SK282862B6 - Derivát 2-[1',2',4'-triazol-3'-yloxymetylén]anilidu, spôsoby jeho prípravy, medziprodukty na jeho prípravu, prostriedok s jeho obsahom a jeho použitie - Google Patents

Info

Publication number

SK282862B6

SK282862B6 SK16-97A SK1697A SK282862B6 SK 282862 B6 SK282862 B6 SK 282862B6 SK 1697 A SK1697 A SK 1697A SK 282862 B6 SK282862 B6 SK 282862B6

Authority

SK

Slovakia

Prior art keywords

formula

methyl

group

pyridyl

carbon atoms

Prior art date

1994-07-06

Links

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• 150000001875 compounds Chemical class 0.000 claims abstract description 144
• 238000002360 preparation method Methods 0.000 claims abstract description 12
• 241000607479 Yersinia pestis Species 0.000 claims abstract description 11
• 241001465754 Metazoa Species 0.000 claims abstract description 8
• 239000000463 material Substances 0.000 claims abstract description 7
• 239000002689 soil Substances 0.000 claims abstract description 6
• -1 C 1 -C 6 alkyl Chemical group 0.000 claims description 390
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 144
• 125000004432 carbon atom Chemical group C* 0.000 claims description 84
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 55
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 47
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 37
• 239000000203 mixture Substances 0.000 claims description 36
• 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 35
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 33
• 239000001257 hydrogen Substances 0.000 claims description 32
• 229910052739 hydrogen Inorganic materials 0.000 claims description 32
• 125000000217 alkyl group Chemical group 0.000 claims description 31
• 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 20
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 20
• 125000004093 cyano group Chemical group *C#N 0.000 claims description 18
• 125000001188 haloalkyl group Chemical group 0.000 claims description 17
• 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 15
• 238000000034 method Methods 0.000 claims description 14
• 241000233866 Fungi Species 0.000 claims description 12
• 125000000753 cycloalkyl group Chemical group 0.000 claims description 11
• 125000004438 haloalkoxy group Chemical group 0.000 claims description 11
• 125000001072 heteroaryl group Chemical group 0.000 claims description 11
• 150000003931 anilides Chemical class 0.000 claims description 10
• 229910052736 halogen Inorganic materials 0.000 claims description 10
• 125000005843 halogen group Chemical group 0.000 claims description 10
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
• CKRZKMFTZCFYGB-UHFFFAOYSA-N N-phenylhydroxylamine Chemical compound ONC1=CC=CC=C1 CKRZKMFTZCFYGB-UHFFFAOYSA-N 0.000 claims description 9
• 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 9
• 150000002367 halogens Chemical class 0.000 claims description 9
• 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims description 8
• 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims description 8
• 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 8
• FQKFPGMGQXQHLP-UHFFFAOYSA-N 1-hydroxytriazole Chemical compound ON1C=CN=N1 FQKFPGMGQXQHLP-UHFFFAOYSA-N 0.000 claims description 7
• 241000244206 Nematoda Species 0.000 claims description 6
• 239000007787 solid Substances 0.000 claims description 6
• 150000001728 carbonyl compounds Chemical class 0.000 claims description 5
• 241000238631 Hexapoda Species 0.000 claims description 4
• 150000001408 amides Chemical class 0.000 claims description 4
• 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 claims description 3
• 230000000269 nucleophilic effect Effects 0.000 claims description 3
• 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
• 125000002071 phenylalkoxy group Chemical group 0.000 claims description 3
• 125000004076 pyridyl group Chemical group 0.000 claims description 3
• 125000000714 pyrimidinyl group Chemical group 0.000 claims description 3
• 125000004183 alkoxy alkyl group Chemical group 0.000 claims description 2
• BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims 4
• 150000002431 hydrogen Chemical class 0.000 claims 2
• 241000239223 Arachnida Species 0.000 claims 1
• ZVSKZLHKADLHSD-UHFFFAOYSA-N benzanilide Chemical compound C=1C=CC=CC=1C(=O)NC1=CC=CC=C1 ZVSKZLHKADLHSD-UHFFFAOYSA-N 0.000 claims 1
• 239000007788 liquid Substances 0.000 claims 1
• 230000002538 fungal effect Effects 0.000 abstract description 9
• 239000000543 intermediate Substances 0.000 abstract description 4
• 238000004519 manufacturing process Methods 0.000 abstract description 2
• 230000003449 preventive effect Effects 0.000 abstract description 2
• 239000000460 chlorine Substances 0.000 description 123
• 125000001309 chloro group Chemical group Cl* 0.000 description 117
• 125000004307 pyrazin-2-yl group Chemical group [H]C1=C([H])N=C(*)C([H])=N1 0.000 description 53
• 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 49
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 43
• 125000001246 bromo group Chemical group Br* 0.000 description 42
• 241000196324 Embryophyta Species 0.000 description 39
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 24
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
• 239000004480 active ingredient Substances 0.000 description 18
• 229910052801 chlorine Inorganic materials 0.000 description 17
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 15
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 15
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
• 125000003118 aryl group Chemical group 0.000 description 15
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 15
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 14
• 229910052794 bromium Inorganic materials 0.000 description 14
• 238000006243 chemical reaction Methods 0.000 description 14
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 14
• 239000002904 solvent Substances 0.000 description 14
• 229910052717 sulfur Inorganic materials 0.000 description 14
• 125000004434 sulfur atom Chemical group 0.000 description 13
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
• 206010061217 Infestation Diseases 0.000 description 12
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
• BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 12
• 125000003545 alkoxy group Chemical group 0.000 description 12
• 239000002585 base Substances 0.000 description 12
• 229910052757 nitrogen Inorganic materials 0.000 description 12
• BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 12
• 239000002253 acid Substances 0.000 description 11
• 125000004433 nitrogen atom Chemical group N* 0.000 description 11
• 229910052760 oxygen Inorganic materials 0.000 description 11
• JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
• 239000006185 dispersion Substances 0.000 description 10
• 239000001301 oxygen Substances 0.000 description 10
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
• 125000004430 oxygen atom Chemical group O* 0.000 description 9
• 239000000243 solution Substances 0.000 description 9
• CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 8
• 239000013543 active substance Substances 0.000 description 8
• 229910052783 alkali metal Inorganic materials 0.000 description 8
• 239000000417 fungicide Substances 0.000 description 8
• 150000002430 hydrocarbons Chemical group 0.000 description 8
• 235000011121 sodium hydroxide Nutrition 0.000 description 8
• 125000000304 alkynyl group Chemical group 0.000 description 7
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
• 239000003995 emulsifying agent Substances 0.000 description 7
• 239000000843 powder Substances 0.000 description 7
• 125000001424 substituent group Chemical group 0.000 description 7
• 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 7
• 241000209140 Triticum Species 0.000 description 6
• 235000021307 Triticum Nutrition 0.000 description 6
• KPCZJLGGXRGYIE-UHFFFAOYSA-N [C]1=CC=CN=C1 Chemical group [C]1=CC=CN=C1 KPCZJLGGXRGYIE-UHFFFAOYSA-N 0.000 description 6
• 150000001340 alkali metals Chemical class 0.000 description 6
• 125000003342 alkenyl group Chemical group 0.000 description 6
• 239000000839 emulsion Substances 0.000 description 6
• 229910052731 fluorine Inorganic materials 0.000 description 6
• 239000003921 oil Substances 0.000 description 6
• 229910000027 potassium carbonate Inorganic materials 0.000 description 6
• 235000011181 potassium carbonates Nutrition 0.000 description 6
• 125000004940 pyridazin-4-yl group Chemical group N1=NC=C(C=C1)* 0.000 description 6
• 125000000246 pyrimidin-2-yl group Chemical group [H]C1=NC(*)=NC([H])=C1[H] 0.000 description 6
• 125000004527 pyrimidin-4-yl group Chemical group N1=CN=C(C=C1)* 0.000 description 6
• 239000000725 suspension Substances 0.000 description 6
• MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
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• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
• 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
• 239000000969 carrier Substances 0.000 description 5
• 235000013339 cereals Nutrition 0.000 description 5
• 239000003795 chemical substances by application Substances 0.000 description 5
• 125000000000 cycloalkoxy group Chemical group 0.000 description 5
• 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 5
• 150000002191 fatty alcohols Chemical class 0.000 description 5
• 239000011737 fluorine Substances 0.000 description 5
• 229910052500 inorganic mineral Inorganic materials 0.000 description 5
• 235000010755 mineral Nutrition 0.000 description 5
• 239000011707 mineral Substances 0.000 description 5
• 150000003839 salts Chemical class 0.000 description 5
• 239000000741 silica gel Substances 0.000 description 5
• 229910002027 silica gel Inorganic materials 0.000 description 5
• 239000007858 starting material Substances 0.000 description 5
• 239000011593 sulfur Chemical group 0.000 description 5
• 239000011701 zinc Substances 0.000 description 5
• 229910052725 zinc Inorganic materials 0.000 description 5
• KDDQRKBRJSGMQE-UHFFFAOYSA-N 4-thiazolyl Chemical group [C]1=CSC=N1 KDDQRKBRJSGMQE-UHFFFAOYSA-N 0.000 description 4
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
• PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 4
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
• 241001414826 Lygus Species 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
• 150000007513 acids Chemical class 0.000 description 4
• 229910000272 alkali metal oxide Inorganic materials 0.000 description 4
• 150000001342 alkaline earth metals Chemical class 0.000 description 4
• 239000008346 aqueous phase Substances 0.000 description 4
• 229910052799 carbon Inorganic materials 0.000 description 4
• 239000004359 castor oil Substances 0.000 description 4
• 235000019438 castor oil Nutrition 0.000 description 4
• 125000000392 cycloalkenyl group Chemical group 0.000 description 4
• 239000002270 dispersing agent Substances 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 4
• 238000009472 formulation Methods 0.000 description 4
• ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
• 239000008187 granular material Substances 0.000 description 4
• 125000000262 haloalkenyl group Chemical group 0.000 description 4
• 125000000232 haloalkynyl group Chemical group 0.000 description 4
• 125000005842 heteroatom Chemical group 0.000 description 4
• 229910052943 magnesium sulfate Inorganic materials 0.000 description 4
• 235000019341 magnesium sulphate Nutrition 0.000 description 4
• 125000001624 naphthyl group Chemical group 0.000 description 4
• 239000012074 organic phase Substances 0.000 description 4
• 150000003254 radicals Chemical class 0.000 description 4
• 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 4
• 239000000080 wetting agent Substances 0.000 description 4
• WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 3
• 125000004890 (C1-C6) alkylamino group Chemical group 0.000 description 3
• 125000001359 1,2,3-triazol-4-yl group Chemical group [H]N1N=NC([*])=C1[H] 0.000 description 3
• 125000001766 1,2,4-oxadiazol-3-yl group Chemical group [H]C1=NC(*)=NO1 0.000 description 3
• 125000004505 1,2,4-oxadiazol-5-yl group Chemical group O1N=CN=C1* 0.000 description 3
• 125000004516 1,2,4-thiadiazol-5-yl group Chemical group S1N=CN=C1* 0.000 description 3
• 125000005918 1,2-dimethylbutyl group Chemical group 0.000 description 3
• 125000004872 1-methylpentylcarbonyl group Chemical group CC(CCCC)C(=O)* 0.000 description 3
• 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 3
• 125000001462 1-pyrrolyl group Chemical group [*]N1C([H])=C([H])C([H])=C1[H] 0.000 description 3
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
• 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 description 3
• 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 3
• 125000000389 2-pyrrolyl group Chemical group [H]N1C([*])=C([H])C([H])=C1[H] 0.000 description 3
• 125000000175 2-thienyl group Chemical group S1C([*])=C([H])C([H])=C1[H] 0.000 description 3
• 125000003682 3-furyl group Chemical group O1C([H])=C([*])C([H])=C1[H] 0.000 description 3
• 125000001541 3-thienyl group Chemical group S1C([H])=C([*])C([H])=C1[H] 0.000 description 3
• CWDWFSXUQODZGW-UHFFFAOYSA-N 5-thiazolyl Chemical group [C]1=CN=CS1 CWDWFSXUQODZGW-UHFFFAOYSA-N 0.000 description 3
• 239000005995 Aluminium silicate Substances 0.000 description 3
• 241000123650 Botrytis cinerea Species 0.000 description 3
• XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
• 240000007594 Oryza sativa Species 0.000 description 3
• 235000007164 Oryza sativa Nutrition 0.000 description 3
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
• ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
• 125000003302 alkenyloxy group Chemical group 0.000 description 3
• 150000008052 alkyl sulfonates Chemical class 0.000 description 3
• 125000004414 alkyl thio group Chemical group 0.000 description 3
• 235000012211 aluminium silicate Nutrition 0.000 description 3
• 125000005228 aryl sulfonate group Chemical group 0.000 description 3
• 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
• MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 3
• 238000004440 column chromatography Methods 0.000 description 3
• 239000003480 eluent Substances 0.000 description 3
• 125000006260 ethylaminocarbonyl group Chemical group [H]N(C(*)=O)C([H])([H])C([H])([H])[H] 0.000 description 3
• 125000004672 ethylcarbonyl group Chemical group [H]C([H])([H])C([H])([H])C(*)=O 0.000 description 3
• 239000003337 fertilizer Substances 0.000 description 3
• 235000013312 flour Nutrition 0.000 description 3
• 229910052740 iodine Inorganic materials 0.000 description 3
• 239000011630 iodine Substances 0.000 description 3
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
• 229910052744 lithium Inorganic materials 0.000 description 3
• RQWNDKMYDFTZIV-UHFFFAOYSA-N methyl n-[2-(bromomethyl)phenyl]-n-methoxycarbamate Chemical compound COC(=O)N(OC)C1=CC=CC=C1CBr RQWNDKMYDFTZIV-UHFFFAOYSA-N 0.000 description 3
• 125000004458 methylaminocarbonyl group Chemical group [H]N(C(*)=O)C([H])([H])[H] 0.000 description 3
• 125000003506 n-propoxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 3
• 150000002825 nitriles Chemical class 0.000 description 3
• 229940044654 phenolsulfonic acid Drugs 0.000 description 3
• 125000002206 pyridazin-3-yl group Chemical group [H]C1=C([H])C([H])=C(*)N=N1 0.000 description 3
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• 229920006395 saturated elastomer Polymers 0.000 description 3
• 239000011734 sodium Substances 0.000 description 3
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• 241000894007 species Species 0.000 description 3
• 239000007921 spray Substances 0.000 description 3
• 238000005507 spraying Methods 0.000 description 3
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
• 239000002699 waste material Substances 0.000 description 3
• 125000006771 (C1-C6) haloalkylthio group Chemical group 0.000 description 2
• 125000001506 1,2,3-triazol-5-yl group Chemical group [H]N1N=NC([H])=C1[*] 0.000 description 2
• 125000004515 1,2,4-thiadiazol-3-yl group Chemical group S1N=C(N=C1)* 0.000 description 2
• 125000006035 1,2-dimethyl-2-propenyl group Chemical group 0.000 description 2
• 125000004509 1,3,4-oxadiazol-2-yl group Chemical group O1C(=NN=C1)* 0.000 description 2
• 125000004317 1,3,5-triazin-2-yl group Chemical group [H]C1=NC(*)=NC([H])=N1 0.000 description 2
• YOOXNSPYGCZLAX-UHFFFAOYSA-N 1,5,8-trihydroxy-3-methylanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(C)=CC(O)=C3C(=O)C2=C1O YOOXNSPYGCZLAX-UHFFFAOYSA-N 0.000 description 2
• PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 2
• HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
• 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 2
• 125000004778 2,2-difluoroethyl group Chemical group [H]C([H])(*)C([H])(F)F 0.000 description 2
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