TW200535223A - Systems, methods, and catalysts for producing a crude product - Google Patents

Abstract

Contact of a crude feed with one or more catalysts produces a total product that include a crude product. The crude product is a liquid mixture at 25 DEG C and 0.101 Mpa. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.

Description

200535223 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates generally to systems, methods, and catalysts for processing crude oil feeds' and to compositions that can be produced using such systems, methods, and catalysts. More specifically, the specific examples described herein relate to systems, methods, and catalysts used to convert crude oil feeds to a total product, where the total product contains a crude product that is liquid at 25t and ㈣1 MPa The mixture also has one or more changed properties compared to the individual properties of the crude feed. [Previous Technology] Crude oils with one or more inappropriate properties that cannot allow crude oil to be transported economically or processed using conventional equipment are often referred to as "inferior crude oils." Inferior crude oil may contain the total acid value that caused the crude oil feed ("TA f into a knife. Inferior crude oil with a phase S South TAN can cause metal components to erode during transportation and / or cores. Remove the inferior crude oil. The acidic ingredients may involve neutralizing the acidity / knife with various alkali chemistry. Or, the rhenium metal can be used in carousel equipment and / or processing equipment. The use of corrosion-resistant metals usually involves considerable costs. The use of T and T * in the current reserve involves the temporary and inferior crude oil in the transportation and / or processing. The use of a corrosion inhibitor and the use of a corrosion inhibitor may affect the products of processed crude oil and / or products made from crude oil. f There is chaos., Poorly prepared crude oil usually contains quite a lot of residues of Shidanhegu ancient "Mada Dali. Such a large amount of residues will be difficult to lose using conventional equipment. Han, and / or processing And expensive pours 200535223 Inferior crude oil usually contains organically bound heteroatoms ^ (such as sulfur, oxygen, and nitrogen). Organically bound heteroatoms can adversely affect the catalyst in some cases. Inferior crude oil may contain When a large amount of metal causes dying materials such as nickel, hunger, and / or iron. During processing of this type of crude oil, metal clutter and / or metal contamination compounds may be deposited in the contact # ^ On the surface or in the pore volume of the catalyst. Such deposits may cause a decrease in catalyst activity. South temperature, which is dramatically formed and / or the regeneration of the catalytic activity of the deposit, may also cause the catalyst to process poor quality crude oil Coke may be anxious on the catalyst surface. The cost of the catalyst contaminated with coke may be expensive. The activity used during regeneration is reduced and / or the catalyst is deteriorated. In addition, crude oil may contain organic acid metal salts. Metals (eg, about, potassium, and / or nano). Metals in the form of metal salts of organic acids are typically separated from crude oil by conventional methods such as desalination and / or pickling. When organic acids are present Metal salt in the form of metal salt, the conventional method often encounters Z. Compared with nickel and hafnium, which are typically deposited near the outer surface of the catalyst, metal with salt form may be preferentially deposited in the pores between the catalyst particles. Yes The top of the catalyst bed. Fouling, such as organic acid 2 = ㈣ metal deposited on the top of the catalyst bed will usually cause the catalyst bed to pass through the catalyst metal. Furthermore, the metal of the organic acid may cause the catalyst's Rapid deactivation. Alternative crude oil may contain organic oxygen compounds. Crude crude oil contains at least ° ... Poor crude oil with 2 grams of oxygen may encounter problems during processing. Organic oxygen compounds during processing 200535223 This may result in the formation of higher oxides (such as ketones and / or alcohols to form acids and / or ethers to form acids), which are difficult to remove from, remove from, and / or Corrosion / contamination of equipment and blockage of dry feed pipelines during processing may occur. $ Inferior crude oil may contain unsaturated hydrocarbons. When processing unsaturated hydrocarbons, especially if unsaturated fragments from cracking processes are produced, then the hydrogen is evenly distributed. The amount must usually be increased. Hydrogenation during processing, which typically involves the use of active = chemical catalysts, may need to inhibit unsaturated fragments from forming coke. ^ Expensive to produce and / or expensive to transfer to processing equipment. . — Poor crude oils also tend to show instability during processing with conventional equipment. Crude oil instability has a tendency to cause component phase separation and / or non-ideal by-products (such as chlorine sulfide, water, and carbon dioxide) during processing. 0, Conventional methods often lack the ability to change the selected properties of inferior crude oils. ^ "Ability of other properties of crude oil. For example, conventional methods often lack the ability to significantly reduce the TAN in inferior crude oil while at the same time only changing the specific eighteen Mb-inferior crude oil by the desired denier. The content of knives (丨 1 such as stone gourd or metal pollutants) are used to improve the quality of crude oil fm ρ,, ρτ ,, '/ Dilution Add thinner to inferior crude oil to reduce the weight percentage of components that cause adverse properties ... Adding a diluent will usually increase the cost of processing inferior or high-quality crude oil due to the added cost. Crude oil may increase in several cases: ::: cost. Diluent added to inferiority awarded-etc .: The stability of this crude oil. Temple People's Wu Guo Patent Case, Tiger 6,547,957; awarded to 200535223

6,277,269 to Meyers et al; 6,063,266 to Kuxin et al; 5,928,502 to Bearden et al; 5,914,030 to Taru et al; 5,897,769 to Trachte et al; and Tnchw 5,871,636 et al .; and 5,85 1,381 awarded to Tanaka et al. Describe various methods, systems, and catalysts for processing crude oil. However, the methods, systems, and catalysts described in these patents have limited applicability due to the many technical issues raised above. In other words, inferior crude oils often have non-ideal properties (for example, a tendency for a relatively high TAN to become unstable during processing, and / or a tendency to consume a significant amount of hydrogen during processing). Other non-ideal properties include considerable amounts of non-ideal ingredients (such as residues, organically bound heteroatoms, metal contaminants, metals in the form of metal salts of organic acids, and / or organic oxygen compounds). This type of property tends to cause problems in conveying and / or processing equipment, including where: increased corrosion during the period, reduced catalyst life, process blockage, and / or hydrogen to account for this. Improved systems, methods, and / or catalysts for converting crude products with more desirable properties still have significant economic: technical: demand. Similarly, there is a significant economic and technical need for systems, methods, and / or media that can change the selected properties of inferior crude oil and change other properties of inferior crude oil. [Summary of the Invention] The system of t ^ A is related to the system used to convert crude oil feed to the total product containing crude oil but not the non-condensable gas in the right embodiment: the method and method Concerning a new spear containing the ingredients, and the composition of the mouth. Such compositions can be obtained using the system and 200535223 method described herein. The present invention provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25t and 0.101 MPaT, and the crude oil The feed has a TAN of at least 0.3, the at least one catalyst has a pore size distribution with a median pore size in the range of 90 A to 180 A, and at least 60% of the total pore size in the pore size distribution has a median of 45 A The pore size in the pore size range, where the pore size distribution is determined by ASTM &D4282; and the contact conditions are controlled so that the crude oil product has a TAN of the crude oil feed with a TAN of up to 90%, where TAN is determined by ASTM method D664 . The invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 ° C and 0.11 MPa Liquid mixture, the crude oil feed has a TAN of at least 0.3, the at least one catalyst has a pore size distribution with a median pore size of at least 90 people, and it is determined by ASTM method D4282. Contains 0.001 to 0.001 g of molybdenum,-or more molybdenum compounds, or mixtures thereof, based on the weight of molybdenum; and controlling the contact conditions so that the crude oil product has a maximum TAN of 90% of the crude oil feed. The TAN of the feed was determined by ASTM method D664. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 2rc and 0_1 () 1㈣ The crude oil feed has a tan of at least 0.3, measured by ASTM D664, X. The at least one catalyst has a pore size distribution with a median pore size of at least 180, and 200535223 measured by ASTM method D4282, the catalyst. Have a pore size distribution that contains one or more metals of the Periodic Table (one or more metals, one or more metals of the Periodic Table 6 or one or more compounds thereof, or a mixture thereof); and control the contact conditions so that the crude oil product has a maximum of butyl AN 90% of the TAN of the crude oil feed, wherein TAN is determined by ASTM method D664. The present invention also provides a method for producing a crude oil product, which includes contacting the crude oil feed with one or more catalysts to produce a product containing The total product of a crude oil product, wherein the crude oil product is a liquid mixture at 25t and 0.1 (1 Mpa), and the f oil feed has a TAN of at least 0.3, which is measured by ASTM method D664. touch The medium contains one or more subordinates in column 6 of the periodic table, one or more metals in the periodic table-or more compounds, or mixtures thereof; and (b) one or more in block 10 of the periodic table. Multiple metals, one or more compounds of one or more metals in column 10 of the Table 2 or a mixture thereof, in which the molar ratio of the total amount of the tenth metal to the total amount of the sixth metal is in the range of 1 to 10, And controlling the contact conditions so that the crude oil product has a TAN of the crude oil feed with a TAN of at most 90%, where the TAN is determined by ASTM method D664. The invention also provides a method for producing a crude oil product, comprising: The crude oil feed is contacted with-or more catalysts to produce a total product containing crude oil products, where the crude oil product is in a liquid mixture of 0.1 (1 MPaT) and the feedstock has a TAN of at least G · 3 The catalyst or catalysts include: (1) the first catalyst, which is contained in the first catalyst per gram, based on the weight of the metal, and contains the 6th block of the periodic table from 0 to 0.06 grams. —Or multiple metals week ”table 6—or multiple metals—or multiple compounds, or mixed 200535 223 substances; and ⑻ the second catalyst 'the second catalyst contains at least 0.02 grams of one or more metals in the sixth table of the periodic table' by metal weight 'per gram of the second catalyst. Column 6—one or more compounds of the metal or a mixture thereof; and controlling the contact conditions so that the crude oil product has a TAN of the crude oil feed with a TAN of up to 90%, where ㈣㈣ is determined by ASTM method D664. The present invention A catalyst composition is also provided, which includes: (i) one or more compounds of the fifth table of the periodic table, one or more metals, or a mixture thereof; (b) a carrier, which has: The oxide content is at least ο ”grams of e-oxide in each gram of the carrier, which is measured by X-ray diffraction. The catalyst has a pore size distribution with a median pore size of at least $ 23〇Α, which is determined by ASTM method D4282. Determination. The present invention also provides a catalyst composition, which includes: one or more metals in the sixth period of the periodic table-one or more compounds of one or more metals in the sixth period of the periodic table, or a mixture thereof, (b) a carrier, It has a θ oxide content of at least ❹ · 1 gram of θ alumina in a gram of carrier. It is measured by X-ray diffraction. The catalyst has a pore size distribution with a median pore size of at least 23〇A. Determined by ASTM method D4282. Ben Miaoming also provides a catalyst composition, which includes ... 0) Period 5 of the Periodic Table—or multiple metals' Periodic Table 帛 5—or one or more species of metal ’s chemical species ’Periodic Table 6 -Or more metals, column 6 of the Periodic Table-or more metals-or more compounds, or mixtures thereof; ⑻ carrier 'which has a θ oxide content of at least 〇 ^ ㊀ oxidized 1 gram per gram of carrier 'It is measured by X-ray diffraction; wherein the catalyst has a pore size distribution with a pore diameter of less than 200535223 and less than 230λ, and the burial is measured by the -ASTM method D4282. The present invention also provides a method for producing tentacles and soil tentacles, which comprises: combining a carrier with one or more metals to form a carrier / tonghuang, a basket / subordinate mixture, wherein the carrier contains Θ oxidation Aluminum, and the one or more metals include one or more metals in column 5 of the periodic table, or one of more than one metal—or more compounds, or mixtures thereof; at a temperature of up to 40 (rc) Thallium oxide carrier / metal mixture; and forming a catalyst, the catalyst has a pore size distribution with a median pore size of at least 230A, which is determined by ASTM method 04282.

The present invention also provides a method for producing a catalyst, comprising: combining a carrier with _ or a plurality of metals to form a carrier / metal mixture, wherein the carrier contains a Θ emulsified inscription, and-or a plurality of metals includes the sixth block of the periodic table-or Multi-metal 'periodic table f 6-or multi-metal-or multiple compounds, t π σ heat-treated at a temperature of at least _ c ㊀ oxide carrier / metal mixture; and forming a catalyst, wherein the catalyst has a medium The pore size is at least a pore size distribution of 23〇A, which is determined by the method of 1) 4282.

The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil base material with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is liquid at 25t and 0.1 (1) milk Mixture, the crude oil feed has at least 0.3 A, the at least one catalyst has a pore size distribution with a median = diameter of at least 18 Α, and by eight methods ^^ Measure =, the catalyst has θ alumina and one or more of the sixth column of the periodic table, which are the pore size distribution of-or more metals-or more compounds, or mixtures thereof, in column 6 of the periodic table; and controlling the contact conditions so that the crude oil product has a TAN The TAN of the crude oil feed is at most 90%. The TAN 12 200535223 is determined by ASTM method D664. The present invention also provides a method for producing a crude oil product, which comprises: One or more catalysts are contacted to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 0.101 MPa, the crude oil feed has at least 03 tan, and the crude oil feed has Oxygen content per gram The crude oil feed has at least ~ grams of oxygen, and the at least one catalyst has a pore size distribution with a median pore size of at least 90A, as determined by the astm method D4282; and controlling the contact conditions to reduce ταν so that the crude product Have M of the crude oil feed with a maximum of 9G%, and reduce the content of organic oxygen compounds so that the crude oil product has the oxygen content of the crude oil feed with an oxygen content of up to 90%, wherein It was measured by ASTM method D664, and the oxygen content was measured by astm method M ". The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is liquid at a depressurization of 0.1 (1) Mpa Mixture, the crude oil feed has at least (MM TAN, the at least one catalyst per gram of catalyst, based on the weight of the metal, contains at least 0.001 g of Periodic Table of the Periodic Table or the genus Discus, cycle One or more compounds of one or more metals, or mixtures thereof, in column 6 of the table; and controlling the contact conditions so that in the contact zone: the liquid space velocity exceeds 10 h 'and the crude product has a maximum of 90% of The TAN of the crude oil feed is determined by the eight hidden method D664. The present invention also provides a method for producing a crude oil product, which comprises: contacting the crude oil feed with one or more catalysts in the presence of a hydrogen source to produce The total product containing crude oil 13 200535223 products, beans φ Shifangdun, Lili ^ /, Zhong 4 crude oil products are liquid mixtures at 25 ° c and 0101 MPa, the crude oil feed has at least 0 10 TAN, the Crude oil feed has a sulfur content of A gram of crude oil feed has at least G side sulphur. The catalysts are listed in the sixth table of the periodic table—or more than one metal, the sixth table of the periodic table—or more than one metal—or multiple compounds, or mixtures thereof. ; And controlling the contact conditions so that the crude oil feed absorbs knife hydrogen at a selected rate during the contact period to suppress phase separation of the crude oil feed during the contact period so that the liquid space velocity in one or more contact zones exceeds G1G h · , So that the crude oil product "has a TAN of 90% of the crude oil feed TAN, and the crude oil product has a sulfur content of sulfur content of 70 to 130% of the crude oil feed, /, medium TAN is measured by ASTM method D664, and sulfur content is measured by ASTM method D4294. The present invention also provides a method for producing crude oil products, which includes: in the presence of a gaseous wind source, feeding crude oil with one or more The catalyst is contacted to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25t and 100 MPa; and the contact conditions are controlled so that the crude oil feed is absorbed at a selected rate during the hydrogen absorption to Suppress the crude oil feed during the contact period ^ The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with hydrogen in the presence of one or more catalysts to produce a total product containing crude oil production, wherein the crude oil product is at 25 and Mb can .〇 〇1〇i 1 r ,, said two people) was μ a night heart; and controlling contacting conditions so that the crude oil feed of hydrogen at the first suction condition and then to a second draw conditions with hydrogen Contact with hydrogen. The first absorption condition is different from the second hydrogen absorption condition. The net absorption of hydrogen 14 200535223 in the first hydrogen absorption condition is controlled to prevent the p value of the crude oil feed / total product mixture from falling below 1 $. One or more properties are changed by up to 90% compared to one or more individual properties of the crude feed. The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with one or more catalysts at a first temperature, and then contacting at a second temperature to produce a total product containing a crude oil product. The crude oil: It is a liquid mixture under the condition of 0.101 MPa, and the crude oil feed has a temperature of f 0.3 and TAN; and the contact condition is controlled so that the first contact temperature is at least 30 C lower than the first contact Λ degree, so that The crude product compared to the crude feed 'has a TAN of up to 90%' where TAN is determined by the astm method D664. The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with-or more thorium to produce a total product containing a crude oil product, wherein 4 crude oil products are a liquid mixture at 25 MPa and 010 MPa The oil feed has at least 0.3 @ TAN, the crude feed has a sulfur content of at least one gram of sulfur per gram of crude feed, and the at least one catalyst contains one or more of column 6 of the periodic table Metal, one or more subordinate compounds of the Periodic Table 6, or mixtures thereof; and controlling the contact conditions so that the crude oil product has at most 90% of the TAN of the crude oil feed, and The crude oil product has sulfur content 1 of the crude oil feed having a sulfur content of 70 to 70, in which TAN is determined by M · method D664 and sulfur content is determined by ASTM method D4294. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feedstock or a plurality of catalysts to produce a total product containing a crude oil product, 15 200535223

Wherein the crude oil product is a liquid mixture at 25.0 and 0 · 101 MPa, the crude oil feed has a tan of at least 0, and the crude oil feed has a residual content of at least 0.1 g per gram of crude oil feed. A residue, the at least one catalyst comprising one or more metals of the sixth table of the periodic table, one or more compounds of one or more metals of the sixth table of the periodic table, or a mixture thereof; and controlling contact conditions so that the crude oil product has The TAN is at most 90% of the TAN of the crude oil feed, so that the crude oil product has a residual content of 70 to 130% of the crude oil feed residue, where TAN is determined by ASTM method 0664 'The residue content was measured by ASTM method D5307.

The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at G.1 () 1 MPaT The f oil feed has a TAN of at least 0.1, the crude oil feed has a VG0 content of at least 0.! G of VG0 per gram of crude oil feed, the at least one catalyst = one containing the sixth block of the periodic table Or more metals, one or more compounds of one or more metals of the sixth table of the periodic table, or a mixture thereof; and controlling the contact conditions so that the crude oil product has a TAN of TAN of up to 90% of the crude oil feed, such that The crude oil product has a VG0 content of the crude oil feed having a VG0 content of 1 to 130%, wherein the VG0 content is determined by ASTM method D5307. The invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 0.1 and 〇 MPa The crude oil feed has at least 03 @ TAN, the at least _ catalysts can be paid by the next 16 200535223 column, make the carrier and the 6th block of the periodic table ^ 6 metal from the evening or 6th block of the periodic table, 6 One or more of one or more metals 丨 V 勰 丄 勰 丄 Gan Gan 4 kinds of 5 substances, or a mixture of them & produces a catalyst driver ... or more sulfur-containing compounds, heated at the temperature of MHTC The catalyst precursor is exposed to conditions so that the crude oil product has T and & TAN of the feed. N is taken as the pure crude oil. The invention also provides a method for producing crude oil products, including: -Contacting one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at a pit and 0.101 Mpa, and the primary oil feed has a viscosity of at least 37 ° (1 崎), The crude feed has an API specific gravity The at least one catalyst comprises one or more metals in the sixth table of the Periodic Table, one or more metals in the Period II, or one or more compounds of the metal, or a mixture thereof; and controlling the contact conditions so that the crude oil product has … 7. The crude oil with a viscosity of up to 90% is fed at 37.8. (: The viscosity of the crude oil product, and the crude oil product having an API gravity of 70 to 13% of the API gravity of the crude oil feed, wherein the API gravity is determined by ASTM method D6822, and the viscosity is measured by astm method D2_ The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25 ° (: and 0.101 MPa). The crude oil feed has a TAN of at least 0.1, and the one or more catalysts include: one or more catalysts containing vanadium, one or more vanadium compounds, or a mixture thereof; and an additional catalyst, wherein the additional catalyst The medium contains one or more Column 6 metals, 17 200535223, or one or more compounds of Column 6 metals, or a combination thereof, and controlling the contact conditions so that the crude oil product has a crude oil feed with a TAN of up to 90% TAN 'where TAN is determined by ASTM method D664.

The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feedstock or a plurality of catalysts to produce a total product containing a crude oil product, and -4 crude oil products at 25. . And 〇1〇1 Mpa is a liquid mixture, the crude oil feed has at least 0 · i # TAN; hydrogen is generated during the contact; and the contact conditions are controlled so that the crude oil product has a TAN for the crude oil feed at most, Among them, TAN is determined by AS Dm ^ d664. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25 ° C and 0.101 MPa, The j oil feed has a TAN of at least (M, the at least one catalyst contains vanadium, or a vanadium compound, or a mixture thereof; and controlling the contact conditions so that the contact temperature is at least 20 (rc, such that the crude oil product has tan Up to 90%

The TAN of the crude oil feed, where TAN is determined by ASTM method D664. The present invention also provides a method for producing a crude oil product, which comprises: contacting the crude oil feed with one or more catalysts to produce a total product containing a crude oil product Wherein the crude oil product is a liquid mixture at 25 ° C and 0.101 MPa, the crude oil feed has a TAN of at least 0.1, the at least one catalyst comprises Kay, one or more vanadium compounds, or a mixture thereof; the supply contains Hydrogen gas source 'long-distance gas flow is supplied to the deer in the direction opposite to the flow of the crude oil feed, and the contact conditions are controlled so that the crude oil product has a TAN of tan with a maximum of 90% of the 18 200535223 crude feed. Determined by ASTM ^ feed. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25t and 0 · ⑻Mpa, and the crude oil The feed has a total of at least 0.02 grams per gram of crude feed

Nl / V / Fe content 'the at least one catalyst contains y- or y' compounds or a mixture thereof ', the y-k catalyst has a pore size distribution with a median pore size of at least $ 80a; and control the contact conditions so that the crude oil The product has a Ni / v / Fe content of the crude oil feed with a total Qin / V / Fe content of up to 90%, where the Ni / V / Fe content is determined by ASTM method D5708. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25 ° C and G.1G1 paper The at least one catalyst contains vanadium, one or more vanadium compounds, or a mixture thereof, and the crude oil feed contains—or more organic acids—or more alkali metal salts, one or more organic acids—or more earth test metals. Salt, or a mixture thereof, the crude oil feed has a total metal and earth metal content in the form of an organic acid metal salt of at least 10,000 grams per gram of crude oil feed; and controlling the contact conditions so that the crude oil The product has organic acid metal salt morphology and soil test metal total of 3 miles. 9G% of the organic acid metal salt morphology and soil test metal in the crude oil feed contains rhenium, pot 5 g The content of alkali metals and alkaline earth metals in the form of f organic acid metal salt is determined by ASTM method D13 [8]. The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing the crude oil product, 19 200535223 wherein the crude oil product is at 25 ° C and 0.1 MPa The following is a liquid mixture. The crude oil feed comprises one or more organic acid one or more metal test salts, one or more organic acid one or more alkaline earth metal salts, or a mixture thereof. The crude oil feed is per gram of crude oil feed. The total metal content and metal content in the organic acid metal salt form of at least 0.00001 grams in the at least one catalyst having a pore size distribution with a median pore size ranging from 90 A to 1 80 A, and at least 60% of the pore size distribution The total number of pores has a pore size in the range of 45 A median pore size, where the pore size distribution is determined by ASTM method D4282; and the contact conditions are controlled so that the crude oil product has an organic acid metal salt form of metal and earth metal The total content of alkali metal and alkaline earth metal in the form of organic acid metal salt of the crude oil feed is more than 90%, and the test metal and alkaline earth metal in the form of organic acid metal salt contain Measured by ASTM method based D1 3 1 8. The invention also provides a method for producing a crude product, comprising: contacting a crude feed with one or more catalysts to produce a total product containing a crude product, wherein the crude product is a liquid mixture at 25 ° C and 0.101 MPa, the The crude feed has a total of at least 20,000 grams per gram of crude feed / V / Fe § '. At least one catalyst has a pore size distribution with a median pore size in the range of% a to 1 A, and at least 60% of the total number of pores in the pore size distribution has a pore size in the 45 A median pore size range, where the pore size distribution It is determined by ASTM method D4282; and the contact conditions are controlled so that the crude oil product has a total Ni / V / Fe content of 90% of the Νί / ν / ^ of the crude oil feed containing 1, where Ni / V / Fe content is measured by ASTM method D57708. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, 20 200535223

The Liaoyuan A product is a liquid mixture under the pit and G1G1 milk. The crude oil feed has at least one total alkali metal and alkaline earth metal content in the form of an organic acid metal salt in the mother gram crude oil feed. The at least one The catalyst has a pore size distribution with a median pore size of at least 18A, which is measured by the method D4282. The catalyst has one or more metals including the sixth column of the periodic table: one or more of column 6 of the periodic table. The pore size distribution of metal or compounds, or mixtures thereof; and controlling the contact conditions so that the crude oil product has the form of an organic acid metal salt, and the metal earth metal content of the organic acid metal in the crude oil feed is at most 90% The metal content and soil content in salt form, among which the organic acid metal salt form, metal and soil content are determined by AS TM method D1 3 1 8.

The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25 ° C and (MG1 MPa, The crude oil feed comprises one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof. The crude oil feed has at least 0.00001 grams per gram of crude oil feed. Total content of alkali metals and alkaline earth metals in the form of metal salts of organic acids. The at least one catalyst has a pore size distribution with a median pore size of at least 230A. It is measured by aSTM method D4282. The catalyst has a Pore size distribution of one or more metals, one or more compounds of one or more metals in column 6 of the periodic table, or a mixture thereof; and controlling the contact conditions so that the crude oil product has a total alkali metal and alkaline earth metal content in the form of an organic acid metal salt At most 90% of the crude metal in the form of organic acid metal salts in the metal test and soil test metal contains 21 200535223 in which there are branches S 夂 metal salt form evil The metal and soil test metal-containing dendrites are determined by the ASTM method D 1 3 1 8. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a crude oil-containing product The total product of which the crude product is a liquid mixture at 25 ... and 0.101 MPa, the crude feed has a total Ni / V / Fe content of at least 0.00002 grams of Ni / V / Fe per gram of crude feed, The at least one catalyst has a pore size distribution with a median pore size of at least 230A, which is determined by ASTM method D4282: the catalyst has one or more metals including a column of the Periodic Table, one or more metals of the second stage of the Periodic Table. The pore size distribution of one or more compounds, or mixtures thereof; and controlling the contact conditions so that the crude oil product has a Ni / V / Fe content of the crude feed of up to 90% total N, V / & / Determined by ASTM method D5708. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is And 0.101 M Under Pa is a liquid mixture. The crude oil feed contains—or more than one organic acid—or more metal test salts, or one or more alkaline earth metal rhenium, or a mixture of organic acids. The crude oil is fed into each gram of crude oil. The total content of metal-testing and soil-testing metals with at least 0 0000i i of organic acid metal in the material 'Xiao at least — the catalyst has a pore size distribution of median pores L to y 9GA, which is determined by ASTM method D4282, The catalyst has a total weight of 0.0001 g to 0.3 g of molybdenum, one or more molybdenum compounds 'or a mixture thereof' and U contact conditions in each gram of catalyst at a weight of 翻. The crude oil product has organic acid metal 22 200535223 salt form of alkali metal and alkaline earth metal with a total content of up to 90% of the organic acid metal salt form metal and soil test metal content in the crude oil feed, and the organic acid metal salt form The content of alkali metals and alkaline earth metals was determined by the Ris'tm method D 1 3 1 8. The present invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 t: and 0.1 (MPa) Liquid mixture, the crude feed having at least 0.3 @ TAN and the crude feed having a total Ni / V / Fe content of at least 0.00002 grams per gram of crude feed, the at least one catalyst having a median pore size of at least 90A The pore size distribution of the catalyst is determined by AST method D4282. The catalyst has a total content of 0.0001 to 0.3 g of molybdenum, one or more molybdenum compounds per gram of catalyst, based on the weight of molybdenum, or A mixture; and controlling contact conditions so that the crude oil product has a TAN of the crude oil feed with a TAN of up to 90% and the crude product has a Ni / V / of a crude oil feed with a total Nl / V / Fe content of up to 90% Fe content, where Ni / V / Fe content is measured by ASTM method d5708, and TAN is measured by ASTM method D664. The invention also provides a method for producing a crude product, comprising: contacting a crude feed with one or more catalysts to produce a total product containing a crude product, wherein the crude product is a liquid mixture at 25 ° C and 0.101 MPa, the The crude oil feed comprises one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, the crude oil feed having at least 0.000 per gram of crude oil feed. Total content of alkali metals and alkaline earth metals in the form of metal salt of organic acid, the at least one catalyst package 23 200535223 2: (a) one or more metals in column 6 of the periodic table, one of the sixth column of the periodic table One or more compounds of one or more metals, or a mixture thereof; and (b) week = one or more metals listed in the table, one or more of the first table of the Periodic Table = gold-of one or more compounds' or a mixture thereof, The molar ratio of the total amount of the 10th metal to the total amount of the 6th metal is controlled within the range of i 1 10 so that the crude oil product has the total content of alkali metals and alkaline earth metals in the form of organic acid metal salts. Up to 9 〇 % Of the crude oil feed = metal gold and soil metal content in the form of acid gold f salt, and the content of organic acid metal, metal and alkaline earth metal in the form are measured by the ASTU method DUU. The invention also provides crude oil products A method comprising: contacting a feedstock with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25t: and 0.11 Mpa, and the crude oil feed has The total Ni / V / Fe content is at least 002 grams of Ni / V / Fe per gram of crude feed. The at least one catalyst contains: ⑷ periodic table f 6-or more metals, the sixth table of the periodic table. -Or more metals ^: or more compounds' or mixtures thereof; & (b) of the Periodic Table. The -or multiple metals' periodic table 帛 10. One or more compounds of one or more metals, or a mixture thereof, in which the molar ratio of the total metal of the 10th to the total metal of the 6th is at! within the range of δ to 0; and controlling the contact conditions so that the crude oil product has a Ni / V / Fe content of the crude oil feed with a total Ni / V / Fe content of up to 90%, of which Ni / V / Fe The content is determined by -M method D5708. The present invention also provides a method for producing a crude oil product, comprising: making crude oil 24 200535223

The content of golden tincture in the soil was determined by ASTM method D1 3 1 8. The present invention also provides a method of producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25. (; And 0.10 MPa is a liquid mixture, the

The feed is contacted with- or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is in a state of mind mixture at a pressure of 0.1 MPa, and the crude oil feed contains one or more organic acids Alkali metals, one or more organic acids, one or more alkaline earth metals M, or mixtures thereof. The total amount of alkali metals and alkaline earth metals in the form of organic acid metal salts of at least 0.00001 i per gram of crude feed from the feed. The content of the one or more catalysts includes: (a) the first catalyst, the first catalyst in each gram of the first catalyst, based on the weight of the metal, containing 6 to 6 grams of the periodic table --Or more metals, in column 6 of the Periodic Table-or more than one of the following: or two or a mixture of them; and (b ... catalysts, the second catalyst at the second catalyst per gram In the medium, based on the weight of the metal, it contains at least 0.02 grams of one or more metals in the sixth table of the periodic table, column 6 in the periodic table-one or more compounds of the plurality of metals, or a mixture thereof; and controlling the contact conditions; So that the crude oil product has the form of an organic acid metal salt The total content of alkali metals and alkaline earth metals is 90% of the alkali metal and alkaline earth metal content in the form of organic acid metal salts in the crude oil feed. The alkali metal crude oil feed in the form of organic acid metal salts contains one or more organic acids. One or more alkali metal salts, one or more organic acid, one or more alkaline earth metal salts, or mixtures thereof, the crude oil feed has at least 0.0001 grams of organic acid metal salt-shaped bases per gram of crude oil feed Total content of metals and alkaline earth metals. The at least one catalyst contains at least 0.001 grams of one or more metals in the sixth column of the Periodic Table, and one or more of the sixth column in the Periodic Table per 25 200535223 grams of the catalyst. One or more compounds of metal 'or mixtures thereof, and controlling the contact conditions so that the liquid space velocity in the contact zone exceeds 10 h-1, and the crude oil product has the total content of alkali metals and alkaline earth metals in the form of metal salts of organic acids The metal test and soil test metal in the form of organic acid metal salt in 90% of the crude oil feed contains: 'The metal test and soil test metal content in the form of organic acid metal salt is Determined by ASTM method D 1 3 1 8. The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 艽And a liquid mixture at 0 · 101 MPa, the crude oil feed has a total Ni / V / Fe content of at least 0 00002 grams per gram of crude oil feed, the at least one catalyst in That contains at least 0.001 grams of one or more metals in column 6 of the Zhous table, one or more compounds of metal or metals in the sixth table of the periodic table, or a mixture thereof; and controlling the contact conditions so that the contact zone makes a liquid space The speed exceeds 10 h 1, so that the crude oil product has a total Ni / v / Fe content of at most 卯% 6 miles' Danjia JNi / V / Fe

Determination of Ni / V / Fe ASTM Method D5708 without this crude feed. Ben Maoming also provides a method for producing a crude oil product, which includes: contacting eyebrows with—or multiple catalysts to produce a total product containing a crude oil product wherein the crude oil product is at 2 5 ° C and η 1 Λ ^ · 1 01 MPa The following is a liquid mixture. The crude oil feed is per gram of crude oil feed. The corpse has a content of at least 0.0001 grams of milk with oxygen and a sulfur content of at least 0.0001 * grams of sulfur. A catalyst comprising 26 200535223 one or more metals of Table 6 of the Periodic Table, one or more compounds of one or more metals of Table 6 of the Periodic Table, or a mixture thereof; and controlling contact conditions so that the crude oil product has an oxygen content The oxygen content of the crude oil feed is at most 90% and the crude product has a sulfur content of 70 to 130% of the crude oil feed, wherein the oxygen content is determined by ASTM method E385, The sulfur content is measured by ASTM method D4294. The present invention also provides a method for producing a crude product, comprising: contacting a crude feed with one or more catalysts to produce a total product containing a crude product, wherein the crude product is a liquid mixture at 25 ° C and 0.101 MPa, the The crude oil feed has a total NW / Fe content of at least 20,000 grams per gram of crude oil feed, and a sulfur content of at least 0.001 grams of sulfur, the at least one catalyst comprising the sixth table of the periodic table One or more metals in the column, one or more compounds of one or more metals in column 6 of the periodic table, or a mixture thereof; and controlling the contact conditions so that the crude oil product has a total Ni / V / Fe content of the crude oil at most for the crude oil. The Ni / V / Fe content of the feedstock, and the crude oil product has a sulfur content of 70 to 130% of the sulfur content of the crude oil feed, wherein the content is determined by AST ^ D measurement and Sulfur content was measured by the astm method D4294. The present invention also provides a method for producing an oil product for production. The method includes: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 ° Γ Λ 1 m λ / γγ »^ Mu and a liquid mixture at 0.101 MPa, the crude oil feed contains one or more alkali metal salts of one or more organic acids, one or more organic acids, or ^ Alkaline earth metal salt, or a mixture thereof, the crude oil feed has at least 0.00001 grams of organic acid metal per gram of crude oil feedstock. 27 200535223 Total alkali and alkaline earth metal content in salt form, residue content A residue of at least 0.1 g, the at least one catalyst comprising one or more metals in column 6 of the periodic table, one or more compounds of one or more metals in column 6 of the periodic table, or a mixture thereof; and controlled contact Conditions such that the crude oil product has a total alkali metal and alkaline earth metal content in the form of organic acid metal salt of up to 90% of the alkali metal and alkaline earth metal content in the form of organic acid metal salt in the crude oil feed, and The crude product is made to have a residual content of 70 to 130% of the crude feed, wherein the content of alkali metal and alkaline earth metal in the form of a metal salt of an organic acid is determined by ASTM method D1318, and the content of the residue is It was measured by ASTM method D5307. The invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 25t and 0.101 MPa, and the crude oil is fed It has a residue content of at least 0.1 g per gram of crude oil feed, and a total Ni / V / Fe content of at least 0.00002 g. The at least one catalyst contains one or more metals in the sixth table of the periodic table. Table 6 lists one or more compounds of one or more metals, or a mixture thereof; and controlling the contact conditions so that the crude oil product has a total Ni / V / Fe content of up to 90%, and the raw Ni / V / Fe content, and the crude oil product has a residue content of A 70 i 130% of the residue content of the crude oil feed, wherein the content is determined by the ASTM method 05708 and the residue ^ amount is It was measured by ASTM method D5307. The invention also provides a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing the crude oil product: 28 200535223 wherein the crude oil product is at 25 ° C and 0. 101 MPa Liquid mixture, the crude oil feed comprising one or more alkali metal salts of one or more organic acids, one or more alkaline earth metal salts of one or more organic acids, or a mixture thereof, the crude oil feed having At least 0.1 g of vacuum gas oil ("VGO") content, 0.0001 g of total metal and alkaline earth metal content in the form of an organic acid metal salt, the at least one catalyst comprising one or more metals in column 6 of the periodic table ' One or more compounds of one or more metals' or a mixture thereof in column 6 of the periodic table; and controlling the contact conditions so that the crude oil product has the form of an organic acid metal salt and a total content of alkali metals and soil test metals of at most 90% of Alkali metals and alkaline earth metals in the form of metal salts of organic acids in the crude oil feed and make the crude oil product have a VGO content of the crude oil feed with a VG 0 content of 70 to 130%, which VGO content-based method for the determination by ASTM D53 07, and forms the alkali metal salts of organic acids and alkaline earth content-based assay by ASTM method D1318. Benmemin also provides a method for producing crude oil products, comprising: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is a liquid mixture at 251 and 0-101 MPa 'the The crude oil feed has a total Ni / V / Fe content of at least 200,000 grams per gram of crude oil feed, and a VG0 content of at least (M grams), the at least one catalyst comprising a Or more metals, one or more compounds of one or more metals' or a mixture thereof in column 6 of the Periodic Table; and controlling the contact conditions so that the crude oil product has a crude Ni / V / Fe content of up to 90% of the crude oil feed. And the VGO content of the crude oil product is 70% to 130% of the VGO content of the crude oil feed, and the vg0 content is 29 200535223. The system is determined by ASTM method D5307. The test method is determined by ASTM method D5708. The method is also provided by the present invention. It also provides a method for feeding materials and one or more products of contact welding. The method includes: contacting crude oil with a catalyst to produce a total product containing crude oil products. Product, where the crude product is at 25. Plant # n Μ 5 C and 0 · M1 MPa is a liquid mixture, the crude oil feed contains — # &# + ^ / one or more alkali metal salts of organic acids, one or more organic acids of one or more organic acids ^ double Earth metal salts, or mixtures thereof, are fed in each gram of crude oil feed, and the crude oil has at least 0 00001 grams of organic acid gold in the form of an organic acid gold test soil and a total metal test soil content, the at least one species The catalyst can be obtained by: combining the carrier with one or more metals in column 6 of the periodic table; "-or more metals" or more compounds in column 6 of the table, or a mixture thereof to produce a catalyst precursor Heating the catalyst precursor at a temperature below 400 ° C under one or more sulfur compounds ϋ to form a catalyst; and controlling the contact conditions so that the crude oil product has an alkali metal and alkaline earth in the form of an organic acid metal salt The crude oil feed with a total metal content of up to 90% ^: the content of alkali metals and alkaline earth metals in the form of organic acid metal salts, wherein the content of alkali metals and alkaline earth metals in the form of organic acid metal salts is determined by the ASTM method. Production of crude oil products is also provided The method comprises: contacting a crude oil feed with one or more catalysts to produce a total product containing crude oil products, wherein the crude oil product is a liquid mixture at 25 ° C and 0.101 MPa, and the crude oil feed is The feed has a total milk / V / Fe content of at least 200000 grams, and the at least one catalyst can be obtained by: loading one or more metals with column 6 of the periodic table, 6 之 之 — 戋 多 30 200535223 Kinds of soil genus or compound, or mixtures thereof, to produce catalyst precursors; in the presence of-or more sulfur-containing compounds, at lower than the total. heating the catalyst precursor at a temperature of c to form a catalyst; and controlling the contact conditions so that the crude oil product has an Nl / V / Fe content of the crude oil feed with the highest total / Fe content, where the rib content is Determined by method. The present invention also provides a crude oil composition which contains the following in each gram of crude oil composition .... at least 0.001 Naxi full stroke eighty-seven + Λ brother's / Foot distribution between 95 C and 2 6 0 C at 0.101 MPa Between the smoke; 5〇π γμ person > '' said Yigong, the main / 0.001 g boiling range distribution of hydrocarbons between 0. 10 Μρ & between 26 (TC and 32 generation; at least q toilet g Focheng distributed hydrocarbons between 32 Gt and ㈣.c at 0.ΗΗ MPa; and contained one or more catalysts greater than 0 g, but less than 0.01 g per gram of crude oil product. Ben Qiming also A crude oil composition containing the following is provided in each gram of crude oil composition: at least 0.01 g of sulfur, which is determined by the method of adding coffee; at least 0.2 g of residue, which is still by the ASTM method The composition has a weight ratio of at least 1.5 of the MCR content to (: 5 asphalt f content). The MCR content is determined by ASTM method D4530, and the q asphaltene content is determined by ASTM method D2007. The present invention also Provided is a method for producing a crude oil product, comprising: contacting a crude oil feed with one or more catalysts to produce a total crude oil product-containing The crude oil product is condensable at 25t and 0.11 MPa. The crude oil feed has an Mcr content of at least 0 Shekel per gram of crude oil feed. The at least one catalyst can be obtained by : Combining the carrier with one or more metals of the sixth table of the Periodic Table, or one or more compounds of one or more metals of the sixth table of the Periodic Table 31 200535223, or a mixture thereof to produce a catalyst precursor; In the presence of sulfur compounds, the catalyst precursor is heated at a temperature below 500 ° C to form a catalyst, and the contact conditions are controlled so that the crude oil product has an MCR content of the crude oil feed of up to 90% , Where the content is determined by ASTM method D4530.

The present invention also provides a method for producing a crude oil product, which comprises: contacting a crude oil feed with one or more catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 X: and 0.1 (1) MPa It can be condensed, the crude oil feed has an MCR content of at least 0.001 grams per gram of crude oil feed, the at least one catalyst has a pore size distribution with a median pore size in the range of 7〇A to i 8〇Α At least 60% of the total pores in the distribution have pore sizes in the 45 A median pore size range, where the pore size distribution is determined by the astm method D4282; and the contact conditions are controlled so that the crude oil product has an mcR of at most 90% The mcr of this crude oil feed, where MCr is borrowed, was determined by the astm method D 4 5 3 0. The present invention also provides a crude oil composition containing the following in each gram of composition: up to 0.004 grams of oxygen, as measured by ASTM method E385; up to 0.003 grams of sulfur, as measured by ASTM method D4294; And at least 0.3 g of residue as determined by ASTM method D5307. The present invention also provides a crude oil composition containing the following in each gram of composition. Up to 0.004 grams of oxygen, measured by ASTM method E385; up to 0.003 grams of sulfur, measured by ASTM method D4294; up to 0.04 grams. Experiential nitrogen, which is determined by ASTM method D2896; at least 0.2 g of residue 'which is measured by ASTM method D5307; and the composition has a TAN of up to 32,2005,35223 and 0.5, which is measured by ASTM method D664. The present invention also provides a crude oil composition containing at least 0.001 g of sulfur per gram of composition, which is determined by ASTM method D4294; to a residue of 0.2 g, which is measured by ASTM method D5307; The composition has a weight ratio of at least MCR content to c5 asphaltene content

And 4 compositions have a maximum of 0.5 TAN, where tan is measured by ASTM method D664 'MCR weight is measured by ASTM method D4530, and C: 5 weight of cyanine is measured by ASTM method 2007 Determination. In several specific examples, the present invention and those combining one or more methods or compositions of the present invention also provide the following crude oil feeds: (a) those that have not been processed, distilled and / or fractionated in a refinery; (b) contain carbon For components with a number greater than 4, the crude oil feed contains at least 0.05 grams of such a feed per gram of crude oil feed. '(C) includes by its part that it has a boiling point below 0.001 mpa. Range distribution, boiling range distribution between 100 ° c and 2000 ° c at 0.101 MPa, boiling range distribution between 200 ° C and 300 ° c at 0.101 MPa, and mediation at 0.101 MPa A boiling range distribution between 300 ° C and 400 ° C, and a boiling range distribution between 400t and 65 ° C at 0.101 MPa; (d) Contains at least: 0.001 per gram of crude oil feed Grams of hydrocarbons with a boiling range distribution below 0.1 CTC at 0.101 MPa, 0.001 grams of hydrocarbons with a boiling range distribution between 100 ° C and 200 ° C at 0.101 MPa, and 0.001 grams with a boiling range distribution of 0.101 MPa Hydrocarbons between 200 ° (: and 30.0%), 0.001 grams of smoke with a boiling range distribution between 0.3 ° C and 400C at 0.11 MPa ’And 0.001 grams of the hydrocarbon with a distribution in ο ″.〗 Hydrocarbons between 400 ° C and 650 ° C under Mpa; (e) Has at least 0, to 200535223

Less than 0.3, or a TAN in the range of 0.3 to 20, 0.4 to 10, or 0.5 to 5; (f) having an initial boiling point of at least 20 (rc at 0.101 MPa; (G) contains nickel, vanadium and iron; (h) contains at least 0.00002 grams of total Ni / V / Fe per gram of crude feed; ⑴ contains sulfur; ⑴ contains at least 0.0001 grams or 0.05 per gram of crude feed Grams of sulfur; (k) containing at least 0.001 grams of VGO per gram of crude feed; (1) containing at least 0.1 grams of residue per gram of crude feed; (m) containing oxygenated hydrocarbons (N) one or more alkali metal salts of one or more organic acids, one or more soil test metal salts of one or more organic acids, or a mixture thereof; (0) at least one zinc salt containing an organic acid; and / Or (P) at least one arsenic salt containing an organic acid. In some specific examples, the method or composition of the present invention also provides a method that can be used to remove naphtha and compounds more volatile than naphtha in crude oil. The obtained crude oil feed. In some specific examples, the present invention and those combining one or more methods or compositions of the present invention also provide a method for connecting the crude oil feed with one or more catalysts. A method for producing a total product containing a crude product, wherein the crude feed and

Both oil products have C5 asphaltene content and MCR content, and: The sum of the C5 asphaltene content of the oil feed and the MCR content of the crude feed is the sum of the C5 asphaltene content of the crude product and the MCR content of the crude product s', controlling the contact conditions so that S is at most 99% of s; and / or 0) making contact conditions so that the weight ratio of the MCR content of the crude product to the cyanine content of the crude product is 1.2 to 20, 1 3 $] 〇 From _ ^ U times to 19 In several specific examples, the present invention and one or more methods or compositions of the present invention also provide a hydrogen source, wherein the hydrogen source is: gas < 34 200535223 Hydrogen; (C) methane; (d) light hydrocarbons; (e) inert Ke # M v J h sex milk; and / or (f) mixtures thereof. In some specific examples, the present invention of the present invention is one, one, one. One or more of the methods or compositions of the present invention also provide a method of contacting a crude oil feed with a meter or catalysts to produce a total product containing crude oil products, J Nagu, where the crude oil feed Make contact in a contact zone located or connected to offshore equipment. In some specific examples, the present invention and the sister, one, or more of the methods or compositions of the present invention also provide a method, Gan-Go # is included in the presence of a gas and / or hydrogen source to make crude oil into And the contact conditions are controlled so that: (a) the ratio of state II hydrogen source to the crude oil feed is in each cubic meter of crude oil feed in contact with one or more catalysts; It is within the range of 5 to _standard cubic meters of gaseous hydrogen source; (b) #The selected net absorption rate of hydrogen is controlled by changing the partial pressure of hydrogen source; the absorption rate of hydrogen makes the crude oil product have a TAN of less than 0.3 The hydrogen uptake is less than the amount of hydrogen uptake that would cause substantial phase separation between the crude oil feed and the total product during the contact; (d) The selected absorption rate for 纟 in the cubic meter of crude feed is: To 30 or i to 8 " within the range of a hydrogen source of standard cubic meters; (e) the liquid space velocity of the gas and / or hydrogen source is at least 11 h1, at least 15 ^, or at most 2 ^; ⑺ Partial pressure of the gas and / or hydrogen source during the contact period; (g) The contact temperature is in the range of 50 to 500 t, and the total liquid space velocity of the gas and / or hydrogen source is 0.1 to 3 〇 In a busy environment, the total pressure of the gas and / or hydrogen source is in the range of 1.0 to 20 MPa. (H) The flow of the gas and / or hydrogen source is in the direction opposite to the flow of the crude oil feed; i) The crude oil product has an H / c of 70 to 130% of the original 'H / C from feed; (j) hydrogen absorbed by the crude feed in 35 200535223 crude feed per cubic meter Within a range of up to 80 and / or 丨 to 80 or 丨 to 50 standard cubic meters of hydrogen; (k) the crude oil product has a total Ni / V / Fe content of up to 90%, up to 50%, or Ni / V / Fe of the crude oil feed up to 10% contains 3: (1) The crude oil product has a sulfur content of 70 to u0% or 80 to 120% of the crude oil feed (M) the crude product has a Vg0 content of 70 to 130 % Or 90 to 110. /. The crude oil has a VGO content of 13% or 9 feeds; (n) the crude oil product has a residual content of 700 to 100% of the crude oil feed; (0) the crude oil product It has an oxygen content of up to 90%, up to 70%, up to 50%, up to 40%, or 10 at most. /. The oxygen content of the crude oil feed; (p) the crude oil product has an organic acid metal salt in the form of a total alkali metal and alkaline earth metal content of up to 90/0, up to 50%, or up to 10% of the crude oil feed Content of alkali metal and alkaline earth metal in the form of metal salt of organic acid; (q) during the contact, the P value of the crude oil feed is at least 15; (r) the crude oil product has a viscosity of up to 90 at 37 8 C %, Up to 50%, or up to 10% of the crude oil feed was 37.8. 〇: viscosity; (s) the crude oil product has an Aρι specific gravity of 70 to 130% of the crude oil feed; and / or ⑴ the crude oil product has a TAN of at most 90%, at most 50%, and at most 30%, the TAN of the crude oil feed taken as much as 20%, or at most 10%, and / or in the range of 0.001 to 0.5 '0.01 to 0.2' or 0.005 to 0.1. In several specific examples, the present invention and those combining one or more of the methods or compositions of the present invention also provide a method comprising contacting a crude oil feed with one or more catalysts and controlling the contact conditions to reduce organic oxygen-containing compounds. (a) Reduce the content of selected organic oxygen compounds so that the 36 200535223 has the oxygen content of the crude oil feed with a maximum oxygen content of at least ⑻, at least one of the compounds of the feed contains a carboxylic acid At least one compound of an organic oxygen compound containing an alkali metal salt of a carboxylic acid: at least one compound of an organic oxygen compound containing at least one acid, an at least one compound of an organic oxygen compound, and at least one compound containing an M compound of gold Wherein the metal includes one or more metals listed in the twelfth table of the periodic table; ⑴ = the oil product has a content of acid organic compounds in the oil into the oil containing a maximum of 90% of non-repellent organic compounds; and / or At least one of the oxygen compounds in the raw material is produced from organic oxygen compounds containing cyclic burning acid or non-slow acid. In several specific examples, the present invention and a combination of one or more of the present invention or a composition also provide a method comprising contacting a crude oil feed with a: media, wherein: at a first temperature, using The crude oil is contacted with at least one catalyst contact, and then contacted at a second temperature, and the connection is controlled so that the first-contact temperature is at least 3 times lower than the second contact temperature; under the conditions of hydrogen absorption and then at the first Under the condition of dichloromethane absorption, the temperature of the absorption 2 枓 is brought into contact with hydrogen. The temperature of the first absorption condition is at least 30t lower than the temperature of the second t; (c) at the first temperature, the crude oil feed bar is reduced. A contact at a certain temperature, followed by a contact at a second temperature. The contact is controlled so that the first contact temperature is lower than the second contact temperature at most. Nitrogen is generated. The nitrogen is generated during the contact, and the conditions are controlled so that the crude oil feed is sucked. At least-part of the generated chlorine; 油 ~ ~ oil into the contact with the first and second catalysts, the contact between the crude oil feed and the first catalyst to produce a crude oil product, where this crude oil product has 37 200535223 ~ more : Broad% of the crude oil TAN of the feedstock; (g) reaction in a stacked bed reaction; (h) contacting in an ebullated bed reactor; ⑴ contacting the two kinds of catalysts with additional catalysts after contact; ⑴ after contacting with hydrogen source Attachment: The material is in contact with the catalyst of the radon catalyst, or the mu catalyst; (k) Hydrogen is generated at a rate in the range of 1 to 20 standard cubic meters per cubic meter of feed. 产生 Gas is generated during the contact. , ^ ^ Φ, Nianfeng produces' ⑴, the material pressure is at least-in the presence of hydrogen generation, § Hai crude oil feed and additional catalyst

Then the gas flow is directed toward ... "", j, the contact conditions are opposite to the direction of movement and the flow of chlorine (). Hai Hai crude oil was fed at the first temperature, and at the second temperature, it was contacted with the force, and the catalyst and the catalyst were contacted, and then the temperature was at least lower than 苐 — ,,,,,,,,,,, and so on. · ⑻Hydrogen is generated during the contact, force: the medium and the branch are in contact with the additional catalyst, and the contact conditions are controlled so that the additional catalyst absorbs at least-part of the raw materials, and the crude oil is fed with the secondary catalyst. The second temperature after the second Guangxi is at least 18 generations. ㈣ contact, control the contact conditions so that

'In some specific examples', the present invention and the method or composition incorporating the present invention also provide contact with one or more catalysts, and two include contacting the crude oil feed with-containing oxidation-, oxidation " chemical " (B) The catalyst is a supported catalyst and:: This method also includes additional catalysts that have been treated before the vulcanization; (d) This is at least the following year; and / or (e) W — the catalyst has a dance life of at least 0.5. The catalyst is in a fixed bed or suspended in the original 38 200535223 oil feed. In the examples, the present invention and one or a method or composition of the present invention are also provided with a "Xiu Xi Chuan Gan Gan", which includes a crude oil feed and a catalyst as a supported catalyst or a block. Metal angle "M catalyst or bulk metal catalyst: ⑷ & contains one or more metals from 5 to 10 of the periodic table, so that M n meets one or more of the cousins in columns 5 to 10 of the month One or more compounds, followed by this compound; (b) in each gram of catalyst: at least 0.000 g, 0.0001 to 0.6 g, or 0.0001 to One or more metals on mi0, Periodic Table No .... Human & metal-or compounds, or mixtures thereof; 3 One or more metals in columns 6 to H) of Periodic Table, 6 to M of Periodic Table : Of-one or more metals-one or more compounds, or a mixture of one or more metals in columns 7 to 10 of the Periodic Table, one or more compounds of one or more metals in Periods 7 to ^, or Mixture; (e) One or more metals containing 0.000 .... 6g or 0.001 to 0 per gram of catalyst, such as Benji and Zhou ^ cousin 7 to 10, 7 to 10 bars: or more gold; H or more compounds' or mixtures thereof; (f) contains: 5 to 6 of the periodic table-or more metals, 5 to 6 周期 of the periodic table: / Or multiple compounds, or mixtures thereof; (g) comprising: 〆 or more metals of Periodic Table 5 'of the Periodic Table of the — or: metal-or ceremonial compounds, or mixtures thereof; (h) Per gram of touch: Contains at least 0.1_1 grams, 0.0001 to 0.6 grams, 0.001 to 0.3 grams, 0.005 = 0.1 grams, or 0.01 to 0.08 grams: 5th of the periodic table One or more metals that are blocked, one or more compounds of one or more metals in column 5 of the Periodic Table, 39 200535223 or mixtures thereof; (i) No. 6 of the Schedule—or column 6 of the multiple tables—or more Metals, peripheries '· 〇 ·) in each gram of catalyst contains: 〇:-or multiple compounds' Woqi mixed gram, 0.005 to 〇 "g, 〇〗 .01 to 0.6 grams, 0.00 to 0.3 Or one or more metals, No. 01 of the sixth table of the periodic table: ^ A compound of the sixth table of the periodic table, or a mixture thereof, of a metal of eight or five species-or more than one, or more than one, the first table of the periodic table: Cousin cousin 10-or more gold or mixtures thereof, ⑴ in every 2 touches: one or more compounds of a metal, to 0.0001 ^ 0.6, to 0.3 g: Periodic Table 1Q_g or 0.001 bar- Or more metals "or more than 10 metals of the Periodic Table of the Elements, or compounds, or mixtures thereof; or-or more compounds, or mixtures or more nickel compounds, or mixtures thereof, or H ^) 3 Cobalt times a variety of cobalt ... Human (P) contains Shao,-or a variety of indium compounds, s eight. (Q) from 0.001 to 0.3 g or 0.005 per gram of catalyst ^ ^ ^ ^ ^ to 0 1 h 3: * head, one or more pin compounds, or mixtures thereof; (Γ) ) == or more crane compounds, or mixtures thereof; (S) in each = :: compound; ⑴ contains-or more metals in the sixth table of the periodic table-and one or more metals in column 10, / cousin Metal blocks and metal blocks are 1 to 5; ⑷ contains column 15 of the periodic table-or more elements-column 15 of the periodic table-or multiple elements-or more compounds, or mixtures thereof; ⑺ per gram The catalyst contains .0 (Η to 0.06 grams of: week's table 15 or more elements, column 5 of the periodic table-or evening elements-or more compounds, or mixtures thereof ; (W) discs, or -200535223 kinds of lin compounds, or mixtures of them, Cantonese, +-Mouthpieces, 00 contains up to 01 grams of alpha alumina per gram of catalyst; and / or () prepared in the mother The gram catalyst contains at least 0.5 Θ oxidation. In some specific examples, the invention can be used for eight generations. Shili / ,,,, σ & One or more methods or compositions of the invention are also A method for forming a catalyst is provided, which includes combining a carrier with one or more metals to form a carrier / metal mixture, wherein the carrier comprises Θ-oxidized at a temperature of at least 400 ° r 66, where Tianr nr M accounts for ^^ C Heat treatment of theta alumina support / metal mixture at a plate temperature, and further comprising: (i) combining the support / metal mixture with water to form a paste, and extruding the paste; (b) at a temperature of at least 800 t Obtaining the oxide by heat-treating the oxide; and / or making the touch: vulcanizing. In some specific examples, the present invention and the method or composition combining the present invention also provide a method comprising: The crude oil feed is in contact with one or more catalysts, wherein the pore size distribution of the one or more catalysts has: at least 60 people, at least 90 A, at least 180 A, at least 200 A, at least 230 people, at least 300 people, up to 230 people, up to 500 people, or 90 to 180 A, 100 to 140 A, 120 to 130 A, 230 to 250 A, and 180 to 5 〇〇a, 230-500a; or within the range of 60-300A Pore size; (b) at least 60% of the total number of pores have a pore size in the range of 45A, 35A, or 25 to the median pore size; (c) at least 60 m2 / g, at least 90 m2 / g, at least A surface area of 100 m2 / g, at least u0m2 / g, at least 150 m2 / g, at least 2000 m2 / g, or at least 22 m2 / g; and / or (d) at least The total volume of all pore diameters is 0.3 cm3 / g, at least 0.4 cm3 / g, at least 0.05 cm / g ', or at least 0.7 cm3 / g. 41 200535223 In several specific examples, the present invention and one or more of the present invention are combined, and the composition or the composition also provides a method, which comprises contacting the crude oil feed with one or more supported catalysts, wherein the carrier · (A) contains alumina, oxygen silica, silica-alumina, titanium oxide, hafnium oxide, magnesia, or a mixture thereof, and / or zeolite; (b) contains alumina and / or 5 oxide Aluminum; (C) in: grams of support containing at least 0.5 grams of yttrium oxide; rhenium in each gram of support-up to 0.3 grams or at least 0.5 grams of rhenium alumina; (e) containing oxide Aluminum, gamma aluminum, delta alumina, Θ alumina, or mixtures thereof; (f) containing up to 0.1 g of alpha alumina per gram of support. In a few specific examples, the present invention and those who combine one or more T-methods or compositions of the present invention also provide a vanadium catalyst: (a) a pore size distribution with a median pore size to 60A; (b) a carrier This support contains θ alumina, and the vanadium catalyst has a pore size distribution with a median pore diameter of at least 60A; (c) contains one or more metals in column 6 of the periodic table, one of: or column 6 of the periodic table One or more compounds, or mixtures thereof; and / or containing up to 0.001 grams per gram of catalyst: one or more mongolians in the periodic table, column 6 of the periodic table—or multiple metals—or Multiple compounds, or mixtures thereof. In the specific example of the right stem, the present invention and a combination of one or more methods or compositions of the present invention also provide a crude oil product having: (a) a maximum of 10.0.001 to 0.5, 0. 1 to 0.2; or TAN to 0.005 to 0.1; (b) up to 0,000009 g of organic acid metal salt per gram of crude oil product ~ metalloid and earth test metal, (c) At least 0.00002 grams of Nl / V / Fe per gram of crude product; and / or at least one catalyst greater than 42 200535223 0 grams, but less than 0.005 grams per gram of crude product. In some specific examples, 'The present invention and those who combine one or more of the present inventions also provide—or one or more metal test salts of organic acids' or one or more metal test salts of organic acids, Or a mixture thereof, wherein: the at least one alkali metal is lithium, sodium, or potassium; and / or the at least one alkaline earth metal is magnesium or calcium. In some specific examples, the present invention and those who combine one or more methods or compositions of the present invention also provide a method comprising contacting a crude oil feed with one or more catalysts to produce a total product containing crude oil products. The method further includes: (i) combining the crude oil product with the same or different crude oil feed to form a blend suitable for transport; (ii) combining the crude oil product with the same or different crude oil feed to form a suitable crude oil A blend of processing equipment; ⑷ > the crude product; and / or ⑷ fractionating the crude product into one or more fractions, and producing transportation fuel from the at least one fraction. In several specific examples, the present invention and those combining one or more methods or compositions of the present invention also provide a supported catalyst composition, which: (a) contains at least 0.3 g or at least 0 per gram of carrier. 5 grams of Θ alumina; (b) containing delta alumina in the carrier; (c) containing up to 0.01 g of alpha oxide per gram of the carrier; (d) having a median pore size of at least 23 alpha Pore size distribution; (0 pores having a pore size distribution having a pore volume of at least 0.3 cmVg or at least 0.7 cm3 / g; (f) having a surface area of at least 60 m2 / g or at least 90 m2 / g; (g) containing One or more metals from 7 to 10 of the periodic table, one or more compounds of one or more metals from columns 7 to 10 of the periodic table, or mixtures thereof; 43 200535223 Containing periodic _-or multiple metals-or: : Attack on a variety of metals, 克 J grams of the fifth block of the periodic table or 0.001 to 0.3 斿 · ^ A variety of 5th block metals, see at a glance. One or ^ 4th species of the 5th column metal compound, or i ,, a ; Ω contains one or more metals of the sixth or periodic σ ifJ ^ μ 谰, one or more of the metals in column 6 of the periodic table ^ General Kigou Raptor—a compound, or a mixture thereof; (k) containing 0.001, to 0.6 g, or 0.001 to 0.3 g in the mother gram catalyst: 〆 or more of the sixth metal, Yiwuxi

wn ^ Column 6 metal compounds, or mixtures thereof, (1) contains hunger, a vanadium compound, or a mixture thereof; containing molybdenum, one or more molybdenum compounds, A mixture thereof, ( η) Contains one or more tungsten compounds, or rewarming human fly, and this compound; (0) Contains cobalt, one or more cobalt compounds, or a mixture thereof, and / or (P) contains nickel, one or Various nickel compounds' or mixtures thereof. In some specific examples, the present invention and the method or composition combining the present invention also provide a crude oil composition, which has a maximum of 0.5, a maximum of 0.5, a maximum of 0.3, or a maximum of 0.1 m ( b) Contains at least 0 gram of boiling range distribution hydrocarbons between 95 C and 26 ° C. under Q igi Mpa in each gram of composition; at least 0.001 g, at least 0.05 g, or at least 0.001 grams of hydrocarbons with a boiling range distribution between 26〇π and 320 ° C at 0101 MPa; and at least 0.001 grams of boiling range distributions between 320 ° C and 650 ° C at Μρ &Hydrocarbons; (c) contains at least 0.0005 grams of test nitrogen per gram of composition; (d) contains at least 0.001 grams or at least 0.01 grams of total nitrogen per gram of composition; and / or (e) in Each gram of composition contains a maximum of 0. 0 0 0 0 5 grams of total nickel and hunger. 44 200535223 In some specific examples, the present invention and a combination of one or more methods or compositions of the present invention also provide a crude oil composition Material, which contains one or more catalysts, the at least one catalyst: (a) has a median pore size of at least 18A, and a maximum of 50 0 A ′ and / or a pinch distribution at 90 to 180 A, 100 to 14 A, and 120 to 130 A; (b) having a median pore size of at least 90 a, More than 60% of the total number of pores have a pore size in the range of 45 persons, 35 pores, or 2 median pore sizes; ⑷ has a surface area of at least 100 m2 / g, at least g, or to J 220 m2 / g; ⑷Contains a carrier; the carrier contains oxidized oxide, oxidized stone, oxidized stone factory oxide, oxidized Γ ::, :: stone 'and / or mixtures thereof ... containing the metals or metals, or metals -One or more compounds of 10 columns-or more than one or more of the genus, M; (f) one or more different mixtures of compounds or compounds containing the fifth or more compounds of the periodic table; () Name ^ 0.0001 grams:-or more of the 5th metal, the catalyst contains at least a compound 'or a mixture thereof; (h) 5 or more metal metals, the sixth table of the periodic table. / Table 6 One or more or a mixture thereof; ⑴ in each gram of contact: 1 or more compounds of the genus, or 6th metal, or one or more of the first: The substance '⑴ contains a compound belonging to the tenth block of the periodic table, or a mixture of ten or more metals—or more than one of the two: a kind of metal' and / or the element ⑷ of the periodic table contains 15th _4 in the column, or a mixture thereof; and elements, 15 or more compounds of the periodic table Dragon, 龙 Ml · Second specific examples of specific specific examples of mixtures of the present invention, the present invention 45 200535223 征 I Combined with the features of other embodiments of the invention. For example, the features of one embodiment of the present invention may be combined with the features of other embodiments. Any of the methods and systems in further specific examples are obtained. Specific examples in further specific examples. [Embodiment] The terms used in the present invention will be described in more detail below. The 'crude oil product may be added to specific specific examples described herein with the additional features described herein. In this article

"ASTM" means the American Standard for Materials Testing.

"API specific gravity" means API specific gravity at 15.5 ° C (60 ° F). API specific gravity is determined by ASTM method D6822.… The percentage of atomic hydrogen and atomic carbon of crude oil feed and crude product are determined by ASTM method D5291 Determination. Unless otherwise stated, the crude oil feed, total products, and / or cruciform distribution of crude oil products were determined by ASTM method D5307.

5 Limonella refers to pentane insoluble asphaltenes. The C5 asphaltene content is determined by ASTM method D2007. "" Column X metal refers to one or more metals in column X of the periodic table or _ or more metals of the periodic table-or more compounds, where X 仏 corresponds to the number of columns in the periodic table (such as i To 12). For example, "the metal, refers to one or more metals of the periodic table and / or column 6 of the periodic table, or multiple metals-or compounds. "Xia Xia 70 element" refers to one or more elements of the Xth column of the periodic table, 46 200535223 / or one or more compounds of one or more elements of the Xth column of the periodic table, where X is the number corresponding to the number of the periodic table ( For example, 13 to 18). For example, "Element in column 15" refers to one or more compounds in column 15 of the periodic table and one or more elements in column 15 of the periodic table. Within the scope of this application, #, the metal weight of the periodic table, the metal compound weight of the periodic table, the element weight of the periodic table, or the elemental-octyl compound weight of the periodic table are calculated based on the metal weight or element weight. For example, if each gram of catalyst is used (M grams of MoO3, the calculated weight of metal in the catalyst is 0.067 grams per gram of catalyst. "Content" refers to the total weight of the substrate The weight of ingredients in a weight fraction or weight percentage matrix (eg, crude oil feed, total product, or crude product). "Wtppm," means parts per million by weight. Crude oil feed / total product mixture, , # ≫ Initially, this mouth is a mixture that comes into contact with the catalyst during the next day during processing. "Crane" refers to the hysteresis distribution between 0 and ⑼M W3C (650 Jr) at 0.ΗΗ MPa. The smoke content of Germany is determined by μ observation method D5307. "Heteroatom" refers to oxygen, nitrogen, and / or sulfur contained in the molecular structure of hydrocarbons. Heteroatom content is E385 for oxygen by ASTM method, D5 762 for total gas and D4294 for sulfur "The total amount of tentative nitrogen refers to those with less than 40 secondary compounds. The tentative nitrogen (,,,) is determined by phantom ..." Nitrogen "Source" means fish; 5 / $ / μ person or chemical product and / or reacts in the presence of crude oil feed and catalyst to the shoulder oil & The compounds in the department provide argon compounds. 47 200535223 Hydrogen sources can include, but are not limited to, hydrocarbons (such as ^ to & ^, propylene, butadiene), water, or mixtures thereof. Can be divided into several groups, B Calculate the amount of net chlorine provided by the compounds in the crude oil feed. S Equilibrium to estimate "flat plate crushing strength," refers to the crushing catalyst: the crushing crushing strength is determined by ASTM method D4179. Plate resistance / LHSV, refers to the volume liquid feed rate / catalyst total volume, which is expressed in small% (hr). The total volume of the catalyst is calculated by the media volume in the total contact area, as in this article. The person.

"Liquid mixture" refers to a composition that is a liquid at a standard temperature and a constant pressure (MPa, hereinafter referred to as "STp"), a β-human compound, or is contained in STP. A combination of one or more compounds in a liquid state and one or more compounds in a solid state. Into the "Periodic Table," means ... the periodic table specified by the International Union of Pure and Applied Chemistry (IUPAC) in January. "Metals in the form of metal salts of organic acids, refer to alkali metals, alkaline earth metals,

:: arsenic, chromium 'or a combination thereof. The metal content of the organic acid metal salt was determined by ASTM method D1318. "Micro-residual carbon, (" MCR ") content refers to the amount of residual carbon left after evaporation and pyrolysis of the substrate. MCR content is determined by ASTM & D453〇." Naphtha "refers to the boiling range distribution Smoke composition between 0.11 Mpa 卞) and air. Naphtha content was determined by ASTM method D5307. "Ni / V / Fe 'means nickel, vanadium, iron, or a combination thereof.

The Ni / V / Fe-containing I '' refers to the content of nickel, vanadium, iron, or a combination thereof. 48 200535223

The Ni / V / Fe content is measured by ASTM method D5708. ‘‘ Nm3 / m3 ’’ means standard cubic meters of gas per cubic meter of crude oil feed. The "non-carboxylic acid-containing organic oxygen compound" means an organic oxygen compound having no carboxyl group (-co2-). Non-weileric acid-containing organic oxygen compounds include, but are not limited to, ethers, cyclic ethers, alcohols, aromatic alcohols, ketones, aldehydes, or combinations thereof, which do not contain a carboxyl group. By "non-condensable gas" is meant a component that is gaseous under STP and / or a mixture of these components. "P (peptide) value" or "P value" means a value indicating the tendency of asphaltenes to flocculate in a crude oil feed. The measurement of the P value is described by JJ Heithaus in ⑽ / ⑽r ^ / (9 / Institute of Petroleum, Vol. 48? Number 458? February 1962, pp. 45-33 "Measurement and Significance of Asphaltene Peptization". "Aperture," "median pore size," and "pore volume" refer to pore size, median pore size, and pore volume as measured by ASTM method D4284 (mercury porosity method at a contact angle of 140 °). Micromeritics® A9220 instrument (Micromeritics Inc., Nor cross Georgia, USA.) Can be used to determine these values. "Residue" means a component with a boiling range distribution above 538 ° C (1000 ° F), as measured by ASTM method D5307. "SCFB" refers to the standard cubic feet of gas in a barrel of crude oil feed. The "surface area" of a catalyst is determined by ASTM method D3663. "TAN" refers to the total acid value in grams per gram ("g") of a sample. KOH is expressed in milligrams ("mg"). TAN is determined by ASTM method D664. "VGO" refers to a boiling range distribution between 343 ° C (650 200535223 T) and 538 ° C (looo 卞) at 0.101 MPa. Of

Between hydrocarbons. The VG0 content is measured by ASTM method D 5 3 0 7. "Viscosity" refers to the dynamic viscosity at 37 8 / M T). Viscosity is measured using ASTM method D445. In the case of this application, it should be understood that if the value of the nature of the tested substrate is obtained in the test method丨 Outside the private dry fence 4, you can modify and / or recalibrate this test method to test such properties. Crude oil can be produced and / or dried in the Donggu from the structured hydrocarbons and then stabilized. Crude oil Crude oil may be included. Crude oil may be solid, semi-solid, and / or liquid. Stabilization may include, but is not limited to, removing non-condensable gases, water, salts, or combinations thereof in crude oil Forming stable and stable small crude oil. This type of stabilization may usually occur at or near production and / or retorting sites. Stable crude oils are typically not yet in processing equipment and / or are divided into cranes to produce specific Multiple components of a boiling range distribution (eg, naphtha, fractions, vg0, and / or lubricating oil). The steaming hall includes, but is not limited to, the repeated distillation method and the Ergejubaobao method. Undistilled and / or unbranched crude oil may contain at least 0.5 grams of ingredients per gram of crude oil. Examples of stabilized crude oils include whole crude oil, surplus -... lean crude oil, desalted crude oil, desalted crude oil, or a combination thereof. "Tamper surplus" damage; baht and processed crude oil, because at least-part of which has a boiling point at G1G1 MPa lower than μ 1 atm (9yF)). Typically, distillate crude has such components in a gram of crude oil as a maximum of 0. U, a maximum of 0.05 g, and a range of 0-02 g. Some stable crude oils have the property of allowing stable crude oils to be transported to conventional processing equipment by means of transport vehicle trains such as 50 200535223 pipelines, trucks or ships. Other oils have one or more inappropriateness f that makes them unfavorable. Inferior crude oil may be unacceptable for transport vehicles and / or processing equipment, so Hezhe gives inferior crude oil a low economic value. This economic value may be as if the production, transportation, and / or processing of a container of inferior crude oil is considered too expensive. 3 The properties of inferior crude oil may include, but are not limited to: a) at least 〇 · 丨, at least 0.3 TAN, b) at least 1 〇r »q ★ from private reasons, η ^ Wang Xi 10 viscosity cSt; A specific gravity of 19; d) total N: i / V / Fe content is at least 0.02 g per gram of crude oil

Or at least 0 · gram of Ni / V / Fe; e) the total content of heteroatoms is at least 0.005 grams of heteroatoms per gram of crude oil; f) the content of residues is at least 0.01 gram per gram of crude oil G) c5 asphaltene content of at least 0.04 grams per gram of crude oil. Asphaltene; h) listening content is up to > 0.002 g of MCR per gram of crude oil; i) metal content in the form of metal salt of organic acid is at least 彳 () · 〇_! G of metal per gram of crude oil; combination. In the specific example of Yougan, inferior crude oil may contain at least 0.3 grams of residue and at least 0.5 grams of residue in each gram of inferior crude oil.

Residues, or residues up to 0.9 grams. In several specific examples, a poor quality crude oil may have a TAN in the range of 0.1 or 0.3 to 20, 0.3 or 0.5 to 10, or 0.4 or 0.5 to 5. In certain specific examples, inferior crude oil may have a sulfur content of at least 5,000 grams, at least 0.001 grams, or at least 0.02 grams per gram of inferior crude oil. In several specific examples, inferior crude oil has properties including, but not limited to: a) a TAN of at least 0.5; b) an oxygen content of 1 gram of crude oil; a gram of oxygen, c) a C5 asphaltene The content is at least 0.04 grams of Cs asphaltene per gram of crude oil feed 51 200535223; greater than the desired viscosity (e.g. for crude oil feeds having an API specific gravity of at least 10)> e) organic The metal content in the form of an acid metal salt is at least 0.00000 grams of metal per gram of crude oil; or f) a combination thereof. Inferior crude oil may include in each gram of inferior crude oil: at least 0.001 g, at least 0.005 g, or at least 0.00 g of boiling range distribution between 90 C and 200 ° C at 001 MPa Hydrocarbons; at least 0.00 g, at least 0.05 g, or at least 0.001 g of hydrocarbons having a boiling range distribution between 200 ° C and 300 ° C at 0-101 MPa; at least 0.001 g, at least 0.005 g Or at least 0.01 grams of hydrocarbons with a boiling range distribution between 0.1 ° C and 40 ° C at 0.101 MPa; and at least 0.001 grams, at least 0.005 grams, or at least 0.005 grams of boiling range distribution at 0.101 MPa Hydrocarbons between 400 ° C and 650 ° C. Inferior crude oil may include in each gram of inferior crude oil: at least 0.0001 g, at least 0.005 g, or at least 0.01 g with a boiling range distribution at 0 101 MPa Hydrocarbons up to 100 ° C; at least 0.0001 grams, at least 0.005 grams, or at least 0.001 grams of hydrocarbons with a boiling range distribution between 0.1 ° C and 200 ° C at 0.101 MPa; At least 0.001 g, at least 0.005 g, or at least 0.001 g of a hydrocarbon having a boiling range distribution between 200 ° C and 300 ° C at 0.101 MPa; at least 0.001 g, At least 0.005 grams, or at least 0_01 grams of hydrocarbons with a boiling range distribution between 300 ° C and 400 ° C at 0.101 MPa; and at least 0.001 grams, at least 0.005 grams, or at least 0.01 grams of boiling range distribution at 0.101 MPa Hydrocarbons between 400 ° C and 650 ° C. In addition to the higher boiling point components, certain inferior crudes may contain at least 0.001 grams, at least 0.005 grams, or at least 0.01 52 200535223 grams of boiling per gram of inferior crude oil. Hydrocarbons with a range of up to 100% at 0.11 MPa. Typically, inferior crude oil has at most 0.2 g or at most 0.1 g of such hydrocarbons per gram of inferior crude oil. Content. Several inferior crude oils may contain at least 0.0001 g 'at least 0.005 g, or at least 0.01 g of hydrocarbons having a boiling range distribution of at least 200 ° C at 0.1 10 MPa per gram of inferior crude oil. Crude oil may contain at least 0.001 grams, at least 0.005 grams, or at least 0.01 grams of hydrocarbons having a boiling range distribution of at least 6500 ° C. per gram of inferior crude. Examples of inferior crudes that may be treated using the methods described herein include, But not limited to crude oil from the following regions of the world: U_s. Gulf Coast and southern California ^ Canada Tar sands ^ Brazilian Santos and Campos basins ^ Egyptian Gulf of Suez > Chad ^ United

Kingdom North Sea, Angola Offshore, Chinese Bohai Bay, Venezuelan Zulia, Malaysia, and Indonesia Sumatra. Processing of poor quality crude oil can enhance the properties of the poor quality crude oil so that the crude oil is acceptable for transportation and / or processing. The crude oil and / or inferior crude oil to be processed is referred to herein as the "crude feed". This crude feed can be a distillate crude as described herein. Crude products derived from processing crude feeds as described herein are generally suitable for transportation and / or processing. The properties of crude oil products produced as described herein are closer to the corresponding properties of West Texas Intermediate crude oil than the crude oil feed, or closer to the corresponding properties of Brent crude oil than the crude oil feed, thereby improving the crude oil feed Economic Value. This type of crude oil product can be refined with little or no pretreatment, thereby improving 53 200535223 refining efficiency. Pretreatment may include desulfurization, demetallization, and / or atmospheric distillation to remove impurities. 2. Processing a crude oil feed according to the present invention may include contacting the crude oil feed with a catalyst in a contact zone and / or a combination of two or more contact zones. At least one property of the feedstock in the contact zone is the same as that of the crude oil feed, which can be changed by contacting the σxuan crude oil feed with one or more catalysts. In some specific examples, contact was made in the presence of a hydrogen source. In several specific examples, the hydrogen source provides one or more hydrocarbons of a relatively small amount of hydrogen to the compounds in the crude feed in order to react under special contact conditions. 1 FIG. 1 is a simplified diagram of a contact system 100 including a contact area 102. The crude oil feed enters the contact zone 102 via a conduit 104. The contact zone may be a reactor, a portion of a, multiple portions of a reaction, or a combination thereof. Examples of contact zones include stacked bed reactors, fixed bed reactors, ebullated bed reactors, continuous sand tank reactors ("CSTR,"), fluidized bed reactors, spray reactions I, and liquid / liquid contact In a specific embodiment, the contact system is located or connected to the offshore equipment. In the contact system 100, the contact of the crude oil feed with the catalyst may be continuous or batch. The contact zone may include a Or multiple catalysts (eg, two catalysts). In several specific examples, contacting the crude oil feed with the first catalyst of the two catalysts can reduce the TAN of the crude oil feed. Crude oil feeds that have been reduced in TAN Subsequent contact with the second catalyst is to reduce the heteroatom content and increase the API specific gravity. In other specific examples, when the crude oil feed is in contact with one or more catalysts =, the TAN, viscosity, Nl / V of the crude oil feed / Fe content, heteroatom content, edging composition, Apl specific gravity, or a combination of these properties will change at least 丨 0% compared with the same properties of the crude oil feed 2005 200535223. Fang, special examples in specific examples , The contact medium in the contact area accumulates to the volume %, To 50% by volume, or 30 to 40% by volume of the total volume of crude oil feed in the contact zone. In a specific example, the catalyst and crude oil feed slurry in the contact zone is # 1〇 The catalyst in the 0 g crude oil feed may contain up to 10 g '0.005 to 5 g, or 0.01 to 3 g.

Contact conditions in the contact zone may include, but are not limited to, temperature, pressure, hydrogen source flow, crude oil feed flow, or a combination thereof. The contact conditions in several specific examples are controlled to produce characteristic crude oil products. The temperature in the contact zone can be distributed in the range of 50 to 500 t, 60 to 4 h, 70 to 4 claws, or 80 to 42 ° C. The pressure in the contact zone can be distributed in ...-one, or 6 to ⑽ The range of the original: the LHSV of the feed is usually distributed in the range of 0-1 to 30h-1, 0.5 to 5 ",] to 20h, 1.5 to 15M, or 2 to 10hi. In several In the specific example, the LHSV is at least 5, at least n, at least m !, or at least 20 Jr1.

In the specific example where the hydrogen source is supplied by a gas (such as hydrogen), the ratio of the gaseous hydrogen source t crude oil feed is typically distributed between 0.1 to 100,000 Nm3 / m, 0.5 to 10, _ Nm3 / m3, 1 to 8,000 Nm3 / m3, 2 to 5,000,000Nm / 1Ώ '5 to 3,000 Nm3 / m3, or 10 to 800 Nm3 / m3 dry area in contact with the catalyst. & Hydrogen originates from several specific examples in combination with a carrier gas and recycled through the contact zone. The carrier gas may be, for example, nitrogen, helium, and / or a late gas limb may promote crude oil feed flow and / or hydrogen source flow in the contact zone. The gas face may also enhance mixing in the contact zone. In several specific 55 200535223 examples, a 'hydrogen source (e.g. hydrogen, methane or ethane) can be used as a carrier gas and recycled through the contact zone. The ugly hydrogen source can enter the contact zone 102 in parallel with the crude oil feed in conduit 104 or via conduit 106. In the contact zone 10 ″, the contact between the crude oil feed and the catalyst produces a total product containing crude oil products, and in some specific examples gas. In some specific examples, the carrier gas system and the crude oil feed and / or Combined with a hydrogen source in 106. The total product can leave the contact zone, such as via conduit 110, into the separation zone 108. In the separation zone 108, 'crude oil products and gases can be separated using commonly known separations', such as gas-liquid separation, Separated from the total product. Crude oil products can leave separation zone 108 via lead 112, and then be transported to conveyance carriers, pipelines, storage vessels, refineries, other processing zones, or a combination thereof. Gases can include those generated during processing Gases (such as hydrogen sulfide, carbon dioxide, and / or carbon monoxide), excess gaseous hydrogen sources, and / or carrier gas. Excess gas can be recycled to the contact system, system 100, purified, and transported to other processing areas, storage containers' Or a combination thereof. In several specific examples, contacting a crude feed with a catalyst to produce a total product is performed in two or more contact zones. The total product can be separated to produce Crude products and gases. Figures 2 to 3 are simplified diagrams of specific examples of contact systems that include two or three contact zones. In Figures 2A and 2B, the contact system 100 includes contact zones 102 and 114. Figures 3A and 3B contain. Contact zones 102, 114, 116. In Figure 2A # 3A, the 'contact zones 10102, 114, are depicted as individual contact zones in a reactor. The crude oil feed is routed through The conduit 104 enters the contact area 102 of 2005 200523523. In the specific example of the chemical reaction, the carrier gas is combined with the hydrogen source in the conduit 106 and guided to the contact area in the form of a mixture. As shown in FIGS. 1, 38, and 3B, the hydrogen source and / or carrier gas may flow through the conduit 106 and / or via conduit 106, in the opposite direction as the crude oil feed, = crude oil feed enters one or Multiple contact zones. Addition of a hydrogen source and / or carrier gas to the crude feed flow can increase the mixing and / or contact of the crude feed with the catalyst. In the contact zone 102, the contact of the crude feed with the catalyst A raw material stream is generated. This raw material stream flows from the contact zone 102 to the contact zone i 14. In FIGS. 38 and 3B The raw material stream flows from the contact zone 114 to the contact zone ιΐ6. The contact zones 102, 114, 116 may contain one or more catalysts. As shown in FIG. 2b, the raw material stream leaves the contact zone 102 through the conduit 118 and enters the contact. Zone Π 4. As shown in FIG. 3B, the raw material stream leaves the contact zone 1 1 4 and enters the contact zone 丨 6 via the conduit J 丨 8. The raw material stream may be in contact with the additional catalyst at the contact zone 114 and / or the contact zone 116 To produce a total product. The total product leaves the contact zone 114 and / or the contact zone 11 1 red from $ guan 1 110 and enters the separation zone i 08. Crude oil products and / or gas systems are separated from the total products. Crude oil products are passed through conduits丨 丨 2 Leave the separation area i08. FIG. 4 is a schematic diagram of a specific example of the separation zone upstream of the contact system 100. Inferior crude oil (distilled or non-distilled) enters the separation zone 120 via the conduit 122. In separation zone 120, at least a portion of the inferior crude oil is separated using techniques known in the art (e.g., spraying, membrane separation, reduced pressure) to produce a crude feed. For example, water can be at least partially divided from inferior crude oil. 57 200535223 Ash removal In addition, in the conventional example, it has a boiling range distribution below 95 ° C or less than 100t: 2 components can be separated at least partially from inferior crude oil to produce crude oil. Feed. In several specific examples, at least a portion of the naphtha and the more chemically active 5 species than naphtha are separated from inferior crude oil. In some specific examples, the components separated by the 乂 σ 卩 knife are separated from the separation zone 120 via the conduit 124. The crude oil obtained from the knife separation zone 120 is fed in several specific examples so that Is i 00c, or in some specific examples, a mixture of components having a boiling range distribution of at least 20 t. Typically, the separated crude oil feed contains a boiling range distribution between 100 and 1000. (:, 120 to 900 C or 200 to 800. (: A mixture of ingredients. At least a portion of the crude oil feed leaves the separation zone 120 via the conduit 126 and enters the contact system ι〇〇 (see the contact zone in Figures 1 to 3) ) The crude oil product is produced by further processing. In several specific examples, the separation zone 120 may be located upstream or downstream of the desalination unit. After processing, the crude oil product leaves the contact system 100 via the conduit 112. In several specific examples The crude oil product is blended with the same or different crude oil feed. For example, the crude oil product can be exchanged with the mm μ raw material with different viscosities between the viscosity of the crude oil product and the viscosity of the crude oil. In another example +, crude oil products can be blended with crude oils with different TANs, and the funerals are gangsters, and Tian Yikou produces a product with a TAN between the crude oil products and the crude TANs. This blending The combined product may be suitable for transportation and / or processing. As shown in ® 5 'in a specific embodiment', the crude oil feed enters the contact system 100 via a conduit m, and at least a portion of the crude product is guided through 58 200535223. 128 leaves the contact system 100 and introduces it into the blending zone 30. In the blending zone] 30, at least a portion of the crude oil product is combined with one or more industrial production liquid streams (eg, hydrocarbon streams, such as separating one or more crude oils) Naphtha produced from the feed), crude oil, crude oil feed, or mixtures thereof to produce blended products. Industrial production fluids are made from raw materials / from the feed, crude oil, or mixtures thereof directly into the blending via conduits 1 2 3 Mixing zone 130 or upstream of such blending zone. The mixing system can be located at or near blending m before the blended products can meet the product specifications specified by the refinery and / or conveyor. Product specifications include, but are not limited to, the specific gravity of Αρι, tan,

Viscosity, or range or limit of combinations. The blended product leaves the blending zone 1 30 for delivery or processing via a catheter ΐ34. In FIG. 6, the inferior crude oil is introduced into the separation zone through the conduit 122, and the inferior crude oil is separated to generate a crude oil feed as previously described. The crude oil feed receiver enters the contact system 100 through a conduit m. At least some of the components of the inferior crude oil leave the separation zone 120 via the conduit 124. At least—a portion of the crude oil product leaves the contact system via conduit 128 and enters blending zone 130.

: Other industrial production fluids and / or crude oil enter the blending zone 130 directly or via the conduit 132 to combine with crude oil products to produce blended products: The conduit 134 leaves the blending zone 13. Production. . This is based on several specific examples of crude oil products and / or push-through refineries and / or processing equipment. Crude oil products and / or, monthly " 4 丁 丁发立 σ 7 口 口 Τ 力 口 ：]: Industrial products, such as transportation fuels, heating fuels. Processing can include tombstones / α / its dagger ... nitrogen and / or fractionated crude oil products to produce one or more fractions. In the specific implementation example of “Rui Sui Su”, the product of crude oil, food products, and / or multiple fractions may be 59200535223. In some specific examples, the crude oil product has a TAN of at most ㈣, at most 50%. Up to 30%, or up to & 10% of crude oil feed

TAN. In several specific examples, the crude oil product has a range of ^ to ⑽%, 20 to 70% ′ 30 to 60%, or 40 to 50% of the TAN of the crude oil feed. In certain specific examples, the crude oil product has a maximum of 丨, a maximum of 0-5 ', a maximum of 0.3, a maximum of 0.2, a maximum of 0.1, or a maximum of 0.05. The TAN of the crude product is usually at least 100,000, and more often, at least G.GG1. In several specific examples, ταν of the crude oil product may be in a range of 0.001 to 0.5, 0.01 to 0.2, or 0.05 to 0 ". In several specific examples, the crude oil product has a total Ni / V / Fe content of: 9G% 'up to $ 5Q%, up to 1 ()%, up to, or up to 3% of Ni / V / Fe content. This crude oil product has a total Nl / V / Fe content in several shellfish examples ranging from 丨 to 80%, to 70%, Shanto to 60%, or 30 to 50% of the crude oil feed. Within the range of Fe content.

In the specific examples of square and special, the crude oil product has a presence in every gram of crude oil product! Total Ni / V / Fe content in the range of X 10 to 7 g to 5 × 10 · 5 g, 3 × 10 7 g to 2 × 1 0 · m, or ΐχΐ〇6 g to 1 × 10 to 5 g. In a specific embodiment, this crude oil contains at most 2 x 10.5 g of Ni / V / Fe. In several discontinuities, the total Ni / V / Fe content of the crude product is 70 to 130%, 80 to 120%, or 90 to 10% of the Ni / V / Fe content of the crude feed. In some specific examples, the total content of the crude oil product in the form of a metal salt of an organic acid is up to 90%, up to 50%, up to 10%, or 5% of the organic acid in the crude oil feed. Total metal content in the form of a metal salt. In the specific example of Dou Chong, the crude oil product has an organic acid metal salt form of gold 60 200535223. The total content is 1 to 80%, 10 to 70%, 20 to 60%, or 30 to 50% organic in the crude oil feed. Within the range of the total metal content in the form of an acid metal salt. Organic acids commonly used to form metal salts include, but are not limited to, carboxylic acids, thiols, imines, sulfonic acids, and sulfonates. Examples of carboxylic acids include, but are not limited to, cyclic acids, phenanthronic acids, and benzoic acid. The metal portion of the metal salt may include alkali metals (such as lithium, sodium, and potassium), alkaline earth metals (such as magnesium, calcium, and barium), column 12 metals (such as zinc and braid), column 15 metals (such as arsenic), 6 columns of metal (such as chromium), or a mixture thereof. In a specific embodiment, the total content of the metal in the form of an organic acid metal salt per gram of crude oil product is from 0.0000001 to 0.00005 grams per gram of crude oil products, and from 3,000 to 3,000 grams per gram of crude oil products. 0.0002 grams, or 0.00001 grams to 0.00001 grams of metal in the form of a metal salt of an organic acid. In some specific examples, the total content of organic acid metal salts in crude oil products is 70 to 130%, 80 to 120%, or 90 to 1100/0 of metal in the form of organic acid metal salts in the crude oil feed. Total content. In specific examples, the API ratio of the crude oil product produced by the contact between the crude oil feed and the catalyst under contact conditions is 70 to 130%, 80 to 120%, 90 to 110%, or 100 to 13% The specific gravity of the Aρι of the crude oil feed. In specific examples, the Apy specific gravity of the crude product is 14 to 40, 15 to 30 ', or 16 to 25. In certain specific examples, the crude oil product has a viscosity of up to 90%, up to 80%, or up to 70% of the viscosity of the crude feed. In several months, the crude oil product has a viscosity in the range of 10 to 60%, or 30 to 40% of the viscosity of the crude oil feed. In a number of specific examples, 61 200535223, the crude oil product of the 孰 田 士 # was again attacked by 90% of the crude oil feed. At this time, the viscosity of the crude product ΑΡίη was 70 to 130%, 80 to 12〇. /, +90 to 110% of the original, and the master from 120 /. Or, the proportion of API by Jinke. = /, Male example _, the crude oil product has a total heteroatom content of 90%, a maximum of 50 / 〇, a maximum of 10%, or a maximum total heteroatom of the feed) /. In the specific example of the crude oil, the crude oil product has a total heteroatom content of at least 0 //,. , To ^, 30 ° / °, at least 80%, or at least the total heteroatom content of the crude oil feed. "9;", in the case of the crude oil product, the sulfur content of the crude oil product may be at most: Dibu 5G / ° 'is at most 1G%, or at most 5% of the crude oil product. Has a sulfur content of at least 1%, at least 30%, at least 8ί) () / +, Xima 80 / °, or at least 99% of the sulfur content of crude oil feed. Yu Ruoqian and Griffon: 7 丨 + and Yougan specific examples, the sulfur content of crude oil products is 70 to 130/0, 80 to 120%, and the sulfur content of crude oil feed to bite to 110%. In several specific examples The total nitrogen content of crude oil products may be at most 90%, at most 80%, at most 1G%, or at most 5% of the total nitrogen content of the crude oil feed. In specific examples, crude oil products Have a total nitrogen content of at least 1%, at least 30%, at least 80%, or at least $ 99% of the total nitrogen content of the crude feed. In several specific examples, the basic nitrogen content of the crude product may be Up to 95% 'Up to 90%, Up to 50%, Up to 10%, or Up to 5% of the basic nitrogen content of the crude oil feed. In certain specific examples, the crude oil product is empirical The gas content is at least 1%, at least 30%, at least 62 200535223 80 / ° or at least 99% of the basic nitrogen content of the crude oil feed. The oxygen content of crude oil products in the specific examples of Fang and Yougan May be up to 50%, up to 50%, up to 1 ()%, or up to 5/0 oxygen content of the crude oil feed. In certain specific examples, crude oil products have at least oxygen content $ 1%, at least dove, at least overlook, or to: 2 99% of the oxygen content of the crude oil feed. In several specific examples. The oxygen content is in the 0%, ...%, 20 to 6 0%, or 30 to ... within the range of oxygen content of the crude oil feed. In some specific examples, the total content of the acid compounds of the original product may be up to 90%, and the maximum is 1 to 1. 〇%, or take as much as 5% of the crude acid feed in the crude oil feed 2 r In a specific embodiment, the crude product has acetic acid compounds total = to 乂 is 1% 'at least 30%, at least 80% %, Or at least osmium acid in the crude oil feed + ㈣ + 4. In the case of the system, selected organic oxygen in the crude oil feed can be reduced 2 4 in several specific examples The slow acid and / or _ metal salt can be chemically reduced before the hydrazone :: oxygen compounds are contained. Crude oil products contain the slow, "canned milk compounds can use generally known spectroscopic methods (for example, off-line analysis , Temporarily suspected of eight, ^ said knife, and 7 or gas chromatography) identified by analysis of crude oil house. This crude oil product is at a specific 90%, at most 嶋, the most ^ has the oxygen content of up to 70%, or at most 50% of the oxygen of the crude oil feed, and the original 7h0 / ^ ^ The TAN of the block is at most 90%, and the maximum is TAN at / U / 〇 ', which is more than 5000 /, or 40% of crude oil feed. In the specific example of special φ, horse, 丄, 丄 + ', / products have oxygen content of at least 1%, at least 63 200535223 99% of the crude oil feed oxygen content, 1%, at least 30%, at least TAN. 30% 'at least 80%, or at least 80%, or at least 99% of this crude oil product has a crude oil feed in addition to the crude oil product It is 90%, up to 7G%, up to dove, or up to 40%, and the content of non-slow-acid organic oxygen compounds is between 70 and 13. Evenings are up to 120%, or 90% 110% of the crude oil feed. Gas = within the range of compounds. & In several specific examples, the crude product contains in its molecular structure > grams of crude product with 0.05 to 0.15 grams or 009 to 013 grams of hydrogen. ::: The oil product may contain, in its molecular structure, 0.88 to 0.83 grams of carbon per gram of crude oil product. The atomic hydrogen and atomic carbon ratio (H / C) of the crude oil product may be in the range of 70 to 130%, 80 to 120% ′, or 90 to 12% of the atomic H / C ratio of the oil feed. The atomic H / c ratio of crude oil products in the range of 10 to 30% of the residual atomic H / C ratio of crude oil shows that relatively little hydrogen is absorbed and / or consumed in the process, and / or Department of Field Student

The zero-yield crude product contains components within a certain boiling point range. In several specific examples, the crude oil product contains per gram of crude oil product: at least 0.001 grams, or 0.001 to 0.5 grams of hydrocarbons with a Fossard distribution at 0101 MPa and up to 100 ° C; at least 0.001 grams, or 0_001 to 0.5 g boiling range hydrocarbons between 100 ° C and 200 ° C at 001 MPa; at least 0.001 g, or 0.001 to 0.5 g boiling range It is between 200 at MPa. Hydrocarbons between 0 ° and 300 ° C; hydrocarbons with a boiling range distribution of at least 0.001 g, or between 0.001 and 0.5 g, between 300 ° C and 400 ° at 010 64 200535223 MPa; and at least 0.0000 g, or a boiling range distribution of 0.001 to 0.5 g is between 400 and 100 MPa. (: And hydrocarbons between 538 ° C. In several specific examples, the crude oil product contains at least 0.001 grams of hydrocarbons with a boiling range distribution of 0,100 MPa and up to 100 ° c per gram of crude oil product, and / Or at least 0.001 gram of hydrocarbon having a boiling range distribution between 0 MPa and 200 ° C at 0 MPa. In several specific examples, the crude oil product may contain at least 0.001 grams per gram of crude oil product. Or at least 0.01 gram of naphtha. In other specific examples, the crude product may have a naphtha content of up to 0.6 grams per gram of crude product, or up to 0.8 grams. In several specific examples, the crude product It has a distillate content of 70 to 130% '80 to 120%, or 90 to 110% of the remainder of the crude feed. The distillate content of the crude product can be in the range of 0.0001 per gram of crude product. To 0.5 g, 0.001 to 0.3 g, or 0.002 g to 0.2. In specific embodiments, the crude product has a VG0 content of 70 to 130%, 80 to 120%, or 90 to 110 % Of vg0 content of crude oil feed. In several specific examples, crude oil products have 0.00001 to 0.8 grams, 0.001 to 0.5 grams, or 0.0002 to 0.4 grams, or VGO content in the range of 0.001 to 0.3 grams. In several specific examples, the crude product has a residue content of 70 to 130% , 80 to 120%, or 90 to 11000/0 of the oil content of 屌 推 from the heart of the residue content you enter. This crude oil product can have 0.001 to gram per gram of crude oil product. · 8 grams, 0.0001 to 0.5 grams, 0.0005 to 0.4 grams, 0.0001 to 〇3 grams, 65 200535223 _ to 0.2 W to 〇 "in the range of specific examples, the original ', From the property 3 miles.

/ Product /,] V1CR contains | g 7Q 13 ％, 80 to 120%, or 90 to 110% of the original m is 70 to the amount, at the same time this crude oil product has the highest content of green matter It contains, or at most is the dove ... The vr is mostly 90%. In the specific example of the original / injected cs asphalt, the c5 asphaltene content of the crude oil feed is at least: Z to = 6. %, Or at least 70% of the crude feedstock. The MCR content of the Rishou crude oil product is between 10 and 300/00.

Huiwuximeng Internet Cafe MCR

Youth :: In the concrete example, the C-calendar shell of the crude oil feed is reduced while maintaining the stability of the mcr 5 calendar / total product mixture. $ 可-加 加油 Jindan 7 In several specific examples of 'can be crusted C' green content and warfare in order to produce a high contrast with the high viscosity components in the crude oil feed # 八 1 in the crude oil products The mathematical relationship between degrees into a knife. For example, the sum of the cyanine Hedan 4 κ crude oil feed (: 5 leaches: the sum of the MCR content of the crude oil feed can be expressed as S. The sum of the crude oil production 5 / calendar month quality content and the MCR content of the crude oil product

. These sums (S, and S) can be compared to estimate crude oil. The s ′ of crude oil products of 里, u ~ 丨, and denier β τ with viscosity components can range from i to 99%, 10 to 90%, or 2 〇 person, within the range of S. In several specific examples, the ratio of the asphaltene content of Cs and C5 of the 'crude oil product is in the range of 10 to 30, 12 to 2. to 1.9. In 90% of the specific examples, crude oil products have a maximum MCR content of M «: ί. In some specific examples, the crude oil product has an MCR content of 66 200535223 in an amount of 1 to 80%, 10 to 70%, 20 to 60%, or 30 to 50%. Within the range of the MCR content of the crude feed. The crude oil product contains, in several specific examples, an MCR of 0.0001 to 0 "grams, 0.05 to 0.008 grams, or 0.01 to 0.05 grams per gram of crude oil product. In several specific examples, the crude oil product contains a total catalyst amount of greater than 0 grams, but less than 0.01 grams, 0.0001 to 0.0001 grams, or 0.0001 to 0.0001 grams per gram of crude oil products. Catalysts can help stabilize crude oil products during transportation and / or processing. Catalysts can inhibit corrosion, inhibit friction, and / or increase the water-separation capacity of crude oil products. The methods described herein can be configured to add one or more of the catalysts described herein to a crude product during a process. The crude oil product produced by contacting the contact system 100 has properties different from those of the crude oil feed. Such properties may include, but are not limited to: 4 reducing Dingan; b) reducing viscosity; c) reducing total Ni / V / Fe content; d) reducing content of sulfur, oxygen, nitrogen 'or combinations thereof; e) $ Low residue content, low 0, reduced C5 asphaltene content; g) reduced MCR to increase API specific gravity; i) reduced metal content in organic acid metal salt form; or J) a combination thereof. In several specific examples, one or more properties of the crude oil product may be selectively changed compared to the crude oil feed, while other properties are not changed substantially or substantially unchanged. For example, t, it may be desirable to select only: to reduce TAN in the crude feed without significantly changing the amount of other components (such as sulfur, residues, lin / Fe, or VG0). Hydrogen uptake during contact in this way can be "concentrated" with a decrease in TAN, while the other components of f are reduced. Therefore, although less hydrogen is used, crude oil can still be added to TAN, because a smaller amount of this hydrogen will also be used to reduce other components in the crude oil feed. For example, if inferior crudes have a high TAN but the sulfur content is acceptable for processing and / or transportation specifications, then such crude feeds can be processed more efficiently to reduce TAN without reducing sulfur as well. The catalyst used in one or more embodiments of the present invention may include one or more bulk metals and / or one or more metals on a carrier. The metal may be in the form of an element or in the form of a metal compound. The catalysts described herein can be introduced into the contact zone in the form of precursors and then become active catalysts in the contact zone (for example, when sulfur and / or sulfur-containing crude oil feeds come into contact with the precursors). The catalyst or catalyst combination used as described herein may or may not be a commercial catalyst. Examples of commercial catalysts used in this article include HDS3; HDS22; HDN60; C234; C3 11; C344; C41 1; C424; C344; C444; C447; C454; C448; C524; C534; DN110; DN120; DN130; DN140 DN190; DN200; DN800; DN2118; DN2318; DN3100; DN3110; DN3300; DN3310; RC400; RC410; RN412; RN400; RN420; RN440; RN450; RN650; RN5210; 603; ZRM; Z703; Z71 3; Z723; Z753; and Z763, which are available from CRI International, Inc. (Houston, Texas, USA). In several specific examples, the catalyst used to modify the properties of the crude oil feed contains One or more of columns 5 to 10 metals. Columns 5 to 10 Metals include, but are not limited to, rhenium, chromium, platinum, copper, iron, copper, iron, iron, nickel, ruthenium, barium, iron, iron, watch, metal, or mixtures thereof. The catalyst may have at least 0.0001 grams, at least 0.001 grams, at least 0.01 200535223 grams per gram of catalyst or between 0.0001 to 0.6 grams, 0.005 to 0.3 grams, and 0.001 to 0.01 grams. 'Or 0.01 to 0.08 grams of the 5th to 10th total metal content. In some specific examples, the catalyst contains the 15th element in addition to the metals in columns 5 to 10. Examples of the 15th element include phosphorus. The catalyst may have a total content of the 15th element in the range of 0.00000 to 10.0 g per gram of catalyst, 0.01 to 0.06 g, 0.05 to 0.003 g, or Within the range of 0.0001 to 0 g.

In a specific embodiment, the catalyst includes a sixth metal. The catalyst name may have at least 0.0001 grams, at least 0.001 grams, at least grams and / or 0.0001 to 0.6 grams, 0.001 to 0.33 grams, 0.05 to 0 grams per gram of catalyst, Or 0.01 to 0.08 grams of the total amount of the 6th metal. In a few specific examples, the catalyst contains 0.001 to 006 grams of metal per gram of catalyst per gram of catalyst. In some specific examples, the catalyst in addition to the sixth metal block: (also contains No. 15 element. 'In several specific examples, the catalyst includes a No. 6 metal plate.

ZZ ... Hold one or more metal combinations. "Molding metal: Mole ratio of Monsidium can be from 0" to 20, 1 to 10, or 2 to 5 white # Mole ratio of the Mth metal and the 7th to 0th metal, * to- H 4 is in the range of 2 to 5. In some specific examples, the catalysts include the 6th metal and the 5th and / or 7th to 10th-ΛΑ Α-human evening metal contact: In addition to the ‘15’ element. In other specific examples, the metal in column 6 and the metal in column H) are metal. In the catalyst, the molar ratio of the total metal content between the 1G and the 6th metal can be in the range of 1 to 10, or 2. In a specific embodiment, the catalyst includes metal in column 5: metal in column 0 69 200535223. The molar ratio of the total amount of metal in column 10 to the total amount of metal in column 5 in the catalyst may be in the range of 1 to 10, or 2 to 5. In several specific examples, the 5-10th metal system is incorporated or deposited on a support to form a catalyst. In some specific examples, a combination of 5th to 10th metal and 15th element is incorporated or deposited on a carrier to form a catalyst. In the specific example of metal and / or element loading, the weight of the catalyst includes all carriers ' all metals and all elements. The support may be porous and may include a refractory oxide, a porous carbon-based material, a zeolite, or a combination thereof. Refractory oxides can include, but are not limited to, alumina, silica, silica · alumina, titania, oxide, magnesia, or mixtures thereof. The carrier can be # i ^ t t ^ ^ ^ ^ Criterion Catalysts and Technologies IP Houston ’Texas, UeS A). Porous carbon-based materials include, but are not limited to, square, reactive slave and / or porous graphite. Examples of the zeolite include Y zeolite, p-boehmite, ZSM-5 zeolite, and zeolite. Zeolites can be obtained from industrial manufacturers, such as Zeolyst (Valley Forge, Bu leg,). In some specific examples, the carrier is prepared so that the carrier has an average pore size of at least 'at least 17G A' or at least ⑽A. In 2 cases, the 'carrier' was prepared by forming a slurry of the carrier. In several cases, an acid was added to the concrete to promote the spreading of the slurry. Water and dilution were required for the method Examples of additions to provide a lack of meaning include, but are not limited to, nitric acid, sulfuric acid, and sulfuric acid. U Pulps can be extruded and cut using commonly known catalyst extrusion and catalyst cutting methods to Extrudate formation. ^ 4 Extrudate can be heat treated at a temperature in the range of 5 to 260 ° C or 85 70 200535223 to 235. (: 0 to 8 hours) and / or until the extrudate The humidity reached the desired value. The heat-treated extrudate may be further heat-treated at a temperature in the range of 800 to 100,000 t or 900 to 110,000 to form a carrier having an average pore size of at least 150 people. In a specific embodiment, the carrier Contains gamma oxide, tritium oxide, aluminum oxide, alpha alumina, or a mixture thereof. The amount of gamma alumina, delta alumina, alumina, or a mixture thereof may be 0.000 per gram of the catalyst carrier. 〇1 to 0.99 grams, 0.001 to 0.5 grams, 0.01 to 0.001 grams, or a maximum of 0 grams, which is determined by X-ray diffraction. In several specific examples, the carrier system Contains alumina alone or in combination with other forms, theta alumina content per gram, within the range of (M to 0.99 g, 0.5 to 0.9 g, or 0.6 to 0.8 g , Which is determined by X-ray diffraction. In some specific examples, the carrier may contain at least 0.1 g, at least 0.3 g, at least 0.5 g, or at least 0.8 g of Θ alumina, which Measured by X-ray diffraction. ^ The supported catalyst can be prepared using generally known catalyst preparation techniques. Examples of catalyst preparation methods are described in US Patent No. 6,218,333 issued to Gabrieiov et al .; 6,29〇, 841 to GabrielOv et al .; 5,744,025 to BON, 5,744,025 to Bhan, and US Patent Application Publication No. 20030111391 to Bhan ”In several specific examples, the carrier may be impregnated with metal to form a catalyst. In a specific embodiment, the carrier may be impregnated at 400 to 12000 ′ at 450 to 1000 ° C, or 600 to 900 Heat treatment at a temperature in the range of C. In some specific examples, the impregnation aid can be used during the preparation of catalyst 71 200535223. The impregnation aid y, & , Ethylenediaminetetraacetic acid (EDTA), ammonia, or mixtures thereof. In a specific embodiment, the catalyst can be formed by adding or incorporating a fifth metal to a heat-treated shaped carrier mixture ("cover"). The top surface of the carrier formed in the ground is covered with metal to have a substantial or relatively uniform degree of metal content, which gives the catalyst favorable catalytic properties. After each coating-after the heat treatment of the formed carrier, there will be a tendency to improve the catalytic activity of the catalyst.

to. The method for preparing the catalyst using the overlay method is described in U.S. Patent Application Publication No. 20001 issued to Bhan. ―The 5 to 10 metal and carrier can be mixed with appropriate mixing equipment to shape the metal / carrier mixture. Columns 5 to 10 Metals / carriers 勹 4, I are mixed using 4 mixing equipment. Examples of suitable mixing equipment ^ Spigot opening or groove, grinding mixer (such as batch or continuous 1), impact mixer, and those that can properly form the 5th to 1G block metal / load! Any other-generally known mixer, or-generally known device.

Therefore, in the specific examples, the materials are mixed until the 5 i 1G rotten metal is evenly dispersed in the carrier. In dry and bulk cases, after the carrier and metal are combined, the catalyst is allowed to reach 150 to 7SO. Wide ~ 00 to 740 C 'or 400 to 73. (: The heat treatment is performed at a temperature. In some specific examples, the catalyst can be removed in hot air and / or oxygen-enriched air at a temperature within the range of 0 and 1 GGG ° c to remove the catalyst. Volatile substances' in order to convert at least a part of the 5th to 10th metal to the corresponding metal oxide. 72 200535223 However, in other specific examples, the catalyst may be in the presence of air at 35 to 500 ° C (for example Heat treatment below 300 ° C, below 400 ° C or below 500 ° C for a period of time ranging from i to 3 hours to remove most of the volatile substances without The metals in columns 5 to 丨 Q are converted into metal oxides. The catalysts prepared by this method are usually called "uncalcined, catalysts. When combined in this way to form a sulfide method: catalyst day inch 'The active metal is dispersible in a carrier. The preparation of such catalysts is described in U.S. Patent No. 6,2 1 8,333 issued to Gabrielov et al., And 6 issued to Gabrielov v. Et al. , 29〇, 841. In a specific embodiment, Θ alumina support can be combined with the 5th to 10th. Stop to form a Θ alumina support / column 5i-10 metal mixture. The oxidized support / column 5-10 metal mixture can be heat treated at a temperature of at least 4 ° C to form a median pore size of at least $ 23G. The heat treatment of the pore size distribution of A, /, and σ is performed at a temperature of up to 1200 ° C.

In some specific examples, the carrier (commercial carrier or body as described herein) can be combined with the supported catalyst and / or bulk metal catalyst. Yu Ruo: In a specific example, the 'supported catalyst may include a 15th metal. For example, the = catalyst and / or bulk metal catalyst can be crushed into powders with an average particle diameter of i to 5 J: surname 2 to 45 microns and 5 to 40 microns. The powder can be used as a buried metal catalyst. In several specific examples, the powder is combined with the carrier, and then you can use the field furnace to extrude it in the autumn, using a private standard technology to extrude it to form a center with seven holes. # 80 to 2000a a

η-or a catalyst with a pore size distribution in the I circle of 90 to 80 A, or 120 to 130 Α. 73 200535223 The catalyst and "Metals in contact with several specific points exist in buried metal contacts: open at least-part of the)) and cause there is less metal on the surface than existed by other methods = two into the carrier. In some specific examples: it is a contact: those with less metal will extend the life of the catalyst by allowing at least one catalyst surface during use and / or the name of the catalyst surface is invaded during the contact of the catalyst with the crude oil feed. In some specific examples, the rhenium and / or mixed catalyst components will make the structure order of the rhenium 6 metal in the crystal structure of the 6th metal compound = the substantially random order of the 6th metal in the structure. "Retained metal =: It can be determined by powder X-ray diffraction method. Compared with the order of all metal oxides, the order of the metal elements in the catalyst can be compared by comparing the X-ray diffraction spectrum of the sixth block oxide. The order of the 6th metal peak in the X-ray diffraction spectrum of the catalyst is determined by the order of the 6th metal peak in the X-ray diffraction spectrum of the catalyst. From the fish X-ray diffraction spectrum, the pattern related to the 6th metal is broadened and / or no pattern From this point of view, it is possible to estimate the sixth random metal that is substantially randomly arranged in the crystal structure. For example, molybdenum trioxide can be combined with an alumina support having a median pore size of at least ΐ80α to form alumina / molybdenum trioxide. Mixtures. Molybdenum trioxide has a well-defined pattern (such as a clear Digg, with osmium and / or h⑽ peaks). Alumina / 6th trioxide mixtures can be heat treated at a temperature of at least 538.0 (10,000). In order to generate a catalyst that does not show a dioxin pattern in the x-ray diffraction spectrum (for example, without D10G peak). In several specific examples, the catalyst may be characterized by a pore structure. The parameters of various pore structures include, but Not limited to aperture , Pore volume, surface area, 74 200535223, or a combination thereof. The catalyst may have a total pore size distribution relative to the pore size. The median pore size of the pore size distribution may be from 30 to 1000, 50 to 500 people, or 60 to In the range of 300 A. In several specific examples, the catalyst containing at least 0-5 grams of gamma alumina per gram of catalyst has a median pore size of 60 to 2000 A; 90 to 180 A '100 to A pore size distribution in the range of 14〇A, or 120 to 130 A. In other specific examples, a catalyst containing at least 0.1 g of alumina per gram of catalyst has a median pore diameter of 180 to 500 A, 200 Pore size distribution in the range of 300 A, or 230 to 250 A. In some specific examples, the median pore size of the pore size distribution is at least 120 A, at least 15 A, at least 180 A, at least 200 A, at least 22 OA, at least 23 OA, or at least 300 A. This type of median pore size is typically up to 1000 A. The catalyst may have a pore size with a median pore size of at least 60 A or at least 90 A Distribution. In several specific examples, the catalyst has a median pore size of 90 to 180 people, 100 to! 40 A, or 120. A pore size distribution ranging from 130 to Λ, at least 60% of the total number of pores in the pore size distribution has a pore size in the median pore size range of 45 A, 35 A, or 25 A. In a specific embodiment, the catalyst has A pore size distribution with a median pore size in the range of 70 to 180 people. At least 60% of the total number of pores in the pore size distribution have a pore size in the range of 45 Λ, 35 Α, or 25 Α. The median pore size is at least 1 80 A, at least 200 people, or at least 2 3 0 A. In the specific example of 'the pore size distribution has more than 6 00/0 total pores with 50 A, 70 A, or pore size within the median pore size range of 90 people. In some specific examples, the catalyst has a pore size of 75 200535223 cloth with a median pore size ranging from 180 to 500 A, 200 to 400 people, or 230 to 300 A. At least 60% of the total pore size distribution The number of pores has a pore diameter in the range of 50 A, 70 A, or 90 A median pore diameter. In several specific examples, the pore volume of the pores may be at least 0.3 cm3 / g, at least 0.7 cm3 / g, or at least 0.9 cmVg. In specific examples, the pore volume of the pores may be in a range of 0.3 to 0.99 cmVg, 0.4 to 0.8 cmVg, or 0.5 to 0.7 cm3 / g. A catalyst having a pore size distribution having a median pore size in the range of 90 to 180 A may have at least 100 m2 / g, at least m2 / g, at least 170 m2 / g, at least A surface area of 22 m2 / g or at least 2 W / g. Such surface areas can range from 100 to 300 mVg, i20 to 2 are m / g, 130 to 250 m2 / g, or 170 to 220 m2 / g. In a specific embodiment, a catalyst having a pore size distribution having a median pore diameter within a dry range of 800 to 300 people may have at least 60 m2 / g, at least 化 m ′, and at least 100. m2 / g, a surface area of at least 120 m2 / g, or at least 270 M ^. Such surface areas can range from 60 to 300 m2 / g, 90 to 2800 m2 / g, 100 to 270 m2 / g, or 120 to 250 m2 / g. In a specific embodiment, the catalyst exists in a shaped form, such as a pellet shape, a talc shape, and / or a broadcast. The catalyst typically has between 500 and 5000 N / Cm '60 to 400 N / cm, 100 to 350 N / cm, 200 to 300 N / Cm, or 220 to 280 N The crush strength of the plate in the range of / cm. In the specific example on the right, catalysts and / or catalyst precursors are melonized using techniques known in the art (eg ACTICATm method, CRI International,) to form metal sulfides (before use). In several embodiments, the 'catalyst can be dried and then vulcanized. Alternatively, the catalyst can be vulcanized in situ by contacting Catalyst 76 200535223 with a crude oil feed containing sulfur compounds. On-site vulcanization can use gaseous chlorine sulfide in the presence of hydrogen, or a liquid-phase vulcanizing agent, for example: organic sulfur compounds (including sulphur, polysulfide compounds, mercaptans, and arsenic). Off-site vulcanization methods are described in the award to Seamans et al. US Patent No. 5,468,372, and 5,688,736 to Seamans et al.

In the example, the ' type-type catalyst (the “type-catalyst”) contains the 5th to the 10th metal that is combined with the carrier, and has a pore size distribution with a median pore size within 150 to 2 250 A. The first catalyst may have a surface area of at least 100: / g. The pore volume of the first catalyst may be at least 0.5%. A catalyst may have a content of γ oxide in the first catalyst per gram, and a gram of γ oxide of 0.5 gram is typically at most 9999 grams. In this specific example, the brother-type catalyst has a total metal content of 6 g per gram of catalyst per gram of catalyst. The first kind of catalyst can remove ... from a part of Ni / V / Fe in the feed, remove the-part of the TAN that caused the crude oil feed, remove at least a part of the [asphaltene, remove crude oil in the crude feed] $ + _ # ^ I ^ Knife in the form of a metal salt of an organic acid in a feed, and combinations thereof. When the crude oil feed is in contact with the first catalyst, other properties (such as sulfur content, VGO content, Aρι specific gravity, residue content, or its composition may show only a small amount of change. Can selectively change crude oil Feeding the biomass while changing other properties only slightly allows the crude oil feed to be processed more efficiently. In several specific examples, one or more of the first type of mediator can be used in any order. In specific specific examples , Chu-4, Ψ The first type of catalyst ("the second type of catalyst,") contains the 5th to 10th metal that is bound by a human carrier, and has a median pore diameter in the range of 9 () to ⑽ 77 200535223. Pore distribution; the number of pores in at least 60 / of the pore size distribution of the second catalyst has a pore size in the range of 45 A median pore size. Under appropriate contact conditions, the crude oil feed and the second catalyst The contact can produce selected properties (such as TAN) that have significantly changed compared to the same properties of the crude feed, while other properties have only a small change in crude oil products. For example, a hydrogen source may be present during the contact.

2. The second catalyst can reduce at least a portion of the components that cause the crude oil feed t TAN to cause at least a portion of the relatively high viscosity, and reduce the exhausted Fe content of at least a portion of the crude oil products. In addition, the contact of the crude oil feed with the second catalyst can produce a crude product whose sulfur content :: slightly changed compared to the sulfur content of the crude oil feed. For example, a crude oil product may have a sulfur content of a crude oil feed having a sulfur content of 70% to 130%. The crude product may also show only a relatively small change in the fraction content 'VG0 content and residue content' compared to the crude feed.

In several specific examples, the crude oil feed may have a relatively low duty position (e.g., up to 50 wtppm), but a relatively high tan, asphaltene content, or metal content in the form of a metal salt of an organic acid. A relatively high ταν (e.g., a TAN of at least 0.3) may make crude oil feed unacceptable for transportation and / or refining. Has relatively high. 5 Inferior crudes with asphaltene content may show lower stability during processing than other crudes with relatively low I asphaltene content. Contacting the crude feed with the second catalyst can remove the acidic components of the crude feed that cause TAN and / or q asphaltenes. In some specific examples, reducing the Cs asphaltenes and / or the ingredients that cause TAN may reduce the viscosity of the crude oil feed / total product mixture compared to the viscosity of the crude oil feed. For each specific horse used to process the horses described in this article, one or more combinations of the second catalyst, when .spoon crude oil is fed, can improve the stability of the total product / crude oil mixture, and minimize the net cost. draw. ΗCatalyst ... In several specific examples of providing hydrogen for crude oil feed, the third is to make the carrier and column 6 all belong to the & person # &) precursor can be in-or more: catalyst precursor And get. In the presence of catalyst sulfur compounds in the presence of sulfur compounds in the presence of less than 500 t (for example, less than 482 ℃), carbuncle also — _ for a relatively short period of time to generate heart ο:: Λ two kinds of contact Media. Typically, the 'catalyst precursor' system is heated to = medium. In a specific example, the third catalyst may have a content of 元素 1 to ⑽f to 〇_〇2 ^ 0.008 to 0.01 Jixi Jinyao District | Shi * & The third type of contact may show significant activity and stability when used to process crude oil feeds as described in this article. In several specific examples, the catalyst precursor is heated at a temperature of less than 5000 t in the presence of one or more sulfur: compounds. The two catalysts can reduce at least a part of the TAN of the crude oil feed, reduce at least a part of the metal in the form of a metal salt of an organic acid, reduce the Nl / V / Fe content of the crude product, and reduce the viscosity of the crude product. In addition, the contact between the crude oil feed and the second catalyst can produce a relatively small change in sulfur content compared to crude oil, and it is relative to the right Shiguali and the relatives of the lice with crude oil feed: crude oil absorbed by Xiaojing product. For example, a crude oil product may have a sulfur content of about 1 to 30% of the crude oil feed. The third crude oil produced by the crude oil product is compared with the crude oil feed. In terms of VGO content and residue content, it may only show two: 79 200535223 = change. The ability to reduce the TAN, organic metal's v / Fe content, and viscosity of crude oil feeds at the same time and only slightly change the fraction content, VG0 denier, * & 1 ratio of straight, neutral and residual content can allow horses Used by various processing equipment. D ,, 'The two kinds of catalysts can reduce the crude oil feed in several specific examples, ι, a part of the MCR contains 詈, and 士 ^, ^ same as 4 to maintain the stability of the crude oil feed / total product Sex. In a specific embodiment, a ^ is. · To (Mg 2: 5: The mother gram catalyst may have "g", 0.005 to 0.05g, or the sixth metal content within the range of 0.001 to 〇 ^, and New Zealand to gram,. 〇05 ounces, or 0.001 ^ 0.01 grams of the 10th metal contained in the range. Brother 6 and 10 column metal catalysts can promote reduction of at least 500. (: or 350 to 45 〇 Xuanzao Wai Min Dao Mu The composition of the MCR in the crude oil feed at a temperature within the main range of the main 450 C and a pressure in the range of 0 to 1: 8 1 MPa or 2 to 5 MPa. In a specific embodiment, the fourth Catalytic catalyst ("Fourth catalyst") contains the fifth column of metal combined with the emulsified carrier. The fourth catalyst has a hole with a median pore size of at least 180 A. ⑤ ⑤ Eight say ^ ^ 〇 仫 刀 布In the specific example of the right stem, the median pore diameter of the fourth catalyst may be at least rabbits. The main eve is 220 A, at least 230 A, at least 250 A ', or at least _ A. The carrier is in each gram of carrier. May contain at least t to 0.5 grams' at least 0.8 grams, or at least 0.9 grams of Θ oxidation ^. In some specific examples, the four catalysts may contain up to 0.1 grams per gram of catalyst 5th metal, and at least 0.001g of the 5th metal per gram of catalyst. In specific examples, the metal in column 5 is hungry. In several specific examples, in the fourth and fourth After catalyst contact, crude oil 80 200535223 feed can be contacted with additional catalyst. The additional catalyst can be the following: the first catalyst, the second catalyst, the third catalyst, the fourth catalyst , The fifth catalyst, the sixth catalyst, the seventh catalyst, the product catalyst, or a combination thereof. J Same as in some specific examples, hydrogen can be contacted with the fourth catalyst in the crude oil feed. It is produced at temperatures ranging from 300 to 400, 32 to 3 δt, or even M. Crude products produced by such contact can have a maximum of 90%, a maximum of 80%, and a maximum of 50%. %, Or TAN of crude oil feed up to $ ⑽. Hydrogen generation can range from i to 50Nm3 / m3,

Nm3 / m3 'or 15 to 25 Nm3 / m3. Crude products can have a total Ni / V / Fe content of up to 90%, a maximum of 8q%, a maximum of at most meso, a maximum of 10%, or a crude Ni / V / Fe content of at least 1%. … In a specific embodiment, the fifth type of catalyst (the "fifth catalyst") contains a column 6 metal in combination with a theta oxide support. The fifth catalyst has a pore size distribution with a median pore size of at least 180 A, at least 22 0 A, at least 23 0 people, at least 250 A, and at least A, or at most _ A. The body may contain at least 0 "grams, at least 0.05 t, or: less oxidation per gram of support. In some specific examples, the carrier has an "alumina content of less than M grams of alpha alumina per gram of catalyst. In some specific examples, the catalyst contains a maximum of ^ G i grams per gram of catalyst. The 6th metal is at least 0.001 g of the 6th metal per gram of catalyst. In some specific examples, the 6th metal is molybdenum and / or tungsten. In a specific example, when crude oil When the feed is in contact with the fifth catalyst at 81 200535223 to 400 ° C, 320 to ι7Λ > C, or 330 to 3 60 ° C, the strangeness of the crude oil feed will be > , And the absorption at the bottom may be considerably lower than 100 Nm3 / m3 ^ 1 δ 〇π χτ ,,, as if 0 · 〇ΐ to Μ 3/3, m / m 5 to 5〇NmVm3, Or 10 to 3

Nm An). Crude oil feed to to 20Nm3 / m3, 2 to ^ 2 and 3 can be taken as 1 in the specific example of the right stem. From the crude oil feed f m m ′ or from 3 to 10 Nm3 / m3, the crude oil and the fifth catalyst have a maximum tan of 90%, and a mangxi heart. / ^ Produced heart products can have 80 / 〇 at most, 50% at most, at night

The τ Δ x A of 10% crude oil feed is taken as

Into the TAN. TA of crude oil products. _ W or 0.02 to. .03 range. In the range of 0.001 to ° .1, in the specific embodiment, the sixth type is combined with the body, 5 metal and 2 = including the catalyst having a median pore meridian to ^ gangλ6 metal. The pore size distribution of Kong Guang 80A. In some specific cases, at least the control can be at least 22 people, at least 230 bodies per gram load-... at least 30. Into, or at most 5 °. This article can contain at least 0

Gram, at least 0,5 gram, 0.5 gram, at least 0.8 A few or at most G? The carrier can contain the most metal and 6th metal per gram of catalyst in the August bean case example, and the amount is: · 5th of the first ^]] and the mother gram catalyst is at least 0. 〇〇〇1 grams of gold repeatedly and the total amount of the sixth metal. In a few concrete examples of _ vertical ^ + 6th eight g% right, the molar ratio of the amount of i to ^ red and the total amount of 5th gold I can be. To plus, metal / or in the range of 2 to 5. In a specific embodiment, the fifth column is vanadium and the sixth column metal is molybdenum and / or tungsten. ^ The oil feed and the sixth catalyst are at 31 ° C. c, when contacted at a temperature between 32 ° and M ′ 330 to 36 ° t, the net of crude feed gas 82 200535223 absorption can be -10 NmVm3 20 Nm / m, -7 NmVni3 to 10

Nm3 / m3 'or _5 Nm3 / m3 absorbs in the range of A + 5 Nm / m. The negative value of hydrogen is taken as the production of lice on the spot ^: 6 荖 produced by the touch, ". The crude oil is fed to the sixth catalyst and the helmet /, and the AN Langxi is 90%, the maximum is 80% The maximum value is 50%, and the maximum is 10%. The TAN of the crude oil product can be between quot and quot of the crude oil feed. To 0 04 H at 0.01 to 0, 1, 0.02 to 0.05. , Or 〇.03 芏 U.04. The origin of the gas: four, five, or sixth catalyst contact period: a small net absorption of wind will reduce production and transportation and / Or treat the acceptable total hydrogen demand during the original processing period. Minimizing the amount of gas used in the process due to production and / or processing will reduce the total processing—in a specific embodiment, the seventh type of catalyst ("the seventh The total content of 6 kinds of metal in the contact weld is within the If jfj of the sixth metal of 0.06 g per gram of catalyst. Chu a 2 q ^ ^ is favorable ... or tungsten. The seventh catalyst system, product -Tau oil products with a TAN up to 90% of the crude oil feed. Your first, second, third, fourth, fifth ^ th: other specific examples of catalysts can also be used in this article In addition ;; Select and use the catalyst and control operating conditions of this application to allow production and the feedstock to be compared to a crude oil product with changed TAN and / or selected properties without significant changes in properties at the same time. The resulting crude oil product 2 Crude oil Compared with the feed material, it may have enhanced properties, so it is more rotatable and / or refined. 83 200535223 The refinery can accept it. Configure two or more ㈣π properties in the order of selection. The order of improving the properties. Example of crude oil feed and TAN, Αρι in the crude oil feed are at least part of the C5 cyanide of the tongue, at least-part of the iron, at least-part of the nickel, and / or at least-part of the energy Reduce the number of heteroatoms in crude oil before the reduction. Wang v Port P knife configuration and / or selection of catalysts in several specific examples and / or stable door catalysts for crude oil feed / total product mixture. Delicious catalyst life and / or crude oil feed. "In the production process, improving the stability of the product and the stability of the product mixture can allow the contact system to run for at least, at least 6 months, or at least 1 year without changing the catalyst in the contact zone. 'Co-selection The medium can make at least a part of the Nl / V / Fe of the knife in the crude oil feed, at least a part of the c5 asphalt before the other properties of the crude oil feed are changed: a part of the organic acid metal salt. Metals, at least a portion, residues that become TAN become at least a portion, or a combination thereof is reduced, while maintaining the stability of the crude oil feed / total product mixture during processing, such as maintaining a crude oil feed below 15 p Alternatively, Q asphaltenes, M = / or API specific gravity can be gradually reduced and / or the ability to selectively change the properties of the crude oil feed by contacting the crude oil feed with the selected catalyst can allow crude oil to be maintained during the workforce Stability of the feed / total product mixture. In the specific implementation examples of Fang, Fang and Yougan, the first catalyst (the above) can be arranged upstream of a catalyst. This configuration of the first catalyst allows removal of high-scoring, wood / wood, metallic dyes, and / or metals in the form of metal salts of organic acids, while maintaining the stability of the crude oil feed / total product mixture Sex. 84 200535223 The first catalyst, in several specific examples, allows the removal of at least a part of the Qin / V / Fe in the crude oil feed, the removal of acidic components, and the removal of components that shorten the life of other catalysts in the system, or Its combination. For example, compared with the crude oil feed, reducing at least a part of the pyrene-5 in the crude oil feed / total product mixture will inhibit the clogging of other catalysts arranged downstream, thus increasing the contact system without supplementary catalyst The duration that the case is still operational. Remove at least-part of @ crude / Fe in the crude oil feed in several specific examples. The life of the catalyst or catalysts can be added after the first catalyst. 〃The second catalyst and / or the third catalyst can be placed downstream of the first catalyst. Further contact of the crude oil feed / total product mixture with the second catalyst and / or the third catalyst can further reduce the TAN, lower the Ni / v / Fe content, lower the sulfur content, lower the oxygen content, and / or Reduce the metal content of organic acid metal salts. In several specific examples, the contact of the crude oil feed with the second catalyst and / or the third one can produce a crude oil feed / total product mixture, which has a reduced UN, reduced sulfur content, reduced-3 scoops of oxygen, reduced gold asphaltene in organic acid metal salt form, low-yield, low-viscosity, reduced viscosity, or a combination thereof, and at the same time during processing The stability of the crude oil feed / total product mixture is maintained. The second catalyst can be configured in parallel;》 y 1, the two catalysts are located upstream of the third catalyst, or vice versa. The ability of hydrogen to transport to a particular contact zone tends to make hydrogen during contact

The use is reduced to 畀, say L, li. The catalyst that promotes the occurrence of hydrogen during the contact period is 彳 妾 Sb ρ, " B The catalyst that absorbs a relatively small amount of hydrogen can be used to change the same properties as the crude oil 85 200535223 feed. ^ ^ Selected properties of crude oil products. For example, Lu's four kinds of catalysts can be blood, one, one, one, two, three, five, eight, and / or seventh. The combination of catalysts used to change the composition of crude oil feed, ..., & natural shellfish, while only changing the original amount

: Other properties of the feed, and 'or at the same time keep the crude feed / total product stable. The order and / or number of catalysts can be selected to minimize the net uptake of hydrogen 'while maintaining the stability of the crude feed / total product. The minimum net uptake of hydrogen, t, d, residue content, VGO content, distillate content, Ap] 38, ..., and s is maintained within the range of the individual properties of the crude oil feed of 20%. ΤΑΝ β / + # 士 〇 >] 1 TAN and / or viscosity of crude oil with a viscosity of up to 900 / 〇. Reducing the net uptake of hydrogen by the crude oil feed can produce a boiling product with a boiling point distribution similar to that of the crude oil feed.] Scissor knife cloth 'reduces the crude oil product compared to the TAN of the crude oil feed. The crude + H / C of the crude product can also be changed only slightly compared to the atomic H / C of the crude feed.

The occurrence of hydrogen in the h & contact zone may allow selective addition of hydrogen to the contact zone and / or allow selective reduction of properties of the crude feed. In several examples, the first and the second catalysts can be configured on the additional catalysts described in this article, downstream, or the mediator "Gan ^"; eight. Hydrogen can occur during the contact between the crude feed and the fourth catalyst, and can transport lice to the contact area containing the additional catalyst. The hydrogen wheel t can reverse the flow of crude oil feed. In several specific examples, the transport of hydrogen may be in the same direction as the flow of crude oil feed. In this example, 3, in a stacked structure (see Figure 2B), hydrogen can be generated in the contact U contact area (such as the contact area 102 of the towel in Figure 2B), gas can be 86 200535223

, ... ~ a U 夕 丨 J such as connection 114 in circle 2B). In several specific examples, the hydrogen flow may be in the same direction as the flow of the crude oil feed. Alternatively, in a stacked structure (see Figure Kun, hydrogen can be generated during a contact in a contact zone (such as the contact zone 102 in the figure). The hydrogen source can be fed by crude oil feed flow. Feed in the opposite direction to the first additional contact zone (for example, in Figure 3B, the beetle causes the lice to be added to the contact zone 1 14 via the conduit 106), and feed the mobile phase with crude oil / y. Entered into the second additional contact zone (as in FIG. 3B), hydrogen is added to the contact zone via the conduit 1 () 6). In some specific examples, the fourth plug book ~ 田田 # 弟 四The catalyst is connected in parallel with the six catalyst systems. The SI catalyst system can be located upstream of the sixth catalyst, or vice versa. The four catalysts and additional catalysts can reduce the amount of hydrogen in the crude oil feed = In the case of taking 'lower TAN, lower _ content, and / or metal content in salt form. A small amount of net absorption of hydrogen is tolerable. Other properties of the crude oil product are slightly changed.' Compared with the same properties of the material In only a few specific examples, Tian Ru, two different seventh catalysts, can be used for ##. The dili used in the upstream smelted the mouth and made the gram catalyst can have the total content of the catalyst in the parent. The range of the first metal in the range of μ μ # is equal to or greater than that of the upstream. In the seventh catalyst downstream of the gram g, or at least QG2 #per gram of catalyst, the total content of 量 6 metal in the catalyst. In some specific examples, the sixth metal in the sixth column contains the total metal species. The catalyst can be reversed. The ability to use a relatively small amount of 1 Wang Meng in the seventh catalyst of Yu and the seventh catalytic activity of the downstream seventh can be delivered to the shop, L +. Other properties of the crude oil product are only slightly changed compared to the same properties of the crude oil 87 200535223 feed. API specific gravity, residue content, content, or combination thereof are changed.) A relatively small amount of crude oil feed at the mouth and upstream and The contact of the seventh downstream catalyst has a maximum tan of 90%, a maximum of 80%, and a maximum of 50%. Eight or to / 丨, the main 彳. / Evening is 10%, "", ° crude oil TAN crude oil product. In some examples, the TAN of the crude oil feed can be gradually reduced by contact with the seventh medium upstream and downstream (for example, the contact of the crude oil feed with the catalyst to produce: Compared with the crude oil feed The crude oil product with changed properties is of the nature of ==; compared with the product, the ability to change to help reduce the TAN progressively can keep the stability of the total product mixture of crude oil feed 7 during processing. Touch specific examples In combination, the combination of catalyst selection and / or catalyst sequence and control (such as wide temperature and / or crude oil feed flow rate) can help reduce the absorption of hydrogen from the raw materials and help maintain crude oil feed during processing. / The total product of raw materials, and compared with the individual properties of the crude oil feed, changes: the nature of white or evening. The stability of the crude oil feed / total product mixture / ° month d f] from the original> by the feed Various phase separations of the feedstock / total product mixture. Phase separation may be caused by, for example, crude oil feed / total product mixture from crude oil: and / or insolubility of crude oil products, asphaltene flocs of crude oil feed / total product mixture; Suspect 'Original >, by feed / The concentration of the components of the product mixture; or the combination thereof. At certain times during the contact, the concentration of the crude oil feed and / or the total product in the crude oil feed / total product mixture may change. When the crude oil feed / Total 88 200535223 When the total product concentration in the product mixture changes due to the formation of crude oil products, the solubility of the 原油 τ crude oil feed component and / or the total product component in the crude oil feed / total product mixture tends to change. g. Crude oil feed may be soluble in crude oil at the beginning of processing, and may be made at the beginning of the year. When the nature of the crude oil feed (such as TAN, MCR, C5 asphaltenes, ρ, Shigan, People, Shang, etc.) When the P value, or a combination thereof, is changed, these ingredients may become less entrenched, not easy, and tend to be in the crude oil feed / total product mixture. In several examples, §, shan w L丨 ^ 4 β, ... the central feed and the total product may form two phases and / or become insoluble with each other. Solubility may also cause the crude oil feed / total product mixture to form two or more gamma-rays. Phase. Due to Asphaltene flocculation, changes in crude oil feed and total product concentration, and / or the formation of two phases in the composition of Shen Dian will tend to reduce the life of one or more of the catalysts. Process efficiency may also decrease. For example, Jb may be required and the crude oil feed / total product mixture must be reprocessed to produce crude oil production with desired properties. ~ During processing, the crude oil feed / total can be monitored The P value of the product mixture can be used to evaluate the process, crude oil inclination, smoke / bucket, shop, L _ ~ crude oil feed / total product mixing stability. Typically, the maximum value is pj. You can indicate the delivery month of the crude oil feed. Flocculation of shellfish usually occurs. If the P-value starts at least 15, and these P-values increase during the contact or are fairly stable, then this means that the crude oil feed is fairly stable during the contact. Selection of crude oil feed / total product mixture = Selecting the evaluator can be controlled by controlling the contact conditions, by selecting the catalyst, by the selective ordering of the catalyst, and by the combination of tools.

Such controlled contact conditions may include controlling LHSV / Limin, M force, hydrogen uptake, crude oil feed flow rate, or a combination thereof. In some specific examples, the contact temperature is controlled in order to remove q-cyanine 89 200535223 and / or other asphaltenes, and Yoin Taimen keeps the MCR content of the crude oil feed. By hydrogen absorption and / or tritium; ^ — contact with the spoon> lowering the MCR content may lead to the formation of two phases, which may be combined with the month + + low crude oil feed / total product mixture Qualitative and / or-life of multiple catalysts. Controlling the contact temperature and hydrogen uptake combined with the catalysts described in this paper can be used to reduce the I asphaltene content at 5 pm while changing the MCR content of the crude oil feed only slightly. In several specific examples, the contact conditions are controlled so that the pulses in one or more contact areas may be different. Operation at different temperatures may allow selective changes in the properties of the crude feed while maintaining the robustness of the crude feed / total product mixture. The crude feed enters the first contact zone at the beginning of the process. The first contact temperature f is a temperature in the first contact region. Other contact temperatures (for example, the first temperature of the second temperature, the first temperature of the fourth temperature, etc.) are the suitability of the contact area disposed behind the first contact area. The first contact temperature may be in the range of 100 to 420 ° C, and the second contact temperature may be in the range of 20 to 100 ° from the first contact temperature, 30 to 90 C or 40 to 60 C. Inside. In some specific examples, the second contact temperature is greater than the first contact temperature. Having different contact temperatures can reduce the TAN and / or q asphaltene content in the crude oil product to a ratio of _ TAN and / or Cs asphaltene content in the crude oil feed, if any, in the first and When the second contact temperatures are the same or different from each other within 10 °, the TAN and / or Cs asphaltenes are reduced to a greater extent. For example, the first contact region may include a first catalyst and / or a fourth catalyst ' and the second contact region may include other catalysts described herein. The first contact temperature may be 350 ° C, and the second contact temperature may be 300 ° F. The contact of the crude oil feed with the first catalyst in the first contact zone and / or the contact with the fourth catalyst at a higher temperature before contact with the other catalyst in the second contact 90 200535223 Causes more TAN and / or c5 asphaltenes in the crude oil feed compared to the reduction in TAN and / or c5 asphaltenes in the same crude oil feed when the first and second contact temperatures differ within 10 ° c Reduction. Examples The following presents non-limiting examples of carrier preparation, catalyst system #, and a system with a selected catalyst configuration and controlled contact conditions. fExample 1 · Preparation of a contact carrier The carrier system uses 585 g of water and 8 g of citric acid to 576 g of aluminum oxide (Cntenon Catalysts and Techno

City, Michigan, U.S.A.) was prepared by milling for 35 minutes. The resulting milled mixture was extruded through a 1.3 Tril0beTM template, dried between 90 and 25, and then calcined at 918 t to obtain 650 g of a calcined support having a median pore size of I82A. This calcined support was placed in an Undberg furnace. The temperature of the furnace was raised to 1,000 to 1000 in the course of 1.5 hours, and then kept in this range M for 2 hours to produce a carrier. This support contained 0.0003 g of gamma alumina, 0.008 g of alpha alumina, 0.0008 g of φ oxidized oxide, and 0.9781 g of dysprosium oxide per gram of the carrier, which were wound by χ rays. Shoot determination. This support has a surface area of 110 m2 / g and a total pore volume of 0.82 cmVg. This carrier has a pore size distribution with a median pore control of 232 A, and 66.7% of the total number of pores in the pore size distribution has a pore size in the 85A median pore size range. This example illustrates how to prepare a support having a pore size distribution of at least 80 A and containing at least 0.1 g of Θ alumina. [Mask __tJiAJ: The median pore diameter is 23, and the hole is light. ^ 91 200535223 The vanadium catalyst of the cloth ^ catalyst 仏 was prepared in the following manner. The oxidized oxide carrier prepared by the method described in Example 1 was impregnated with a hunger dipping solution, which was prepared by combining 7.69 g of VOSO4 and 82 g of deionized water. The value of this solution is m. Alumina (100 g) was impregnated with a rhenium immersion solution, aged for 2 hours with occasional agitation, dried at 125 ° C for several hours, and then at 48 ° C.锻 Calcined for 2 hours. The obtained catalyst contained 0.001 g of hunger per gram of catalyst, and the remainder was the carrier. This catalyst has a pore volume of 0.69 cm / g and a surface area of j 10 m2 / g. In addition, 66% of the pore size distribution of the catalyst has a pore size in the range of 70 A median pore size. This example illustrates the preparation of a column 5 catalyst having a pore size distribution with a median pore size of at least A 230 A. The diameter of the catalyst is at least 230 A ^. The catalyst is prepared in the following manner. The oxidized oxide carrier prepared by the method described in Example i is impregnated with an osmium immersion solution. The solution was combined with 4.26 grams of ⑽4) coffee 207, 6 38 grams of heart 03, 112 grams of 30% HU "gram of monoethanolamine ⑽A) 'and 651 grams of deionized water to form a tremor While prepared. This—heat to 65 t until the solids are dissolved. The heating solution was allowed to cool to room temperature. The pH of the solvent was 5 36. Adjust the solution volume to 82 mL with ionized water. Oxidation! Lu carrier (100g) was impregnated with a dipping solution and accidentally taught. Dynamic aging for 2 hours 'dry at 125 ° C for several hours' and then at 480. "92 200535223 calcined for 2 hours. The catalyst obtained contains 0.04 g of molybdenum per gram of catalyst, and the remainder is the carrier. This molybdenum catalyst has a pore size distribution with a median pore diameter of 2 50 A '0.7 7 cm3 / g Pore volume, and a surface area of 116 m2 / g. In addition, 67.7% of the total pore number in the pore size distribution of the molybdenum catalyst has a pore size in the 86 A median pore size range. This example illustrates that the preparation has a medium size No. 6 catalyst with a pore size distribution of at least 230 people. Example 4: Preparation of a molybdenum / vanadium catalyst with a pore size distribution of a median pore size of at least 230 people. A platinum / vanadium catalyst was prepared in the following manner. The alumina support prepared by the method described in Example 1 was impregnated with a molybdenum / vanadium impregnation solution prepared as follows. The first solution was obtained by combining 2.14 g of (ΝΗ4) 2Μο207, 3.21 g of Mo03, 0.56 30 g of hydrogen peroxide (η202), 0.4 g of monoethanolamine (MEA), and 3.28 g of deionized water were formed into a slurry. This slurry was heated to 65 ° C until the solids were dissolved. The heated solution was cooled to room temperature. The second solution was obtained by combining 3.57 grams of V0S04 and 40 The first solution is combined with the second solution, and sufficient deionized water is added to make the volume of the combined solution reach 82 ml to produce a molybdenum / vanadium immersion / below solution. Alumina is molybdenum / The vanadium impregnation solution was impregnated, aged by accidental agitation for 2 hours, dried at 125 ° C for several hours, and then calcined at 48 ° C for 2 hours. The resulting catalyst contained 0.02 g of vanadium and gram per gram of catalyst. 〇2g of molybdenum, the rest is the carrier. This molybdenum / vanadium catalyst has a pore size distribution with a median pore size of 3 mm. This example illustrates the preparation of column 6 with a median pore size of at least 230 people. Metal and metal catalysts in column 5. The tubular reactor equipped with a temperature measuring sleeve in the center is equipped with a thermocouple to measure the temperature and sound of the entire catalyst bed. + Total w ^ + ^ The space between the temperature measuring sleeve and the inner wall is filled with a total of Agan j dj, a catalyst, and a branched silicon (2〇_grid, SUnf〇rd

MaW; Allso Vlej0, CA). It is believed that such carbonized fossils, if any, have low catalytic properties under the operating conditions described herein. Before placing the mixture in the anti-weeping contact area, make all the catalyst discs

An equal volume of silicon carbide is blended.的 The crude oil feed flow of the reactor is from the top of the reactor to the -ρ anoxic silica system at the bottom of the reactor as a bottom carrier. The catalyst / carbonized carbide mixture (42 cm3) at the bottom is arranged above the carbonized carbide to form the bottom contact area. The bottom catalyst has pores and points with a median of 77 a. 66.7% of the total number of pores in the pore size distribution has a pore size within a 20 A median diameter. The bottom catalyst is contained in each gram of catalyst; t 0.095 grams of indium # G.G25 grams of recording, the rest is oxide carrier.

The middle catalyst / silicon carbide mixture (56 cm3) is placed above the bottom contact two to form the middle contact area. The intermediate catalyst has a median pore diameter of 98 Å, and a total of 66.7% of the pore distribution in the pore diameter distribution has a pore diameter within the range of M a ^ median pore size. The financial catalyst contains .02 grams of nickel and 0.08 grams of molybdenum per gram of catalyst, and the rest is an alumina carrier. District page. The catalyst / carbonite mixture of P (cm3) is arranged above the contact between the towels to form a top contact area. The top catalyst has a median pore diameter of 1 ”into the pore service distribution. Each gram of the catalyst contains 0.004 grams of tumour. The rest of the main catalyst is 2005 352223. It is a gamma alumina carrier. The top is filled with vacancies and serves as a preheating zone. The catalyst bed is loaded into a Lindberg furnace, which includes five heating zones corresponding to the preheating zone, the top, middle, and bottom contact zones, and the bottom carrier.

The catalyst is a rate of 1.5 liters of a gaseous mixture per unit volume (mL) of the gaseous mixture of 5 vol% hydrogen sulfide and 95 vol% hydrogen gas (silicon carbide is not considered as a volume part of the catalyst). Induces contact with the area to form sulfides. The temperature in the contact area is below! During the hour, it increased to 204 t (400 卞) and remained at 204. (: Next 2 hours. After keeping it below 204, the contact zone was gradually increased to 31.6 (600) at a rate of 10 t (50τ) per hour. The contact zone was kept at 316. During the hour, the temperature was gradually raised to WO ° C (700 ° F) and maintained at 37 ° C for two hours. The contact zone was cooled to the surrounding temperature. A Filtered crude oil from Mars rig in Gulf〇fMexic〇, Then at%. [(200 T) 'Heating in an oven] for 2 to 24 hours to generate a crude oil feed having the properties summarized in Table 1, Figure 7. The crude oil feed was fed to the top of the reaction. Crude oil feed System, the preheating zone flowing through the reactor, the contact zone at the top contact zone, the bottom contact and the bottom carrier. The crude oil feed is in contact with each catalyst in the presence of chlorine gas. The contact conditions are as follows: radon gas and supply to The crude oil feed ratio of the reactor was 328 NmVm3 (2000 SCFB), lhsv and pressure was 6.9 MPa_.7 psi). The three contact zones add…, to 370 C (700 卞) and remain at 37 () t for _ hours. The temperature of the three contact zones was then increased and maintained in the following order: it was ⑺5 T) for 500 hours, followed by 388 (73 ° .... ⑼ hours, 95 200535223, then 390 C (734 °), 1800 hours, and then 394 ° C (742 ° F) 2400 hours. The total products (in other words, crude oil products and gases) leave the catalyst bed. The total products are introduced into a gas-liquid phase separator. In the gas-liquid phase separator, the total products are separated into crude oil products And gas. The gas input of the system is controlled by mass flow. The gas system leaving the system is measured by a hygrometer. Crude oil products are regularly analyzed to determine the weight percentage of the crude product components. The results listed are the measured weight percentages of the components. The properties of the crude oil product are summarized in Table 1 of Figure 7. As shown in Table 1, the crude oil product has a sulphur content of 0.00 gram per gram of crude product, a residue content of 0.255 gram, The oxygen content of 0.007 grams. The crude oil product has a ratio of MCR content to cs asphaltene content of! 9 and 〇09. TAN. The total amount of nickel and vanadium is 22 4 wtppm. By measuring The average bed temperature ("WAbt") is determined by the operating time of the crude oil feed. The catalyst life may be related to the temperature of the catalyst bed. It is believed that when the catalyst life is shortened, WABT will increase. Figure 8 is this example The graph of WABT versus time (t) for improving the crude oil feed in the contact zone described in the graph. Curves 36 represent the average pair of crude oil feeds in the three contact zones in contact with the top, middle, and bottom catalysts. Hours of running time During most of the running time, the WABT in the contact area was only changed to about 〇 Π 〇 Guangwen,, ', C. From the perspective of a fairly stable WABT, the catalytic activity of the catalyst can be judged. Affected by the impact of Asia. Typically, an intermediate plant operating time of 3,000 to one hour is related to one year of industrial operation. This example illustrates how to control the conditions of contact to make crude oil feed 96 200535223. A catalyst in the pore # distribution contacts a pore size distribution in the range of 18 OA, with a median pore size of at least 180 A and with a median pore size between 90 and 45 A with a median pore size to produce crude oil containing The total product of this pore size distribution is at least 60% of the total pore number within the range of additional catalyst contact, these properties of crude oil feed. Product. As measured by the P value, the stability of the crude oil feed / total product mixture is maintained. Compared with crude oil feed, crude oil products have lower Ni / V / Fe content, lower sulfur content, and lower oxygen content, while the residual content and VG content of the crude product are 9%. % To ⑽

First, the pore size is between Q0 empty reactor equipment (except the number and content of contact areas), the catalyst is opened; the method, the method of isolating the total product and the method of analyzing the crude product are the same as in Example 5. Each type of catalyst is mixed with the accumulation.

The crude oil feed flow from the reactor is from the top of the reactor to the reactor bottom port P. The reactor was filled from bottom to top by ^ ^ ^ ^ ^ 弋 in the following manner. The bottom of the carbonization reactor served as the bottom support. The catalyst / carbonized M at the bottom is arranged above the carbon cut to form the bottom junction zone. The σM Shu media has a median pore size of 127 persons; f | > γ Bade Λ female "勹" Α pore size distribution, which Hole knife cloth has 66.7% of the total number of holes with a diameter within 32 you-A i τ hole diameter. The far bottom catalyst is locked in each gram of catalyst, and the rest is the carrier. 〇 " Gram's translation. . 2 The top catalyst / silicon carbide mixture 1 U Cm) is arranged at the bottom, 97 200535223 area to form the top contact area. 1 catalyst has

Pore size distribution, eh?丨 Yanba ^ work is 1 00 A

There are 66.7% of the total number of holes in the μ 仫 knife cloth. The median hole diameter is stained with meat, and the bucket has a 20 A coupon. The top catalyst contains 0.03 g of thallium at Γ · 12 g per gram of catalyst, and the rest is oxidized. "Carbonization" configuration; the top of the contact area is filled with vacancies and used as a preheating zone. The contact is installed in Lindberg 掳, and the bottom of the screw bed system m corresponds to the preheating zone, two contact zones, and nylon. The four heating zones carrying the limbs are summarized in Table 2 ', Figure BS-4 crude oil (Vene_)

... into the top of the reactor. Crude oil feed flows through the reactor's preliminary zone, top contact zone, bottom j ... bottom contact and bottom support. The crude oil feed is based on hydrogen atoms in contact with each catalyst. The contact conditions were as follows: the ratio of hydrogen to the original / supply feed to A- was 160 Nm3 / m3 (100 000, L was i h 'and the pressure was 6.9 he (ι0ΐ4 · 7㈣). The two contact zones are heated to 260. (: (500 卞) and maintained at 26〇π (500 卞) 2 87 small 4. The temperature of the two contact zones is then increased in the following order and

Hold 270 C (5 25 F) for 190 hours, then 288 ° C (550 ° F) for 216 hours, then 315 ° C (600 ° F) for 36 hours, and then 343 ° C (65 0 1 20 hours) to Achieved! I Total operating time of 73 hours. ~ The product leaves the reaction and is separated as described in Example 5. The crude product has an average Ding AN of 0.42 and an average API specific gravity of 12.5 during processing. The crude The product contains 0.0023 grams of sulfur, 0.0034 grams of oxygen, 0.441 grams of vg0, and 0.378 grams of residue per gram of crude oil product. The additional properties of the crude oil product are shown in Table 2 of Figure 9. This example shows that The crude oil feed is contacted with a catalyst having a median pore size in the range of 90 to 98 200535223 1 8 0 A to divide the catalyst with a knife cloth to produce a crude oil product. Compared with the properties of the oil feed, it has Reduced I—, reduced rib V / Fe oxygen content 'while the residual content of crude oil products and the individual properties of VG0 containing crude oil feeds at 99% and 100%. Contact of media. Reactor equipment (except for contact Area number and content), catalyst, total product separation method, ^ 山 吝 私Eight 1 — 'W product analysis, and catalyst formation sulfide system is the same as described in Example 6. ^

/ Crude feed (c_i0 crude oil) with properties summarized in Table 3, 10) was fed to the top of the reactor. The crude oil feed flows through the preheating zone, the contact zone, the bottom contact zone and the bottom carrier of the reactor. The contact conditions are as follows: the ratio of chlorine gas to the crude oil feed to the reaction state is Nm3 / m3 (5⑼ SCFB) ′ LHSV is 2 h-i ′ and the pressure is 6 9 Mpa (ι〇ΐ4 7 ㈣). The two contact zones gradually heated i 343 t (65 ° F). The total running time is 1007 hours. Crude products have an average TAN * 16.2 API weighting during processing. The Yuan crude product contains 9 g of calcium, 6 g of sodium = 0.6 g of PPm of sodium, and 3 wt ppm of potassium. The crude oil product contained 0.0003 g of sulfur, 2000 g of oxygen, 0 "% of VGO, and 0.401 g of residue per gram of crude product. Additional properties of the crude product are listed in Table 3 of FIG. This example shows that a crude oil feed is contacted with a selected catalyst having a pore size distribution in the range of 90 to 80 A to produce a crude product with reduced TAN, reduced total calcium, sodium, zinc, and potassium Content, while the crude oil product has 99 200535223 sulfur content, VGO content and residue content of 76%, 94% and 103% of the individual properties of the crude oil feed. ^ · ^ N. J oil production ^ contact with aeration conditions 1 parent reaction equipment (except the number and content of contact areas), each catalyst to form sulfide method, each total product separation method And each analysis is the same as described in Example 5. Unless otherwise stated, all catalysts were mixed with silicon carbide in a volume ratio of 2 parts silicon carbide to 1 part catalyst. The crude oil feed flow through the mother reactor is from the top of the reactor to the upper part of the reactor. The silicon carbide system is arranged at the bottom of each reactor as a bottom load two. The female reactors have a bottom contact zone and a top contact zone. After the catalyst / silicon carbide compound is placed in the contact area of each reactor, the silicon carbide system is disposed above the top contact area to fill the voids and serve as a preheating area for each reactor. The mother reactor was charged into a Lindberg furnace, which included four heating zones corresponding to a preheating zone, two contact zones, and a bottom carrier. In Example 8, an uncalcined molybdenum / nickel catalyst / silicon carbide mixture (48 cm) was disposed in the bottom contact area. The catalyst contained 0.146 grams of per gram of catalyst, 0.0047 grams of records, and GQ2i grams of phosphorus, and the remainder was an alumina support.的 A catalyst / ¼fossil mixture (12 cm3) containing a catalyst with a pore size distribution with a median pore size of # 18G A was placed in the top contact area. The pin catalyst has a total content of 0.04 grams per gram of catalyst, and the remainder is a carrier containing at least 0.50 grams of gamma alumina per gram of carrier. In Example 9, the uncalcined molybdenum / cobalt catalyst / silicon carbide mixture (48 200535223 ⑽3) was arranged in two contact areas. The unburned Langu catalyst contains 43 grams of noodles, 0.043 grams of inscription, and ο ·. . Grams of phosphorus, the rest: alumina support. The molybdenum catalyst / silicon carbide mixture (12 cm3) is arranged in the top contact area. The σ-hai molybdenum catalyst is the same as that in the top contact area of Example 8. In Example 10, the molybdenum catalyst system as described in the top contact area of Example 8 was mixed with the carbonized carbide and arranged in the two contact areas 3). In yoke example 11, the unfired molybdenum / nickel catalyst / silicon carbide mixture (M⑽3) is arranged in the bottom contact area. The unburned mindbook: The medium contains 0.09 grams of lip, 0.25 grams of nickel, and 0.25 grams in the mother gram catalyst. Buick's phosphorus, the rest is alumina support. : ^ A certain / anaerobic silicon compound (12⑽3) is arranged in the top contact area. The hafnium-molybdenum catalyst is the same as that in the top contact area of Example 8. . The plant also considers crude oil from the Mars rig (Gulf〇f Mexic〇), and then heats it in a flood box at% ^ (200 F) for 12 to 24 hours to generate A summary of the crude oil feed of Table 4 is shown in Table 4. , + T,, D enter the top of the reactor of this sequential embodiment. Crude oil: The preheating zone, top contact zone, bottom contact zone, and bottom-loaded crude oil passing through the reactor are in contact with each catalyst in the presence of hydrogen. The contact conditions for each example are as follows: ratio of hydrogen to crude oil feed during contact

NmVm3 (1_SCFB), and the total capacity of each system is U, (Gl4j7 PS1). During the first 200 hours of the contact, the LHSV was 2 0 'and then the remaining contact time LHsv decreased to the temperature of the Uh contact zone ... C (65 ") contact 5. . hour. Two 101 200535223 hours ‘The temperature of all contact areas is controlled as follows: the temperature of the contact area is raised to 354 (670 T)’ and maintained at 354. 2,000 hours below 200 ° C; rise to 366 ° C (690 T) and hold at 366 t for 200 hours; rise to 37 it (700 ° F) and hold at 371 t: 1000 hours below; rise to 385 t (725 ° F), kept at 385. (: 200 hours down, then rise to a final temperature of 399 ° C (750 ° F) and keep it at 399 t for 200 hours to reach a total contact time of 23,000 hours. Crude oil products are regularly analyzed to measure 胄, Hydrogen uptake of crude oil feed

Take, P value, VGO content, residue content, and Lihan 3 louse. The series of average values of the properties of the crude oil products produced in Examples f to 11 are shown in the table in Figure η.

Graphical representation of value ("p") versus operating time ("t"). The force is fed and there is, Bu: value. Qu, 140, 142, 144, and 146 represent P values obtained by contacting the four catalyst systems of Examples 8 to n by ㈣: 枓 individually to the P value of the oil product. For the examples ... Catalyst system, and the p-value of crude oil products from 1 to 2300 small days ’remains at least 15. In pain, most operating times have a P value greater than K5. In the example ^ turn (2300 hours ρ Shibushishi ^ ^ U 1)-beam day "P value is U. From the crude oil of each test, it can be inferred that the crude oil was fed in the contact period in each test. (E.g., crude oil feed has no phase two, except for the ρ β in port 10 in Example 10, except for the increase in ρ value in VIII), the P value of the crude oil product remains the same in each test of the trowel. fixed.

Figure 13 is a graphical representation of U 102 200535223 absorption (H2) versus operating time ("t") of crude oil feeds for four catalyst systems in the presence of gas. The curve, 15 °, 52, 154, τ, ji, ′, ′, and ′ are the net absorption of hydrogen obtained by contacting the crude oil feed individually with each of the catalyst systems of Examples 8 to 丨. The net uptake of hydrogen from the crude feed is in the range of 7 to 48 NmVm3 (43.8 to 300) during the 2300 koji operation period. As shown in Figure 3, the net uptake of hydrogen by the crude feed was fairly constant in each experiment. ^ FIG. 14 is a graph showing the residual content (“R”) of the raw / free product versus the operating time (,,,) of each catalyst system in Examples 8 to 11 by weight. In each of the four trials, the crude oil product had a residue content-a residue content of the crude feed of 88 to 90%. The curves ι56, ι58, ι⑼, represent the residual content of the crude oil products obtained by contacting the crude oil feeds individually with the catalyst systems of Examples 8 to 11. As shown in Figure 14, the residue content of the crude product remained fairly constant in most of the experiments.

FIG. 15 is a graph showing the change in ApI specific gravity (“ΔAPI,”) of crude oil products of each catalyst system of Examples 8 to u as a function of operating time (′ ′ t). Curves 164, 66 1 68, 170 represent the viscosities of the crude oil feeds individually and within the range of Examples 8 to. The specific gravity API of each crude oil increases by M to 4 ″, degrees. The increased API specific gravity corresponds to the API specific gravity of crude oil products in the range of 21.7 to 22 95. The Aρι specific gravity in this range is i 1 0 to 11 7% of the API gravity of crude oil feed. The catalyst system of 11 was contacted with the Aρι specific gravity of the crude product obtained. In each of the four tests, each crude oil product has a range of 58.3 to 72: 7 cSt. FIG. 16 shows the crude oil product expressed by weight percentage 103 200535223 for each catalyst system of Examples 8 to Π. The oxygen content ('' 0, '') is clearly indicated to the operation. Curves 172, 174, I%, and 一 1—W—78 represent the crude oil products obtained by contacting the crude oil feed with the catalyst systems of Examples 8 to 11 respectively.

Oxygen content. Each crude product has plutonium with the most oxygen in the crude feed. Each crude oil product had an oxygen content per gram of crude oil production during each test period. Within the range of 0. 0 to 0. 0 grams. As shown in Fig. 16, the L-containing milky tadpole remained relatively fixed after 200 hours of contact time. The relatively constant oxygen content of the crude oil product shows a reduction in the selected organic oxygen compounds during the contact. Since the TAN is also reduced in these examples, it can be concluded that at least-part of the slow acid-containing organic oxygen compounds are more selectively reduced than the non-reactive acid-containing compounds. " In Example U, the reaction conditions are: 371 t (卞), the force is 6.9 MPa (10.14.7 Psi), and the ratio of hydrogen and crude oil feed is ⑽ NmW (_ SCFB). By weight, the reduction in mcr content in the crude feed was 17.5 Wt%. At a temperature of 399 (75 ° F), at the same pressure and the ratio of hydrogen and crude oil feed, the reduction in the MCR content of the crude oil feed, based on the weight of the crude oil feed, was 25 4 wt%. In Example 9, the reaction conditions were: 371 it (700 卞), the pressure was 6.9 MPa (104.7 psi), and the ratio of hydrogen and crude oil feed was ^ NmW (1_SCFB) 'with crude oil feed By weight, the reduction in mcr content of the crude feed was Π.5 wt%. At a temperature of 399 t (750 V), at the same pressure and the ratio of hydrogen and crude oil feed, based on the weight of the crude oil feed, the reduction in the MCR content of the crude oil feed is: 9 wt%. The increase in these decreases in the MCR content of crude oil feeds indicates that the 6th and 10th metal catalysts that have not been calcined 104 200535223 have been able to promote MCR at higher temperatures than the 6 and 9th metal catalysts that have not been calcined. Decreased content. These examples show that a crude oil feed having a relatively high TAN (G.8 # TAN) is contacted with one or more catalysts to produce crude oil products' while maintaining the stability of the crude oil feed / total product mixture and having a relatively small amount of tritium. Net draw. The selected crude oil product has properties up to 70% of the same properties of the crude oil feed, and the selected properties of the crude oil product are within the same range of the 20-30% crude oil feed. Specifically, as shown in Table 4, each crude oil product has a maximum of 44 ·

NmW (275 SCFB) Crude Feed Hydrogen Net Absorption Production. This type of production has an average TAN of up to 4% of the crude oil feed and an average total ride content of up to 61% of the total lin content of the crude oil feed, while maintaining a P-value of crude oil feed above 3. The average residue content of each crude oil product is from 88 to 90% of the residue content of the crude oil feed. Average per crude product

VG0 contains a VGO content of 1 to 117% of the crude oil feed. The average API specific gravity of each crude oil product is " API specific gravity of crude oil feed ' to ⑽, and the viscosity of each crude oil product is at most 45% of crude oil feed. 4 12 _ The pore size distribution of the star material after the pores are formed in the smallest hydrogen contact in Examples 12 to 14, each reactor equipment (except the number and content of contact areas), each catalyst forms a sulfide method 2. Each total product separation method and each crude oil product analysis system are the same as those described in Example 5. All catalysts are mixed with an equal volume of broken fossils. Crude feed stream for each reactor 105 200535223 The kinetics runs from the top of the reactor to the bottom of the reactor. The silicon carbide system is arranged at the bottom of each reactor as a bottom carrier. Each reactor contains a contact zone. After the catalyst / silicon carbide mixture was placed in the contact area of each reactor, the petrified silica system was placed above the top contact area to fill the voids and serve as a preheating area for each reactor. Each reactor was charged into a Lindberg furnace, which included three heating zones corresponding to a preheating zone, a contact zone, and a bottom carrier. The crude oil feed was contacted with each catalyst in the presence of hydrogen. The catalyst / silicon carbide mixture (40 cm3) is placed over the silicon carbide to form the contact area. The catalyst used in Example 12 was the Lu vanadium catalyst prepared in Example 2. The catalyst used in Example 13 was the molybdenum catalyst prepared in Example 3. The catalyst used in Example 14 was the molybdenum / vanadium catalyst prepared in Example 4. The contact conditions for adding only Examples 12 to 14 were as follows: the ratio of hydrogen to the crude oil feed to the reactor was 160 Nm3 / m3 (1000 SCFB), the LHSV was 1 L1, and the pressure was 6.9 MPa (1014.7 psi). The contact zone was gradually heated to 343 (65 ° C) over a period of time and maintained at 343. 〇 down 1 20 small days τ 'to achieve a total operating time of 36G hours. The total product leaves the contact zone and separates as described in Example 5. The net uptake of hydrogen by each catalyst system was measured during the contact period. In Example 12, the net absorption of hydrogen was -10 · 7 Nm3 / m3 (-65 SCFB), and the crude product had a TAN of 6.75. In Example 13, the net absorption of hydrogen was in the range of 2.2 to 3.0 Nm3 / m3 (13.9 to 18.7 SCFB), and the crude product had a TAN in the range of 0.3 to 0.5. In Example 14, during the contact between the crude oil feed and the molybdenum / vanadium catalyst, the net absorption of hydrogen was in the range of .005 Nm3 / m3 to 106 200535223 0-6 NmW (-0.36 SCFB to 4.0 SCFB) crude oil. The product has a TAN in the range of 0.2 to 0.5. From the point of view of the net hydrogen absorption during the contact period, it is estimated that during the contact of the right horse 1% crude oil feed with the vanadium catalyst, the hydrogen system generated hydrogen at a rate of 10.7 Nm3 / m3 (65 SCFB) during the contact period. The hydrogen dendrite used in the manufacturing process can be used to reduce the use of less hydrogen in the manufacturing process to improve poor quality raw shellfish. The need for less hydrogen during the contact tends to reduce the cost of processing crude oil. In addition, the contact between the crude oil feed and the molybdenum / hungry catalyst produces TANs that have a lower TAN than the crude oil product produced by the indium catalyst alone; §, and Shanli w > products. Return to 18. Crude oil feed and contact. —- Each reactor equipment (except for the number and content of contact zones), each catalyst sulfide formation method, each total product separation method, and each crude oil product analysis system are the same as those described in Example 5. Unless otherwise stated, all catalysts were mixed with silicon carbide in a volume ratio of 2 parts silicon carbide to 1 part catalyst. The crude feed flow from each reactor is from the top of the reactor to the bottom of the reactor. The silicon carbide system is arranged at the bottom of each reactor as a bottom carrier. Each reactor has a bottom contact zone and a top contact zone. After the catalyst / silicon carbide mixture is placed in the contact area of each reaction source, the silicon carbide system is arranged above the top contact area to fill the vacancy and serve as a preheating area for each reactor. Each reactor was charged into a Lindberg furnace, which included four heating zones corresponding to a preheating zone, two contact zones, and a bottom carrier. In each example, a vanadium catalyst was prepared as described in Example 2 and used with an additional catalyst. 107 200535223 In Example 15, a molybdenum catalyst prepared by placing in a bottom contact zone. In the top contact area. The 'additional catalyst / silicon carbide mixture (45 cm3) is formulated' The additional catalyst is the square catalyst / hardened second mixture (1 5 cm3) described in Example 3 and is configured in the same way as in Example 16 Molybdenum catalyst prepared by placing in the bottom contact zone. In the top contact area. The additional catalyst / silicon carbide mixture (30 cm3) is formulated with the σxuan additional catalyst as described in Example 3. The catalyst / silicon carbide mixture (30 cm3) is disposed at

Example 1 'Additional Catalyst / Carbonide Evening Mixture (30 cm3) in Example 17 is equipped with & P contact area, far additional catalyst is indium prepared as in Example 4! Please # 1catalyst / slave The fossil evening mixture ⑼ · 3) is arranged in the top contact area. In Example 18, Pyrex® (Glass w〇rks ㈣ "⑽, Ν⑽

York 'U.S.A.) beads (30 cm3) are arranged in each contact area. Crude oil (Santos Basin, BrazU) having the properties summarized in Table 5 and Figure 17 used in Examples 15 to 18 was fed to the top of the reactor. The crude oil feed flows through the reactor's preheat zone, top contact zone, bottom contact zone, and bottom carrier. Crude oil feed was passed on to $ 6 + Ye You contacted the mother with a catalyst in the presence of lice milk. The contact conditions of each example were as follows: the ratio of t gas to the crude oil feed to the reactor was 160 Nm3 / m3 (100 SCFB) for the first 86 hours and 80 NmW (5 SCFB), LHSV is i h.], And the pressure is 6.9 MPa (1014.7 psi). The contact zone is gradually heated to 343 ° C (650 卞) over a period of time and maintained at 343 t for a total operating time of one hour. 108 200535223 These examples show that in the presence of a hydrogen source, the third feed with a pore size distribution of 350 A and the order pore size in the -A range touches: and combines with the medium to produce crude oil products' The same is expected: the nature of the additional catalyst contact 'and the other properties of the crude oil product are only slightly changed compared with the changes. In addition, during the processing period, a relatively small amount of ammonia of the same nature of the feed is taken up. Crude oil feed was observed. Specifically, such as 矣 5, Yuan Table 5, and Fig. 17, not shown in Examples 17 to Γ: = AN is at most 15% of the tan of crude oil feed. Example 2 Compared with the same properties of crude oil products and crude oil feeds, the total Nl / V / Fe content is up to 50% and the viscosity is 75 / °. In addition, in Examples 15 to 17, the feedstocks each had crude oil having an API specific gravity of ⑽ to 1G3% and the API specific gravity of the raw materials. # The crude oil product produced under the catalysis conditions (Example 18) compared with the crude oil Λητ + degree and the API specific gravity produced products with increased f degree and reduced API specific gravity. From the perspective of increasing viscosity and decreasing API specific gravity, it can be concluded that coking and / or polymerization of the crude oil feed has been initiated. ~ Material contact under various LHSV. The contact system and catalyst system are the same as those described in Example 6. The properties of the crude oil feed are listed in Table 6] s φ ^ M i δ dry. The contact conditions are as follows: The ratio of hydrogen to the crude oil feed to the reaction chamber is 160 Nm3 / m3 (1000 SCFB), and the pressure is 6.9 Pa, Ίπΐ / i. . ^ ϋ14 · 7 Psi), and the temperature of the contact zone was 371 ° C (700 F), reaching between 棘 and τ. In the implementation example μ, the lhsv during the contact period was increased from 1 h · 1 to 12 hr1 during a period of 109 200535223 and maintained at 12 ^ for 48 hours, and then the LHSV was increased to 20.7 h · 1 and maintained at 2 07 γ hours. Under 96 in Example 19, the crude product was analyzed to determine the TAN, viscosity, density, VG0 content, residue content, heteroatom content, and organic content during the time periods of LHSV of 12 and 20.7 h · 1. Gold = acid metal salt form. The average values of the properties of the crude oil products are shown in Table 6 and Figure 18. As shown in Table 6, FIG. 18, the crude oil product of Example 19 has a reduced TAN and a reduced viscosity compared to the TAN and viscosity of the crude oil feed, and the crude oil product of Shandong has an API proportion of 104 to 11%. Crude feed has a specific gravity of Aρm. The weight ratio of MCR content to C5 asphaltene content is at least 1.5. The sum of Mcr content and Cs asphaltene content is less than the sum of MCR content and C5 asphaltene content of crude oil feed. From the weight ratio of the MCR content to the q asphaltene content and the reduction of the sum of the MCR content and c: 5 asphaltene, it can be inferred that the components that have a tendency to form coke will be reduced because of the pitch. The crude oil product also has a total metal content of up to 60% of the crude oil feed with a total potassium, sodium, zinc and calcium content. The crude product has a sulfur content of 80 to 90% of the sulfur content of the crude feed. Examples 6 and 19 show that the contact conditions can be controlled so that lhsv through the contact zone is greater than 10 h ·] compared to a process with lhsv of 1 h · 1] to produce crude products with similar properties. The ability to selectively change the properties of the crude oil feed at a liquid space velocity greater than i 0 h · 1 allows the contact method to be performed in a container that is smaller in size than a commercially available container. The smaller container size allows the processing of inferior crude oil to be carried out at production sites with size restrictions (eg offshore facilities 110 200535223). The feed system and catalyst system at each contact temperature were the same as those described in Example 6. A crude oil feed having the properties listed in Table 7 of Figures 19 to 19 was added to the top of the reactor and contacted with two catalysts in two contact zones in the presence of hydrogen to produce crude oil products. The two contact zones operate at different temperatures. The contact conditions of the top contact zone are as follows: LHSV is 丨 h i; the temperature of the top contact zone is 260 aC (500 卞);

160 Nm / m (1000 SCFB); and a pressure of 6 9 (⑻4 7 ㈣. The contact conditions in the bottom 邛 contact zone are as follows: LHSV is h ... bottom ", C (600F); The ratio shoulder is 60 Nm / m (1000 SCFB); and the repeated force is 6 9 Mpa ㈣). The total product leaves the bottom contact zone and is introduced into the gas-liquid phase separator. In the gas phase phase separator, the total product is separated It is formed into crude oil products and gases. Crude oil products are regularly analyzed to determine TAN and C5 asphaltene content.

The average values of the properties of the crude oil products obtained during operation are shown in Table 7, Figure 19. The crude oil feed has a tan & & asphaltene content of 0.055 g per gram of crude oil feed. The crude product has an average TAN of 0 and c5> average content of cyanine per gram. Crude oil products have 0.039 grams of C5 asphaltenes. The C5 asphaltene content of crude oil products is at most 71% of the C5 asphaltene content of crude oil feeds. The total content of unloaded crude steel and steel is at most 53% of crude oil feeds. The total content of the same metals in the feed. The TAN of the crude oil product is at most 10% of the TAN of the crude oil feed. During the contact period, the p value is maintained at 15 or higher. 111 200535223 As in Examples 6 and 20 (bottom) A contact temperature of 50 ° C tends to reduce the production of crude greens by crude oil. No, C5 asphaltenes with a first (top in this example) contact that is lower than the second (c in this example) c The content is more than two times lower than the C5 content of the crude oil feed. Π:;: ί will make the organic acid-a crude oil-containing feed / total product mixture: the name of the parent, and yttrium (as measured by P value)

The original ... 4 The total potassium and sodium content of the crude product was reduced more than the total potassium and sodium content of the product of Example 6. Use the first contact of the driver ’s low temperature. You can remove the high molecular weight compound and 2 ° 5 cyanide and / or organic acid metal salt), which will form a polymer, have softness and / or stickiness. Physical properties of compounds such as gums and / or ... oils). Removal of these compounds at lower temperatures allows such compounds to be removed before they plug and coat the catalyst, thereby increasing the life of the catalyst disposed at the higher temperature behind the first contact zone.

2U_ 见 座 JU4 contact with the catalyst in the form of a suspension. The bulk metal catalysts and / or catalysts in this application (containing 0 · 0_ to 5g or 0.02 to 4g of catalyst per 100 grams of crude oil) Crude oil can be used in several specific examples The feed is suspended and reacts under the following conditions: The temperature is in the range of 85 to 425 C (185 to 797 τ), the pressure is in the range of 0.5 to 10 MPa, and the The ratio is between 6 and 1 m / ηι for days τ. After a reaction time sufficient to produce the crude product, the crude product is separated using separation equipment such as filters and / or centrifuges, and the catalyst and / or residual crude feed. Crude oil products compared to crude oil feed 112 200535223 may have altered TAN, iron, and asphaltene content. And / or the content of hunger and the further modified and substituted form of the C5 form: T: see the name of the present invention, all specific examples. Therefore, it is considered as an illustration and used to achieve the instruction of those familiar with the technology.

! Purpose of the method. It should be understood that the present dioxin system expressed and summarized in this article serves as an example of a specific example. Can replace the illustrations and descriptions shown in this article # Elements and materials, parts and procedures of the present invention can be reversed, and certain features that can be invented individually 'All of the above after the benefits of the description of the present invention' should be used as a reference Obvious to the skilled person. Changes can be made to the elements shown in this article without departing from the spirit and scope of the present humiliation as described in the appended patent claims. [Brief description of the drawing] Simple description of the first formula ----- For those skilled in the art, the advantages of the present invention with the following detailed description will become apparent after referring to the drawings, among which:

FIG. 1 is a schematic diagram of a specific example of a contact system. Figures 2A and 2B are simplified diagrams of a specific example of a contact system including two contact areas. 3A and 3B are diagrams showing a specific example of a contact system including three contact areas. Fig. 4 is a schematic diagram of a specific example of a separation zone incorporating a contact system. Fig. 5 is a schematic diagram of a specific example of a blending zone of a contact system. Fig. 6 is a schematic diagram of a specific example of the combined crude oil and separation zone, contact system, and blending zone. Fig. 7 is a list of representative properties of the actual feed and crude oil products that brought the crude oil feed into contact with three catalysts. Figure 8 is a graphical representation of crude oil feed and one or more weighted average bed temperatures versus operating time. Figure 9 is an example of a n-limb example of contacting crude oil feed with two catalysts. Representative feed and crude oil products List of properties. Fig. 10 is another list of representative properties of crude oil feedstock and crude oil products in a specific example of contacting the crude oil feed pan rain record catalyst. Figure 11 is a list of the crude oil feeds and crude oil products that brought the crude oil feeds into contact with four different catalyst systems. Figure 2 is a graphical representation of the P value of crude products versus operating time for a specific example of contacting a crude feed with four different catalyst systems. Figure 13 is a graphical representation of the net uptake of hydrogen from the crude oil feed versus operating time for a specific example of contacting the crude oil feed with four different catalyst systems. Figure 14 is a graphical representation of the residual content of crude oil products expressed in percent by weight as a function of operating time by contacting the crude oil feed with four different catalyst systems. Figure 15 is a graphical representation of changes in API specific gravity of crude oil products versus operating time for a specific example of contacting a crude feed with four different catalyst systems. Fig. 16 is a graphic illustration of specific examples of contacting a crude oil feed with four different catalyst systems, the oxygen content of the crude oil product expressed as a percentage by weight versus operating time. Fig. 17 is a list of representative examples of crude oil that brought the crude oil feed into contact with the catalyst system. 114 200535223 The representative properties of the feed and crude oil products. The catalyst system contains various quantities, ': catalysts and catalysts. Catalyst and molybdenum / hungry catalysts, and glass beads. Figure 18 is a list of properties of crude oil feeds and crude oil products for specific examples of contacting the crude oil feed with one or more catalysts at various liquid space velocities. — FIG. 19 is a list of properties of a crude oil feed and a crude oil product of a specific kappa case in which a crude oil feed is brought into contact at various contact temperatures. The present invention allows various modifications and alternative forms, but 1 specific aspect = example is represented by an example in the figure. Such illustrations are possible; according to the drawings, it should be understood that their illustrations and detailed descriptions are not intended to limit the invention to what is not disclosed: a specific form of 'but to the contrary' is intended to cover the fall into the scope of the patent application as attached All modifications, equivalents, and alternatives within the defined spirit and scope. [Description of main component symbols] 100: contact system 102: contact area 104: conduit φ 106; conduit 106 ': conduit 1 G 8: separation area 110: conduit 1 12: conduit U 4: contact area U 6: contact area 115 200535223 1 18: Catheter 1 2 0: Separation zone 122: Catheter 124: Catheter 126: Catheter 128: Catheter 130: Blend zone 132: Catheter 134: Catheter 136: Forced weighted average bed temperature (WABT) versus operating time Curve 140-146: P value of crude oil product versus operating time curve 148-154: Net absorption of hydrogen versus operating time curve 15 6-162: Residual content of crude oil product versus operating time curve 164-170: crude oil product API gravity vs. running time curve 1 72-1 78: Oxygen content of crude oil product vs. running time curve

Claims (1)

200535223 X. Scope of patent application: 1. A method for producing crude oil products, which includes: contacting a crude oil feed with one or more catalysts to produce crude oil products 々. The product where the crude product is at 25. (: And a liquid mixture at 0.1 MPa; the crude oil feed has a total acid number (TAN) of at least 0.3, the at least one catalyst has a pore size distribution with a median pore size of at least ⑽A, ASTM method D4282 determines that the catalyst has a pore size distribution that contains the second or sixth metal of the periodic table: the species of the sixth table of the periodic table—or more than one metal—or more than one port, or a mixture thereof; and The crude oil product has a maximum of tan, by, and TAN ', where TAN is determined by the As ™ method D664. TAN is the second method of patent negotiation 1, where T = Γ of the crude oil product is 50%, the most For Cong, or at most-the crude oil feed 3. If the method of applying for the scope of item 丁 i of the patent application, Ding AN is from the crude oil feed of "1, COSCO crude oil products" to 70%, 30 to _, or 40 to ... / The TAN of the crude oil product in the range of i to 3 of the patent application scope is & &, 'wherein J iAJN 疋 is from 0.001 to 0.05, ΛΛ or in the range from 0.05 to (U.… "_. 1 to .. 2 '5. As in the scope of the patent application No .... The TAN of the crude oil feed is in a range from .3 to 2., from:;, wherein it ranges from 5. to 10, or from 0.5 to 6 ·, a method for producing crude oil products, which Including ... 117 200535223 Contacting the crude oil feed with-or multiple catalysts to produce a total product containing crude oil products, where the crude oil product is a liquid mixture at 25 / C and CMCH MPa 'The crude oil feed is per gram of crude oil The feed has a total metal content and soil metal content in the form of a metal salt of an organic acid of at least 0.00 g. The at least one catalyst has a pore size distribution with a median pore size of at least 18G A. It is freshly prepared by ASTM method D4282 ^, The catalyst has a pore size distribution comprising one or more metals in Shelf 6 of the Periodic Table, Column 6 of the Periodic Table—or more than one metal—or multiple compounds' or mixtures thereof; and controlling the contact conditions so that the crude oil product is organic The total content of alkali metals and alkaline earth metals in the form of acid metal salts is up to 90%. The content of alkali metals and alkaline earth metals in the form of organic acid metal salts in the crude oil feed, wherein the content of alkali metals and alkaline earth metals in the form of organic acid metal salts is Measured by the asTm method D1 3 1 8 / 7. The method of deleting 6 items according to the patent application, wherein the total content of alkali metals and alkaline earth metals in the form of organic acid metal salts in the crude oil product is at most 50% and at most 1G% , Or up to 5% of the organic acid metal salt in the crude oil feed in the form of a metal and soil test metal content. 8. If the scope of the patent application 帛 6 workers method, wherein the crude acid product in the form of organic acid metal salt The total content of alkali metals and alkaline earth metals is alkali metals and alkaline earths in the form of metal salts of organic acids in the crude oil feed from 1 to 80%, 1070%, 2060%, or 305%. Within the metal content. 9. The method according to any one of claims 6 to 8 of the scope of patent application, wherein the crude oil product has from 0.0000 g to 0.00005 g per gram of crude oil product, from 0.000 g 0.003 grams to 0.0002 grams, or from 0.000001 118 200535223 grams to 0._ (H grams of metal acid and soil metal in the form of an organic acid metal salt. Double 10 · If you apply for a patent The method of τ 丨 in the range of items 丨 to 9, and the 6th paste metal in 苴 is 翻 and / or 镌. Η. If the method of any of the _i 1 () items in the scope of the patent application, you should immediately contact The medium has one or more compounds that additionally contain one or more columns of metals in column 5 of the periodic table 'one or more metals in columns 7 to 10 of the periodic table ^ or multiple metals in columns 7 to 1G-or more compounds, and The pore size distribution of the mixture or its mixture. 12. The method according to any one of the scope of the application for patent application, wherein the feedstock has a total of at least OOg per gram of crude oil feed ... wherein the contact conditions are controlled so that This crude oil product has a total Ni / V / Fe content of up to 90/100%, and is fed from the fed Ni / V / Fe content. 3. A method of producing a crude oil product, comprising: contacting a crude oil feed with-or a plurality of catalysts to produce a total product containing a crude oil product, wherein the crude oil product is at 25 C and A liquid mixture at 0.101 MPa 'This crude oil feed has a total still / Fe content of at least OO_2 grams per gram of crude oil feed, the at least one species-containing n multiple species: compounds, or mixtures thereof, the hungry The medium has a pore size distribution with a median pore size of at least ⑽ A; and n controls the contact conditions so that the crude oil product has a total Ni / WFe content where f is ㈣ for the Ni / V / Fe content of the crude feed, of which The inside is determined by ASTM method D5708. 14. According to the method of claim 12 or item 13, the Ni / V / Fe content of the crude oil 119 200535223 product is at most 50%, at most ι0%, at most Ni / V / Fe content of crude oil feed of 5%, or up to 3%. 15. The method of claim 12 or 13, wherein the Ni / V / Fe content of the crude product is square%. A Each mile is between 1 and 80%, 10 to 700 / 〇, 20 to 60%, or 30 to 50% of the crude oil feed. Within the range of Ni / V / Fe. 16. The method according to any one of claims 12 to 15 of the scope of application for a patent, wherein the crude oil product contains from 100,000 to 100,000 per gram of crude oil product. _〇5 grams, from 0.00000 grams to 〇01 grams, or from 0.00000 grams to 0.00005 grams of Ni / V / Fe. See I? The method of any one of 13 to 16 patents, wherein the catalyst has-or more metals-column 6 of the periodic table, or-6 or more compounds of the metal, and 7 to 10 of the periodic table The pores of one or more metals'-or f 7 i 1G metal-or compounds, and / or mixtures thereof are distributed. 18. The method as claimed in any one of claims 17 to 17, wherein the catalyst has one or more compounds additionally containing one or more elements of column 15 of the periodic table and / or one or more elements of column 15 Pore size distribution. 19. If the scope of patent application is the first! The method according to any one of 18 to 18, wherein the median aperture is at most 500 A. 20. The method according to any one of claims 1 to 19, wherein the one or more catalysts additionally include an additional catalyst, and the additional catalyst has a median pore diameter of at least 60 A, or at least i 8 〇 Human pore size distribution. 21. The method according to any one of claims 1 to 20, wherein the crude oil feed is brought into contact in a contact zone located or connected to an offshore device. 120 200535223. 22. The method as claimed in any one of the patent applications, wherein the contact includes contacting in the presence of a hydrogen source. 23. A method as claimed in any one of claims 1 to 22, wherein the method further comprises combining the crude oil product with crude oil of the same or different crude oil feed to form a blend. 24. A kind of crude oil product, which can be covered by patent application! Obtained by the method of any one of items u. 25 ·-crude oil products, which make the crude oil product per gram of crude oil product φ contain: at least 0.001 g of sulfur, determined by ASTM method D4294; at least 0.2 g of residue, by ASTM method D53 〇7 Determination, and the crude product has a reset ratio of micro residual carbon (MCR) content and c5 asphaltene content of at least 1.5, the crude product has a total acid value (TAN) of at most 0.5, where TAN is The MCR content was measured by ASTM method D664, the CCR asphaltene content was measured by ASTM method D2007. 26. The crude oil product according to item 25 of the patent application scope, wherein the crude oil product also contains per gram of crude oil product: a boiling range distribution of at least 0.001 g between 0.1 ° C and 95 ° C and Hydrocarbons; hydrocarbons with a boiling range distribution of at least 0.001 gram between 260 ° C and 320 ° C at 0.101 MPa; and a boiling range distribution of at least 0.001 g between 320 ° at 0.11 MPa Hydrocarbons between C and 65 0 ° C. 121 200535223 27. The crude product of item 25 or 26 of the patent scope as claimed in the above, whose crude product also contains at least 0.005 and nitrogen in each gram of crude product, which is determined by ASTM method D2896. 28. As described in any one of claims 25 to 28, the total nitrogen content of the crude oil product per gram of crude oil to the gram of small crude oil is determined by the ASTM method. D5762 determination. Even 0.001 29. The original of any of the items in the 25th to 28th scope of the application for a patent, wherein the TAN of the crude oil product is the most ′, π 7 two 1 or at most 0 determined by ASTM method D664. · 3 /, hunting 30. A method for producing transportation fuels and additives, white…, using fuels, lubricants or chemical items 1 ^ 4 benefits _ items 24 to 29-crude oil of members Product or blend. 31. If the scope of the patent application is No. 30, the base of the crude oil product or the complex is transformed into a method: wherein the processing includes ^ _, ..., and one or more fractions. . · Oral Platinum claim No. 30 includes hydroprocessing. The method of flying "1 item, in which the processing