RU2552728C2 - Применение поверхностно модифицированного технического углерода в эластомерах для снижения гистерезиса резин и сопротивления качению шин и улучшения сцепления с дорогой во влажном состоянии - Google Patents
Применение поверхностно модифицированного технического углерода в эластомерах для снижения гистерезиса резин и сопротивления качению шин и улучшения сцепления с дорогой во влажном состоянии Download PDFInfo
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- RU2552728C2 RU2552728C2 RU2012111684/05A RU2012111684A RU2552728C2 RU 2552728 C2 RU2552728 C2 RU 2552728C2 RU 2012111684/05 A RU2012111684/05 A RU 2012111684/05A RU 2012111684 A RU2012111684 A RU 2012111684A RU 2552728 C2 RU2552728 C2 RU 2552728C2
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- Prior art keywords
- functional groups
- carbon black
- polymer
- rubber
- modified carbon
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 177
- 239000005060 rubber Substances 0.000 title claims abstract description 120
- 238000005096 rolling process Methods 0.000 title claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 239000000806 elastomer Substances 0.000 title claims description 57
- 239000000203 mixture Substances 0.000 claims abstract description 160
- 229920000642 polymer Polymers 0.000 claims abstract description 98
- 125000000524 functional group Chemical group 0.000 claims abstract description 70
- 150000001875 compounds Chemical class 0.000 claims abstract description 48
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims description 107
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 70
- 230000003993 interaction Effects 0.000 claims description 43
- 239000000377 silicon dioxide Substances 0.000 claims description 35
- 150000001721 carbon Chemical class 0.000 claims description 34
- 235000012239 silicon dioxide Nutrition 0.000 claims description 31
- 239000000945 filler Substances 0.000 claims description 28
- 150000001412 amines Chemical class 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 16
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 13
- 238000005299 abrasion Methods 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 241000872198 Serjania polyphylla Species 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- 150000002978 peroxides Chemical class 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 8
- 239000004570 mortar (masonry) Substances 0.000 claims description 6
- 238000005660 chlorination reaction Methods 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 229920002943 EPDM rubber Polymers 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 238000010301 surface-oxidation reaction Methods 0.000 claims description 2
- 239000007800 oxidant agent Substances 0.000 claims 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 5
- 239000012320 chlorinating reagent Substances 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 239000005062 Polybutadiene Substances 0.000 claims 1
- MKKVKFWHNPAATH-UHFFFAOYSA-N [C].N Chemical compound [C].N MKKVKFWHNPAATH-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 21
- 238000009472 formulation Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 78
- 230000007423 decrease Effects 0.000 description 23
- 230000009467 reduction Effects 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- 239000003607 modifier Substances 0.000 description 9
- 230000008901 benefit Effects 0.000 description 8
- 238000004073 vulcanization Methods 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241001441571 Hiodontidae Species 0.000 description 3
- -1 functional groups carboxylic acid Chemical class 0.000 description 3
- 238000006385 ozonation reaction Methods 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 238000010058 rubber compounding Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- MFHNAXHSHOCFEC-UHFFFAOYSA-N 1,1-diphenylguanidine Chemical compound C=1C=CC=CC=1N(C(=N)N)C1=CC=CC=C1 MFHNAXHSHOCFEC-UHFFFAOYSA-N 0.000 description 1
- CBXRMKZFYQISIV-UHFFFAOYSA-N 1-n,1-n,1-n',1-n',2-n,2-n,2-n',2-n'-octamethylethene-1,1,2,2-tetramine Chemical compound CN(C)C(N(C)C)=C(N(C)C)N(C)C CBXRMKZFYQISIV-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000012767 functional filler Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 238000005550 wet granulation Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Tires In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23759309P | 2009-08-27 | 2009-08-27 | |
| US61/237,593 | 2009-08-27 | ||
| PCT/US2010/043384 WO2011028337A2 (en) | 2009-08-27 | 2010-07-27 | Use of surface-treated carbon blacks in an elastomer to reduce compound hysteresis and tire rolling resistance and improve wet traction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012111684A RU2012111684A (ru) | 2013-10-10 |
| RU2552728C2 true RU2552728C2 (ru) | 2015-06-10 |
Family
ID=43649851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012111684/05A RU2552728C2 (ru) | 2009-08-27 | 2010-07-27 | Применение поверхностно модифицированного технического углерода в эластомерах для снижения гистерезиса резин и сопротивления качению шин и улучшения сцепления с дорогой во влажном состоянии |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US20130046064A1 (e) |
| EP (2) | EP3666825A1 (e) |
| JP (1) | JP5976538B2 (e) |
| KR (1) | KR101679455B1 (e) |
| CN (1) | CN102575082B (e) |
| AR (1) | AR078145A1 (e) |
| BR (1) | BR112012004206A2 (e) |
| ES (1) | ES2771474T3 (e) |
| HU (1) | HUE047720T2 (e) |
| IN (1) | IN2012DN02519A (e) |
| MX (1) | MX365870B (e) |
| MY (1) | MY170989A (e) |
| PL (1) | PL2470604T3 (e) |
| RU (1) | RU2552728C2 (e) |
| SG (2) | SG10201405280VA (e) |
| TW (1) | TWI534187B (e) |
| WO (1) | WO2011028337A2 (e) |
| ZA (1) | ZA201202207B (e) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI465500B (zh) | 2010-09-03 | 2014-12-21 | Cabot Corp | 經修飾充填物及包含其之彈性複合物 |
| US9175150B2 (en) | 2012-03-02 | 2015-11-03 | Cabot Corporation | Modified carbon blacks having low PAH amounts and elastomers containing the same |
| KR101696529B1 (ko) | 2012-03-02 | 2017-01-13 | 캐보트 코포레이션 | 개질된 충전제 및 관능화 엘라스토머를 함유하는 엘라스토머 복합재 |
| JP5977079B2 (ja) * | 2012-05-17 | 2016-08-24 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP5977078B2 (ja) * | 2012-05-17 | 2016-08-24 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
| JP2013241480A (ja) * | 2012-05-17 | 2013-12-05 | Sumitomo Rubber Ind Ltd | タイヤ用ゴム組成物及び空気入りタイヤ |
| WO2015178309A1 (ja) * | 2014-05-23 | 2015-11-26 | ダイキン工業株式会社 | フッ素ゴム組成物及びフッ素ゴム成形品 |
| DE102016201801A1 (de) | 2015-11-21 | 2017-05-24 | Suncoal Industries Gmbh | Partikelförmiges Kohlenstoffmaterial herstellbar aus nachwachsenden Rohstoffen und Verfahren zu dessen Herstellung |
| CN109414959A (zh) | 2016-06-29 | 2019-03-01 | 汉森和罗森塔尔公司 | 包含酯的组合物 |
| US20180171114A1 (en) | 2016-12-21 | 2018-06-21 | The Goodyear Tire & Rubber Company | Rubber composition and pneumatic tire |
| US10457797B2 (en) | 2017-04-04 | 2019-10-29 | The Goodyear Tire & Rubber Company | Tire with tread with oxidized carbon black |
| US10208189B2 (en) * | 2017-04-04 | 2019-02-19 | The Goodyear Tire & Rubber Company | Tire with tread with oxidized carbon black |
| EP3642043A4 (en) * | 2017-06-21 | 2021-04-14 | Birla Carbon U.S.A., Inc. | CARBON BLACK FUNCTIONALIZED FOR INTERACTION WITH LIQUID OR POLYMERIC SYSTEMS |
| US20200131344A1 (en) * | 2017-07-07 | 2020-04-30 | Birla Carbon U.S.A., Inc. | Epoxidized Natural Rubber Composition |
| US20190061424A1 (en) | 2017-08-31 | 2019-02-28 | The Goodyear Tire & Rubber Company | Heavy duty tire with natural rubber based tread containing oxidized carbon black reinforcing filler |
| WO2019094926A1 (en) * | 2017-11-13 | 2019-05-16 | Birla Carbon U.S.A. Inc. | High resistivity rubber compositions comprising oxidized carbon black |
| WO2020028903A1 (en) * | 2018-08-03 | 2020-02-06 | Birla Carbon U.S.A., Inc. | Rubber composition with surface-modified carbon black and functionalized process oil |
| DE102018220946A1 (de) | 2018-12-04 | 2020-06-04 | Suncoal Industries Gmbh | Partikelförmige Kohlenstoffmaterialien und Verfahren zu deren Auftrennung |
| WO2020169809A2 (de) | 2019-02-21 | 2020-08-27 | Suncoal Industries Gmbh | Verfahren zur geruchsreduktion partikelförmiger kohlenstoffmaterialien |
| US11220595B2 (en) | 2019-03-04 | 2022-01-11 | The Goodyear Tire & Rubber Company | Reinforced rubber containing silylated triglyceride oil |
| US20200399497A1 (en) | 2019-06-20 | 2020-12-24 | The Goodyear Tire & Rubber Company | Wire coat composition and a tire comprising a wire coat composition |
| CN114127163B (zh) * | 2019-07-02 | 2024-03-08 | 欧励隆工程炭知识产权有限两合公司 | 官能化炭黑、其制备和在可硫化橡胶组合物中的用途 |
| US12522627B2 (en) | 2019-07-10 | 2026-01-13 | Suncoal Industries Gmbh | Method for producing stabilized lignin |
| EP3960491A1 (en) | 2020-08-27 | 2022-03-02 | Orion Engineered Carbons GmbH | Solid carbon black material, preparation thereof and compositions and articles containing the same |
| US11753549B2 (en) * | 2021-01-29 | 2023-09-12 | Continental Carbon Co. | Surface modified carbon black to simultaneously improve rolling resistance, wet traction, and wear resistance |
| US12391835B2 (en) | 2021-01-29 | 2025-08-19 | Continental Carbon Co. | Refined surface modified carbon black and methods of making same |
| EP4650395A1 (en) | 2024-05-16 | 2025-11-19 | Orion Engineered Carbons IP GmbH & Co. KG | Functionalized carbon black and use thereof in vulcanizable rubber compositions |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1068445A1 (ru) * | 1981-05-12 | 1984-01-23 | Научно-исследовательский и проектно-конструкторский институт углеродистых пигментов и наполнителей | Вулканизуема резинова смесь |
| US5248722A (en) * | 1992-06-02 | 1993-09-28 | Bridgestone Corporation | Tire tread composition |
| US5977238A (en) * | 1997-07-11 | 1999-11-02 | Michelin & Cie | Rubber composition based on carbon black having silica fixed to its surface and on diene polymer functionalized with alkoxysilane |
| US6071995A (en) * | 1997-05-07 | 2000-06-06 | Michelin & Cie | Rubber composition based on carbon black having silica fixed to its surface and on diene polymer functionalized or modified with silanol functions |
| RU2215756C2 (ru) * | 2001-06-08 | 2003-11-10 | Химический факультет МГУ им. М.В. Ломоносова | Резиновая композиция |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3364156A (en) * | 1965-08-12 | 1968-01-16 | Phillips Petroleum Co | Rubber reinforced with carbon black blends |
| US3330799A (en) * | 1966-01-24 | 1967-07-11 | Huber Corp J M | Electrically insulating vulcanizates containing oxidized carbon black |
| US3565657A (en) * | 1967-06-19 | 1971-02-23 | Cabot Corp | Process for treating furnace carbon black |
| JPH068366B2 (ja) * | 1987-04-23 | 1994-02-02 | 株式会社ブリヂストン | タイヤ用ゴム組成物 |
| US5264290A (en) * | 1988-01-29 | 1993-11-23 | The United States Of America As Represented By The Secretary Of The Army | Rubber compound for tracked vehicle track pads |
| FR2673187B1 (fr) | 1991-02-25 | 1994-07-01 | Michelin & Cie | Composition de caoutchouc et enveloppes de pneumatiques a base de ladite composition. |
| JP3157034B2 (ja) * | 1992-03-12 | 2001-04-16 | 日本エラストマー株式会社 | カルボキシル基含有共役ジエン系重合体の製造方法 |
| US5494955A (en) | 1994-04-08 | 1996-02-27 | Columbian Chemicals Company | Use of silane coupling agent with carbon black to enhance the balance of reinforcement properties of rubber compounds |
| US5708055A (en) | 1995-02-01 | 1998-01-13 | Columbian Chemicals Company | Thermoplastic composition comprising chemically modified carbon black and their applications |
| US6471933B1 (en) | 1995-02-21 | 2002-10-29 | Anderson Oliver Dotson | Ozone-oxidized carbon black composition with low conductivity and improved color |
| US6323273B1 (en) * | 1995-05-22 | 2001-11-27 | Cabot Corporation | Elastomeric compounds incorporating silicon-treated carbon blacks |
| FR2740778A1 (fr) * | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
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| US5723531A (en) * | 1997-04-30 | 1998-03-03 | The Goodyear Tire & Rubber Company | Rubber composition and tire having tread thereof |
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-
2010
- 2010-07-27 IN IN2519DEN2012 patent/IN2012DN02519A/en unknown
- 2010-07-27 ES ES10814124T patent/ES2771474T3/es active Active
- 2010-07-27 EP EP19208378.0A patent/EP3666825A1/en not_active Withdrawn
- 2010-07-27 MX MX2012002304A patent/MX365870B/es active IP Right Grant
- 2010-07-27 US US13/391,085 patent/US20130046064A1/en not_active Abandoned
- 2010-07-27 WO PCT/US2010/043384 patent/WO2011028337A2/en not_active Ceased
- 2010-07-27 KR KR1020127007848A patent/KR101679455B1/ko active Active
- 2010-07-27 BR BR112012004206A patent/BR112012004206A2/pt not_active Application Discontinuation
- 2010-07-27 HU HUE10814124A patent/HUE047720T2/hu unknown
- 2010-07-27 CN CN201080037772.2A patent/CN102575082B/zh active Active
- 2010-07-27 SG SG10201405280VA patent/SG10201405280VA/en unknown
- 2010-07-27 EP EP10814124.3A patent/EP2470604B8/en active Active
- 2010-07-27 PL PL10814124T patent/PL2470604T3/pl unknown
- 2010-07-27 SG SG2012011722A patent/SG178513A1/en unknown
- 2010-07-27 JP JP2012526792A patent/JP5976538B2/ja active Active
- 2010-07-27 MY MYPI2012000787A patent/MY170989A/en unknown
- 2010-07-27 RU RU2012111684/05A patent/RU2552728C2/ru active
- 2010-08-23 TW TW099128121A patent/TWI534187B/zh active
- 2010-08-26 AR ARP100103131A patent/AR078145A1/es active IP Right Grant
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2012
- 2012-03-27 ZA ZA2012/02207A patent/ZA201202207B/en unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2470604B1 (en) | 2019-11-13 |
| SG178513A1 (en) | 2012-03-29 |
| ES2771474T3 (es) | 2020-07-06 |
| SG10201405280VA (en) | 2014-10-30 |
| US20130046064A1 (en) | 2013-02-21 |
| HK1172361A1 (en) | 2013-04-19 |
| EP3666825A1 (en) | 2020-06-17 |
| CN102575082A (zh) | 2012-07-11 |
| RU2012111684A (ru) | 2013-10-10 |
| MX365870B (es) | 2019-06-18 |
| EP2470604A2 (en) | 2012-07-04 |
| WO2011028337A3 (en) | 2011-05-12 |
| JP2013503240A (ja) | 2013-01-31 |
| IN2012DN02519A (e) | 2015-08-28 |
| PL2470604T3 (pl) | 2020-06-15 |
| KR101679455B1 (ko) | 2016-11-24 |
| EP2470604A4 (en) | 2015-08-26 |
| CN102575082B (zh) | 2014-10-29 |
| TWI534187B (zh) | 2016-05-21 |
| AR078145A1 (es) | 2011-10-19 |
| ZA201202207B (en) | 2013-09-25 |
| HUE047720T2 (hu) | 2020-05-28 |
| EP2470604B8 (en) | 2019-12-25 |
| BR112012004206A2 (pt) | 2017-05-30 |
| TW201118122A (en) | 2011-06-01 |
| MX2012002304A (es) | 2012-06-19 |
| JP5976538B2 (ja) | 2016-08-23 |
| KR20120104171A (ko) | 2012-09-20 |
| MY170989A (en) | 2019-09-23 |
| WO2011028337A2 (en) | 2011-03-10 |
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