SG11201600702VA - Preparation of methyl acrylate via an oxidative esterification process - Google Patents

Preparation of methyl acrylate via an oxidative esterification process

Info

Publication number
SG11201600702VA
SG11201600702VA SG11201600702VA SG11201600702VA SG11201600702VA SG 11201600702V A SG11201600702V A SG 11201600702VA SG 11201600702V A SG11201600702V A SG 11201600702VA SG 11201600702V A SG11201600702V A SG 11201600702VA SG 11201600702V A SG11201600702V A SG 11201600702VA
Authority
SG
Singapore
Prior art keywords
preparation
methyl acrylate
esterification process
oxidative esterification
acrylate via
Prior art date
Application number
SG11201600702VA
Other languages
English (en)
Inventor
Kirk Limbach
Dmitri A Kraptchetov
Christopher D Frick
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of SG11201600702VA publication Critical patent/SG11201600702VA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201600702VA 2013-07-29 2014-07-29 Preparation of methyl acrylate via an oxidative esterification process SG11201600702VA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361859551P 2013-07-29 2013-07-29
PCT/US2014/048667 WO2015017437A1 (fr) 2013-07-29 2014-07-29 Préparation d'acrylate de méthyle par le biais d'un procédé d'estérification oxydative

Publications (1)

Publication Number Publication Date
SG11201600702VA true SG11201600702VA (en) 2016-02-26

Family

ID=51303130

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201600702VA SG11201600702VA (en) 2013-07-29 2014-07-29 Preparation of methyl acrylate via an oxidative esterification process

Country Status (12)

Country Link
US (1) US9676699B2 (fr)
EP (1) EP2989077B1 (fr)
JP (1) JP6506281B2 (fr)
KR (1) KR102287643B1 (fr)
CN (1) CN105377806B (fr)
BR (1) BR112016001127B1 (fr)
CA (1) CA2918403C (fr)
MX (1) MX363805B (fr)
SA (1) SA516370404B1 (fr)
SG (1) SG11201600702VA (fr)
TW (1) TW201509901A (fr)
WO (1) WO2015017437A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201509522A (zh) * 2013-07-29 2015-03-16 Rohm & Haas 氧化酯化催化劑
JP6382969B2 (ja) 2013-10-28 2018-08-29 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ メタクロレインを分離するための方法
CA3071239A1 (fr) * 2017-07-28 2019-01-31 Rohm And Haas Company Catalyseur heterogene
EP3587390A1 (fr) 2018-06-26 2020-01-01 Röhm GmbH Procédé de fabrication de mma en grandes quantités
CN113477252B (zh) * 2021-06-30 2023-06-30 常州大学 一种同时含钛及其它过渡金属的复合多孔催化剂的制备方法和应用

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* Cited by examiner, † Cited by third party
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JPS5368718A (en) * 1976-11-27 1978-06-19 Nippon Kayaku Co Ltd Simultaneous preparation of methacrylic acid and its ester or acrylicacid and its ester
DE2848978A1 (de) 1978-11-11 1980-05-22 Bayer Ag Traegerkatalysatoren, ihre herstellung und verwendung
DE3018071C2 (de) 1979-05-17 1985-06-05 Asahi Kasei Kogyo K.K., Osaka Verfahren zur Herstellung von Carbonsäureestern
JPS55151533A (en) * 1979-05-17 1980-11-26 Asahi Chem Ind Co Ltd Preparation of carboxylic acid ester
JPS5687530A (en) 1979-12-19 1981-07-16 Asahi Chem Ind Co Ltd Dehydrating method of gas containing unsaturated aldehyde
US4714695A (en) * 1985-04-18 1987-12-22 The Standard Oil Company Method for the preparation of high activity palladium based catalysts
JP3258354B2 (ja) 1991-11-28 2002-02-18 三井化学株式会社 カルボン酸エステルの製造法
CN1086313C (zh) 1995-07-18 2002-06-19 旭化成株式会社 用于生产羧酸脂的催化剂
JPH09216850A (ja) * 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
TW385304B (en) 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
TW377306B (en) 1996-12-16 1999-12-21 Asahi Chemical Ind Noble metal support
JP3511350B2 (ja) 1997-03-25 2004-03-29 旭化成ケミカルズ株式会社 カルボン酸エステル製造用触媒
SG71815A1 (en) 1997-07-08 2000-04-18 Asahi Chemical Ind Method of producing methyl methacrylate
CN1122569C (zh) 1997-08-07 2003-10-01 三菱丽阳株式会社 用于制造羧酸酯的催化剂和羧酸酯的制造方法
US6506930B1 (en) * 1997-11-17 2003-01-14 Rohm And Haas Company Process for preparing alkyl (meth)acrylates
JP3748820B2 (ja) 1999-10-05 2006-02-22 昭和電工株式会社 酢酸製造用触媒、その製造方法及びそれを用いた酢酸の製造方法
CN1179788C (zh) * 2000-09-29 2004-12-15 中国石油化工股份有限公司 不饱和烃选择加氢催化剂、其制备方法及其应用
US7326806B2 (en) 2001-06-04 2008-02-05 Nippon Shokubai Co., Ltd. Catalyst for the preparation of carboxylic esters and method for producing carboxylic esters
JP4145621B2 (ja) * 2002-10-16 2008-09-03 旭化成ケミカルズ株式会社 不飽和カルボン酸エステル合成反応の反応開始方法
CN1214865C (zh) 2003-01-22 2005-08-17 中国科学院过程工程研究所 一种用于甲基丙烯醛一步氧化酯化生产甲基丙烯酸甲酯的新型催化剂
JP2004345973A (ja) * 2003-05-20 2004-12-09 Asahi Kasei Chemicals Corp 不飽和カルボン酸エステルの製造方法
DE102004038013A1 (de) * 2004-08-04 2006-03-16 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäureestern
GB2428014B (en) * 2005-07-08 2010-02-10 Lee Chang Yung Chemical Indust Catalyst and process for preparing carboxylic acid esters
BRPI0815166A8 (pt) 2007-08-13 2016-12-20 Asahi Kasei Chemicals Corp Catalisador para uso na produção de éster de ácido carboxílico, processos para produzir o mesmo, e, para produzir éster de ácido carboxílico
JP2011104457A (ja) * 2009-11-12 2011-06-02 Mitsubishi Rayon Co Ltd パラジウム含有担持触媒、その製造方法、およびα，β−不飽和カルボン酸の製造方法
US9120085B2 (en) 2010-09-16 2015-09-01 Asahi Kasei Chemicals Corporation Silica-based material and process for producing the same, noble metal supported material and process for producing carboxylic acids by using the same as catalyst
US8802588B2 (en) 2012-01-23 2014-08-12 Celanese International Corporation Bismuth catalyst composition and process for manufacturing ethanol mixture

Also Published As

Publication number Publication date
CN105377806B (zh) 2017-09-05
WO2015017437A1 (fr) 2015-02-05
CN105377806A (zh) 2016-03-02
EP2989077B1 (fr) 2017-12-27
KR102287643B1 (ko) 2021-08-06
US9676699B2 (en) 2017-06-13
US20160159728A1 (en) 2016-06-09
SA516370404B1 (ar) 2017-05-29
KR20160035590A (ko) 2016-03-31
TW201509901A (zh) 2015-03-16
CA2918403A1 (fr) 2015-02-05
BR112016001127B1 (pt) 2020-12-29
CA2918403C (fr) 2021-07-06
EP2989077A1 (fr) 2016-03-02
BR112016001127A8 (pt) 2019-10-01
MX363805B (es) 2019-04-03
JP6506281B2 (ja) 2019-04-24
MX2016000767A (es) 2016-04-19
JP2016525578A (ja) 2016-08-25

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