SK282581B6 - Spôsob katalytického odparafínovania suroviny uhľovodíkového oleja obsahujúcej voskovité molekuly - Google Patents
Spôsob katalytického odparafínovania suroviny uhľovodíkového oleja obsahujúcej voskovité molekuly Download PDFInfo
- Publication number
- SK282581B6 SK282581B6 SK1699-97A SK169997A SK282581B6 SK 282581 B6 SK282581 B6 SK 282581B6 SK 169997 A SK169997 A SK 169997A SK 282581 B6 SK282581 B6 SK 282581B6
- Authority
- SK
- Slovakia
- Prior art keywords
- selective
- catalyst
- zeolite
- product
- cracking
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 65
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 38
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 25
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 23
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 72
- 239000010457 zeolite Substances 0.000 claims abstract description 56
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 47
- 238000006317 isomerization reaction Methods 0.000 claims abstract description 35
- 238000005336 cracking Methods 0.000 claims abstract description 33
- 239000011148 porous material Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 25
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 238000006555 catalytic reaction Methods 0.000 claims abstract 5
- 239000003054 catalyst Substances 0.000 claims description 76
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 46
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 44
- 230000008569 process Effects 0.000 claims description 42
- 239000002808 molecular sieve Substances 0.000 claims description 34
- 238000005984 hydrogenation reaction Methods 0.000 claims description 31
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 26
- 239000013078 crystal Substances 0.000 claims description 24
- 239000000377 silicon dioxide Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 17
- 229910052697 platinum Inorganic materials 0.000 claims description 11
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 10
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 9
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 229910052763 palladium Inorganic materials 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052680 mordenite Inorganic materials 0.000 claims description 4
- 150000004761 hexafluorosilicates Chemical class 0.000 claims description 2
- 238000005275 alloying Methods 0.000 claims 1
- 235000012438 extruded product Nutrition 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 8
- 238000002955 isolation Methods 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 33
- 239000000047 product Substances 0.000 description 31
- 239000007789 gas Substances 0.000 description 28
- 239000010687 lubricating oil Substances 0.000 description 24
- 229910052782 aluminium Inorganic materials 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 14
- 238000004821 distillation Methods 0.000 description 12
- 238000005269 aluminizing Methods 0.000 description 11
- 238000007710 freezing Methods 0.000 description 9
- 239000002609 medium Substances 0.000 description 9
- 238000000926 separation method Methods 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000008014 freezing Effects 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- -1 hexafluorosilicate salt Chemical class 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000005292 vacuum distillation Methods 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 4
- 238000002425 crystallisation Methods 0.000 description 4
- 230000008025 crystallization Effects 0.000 description 4
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 239000002199 base oil Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 229940119177 germanium dioxide Drugs 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- NOWPEMKUZKNSGG-UHFFFAOYSA-N azane;platinum(2+) Chemical compound N.N.N.N.[Pt+2] NOWPEMKUZKNSGG-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012595 freezing medium Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP95401379 | 1995-06-13 | ||
| PCT/EP1996/002578 WO1996041849A1 (fr) | 1995-06-13 | 1996-06-12 | Procede catalytique de deparaffinage et composition de catalyseur |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SK169997A3 SK169997A3 (en) | 1998-08-05 |
| SK282581B6 true SK282581B6 (sk) | 2002-10-08 |
Family
ID=8221497
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1699-97A SK282581B6 (sk) | 1995-06-13 | 1996-06-12 | Spôsob katalytického odparafínovania suroviny uhľovodíkového oleja obsahujúcej voskovité molekuly |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5804058A (fr) |
| EP (1) | EP0832171B1 (fr) |
| JP (1) | JP3839848B2 (fr) |
| KR (1) | KR100404500B1 (fr) |
| CN (1) | CN1047789C (fr) |
| AT (1) | ATE188502T1 (fr) |
| AU (1) | AU755963B2 (fr) |
| BR (1) | BR9608802A (fr) |
| CA (1) | CA2224648C (fr) |
| DE (1) | DE69606035T2 (fr) |
| DK (1) | DK0832171T3 (fr) |
| ES (1) | ES2142069T3 (fr) |
| MY (1) | MY125670A (fr) |
| SA (1) | SA96170135B1 (fr) |
| SK (1) | SK282581B6 (fr) |
| WO (1) | WO1996041849A1 (fr) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU1810599A (en) * | 1997-12-22 | 1999-07-12 | Chevron U.S.A. Inc. | Raffinate dewaxing process |
| US6294493B1 (en) | 1998-05-26 | 2001-09-25 | Exxon Mobil Chemical Patents Inc. | Silicoaluminophosphates having an AEL structure |
| ES2251249T3 (es) * | 1998-11-16 | 2006-04-16 | Shell Internationale Research Maatschappij B.V. | Procedimiento de desparafinado catalitico. |
| ES2198975T3 (es) * | 1998-11-18 | 2004-02-01 | Shell Internationale Research Maatschappij B.V. | Procedimiento de desparafinado catalitico. |
| AU761082C (en) * | 1999-01-15 | 2003-12-18 | Albemarle Netherlands B.V. | A novel mixed metal catalyst, its preparation by co-precipitation, and its use |
| WO2001007538A1 (fr) * | 1999-07-26 | 2001-02-01 | Shell Internationale Research Maatschappij B.V. | Procede de preparation d'huile minerale lubrifiante |
| CN1136993C (zh) * | 1999-07-27 | 2004-02-04 | 国际壳牌研究有限公司 | 分子筛-粘合剂挤出物的浸渍方法 |
| US6709570B1 (en) | 1999-09-27 | 2004-03-23 | Shell Oil Company | Method for preparing a catalyst |
| KR100353412B1 (ko) * | 2000-01-31 | 2002-09-18 | 한국과학기술원 | 탈왁스 공정용 금속함유 이원촉매의 제조방법 |
| RU2272068C2 (ru) | 2000-12-19 | 2006-03-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения веретенного масла, легкого машинного масла и среднего машинного масла из остаточных фракций процесса топливного гидрокрекинга |
| US7670996B2 (en) | 2001-02-13 | 2010-03-02 | Shell Oil Company | Lubricant composition having a base oil and one or more additives, wherein the base oil has been obtained from waxy paraffinic fischer-tropsch synthesized hydrocarbons |
| AR032930A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Procedimiento para preparar un aceite de base lubricante y gas oil |
| MY137259A (en) * | 2001-03-05 | 2009-01-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil. |
| AR032941A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones |
| JP2004531607A (ja) | 2001-04-19 | 2004-10-14 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | 高飽和物含有量を有するベース油の製造方法 |
| TWI277649B (en) | 2001-06-07 | 2007-04-01 | Shell Int Research | Process to prepare a base oil from slack-wax |
| WO2003033630A1 (fr) | 2001-10-16 | 2003-04-24 | Shell Internationale Research Maatschappij B.V. | Valorisation des huiles usagees pretraitees |
| ATE462775T1 (de) | 2002-02-25 | 2010-04-15 | Shell Int Research | Gasöl oder gasöl mischkomponente |
| DE60303385T2 (de) | 2002-07-12 | 2006-09-14 | Shell Internationale Research Maatschappij B.V. | Verfahren zur herstellung eines schweren und eines leichten schmier l-grund ls |
| WO2004009739A2 (fr) | 2002-07-18 | 2004-01-29 | Shell Internationale Research Maatschappij B.V. | Procede de preparation d'une cire microcristalline et d'un combustible de distillat moyen |
| AU2003251459A1 (en) | 2002-07-19 | 2004-02-09 | Shell Internationale Research Maatschappij B.V. | Composition comprising epdm and a paraffinic oil |
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-
1996
- 1996-06-11 MY MYPI96002359A patent/MY125670A/en unknown
- 1996-06-12 BR BR9608802A patent/BR9608802A/pt not_active IP Right Cessation
- 1996-06-12 ES ES96921992T patent/ES2142069T3/es not_active Expired - Lifetime
- 1996-06-12 CN CN96196290A patent/CN1047789C/zh not_active Expired - Lifetime
- 1996-06-12 CA CA002224648A patent/CA2224648C/fr not_active Expired - Lifetime
- 1996-06-12 DK DK96921992T patent/DK0832171T3/da active
- 1996-06-12 SK SK1699-97A patent/SK282581B6/sk not_active IP Right Cessation
- 1996-06-12 KR KR1019970709360A patent/KR100404500B1/ko not_active IP Right Cessation
- 1996-06-12 WO PCT/EP1996/002578 patent/WO1996041849A1/fr active IP Right Grant
- 1996-06-12 DE DE69606035T patent/DE69606035T2/de not_active Expired - Lifetime
- 1996-06-12 AU AU63034/96A patent/AU755963B2/en not_active Ceased
- 1996-06-12 AT AT96921992T patent/ATE188502T1/de not_active IP Right Cessation
- 1996-06-12 JP JP50264897A patent/JP3839848B2/ja not_active Expired - Lifetime
- 1996-06-12 EP EP96921992A patent/EP0832171B1/fr not_active Expired - Lifetime
- 1996-06-13 US US08/662,596 patent/US5804058A/en not_active Expired - Lifetime
- 1996-07-06 SA SA96170135A patent/SA96170135B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2224648C (fr) | 2007-07-10 |
| CN1047789C (zh) | 1999-12-29 |
| CN1193335A (zh) | 1998-09-16 |
| DE69606035T2 (de) | 2000-07-13 |
| AU6303496A (en) | 1997-01-09 |
| SA96170135B1 (ar) | 2006-03-15 |
| EP0832171B1 (fr) | 2000-01-05 |
| BR9608802A (pt) | 1999-02-17 |
| CA2224648A1 (fr) | 1996-12-27 |
| MY125670A (en) | 2006-08-30 |
| WO1996041849A1 (fr) | 1996-12-27 |
| DK0832171T3 (da) | 2000-05-08 |
| JP3839848B2 (ja) | 2006-11-01 |
| DE69606035D1 (de) | 2000-02-10 |
| US5804058A (en) | 1998-09-08 |
| EP0832171A1 (fr) | 1998-04-01 |
| KR19990022891A (ko) | 1999-03-25 |
| ES2142069T3 (es) | 2000-04-01 |
| SK169997A3 (en) | 1998-08-05 |
| AU755963B2 (en) | 2003-01-02 |
| KR100404500B1 (ko) | 2004-02-19 |
| JPH11507969A (ja) | 1999-07-13 |
| ATE188502T1 (de) | 2000-01-15 |
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| Date | Code | Title | Description |
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| MM4A | Patent lapsed due to non-payment of maintenance fees |
Effective date: 20090612 |