SU490278A3 - Способ получени серебр ного катализатора - Google Patents
Способ получени серебр ного катализатораInfo
- Publication number
- SU490278A3 SU490278A3 SU1719711A SU1719711A SU490278A3 SU 490278 A3 SU490278 A3 SU 490278A3 SU 1719711 A SU1719711 A SU 1719711A SU 1719711 A SU1719711 A SU 1719711A SU 490278 A3 SU490278 A3 SU 490278A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- silver
- ethanolamine
- solution
- ethylene
- mol
- Prior art date
Links
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title description 19
- 239000004332 silver Substances 0.000 title description 19
- 229910052709 silver Inorganic materials 0.000 title description 19
- 239000003054 catalyst Substances 0.000 title description 8
- 238000000034 method Methods 0.000 title description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 30
- 239000000243 solution Substances 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910001958 silver carbonate Inorganic materials 0.000 description 2
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BWZOPYPOZJBVLQ-UHFFFAOYSA-K aluminium glycinate Chemical compound O[Al+]O.NCC([O-])=O BWZOPYPOZJBVLQ-UHFFFAOYSA-K 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- KIIUTKAWYISOAM-UHFFFAOYSA-N silver sodium Chemical compound [Na].[Ag] KIIUTKAWYISOAM-UHFFFAOYSA-N 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical group [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9426970A | 1970-12-02 | 1970-12-02 | |
| US9436670A | 1970-12-02 | 1970-12-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU490278A3 true SU490278A3 (ru) | 1975-10-30 |
Family
ID=26788686
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1719711A SU490278A3 (ru) | 1970-12-02 | 1971-11-30 | Способ получени серебр ного катализатора |
| SU1847494A SU540554A3 (ru) | 1970-12-02 | 1972-11-06 | Серебр ный катальзатор дл окислени органических соединений |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1847494A SU540554A3 (ru) | 1970-12-02 | 1972-11-06 | Серебр ный катальзатор дл окислени органических соединений |
Country Status (16)
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL172326C (nl) * | 1972-12-15 | 1984-02-16 | Shell Int Research | Werkwijze ter bereiding van ethyleenoxyde, werkwijze ter bereiding van een daarbij te gebruiken katalysator, alsmede gevormde voortbrengselen, bestaande uit deze katalysator. |
| DE2418712C2 (de) * | 1974-04-18 | 1982-07-29 | Nižnetagil'skij zavod plastmass, Nižnij Tagil, Sverdlovskaja oblast' | Verfahren zur Herstellung von Formaldehyd durch Oxydation von Methanol in Gegenwart eines Silberkatalysators |
| GB1517608A (en) * | 1975-12-29 | 1978-07-12 | Texaco Development Corp | Silver catalyst for ethylene epoxidation |
| US4097414A (en) * | 1976-08-30 | 1978-06-27 | Texaco Development Corp. | Modified ethylene oxide catalyst and a process for its preparation |
| FR2432023A2 (fr) * | 1978-04-28 | 1980-02-22 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d''oxyde d'ethylene |
| JPS57168253U (enrdf_load_stackoverflow) * | 1981-04-18 | 1982-10-23 | ||
| JPS5895665U (ja) * | 1981-12-23 | 1983-06-29 | 株式会社リコー | フオトカツプラ |
| DE3582097D1 (de) * | 1984-08-21 | 1991-04-18 | Mitsubishi Petrochemical Co | Silberkatalysator fuer die herstellung von ethylenoxid aus ethylen und verfahren zu dessen herstellung. |
| JPS61114862U (enrdf_load_stackoverflow) * | 1984-12-28 | 1986-07-19 | ||
| DE3528313A1 (de) * | 1985-08-07 | 1987-02-12 | Basf Ag | Silberkatalysator, seine herstellung und verwendung |
| JPH0678271B2 (ja) * | 1986-07-12 | 1994-10-05 | 三菱油化株式会社 | シユウ酸銀の製造法 |
| DE3937247A1 (de) * | 1989-11-09 | 1991-05-16 | Huels Chemische Werke Ag | Silberkatalysator fuer die oxidation von ethylen und verfahren zu seiner herstellung |
| US5173469A (en) * | 1989-11-09 | 1992-12-22 | Huels Aktiengesellschaft | Silver catalyst suitable for oxidation of ethylene and process for the production of the catalyst |
| DE59003342D1 (de) * | 1989-11-09 | 1993-12-09 | Huels Chemische Werke Ag | Silberkatalysator für die Oxidation von Ethylen und Verfahren zu seiner Herstellung. |
| DE10131297A1 (de) | 2001-06-29 | 2003-01-09 | Basf Ag | Verfahren zur Herstellung von partiellen Oxidationsprodukten und/oder partiellen Ammoxidationsprodukten wenigstens eines olefinischen Kohlenwasserstoffs |
| DE10232482A1 (de) | 2002-07-17 | 2004-01-29 | Basf Ag | Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung |
| US7115776B2 (en) | 2002-07-18 | 2006-10-03 | Basf Aktiengesellschaft | Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
| US6958414B2 (en) | 2002-12-16 | 2005-10-25 | Basf Aktiengesellschaft | Preparation of at least one organic compound by heterogeneously catalyzed partial gas-phase oxidation |
| WO2005016852A2 (de) | 2003-08-06 | 2005-02-24 | Basf Aktiengesellschaft | Verfahren zum betreiben einer kontinuierlichen heterogen katalysierten gasphasen-partialoxidation wenigstens einer organischen verbindung |
| WO2005113123A1 (de) | 2004-05-07 | 2005-12-01 | Basf Aktiengesellschaft | Verfahren zur strukturierten befüllung von kontaktrohren eines kontaktrohrbündels |
| DE102004025445A1 (de) | 2004-05-19 | 2005-02-10 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung |
| US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
| DE102006000996A1 (de) | 2006-01-05 | 2007-07-12 | Basf Ag | Verfahren der heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Ausgangsverbindung |
| EP1734030A1 (de) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
| DE102007004961A1 (de) | 2007-01-26 | 2008-07-31 | Basf Se | Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist |
| DE102007017080A1 (de) | 2007-04-10 | 2008-10-16 | Basf Se | Verfahren zur Beschickung eines Längsabschnitts eines Kontaktrohres |
| DE102007025869A1 (de) | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
| DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
| DE102007028332A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
| DE102012212437A1 (de) | 2012-07-16 | 2014-01-16 | Basf Se | Verfahren zur Herstellung von Acrylsäure aus Ethylenoxid und Kohlenmonoxid |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2459896A (en) * | 1945-01-18 | 1949-01-25 | Schwarz George | Silver impregnation |
| US2773844A (en) * | 1953-06-12 | 1956-12-11 | Shell Dev | Method for making supported silver catalysts |
| US3147154A (en) * | 1961-05-25 | 1964-09-01 | Texaco Inc | Method of depositing metal-containing material onto an extended surface |
| GB1020759A (en) * | 1961-10-02 | 1966-02-23 | Halcon International Inc | Olefin oxidation process and catalyst therefor |
| US3423328A (en) * | 1965-11-22 | 1969-01-21 | Engelhard Ind Inc | Silver-barium catalyst |
| GB1170663A (en) * | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| GB1257352A (enrdf_load_stackoverflow) * | 1968-04-24 | 1971-12-15 |
-
1971
- 1971-11-23 BE BE775697A patent/BE775697A/xx not_active IP Right Cessation
- 1971-11-26 NL NLAANVRAGE7116246,A patent/NL171237C/xx not_active IP Right Cessation
- 1971-11-30 DD DD159256A patent/DD96643A5/xx unknown
- 1971-11-30 JP JP9595971A patent/JPS5522146B1/ja active Pending
- 1971-11-30 NO NO04403/71A patent/NO130419B/no unknown
- 1971-11-30 GB GB5553271A patent/GB1369639A/en not_active Expired
- 1971-11-30 SE SE7115287A patent/SE374279B/xx unknown
- 1971-11-30 DE DE2159346A patent/DE2159346C3/de not_active Expired
- 1971-11-30 CS CS718337A patent/CS191201B2/cs unknown
- 1971-11-30 FR FR7142899A patent/FR2117183A5/fr not_active Expired
- 1971-11-30 SU SU1719711A patent/SU490278A3/ru active
- 1971-11-30 IT IT31846/71A patent/IT941880B/it active
- 1971-11-30 CA CA128,976A patent/CA1004214A/en not_active Expired
- 1971-11-30 AU AU36314/71A patent/AU458053B2/en not_active Expired
- 1971-11-30 CH CH1741871A patent/CH587080A5/xx not_active IP Right Cessation
- 1971-11-30 IE IE1511/71A patent/IE35857B1/xx unknown
-
1972
- 1972-11-06 SU SU1847494A patent/SU540554A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| GB1369639A (en) | 1974-10-09 |
| CA1004214A (en) | 1977-01-25 |
| SE374279B (enrdf_load_stackoverflow) | 1975-03-03 |
| DE2159346C3 (de) | 1982-06-03 |
| AU458053B2 (en) | 1975-02-20 |
| BE775697A (enrdf_load_stackoverflow) | 1972-05-23 |
| NL171237B (nl) | 1982-10-01 |
| NL171237C (nl) | 1983-03-01 |
| IE35857B1 (en) | 1976-06-09 |
| DE2159346B2 (de) | 1977-09-15 |
| IT941880B (it) | 1973-03-10 |
| DE2159346A1 (de) | 1972-06-08 |
| DD96643A5 (enrdf_load_stackoverflow) | 1973-04-05 |
| FR2117183A5 (enrdf_load_stackoverflow) | 1972-07-21 |
| NO130419B (enrdf_load_stackoverflow) | 1974-09-02 |
| AU3631471A (en) | 1973-06-07 |
| CH587080A5 (enrdf_load_stackoverflow) | 1977-04-29 |
| SU540554A3 (ru) | 1976-12-25 |
| CS191201B2 (en) | 1979-06-29 |
| NL7116246A (enrdf_load_stackoverflow) | 1972-06-06 |
| JPS5522146B1 (enrdf_load_stackoverflow) | 1980-06-14 |
| IE35857L (en) | 1972-06-02 |
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