HU212802B - Phytoactive sack-like composition containing glyphosate-izopropylamine salt - Google Patents

Abstract

New non-absorbent crystal mono-amino saline general I formulas, in which -R1 means hydroxyl or alkyl, -A means groups of C1-4 alkyl amino - or amino alkyl with primary or secondary amino-clumps, the best with - CH2-NH- or -CH(NH2)-CH2- groups.-B means amino ion or amino ion changed with alkyl. There are also methods to obtain this saline, producing the saline of the I formula according to any generally known method for saline abstraction, where - avoiding other pollution - in a saline forming process or after it, the formation of di-ammonium saline general V formula, in which -R1, A and B has the meanings described above, is eliminated or repressed. The described herbicidal or plant growth regulating compositions with this non-absorbent saline, its abstraction methods, and the processing methods of unacceptable plants and weeds, and also tough and flexible dry capsules for storing these compositions are made of polymers which are deliquescent in water.

Description

(57) EXTRAS

FIELD OF THE INVENTION The present invention relates to a solid phytoactive composition containing glyphosate salt as an active ingredient, together with customary excipients, which is packaged in a polymeric bag that is ready to use, water soluble, dry solid and flexible. At least one active ingredient of the composition is a non-hygroscopic solid N-phosphonomethylglycine monoisopropylamine salt. The composition may optionally contain additional solid active ingredients compatible with the above active ingredient.

Scope of the description: 8 pages

CO

HU 212 802

HU 212 802 Β

FIELD OF THE INVENTION The present invention relates to a solid phytoactive composition containing an N-phosphonomethylglycine monoisopropylamine salt as an active ingredient, together with the usual excipients, which is packaged in a polymeric bag that is ready for use, water soluble, dry solid and flexible. One of the active ingredients is a non-hygroscopic solid N-phosphonomethylglycine monoisopropylamine salt and optionally contains other known solid active ingredients which are compatible with the above active ingredient.

The N-phosphonomethylglycine monoisopropylamine salt which is non-hygroscopic and thus stored, transported, etc. in the bags until use, can be used to formulate the bags of the invention. Such non-hygroscopic salts and their preparation are described in U.S. Pat. in our Hungarian patent application.

"Non-hygroscopic" as used herein means that the product has a water content of 60% relative humidity at 25 ° C and a water uptake of less than 0.1%. The new, non-hygroscopic N- (phosphonomethyl) glycine monoisopropylamine salt is crystalline. It was found that it appeared in the form of α and β, which differed in melting points from crystalline-plate levels in X-ray diffraction measurements. Both forms can be used to be presented in a sachet according to the invention.

"Phytoactive effect" as used herein includes known plant effects of glyphosate, namely herbicidal, growth regulating, defoliant effects.

N-phosphonomethylglycine (glyphosate) and its derivatives are known worldwide and are widely used as active ingredients in highly effective herbicides and plant growth regulators. The preparation and use of these active ingredients are described, inter alia, in 3,445,675; 3,556,762; 3,799,758; 3,977,860; 3,868,407; U.S. Patent No. 4,405,531; and Hungarian Patent Application No. 184,601. It is known from the literature and from our own experience that N- (phosphonomethyl) glycine is practically insoluble in water (12 g / l). Therefore, N-phosphonomethylglycine is generally prepared in the form of a water-soluble salt and is thus marketed in various formulations. Of these, the water-soluble monoisopropylamine salt of N-phosphonomethylglycine is most widely used. Preparations containing these salts are commercially available in the form of an aqueous solution rather than in solid form and therefore appear in expensive packaging containers which are not usually completely emptied by the application of the herbicide and which still contain dispersed containers which are dispersed in the environment. certain amounts of herbicides which may be harmful to the environment. Roundup ^R and Glialka ^R herbicidal formulations contain the N-phosphonomethylglycine monoisopropylamine salt, surfactants, additives and water and are accordingly marketed in containers.

Many research and development efforts are currently underway around the world to produce ready-to-use formulations containing water-soluble glyphosate or glyphosate derivatives that do not pollute the environment.

Such formulations are described in U.S. Pat.

28), published in Hungarian Patent Application Rhone-Poulenc Agrochimie. BACKGROUND OF THE INVENTION The present invention relates to a ready-to-use herbicidal combination comprising a wettable powder formulation containing N-phosphonomethylglycine or a sodium or potassium salt thereof when enclosed in a bag in a dry and water-soluble polymer. The present invention also relates to a combination of the above agents and other herbicides. It has been reported that attempts have been made to prepare a water soluble packaging composition from the glyphosate monoisopropylamine salt, but it has been found that the glyphosate monoisopropylamine salt cannot be used (not solved) because of the hygroscopic nature of the active ingredient. It has also been found that the aqueous solution in which the salt is most commonly marketed is even less suitable for filling into water-soluble bags after the aqueous solution dissolves the bag or bag immediately before use.

SUMMARY OF THE INVENTION It is an object of the present invention to provide solid compositions containing the most advantageous property of the N-phosphonomethylglycine monoisopropylamine salt in such a manner as to minimize adverse effects on the environment, users should be in direct contact with the plant protection product and the use of the container itself should be minimized. From the literature and experience, we know that water-soluble plastics or polymers may be suitable for solving these environmental problems.

It is a further object of the present invention to provide an environmentally friendly herbicidal composition containing a glyphosate monoisopropylamine salt which is ready for use, easy to handle and safe in a water-soluble bag or sachet.

The present invention is based on the discovery that the N-phosphonomethylglycine monoisopropylamine salt prepared according to the process described in our Hungarian Patent Application No. 1248/91 (published as T 72 428) has a well-defined crystalline, non-hygroscopic salt. In terms of material and handling, the formulations of the active ingredient thus prepared can be easily filled into water-soluble plastic bags to provide a state-of-the-art, environmentally friendly, ready-to-use herbicide.

SUMMARY OF THE INVENTION The present invention relates to ready-to-use solid phytoactive compositions which, in a bag or sack made of water-soluble polymer, are non-hygroscopic N- (phosphonomethyl)

They contain a salt of cinnamon monoisopropylamine in water-soluble or wettable solid form.

The bags used in the compositions of the present invention have a size of 0.1 to 10 kg, preferably 0.5 to 5 kg. It is preferred that the bags are completely filled with the herbicidal composition. The bags used in the present invention are solid and preferably flexible. Their wall thickness is generally 20-100 microns, preferably 30-60 microns, and has at least one welded edge. It is preferred that each bag or bag contains a unit amount of plant treatment.

The water-soluble polymer bags used in the present invention are known per se. The water-soluble polymer may be, for example:

- polyvinyl alcohol - preferably a vinyl alcohol polymer plasticized with polyhydric alcohols,

- methylcellulose,

- ethylene oxide copolymers,

- polymers of vinyl pyrrolidone or vinyl acetate,

- gelatin, carboxymethylcellulose, dextrose, hydroxyethylcellulose, or

methylcellulose combined with polyhydric alcohols such as ethylene glycol, propylene glycol, glycerol or sorbitol.

The compositions of the invention are generally somewhat fragile, so it is necessary to place them in a less fragile outer container or multipack, preferably made of a cheap material such as plastic, cardboard or aluminum. These external supports do not pose a pollutant to the environment as they do not come into direct contact with pesticides.

In the case of the N-phosphonomethylglycine monoisopropylamine salt of the present invention or combinations thereof, the solid herbicidal composition in sacks may contain other known components such as protective colloids, adhesives, thickeners, thixotropic agents, absorption agents, stabilizers. The non-hygroscopic N- (phosphonomethyl) glycine monoisopropylamine salt content of the composition of the present invention is from 0.001% to 95%. The composition comprises from 0.001% to 95% by weight of one or more herbicidal active ingredients and from 99% to 5% by weight of a solid carrier, one or more surfactants and / or other additives.

In general, it will be appreciated that the compounds used in the present invention may be combined with solid or liquid additives commonly used in the manufacture of pesticides. Formulations containing salts containing ethoxylated fatty amine and ammonium ions, in particular sulfate, are preferred.

Optionally, it may also contain other pesticidal agents compatible with the glyphosate salt, preferably insecticides, fungicides or herbicides, and other plant growth regulators.

The following is a list of some pesticides which may be advantageously used in combination with the non-hygroscopic glyphosate monoisopropylamine salt in the solid compositions of the present invention.

- 2,4-D (2,4-dichlorophenoxyacetic acid),

- endothalate (7-oxabicyclo [2.2.1] heptene-2,3-dicarboxylic acid),

- 2,4,5-T (2,4,5-trichlorophenoxyacetic acid),

- MCPA (4-chloro-o-tolyloxyacetic acid),

- MCPB [ammonium / 3-amino-3-carboxypropyl / methylphosphinate],

- glufosinate [ammonium (3-amino-3-carboxypropyl) methylphosphinate]

- bialafos (dl-homoalanine-4-ylmethylphosphinate),

- ethephon (2-chloroethane phosphonic acid),

- mecoprop (2- (2-methyl-4-chlorophenoxy) propionic acid),

- picloram (4-amino-3,5,6-trichloro-picolic acid),

- benzac (2,3,6-trichlorobenzoic acid),

- dalapon (2,2-dichloropropionic acid),

- dicamba (3,6-dichloro-o-anisic acid),

- dichlorprop (2- / 2,4-dichlorophenoxy / propionic acid),

- imazaquin (2- [4,5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl] -3-quinolinecarboxylic acid),

- imazetapyr (2- [4,5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl] -5-ethyl-3-pyridinecarboxylic acid),

- atrazine (2-chloro-4- (ethylamino) -6- (isopropylamino) -s-triazine),

- simazine (2-chloro-4,6-bis (ethylamino) -s-triazine),

- diuron [3- (3,4-dichlorophenyl) -1,2-dimethylurea],

- linuron (3- (3,4-dichlorophenyl) -1-methoxy-1-methylurea),

- NES (1-naphthyl acetic acid),

- 2- (3- (4,6-dimethylpyrimidin-2-yl) -ureido-sulfonyl) -benzoic acid,

- chlorosulfuron (1- (2-chlorophenylsulfonyl) -3- (4-methoxy-6-methyl-1,3,5-triazin-2-ylurea),

- Methylsulfuron (Methyl 2 - [[4-methoxy-4-methyl-1,3,5-triazinyl-2-yl] aminocarbonyl] -aminosulfonyl] benzoate)

- chlororinuron (ethyl 2 - [(4-chloro-6-methoxypyrimidin-2ylamino) carbonylaminosulfonylbenzoate),

- fomesafen (5- [2-chloro-4- (trifluoromethyl) phenoxy] -N- (methylsulfonyl) -2-nitrobenzamide),

- oxyfluorfen (2-chloro-1- (3-ethoxy-4-nitrophenoxy) -4-trifluoromethyl-benzene),

fenoxaprop-P [(R) -2 - [(R) -2- [4- (6-chloro-1,3-benzoxazol-2-yloxy) phenoxypropionic acid]

- alachlor (2-chloro-2,6-diethyl-N- (methoxymethyl) acetanilide),

- propachlor (N-isopropyl-2-chloroacetanilide),

- butachlor (N-butoxymethyl-2,6-diethyl-2-chloroacetanilide),

- metolachlor (2-chloro-2-ethyl-6-methyl-N- (1-methyl-2-methoxyethyl) acetanilide).

In combination with the right partners

The content of N-phosphonomethylglycine monoisopropylamine salt is 0.001-95%.

Since these are solid active ingredients, they can be combined in any ratio in the formulation to suit the purpose.

The composition, after or with mixing, may be formulated into any desired form e.g. pellets, powders, tablets, granules, etc. Suitable equipment, extruder and dryer, as well as granulating equipment are used.

The carrier can be any carrier, known in the art, of organic or inorganic, natural or synthetic origin, compatible with the active ingredient and miscible, and to facilitate application and incorporation into the plant. These carriers are generally known and need to be agriculturally acceptable. The carrier is preferably a solid such as clay, natural or synthetic silicate, silica, in particular various resins, waxes or solid fertilizers.

The surfactant may be an emulsifying, dispersing, wetting agent of the ionic or nonionic type, or a mixture of these surfactants. Examples include:

- water-soluble alkyl sulphates, alkyl phosphates, alkyl benzene sulphonates,

- naphthyl sulphonates and alkyl naphthyl sulphonates,

- sulphated fatty alcohols, amines, acid amides,

- sulphated or sulphonated fatty acid esters,

- sulphonated vegetable oils,

- alkylphenols, in particular polyoxyethylene derivatives of isooctylphenol and nonylphenol, and polyoxyethylene derivatives of mono- (long-chain) fatty acid esters of hexital anhydrides,

- polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ethers,

- polyoxyethylene alkyl aryl ether formaldehyde condensates,

- polyoxyethylene alkylene aryl ethers,

- polyoxyalkylene alkyl esters,

- polyoxyalkylene sorbital, sorbitan or. glycerol esters,

- polyoxyalkylene block copolymers,

- polyoxyalkylene alkylsulfonamides,

- polyoxyalkylene alkyl glycerol esters,

- polyoxyalkylene resin esters,

- polyoxypropylene block copolymers,

- polyoxyethylene oleyl ethers,

- polyoxyalkylene alkyl phenols, mixtures thereof and the like,

polyoxyalkylene alkylamines such as ethoxylated tallow amine (preferably containing 15-20 moles ethylene oxide),

- ethoxylated oleinamine, ethoxylated soya amine, ethoxylated cocoa amine, ethoxylated synthetic alkyl amines,

- propoxylated amines and their mixtures,

- polyoxyalkylene alkyl and alkyl aryl ether sulphates,

- polyoxyalkylene styrylphenyl ether sulphates,

- alkyl naphthalene formaldehyde condensates,

- alkyl diphenyl ether sulfonates,

- polyoxyalkoxyalkyl phosphates,

- polyoxyalkylene phenyl ether phosphates,

- polyoxyalkyl phenol phosphates,

- polycarboxylates, N-methyl fatty acid laurides, mixtures thereof and the like,

- various amine oxides such as lauryldimethylamine oxide and the like,

- surfactant salts of N-phosphonomethylglycine, such as the N, N-bis (hydroxyethyl cocoamine) salt of N-phosphonomethylglycine,

- saturated fatty alcohols, cetyl, stearyl, oleyl alcohols, 2-octyldodecanol, isotridecyl alcohol,

- esters of organic acids, ethyl lactic acid, dibutyl phthalate, isopropyl ester of adipic acid,

- fatty acids, fatty acid salts, fatty acid esters,

- ethyl oleate, ethyl stearate, di-n-butyl adipate,

- lauric hexyl ester, dipropylene glycol pelargonate,

- isopropyl myristate, isopropyl palmitate, isopropyl stearate,

- oleic ester of oleic acid, dodecyl ester of oleic acid, polyglyceryl lauric ester,

- caprylic / caprylic esters of saturated fatty alcohols, their mixtures and the like,

- glycerol-polyvinyl alcohol derivatives,

- phospholipids, alkyl polyglycoside derivatives,

- methyl, hydroxyethyl, hydroxymethyl and other cellulose derivatives,

- polyvinyl derivatives,

- lignin sulphonates, polymeric alkyl naphthalene sulphonates,

- Polymethylene bis (naphthalene sulphonate), N-methylN (long chain) fatty acid laurates

- quaternary ammonium salts, alkyl or alk. alkylaryl ammonium halides such as C 10 -C 18 alkyldimethyl, alkyltrimethyl, alkylbenzyldimethylammonium chloride, preferably cetyltrimethylammonium chloride,

- anionic, cationic, nonionic or nonionic. amphoteric fluoroaliphatic wetting agents,

silicone copolymer based surfactants, tetraethoxysilane derivatives and the like.

The compositions may advantageously contain nitrogenous organic or inorganic compounds, urea and urea derivatives, inorganic salts such as calcium, sodium, ammonium chloride, sulfate, phosphate, borate and the like,

- paraffinic hydrocarbons, aliphatic mineral oils, natural vegetable oils, organic solvents,

inert carriers such as diatomaceous earth, kaolin, attapulgite, fuller earth, montmortillonite, benzonite, synthetic silica, thiosulfates.

The use of surfactants is generally unavoidable if water-insoluble or poorly soluble combination partners, additives, inert carriers are used and water is used as the carrier for the final application.

HU 212 802 Β

The water-soluble or wettable solid compositions will generally contain one or more active ingredients, optionally a solid carrier, a wetting agent, a dispersing agent and, if desired, one or more stabilizers and / or other additives.

EXAMPLES

1. PREPARATIONS

The following describes some of the water-soluble or wettable solid compositions of the present invention and their uses. In each of the examples, one of the active ingredients is the non-hygroscopic N-phosphonomethylglycine monoisopropylamine salt (abbreviated in the examples as "glyphosate-IPA"). Weight percentages are always included.

1.1. Glyphosate IPA 98% Ethoxylated nonylphenol 2% 1.2. Glyphosate IPA 95% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 4% 1.3. Glyphosate IPA 80% Ethoxylated nonylphenol 2% Ethoxylated fatty amine 18% 1.4. Glyphosate IPA 77% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 7% Ethoxylated fatty amine 10% Urea 5% 1.5. Glyphosate IPA 60% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 7% Ethoxylated fatty amine 10% Polyalkoxylated fatty alcohol 2% Ammonium sulfate 20% 1.6. Glyphosate IPA 70% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 4% Ammonium sulfate 20% Silicon dioxide 5% 1.7. Glyphosate IPA 68.00% Ethoxylated nonylphenol 2.00% Ethoxylated alkylamine 4.50% Ethoxylated fatty amine 9.60% Isotridecyl alcohol polyglycol ether 7.30% Potassium chloride 3.45% 1-naphthylacetic acid 0.05% Boric acid 0.10% Silicon dioxide 5.00% 1.8. Glyphosate IPA 50% 2,4-D IPA 32% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 4% Ammonium sulfate 8% Silicon dioxide 5% 1.9. Glyphosate IPA 40% Glufosinate-IPA 7% Ethoxylated nonylphenol 2% Sodium lignosulfonate 3% Ammonium sulfate 33% Silicon dioxide 5%

Kaolin 10% 1:10. Glyphosate IPA 40% dimethipin 7% Ethoxylated nonylphenol 2% Sodium lignosulfonate 3% Ammonium sulfate 33% Silicon dioxide 5% Kaolin 10% 1:11. Glyphosate IPA 50% oxyfluorfen 4% Ethoxylated nonylphenol 2% Sodium lignosulfonate 3% Silicon dioxide 5% Ammonium sulfate 16% Kaolin 20% 1:12. Glyphosate IPA salt 40% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 4% Ethoxylated fatty amine 15% Ammonium sulfate 30% Kaolin 10% 1:13. Glyphosate-IPA salt 80% ATPLUS 411 ^R Surfactant (ICI) 19% Polyalkoxylated fatty alcohol 1% 1:14. Glyphosate IPA 40% Glufosinate-ammonium salt 20% Ethoxylated nonylphenol 1% Ethoxylated alkylamine 4% Ammonium sulfate 35% 1:15. Glyphosate IPA 0.05% Ammonium sulfate 80.00% Ethoxylated nonylphenol 1.00% Ethoxylated fatty amine 18.95% 1:16. Glyphosate IPA 99% Ethoxylated nonylphenol 1% 1.17. Glyphosate IPA 1% Dissover S ^R (SZVKI) 99% 1.18. Glyphosate IPA 1% Ammonium sulfate 70% Ammonium nitrate 28% Polyalkoxylated fatty alcohol 1% 1.19. Glyphosate IPA 99.9% Polyalkoxylated fatty alcohol 0.1% If necessary, the above water soluble and wettable

or dispersible solid compositions are finely milled in a mill or other suitable milling equipment.

//. PHYSICAL EXAMINATIONS

II. Example I

The flowability of water-soluble solid formulations was investigated below. This is absolutely necessary for the products to be filled in water soluble bags. For the assay, 100 g of the solid preparation prepared above were filled into a 2 cm drainage funnel and the time required for 100 g of powder to flow out was determined. In the case of free-flowing powder material or normal porn that has a good flow rate, this time should be less than 10 seconds. 1-14. examples

In the case of solid preparations having a composition according to HU 212 802 Β, the following results were obtained:

Example number Discharge Time (sec) 1 4.0 2 2.0 3 4.0 4 2.0 5 1.5 6 2.0 7 7.0 8 5.0 9 5.0 10 9.5 11 7.2 12 4.5 13 4.0 14 3.0

The results prove that the glyphosate isopropylamine salt is suitable for formulation in water-soluble bags.

111. APPLICATION

III.I. Example kg 1.1, -1.19. The solid composition of Examples 1 to 4 is filled into a size bag suitable for receiving this amount.

The bag is made of polyvinyl alcohol plasticized with polyhydric alcohol and has a square shape and is sealed on three sides. Due to the nature of apor, the above preparations can be easily filled into the bag. The full bag is sealed by welding.

Before use, the filled bag is discarded in the desired amount of water with vigorous stirring. The polymer material disappears within 2 minutes and the herbicidal composition is completely dissolved or dispersed in water. The resulting composition is sprayed onto the desired area. The amount of glyphosate salt applied is substantially the same as that known in the art, so it depends on the crop to be treated, the excipient used and its ratio, and the climatic conditions.

If the ethoxylated alkylamine is the surfactant applied at a 1: 2 ratio to the glyphosate salt and if a herbicidal effect is desired, an acid equivalent of 0.125 kg to 12 kg of glyphosate per hectare is generally appropriate (lower, grass, for berries).

PATENT CLAIMS

Claims (4)

What is claimed is: 1. A solid phytoactive formulation containing an N-phosphonomethylglycine monoisopropylamine salt as an active ingredient, together with the usual excipients, which is packaged in a polymeric bag that is ready for use, water soluble, dry and flexible in its dry state. characterized in that at least one of the active ingredients of the composition is a non-hygroscopic solid N-phosphonomethylglycine monoisopropylamine salt and optionally contains another active ingredient compatible with the above active ingredient. Composition according to claim 1, characterized in that it contains, in addition to the non-hygroscopic solid N-phosphonomethylglycine isopropylamine salt, any of the following additional active substances: - 2,4-D (2,4-dichlorophenoxyacetic acid), - endothalate (7-oxabicyclo [2.2.1] heptene-2,3-dicarboxylic acid), - 2,4,5-T (2,4,5-trichlorophenoxyacetic acid), - MCPA (4-chloro-o-tolyloxyacetic acid), - MCPB [ammonium / 3-amino-3-carboxypropyl / methylphosphinate], - glufosinate [ammonium (3-amino-3-carboxypropyl) methylphosphinate] - bialafos (dl-homoalanine-4-ylmethylphosphinate), - ethephon (2-chloroethane phosphonic acid), mecoprop (2- (2-methyl-4-chlorophenoxy) propionic acid), - picloram (4-amino-3,5,6-trichloro-picolic acid), - benzac (2,3,6-trichlorobenzoic acid), - dalapon (2,2-dichloropropionic acid), - dicamba (3,6-dichloro-o-anisic acid), - dichlorprop [2- / 2,4-dichlorophenoxy / propionic acid], - imazaquin (2- [4,5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl) -3-quinolinecarboxylic acid}, - imazetapyr (2- [4,5-dihydro-4-methyl-4- (1-methylethyl) -5-oxo-1H-imidazol-2-yl) -5-ethyl-3-pyridinecarboxylic acid, - atrazine (2-chloro-4- (ethylamino) -6- (isopropylamino) -s-triazine), - simazine (2-chloro-4,6-bis (ethylamino) -s-triazine), - diuron (3- (3,4-dichlorophenyl) -1,2-dimethylurea), - linuron (3- (3,4-dichlorophenyl) -1-methoxy-1-methylurea), - NES (1-naphthyl acetic acid), - 2- [3- (4,6-dimethyl-pyrimidin-2-yl) -ureido-sulfonyl] -benzoic acid, - chlorosulfuron (1- (2-chlorophenylsulfonyl) -3- (4-methoxy-6-methyl-1,3,5-triazin-2-ylurea), - Methylsulfuron Methyl 2 - [[4-methoxy-4-methyl-1,3,5-triazinyl-2-yl] aminocarbonyl] -aminosulfonyl] benzoate - chlororinuron (ethyl 2 - [(4-chloro-6-methoxypyrimidin-2-yl) amino] carbonylaminosulfonylbenzoate), - fomesafen (5- [2-chloro-4- (trifluoromethyl) phenoxy] -N- (methylsulfonyl) -2-nitrobenzamide), - oxyfluorfen (2-chloro-1- (3-ethoxy-4-nitrophenoxy) -4-trifluoromethyl-benzene), fenoxaprop-P [(R) -2 - [(R) -2- [4- (6-chloro-1,3-benzoxazol-2-yloxy) phenoxypropionic acid], - alachlor (2-chloro-2,6-diethyl-N- (methoxymethyl) acetanilide), Characterized in that it contains from 0.001% to 95% by weight of one or more herbicides and from 99% to 5% by weight of a solid carrier, one or more surfactants and / or other additives. 5. Solid preparation according to any one of claims 1 to 3, characterized in that a portion thereof is packaged in a quantity suitable for plant treatment in a water-soluble bag. - propachlor (N-isopropyl-2-chloroacetanilide), - butachlor (N-butoxymethyl-2,6-diethyl-2-chloroacetanilide), - metolachlor (2-chloro-2-ethyl-6-methyl-N- (1-methyl-2-methoxyethyl) acetanilide). 5 3. The composition according to claim 1 or 2, wherein the non-hygroscopic N-phosphonomethylglycine monoisopropylamine salt content is 0.001% to 95%. 4. Preparation according to any one of claims 1 to 4