RU2719592C2 - Способ получения ацилфосфатов - Google Patents

Способ получения ацилфосфатов Download PDF

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Publication number
RU2719592C2
RU2719592C2 RU2015116292A RU2015116292A RU2719592C2 RU 2719592 C2 RU2719592 C2 RU 2719592C2 RU 2015116292 A RU2015116292 A RU 2015116292A RU 2015116292 A RU2015116292 A RU 2015116292A RU 2719592 C2 RU2719592 C2 RU 2719592C2
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RU
Russia
Prior art keywords
formula
hydrogen
substituent
equal
alkyl
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RU2015116292A
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English (en)
Russian (ru)
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RU2015116292A (ru
Inventor
Хансйорг ГРЮТЦМАХЕР
Георгина МЮЛЛЕР
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Этх Цюрих
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5036—Phosphines containing the structure -C(=X)-P or NC-P
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5063—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds
    • C07F9/5072—Preparation; Separation; Purification; Stabilisation from compounds having the structure P-H or P-Heteroatom, in which one or more of such bonds are converted into P-C bonds from starting materials having the structure P-H
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/572—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/58—Pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
    • C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
RU2015116292A 2012-10-01 2013-09-30 Способ получения ацилфосфатов RU2719592C2 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP12006822 2012-10-01
EP12006822.6 2012-10-01
EP13003616 2013-07-18
EP13003616.3 2013-07-18
PCT/EP2013/070378 WO2014053455A1 (en) 2012-10-01 2013-09-30 A process for the preparation of acylphosphanes

Publications (2)

Publication Number Publication Date
RU2015116292A RU2015116292A (ru) 2016-11-27
RU2719592C2 true RU2719592C2 (ru) 2020-04-21

Family

ID=49301475

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015116292A RU2719592C2 (ru) 2012-10-01 2013-09-30 Способ получения ацилфосфатов

Country Status (9)

Country Link
US (2) US9701700B2 (enExample)
EP (2) EP2903995B1 (enExample)
JP (1) JP6445438B2 (enExample)
KR (1) KR102135300B1 (enExample)
CN (2) CN108383874B (enExample)
BR (1) BR112015007295B1 (enExample)
ES (2) ES2881686T3 (enExample)
RU (1) RU2719592C2 (enExample)
WO (1) WO2014053455A1 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3031798B1 (en) 2014-12-10 2017-09-27 Belenos Clean Power Holding AG A novel cross-linker for the preparation of a new family of single ion conduction polymers for electrochemical devices and such polymers
EP3296301A1 (en) 2016-09-19 2018-03-21 ETH Zürich A versatile process for the preparation of acylphosphines
JP2020500092A (ja) 2016-11-16 2020-01-09 エコール・ポリテクニーク・フェデラル・ドゥ・ローザンヌ (ウ・ペ・エフ・エル)Ecole Polytechnique Federale De Lausanne (Epfl) 光重合性骨充填材材料
EP3409680B1 (en) * 2017-05-30 2021-01-06 IGM Group B.V. Synthesis of bis(acyl)phosphines by activation of unreactive metal phosphides
CN107400144B (zh) * 2017-08-03 2020-04-14 深圳有为技术控股集团有限公司 酰基膦(氧)化合物及其制备方法和应用
EP3539924A1 (en) 2018-03-14 2019-09-18 ETH Zurich Novel vinyl phosphines and photo-initiators obtainable therefrom
EP3539969A1 (en) 2018-03-14 2019-09-18 ETH Zurich Novel photo-initiators and their application
EP3847179A1 (en) 2018-09-07 2021-07-14 IGM Resins Italia S.r.l. Multifunctional bisacylphosphine oxide photoinitiators
EP3747942A1 (en) 2019-06-05 2020-12-09 EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt Bridged phosphorus based flame retardants
CN114728520B (zh) * 2019-11-11 2024-03-08 富士胶片株式会社 活性能量射线固化型油墨及图像记录方法
EP4114339A1 (en) 2020-05-29 2023-01-11 Lumendo AG Crosslinkable prepolymers for chemically stable polymer gels
CN112547122A (zh) * 2020-12-18 2021-03-26 商河知济新材料技术中心 叔丁醇盐和吡啶盐在制备一种光引发剂中的用途
CN120187778A (zh) 2022-09-15 2025-06-20 埃肯有机硅法国简易股份公司 用于生产有机硅弹性体制品的增材制造方法
CN120365331B (zh) * 2025-06-26 2025-11-04 北京大学深圳研究生院 一种光引发剂及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2181726C2 (ru) * 1996-08-28 2002-04-27 Циба Спешиалти Кемикалз Холдинг Инк. Молекулярно-комплексное соединение, фотополимеризующийся состав и способ фотополимеризации
WO2006056541A1 (en) * 2004-11-23 2006-06-01 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphanes and derivatives thereof
RU2396287C2 (ru) * 2004-04-15 2010-08-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ фотохимического отверждения светоизлучающими диодами
WO2011003772A1 (en) * 2009-07-06 2011-01-13 Basf Se Polymer-bound bisacylphosphine oxides
RU2554084C2 (ru) * 2010-06-30 2015-06-27 ДСМ Ай Пи ЭССЕТС Б.В. Жидкий бис(ацил)фосфиноксидный фотоинициатор d1492 и его применение в отверждаемых облучением композициях

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2957931A (en) * 1949-07-28 1960-10-25 Socony Mobil Oil Co Inc Synthesis of compounds having a carbonphosphorus linkage
US2822376A (en) * 1957-02-27 1958-02-04 American Cyanamid Co Reaction of phosphine with alpha, beta-unsatu-rated compounds
TW303379B (enExample) * 1994-03-02 1997-04-21 Ciba Sc Holding Ag
DE59506142D1 (de) * 1994-07-29 1999-07-15 Ciba Sc Pfersee Gmbh Verfahren zur Herstellung von Diestern von Phosphonocarbonsäurederivaten
AU760237B2 (en) 1998-11-30 2003-05-08 Igm Group B.V. Process for preparing acylphosphines and derivatives
JP2001200007A (ja) * 2000-01-19 2001-07-24 Shin Etsu Chem Co Ltd 光硬化性樹脂組成物及び光ファイバー用被覆材
GB2360283B (en) 2000-02-08 2002-08-21 Ciba Sc Holding Ag Monoacylarylphosphines and acylphosphine oxides and sulphides
KR20050044549A (ko) 2001-11-20 2005-05-12 시바 스페셜티 케미칼스 홀딩 인크. 아실포스핀 및 이의 유도체의 멀티머 형태
JP2003228150A (ja) * 2002-02-04 2003-08-15 Konica Corp 光熱写真画像形成材料
BR0312133A (pt) 2002-06-11 2005-04-05 Ciba Sc Holding Ag Formas dìmeras e multìmeras de óxidos de monoacifosfinas e bis-acifosfinas, processo para a preparação das mesmas, bem como composição fotopolimerizável
WO2005014605A1 (en) 2003-07-18 2005-02-17 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphanes and derivatives thereof
WO2006074983A1 (en) 2005-01-17 2006-07-20 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphanes and their oxides and sulphides
JP2007272106A (ja) * 2006-03-31 2007-10-18 Fujifilm Corp ホログラム記録媒体用組成物及びホログラム記録媒体
WO2008003601A1 (en) 2006-07-04 2008-01-10 Ciba Holding Inc. Water based concentrated product forms of photoinitiators made by a heterophase polymerization technique

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2181726C2 (ru) * 1996-08-28 2002-04-27 Циба Спешиалти Кемикалз Холдинг Инк. Молекулярно-комплексное соединение, фотополимеризующийся состав и способ фотополимеризации
RU2396287C2 (ru) * 2004-04-15 2010-08-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ фотохимического отверждения светоизлучающими диодами
WO2006056541A1 (en) * 2004-11-23 2006-06-01 Ciba Specialty Chemicals Holding Inc. Process for preparing acylphosphanes and derivatives thereof
WO2011003772A1 (en) * 2009-07-06 2011-01-13 Basf Se Polymer-bound bisacylphosphine oxides
RU2554084C2 (ru) * 2010-06-30 2015-06-27 ДСМ Ай Пи ЭССЕТС Б.В. Жидкий бис(ацил)фосфиноксидный фотоинициатор d1492 и его применение в отверждаемых облучением композициях

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
Ekkehard Lindener et al, Zeitschrift fuer naturforschung teil B, anorganische chemie, organische chemie, verlag der zeitschrift fuer naturforschung, tuebingen, 1978, vol. 338, N 12, 1457-1460. *
Jana Podlahova et al. Collection zechosiovak Chem. Commun., 1983, vol. 48, 2604-2608. *
Kharullin V.K. et al. Bulletin of the academy of sciences of the USSR, Division of chemical science, 1972, vol. 21, N 9, 1997-2000. *
Kharullin V.K. et al. Bulletin of the academy of sciences of the USSR, Division of chemical science, 1972, vol. 21, N 9, 1997-2000. Steffen Jockusch et al. Journal of the American chemical society, 1998, vol. 120, 45, 11773-11777. *
R.G. Kostyanovskii et al. Bulletin of the academy of sciences of the USSR, division of chemical sciences, vol. 31, N7, 1433-1441 (таблица 1, экспериментальная часть, соединение (VI). *
R.G. Kostyanovskii et al. Bulletin of the academy of sciences of the USSR, division of chemical sciences, vol. 31, N7, 1433-1441 (таблица 1, экспериментальная часть, соединение (VI). Ekkehard Lindener et al, Zeitschrift fuer naturforschung teil B, anorganische chemie, organische chemie, verlag der zeitschrift fuer naturforschung, tuebingen, 1978, vol. 338, N 12, 1457-1460. Jana Podlahova et al. Collection zechosiovak Chem. Commun., 1983, vol. 48, 2604-2608. *
Sasse K. "Methoden der organischen chemie", Houben-Weyl G. Thieme Verlag Stutgart, 1963, vol. 12, 25-28. *
Steffen Jockusch et al. Journal of the American chemical society, 1998, vol. 120, 45, 11773-11777. *

Also Published As

Publication number Publication date
US9701700B2 (en) 2017-07-11
CN108383874B (zh) 2021-10-08
ES2720760T3 (es) 2019-07-24
RU2015116292A (ru) 2016-11-27
ES2881686T3 (es) 2021-11-30
US10273258B2 (en) 2019-04-30
KR102135300B1 (ko) 2020-08-27
JP2015532275A (ja) 2015-11-09
WO2014053455A1 (en) 2014-04-10
EP2903995A1 (en) 2015-08-12
EP3508489A1 (en) 2019-07-10
KR20150064747A (ko) 2015-06-11
US20180002357A1 (en) 2018-01-04
BR112015007295B1 (pt) 2021-12-14
CN108383874A (zh) 2018-08-10
BR112015007295A2 (pt) 2017-07-04
CN104703995A (zh) 2015-06-10
CN104703995B (zh) 2018-04-20
JP6445438B2 (ja) 2018-12-26
EP3508489B1 (en) 2021-04-14
EP2903995B1 (en) 2019-01-16
US20150299231A1 (en) 2015-10-22

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