SU1731067A3 - Способ получени L-2-амино-4-(гидроксиметилфосфинил)-масл ной кислоты - Google Patents
Способ получени L-2-амино-4-(гидроксиметилфосфинил)-масл ной кислоты Download PDFInfo
- Publication number
- SU1731067A3 SU1731067A3 SU874202766A SU4202766A SU1731067A3 SU 1731067 A3 SU1731067 A3 SU 1731067A3 SU 874202766 A SU874202766 A SU 874202766A SU 4202766 A SU4202766 A SU 4202766A SU 1731067 A3 SU1731067 A3 SU 1731067A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- atcc
- streptomyces
- acid
- ifo
- hydroxymethylphosphinyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 16
- FNJQGUKETYGBGL-BYPYZUCNSA-N OC(=O)[C@@H](N)CCP(=O)CO Chemical compound OC(=O)[C@@H](N)CCP(=O)CO FNJQGUKETYGBGL-BYPYZUCNSA-N 0.000 title abstract description 5
- 102000003929 Transaminases Human genes 0.000 claims abstract description 24
- 108090000340 Transaminases Proteins 0.000 claims abstract description 24
- YJTNHDYMQPHXFO-UHFFFAOYSA-N 4-(hydroxymethylphosphinyl)-2-oxobutyric acid Chemical compound CP(O)(=O)CCC(=O)C(O)=O YJTNHDYMQPHXFO-UHFFFAOYSA-N 0.000 claims abstract description 17
- 241000187747 Streptomyces Species 0.000 claims description 13
- 235000013922 glutamic acid Nutrition 0.000 claims description 13
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000004220 glutamic acid Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 9
- 208000019585 progressive encephalomyelitis with rigidity and myoclonus Diseases 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims description 6
- -1 hydroxymethylphosphinyl Chemical group 0.000 claims description 5
- 238000005891 transamination reaction Methods 0.000 claims description 5
- 241000589516 Pseudomonas Species 0.000 claims description 4
- 241000187311 Streptomyces morookaense Species 0.000 claims description 3
- 241001468213 Amycolatopsis mediterranei Species 0.000 claims description 2
- 241000894006 Bacteria Species 0.000 claims description 2
- 241000235395 Mucor Species 0.000 claims description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 2
- 235000003704 aspartic acid Nutrition 0.000 claims description 2
- 241000187191 Streptomyces viridochromogenes Species 0.000 claims 3
- LCTONWCANYUPML-UHFFFAOYSA-N PYRUVIC-ACID Natural products CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 claims 2
- 241000187759 Streptomyces albus Species 0.000 claims 2
- 229940107700 pyruvic acid Drugs 0.000 claims 2
- OZDAOHVKBFBBMZ-UHFFFAOYSA-N 2-aminopentanedioic acid;hydrate Chemical compound O.OC(=O)C(N)CCC(O)=O OZDAOHVKBFBBMZ-UHFFFAOYSA-N 0.000 claims 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims 1
- 241000222120 Candida <Saccharomycetales> Species 0.000 claims 1
- 241000203619 Nocardiopsis dassonvillei Species 0.000 claims 1
- 241000187392 Streptomyces griseus Species 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims 1
- 244000005700 microbiome Species 0.000 abstract description 8
- 239000004009 herbicide Substances 0.000 abstract description 2
- 150000001371 alpha-amino acids Chemical class 0.000 abstract 1
- 235000008206 alpha-amino acids Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 9
- 235000015097 nutrients Nutrition 0.000 description 9
- 235000010633 broth Nutrition 0.000 description 8
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 7
- 229960002989 glutamic acid Drugs 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229940024606 amino acid Drugs 0.000 description 6
- 235000001014 amino acid Nutrition 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- CKLJMWTZIZZHCS-UHFFFAOYSA-N D-OH-Asp Natural products OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 4
- 238000005119 centrifugation Methods 0.000 description 4
- KPGXRSRHYNQIFN-UHFFFAOYSA-N 2-oxoglutaric acid Chemical compound OC(=O)CCC(=O)C(O)=O KPGXRSRHYNQIFN-UHFFFAOYSA-N 0.000 description 3
- CKLJMWTZIZZHCS-UWTATZPHSA-N L-Aspartic acid Natural products OC(=O)[C@H](N)CC(O)=O CKLJMWTZIZZHCS-UWTATZPHSA-N 0.000 description 3
- 229960005261 aspartic acid Drugs 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 230000000813 microbial effect Effects 0.000 description 3
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical compound Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 241000187391 Streptomyces hygroscopicus Species 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- 239000012897 dilution medium Substances 0.000 description 2
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 2
- 238000006911 enzymatic reaction Methods 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 239000002054 inoculum Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 150000004715 keto acids Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 241000186361 Actinobacteria <class> Species 0.000 description 1
- 241000222122 Candida albicans Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 150000008537 L-aspartic acids Chemical class 0.000 description 1
- 150000008539 L-glutamic acids Chemical class 0.000 description 1
- 241000607715 Serratia marcescens Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012431 aqueous reaction media Substances 0.000 description 1
- 150000001510 aspartic acids Chemical class 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 239000012531 culture fluid Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000000291 glutamic acid group Chemical group N[C@@H](CCC(O)=O)C(=O)* 0.000 description 1
- 150000002307 glutamic acids Chemical class 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 239000008055 phosphate buffer solution Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011218 seed culture Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009210 therapy by ultrasound Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/04—Alpha- or beta- amino acids
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Biotechnology (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Enzymes And Modification Thereof (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13174386 | 1986-06-09 | ||
| JP1251387 | 1987-01-23 | ||
| JP7447687 | 1987-03-30 | ||
| JP10115287 | 1987-04-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1731067A3 true SU1731067A3 (ru) | 1992-04-30 |
Family
ID=27455820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU874202766A SU1731067A3 (ru) | 1986-06-09 | 1987-06-08 | Способ получени L-2-амино-4-(гидроксиметилфосфинил)-масл ной кислоты |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0249188B1 (https=) |
| JP (1) | JP2589693B2 (https=) |
| KR (1) | KR940005654B1 (https=) |
| CN (1) | CN87105130A (https=) |
| AT (1) | ATE111530T1 (https=) |
| AU (1) | AU599985B2 (https=) |
| DE (1) | DE3750523T2 (https=) |
| DK (1) | DK289687A (https=) |
| ES (1) | ES2059324T3 (https=) |
| HU (1) | HU200342B (https=) |
| IL (1) | IL82786A0 (https=) |
| IN (1) | IN165699B (https=) |
| NZ (1) | NZ220576A (https=) |
| SU (1) | SU1731067A3 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2275428C2 (ru) * | 1999-04-30 | 2006-04-27 | Авентис Кропсайенс Гмбх | Способ получения l-фосфинотрицина путем ферментативного трансаминирования с помощью аспартата |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4826766A (en) * | 1985-09-23 | 1989-05-02 | Genetics Institute, Inc. | Production of amino acids using coupled aminotransferases |
| EP0533216B1 (de) * | 1986-06-04 | 2000-03-22 | Hoechst Schering AgrEvo GmbH | Verfahren zur Herstellung von L-tertiär-Leucin durch Transaminierung |
| DE3818851A1 (de) * | 1988-06-03 | 1989-12-14 | Hoechst Ag | Neue transaminase, ihre herstellung und ihre verwendung |
| EP0349965A3 (en) * | 1988-07-04 | 1990-06-13 | Meiji Seika Kaisha Ltd. | Novel genes encoding transaminase |
| JPH0693839B2 (ja) * | 1988-10-27 | 1994-11-24 | 明治製菓株式会社 | Ｌ−２−アミノ−４−（ヒドロキシメチルホスフィニル）酪酸の製造方法 |
| DE3842025A1 (de) * | 1988-12-14 | 1990-07-05 | Hoechst Ag | Verfahren zur herstellung von l-phosphinothricin |
| DE3920570A1 (de) * | 1989-06-23 | 1991-01-03 | Hoechst Ag | Verfahren zur isolierung von l-2-amino-4-methylphosphinobuttersaeure-ammoniumsalz aus einer enzymatischen transaminierungsloesung |
| DE4030578A1 (de) * | 1990-09-27 | 1992-04-16 | Hoechst Ag | Verfahren zur herstellung von l-phosphinothricin durch eine gekoppelte enzymatische reaktion |
| TW353663B (en) * | 1991-04-06 | 1999-03-01 | Hoechst Ag | Process for the preparation of phosphorus-containing L-amino acids, their derivatives and intermediates for this process |
| IL101539A (en) | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Non-hygroscopic mono-ammonium salts of n-phosphonomethyl glycine derivatives their preparation and pesticidal compositons containing them |
| HU212802B (en) | 1991-07-19 | 1996-11-28 | Monsanto Europe Sa | Phytoactive sack-like composition containing glyphosate-izopropylamine salt |
| JPH06245780A (ja) * | 1993-02-25 | 1994-09-06 | Meiji Seika Kaisha Ltd | Ｌ−２−アミノ−４−（ヒドロキシメチルホスフィニル）−酪酸の製造法 |
| US6910691B2 (en) * | 2003-03-04 | 2005-06-28 | Sywan-Min Shih | Cubic puzzle |
| WO2007100101A1 (ja) * | 2006-03-02 | 2007-09-07 | Meiji Seika Kaisha, Ltd. | アスパラギン酸アミノトランスフェラーゼ遺伝子およびｌ－ホスフィノスリシンの製造方法 |
| CN101641363A (zh) | 2007-03-23 | 2010-02-03 | 明治制果株式会社 | 含磷的α-酮酸的制造方法 |
| PH12014500673A1 (en) | 2011-09-30 | 2014-05-05 | Meiji Seika Pharma Co Ltd | Method for producing glufosinate p free acid |
| EP3294064A1 (en) | 2015-05-11 | 2018-03-21 | Bayer CropScience AG | Herbicide combinations comprising l-glufosinate and indaziflam |
| CN105567780A (zh) * | 2016-01-14 | 2016-05-11 | 重庆惠健生物科技有限公司 | 一种l-草铵膦的酶-化学催化去消旋化制备方法 |
| CN105603015B (zh) * | 2016-01-22 | 2018-12-11 | 浙江大学 | 一种l-草铵膦的生产方法 |
| IL261271B2 (en) | 2016-03-02 | 2025-03-01 | Agrimetis Llc | Methods for preparing L-glucosinate |
| WO2018108794A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von d-glufosinat oder dessen salzen unter verwendung von ephedrin |
| WO2018108797A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von l-glufosinat oder dessen salzen unter verwendung von ephedrin |
| WO2019018406A1 (en) | 2017-07-18 | 2019-01-24 | Agrimetis, Llc | METHODS OF PURIFYING L-GLUFOSINATE |
| BR112020001585A2 (pt) | 2017-07-27 | 2020-08-11 | Basf Se | usos de uma composição e método para controlar plantas prejudiciais em uma cultura de campo tolerante a glufosinato |
| CN108484665B (zh) * | 2018-04-16 | 2020-06-23 | 浙江工业大学 | 一种从酶转化液中分离提取l-草铵膦的方法 |
| US12559777B2 (en) | 2018-09-05 | 2026-02-24 | Basf Se | Methods for improving yields of L-glufosinate |
| BR112022014559A2 (pt) | 2020-01-23 | 2022-09-20 | Basf Se | Composição agroquímica, composto de fórmula (i), solução adjuvante e método para controlar vegetação indesejável |
| US20230076646A1 (en) | 2020-01-31 | 2023-03-09 | Basf Se | Herbicide combinations comprising glufosinate and sulfentrazone |
| US20230091888A1 (en) | 2020-01-31 | 2023-03-23 | Basf Se | Herbicide combinations comprising glufosinate and selected ppo inhibitors |
| US12568968B2 (en) | 2020-01-31 | 2026-03-10 | Basf Se | Herbicide combinations comprising glufosinate and epyrifencacil |
| BR112022014879A2 (pt) | 2020-01-31 | 2022-09-20 | Basf Se | Combinação de herbicidas, composição, métodos de produção de combinações de herbicidas, de tratamento ou proteção de plantas produtoras em fileiras e de tratamento ou proteção de plantas especializadas e uso da combinação de herbicidas |
| WO2021151744A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and oxyfluorfen |
| BR112022014800A2 (pt) | 2020-01-31 | 2022-09-20 | Basf Se | Combinação de herbicidas, composição, métodos para produzir combinação de herbicidas, para controlar o crescimento indesejado das plantas e/ou controle de plantas nocivas e para tratar ou proteger culturas e uso da combinação de herbicidas |
| BR112022014950A2 (pt) | 2020-01-31 | 2022-09-20 | Basf Se | Combinação de herbicidas, composição, métodos de produção de combinações de herbicidas, de controle do crescimento vegetal indesejado e de tratamento ou proteção de plantas e uso da combinação de herbicidas |
| BR112022014824A2 (pt) | 2020-01-31 | 2022-12-13 | Basf Se | Combinação de herbicidas, composição, métodos de produção de combinações herbicidas, de tratamento ou proteção de plantas produtoras em fileiras e de tratamento ou proteção de plantas especializadas e uso da composição herbicida |
| BR112022014960A2 (pt) | 2020-01-31 | 2022-09-20 | Basf Se | Combinação de herbicidas, composição, métodos de produção de uma combinação de herbicidas, para controlar o crescimento de plantas indesejadas, para tratar ou proteger culturas em linha e culturas de especialidades e uso |
| WO2021151734A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and flumiclorac-pentyl |
| WO2021151741A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and tiafenacil |
| BR112022014727A2 (pt) | 2020-01-31 | 2022-10-11 | Basf Se | Combinação de herbicidas, composição, métodos para produzir uma combinação de herbicidas, para controlar o crescimento indesejado das plantas, para tratar ou proteger culturas em linha e para tratar ou proteger culturas especiais e uso de uma combinação de herbicidas |
| US20230068414A1 (en) | 2020-01-31 | 2023-03-02 | Basf Se | Herbicide combinations comprising glufosinate and trifludimoxazin |
| BR112022014955A2 (pt) | 2020-01-31 | 2022-09-20 | Basf Se | Combinação herbicida, composição, métodos para produzir uma combinação herbicida, para controlar o crescimento indesejado das plantas e/ou controlar plantas nocivas, para tratar ou proteger culturas em linha e para tratar ou proteger culturas especiais e uso de combinação herbicida |
| EP4000400A1 (en) | 2020-11-17 | 2022-05-25 | Basf Se | Herbicide combination comprising glufosinate, saflufenacil and trifludimoxazin |
| WO2022078972A1 (en) | 2020-10-12 | 2022-04-21 | Basf Se | Herbicide combination comprising glufosinate, saflufenacil and trifludimoxazin |
| US20230397609A1 (en) | 2020-10-27 | 2023-12-14 | Basf Se | Pesticide microemulsion compositions |
| CR20230380A (es) | 2021-02-05 | 2023-10-12 | Basf Se | Composiciones herbicidas liquidas |
| IL307248A (en) | 2021-04-01 | 2023-11-01 | Basf Se | Methods for preparing L-glufosinate |
| CA3219689A1 (en) | 2021-05-21 | 2022-11-24 | Anna SOYK | Computer-implemented method for applying a glutamine synthetase inhibitor on an agricultural field |
| EP4432830A1 (en) | 2021-11-15 | 2024-09-25 | Basf Se | Method for increasing the efficacy of a herbicide |
| CN118401535A (zh) | 2021-12-10 | 2024-07-26 | 巴斯夫欧洲公司 | 草铵膦衍生物的酶促脱氨基甲酰化 |
| CN118369324A (zh) | 2021-12-10 | 2024-07-19 | 巴斯夫欧洲公司 | 使用基于乙内酰脲酶的工艺的草铵膦合成 |
| CA3266992A1 (en) | 2022-09-14 | 2024-03-21 | Basf Se | USE OF AN ALKYLETHOLTER SULFATE TO IMPROVE THE EFFICACY OF HERBICIDES |
| EP4338592A1 (en) | 2022-09-15 | 2024-03-20 | Basf Se | Use of compound for improving the efficacy of herbicides |
| CN120641571A (zh) | 2023-02-23 | 2025-09-12 | 巴斯夫欧洲公司 | 从氰醇或氰醇衍生物制备l-草铵膦的方法 |
| TW202512923A (zh) | 2023-06-13 | 2025-04-01 | 德商巴地斯顏料化工廠 | 使用基於醯胺酶之製程合成固殺草 |
| AR133862A1 (es) | 2023-09-21 | 2025-11-12 | Specialty Operations France | Emulsión en agua concentrada que comprende glufosinato, inhibidor de vlcfa y tensioactivos específicos |
| AR133857A1 (es) | 2023-09-21 | 2025-11-05 | Specialty Operations France | Composiciones herbicidas que comprenden tensioactivos específicos |
| WO2025219238A1 (en) | 2024-04-15 | 2025-10-23 | Basf Se | Process for producing l-glufosinate from a diol or diol derivative |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4466913A (en) * | 1981-06-30 | 1984-08-21 | Maiji Seika Kaisha Ltd. | Phosphorus-containing compounds and process for producing the same |
| SE8502315L (sv) * | 1984-07-05 | 1986-01-06 | Grace W R & Co | Forbettrat transamineringsforfarande for framstellning av aminosyror |
| EP0533216B1 (de) * | 1986-06-04 | 2000-03-22 | Hoechst Schering AgrEvo GmbH | Verfahren zur Herstellung von L-tertiär-Leucin durch Transaminierung |
-
1987
- 1987-06-02 AU AU73750/87A patent/AU599985B2/en not_active Ceased
- 1987-06-03 IN IN438/CAL/87A patent/IN165699B/en unknown
- 1987-06-04 DK DK289687A patent/DK289687A/da not_active Application Discontinuation
- 1987-06-05 NZ NZ220576A patent/NZ220576A/xx unknown
- 1987-06-05 IL IL82786A patent/IL82786A0/xx unknown
- 1987-06-05 JP JP62139933A patent/JP2589693B2/ja not_active Expired - Lifetime
- 1987-06-08 SU SU874202766A patent/SU1731067A3/ru active
- 1987-06-08 HU HU872606A patent/HU200342B/hu not_active IP Right Cessation
- 1987-06-08 CN CN198787105130A patent/CN87105130A/zh active Pending
- 1987-06-09 EP EP87108292A patent/EP0249188B1/en not_active Expired - Lifetime
- 1987-06-09 DE DE3750523T patent/DE3750523T2/de not_active Expired - Lifetime
- 1987-06-09 AT AT87108292T patent/ATE111530T1/de not_active IP Right Cessation
- 1987-06-09 KR KR1019870005835A patent/KR940005654B1/ko not_active Expired - Lifetime
- 1987-06-09 ES ES87108292T patent/ES2059324T3/es not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| Опубликованна за вка JP bfe 47485/82, ка. С 12 Р 13/04, 1984. За вка EP № 135846, кл. С 12 Р 13/04, 1985. * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2275428C2 (ru) * | 1999-04-30 | 2006-04-27 | Авентис Кропсайенс Гмбх | Способ получения l-фосфинотрицина путем ферментативного трансаминирования с помощью аспартата |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ220576A (en) | 1990-05-28 |
| EP0249188A2 (en) | 1987-12-16 |
| AU599985B2 (en) | 1990-08-02 |
| KR940005654B1 (ko) | 1994-06-22 |
| KR880000593A (ko) | 1988-03-28 |
| JPS6427485A (en) | 1989-01-30 |
| AU7375087A (en) | 1987-12-10 |
| DK289687D0 (da) | 1987-06-04 |
| IN165699B (https=) | 1989-12-16 |
| EP0249188B1 (en) | 1994-09-14 |
| DK289687A (da) | 1987-12-10 |
| ATE111530T1 (de) | 1994-09-15 |
| IL82786A0 (en) | 1987-12-20 |
| EP0249188A3 (en) | 1989-01-25 |
| CN87105130A (zh) | 1988-06-15 |
| HUT46698A (en) | 1988-11-28 |
| JP2589693B2 (ja) | 1997-03-12 |
| ES2059324T3 (es) | 1994-11-16 |
| DE3750523T2 (de) | 1995-02-02 |
| DE3750523D1 (de) | 1994-10-20 |
| HU200342B (en) | 1990-05-28 |
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