量を算出し、この光量に基づいて、公知の方法により、膜厚演算を行う。
 光量データのサンプリング及びこの光量に基づく膜厚演算は、得られた膜厚データが、最初に設定された所望の膜厚値に一致するまで行われる。
Next, the control device 48 determines whether or not the current address detected by the timing sensor 16 is an address at which sampling of the light amount data is finished. If the current address is an address at which the sampling of the light amount data is finished, the sampling of the light amount data is ended.
Thereafter, the control device 48 calculates the light amount by integrating the intensity of the light received between the address where the sampling of the light amount data is started and the address where the sampling is finished, and based on this light amount, the film thickness is determined by a known method. Perform the operation.
The sampling of the light amount data and the film thickness calculation based on the light amount are performed until the obtained film thickness data matches the desired film thickness value set first.
 膜厚データが、所望の膜厚値に一致すると、制御装置48の指令により、成膜プロセス領域26Aおよび反応プロセス領域36での薄膜形成処理を終了する。
 次いで、成膜プロセス領域26Bおよび反応プロセス領域36での薄膜形成処理を開始する。この処理では、成膜プロセス領域26Aおよび反応プロセス領域36での薄膜形成処理と、光量データのサンプリング,膜厚演算と同様の処理が行われ、膜厚データが、所望の膜厚値に一致すると、制御装置48の指令により、成膜プロセス領域26Bおよび反応プロセス領域36での薄膜形成処理を終了する。
When the film thickness data matches the desired film thickness value, the thin film forming process in the film forming process region 26A and the reaction process region 36 is terminated by a command from the control device 48.
Next, thin film formation processing is started in the film formation process region 26B and the reaction process region 36. In this process, the thin film forming process in the film forming process area 26A and the reaction process area 36, the same process as the sampling of the light amount data, and the film thickness calculation are performed, and when the film thickness data matches the desired film thickness value. Then, the thin film forming process in the film forming process region 26B and the reaction process region 36 is terminated by a command from the control device 48.
 本実施形態では、投光側レンズ51と受光側レンズ52とを、別体のレンズから構成したが、投光側レンズ51と受光側レンズ52の代わりに、図4のように、投光側レンズと受光側レンズとを兼用し、基板Sへ照射される測定光と基板Sからの反射光の双方を導光する一体の投受光側兼用レンズ53から構成してもよい。このとき、投受光側兼用レンズ53の基板S逆側に、測定光を透過し、反射光を反射するビームスプリッタ54を設けることにより、測定光と反射光とを分離可能する。
 投受光側兼用レンズ53は、径が15~40mmで、一般的な光学膜厚計に用いられる公知のアクロマートレンズからなる。アクロマートレンズは、特許請求の範囲の組レンズに該当する。
 図4のビームスプリッタ54は、公知のプレートビームスプリッタから構成しているが、基板S逆側から入射する測定光を透過し、基板S側から入射する反射光を反射するビーム分岐面を、測定光の光軸及び反射光の光軸に対して45°の角度で備えていればよく、キューブビームスプリッタ,ペルクルビームスプリッタから構成してもよい。
In the present embodiment, the light projecting side lens 51 and the light receiving side lens 52 are configured as separate lenses, but instead of the light projecting side lens 51 and the light receiving side lens 52, as shown in FIG. The lens and the light-receiving side lens may be used together, and the lens may be configured as an integral light-receiving / light-receiving side lens 53 that guides both the measurement light applied to the substrate S and the reflected light from the substrate S. At this time, the measurement light and the reflected light can be separated by providing a beam splitter 54 that transmits the measurement light and reflects the reflected light on the opposite side of the substrate S of the light emitting / receiving lens 53.
The light emitting / receiving lens 53 has a diameter of 15 to 40 mm and is a known achromatic lens used in a general optical film thickness meter. The achromatic lens corresponds to the grouped lens in the claims.
The beam splitter 54 shown in FIG. 4 is composed of a known plate beam splitter, but measures a beam branch plane that transmits measurement light incident from the opposite side of the substrate S and reflects reflected light incident from the substrate S side. It suffices if it is provided at an angle of 45 ° with respect to the optical axis of the light and the optical axis of the reflected light, and it may be composed of a cube beam splitter and a pellicle beam splitter.
 また、ビームスプリッタ54と投光用測光プローブ43との間には、アパーチャ部材55が設けられ、アパーチャ部材55には、投光用測光プローブ43から出射される光ビームの形状を整形するアパーチャ55aが形成されている。アパーチャ55aは、基板Sからの反射光の光路に相当する位置の投光の光量を約20~50%制限可能な形状である。 In addition, an aperture member 55 is provided between the beam splitter 54 and the light projecting photometric probe 43, and the aperture member 55 has an aperture 55a for shaping the shape of the light beam emitted from the light projecting photometric probe 43. Is formed. The aperture 55a has a shape that can limit the amount of light projected at a position corresponding to the optical path of the reflected light from the substrate S by about 20 to 50%.
 このように、アパーチャ55aを備えているため、基板Sが測定光の光軸に垂直な面に対して若干傾斜して、測定光の入射角が変化した場合であっても、反射光が回転ドラム12の回転方向Vに沿って広がることが抑制される。その結果、反射光が投受光側兼用レンズ53からはみ出すことが抑制され、基板角度のばらつきによって膜厚測定値に誤差が生じることを抑制できる。
 なお、アパーチャ部材55を設ける代わりに、ビームスプリッタ54に、基板Sからの反射光の光路に相当する位置の投光の光量を約20~50%制限可能な形状の孔が形成された銀膜等の反射金属を貼り付けてもよい。
As described above, since the aperture 55a is provided, even if the substrate S is slightly inclined with respect to the plane perpendicular to the optical axis of the measurement light and the incident angle of the measurement light is changed, the reflected light is rotated. Spreading along the rotation direction V of the drum 12 is suppressed. As a result, it is possible to suppress the reflected light from protruding from the light projecting / receiving lens 53, and to suppress an error in the film thickness measurement value due to variations in the substrate angle.
Instead of providing the aperture member 55, a silver film in which a hole having a shape capable of limiting the amount of light projected at a position corresponding to the optical path of the reflected light from the substrate S by about 20 to 50% is formed in the beam splitter 54. A reflective metal such as may be attached.
 図4の例では、投受光側兼用レンズ53から基板Sまでの間の距離WDが75~350mmで、投受光側兼用レンズ53と投光用測光プローブ43までの間の距離S2が、35~90mmである。
 このように、WDをS2よりも長く構成することにより、基板Sに入射する測定光を、平行光に近いものとすることができる。
 また、受光用測光プローブ44は、投光用測光プローブ43及びビームスプリッタ54よりも基板S側の位置で、投受光側兼用レンズ53の光軸の投光用測光プローブ43逆側の位置に、投光用測光プローブ43に対して角度を持って設置されている。
In the example of FIG. 4, the distance WD between the light projecting / receiving side lens 53 and the substrate S is 75 to 350 mm, and the distance S2 between the light projecting / receiving side lens 53 and the light projecting photometric probe 43 is 35 to 35 mm. 90 mm.
Thus, by configuring the WD to be longer than S2, the measurement light incident on the substrate S can be made to be close to parallel light.
The light-receiving photometric probe 44 is positioned closer to the substrate S than the light-projecting photometric probe 43 and the beam splitter 54, and to the position on the opposite side of the light-projecting photometric probe 43 with respect to the optical axis of the light-projecting / receiving-side lens 53. The light projecting photometric probe 43 is installed at an angle.
 図4のビームスプリッタ54及びアパーチャ部材55を設けた例では、投光用測光プローブ43から照射された測定光は、アパーチャ55aにより、基板Sからの反射光の光路に相当する位置の投光の光量が約20~50%制限された後、ビームスプリッタ54を透過し、投受光側兼用レンズ53で導光されて基板Sに照射される。基板Sに入射した測定光の一部は、基板Sで反射されて、投受光側兼用レンズ53で導光されビームスプリッタ54に入射する。反射光は、ビームスプリッタ54で垂直方向に反射され、受光用測光プローブ44で受光される。
 図4の例では、アパーチャ部材55,ビームスプリッタ54及び投受光側兼用レンズ53が、特許請求の範囲の投光側レンズユニット、投受光側兼用レンズ53及びビームスプリッタ54が、特許請求の範囲の受光側レンズユニットに該当する。
In the example in which the beam splitter 54 and the aperture member 55 in FIG. 4 are provided, the measurement light irradiated from the light projecting photometric probe 43 is projected by the aperture 55a at a position corresponding to the optical path of the reflected light from the substrate S. After the amount of light is limited by about 20 to 50%, the light is transmitted through the beam splitter 54, guided by the light projecting / receiving side lens 53, and irradiated onto the substrate S. A part of the measurement light incident on the substrate S is reflected by the substrate S, guided by the light projecting / receiving lens 53 and incident on the beam splitter 54. The reflected light is reflected in the vertical direction by the beam splitter 54 and received by the photometric probe 44 for light reception.
In the example of FIG. 4, the aperture member 55, the beam splitter 54, and the light projecting / receiving side combined lens 53 are the light projecting side lens unit, the light projecting / receiving side combined lens 53, and the beam splitter 54 are within the scope of the claims. Corresponds to the light-receiving side lens unit.
 また、図3,図4のレンズ構成の代わりに、図5,図6のようなレンズ構成としてもよい。
 図5,図6の例では、投光用測光プローブ43と回転ドラム12との間に投光側レンズ56,受光側レンズ57,集光レンズ58を配置している。
Moreover, it is good also as a lens structure as FIG. 5, FIG. 6 instead of the lens structure of FIG. 3, FIG.
In the example of FIGS. 5 and 6, a light projecting side lens 56, a light receiving side lens 57, and a condensing lens 58 are disposed between the light projecting photometric probe 43 and the rotary drum 12.
 投光側レンズ56,受光側レンズ57の基板S側には、受光側レンズ57を通った測定光の導光と基板Sからの反射光の導光とに兼用される集光レンズ58が設けられている。集光レンズ58の径は、投光側レンズ56,受光側レンズ57の径の和よりも大きく、40mmである。
 集光レンズ58は、一方の面が投光側レンズ56及び受光側レンズ57に対向し、他方の面が基板Sに対向するように配置されている。
 集光レンズ58と基板Sとの間の距離WDは、75~350mmで、受光側レンズ57と受光用測光プローブ44との間の距離S3,S4は、35~90mmである。
 図5,図6の例では、受光用測光プローブ44及び投光側レンズ56のそれぞれが、投光用測定プローブ43及び受光側レンズ57のそれぞれよりも、集光レンズ58及び基板S寄りに配置されている。従って、測定光及び反射光の進行方向に略沿った方向において、受光用測定プローブ44と受光側レンズ57が、投光用測定プローブ43と投光側のレンズ56との間に挟まれた位置関係となっている。
 投光側レンズ56は、投光用測光プローブ43からの測定光を導光するレンズであり、径が約15mmである。受光側レンズ57は、基板Sからの反射光を導光するレンズであり、径が投光側レンズ56よりも大きく、20mmである。投光側レンズ56,受光側レンズ57のその他の構成は、投光側レンズ51,受光側レンズ52とそれぞれ同様である。
On the substrate S side of the light projecting side lens 56 and the light receiving side lens 57, there is provided a condensing lens 58 that is used both for guiding the measurement light passing through the light receiving side lens 57 and for guiding reflected light from the substrate S. It has been. The diameter of the condensing lens 58 is 40 mm, which is larger than the sum of the diameters of the light projecting side lens 56 and the light receiving side lens 57.
The condensing lens 58 is disposed so that one surface thereof faces the light projecting side lens 56 and the light receiving side lens 57 and the other surface thereof faces the substrate S.
The distance WD between the condenser lens 58 and the substrate S is 75 to 350 mm, and the distances S3 and S4 between the light receiving side lens 57 and the light receiving photometric probe 44 are 35 to 90 mm.
5 and 6, the light receiving photometric probe 44 and the light projecting side lens 56 are arranged closer to the condenser lens 58 and the substrate S than the light projecting measuring probe 43 and the light receiving side lens 57, respectively. Has been. Therefore, the position where the light receiving measurement probe 44 and the light receiving side lens 57 are sandwiched between the light projecting measuring probe 43 and the light projecting side lens 56 in a direction substantially along the traveling direction of the measurement light and the reflected light. It has become a relationship.
The light projecting side lens 56 is a lens for guiding the measurement light from the light projecting photometric probe 43 and has a diameter of about 15 mm. The light-receiving side lens 57 is a lens that guides reflected light from the substrate S, and has a diameter larger than that of the light-projecting side lens 56 and 20 mm. Other configurations of the light projecting side lens 56 and the light receiving side lens 57 are the same as those of the light projecting side lens 51 and the light receiving side lens 52, respectively.
 投光側レンズ56及び受光側レンズ57は、投光側レンズ56の中心56C及び受光側レンズ57の中心57Cが、集光レンズ58の光軸58aを挟んだ両側に位置するように配置されている。また、図5,図6に示すように、集光レンズ58の光軸58aは、隣り合って設けられた受光側レンズ56及び投光側レンズ57のうち、大径の受光側レンズ57の端部が近くなるように配置されている。また、集光レンズ58の光軸58aが、大径の受光側レンズ57を貫通するように配置されていてもよい。
 投光用測光プローブ43は、投光側レンズ56の焦点近傍に配置され、受光用測光プローブ44は、受光側レンズ57の焦点近傍に配置されている。図5,図6の例では、受光側レンズ57の焦点距離よりも、投光側レンズ56の焦点距離の方が長いため、受光用測光プローブ44が、投光用測光プローブ43よりも基板S側に配置されているが、これに限定されるものではない。
The light projecting side lens 56 and the light receiving side lens 57 are arranged such that the center 56C of the light projecting side lens 56 and the center 57C of the light receiving side lens 57 are located on both sides of the optical axis 58a of the condenser lens 58. Yes. As shown in FIGS. 5 and 6, the optical axis 58 a of the condensing lens 58 is the end of the large-diameter light receiving side lens 57 among the light receiving side lens 56 and the light projecting side lens 57 provided adjacent to each other. It is arranged so that the parts are close. Further, the optical axis 58 a of the condenser lens 58 may be disposed so as to penetrate the large-diameter light-receiving side lens 57.
The light projecting photometric probe 43 is disposed in the vicinity of the focal point of the light projecting side lens 56, and the light receiving photometric probe 44 is disposed in the vicinity of the focal point of the light receiving side lens 57. In the example of FIGS. 5 and 6, since the focal length of the light projecting side lens 56 is longer than the focal length of the light receiving side lens 57, the light receiving photometric probe 44 is larger than the light projecting photometric probe 43. Although it arrange | positions at the side, it is not limited to this.
 図5,図6の例では、投光用測光プローブ43から投光された測定光は、投光側レンズ56を通って集光レンズ58に入射し、集光レンズ58で収束されて、基板Sを照射する。この測定光は、基板Sで反射し反射光が集光レンズ58へ導光される。導光された測定光は、受光側レンズ57で収束され、受光用測光プローブ44で受光される。 5 and 6, the measurement light projected from the light projecting photometric probe 43 is incident on the condensing lens 58 through the light projecting side lens 56, and converged by the condensing lens 58. S is irradiated. The measurement light is reflected by the substrate S, and the reflected light is guided to the condenser lens 58. The guided measurement light is converged by the light receiving side lens 57 and received by the light receiving photometric probe 44.
 以下、実施例により本発明を更に詳細に説明するが、本発明はこれらに限定されるものではない。
(シミュレーション例1:相対反射率)
 径500mmの回転ドラム12に有効測定範囲が径20mmである基板Sを搭載したスパッタ装置1に、図3で示すレンズ配置を備えた実施例1に係る膜厚計,図4で示す配置を備えた実施例2に係る膜厚計,対比例1に係る膜厚計を設置した場合のシミュレーションを行った。
 ここで、対比例1のレンズ配置は、基板Sと投光用測光プローブ43及び受光用測光プローブ44との間に、不図示の単一の集光レンズを投光用測光プローブ43の軸に対して略垂直に設ける従来技術のレンズ配置とした。
 図3,図4の距離WD,対比例1の不図示の集光レンズと基板Sとの間の距離WDは、160mmとした。
EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to these.
(Simulation example 1: Relative reflectance)
A sputtering apparatus 1 in which a substrate S having an effective measurement range of 20 mm in diameter is mounted on a rotary drum 12 having a diameter of 500 mm, a film thickness meter according to Example 1 having the lens arrangement shown in FIG. 3, and the arrangement shown in FIG. A simulation was conducted in the case where the film thickness meter according to Example 2 and the film thickness meter according to Comparative Example 1 were installed.
Here, the lens arrangement of the proportional 1 is such that a single condensing lens (not shown) is placed between the substrate S and the light projecting photometric probe 43 and the light receiving photometric probe 44 as an axis of the light projecting photometric probe 43. On the other hand, the lens arrangement of the prior art provided substantially perpendicularly is used.
The distance WD between the condensing lens (not shown) of FIG. 3 and FIG.
 回転ドラム12に保持された基板Sを、投光用測光プローブ43及び受光用測光プローブ44に対向する面に対して、0.0°~2.0°の範囲内の各角度でそれぞれ傾斜させた配置とした。
 つまり、図3の実施例1の場合には、光軸51aと光軸52aとの角度を二等分する二等分線Bに垂直な面に対して、0.0°~2.0°の範囲内の各角度でそれぞれ傾斜させた配置とした。
 また、図4の実施例2及び対比例1の場合には、投受光側兼用レンズ53又は不図示の集光レンズの光軸に垂直な面に対して、0.0°~2.0°の範囲内の各角度でそれぞれ傾斜させた配置とした。
 この状態で、相対反射率を算出した。
 相対反射率の算出は、光源より投光し、光学検出装置46で受光する光の強度を算出することによって行った。実施例1,2及び対比例1のそれぞれについて、基板Sの傾き角度が0.0°のときの算出値を標準値として、各傾斜角度における相対反射率を算出した。
 実施例1,2及び対比例1の各傾斜角度における相対反射率(%)の算出結果を、表1及び図7に示す。
The substrate S held on the rotary drum 12 is inclined at each angle within a range of 0.0 ° to 2.0 ° with respect to the surface facing the light projecting photometric probe 43 and the light receiving photometric probe 44. Was arranged.
That is, in the case of Example 1 in FIG. 3, 0.0 ° to 2.0 ° with respect to the plane perpendicular to the bisector B that bisects the angle between the optical axis 51a and the optical axis 52a. The arrangement was inclined at each angle within the range of.
Further, in the case of Example 2 and Comparative Example 1 in FIG. 4, 0.0 ° to 2.0 ° with respect to a plane perpendicular to the optical axis of the light emitting / receiving lens 53 or a condensing lens (not shown). The arrangement was inclined at each angle within the range of.
In this state, the relative reflectance was calculated.
The relative reflectance was calculated by calculating the intensity of light projected from the light source and received by the optical detection device 46. For each of Examples 1 and 2 and Comparative Example 1, the relative reflectance at each tilt angle was calculated using the calculated value when the tilt angle of the substrate S was 0.0 ° as a standard value.
Table 1 and FIG. 7 show the calculation results of the relative reflectance (%) at each inclination angle of Examples 1 and 2 and Comparative Example 1.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1に示すように、基板Sの傾きが1.2°のときに、対比例1では、相対反射率が68.9%であり、反射光量の変化率は、約31%であった。つまり、径500mmの回転ドラム12に有効測定範囲が径20mmである基板Sを搭載した場合、回転ドラム12の回転むらや、回転ドラム12への基板Sの取付誤差により、膜厚測定時に、基板Sに1.2°程度までの傾きが生じ得るが、対比例1では、一般的に誤差として生じ得る基板Sの傾きによっても、反射光量が3割程度も低減されてしまうことから、膜厚計として、実用的な程度の正確性を有しないことが分かった。 As shown in Table 1, when the inclination of the substrate S is 1.2 °, the relative reflectance is 68.9% and the rate of change in the amount of reflected light is about 31%. That is, when the substrate S having an effective measurement range of 20 mm is mounted on the rotary drum 12 having a diameter of 500 mm, the substrate is measured during film thickness measurement due to uneven rotation of the rotary drum 12 or mounting errors of the substrate S to the rotary drum 12. Although S can be tilted up to about 1.2 °, in contrast 1, the amount of reflected light is reduced by about 30% due to the tilt of the substrate S that can generally occur as an error. As a total, it was found that there was no practical degree of accuracy.
 一方、実施例1及び2では、基板Sの傾きが1.2°のときの相対反射率が90%以上であって、それぞれ、一般的に誤差として生じ得る程度の傾きを基板Sが有するときに、反射光量の変化率が、それぞれ、5.8%と0.4%に過ぎなかった。
 一般的に、回転式の薄膜形成装置において、光学式膜厚計で膜厚を測定する際、基板Sの取付誤差や回転むらにより、回転ドラムの径及び基板Sの大きさによって、基板Sの傾きには数°のばらつきが生じるが、実施例1及び2の膜厚計によれば、数°基板Sが傾いたときでも、実用上十分な反射光量が得られ、膜厚計としての正確性が担保されることが分かった。
On the other hand, in Examples 1 and 2, the relative reflectance when the inclination of the substrate S is 1.2 ° is 90% or more, and the substrate S has an inclination that can generally occur as an error. Moreover, the rate of change in the amount of reflected light was only 5.8% and 0.4%, respectively.
In general, when a film thickness is measured with an optical film thickness meter in a rotary thin film forming apparatus, due to a mounting error or rotation unevenness of the substrate S, depending on the diameter of the rotating drum and the size of the substrate S, Inclination varies by several degrees, but according to the film thickness meters of Examples 1 and 2, even when the substrate S is tilted by several degrees, a practically sufficient amount of reflected light can be obtained, which is accurate as a film thickness meter. It was found that sex was secured.
(実験例1)
 図3に係るレンズ配置を備えた膜厚計40により膜厚を制御して、基板S上に多層AR膜を形成する実験を複数回繰返した場合における薄膜形成中の光量変化及び多層AR膜の分光特性のばらつきについて検討した。このとき、図3の距離WDは、200mmとし、図3の投光側レンズ51,受光側レンズ52の径は30mm,20mmとした。
(Experimental example 1)
The film thickness is controlled by the film thickness meter 40 having the lens arrangement shown in FIG. 3 and the experiment for forming the multilayer AR film on the substrate S is repeated a plurality of times, and the light amount change during the thin film formation and the multilayer AR film The variation of spectral characteristics was examined. At this time, the distance WD in FIG. 3 was 200 mm, and the diameters of the light projecting side lens 51 and the light receiving side lens 52 in FIG. 3 were 30 mm and 20 mm.
 本例では、図1のスパッタ装置1に、第一のターゲット22Aとしてケイ素(Si)を、第二のターゲット22Bとしてニオブ(Nb)を、成膜プロセス領域26A,26Bに導入されるスパッタガスとしてアルゴンガスを、反応プロセス領域36に導入される反応性ガスとして酸素ガスを使用して、回転ドラム12に保持させた複数の基板S上に、酸化珪素(SiO)と酸化ニオブ(Nb)の薄膜を交互に3層と2層積層させた光学多層膜、つまり基板Sに近い順に、SiO-Nb-SiO-Nb-SiOの薄膜が積層された5層構造の多層膜を成膜した。 In this example, silicon (Si) is used as the first target 22A, niobium (Nb) is used as the second target 22B, and the sputtering gas introduced into the film forming process regions 26A and 26B in the sputtering apparatus 1 of FIG. Argon gas is used as a reactive gas introduced into the reaction process region 36, and silicon oxide (SiO 2 ) and niobium oxide (Nb 2 O) are formed on the plurality of substrates S held on the rotary drum 12. 5 ) An optical multilayer film in which three thin films are alternately laminated, that is, a thin film of SiO 2 —Nb 2 O 5 —SiO 2 —Nb 2 O 5 —SiO 2 is laminated in the order closer to the substrate S. A multilayer film having a five-layer structure was formed.
 このとき、第一層のSiO層及び第二層のNb層については、絶対値制御方式によって膜厚を制御した。つまり、図3の配置の膜厚計40を用い、光源41から発せられている測定光を投光用測光プローブ43から基板Sに向けて照射し、受光用測光プローブ44で受光した反射光の強度を光学検出装置46で検知し、この反射光の強度データに基づき、制御装置48で、光量を算出し、この光量をプロットした光量変化曲線の変動状況を監視することによって、膜厚を監視した。そして、膜厚が、あらかじめ定めた目標値に達したときに、成膜を終了した。
 また、第二層成膜終了時には、成膜を終了したときの膜厚を成膜にかかった成膜時間で除することにより、時間制御用の成膜レート係数を算出した。
At this time, the film thickness of the first SiO 2 layer and the second Nb 2 O 5 layer was controlled by an absolute value control method. That is, using the film thickness meter 40 arranged in FIG. 3, the measurement light emitted from the light source 41 is irradiated from the light projecting photometric probe 43 toward the substrate S, and the reflected light received by the light receiving photometric probe 44 is reflected. The film thickness is monitored by detecting the intensity with the optical detection device 46, calculating the amount of light with the control device 48 based on the intensity data of the reflected light, and monitoring the fluctuation state of the light amount change curve in which the amount of light is plotted. did. The film formation was terminated when the film thickness reached a predetermined target value.
Further, at the end of the second layer film formation, the film formation rate coefficient for time control was calculated by dividing the film thickness when the film formation was completed by the film formation time required for the film formation.
 また、第三層のSiO層は、図3のレンズ配置の膜厚計40を用い、B/A制御方式によって膜厚を制御した。
 B/A制御方式とは、生成中の薄膜にモニタ光を照射し、薄膜から透過/反射されたモニタ光の透過率変化を計測して、この透過率変化が描く一定の振幅、極大値、極小値を有する軌跡について、軌跡の上下の幅Aに対する停止光量Bの極値からの変化分Aの割合(B/A)を用いて制御する方法である。本例では、実際の透過率変化に基づくB/A値が所望の膜厚に対応するB/A値と一致したときに成膜を停止することにより、成膜中の膜厚を所望の膜厚に設定した。
 また、第三層成膜終了時には、成膜を終了したときの膜厚を成膜にかかった成膜時間で除することにより、時間制御用の成膜レート係数を算出した。
Further, the film thickness of the third SiO 2 layer was controlled by the B / A control method using the film thickness meter 40 having the lens arrangement shown in FIG.
The B / A control method is to irradiate the generated thin film with monitor light, measure the change in transmittance of the monitor light transmitted / reflected from the thin film, and to express a certain amplitude, maximum value, This is a method of controlling a trajectory having a minimum value by using a ratio (B / A) of a change A from an extreme value of the stop light amount B with respect to an upper and lower width A of the trajectory. In this example, when the B / A value based on the actual transmittance change coincides with the B / A value corresponding to the desired film thickness, the film formation is stopped, so that the film thickness during the film formation can be reduced. Set to thickness.
At the end of the third layer film formation, the film formation rate coefficient for time control was calculated by dividing the film thickness at the end of film formation by the film formation time taken for film formation.
 第四層のNb層及び第五層のSiO層は、第二層,第三層成膜時に算出した成膜レート係数を用いた時間制御方式によって膜厚を制御した。つまり、それぞれ、第二層,第三層の成膜レートと第四層,第五層で成膜する所望の膜厚とから第四層,第五層の成膜時間を算出し、成膜をこの成膜時間行うことにより、第四層,第五層を成膜した。 The film thicknesses of the fourth Nb 2 O 5 layer and the fifth SiO 2 layer were controlled by a time control method using the film formation rate coefficients calculated during the formation of the second and third layers. In other words, the film formation times of the fourth layer and the fifth layer are calculated from the film formation rates of the second layer and the third layer and the desired film thicknesses formed by the fourth layer and the fifth layer, respectively. The fourth layer and the fifth layer were formed by performing this step for forming the film.
 この5層構造の多層膜の成膜工程を、3回繰り返し、基板S上に5層AR膜を備えたサンプル1~3を得た。図8に、サンプル1~3の成膜中における光量変化のグラフを示す。図8に示すように、同様の工程を繰り返した3つのサンプルにおいて、殆ど同様の光量変化を示しており、再現性が高いことが示された。
 また、図9に、基板S上に5層AR膜を備えたサンプル1~3の分光特性のグラフを示す。図9に示すように、サンプル1~3が殆ど同様の分光特性を備えており、本例の膜厚計を用いて膜厚を制御することにより、ほぼ同様の分光特性を備えた5層AR膜を再現性よく成膜できることが分かった。
The film formation process of the multilayer film having the five-layer structure was repeated three times to obtain Samples 1 to 3 having the five-layer AR film on the substrate S. FIG. 8 shows a graph of the change in light amount during film formation of samples 1 to 3. As shown in FIG. 8, in the three samples in which the same process was repeated, almost the same change in the amount of light was shown, indicating that the reproducibility was high.
FIG. 9 shows a graph of spectral characteristics of Samples 1 to 3 having a 5-layer AR film on the substrate S. As shown in FIG. 9, Samples 1 to 3 have almost the same spectral characteristics, and by controlling the film thickness using the film thickness meter of this example, a five-layer AR having substantially the same spectral characteristics. It was found that the film can be formed with good reproducibility.
B 二等分線
S 基板
Z 回転軸
1 スパッタ装置
11 真空容器
11A 薄膜形成室
11B ロードロック室
12 回転ドラム
13,14 仕切壁
15 タイミング検出用反射板
16 タイミングセンサー
17 測定用窓
20A,20B スパッタ源
21A,21B マグネトロンスパッタ電極
22A,22B ターゲット
23A,23B トランス
24A,24B 交流電源
25A,25B ガスボンベ
26A,26B 成膜プロセス領域
30 プラズマ源
31 ケース体
32 誘電体板
33 マッチングボックス
34 高周波電源
35 ガスボンベ
36 反応プロセス領域
40 膜厚計
41 光源
42 光ファイバ
43 投光用測光プローブ
44 受光用測光プローブ
45 光ファイバ
46 光学検出装置
47 積分アンプ
48 制御装置
51,56 投光側のレンズ
51C,52C,56C,57C 中心
52,57 受光側レンズ
53 投受光側兼用レンズ
54 ビームスプリッタ
55 アパーチャ部材
55a アパーチャ
58 集光レンズ
B Bisecting line S Substrate Z Rotating shaft 1 Sputtering device 11 Vacuum vessel 11A Thin film forming chamber 11B Load lock chamber 12 Rotating drums 13 and 14 Partition wall 15 Timing detecting reflector 16 Timing sensor 17 Measuring windows 20A and 20B Sputtering source 21A, 21B Magnetron sputtering electrodes 22A, 22B Targets 23A, 23B Transformers 24A, 24B AC power supplies 25A, 25B Gas cylinders 26A, 26B Deposition process area 30 Plasma source 31 Case body 32 Dielectric plate 33 Matching box 34 High frequency power supply 35 Gas cylinder 36 Reaction Process area 40 Film thickness meter 41 Light source 42 Optical fiber 43 Light metering probe 44 Light metering probe 45 Light fiber 46 Optical detector 47 Integrating amplifier 48 Controllers 51, 56 Lenses 51C, 52C, 5 on the light emitting side C, 57C center 52 and 57 receiving side lens 53 projecting the light receiving side combinational lens 54 the beam splitter 55 aperture member 55a aperture 58 converging lens

Claims (10)

  1.  回転式の光学薄膜形成装置の基板ホルダに取付けられ、該基板ホルダの回転に応じて回転している基板上の光学薄膜の膜厚を測定する反射式の光学式膜厚計であって、
     測定光を、前記回転している前記基板に向けて投光する投光部と、
     該投光部と前記基板の間に配置され、前記投光部から出射する前記測定光を受けて、該測定光を前記基板に導光する投光側のレンズを備えた投光側レンズユニットと、
     前記基板から前記測定光の反射光を受光する受光部と、
     該受光部と前記基板の間に配置され、前記基板からの反射光を受けて、該反射光を前記受光部に導光する受光側のレンズを備えた受光側レンズユニットと、を備え、
     該受光側レンズユニットの光路と前記投光側レンズユニットの光路とは、少なくとも一部が分離され、
     前記投光側レンズユニットの有効面積は、前記受光側レンズユニットの有効面積よりも小さいことを特徴とする光学式膜厚計。
    A reflective optical film thickness meter that is attached to a substrate holder of a rotary optical thin film forming apparatus and measures the film thickness of an optical thin film on a substrate that is rotating according to the rotation of the substrate holder,
    A light projecting unit that projects measurement light toward the rotating substrate;
    A light-projecting side lens unit comprising a light-projecting lens that is disposed between the light projecting unit and the substrate, receives the measurement light emitted from the light projecting unit, and guides the measurement light to the substrate. When,
    A light receiving unit for receiving reflected light of the measurement light from the substrate;
    A light-receiving-side lens unit that is disposed between the light-receiving unit and the substrate, includes a light-receiving-side lens that receives reflected light from the substrate and guides the reflected light to the light-receiving unit,
    The light path of the light receiving side lens unit and the light path of the light projecting side lens unit are at least partially separated,
    An optical film thickness meter, wherein an effective area of the light-projecting lens unit is smaller than an effective area of the light-receiving lens unit.
  2.  前記投光側のレンズと前記受光側のレンズは、相互に独立した別体のレンズであり、
     前記投光側のレンズの有効径は、前記受光側のレンズの有効径よりも小さいことを特徴とする請求項1記載の光学式膜厚計。
    The light-projecting side lens and the light-receiving side lens are separate and independent lenses,
    2. The optical film thickness meter according to claim 1, wherein an effective diameter of the lens on the light emitting side is smaller than an effective diameter of the lens on the light receiving side.
  3.  前記投光側のレンズの光軸と、前記受光側のレンズの光軸との角度は、3°以上10°以下であって、
     前記投光側のレンズから前記基板までの距離は、前記投光部から前記投光側のレンズまでの距離よりも長く、
     前記受光側のレンズから前記基板までの距離は、前記受光部から前記受光側のレンズまでの距離よりも長いことを特徴とする請求項2記載の光学式膜厚計。
    The angle between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens is 3 ° or more and 10 ° or less,
    The distance from the lens on the light projecting side to the substrate is longer than the distance from the light projecting unit to the lens on the light projecting side,
    3. The optical film thickness meter according to claim 2, wherein a distance from the light receiving side lens to the substrate is longer than a distance from the light receiving unit to the light receiving side lens.
  4.  前記投光側のレンズの光軸と前記受光側のレンズの光軸との交点を通り、前記投光側のレンズの光軸と前記受光側のレンズの光軸のなす角度を二等分する直線が、通過する位置に、前記受光側のレンズが配置されていることを特徴とする請求項2又は3記載の光学式膜厚計。 The angle formed between the optical axis of the light-projecting lens and the optical axis of the light-receiving lens passes through the intersection of the optical axis of the light-projecting lens and the optical axis of the light-receiving lens. 4. The optical film thickness meter according to claim 2, wherein the lens on the light receiving side is disposed at a position where the straight line passes.
  5.  前記投光側のレンズ及び前記受光側のレンズと、測定対象の前記基板との間に、前記投光側のレンズ,前記受光側のレンズ及び前記基板に対向する集光レンズを備え、
     該集光レンズの有効径は、前記投光側のレンズの有効径と前記受光側のレンズの有効径の和より大きいことを特徴とする請求項1乃至4いずれか記載の光学式膜厚計。
    Between the light-projecting side lens and the light-receiving side lens and the measurement target substrate, the light-projecting side lens, the light-receiving side lens, and a condensing lens facing the substrate,
    5. The optical film thickness meter according to claim 1, wherein an effective diameter of the condenser lens is larger than a sum of an effective diameter of the light-projecting lens and an effective diameter of the light-receiving lens. .
  6.  前記投光側のレンズと前記受光側のレンズは、一体に形成された単一の投受光側兼用レンズからなり、
     該投受光側兼用レンズと前記受光部との間に、前記測定光を透過すると同時に前記反射光を反射し、前記反射光の軸に対して傾斜したビーム分岐面を備えたビームスプリッタが配置されていることを特徴とする請求項1記載の光学式膜厚計。
    The light projecting side lens and the light receiving side lens are composed of a single lens for both light projecting and receiving side formed integrally,
    A beam splitter having a beam branching surface that transmits the measurement light and reflects the reflected light at the same time and is inclined with respect to the axis of the reflected light is disposed between the lens for light emitting and receiving side and the light receiving unit. The optical film thickness meter according to claim 1, wherein:
  7.  前記投受光側兼用レンズと前記投光部との間に、前記投光部から出射される測定光の光量を制限するアパーチャが設けられ、
     前記投光側レンズユニットは、前記投受光側兼用レンズ,前記ビームスプリッタ及び前記アパーチャから構成されていることを特徴とする請求項6記載の光学式膜厚計。
    An aperture for limiting the amount of measurement light emitted from the light projecting unit is provided between the light projecting / receiving lens and the light projecting unit,
    The optical film thickness meter according to claim 6, wherein the light projecting side lens unit includes the light projecting / receiving side lens, the beam splitter, and the aperture.
  8.  前記レンズは、該レンズが出射する光のビームの収差を除去するよう複数枚のレンズを組み合わせた組レンズからなることを特徴とする請求項1乃至7いずれか記載の光学式膜厚計。 The optical film thickness meter according to any one of claims 1 to 7, wherein the lens is composed of a combined lens in which a plurality of lenses are combined so as to remove aberration of a beam of light emitted from the lens.
  9.  真空容器内に基板を支持して回転可能な基板ホルダと、
     該基板ホルダに保持された前記基板に対向して配設された薄膜形成手段と、
     前記基板が取付けられた前記基板ホルダが回転している状態で、前記基板に測定光を照射して前記基板上の光学薄膜の膜厚を測定する光学式膜厚計と、を備えた薄膜形成装置であって、
     前記光学式膜厚計は、請求項1乃至8いずれか記載の光学式膜厚計からなることを特徴とする薄膜形成装置。
    A substrate holder that can rotate while supporting the substrate in a vacuum vessel;
    A thin film forming means disposed to face the substrate held by the substrate holder;
    An optical film thickness meter that measures the film thickness of the optical thin film on the substrate by irradiating the substrate with measurement light while the substrate holder to which the substrate is attached is rotating. A device,
    The optical film thickness meter comprises the optical film thickness meter according to any one of claims 1 to 8.
  10.  回転式光学薄膜形成装置の基板ホルダの回転に応じて回転している基板に形成された光学薄膜の膜厚を測定する反射式の膜厚測定方法であって、
     測定光を投光部から、投光側のレンズを備えた投光側レンズユニットを介して、前記回転している基板に向けて投光し、
     前記基板で反射した前記測定光の反射光を、受光側のレンズを備え、前記投光側レンズユニットの光路とは、少なくとも一部が分離された光路を有し、前記投光側レンズユニットの有効面積よりも大きい有効面積を備えた受光側レンズユニットを介して、受光部に導光し、
     該受光部が受光した前記反射光の光量データを解析することにより、前記光学薄膜の膜厚を測定することを特徴とする膜厚測定方法。
    A reflective film thickness measuring method for measuring the film thickness of an optical thin film formed on a rotating substrate according to the rotation of a substrate holder of a rotary optical thin film forming apparatus,
    The measurement light is projected from the light projecting unit through the light projecting side lens unit including the lens on the light projecting side toward the rotating substrate,
    The reflected light of the measurement light reflected by the substrate is provided with a light receiving side lens, and has an optical path at least partially separated from the light path of the light projecting side lens unit. The light is guided to the light receiving unit through the light receiving side lens unit having an effective area larger than the effective area,
    A film thickness measuring method comprising measuring the film thickness of the optical thin film by analyzing light quantity data of the reflected light received by the light receiving section.
PCT/JP2013/068887 2013-07-10 2013-07-10 Optical film thickness measurement device, thin film forming device, and method for measuring film thickness WO2015004755A1 (en)

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