SG11201706530RA - Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation - Google Patents

Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

Info

Publication number
SG11201706530RA
SG11201706530RA SG11201706530RA SG11201706530RA SG11201706530RA SG 11201706530R A SG11201706530R A SG 11201706530RA SG 11201706530R A SG11201706530R A SG 11201706530RA SG 11201706530R A SG11201706530R A SG 11201706530RA SG 11201706530R A SG11201706530R A SG 11201706530RA
Authority
SG
Singapore
Prior art keywords
regeneration
zeolite catalyst
titanium zeolite
propylene epoxidation
epoxidation
Prior art date
Application number
SG11201706530RA
Other languages
English (en)
Inventor
Dominic Riedel
Joaquim Henrique Teles
Daniel Urbanczyk
Ulrike Wegerle
Luise Spiske
Andrei-Nicolae Parvulescu
Alexander Schroeder
Ulrich Mueller
Meinolf Weidenbach
Werner J Witzl
Original Assignee
Basf Se
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Dow Global Technologies Llc filed Critical Basf Se
Publication of SG11201706530RA publication Critical patent/SG11201706530RA/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/085Group IVB- metallosilicates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201706530RA 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation SG11201706530RA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562115658P 2015-02-13 2015-02-13
EP15154998 2015-02-13
PCT/EP2016/052983 WO2016128538A1 (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

Publications (1)

Publication Number Publication Date
SG11201706530RA true SG11201706530RA (en) 2017-09-28

Family

ID=52472215

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201706530RA SG11201706530RA (en) 2015-02-13 2016-02-12 Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation

Country Status (11)

Country Link
US (1) US10195598B2 (ru)
EP (1) EP3256252B1 (ru)
JP (1) JP6685315B2 (ru)
KR (1) KR102512661B1 (ru)
CN (1) CN107530693A (ru)
BR (1) BR112017017269B1 (ru)
MX (1) MX2017010402A (ru)
MY (1) MY189272A (ru)
PL (1) PL3256252T3 (ru)
SG (1) SG11201706530RA (ru)
WO (1) WO2016128538A1 (ru)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3292099B1 (en) 2015-05-04 2020-07-22 Basf Se Process for the preparation of melonal
RU2018105604A (ru) 2015-07-15 2019-08-15 Басф Се Способ получения арилпропена
CN108137523B (zh) 2015-07-22 2022-07-26 巴斯夫欧洲公司 制备呋喃-2,5-二甲酸的方法
EP3170828A1 (de) 2015-11-23 2017-05-24 Basf Se Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten
WO2017089410A1 (en) 2015-11-27 2017-06-01 Basf Se Ultrafast high space-time-yield synthesis of metal-organic frameworks
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
BR112018011459A2 (pt) 2015-12-08 2018-11-27 Basf Se processo, material zeolítico, e, uso de um material zeolítico.
WO2017133995A1 (de) 2016-02-01 2017-08-10 Basf Se Verfahren zur herstellung von c4-c15-lactamen
WO2018002040A1 (en) 2016-06-29 2018-01-04 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
EP3481800B1 (en) 2016-07-08 2020-08-05 Basf Se Process for preparing an organic sulfone
US10544116B2 (en) 2016-07-20 2020-01-28 Basf Se Process for purifying propylene oxide
WO2018019983A1 (en) 2016-07-29 2018-02-01 Basf Se Process for the preparation of a zeolitic material having a fau-type framework structure and use thereof in the selective catalytic reduction of nox
EP3544730A1 (en) 2016-11-28 2019-10-02 Basf Se Catalyst composite comprising an alkaline earth metal containing cha zeolite and use thereof in a process for the conversion of oxygenates to olefins
BR112019008783A2 (pt) 2016-11-30 2019-07-16 Basf Se processo para a conversão de etano-1,2-diol em etano-1,2-diamina
WO2018099964A1 (en) 2016-11-30 2018-06-07 Basf Se Process for the conversion of monoethanolamine to ethylenediamine employing a copper-modified zeolite of the mor framework structure
JP7068298B2 (ja) 2016-12-13 2022-05-16 ビーエーエスエフ ソシエタス・ヨーロピア チタン含有ゼオライトの製造の方法
EP3728173A1 (en) * 2017-12-21 2020-10-28 Basf Se Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase
EP3604222A1 (en) * 2018-07-30 2020-02-05 Evonik Operations GmbH Process for the purification of hydrogen cyanide
AU2018449272B2 (en) * 2018-11-15 2022-09-01 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Method for preparing hierarchical porous titanosilicate TS-1 molecular sieve
TW202045484A (zh) * 2019-02-08 2020-12-16 德商贏創運營有限公司 有機化合物的氧化
CN110252393A (zh) * 2019-05-21 2019-09-20 江西农业大学 一种用于合成环氧大豆油的钛硅沸石负载镉催化剂、制备方法及应用
CN110075914A (zh) * 2019-05-28 2019-08-02 江苏扬农化工集团有限公司 一种hppo工艺失活钛硅分子筛催化剂器内再生的方法
EP3812375A1 (en) * 2019-10-21 2021-04-28 Evonik Operations GmbH Process for the epoxidation of propene
CN112354557B (zh) * 2020-11-16 2023-03-24 华东师范大学 一种整体式钛沸石催化剂制备方法及其应用
CN112678866B (zh) * 2020-12-24 2023-07-04 中国石油化工股份有限公司 一种烯烃聚合工业废酸渣资源化处理方法
CN112844468A (zh) * 2021-01-19 2021-05-28 中国科学院大连化学物理研究所 一种用于丙烯气相环氧化制环氧丙烷的催化剂及其制备方法
CN113368895B (zh) * 2021-07-13 2023-09-29 福州大学 一种具有高转化率的丙烯气相环氧化催化剂的制备方法
WO2023056231A1 (en) * 2021-09-30 2023-04-06 Basf Corporation Pretreatment of porous metal oxide catalysts for use in dehydrogenation and other reactions
WO2024115737A1 (en) 2022-12-02 2024-06-06 Basf Se Process for regeneration of an epoxidation reactor

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19723751A1 (de) 1997-06-06 1998-12-10 Basf Ag Formkörper und Verfahren zu dessen Herstellung
US6114551A (en) 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
DE10044798A1 (de) * 2000-09-11 2002-04-04 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
EP1221442B1 (de) 2001-01-08 2010-07-28 Evonik Degussa GmbH Verfahren zur Epoxidierung von Olefinen
DE10320635A1 (de) 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
EP1489074A1 (en) 2003-06-18 2004-12-22 Degussa AG Process for the epoxidation of propene
US20050277542A1 (en) 2004-06-14 2005-12-15 Kaminsky Mark P Catalyst regeneration process
KR101166932B1 (ko) 2005-07-27 2012-07-19 에스케이이노베이션 주식회사 티타늄 함유 분자체 촉매의 재생방법
JP2009233656A (ja) * 2008-03-05 2009-10-15 Sumitomo Chemical Co Ltd チタノシリケート触媒の再生方法
CN101480623B (zh) * 2009-02-24 2011-06-08 江苏扬农化工集团有限公司 一种钛硅分子筛催化剂的再生方法
KR20130005269A (ko) * 2010-03-18 2013-01-15 스미또모 가가꾸 가부시끼가이샤 티타노실리케이트 촉매의 재생 방법
SG10201606438RA (en) 2012-02-07 2016-09-29 Basf Se Micropowder and molding containing a zeolitic material containing ti and zn
CN104014365B (zh) * 2013-02-28 2016-08-24 中国石油化工股份有限公司 一种钛硅分子筛的再生方法
JP6581577B2 (ja) * 2013-07-24 2019-09-25 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se チタン含有ゼオライトの再生

Also Published As

Publication number Publication date
KR102512661B1 (ko) 2023-03-21
KR20170117509A (ko) 2017-10-23
BR112017017269B1 (pt) 2022-05-24
EP3256252B1 (en) 2021-04-07
JP2018511459A (ja) 2018-04-26
PL3256252T3 (pl) 2021-10-25
BR112017017269A2 (pt) 2018-04-17
US10195598B2 (en) 2019-02-05
MY189272A (en) 2022-01-31
CN107530693A (zh) 2018-01-02
JP6685315B2 (ja) 2020-04-22
US20180036723A1 (en) 2018-02-08
EP3256252A1 (en) 2017-12-20
MX2017010402A (es) 2018-05-28
WO2016128538A1 (en) 2016-08-18

Similar Documents

Publication Publication Date Title
SG11201706530RA (en) Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation
IL255232A0 (en) A process for the preparation of terpinolene epoxide
HK1224246A1 (zh) 用於血液淨化的血液透析器
GB2530838B (en) Process for purifying mesotrione
ZA201900923B (en) A process for purifying propylene oxide
HUE054720T2 (hu) Eljárás és reaktor propén epoxidálására
HUE045453T2 (hu) Eljárás propén epoxidálására
ZA201900922B (en) A process for purifying propylene oxide
PL3380461T3 (pl) Sposób epoksydowania propenu
HUE045670T2 (hu) Eljárás propén epoxidálására
SG11201708669WA (en) Catalyst reactor basket
PT3554679T (pt) Reactor de reactivação de sólidos
EP3281700A4 (en) Method for regenerating catalyst
GB201621549D0 (en) Catalytic process
SG10201605245UA (en) Method For Completely Emptying A Catalytic Reactor
EP3284533A4 (en) Method of regenerating used denitration catalyst
EP3280530A4 (en) Zsm-5 catalyst
PL3383856T3 (pl) Sposób epoksydowania propenu
IL247151B (en) A process for purifying partially hydrolyzed cellulose
SG10201508161YA (en) Catalyst system for producing ketones from epoxides
EP3229739A4 (en) Three-dimensional scaffold for bone regeneration
SG11201702270SA (en) Process for adsorber regeneration
PL3433240T3 (pl) Sposób epoksydacji propenu
SG11201505598UA (en) Process for treating zeolite catalysts
ZA201706056B (en) Process for the regeneration of a titanium zeolite catalyst for propylene epoxidation