RU94040899A - Способ приготовления катализаторов для применения при получении винилацетата - Google Patents
Способ приготовления катализаторов для применения при получении винилацетатаInfo
- Publication number
- RU94040899A RU94040899A RU94040899/04A RU94040899A RU94040899A RU 94040899 A RU94040899 A RU 94040899A RU 94040899/04 A RU94040899/04 A RU 94040899/04A RU 94040899 A RU94040899 A RU 94040899A RU 94040899 A RU94040899 A RU 94040899A
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- palladium
- vinyl acetate
- synthesis
- barium salt
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
- B01J37/035—Precipitation on carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
В способе получения катализаторов оболочкового типа из палладия и палладия/золота для получения винилацетата усовершенствование заключается в использовании соли бария для осаждения водонерастворимых соединений палладия и, возможно, золота на носитель до восстановления с помощью восстанавливающего агента. Добавка в виде соли бария также может быть введена в катализатор после восстановления с целью уменьшения стремления катализатора к потере активности при использовании.
Claims (1)
- В способе получения катализаторов оболочкового типа из палладия и палладия/золота для получения винилацетата усовершенствование заключается в использовании соли бария для осаждения водонерастворимых соединений палладия и, возможно, золота на носитель до восстановления с помощью восстанавливающего агента. Добавка в виде соли бария также может быть введена в катализатор после восстановления с целью уменьшения стремления катализатора к потере активности при использовании.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB939323857A GB9323857D0 (en) | 1993-11-19 | 1993-11-19 | Process |
GB939323823A GB9323823D0 (en) | 1993-11-19 | 1993-11-19 | Catalyst |
GB9323823.6 | 1993-11-19 | ||
GB9323857.4 | 1993-11-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU94040899A true RU94040899A (ru) | 1996-10-10 |
RU2132230C1 RU2132230C1 (ru) | 1999-06-27 |
Family
ID=26303891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU94040899A RU2132230C1 (ru) | 1993-11-19 | 1994-11-18 | Способ получения катализатора для синтеза винилацетата и способ получения винилацетата |
Country Status (16)
Country | Link |
---|---|
US (1) | US5567839A (ru) |
EP (1) | EP0654301B1 (ru) |
JP (1) | JPH07308576A (ru) |
KR (1) | KR950013579A (ru) |
CN (1) | CN1107831A (ru) |
BR (1) | BR9404493A (ru) |
CA (1) | CA2135021A1 (ru) |
DE (1) | DE69407548T2 (ru) |
ES (1) | ES2110701T3 (ru) |
FI (1) | FI945418A (ru) |
MY (1) | MY131699A (ru) |
NO (1) | NO305158B1 (ru) |
NZ (1) | NZ264940A (ru) |
RU (1) | RU2132230C1 (ru) |
SG (1) | SG50366A1 (ru) |
YU (1) | YU48693B (ru) |
Families Citing this family (35)
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ATE193844T1 (de) * | 1996-04-16 | 2000-06-15 | Hoechst Celanese Corp | Verfahren zur zweistufigen goldauftragung für die herstellung eines katalysators für die herstellung von vinylacetat |
SA97180048B1 (ar) * | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
US5859287A (en) * | 1997-10-30 | 1999-01-12 | Celanese International Corporation | Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals |
US6072078A (en) * | 1997-12-12 | 2000-06-06 | Celanese International Corporation | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
TW471982B (en) | 1998-06-02 | 2002-01-11 | Dairen Chemical Corp | Catalyst manufacture method and its use for preparing vinyl acetate |
ID26891A (id) * | 1998-06-02 | 2001-02-15 | Celanese Internasional Corp | Katalis vinil asetat yang terdiri dari palladium logam dan emas yang dibuat dengan potasium aurat |
JP2000070718A (ja) * | 1998-06-17 | 2000-03-07 | Nippon Shokubai Co Ltd | ベンジルエステルの製造方法 |
GB9907704D0 (en) * | 1999-04-01 | 1999-05-26 | Bp Chem Int Ltd | Catalyst and process utilising the catalyst |
CN1109578C (zh) * | 1999-05-26 | 2003-05-28 | 冯士光 | 一种汽车排气净化催化剂及其净化装置 |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
US6794332B2 (en) | 2000-07-07 | 2004-09-21 | Saudi Basic Industries Corporation | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
US6420308B1 (en) * | 2000-07-07 | 2002-07-16 | Saudi Basic Industries Corp | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
US6534438B1 (en) * | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
DE60034792T2 (de) * | 2000-11-09 | 2008-01-17 | Dairen Chemical Corp. | Verfahren zur Herstellung von Katalysatoren |
TW201236755A (en) | 2003-12-19 | 2012-09-16 | Celanese Int Corp | Halide free precursors for catalysts |
US20050283256A1 (en) * | 2004-02-09 | 2005-12-22 | Codman & Shurtleff, Inc. | Collagen device and method of preparing the same |
KR100932575B1 (ko) | 2004-12-20 | 2009-12-17 | 셀라니즈 인터내셔날 코포레이션 | 촉매용 개질된 지지체 물질 |
US8227369B2 (en) | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
JP4963922B2 (ja) * | 2006-10-04 | 2012-06-27 | 昭和電工株式会社 | 酢酸アルケニル製造用触媒の製造方法 |
US7825204B2 (en) | 2006-12-19 | 2010-11-02 | Lyondell Chemical Technology, L.P. | Inorganic oxide extrudates |
JP4964170B2 (ja) * | 2007-04-09 | 2012-06-27 | 昭和電工株式会社 | 酢酸アルケニル製造用触媒の製造方法 |
DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025443A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025358A1 (de) * | 2007-05-31 | 2009-01-08 | Süd-Chemie AG | Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators |
DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
DE102007047430A1 (de) | 2007-10-04 | 2009-04-09 | Evonik Degussa Gmbh | Katalysator |
DE202008017277U1 (de) | 2008-11-30 | 2009-04-30 | Süd-Chemie AG | Katalysatorträger |
WO2011104170A1 (en) | 2010-02-24 | 2011-09-01 | Evonik Degussa Gmbh | Thermally and mechanically stable precious metal-loaded catalysts |
GB201110850D0 (en) | 2011-03-04 | 2011-08-10 | Johnson Matthey Plc | Catalyst and mehtod of preparation |
DE102013015436A1 (de) | 2012-09-19 | 2014-03-20 | Clariant International Ltd. | Kupfer-promotierter Schalenkatalysator zur Herstellung von Alkenylcarbonsäureestern |
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DE1252662B (ru) * | 1965-06-25 | |||
CH534005A (de) * | 1968-02-01 | 1973-02-28 | Bayer Ag | Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators |
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DE2315037C3 (de) * | 1973-03-26 | 1978-03-09 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von ungesättigten Estern von Carbonsäuren |
JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
JPS5136413A (en) * | 1974-09-10 | 1976-03-27 | Kuraray Co | Fuhowaesuteru no seizoho |
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GB1571910A (en) * | 1975-12-18 | 1980-07-23 | Nat Distillers Chem Corp | Vinyl acetate process and catalyst therefor |
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US4158737A (en) * | 1976-12-14 | 1979-06-19 | National Distillers And Chemical Corp. | Vinyl acetate preparation |
DE2811115A1 (de) * | 1978-03-15 | 1979-09-27 | Hoechst Ag | Traeger-katalysator fuer die herstellung von vinylacetat aus ethylen, essigsaeure und sauerstoff in der gasphase |
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US4550097A (en) * | 1984-08-20 | 1985-10-29 | Phillips Petroleum Company | Catalyst for the production of allyl acetate |
DE3803900A1 (de) * | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
US5225388A (en) * | 1989-12-05 | 1993-07-06 | Hoechst Aktiengesellschaft | Method for making a catalyst |
US5179056A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Production of alkenyl alkanoate catalysts |
US5274181A (en) * | 1991-05-06 | 1993-12-28 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5185308A (en) * | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5179057A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for alkenyl alkanoate production |
US5342987A (en) * | 1991-05-06 | 1994-08-30 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate production |
TW213869B (ru) * | 1991-06-21 | 1993-10-01 | Hoechst Ag | |
DE4120492A1 (de) * | 1991-06-21 | 1992-12-24 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
US5189004A (en) * | 1991-11-18 | 1993-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
DE69217648T2 (de) * | 1992-03-30 | 1997-06-12 | Union Carbide Chem Plastic | Verfahren für die Herstellung eines Katalysators für die Bereitung von Alkenylalkanoaten |
TW330160B (en) * | 1992-04-08 | 1998-04-21 | Hoechst Ag | Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate |
US5347046A (en) * | 1993-05-25 | 1994-09-13 | Engelhard Corporation | Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters |
-
1994
- 1994-11-03 CA CA002135021A patent/CA2135021A1/en not_active Abandoned
- 1994-11-04 NO NO944220A patent/NO305158B1/no unknown
- 1994-11-10 SG SG1995001777A patent/SG50366A1/en unknown
- 1994-11-10 EP EP94308282A patent/EP0654301B1/en not_active Expired - Lifetime
- 1994-11-10 DE DE69407548T patent/DE69407548T2/de not_active Expired - Fee Related
- 1994-11-10 ES ES94308282T patent/ES2110701T3/es not_active Expired - Lifetime
- 1994-11-17 FI FI945418A patent/FI945418A/fi unknown
- 1994-11-17 NZ NZ264940A patent/NZ264940A/en unknown
- 1994-11-18 KR KR1019940030447A patent/KR950013579A/ko not_active Application Discontinuation
- 1994-11-18 YU YU67094A patent/YU48693B/sh unknown
- 1994-11-18 BR BR9404493A patent/BR9404493A/pt not_active Application Discontinuation
- 1994-11-18 JP JP6285477A patent/JPH07308576A/ja active Pending
- 1994-11-18 MY MYPI94003089A patent/MY131699A/en unknown
- 1994-11-18 US US08/342,314 patent/US5567839A/en not_active Expired - Fee Related
- 1994-11-18 RU RU94040899A patent/RU2132230C1/ru active
- 1994-11-19 CN CN94118926A patent/CN1107831A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
SG50366A1 (en) | 1998-07-20 |
YU48693B (sh) | 1999-07-28 |
EP0654301B1 (en) | 1997-12-29 |
NO944220L (no) | 1995-05-22 |
US5567839A (en) | 1996-10-22 |
CA2135021A1 (en) | 1995-05-20 |
NZ264940A (en) | 1995-11-27 |
MY131699A (en) | 2007-08-30 |
CN1107831A (zh) | 1995-09-06 |
YU67094A (sh) | 1997-05-28 |
FI945418A0 (fi) | 1994-11-17 |
NO305158B1 (no) | 1999-04-12 |
DE69407548D1 (de) | 1998-02-05 |
RU2132230C1 (ru) | 1999-06-27 |
ES2110701T3 (es) | 1998-02-16 |
EP0654301A1 (en) | 1995-05-24 |
JPH07308576A (ja) | 1995-11-28 |
NO944220D0 (no) | 1994-11-04 |
BR9404493A (pt) | 1995-07-11 |
KR950013579A (ko) | 1995-06-15 |
FI945418A (fi) | 1995-05-20 |
DE69407548T2 (de) | 1998-05-07 |
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