TW201022355A - Polymer blends with ethylene/α-olefin interpolymers - Google Patents
Polymer blends with ethylene/α-olefin interpolymers Download PDFInfo
- Publication number
- TW201022355A TW201022355A TW098133585A TW98133585A TW201022355A TW 201022355 A TW201022355 A TW 201022355A TW 098133585 A TW098133585 A TW 098133585A TW 98133585 A TW98133585 A TW 98133585A TW 201022355 A TW201022355 A TW 201022355A
- Authority
- TW
- Taiwan
- Prior art keywords
- ethylene
- polymer
- olefin
- interpolymer
- block
- Prior art date
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- 239000005977 Ethylene Substances 0.000 title claims abstract description 223
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 222
- 239000004711 α-olefin Substances 0.000 title claims abstract description 83
- 229920002959 polymer blend Polymers 0.000 title description 25
- 239000000203 mixture Substances 0.000 claims abstract description 220
- 238000009826 distribution Methods 0.000 claims abstract description 51
- 238000010828 elution Methods 0.000 claims abstract description 45
- 229920000642 polymer Polymers 0.000 claims description 347
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- 229920001400 block copolymer Polymers 0.000 claims description 106
- 150000001336 alkenes Chemical class 0.000 claims description 84
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 68
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 63
- 238000002844 melting Methods 0.000 claims description 59
- 230000008018 melting Effects 0.000 claims description 59
- 239000000178 monomer Substances 0.000 claims description 50
- 238000007906 compression Methods 0.000 claims description 45
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- 229930195733 hydrocarbon Natural products 0.000 claims description 33
- 239000000155 melt Substances 0.000 claims description 31
- 150000002430 hydrocarbons Chemical class 0.000 claims description 30
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 28
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- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
- 238000011084 recovery Methods 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 238000000985 reflectance spectrum Methods 0.000 claims description 13
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- OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 claims description 2
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- 238000009472 formulation Methods 0.000 description 32
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- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 29
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- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 27
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- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 20
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- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 14
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 14
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
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- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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| TWI703041B (zh) * | 2015-03-17 | 2020-09-01 | 美商陶氏全球科技有限責任公司 | 用於將撓性配件密封至撓性膜之方法 |
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| EP2238185B1 (en) * | 2008-01-30 | 2019-01-16 | Dow Global Technologies LLC | Butene/ -olefin block interpolymers |
| CN101981074A (zh) * | 2008-01-30 | 2011-02-23 | 陶氏环球技术公司 | 丁烯/α-烯烃嵌段互聚物 |
| JP4634535B1 (ja) * | 2009-07-17 | 2011-02-16 | 三菱樹脂株式会社 | 太陽電池封止材及びそれを用いて作製された太陽電池モジュール |
| KR101795085B1 (ko) * | 2009-10-02 | 2017-11-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 열가소성 가황물 응용에서의 블록 복합체 |
| CN103068870B (zh) | 2010-06-18 | 2015-06-24 | 陶氏环球技术有限责任公司 | 导电的、中间相-分离的烯烃多嵌段共聚物组合物 |
| BR112012032686B1 (pt) | 2010-06-21 | 2021-01-05 | Dow Global Technologies Llc | composição |
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| US11732071B2 (en) * | 2018-05-04 | 2023-08-22 | Lg Chem, Ltd. | Olefin-based copolymer and method for preparing the same |
| US11629208B2 (en) * | 2018-05-04 | 2023-04-18 | Lg Chem, Ltd. | Olefin-based copolymer and method for preparing the same |
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| WO2021188361A1 (en) | 2020-03-20 | 2021-09-23 | Exxonmobil Chemical Patents Inc. | Linear alpha-olefin copolymers and impact copolymers thereof |
| WO2021210749A1 (ko) * | 2020-04-16 | 2021-10-21 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
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| JP7418579B2 (ja) * | 2020-04-16 | 2024-01-19 | エルジー・ケム・リミテッド | 電気絶縁性に優れたエチレン／α－オレフィン共重合体 |
| KR102387101B1 (ko) * | 2020-04-16 | 2022-04-18 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
| CN115943182B (zh) * | 2020-04-29 | 2025-07-01 | 陶氏环球技术有限责任公司 | 含有高熔体指数乙烯/α-烯烃多嵌段互聚物的组合物 |
| CN117222520A (zh) | 2021-05-18 | 2023-12-12 | 美国圣戈班性能塑料公司 | 复合管及其制造方法 |
| CN119998387A (zh) * | 2022-09-02 | 2025-05-13 | 陶氏环球技术有限责任公司 | 具有优异耐巴利挠曲性的基于乙烯/α-烯烃多嵌段互聚物的组合物 |
| KR20250076606A (ko) | 2022-09-30 | 2025-05-29 | 다우 글로벌 테크놀로지스 엘엘씨 | 충격 강도 및 광투과율이 우수한 폴리올레핀 조성물 |
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| CN1934150A (zh) | 2004-03-17 | 2007-03-21 | 陶氏环球技术公司 | 用于形成乙烯共聚物的包括穿梭剂的催化剂组合物 |
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| US7858706B2 (en) | 2004-03-17 | 2010-12-28 | Dow Global Technologies Inc. | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| US7622529B2 (en) * | 2004-03-17 | 2009-11-24 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility |
| MX2007011349A (es) * | 2005-03-17 | 2007-10-03 | Dow Global Technologies Inc | Modificacion del impacto de termoplasticos con interpolimeros de etileno/a-olefina. |
| KR101315567B1 (ko) * | 2005-03-17 | 2013-10-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/알파-올레핀 혼성중합체 블렌드 및 이로부터 제조된프로파일 및 개스킷 |
| AR056640A1 (es) * | 2005-03-17 | 2007-10-17 | Dow Global Technologies Inc | Composiciones de interpolimeros de multiples bloques de etileno/(alpha)-olefina para peliculas sopladas con elevada pegajosidad en caliente |
| WO2006101968A2 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates |
| US7737215B2 (en) * | 2005-03-17 | 2010-06-15 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| BRPI0609852B1 (pt) * | 2005-03-17 | 2017-12-26 | Dow Global Technologies Inc | Polymeric mixture, molded article, sheet article, thermoconformed article and profile article |
| WO2006102154A2 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies, Inc. | Polymer blends from interpolymers of ethylene/alpha-olefins and flexible molded articles made therefrom |
| JP5231985B2 (ja) * | 2005-03-17 | 2013-07-10 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／α−オレフィンの共重合体およびそれらから製造される製品のレオロジー改良 |
| CA2601292A1 (en) * | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | Ethylene/alpha-olefins block interpolymers |
| US7906587B2 (en) * | 2005-09-16 | 2011-03-15 | Dow Global Technologies Llc | Polymer blends from interpolymer of ethylene/α olefin with improved compatibility |
| US7695812B2 (en) * | 2005-09-16 | 2010-04-13 | Dow Global Technologies, Inc. | Fibers made from copolymers of ethylene/α-olefins |
| SG170126A1 (en) * | 2006-03-15 | 2011-04-29 | Dow Global Technologies Inc | PROPYLENE/a-OLEFINS BLOCK INTERPOLYMERS |
| KR101613165B1 (ko) * | 2008-01-30 | 2016-04-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀 블록 혼성중합체 |
| WO2009097565A1 (en) * | 2008-01-30 | 2009-08-06 | Dow Global Technologies Inc. | ETHYLENE/α-OLEFIN BLOCK INTERPOLYMERS |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI703041B (zh) * | 2015-03-17 | 2020-09-01 | 美商陶氏全球科技有限責任公司 | 用於將撓性配件密封至撓性膜之方法 |
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| US8921491B2 (en) | 2014-12-30 |
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| US20100113698A1 (en) | 2010-05-06 |
| JP6317055B2 (ja) | 2018-05-09 |
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