RU2263670C2 - Способ осуществления эпоксидирования этилена - Google Patents
Способ осуществления эпоксидирования этилена Download PDFInfo
- Publication number
- RU2263670C2 RU2263670C2 RU2002135677/04A RU2002135677A RU2263670C2 RU 2263670 C2 RU2263670 C2 RU 2263670C2 RU 2002135677/04 A RU2002135677/04 A RU 2002135677/04A RU 2002135677 A RU2002135677 A RU 2002135677A RU 2263670 C2 RU2263670 C2 RU 2263670C2
- Authority
- RU
- Russia
- Prior art keywords
- ethylene
- ethylene oxide
- catalyst
- concentration
- phase
- Prior art date
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59152500A | 2000-06-09 | 2000-06-09 | |
| US09/591,525 | 2000-06-09 | ||
| US09/735,360 | 2000-12-12 | ||
| US09/735,360 US6372925B1 (en) | 2000-06-09 | 2000-12-12 | Process for operating the epoxidation of ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2002135677A RU2002135677A (ru) | 2004-05-10 |
| RU2263670C2 true RU2263670C2 (ru) | 2005-11-10 |
Family
ID=27081174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2002135677/04A RU2263670C2 (ru) | 2000-06-09 | 2001-06-05 | Способ осуществления эпоксидирования этилена |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US6372925B1 (forum.php) |
| EP (1) | EP1292587B1 (forum.php) |
| JP (1) | JP5097325B2 (forum.php) |
| KR (1) | KR100827473B1 (forum.php) |
| CN (1) | CN1217941C (forum.php) |
| AT (1) | ATE342259T1 (forum.php) |
| AU (1) | AU2001266704A1 (forum.php) |
| BR (1) | BR0111475B1 (forum.php) |
| CA (1) | CA2411070C (forum.php) |
| DE (1) | DE60123788T2 (forum.php) |
| ES (1) | ES2269421T3 (forum.php) |
| GC (1) | GC0000430A (forum.php) |
| IN (1) | IN2002DE01165A (forum.php) |
| MX (1) | MXPA02012036A (forum.php) |
| MY (1) | MY128386A (forum.php) |
| RU (1) | RU2263670C2 (forum.php) |
| TW (1) | TWI230707B (forum.php) |
| WO (1) | WO2001096324A2 (forum.php) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2447069C2 (ru) * | 2007-09-10 | 2012-04-10 | Сд Лиценцфервертунгсгезелльшафт Мбх Унд Ко.Кг. | Способ оптимизации химического процесса, который предполагает безопасность химического технологического оборудования |
| RU2547146C2 (ru) * | 2009-11-10 | 2015-04-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения этиленоксида |
| RU2647596C2 (ru) * | 2013-02-12 | 2018-03-16 | Ифп Энержи Нувелль | Термически и механически интегрированный способ получения окиси этилена из потока этанола |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6372925B1 (en) * | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| BRPI0312010B1 (pt) * | 2002-06-28 | 2017-11-28 | Shell Internationale Research Maatschappij B.V | Method for detaining an epoxidation process and a process for the epoxidation of an olefine |
| AU2003243757A1 (en) * | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN100376561C (zh) * | 2002-06-28 | 2008-03-26 | 国际壳牌研究有限公司 | 环氧化方法的开车方法、烯烃环氧化的催化剂和方法 |
| AU2003284195A1 (en) * | 2002-10-28 | 2004-05-25 | Shell Internationale Research Maatschappij B.V. | Olefin oxide catalysts |
| MY146505A (en) * | 2003-02-28 | 2012-08-15 | Shell Int Research | A method of manufacturing ethylene oxide |
| MY153179A (en) * | 2003-02-28 | 2015-01-29 | Shell Int Research | A method of manufacturing ethylene oxide |
| MY136774A (en) * | 2003-02-28 | 2008-11-28 | Shell Int Research | Method of improving the operation of a manufacturing process |
| TWI346574B (en) | 2003-03-31 | 2011-08-11 | Shell Int Research | A catalyst composition, a process for preparing the catalyst composition and a use of the catalyst composition |
| CA2520776C (en) * | 2003-04-01 | 2012-05-08 | Shell Internationale Research Maatschappij B.V. | An olefin epoxidation process and a catalyst for use in the process |
| US7348444B2 (en) * | 2003-04-07 | 2008-03-25 | Shell Oil Company | Process for the production of an olefin oxide |
| US6858560B2 (en) | 2003-04-23 | 2005-02-22 | Scientific Design Co., Inc. | Ethylene oxide catalyst |
| EP1624964B1 (en) | 2003-05-07 | 2019-07-31 | Shell International Research Maatschappij B.V. | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
| US20040225138A1 (en) * | 2003-05-07 | 2004-11-11 | Mcallister Paul Michael | Reactor system and process for the manufacture of ethylene oxide |
| US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| TW200602123A (en) * | 2004-04-01 | 2006-01-16 | Shell Int Research | Process for preparing a catalyst, the catalyst, and a use of the catalyst |
| US8536083B2 (en) | 2004-09-01 | 2013-09-17 | Shell Oil Company | Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier |
| EP2617488A3 (en) * | 2004-09-01 | 2014-01-22 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst for use in an olefin epoxidation process and epoxidation process using the catalyst |
| CA2580983A1 (en) * | 2004-09-24 | 2006-04-06 | Shell Internationale Research Maatschappij B.V. | A process for selecting shaped particles, a process for installing a system, a process for reacting a gaseous feedstock in such a system, a computer program product, and a computer system |
| BRPI0608552A2 (pt) * | 2005-02-25 | 2010-01-12 | Sumitomo Chemical Co | processo para produção de óxido de olefina |
| WO2006102189A1 (en) * | 2005-03-22 | 2006-09-28 | Shell Internationale Research Maatschappij B.V. | A reactor system and process for the manufacture of ethylene oxide |
| KR101369619B1 (ko) | 2005-06-07 | 2014-03-05 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법 |
| CN101384570A (zh) * | 2005-12-22 | 2009-03-11 | 国际壳牌研究有限公司 | 制备环氧烷或可由环氧烷衍生的化学品的方法 |
| US7459589B2 (en) | 2005-12-22 | 2008-12-02 | Shell Oil Company | Process for the preparation of an alkylene glycol |
| US7750170B2 (en) | 2005-12-22 | 2010-07-06 | Shell Oil Company | Process for mixing an oxidant having explosive potential with a hydrocarbon |
| KR20080102155A (ko) * | 2006-02-03 | 2008-11-24 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 촉매의 처리 방법, 처리된 촉매, 및 이 촉매의 용도 |
| JP5250431B2 (ja) * | 2006-02-10 | 2013-07-31 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の調製方法、触媒、およびオレフィンオキシド、1,2−ジオール、1,2−ジオールエーテルまたはアルカノールアミンの製造方法 |
| US7553795B2 (en) * | 2006-03-21 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Activation of high selectivity ethylene oxide catalyst |
| EP2013194A2 (de) * | 2006-04-21 | 2009-01-14 | Basf Se | Verfahren zur herstellung von ethylenoxid in einem mikrokanalreaktor |
| US8097557B2 (en) * | 2006-08-08 | 2012-01-17 | Sd Lizenverwertungsgesellschaft Mbh & Co. Kg | Two-stage calcination for catalyst production |
| CA2661080C (en) * | 2006-09-01 | 2016-08-16 | Dow Global Technologies Inc. | Improved control and optimization of process for making ethylene oxide |
| US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| CA2686825C (en) * | 2007-05-09 | 2016-09-13 | Shell Internationale Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| BRPI0811282B1 (pt) | 2007-05-09 | 2016-12-27 | Shell Int Research | processos para a epoxidação de uma olefina e para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina |
| KR20100017689A (ko) | 2007-05-09 | 2010-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 촉매, 이 촉매의 제조방법, 및 산화올레핀, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산 방법 |
| WO2008144402A2 (en) | 2007-05-18 | 2008-11-27 | Shell Oil Company | A reactor system, an absorbent and a process for reacting a feed |
| JP5507446B2 (ja) * | 2007-05-18 | 2014-05-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 反応器システム並びにオレフィンオキシド、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートおよびアルカノールアミンの調製方法 |
| US9144765B2 (en) | 2007-05-18 | 2015-09-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| US7803957B2 (en) | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
| DE102008014910A1 (de) | 2008-03-19 | 2009-09-24 | Basf Se | Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung |
| US7763096B2 (en) | 2008-05-06 | 2010-07-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Recovery of rhenium |
| BRPI0912391B1 (pt) * | 2008-05-07 | 2018-04-17 | Shell Internationale Research Maatschappij B.V. | Processo para epoxidação de uma olefina |
| EP2297124B1 (en) | 2008-05-07 | 2013-08-21 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| WO2009140318A1 (en) * | 2008-05-15 | 2009-11-19 | Shell Oil Company | Process for the preparation of an alkylene carbonate and an alkylene glycol |
| TWI455930B (zh) | 2008-05-15 | 2014-10-11 | Shell Int Research | 製備碳酸伸烷酯及/或烷二醇的方法 |
| DE102008025835A1 (de) * | 2008-05-29 | 2009-12-03 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Ethylenoxid |
| WO2009150208A1 (en) * | 2008-06-13 | 2009-12-17 | Shell Internationale Research Maatschappij B.V. | Method for measuring the selectivity of a process for the production of ethylene oxide |
| US8933254B2 (en) * | 2008-07-14 | 2015-01-13 | Basf Se | Process for making ethylene oxide |
| CN102099345A (zh) * | 2008-07-14 | 2011-06-15 | 万罗赛斯公司 | 使用微通道工艺技术制造环氧乙烷的方法 |
| US8349765B2 (en) | 2008-07-18 | 2013-01-08 | Scientific Design Company, Inc. | Mullite-containing carrier for ethylene oxide catalysts |
| US8524927B2 (en) | 2009-07-13 | 2013-09-03 | Velocys, Inc. | Process for making ethylene oxide using microchannel process technology |
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| US8742146B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| CN103261180B (zh) * | 2010-12-10 | 2016-05-25 | 陶氏技术投资有限责任公司 | 在使用高效催化剂制造环氧烷工艺中降低环氧烷生产参数值的方法 |
| KR101780970B1 (ko) * | 2010-12-15 | 2017-10-23 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 고효율 촉매를 사용하는 알킬렌 옥사이드 생산 공정의 개시 방법 |
| CN102558099B (zh) * | 2010-12-29 | 2014-11-12 | 中国石油化工股份有限公司 | 由乙烯生产环氧乙烷的方法 |
| KR102027597B1 (ko) | 2011-04-29 | 2019-10-01 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | Eo 촉매의 선택성 개선 방법 |
| KR102109990B1 (ko) | 2011-12-09 | 2020-05-12 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 고효율 촉매를 사용하여 알킬렌 옥사이드를 제조하는 공정에서 알킬렌 옥사이드 생산 변수 값을 유지하는 방법 |
| CN104888855B (zh) * | 2015-04-03 | 2017-03-01 | 江南大学 | 一种用于烯烃环氧化反应的乙酰丙酮氧钼固体催化剂及其制备方法 |
| KR102678884B1 (ko) | 2016-08-09 | 2024-06-27 | 사이언티픽 디자인 컴파니 인코포레이티드 | 글리콜 에테르 제조 방법 |
| TWI774707B (zh) | 2016-12-02 | 2022-08-21 | 荷蘭商蜆殼國際研究所 | 用於調節乙烯環氧化催化劑之方法及用於製造環氧乙烷之相關方法 |
| WO2019055773A1 (en) | 2017-09-15 | 2019-03-21 | MultiPhase Solutions, Inc. | GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES |
| WO2019110713A1 (en) * | 2017-12-08 | 2019-06-13 | Shell Internationale Research Maatschappij B.V. | Process for preparing ethylene carbonate and ethylene glycol |
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| US4400559A (en) * | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| RU2045335C1 (ru) * | 1989-04-18 | 1995-10-10 | Юнион Карбайд Кемикалз энд Пластикс Компани Инк. | Катализатор для получения оксида этилена |
| RU2126296C1 (ru) * | 1993-09-08 | 1999-02-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализатор для парофазного эпоксидирования олефинов и способ получения носителя для него |
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| GB1191983A (en) | 1968-04-11 | 1970-05-13 | Sir Soc Italiana Resine Spa | Preparation of Ethylene Oxide |
| US3960775A (en) | 1969-08-26 | 1976-06-01 | Snam Progetti S.P.A. | Catalyst for the production of ethylene oxide |
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| IT972792B (it) * | 1972-12-22 | 1974-05-31 | Sir Soc Italiana Resine Spa | Procedimento per la preparazione di glicoli eteri |
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-
2000
- 2000-12-12 US US09/735,360 patent/US6372925B1/en not_active Expired - Lifetime
-
2001
- 2001-06-05 MX MXPA02012036A patent/MXPA02012036A/es active IP Right Grant
- 2001-06-05 CA CA2411070A patent/CA2411070C/en not_active Expired - Lifetime
- 2001-06-05 BR BRPI0111475-1A patent/BR0111475B1/pt not_active IP Right Cessation
- 2001-06-05 AU AU2001266704A patent/AU2001266704A1/en not_active Abandoned
- 2001-06-05 EP EP01944278A patent/EP1292587B1/en not_active Revoked
- 2001-06-05 JP JP2002510467A patent/JP5097325B2/ja not_active Expired - Lifetime
- 2001-06-05 CN CN01811606XA patent/CN1217941C/zh not_active Expired - Lifetime
- 2001-06-05 DE DE60123788T patent/DE60123788T2/de not_active Expired - Lifetime
- 2001-06-05 US US10/297,522 patent/US6717001B2/en not_active Expired - Lifetime
- 2001-06-05 ES ES01944278T patent/ES2269421T3/es not_active Expired - Lifetime
- 2001-06-05 KR KR1020027016739A patent/KR100827473B1/ko not_active Expired - Lifetime
- 2001-06-05 RU RU2002135677/04A patent/RU2263670C2/ru not_active IP Right Cessation
- 2001-06-05 WO PCT/US2001/018097 patent/WO2001096324A2/en not_active Ceased
- 2001-06-05 AT AT01944278T patent/ATE342259T1/de not_active IP Right Cessation
- 2001-06-06 GC GCP20011416 patent/GC0000430A/xx active
- 2001-06-07 MY MYPI20012666A patent/MY128386A/en unknown
- 2001-06-08 TW TW090113981A patent/TWI230707B/zh not_active IP Right Cessation
-
2002
- 2002-11-27 IN IN1165DE2002 patent/IN2002DE01165A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4400559A (en) * | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| RU2045335C1 (ru) * | 1989-04-18 | 1995-10-10 | Юнион Карбайд Кемикалз энд Пластикс Компани Инк. | Катализатор для получения оксида этилена |
| RU2126296C1 (ru) * | 1993-09-08 | 1999-02-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Катализатор для парофазного эпоксидирования олефинов и способ получения носителя для него |
| DE19843697A1 (de) * | 1998-09-23 | 2000-03-30 | Basf Ag | Verfahren zur Herstellung von hochreinem Monoethylenglykol |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2447069C2 (ru) * | 2007-09-10 | 2012-04-10 | Сд Лиценцфервертунгсгезелльшафт Мбх Унд Ко.Кг. | Способ оптимизации химического процесса, который предполагает безопасность химического технологического оборудования |
| RU2547146C2 (ru) * | 2009-11-10 | 2015-04-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения этиленоксида |
| RU2647596C2 (ru) * | 2013-02-12 | 2018-03-16 | Ифп Энержи Нувелль | Термически и механически интегрированный способ получения окиси этилена из потока этанола |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2004503548A (ja) | 2004-02-05 |
| ATE342259T1 (de) | 2006-11-15 |
| JP5097325B2 (ja) | 2012-12-12 |
| MY128386A (en) | 2007-01-31 |
| CA2411070A1 (en) | 2001-12-20 |
| WO2001096324A2 (en) | 2001-12-20 |
| DE60123788T2 (de) | 2007-09-06 |
| BR0111475A (pt) | 2003-03-25 |
| CA2411070C (en) | 2010-08-10 |
| BR0111475B1 (pt) | 2012-04-17 |
| IN2002DE01165A (forum.php) | 2008-09-26 |
| WO2001096324A3 (en) | 2002-03-28 |
| CN1217941C (zh) | 2005-09-07 |
| KR20030034090A (ko) | 2003-05-01 |
| CN1437590A (zh) | 2003-08-20 |
| ES2269421T3 (es) | 2007-04-01 |
| US6717001B2 (en) | 2004-04-06 |
| DE60123788D1 (de) | 2006-11-23 |
| US6372925B1 (en) | 2002-04-16 |
| KR100827473B1 (ko) | 2008-05-06 |
| EP1292587A2 (en) | 2003-03-19 |
| US20030139633A1 (en) | 2003-07-24 |
| TWI230707B (en) | 2005-04-11 |
| EP1292587B1 (en) | 2006-10-11 |
| MX231687B (forum.php) | 2005-10-28 |
| AU2001266704A1 (en) | 2001-12-24 |
| GC0000430A (en) | 2007-09-30 |
| MXPA02012036A (es) | 2003-06-06 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20090606 |