RU2315780C2 - Микроячеистый или неячеистый светоустойчивый полиуретановый материал и способ его приготовления - Google Patents
Микроячеистый или неячеистый светоустойчивый полиуретановый материал и способ его приготовления Download PDFInfo
- Publication number
- RU2315780C2 RU2315780C2 RU2005101616/04A RU2005101616A RU2315780C2 RU 2315780 C2 RU2315780 C2 RU 2315780C2 RU 2005101616/04 A RU2005101616/04 A RU 2005101616/04A RU 2005101616 A RU2005101616 A RU 2005101616A RU 2315780 C2 RU2315780 C2 RU 2315780C2
- Authority
- RU
- Russia
- Prior art keywords
- catalyst
- groups
- alkyl
- formula
- alkenyl group
- Prior art date
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- 239000004814 polyurethane Substances 0.000 title claims abstract description 84
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 84
- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims description 79
- 239000003054 catalyst Substances 0.000 claims abstract description 211
- 239000012948 isocyanate Substances 0.000 claims abstract description 51
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 43
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 41
- 150000001875 compounds Chemical class 0.000 claims abstract description 30
- 239000011541 reaction mixture Substances 0.000 claims abstract description 30
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 29
- -1 isocyanate compound Chemical group 0.000 claims abstract description 24
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 239000002243 precursor Substances 0.000 claims abstract description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 43
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 37
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- 230000003197 catalytic effect Effects 0.000 claims description 21
- 238000004132 cross linking Methods 0.000 claims description 13
- 239000011701 zinc Substances 0.000 claims description 13
- 230000001413 cellular effect Effects 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 11
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 9
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 8
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000005644 linolenyl group Chemical group 0.000 claims description 4
- 125000005645 linoleyl group Chemical group 0.000 claims description 4
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 150000002902 organometallic compounds Chemical class 0.000 claims description 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims 1
- 239000012855 volatile organic compound Substances 0.000 abstract description 28
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- 239000002861 polymer material Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 24
- 229920005862 polyol Polymers 0.000 description 13
- 150000003077 polyols Chemical class 0.000 description 12
- 150000007942 carboxylates Chemical class 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 230000007062 hydrolysis Effects 0.000 description 10
- 238000006460 hydrolysis reaction Methods 0.000 description 10
- RHGQOMYDGHIKFH-GNOQXXQHSA-K bis[[(z)-octadec-9-enoyl]oxy]bismuthanyl (z)-octadec-9-enoate Chemical compound [Bi+3].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O RHGQOMYDGHIKFH-GNOQXXQHSA-K 0.000 description 9
- ZZUFUNZTPNRBID-UHFFFAOYSA-K bismuth;octanoate Chemical compound [Bi+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O ZZUFUNZTPNRBID-UHFFFAOYSA-K 0.000 description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- OYHQOLUKZRVURQ-HZJYTTRNSA-M 9-cis,12-cis-Octadecadienoate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O OYHQOLUKZRVURQ-HZJYTTRNSA-M 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 150000002483 hydrogen compounds Chemical class 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229920005903 polyol mixture Polymers 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000012974 tin catalyst Substances 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 5
- 229940066675 ricinoleate Drugs 0.000 description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- PGQPMLCDSAVZNJ-BGSQTJHASA-L [dimethyl-[(z)-octadec-9-enoyl]oxystannyl] (z)-octadec-9-enoate Chemical class CCCCCCCC\C=C/CCCCCCCC(=O)O[Sn](C)(C)OC(=O)CCCCCCC\C=C/CCCCCCCC PGQPMLCDSAVZNJ-BGSQTJHASA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 229940049918 linoleate Drugs 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 210000000056 organ Anatomy 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 235000019809 paraffin wax Nutrition 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 230000009974 thixotropic effect Effects 0.000 description 3
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- NUMHJBONQMZPBW-UHFFFAOYSA-K bis(2-ethylhexanoyloxy)bismuthanyl 2-ethylhexanoate Chemical compound [Bi+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O NUMHJBONQMZPBW-UHFFFAOYSA-K 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 150000002611 lead compounds Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- XZZXKVYTWCYOQX-UHFFFAOYSA-J octanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O XZZXKVYTWCYOQX-UHFFFAOYSA-J 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- CLCOFENYRCVGPP-WPFVNVICSA-J tris[[(Z,12R)-12-hydroxyoctadec-9-enoyl]oxy]stannyl (Z,12R)-12-hydroxyoctadec-9-enoate Chemical compound [Sn+4].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O CLCOFENYRCVGPP-WPFVNVICSA-J 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- 229940114069 12-hydroxystearate Drugs 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- OGFZJRIBYKSVTN-UHFFFAOYSA-N 2-amino-2-methylpentane-1,3-diol Chemical compound CCC(O)C(C)(N)CO OGFZJRIBYKSVTN-UHFFFAOYSA-N 0.000 description 1
- JCBPETKZIGVZRE-UHFFFAOYSA-N 2-aminobutan-1-ol Chemical compound CCC(N)CO JCBPETKZIGVZRE-UHFFFAOYSA-N 0.000 description 1
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 1
- KQIGMPWTAHJUMN-UHFFFAOYSA-N 3-aminopropane-1,2-diol Chemical compound NCC(O)CO KQIGMPWTAHJUMN-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KCDMKBFJZCZGES-YFTRRBBBSA-K C(CCCCCCC\C=C/CCCC)(=O)[O-].[Bi+3].C(CCCCCCC\C=C/CCCC)(=O)[O-].C(CCCCCCC\C=C/CCCC)(=O)[O-] Chemical compound C(CCCCCCC\C=C/CCCC)(=O)[O-].[Bi+3].C(CCCCCCC\C=C/CCCC)(=O)[O-].C(CCCCCCC\C=C/CCCC)(=O)[O-] KCDMKBFJZCZGES-YFTRRBBBSA-K 0.000 description 1
- 0 C*(C1)C1N(OC(C1NCC1)O)O*(C)(C)ON(C1CNC1)OC Chemical compound C*(C1)C1N(OC(C1NCC1)O)O*(C)(C)ON(C1CNC1)OC 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- FGPCETMNRYMFJR-UHFFFAOYSA-L [7,7-dimethyloctanoyloxy(dimethyl)stannyl] 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)O[Sn](C)(C)OC(=O)CCCCCC(C)(C)C FGPCETMNRYMFJR-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- MDUKBPIXTZFODN-UHFFFAOYSA-K bismuth tetradecanoate Chemical compound C(CCCCCCCCCCCCC)(=O)[O-].[Bi+3].C(CCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCC)(=O)[O-] MDUKBPIXTZFODN-UHFFFAOYSA-K 0.000 description 1
- JDIBGQFKXXXXPN-UHFFFAOYSA-N bismuth(3+) Chemical group [Bi+3] JDIBGQFKXXXXPN-UHFFFAOYSA-N 0.000 description 1
- NSPSPMKCKIPQBH-UHFFFAOYSA-K bismuth;7,7-dimethyloctanoate Chemical compound [Bi+3].CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O.CC(C)(C)CCCCCC([O-])=O NSPSPMKCKIPQBH-UHFFFAOYSA-K 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000007036 catalytic synthesis reaction Methods 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- LBVKKIZHXBASRJ-UHFFFAOYSA-K di(hexadecanoyloxy)bismuthanyl hexadecanoate Chemical compound [Bi+3].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O LBVKKIZHXBASRJ-UHFFFAOYSA-K 0.000 description 1
- GRBFCEINWFRDOG-UHFFFAOYSA-K di(octadecanoyloxy)bismuthanyl octadecanoate Chemical compound [Bi+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O GRBFCEINWFRDOG-UHFFFAOYSA-K 0.000 description 1
- JQZRVMZHTADUSY-UHFFFAOYSA-L di(octanoyloxy)tin Chemical compound [Sn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O JQZRVMZHTADUSY-UHFFFAOYSA-L 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- HLJDOURGTRAFHE-UHFFFAOYSA-N isocyanic acid;3,5,5-trimethylcyclohex-2-en-1-one Chemical compound N=C=O.N=C=O.CC1=CC(=O)CC(C)(C)C1 HLJDOURGTRAFHE-UHFFFAOYSA-N 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- BWTBHGDNJBIYAQ-UHFFFAOYSA-N n,n'-diethyl-n,n'-dimethylethane-1,2-diamine Chemical compound CCN(C)CCN(C)CC BWTBHGDNJBIYAQ-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229940031826 phenolate Drugs 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical compound [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/244—Catalysts containing metal compounds of tin tin salts of carboxylic acids
- C08G18/246—Catalysts containing metal compounds of tin tin salts of carboxylic acids containing also tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
- C08G18/6688—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3271
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2290/00—Compositions for creating anti-fogging
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
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| BEPCT/BE02/00104 | 2002-06-21 |
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| RU2005101616A RU2005101616A (ru) | 2005-08-10 |
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Country Status (16)
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| US (1) | US20040019175A1 (enExample) |
| EP (1) | EP1519974B1 (enExample) |
| JP (1) | JP4538317B2 (enExample) |
| KR (1) | KR101071099B1 (enExample) |
| CN (1) | CN1295263C (enExample) |
| AU (1) | AU2003238574A1 (enExample) |
| BR (1) | BR0311962A (enExample) |
| CA (1) | CA2489547C (enExample) |
| HR (1) | HRP20050063A2 (enExample) |
| IN (1) | IN2004CH03182A (enExample) |
| MX (1) | MXPA05000007A (enExample) |
| PL (1) | PL374319A1 (enExample) |
| RS (1) | RS111604A (enExample) |
| RU (1) | RU2315780C2 (enExample) |
| WO (1) | WO2004000905A1 (enExample) |
| ZA (1) | ZA200410091B (enExample) |
Cited By (7)
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| RU2543197C2 (ru) * | 2009-05-27 | 2015-02-27 | Байер Матириальсайенс Аг | Способ получения пенополиуретанов |
| RU2564662C2 (ru) * | 2009-10-30 | 2015-10-10 | Байер Матириальсайенс Аг | Применение оловосодержащих катализаторов для изготовления полиуретановых покрытий |
| RU2571419C2 (ru) * | 2010-07-08 | 2015-12-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полиуретаны, изготовленные с применением цинковых катализаторов |
| RU2604531C2 (ru) * | 2011-07-26 | 2016-12-10 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Способ получения гибкого пенополиуретана |
| RU2632891C2 (ru) * | 2011-12-12 | 2017-10-11 | Сикэ Текнолоджи Аг | Висмутсодержащий катализатор для полиуретановых композиций |
| RU2652984C2 (ru) * | 2012-11-29 | 2018-05-04 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Способ получения пенополиуретана с использованием катализатора на основе тетраалкилоксиолова |
| RU2759642C2 (ru) * | 2017-04-28 | 2021-11-16 | Ректисель Аутомобильзюстеме Гмбх | Эластомерные композитные полиуретановые обшивки |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE10052856A1 (de) * | 2000-10-24 | 2002-04-25 | Linde Ag | Speicherbehälter für kryogene Medien |
| EP1375546A1 (en) * | 2002-06-21 | 2004-01-02 | Crompton GmbH | Low emission tin catalysts |
| DE102004009740A1 (de) * | 2004-02-25 | 2005-09-15 | Basf Ag | Zinn- und Übergangsmetallfreie Polyurethanschaumstoffe |
| US7021498B2 (en) | 2004-04-06 | 2006-04-04 | Advanced Controls And Engineering | Urethane spray gun assembly |
| US20070185223A1 (en) * | 2005-02-18 | 2007-08-09 | Basf Aktiengesellschaft | Tin and transition metal free polyurethane foams |
| US7615177B2 (en) | 2005-02-23 | 2009-11-10 | Calsonickansei North America, Inc. | Trim articles with invisible tear seams and methods of making the same |
| DE102005028785A1 (de) * | 2005-06-22 | 2006-12-28 | Bayer Materialscience Ag | Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US7772353B2 (en) * | 2005-12-15 | 2010-08-10 | Bayer Materialscience Llc | Fast curing aliphatic RIM elastomers |
| BRPI0621754B1 (pt) | 2006-05-30 | 2017-05-16 | Recticel Automobilsysteme Gmbh | método para a produção de uma película de poliuretano compósita elastomérica flexível, e, película de poliuretano compósita elastomérica flexível |
| CN102558477B (zh) * | 2006-05-30 | 2014-09-10 | 雷克蒂塞尔汽车配件有限公司 | 柔韧性弹性聚氨酯表皮层的制备方法 |
| RU2565080C2 (ru) * | 2006-05-30 | 2015-10-20 | Ректисел Аутомобилзюстем Гмбх | Способ изготовления гибкой эластомерной полиуретановой кожи |
| GB0705685D0 (en) * | 2007-03-24 | 2007-05-02 | Nauer Fritz Ag | Polyurethane foam |
| GB0903717D0 (en) | 2009-03-04 | 2009-04-15 | Innochem Ltd | Flexible polyurethane foam |
| DE102009033710A1 (de) * | 2009-07-18 | 2011-01-20 | Evonik Goldschmidt Gmbh | Verwendung von Metallsalzen einer Carbonsäure bei der Herstellung von Polyurethansystemen |
| DE102009046074A1 (de) * | 2009-10-28 | 2011-05-12 | Henkel Ag & Co. Kgaa | Verwendung von Salzen verzweigter Fettsäuren als Katalysator zur Umsetzung von sternförmigen Alkoholen mit Isocyanaten |
| TWI507294B (zh) | 2009-12-08 | 2015-11-11 | Bayer Materialscience Ag | 具有增進之附著性之聚碳酸酯／聚酯組成物及聚胺基甲酸酯的複合構件 |
| DE102009058182A1 (de) | 2009-12-15 | 2011-06-30 | Bayer MaterialScience AG, 51373 | Verbundbauteile mit verbesserter Haftung aus Polycarbonat- / Polyesterzusammensetzungen und Polyurethan |
| US20110135934A1 (en) | 2009-12-08 | 2011-06-09 | Bayer Materialscience Ag | Process For The Production Of Polyurethane Composite Components |
| DE102009058180A1 (de) | 2009-12-15 | 2011-06-16 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyurethan-Verbundbauteilen |
| EP2365012A1 (en) | 2010-03-05 | 2011-09-14 | RECTICEL Automobilsysteme GmbH | Method for producing a skin layer of a flexible, elastomeric, thermoset, phase-separated polyurethane material |
| WO2012020027A1 (de) | 2010-08-12 | 2012-02-16 | Bayer Materialscience Ag | Lichtechte polyurethane und ihre verwendung |
| MX2014007863A (es) | 2011-12-29 | 2014-09-22 | Bayer Ip Gmbh | Composiciones polimericas con adhesion mejorada. |
| EP2679380A1 (en) | 2012-06-28 | 2014-01-01 | RECTICEL Automobilsysteme GmbH | Method for manufacturing a flexible skin having at least one insert adhered thereto. |
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| EP3009248A1 (en) | 2014-10-13 | 2016-04-20 | RECTICEL Automobilsysteme GmbH | Method for producing an elastomeric skin having a grained surface |
| WO2016178793A1 (en) * | 2015-05-05 | 2016-11-10 | Air Products And Chemicals, Inc. | Delayed action gelling catalyst compositions and methods for making polyurethane polymers |
| WO2018122137A1 (de) | 2016-12-28 | 2018-07-05 | Covestro Deutschland Ag | Verbundbauteil |
| US11046850B2 (en) * | 2017-09-27 | 2021-06-29 | Evonik Operations Gmbh | Mixed metal catalyst compositions and methods for making polyurethane foam |
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| EP3556527A1 (en) | 2018-04-19 | 2019-10-23 | Covestro Deutschland AG | Thermoplastic composite article and manufacturing method and use thereof |
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| KR20220054797A (ko) | 2019-08-28 | 2022-05-03 | 코베스트로 인텔렉쳐 프로퍼티 게엠베하 운트 콤파니 카게 | 난연성 폴리카르보네이트 조성물 및 그로부터 제조된 성형품 뿐만 아니라 물품 |
| EP3883806B1 (en) | 2020-01-16 | 2022-03-30 | Ascorium GmbH | Skin for a vehicle interior trim part comprising a light source |
| CN114845850B (zh) | 2020-01-16 | 2025-09-05 | 阿斯科瑞姆有限责任公司 | 包含操作元件的用于车辆内部装饰部件的蒙皮 |
| WO2024017706A1 (de) | 2022-07-18 | 2024-01-25 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend polycarbonat mit spezifischem oh-gehalt |
| EP4309864B1 (de) | 2022-07-18 | 2024-06-26 | Covestro Deutschland AG | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend polycarbonat mit spezifischem oh-gehalt |
| EP4309865A1 (de) | 2022-07-18 | 2024-01-24 | Covestro Deutschland AG | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend eine hydroxylkomponente |
| WO2024163147A1 (en) * | 2023-02-03 | 2024-08-08 | Galata Chemicals Llc | Process for manufacturing polyurethane foam |
| WO2025082842A1 (de) | 2023-10-17 | 2025-04-24 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils umfassend den schritt des kontaktlosen aufbringens eines flüssigen beschichtungsmittels |
| WO2025132584A1 (de) | 2023-12-21 | 2025-06-26 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils mit einem träger mit aliphatischen oh-gruppen |
| WO2025132581A1 (de) | 2023-12-21 | 2025-06-26 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils umfassend einen träger mit spezifischem oh-gehalt |
| WO2025132585A1 (de) | 2023-12-21 | 2025-06-26 | Covestro Deutschland Ag | Verfahren zur herstellung eines verbundbauteils mit einem träger umfassend polycarbonat und ein additiv, wobei der träger einen spezifischen oh-gehalt aufweist |
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| US4223098A (en) * | 1978-10-30 | 1980-09-16 | M&T Chemicals Inc. | Blowing catalyst composition for low density flexible polyurethane foams |
| US4284751A (en) * | 1980-05-14 | 1981-08-18 | Products Research & Chemical Corp. | Polyurethane sealant system |
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| US5156915A (en) * | 1991-11-26 | 1992-10-20 | Eastman Kodak Company | Moisture stable polyurethane biasable members |
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-
2003
- 2003-06-17 RS YUP-1116/04A patent/RS111604A/sr unknown
- 2003-06-17 WO PCT/BE2003/000107 patent/WO2004000905A1/en not_active Ceased
- 2003-06-17 BR BR0311962-9A patent/BR0311962A/pt not_active Application Discontinuation
- 2003-06-17 EP EP03732138.7A patent/EP1519974B1/en not_active Expired - Lifetime
- 2003-06-17 KR KR1020047020824A patent/KR101071099B1/ko not_active Expired - Lifetime
- 2003-06-17 HR HR20050063A patent/HRP20050063A2/hr not_active Application Discontinuation
- 2003-06-17 CN CNB038145537A patent/CN1295263C/zh not_active Expired - Lifetime
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- 2003-06-17 MX MXPA05000007A patent/MXPA05000007A/es active IP Right Grant
- 2003-06-17 AU AU2003238574A patent/AU2003238574A1/en not_active Abandoned
- 2003-06-17 RU RU2005101616/04A patent/RU2315780C2/ru not_active IP Right Cessation
- 2003-06-17 PL PL03374319A patent/PL374319A1/xx not_active Application Discontinuation
- 2003-06-17 JP JP2004514451A patent/JP4538317B2/ja not_active Expired - Lifetime
- 2003-06-20 US US10/465,816 patent/US20040019175A1/en not_active Abandoned
-
2004
- 2004-12-13 IN IN3182CH2004 patent/IN2004CH03182A/en unknown
- 2004-12-14 ZA ZA200410091A patent/ZA200410091B/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1275018A1 (ru) * | 1985-03-15 | 1986-12-07 | Казанский Ордена Трудового Красного Знамени Химико-Технологический Институт Им.С.М.Кирова | Способ получени эластичных пенополиуретанов |
| US5159012A (en) * | 1991-11-29 | 1992-10-27 | Textile Rubber & Chemical Co., Inc. | Process for the manufacture of polyurethane elastomers |
| US6242555B1 (en) * | 1996-10-01 | 2001-06-05 | Recticel | Light-stable elastomeric polyurethane mouldings and process for the production thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2543197C2 (ru) * | 2009-05-27 | 2015-02-27 | Байер Матириальсайенс Аг | Способ получения пенополиуретанов |
| RU2543197C9 (ru) * | 2009-05-27 | 2015-12-10 | Байер Матириальсайенс Аг | Способ получения пенополиуретанов |
| RU2564662C2 (ru) * | 2009-10-30 | 2015-10-10 | Байер Матириальсайенс Аг | Применение оловосодержащих катализаторов для изготовления полиуретановых покрытий |
| RU2571419C2 (ru) * | 2010-07-08 | 2015-12-20 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полиуретаны, изготовленные с применением цинковых катализаторов |
| RU2604531C2 (ru) * | 2011-07-26 | 2016-12-10 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Способ получения гибкого пенополиуретана |
| RU2632891C2 (ru) * | 2011-12-12 | 2017-10-11 | Сикэ Текнолоджи Аг | Висмутсодержащий катализатор для полиуретановых композиций |
| RU2652984C2 (ru) * | 2012-11-29 | 2018-05-04 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Способ получения пенополиуретана с использованием катализатора на основе тетраалкилоксиолова |
| RU2759642C2 (ru) * | 2017-04-28 | 2021-11-16 | Ректисель Аутомобильзюстеме Гмбх | Эластомерные композитные полиуретановые обшивки |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20050013228A (ko) | 2005-02-03 |
| IN2004CH03182A (enExample) | 2006-03-03 |
| WO2004000905A1 (en) | 2003-12-31 |
| PL374319A1 (en) | 2005-10-17 |
| ZA200410091B (en) | 2006-08-30 |
| RS111604A (sr) | 2007-02-05 |
| CN1295263C (zh) | 2007-01-17 |
| JP4538317B2 (ja) | 2010-09-08 |
| CA2489547C (en) | 2011-08-02 |
| CA2489547A1 (en) | 2003-12-31 |
| BR0311962A (pt) | 2005-03-22 |
| HRP20050063A2 (en) | 2005-04-30 |
| EP1519974B1 (en) | 2017-08-09 |
| JP2005530011A (ja) | 2005-10-06 |
| KR101071099B1 (ko) | 2011-10-10 |
| CN1662574A (zh) | 2005-08-31 |
| US20040019175A1 (en) | 2004-01-29 |
| AU2003238574A1 (en) | 2004-01-06 |
| EP1519974A1 (en) | 2005-04-06 |
| RU2005101616A (ru) | 2005-08-10 |
| MXPA05000007A (es) | 2005-04-08 |
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