GB1369639A - Process for producing metallic silver deposits and silver-coated bodies resulting from the said process - Google Patents
Process for producing metallic silver deposits and silver-coated bodies resulting from the said processInfo
- Publication number
- GB1369639A GB1369639A GB5553271A GB5553271A GB1369639A GB 1369639 A GB1369639 A GB 1369639A GB 5553271 A GB5553271 A GB 5553271A GB 5553271 A GB5553271 A GB 5553271A GB 1369639 A GB1369639 A GB 1369639A
- Authority
- GB
- United Kingdom
- Prior art keywords
- silver
- coated
- deposits
- producing
- producing metallic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
Abstract
1369639 Producing silver-coated bodies SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ NV 30 Nov 1971 [2 Dec 1970 (2)] 55532/71 Heading C7F [Also in Divisions B1 and C2] A process for producing metallic silver deposits on surfaces of bodies, in particular on the surfaces of porous refractory catalyst supports so as to prepare supported silver catalysts, characterized in that the surfaces concerned are at first coated with at least one organic amine and an aqueous solution of a silver salt of a carboxylic acid, the coating then being dried and the silver salt being reduced to metallic silver by heating the amine present acting as reducing agent. The silver is produced in the form of discontinuous, substantially uniformly spaced, discrete, substantially hemispherical particles of diameters less than 10, 000 Angstrom units. A number of suitable catalyst support materials are referred to including aluminium oxides and charcoal.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9426970A | 1970-12-02 | 1970-12-02 | |
US9436670A | 1970-12-02 | 1970-12-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1369639A true GB1369639A (en) | 1974-10-09 |
Family
ID=26788686
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5553271A Expired GB1369639A (en) | 1970-12-02 | 1971-11-30 | Process for producing metallic silver deposits and silver-coated bodies resulting from the said process |
Country Status (16)
Country | Link |
---|---|
JP (1) | JPS5522146B1 (en) |
AU (1) | AU458053B2 (en) |
BE (1) | BE775697A (en) |
CA (1) | CA1004214A (en) |
CH (1) | CH587080A5 (en) |
CS (1) | CS191201B2 (en) |
DD (1) | DD96643A5 (en) |
DE (1) | DE2159346C3 (en) |
FR (1) | FR2117183A5 (en) |
GB (1) | GB1369639A (en) |
IE (1) | IE35857B1 (en) |
IT (1) | IT941880B (en) |
NL (1) | NL171237C (en) |
NO (1) | NO130419B (en) |
SE (1) | SE374279B (en) |
SU (2) | SU490278A3 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4746749A (en) * | 1986-07-12 | 1988-05-24 | Mitsubishi Petrochemical Co., Ltd. | Process for producing silver oxalate |
US7074955B2 (en) | 2002-07-17 | 2006-07-11 | Basf Aktiengesellschaft | Safe operation of a continuous heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
US7196217B2 (en) | 2003-08-06 | 2007-03-27 | Basf Aktiengesellschaft | Operation of a continuous heterogeneously catalyzed gas phase partial oxidation of at least one organic compound |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL172326C (en) * | 1972-12-15 | 1984-02-16 | Shell Int Research | PROCESS FOR PREPARING ETHYLENE OXIDE, PROCESS FOR PREPARING A CATALYST USED THEREIN, AND PRODUCTS FORMED, CONTAINING THIS CATALYST. |
DE2418712C2 (en) * | 1974-04-18 | 1982-07-29 | Nižnetagil'skij zavod plastmass, Nižnij Tagil, Sverdlovskaja oblast' | Process for the production of formaldehyde by the oxidation of methanol in the presence of a silver catalyst |
GB1517608A (en) * | 1975-12-29 | 1978-07-12 | Texaco Development Corp | Silver catalyst for ethylene epoxidation |
US4097414A (en) * | 1976-08-30 | 1978-06-27 | Texaco Development Corp. | Modified ethylene oxide catalyst and a process for its preparation |
FR2432023A2 (en) * | 1978-04-28 | 1980-02-22 | Ugine Kuhlmann | SILVER-BASED CATALYSTS FOR THE PRODUCTION OF ETHYLENE OXIDE |
JPS57168253U (en) * | 1981-04-18 | 1982-10-23 | ||
JPS5895665U (en) * | 1981-12-23 | 1983-06-29 | 株式会社リコー | Foto Katsupura |
EP0172565B1 (en) * | 1984-08-21 | 1991-03-13 | Mitsubishi Petrochemical Co., Ltd. | Silver catalyst for production of ethylene oxide from ethylene, and process for production thereof |
JPS61114862U (en) * | 1984-12-28 | 1986-07-19 | ||
DE3528313A1 (en) * | 1985-08-07 | 1987-02-12 | Basf Ag | SILVER CATALYST, ITS PRODUCTION AND USE |
DE59003342D1 (en) * | 1989-11-09 | 1993-12-09 | Huels Chemische Werke Ag | Silver catalyst for the oxidation of ethylene and process for its production. |
US5173469A (en) * | 1989-11-09 | 1992-12-22 | Huels Aktiengesellschaft | Silver catalyst suitable for oxidation of ethylene and process for the production of the catalyst |
DE3937247A1 (en) * | 1989-11-09 | 1991-05-16 | Huels Chemische Werke Ag | Silver catalyst for oxidn. of ethylene to ethylene oxide - by pptn. of silver on porous, heat-resistant support so concn. of silver at surface is higher than inside particles |
DE10131297A1 (en) | 2001-06-29 | 2003-01-09 | Basf Ag | Production of partial (ammo)oxidation products of an olefinic hydrocarbon, useful for acrolein/acrylic acid from propane, comprises intermittent supplementation of olefin from another source. |
US7115776B2 (en) | 2002-07-18 | 2006-10-03 | Basf Aktiengesellschaft | Heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
US6958414B2 (en) | 2002-12-16 | 2005-10-25 | Basf Aktiengesellschaft | Preparation of at least one organic compound by heterogeneously catalyzed partial gas-phase oxidation |
BRPI0509632B1 (en) | 2004-05-07 | 2015-09-08 | Basf Ag | process for loading contact tubes from a contact tube bundle in a structured manner |
DE102004025445A1 (en) | 2004-05-19 | 2005-02-10 | Basf Ag | Gas-phase partial oxidation of an organic compound on a heterogeneous catalyst comprises counteracting deactivation of the catalyst by increasing the gas pressure |
US7439389B2 (en) | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
DE102006000996A1 (en) | 2006-01-05 | 2007-07-12 | Basf Ag | Heterogeneously catalyzed gas phase partial oxidation of organic compound in fixed catalyst bed involves recovering quality of catalyst bed by replacing its portion, with a catalyst having activity lower than that of the replaced catalyst |
EP1734030A1 (en) | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Method for long term operation of a heterogeneously catalysed gas phase partial oxidation of an organic educt |
DE102007004961A1 (en) | 2007-01-26 | 2008-07-31 | Basf Se | Preparing a catalyst molded body, useful e.g. to prepare catalyst for gas phase partial oxidation of an organic compound, comprises molding a precursor mixture to a desired geometry, using graphite, and thermally treating the molded body |
DE102007017080A1 (en) | 2007-04-10 | 2008-10-16 | Basf Se | Method for feeding a longitudinal section of a contact tube |
DE102007025869A1 (en) | 2007-06-01 | 2008-07-03 | Basf Se | To service tube bundle of gas-phase hydrocarbon oxidation reactor immediately prior to re-charging with fresh bed of catalyst solids, they are brushed internally |
DE102007028332A1 (en) | 2007-06-15 | 2008-12-18 | Basf Se | A method for feeding a reactor with a fixed catalyst bed comprising at least annular shaped catalyst bodies K. |
DE102007028333A1 (en) | 2007-06-15 | 2008-12-18 | Basf Se | Method for introducing a subset taken from at least one production batch of annular shell catalysts K into a reaction tube of a tube bundle reactor |
DE102012212437A1 (en) | 2012-07-16 | 2014-01-16 | Basf Se | Process for the preparation of acrylic acid from ethylene oxide and carbon monoxide |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2459896A (en) * | 1945-01-18 | 1949-01-25 | Schwarz George | Silver impregnation |
US2773844A (en) * | 1953-06-12 | 1956-12-11 | Shell Dev | Method for making supported silver catalysts |
US3147154A (en) * | 1961-05-25 | 1964-09-01 | Texaco Inc | Method of depositing metal-containing material onto an extended surface |
GB1020759A (en) * | 1961-10-02 | 1966-02-23 | Halcon International Inc | Olefin oxidation process and catalyst therefor |
US3423328A (en) * | 1965-11-22 | 1969-01-21 | Engelhard Ind Inc | Silver-barium catalyst |
GB1170663A (en) * | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
GB1257352A (en) * | 1968-04-24 | 1971-12-15 |
-
1971
- 1971-11-23 BE BE775697A patent/BE775697A/xx not_active IP Right Cessation
- 1971-11-26 NL NLAANVRAGE7116246,A patent/NL171237C/en not_active IP Right Cessation
- 1971-11-30 CA CA128,976A patent/CA1004214A/en not_active Expired
- 1971-11-30 SE SE7115287A patent/SE374279B/xx unknown
- 1971-11-30 IE IE1511/71A patent/IE35857B1/en unknown
- 1971-11-30 NO NO04403/71A patent/NO130419B/no unknown
- 1971-11-30 SU SU1719711A patent/SU490278A3/en active
- 1971-11-30 AU AU36314/71A patent/AU458053B2/en not_active Expired
- 1971-11-30 GB GB5553271A patent/GB1369639A/en not_active Expired
- 1971-11-30 FR FR7142899A patent/FR2117183A5/fr not_active Expired
- 1971-11-30 IT IT31846/71A patent/IT941880B/en active
- 1971-11-30 DD DD159256A patent/DD96643A5/xx unknown
- 1971-11-30 CS CS718337A patent/CS191201B2/en unknown
- 1971-11-30 DE DE2159346A patent/DE2159346C3/en not_active Expired
- 1971-11-30 JP JP9595971A patent/JPS5522146B1/ja active Pending
- 1971-11-30 CH CH1741871A patent/CH587080A5/xx not_active IP Right Cessation
-
1972
- 1972-11-06 SU SU1847494A patent/SU540554A3/en active
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4746749A (en) * | 1986-07-12 | 1988-05-24 | Mitsubishi Petrochemical Co., Ltd. | Process for producing silver oxalate |
US7074955B2 (en) | 2002-07-17 | 2006-07-11 | Basf Aktiengesellschaft | Safe operation of a continuous heterogeneously catalyzed gas-phase partial oxidation of at least one organic compound |
US7196217B2 (en) | 2003-08-06 | 2007-03-27 | Basf Aktiengesellschaft | Operation of a continuous heterogeneously catalyzed gas phase partial oxidation of at least one organic compound |
Also Published As
Publication number | Publication date |
---|---|
NO130419B (en) | 1974-09-02 |
DD96643A5 (en) | 1973-04-05 |
DE2159346C3 (en) | 1982-06-03 |
SU490278A3 (en) | 1975-10-30 |
CS191201B2 (en) | 1979-06-29 |
DE2159346B2 (en) | 1977-09-15 |
NL7116246A (en) | 1972-06-06 |
CH587080A5 (en) | 1977-04-29 |
JPS5522146B1 (en) | 1980-06-14 |
BE775697A (en) | 1972-05-23 |
IE35857B1 (en) | 1976-06-09 |
AU3631471A (en) | 1973-06-07 |
NL171237C (en) | 1983-03-01 |
IT941880B (en) | 1973-03-10 |
SE374279B (en) | 1975-03-03 |
AU458053B2 (en) | 1975-02-20 |
FR2117183A5 (en) | 1972-07-21 |
SU540554A3 (en) | 1976-12-25 |
IE35857L (en) | 1972-06-02 |
DE2159346A1 (en) | 1972-06-08 |
NL171237B (en) | 1982-10-01 |
CA1004214A (en) | 1977-01-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |