RU2307431C2 - Активный катодный материал, содержащий добавку для улучшения переразрядных характеристик, и вторичная литиевая батарея с его использованием - Google Patents
Активный катодный материал, содержащий добавку для улучшения переразрядных характеристик, и вторичная литиевая батарея с его использованием Download PDFInfo
- Publication number
- RU2307431C2 RU2307431C2 RU2005134662/09A RU2005134662A RU2307431C2 RU 2307431 C2 RU2307431 C2 RU 2307431C2 RU 2005134662/09 A RU2005134662/09 A RU 2005134662/09A RU 2005134662 A RU2005134662 A RU 2005134662A RU 2307431 C2 RU2307431 C2 RU 2307431C2
- Authority
- RU
- Russia
- Prior art keywords
- lithium
- manganese oxide
- cathode material
- active cathode
- cathode
- Prior art date
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- 239000006182 cathode active material Substances 0.000 title claims abstract description 43
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 30
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 239000000463 material Substances 0.000 title claims 2
- 229910002102 lithium manganese oxide Inorganic materials 0.000 claims abstract description 39
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000011572 manganese Substances 0.000 claims abstract description 34
- 230000002427 irreversible effect Effects 0.000 claims abstract description 16
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 9
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 9
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000009831 deintercalation Methods 0.000 claims abstract description 7
- 238000009830 intercalation Methods 0.000 claims abstract description 7
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims description 22
- 230000000996 additive effect Effects 0.000 claims description 22
- 229910052596 spinel Inorganic materials 0.000 claims description 13
- 239000011029 spinel Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 10
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 claims description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 5
- -1 LiCF 3 SO 3 Inorganic materials 0.000 claims description 5
- 239000003792 electrolyte Substances 0.000 claims description 5
- 229910003002 lithium salt Inorganic materials 0.000 claims description 5
- 159000000002 lithium salts Chemical class 0.000 claims description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 5
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 4
- 229910015645 LiMn Inorganic materials 0.000 claims description 4
- 229910013716 LiNi Inorganic materials 0.000 claims description 4
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims description 4
- 239000011255 nonaqueous electrolyte Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 3
- KKQAVHGECIBFRQ-UHFFFAOYSA-N methyl propyl carbonate Chemical compound CCCOC(=O)OC KKQAVHGECIBFRQ-UHFFFAOYSA-N 0.000 claims description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 2
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 2
- 229910013733 LiCo Inorganic materials 0.000 claims description 2
- 229910011281 LiCoPO 4 Inorganic materials 0.000 claims description 2
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 2
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 2
- 229910014689 LiMnO Inorganic materials 0.000 claims description 2
- 229910013131 LiN Inorganic materials 0.000 claims description 2
- 229910013290 LiNiO 2 Inorganic materials 0.000 claims description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims 1
- 229910001947 lithium oxide Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002687 intercalation Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 2
- 230000002411 adverse Effects 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 8
- 238000007599 discharging Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 238000009784 over-discharge test Methods 0.000 description 7
- 239000011651 chromium Substances 0.000 description 6
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 5
- 239000010405 anode material Substances 0.000 description 5
- 229910001431 copper ion Inorganic materials 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 230000009466 transformation Effects 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000011889 copper foil Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000012916 structural analysis Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 229910021383 artificial graphite Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000005676 cyclic carbonates Chemical class 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000010295 mobile communication Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0438—Processes of manufacture in general by electrochemical processing
- H01M4/044—Activating, forming or electrochemical attack of the supporting material
- H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
- H01M2300/004—Three solvents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2003-0022429A KR100533095B1 (ko) | 2003-04-09 | 2003-04-09 | 과방전 방지제를 포함하는 양극 활물질 및 이를 이용한리튬 이차 전지 |
| KR10-2003-0022429 | 2003-04-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005134662A RU2005134662A (ru) | 2006-04-10 |
| RU2307431C2 true RU2307431C2 (ru) | 2007-09-27 |
Family
ID=36241085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005134662/09A RU2307431C2 (ru) | 2003-04-09 | 2004-04-06 | Активный катодный материал, содержащий добавку для улучшения переразрядных характеристик, и вторичная литиевая батарея с его использованием |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20070015055A1 (https=) |
| EP (1) | EP1609201A4 (https=) |
| JP (1) | JP2006512747A (https=) |
| KR (1) | KR100533095B1 (https=) |
| CN (1) | CN1771618A (https=) |
| BR (1) | BRPI0409759B8 (https=) |
| CA (1) | CA2522107C (https=) |
| RU (1) | RU2307431C2 (https=) |
| TW (1) | TWI269472B (https=) |
| WO (1) | WO2004091016A1 (https=) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2403654C1 (ru) * | 2007-10-29 | 2010-11-10 | ДАЭДЖУНГ ЭМ КО., Лтд. | Катодный активный материал для литиевых вторичных батарей с высокой безопасностью, способ приготовления этого материала и литиевые вторичные батареи, содержащие этот материал |
| RU2430449C1 (ru) * | 2007-10-13 | 2011-09-27 | ЭлДжи КЕМ, ЛТД. | Активный катодный материал для перезаряжаемых литиевых батарей |
| RU2444815C1 (ru) * | 2010-08-27 | 2012-03-10 | Учреждение Российской академии наук Институт химии твердого тела и механохимии Сибирского отделения РАН (ИХТТМ СО РАН) | СПОСОБ ПОЛУЧЕНИЯ ВЫСОКОДИСПЕРСНЫХ КАТОДНЫХ МАТЕРИАЛОВ LixFeyMzPO4/C СО СТРУКТУРОЙ ОЛИВИНА |
| RU2457585C1 (ru) * | 2011-05-05 | 2012-07-27 | Государственное образовательное учреждение высшего профессионального образования Саратовский государственный технический университет (ГОУ ВПО СГТУ) | Катодный материал для литиевого источника тока |
| RU2538605C2 (ru) * | 2011-08-03 | 2015-01-10 | Российская Федерация,от имени которой выступает Министерство образования и науки Российской Федерации | Способ получения нитевидных кристаллов активного материала положительного электрода литий-воздушного аккумулятора |
| RU2693858C1 (ru) * | 2018-01-17 | 2019-07-05 | Тойота Дзидося Кабусики Кайся | Катодная смесь для полностью твердотельной батареи, катод для полностью твердотельной батареи, полностью твердотельная батарея и способ их изготовления |
| RU2702785C1 (ru) * | 2018-08-29 | 2019-10-14 | Автономная некоммерческая образовательная организация высшего образования "Сколковский институт науки и технологий" | Защитное шпинельное покрытие для ni-mn-co (nmc) катода с повышенным содержанием li для литий-ионных аккумуляторов, способ нанесения указанного покрытия на катод и катод с указанным покрытием |
| RU2755515C1 (ru) * | 2020-03-18 | 2021-09-16 | Тойота Дзидося Кабусики Кайся | Активный материал положительного электрода и аккумулятор, содержащий активный материал положительного электрода |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2270901B1 (en) * | 2003-09-26 | 2012-12-26 | LG Chem, Ltd. | Method for regulating terminal voltage of cathode during overdischarge and cathode active matrial for lithium secondary battery |
| US20070259271A1 (en) * | 2004-12-13 | 2007-11-08 | Tetsuo Nanno | Laminate Including Active Material Layer and Solid Electrolyte Layer, and All Solid Lithium Secondary Battery Using the Same |
| WO2006108302A1 (en) * | 2005-04-15 | 2006-10-19 | Avestor Limited Partnership | LITHIUM RECHARGEABLE CELL HAVING AN EXCESS OF LiFePO4 BASED CATHODE RELATIVE TO A Li4Ti5O12 BASED ANODE |
| WO2006112674A1 (en) | 2005-04-22 | 2006-10-26 | Lg Chem, Ltd. | New system of lithium ion battery containing material with high irreversible capacity |
| US7923150B2 (en) | 2005-08-26 | 2011-04-12 | Panasonic Corporation | Non-aqueous electrolyte secondary battery |
| JP5016814B2 (ja) * | 2005-12-14 | 2012-09-05 | 株式会社日立製作所 | 非水系二次電池 |
| US7494744B2 (en) * | 2006-03-08 | 2009-02-24 | Changs-Ascending Enterprise Co. | Cathode material for Li-ion battery applications |
| CN102037601B (zh) | 2007-07-12 | 2014-04-23 | A123系统公司 | 用于锂离子电池的多功能混合金属橄榄石 |
| TWI466370B (zh) | 2008-01-17 | 2014-12-21 | A123 Systems Inc | 鋰離子電池的混合式金屬橄欖石電極材料 |
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| TWI496737B (zh) * | 2009-09-18 | 2015-08-21 | A123 Systems Llc | 磷酸鐵及其製備方法 |
| US10305104B2 (en) | 2010-04-02 | 2019-05-28 | A123 Systems, LLC | Li-ion battery cathode materials with over-discharge protection |
| JP5970978B2 (ja) * | 2011-07-04 | 2016-08-17 | 日産自動車株式会社 | 電気デバイス用正極活物質、電気デバイス用正極及び電気デバイス |
| US9991566B2 (en) * | 2011-11-03 | 2018-06-05 | Johnson Controls Technology Company | Cathode active material for overcharge protection in secondary lithium batteries |
| WO2013108396A1 (ja) * | 2012-01-20 | 2013-07-25 | トヨタ自動車株式会社 | 非水電解質二次電池の製造方法及び非水電解質二次電池 |
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| CN102779998A (zh) * | 2012-07-19 | 2012-11-14 | 东莞新能源科技有限公司 | 一种防止过放电的锂离子单体电池 |
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| WO2015126932A1 (en) * | 2014-02-18 | 2015-08-27 | Brookhaven Science Associates, Llc | Multifunctional cathode additives for battery technologies |
| US20160062984A1 (en) * | 2014-09-03 | 2016-03-03 | Lenovo (Singapore) Pte. Ltd. | Devices and methods for determining a recipient for a message |
| CN106104867B (zh) * | 2015-02-16 | 2019-11-05 | 株式会社东芝 | 非水电解质电池及电池包 |
| CN105206868A (zh) * | 2015-10-23 | 2015-12-30 | 东莞市致格电池科技有限公司 | 一种内燃机启动用锂离子二次电池 |
| KR102268176B1 (ko) * | 2017-08-28 | 2021-06-22 | 주식회사 엘지에너지솔루션 | 리튬 이차전지 |
| KR102346153B1 (ko) | 2017-11-17 | 2022-01-03 | 주식회사 엘지에너지솔루션 | 리튬 이차전지용 양극재에 포함되는 비가역 첨가제의 제조방법, 이에 의해 제조된 비가역 첨가제를 포함하는 양극재, 및 양극재를 포함하는 리튬 이차전지 |
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| PL3985762T3 (pl) * | 2020-01-31 | 2023-10-23 | Lg Energy Solution, Ltd. | Nieodwracalny dodatek zawarty w materiale katodowym dla baterii akumulatorowej, zawierający go materiał katodowy i bateria akumulatorowa zawierająca materiał katodowy |
| WO2023070287A1 (zh) * | 2021-10-25 | 2023-05-04 | 宁德新能源科技有限公司 | 正极极片、电化学装置及电子装置 |
| EP4425596A4 (en) * | 2021-10-25 | 2025-03-05 | Ningde Amperex Technology Limited | Positive plate and lithium-ion secondary battery including same |
| JP7815430B2 (ja) * | 2021-10-25 | 2026-02-17 | 寧徳新能源科技有限公司 | 電気化学装置及びそれを含む電子装置 |
| CN115602817B (zh) * | 2022-11-01 | 2025-09-23 | 国联汽车动力电池研究院有限责任公司 | 补锂型复合正极材料及其制备方法和补锂方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2107360C1 (ru) * | 1993-03-04 | 1998-03-20 | Асахи Касеи Когио Кабусики Кайся | Аккумуляторная батарея |
| RU98120482A (ru) * | 1996-04-08 | 2000-09-20 | Дьюраселл Инк. | Способ получения оксида лития и марганца li8mn2o4-5 со структурой шпинели (варианты) и вторичная перезаряжаемая батарея |
| US6183911B1 (en) * | 1999-03-10 | 2001-02-06 | Samsung Display Devices Co., Ltd. | Positive active material for rechargeable lithium battery and method of preparing same |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5609975A (en) * | 1994-05-13 | 1997-03-11 | Matsushita Electric Industrial Co., Ltd. | Positive electrode for non-aqueous electrolyte lithium secondary battery and method of manufacturing the same |
| CA2240844A1 (en) * | 1995-12-27 | 1997-07-10 | Motorola, Inc. | Electrode material for lithium intercalation electrochemical cells |
| US5753202A (en) * | 1996-04-08 | 1998-05-19 | Duracell Inc. | Method of preparation of lithium manganese oxide spinel |
| JP2974213B1 (ja) * | 1998-11-13 | 1999-11-10 | 宇部興産株式会社 | リチウム二次電池用正極活物質とその製造方法及びその用途 |
| JP2001235312A (ja) * | 2000-02-25 | 2001-08-31 | Hitachi Koki Co Ltd | 電子写真印刷装置の用紙厚検出方法 |
| JP2001339774A (ja) * | 2000-05-30 | 2001-12-07 | Sony Corp | 電子機器 |
| JP4375642B2 (ja) * | 2000-08-30 | 2009-12-02 | 東邦チタニウム株式会社 | マンガン酸リチウムの製造方法、マンガン酸リチウム、これを正極活物質とするリチウムイオン二次電池用正極、及びリチウムイオン二次電池 |
| JP4082855B2 (ja) * | 2000-09-25 | 2008-04-30 | Ａｇｃセイミケミカル株式会社 | リチウム二次電池 |
-
2003
- 2003-04-09 KR KR10-2003-0022429A patent/KR100533095B1/ko not_active Expired - Lifetime
-
2004
- 2004-04-06 CN CNA2004800094978A patent/CN1771618A/zh active Pending
- 2004-04-06 CA CA2522107A patent/CA2522107C/en not_active Expired - Lifetime
- 2004-04-06 EP EP04726032A patent/EP1609201A4/en not_active Withdrawn
- 2004-04-06 JP JP2005518275A patent/JP2006512747A/ja active Pending
- 2004-04-06 BR BRPI0409759A patent/BRPI0409759B8/pt active IP Right Grant
- 2004-04-06 US US10/552,529 patent/US20070015055A1/en not_active Abandoned
- 2004-04-06 WO PCT/KR2004/000786 patent/WO2004091016A1/en not_active Ceased
- 2004-04-06 TW TW093109421A patent/TWI269472B/zh not_active IP Right Cessation
- 2004-04-06 RU RU2005134662/09A patent/RU2307431C2/ru active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2107360C1 (ru) * | 1993-03-04 | 1998-03-20 | Асахи Касеи Когио Кабусики Кайся | Аккумуляторная батарея |
| RU98120482A (ru) * | 1996-04-08 | 2000-09-20 | Дьюраселл Инк. | Способ получения оксида лития и марганца li8mn2o4-5 со структурой шпинели (варианты) и вторичная перезаряжаемая батарея |
| US6183911B1 (en) * | 1999-03-10 | 2001-02-06 | Samsung Display Devices Co., Ltd. | Positive active material for rechargeable lithium battery and method of preparing same |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2430449C1 (ru) * | 2007-10-13 | 2011-09-27 | ЭлДжи КЕМ, ЛТД. | Активный катодный материал для перезаряжаемых литиевых батарей |
| RU2403654C1 (ru) * | 2007-10-29 | 2010-11-10 | ДАЭДЖУНГ ЭМ КО., Лтд. | Катодный активный материал для литиевых вторичных батарей с высокой безопасностью, способ приготовления этого материала и литиевые вторичные батареи, содержащие этот материал |
| RU2444815C1 (ru) * | 2010-08-27 | 2012-03-10 | Учреждение Российской академии наук Институт химии твердого тела и механохимии Сибирского отделения РАН (ИХТТМ СО РАН) | СПОСОБ ПОЛУЧЕНИЯ ВЫСОКОДИСПЕРСНЫХ КАТОДНЫХ МАТЕРИАЛОВ LixFeyMzPO4/C СО СТРУКТУРОЙ ОЛИВИНА |
| RU2457585C1 (ru) * | 2011-05-05 | 2012-07-27 | Государственное образовательное учреждение высшего профессионального образования Саратовский государственный технический университет (ГОУ ВПО СГТУ) | Катодный материал для литиевого источника тока |
| RU2538605C2 (ru) * | 2011-08-03 | 2015-01-10 | Российская Федерация,от имени которой выступает Министерство образования и науки Российской Федерации | Способ получения нитевидных кристаллов активного материала положительного электрода литий-воздушного аккумулятора |
| RU2693858C1 (ru) * | 2018-01-17 | 2019-07-05 | Тойота Дзидося Кабусики Кайся | Катодная смесь для полностью твердотельной батареи, катод для полностью твердотельной батареи, полностью твердотельная батарея и способ их изготовления |
| RU2702785C1 (ru) * | 2018-08-29 | 2019-10-14 | Автономная некоммерческая образовательная организация высшего образования "Сколковский институт науки и технологий" | Защитное шпинельное покрытие для ni-mn-co (nmc) катода с повышенным содержанием li для литий-ионных аккумуляторов, способ нанесения указанного покрытия на катод и катод с указанным покрытием |
| RU2755515C1 (ru) * | 2020-03-18 | 2021-09-16 | Тойота Дзидося Кабусики Кайся | Активный материал положительного электрода и аккумулятор, содержащий активный материал положительного электрода |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1609201A4 (en) | 2009-11-11 |
| BRPI0409759B1 (pt) | 2015-12-29 |
| RU2005134662A (ru) | 2006-04-10 |
| KR20040088292A (ko) | 2004-10-16 |
| US20070015055A1 (en) | 2007-01-18 |
| BRPI0409759B8 (pt) | 2023-01-17 |
| TW200501472A (en) | 2005-01-01 |
| EP1609201A1 (en) | 2005-12-28 |
| JP2006512747A (ja) | 2006-04-13 |
| BRPI0409759A (pt) | 2006-05-09 |
| WO2004091016A1 (en) | 2004-10-21 |
| CN1771618A (zh) | 2006-05-10 |
| CA2522107C (en) | 2013-04-02 |
| KR100533095B1 (ko) | 2005-12-01 |
| TWI269472B (en) | 2006-12-21 |
| CA2522107A1 (en) | 2004-10-21 |
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