RU2235115C2 - Способ каталитической депарафинизации и каталитическая композиция для его осуществления - Google Patents
Способ каталитической депарафинизации и каталитическая композиция для его осуществления Download PDFInfo
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- RU2235115C2 RU2235115C2 RU2001116572/04A RU2001116572A RU2235115C2 RU 2235115 C2 RU2235115 C2 RU 2235115C2 RU 2001116572/04 A RU2001116572/04 A RU 2001116572/04A RU 2001116572 A RU2001116572 A RU 2001116572A RU 2235115 C2 RU2235115 C2 RU 2235115C2
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- Prior art keywords
- crystallites
- zeolite
- blocks
- binder
- type
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 67
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 230000008569 process Effects 0.000 title claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 18
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 16
- 239000012188 paraffin wax Substances 0.000 claims abstract description 15
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 88
- 239000010457 zeolite Substances 0.000 claims description 77
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 75
- 229910021536 Zeolite Inorganic materials 0.000 claims description 62
- 239000011230 binding agent Substances 0.000 claims description 38
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 36
- 239000000377 silicon dioxide Substances 0.000 claims description 32
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 26
- 238000001125 extrusion Methods 0.000 claims description 20
- 229910052697 platinum Inorganic materials 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 230000035699 permeability Effects 0.000 claims description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910004283 SiO 4 Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 229940104869 fluorosilicate Drugs 0.000 claims description 6
- 229910052914 metal silicate Inorganic materials 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000001354 calcination Methods 0.000 claims description 5
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229910001657 ferrierite group Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 229910052909 inorganic silicate Inorganic materials 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 58
- 239000010687 lubricating oil Substances 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 16
- -1 for example Chemical class 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 239000003921 oil Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 101800000628 PDH precursor-related peptide Proteins 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- PQGCEDQWHSBAJP-TXICZTDVSA-N 5-O-phosphono-alpha-D-ribofuranosyl diphosphate Chemical compound O[C@H]1[C@@H](O)[C@@H](O[P@](O)(=O)OP(O)(O)=O)O[C@@H]1COP(O)(O)=O PQGCEDQWHSBAJP-TXICZTDVSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- ZMANZCXQSJIPKH-UHFFFAOYSA-N N,N-Diethylethanamine Substances CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229920003091 Methocel™ Polymers 0.000 description 3
- 239000002199 base oil Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229940075614 colloidal silicon dioxide Drugs 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 3
- 239000008240 homogeneous mixture Substances 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 229910052810 boron oxide Inorganic materials 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 2
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 2
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 description 2
- 239000000391 magnesium silicate Substances 0.000 description 2
- 235000019792 magnesium silicate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 201000011540 mitochondrial DNA depletion syndrome 4a Diseases 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- RPZANUYHRMRTTE-UHFFFAOYSA-N 2,3,4-trimethoxy-6-(methoxymethyl)-5-[3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxyoxane;1-[[3,4,5-tris(2-hydroxybutoxy)-6-[4,5,6-tris(2-hydroxybutoxy)-2-(2-hydroxybutoxymethyl)oxan-3-yl]oxyoxan-2-yl]methoxy]butan-2-ol Chemical compound COC1C(OC)C(OC)C(COC)OC1OC1C(OC)C(OC)C(OC)OC1COC.CCC(O)COC1C(OCC(O)CC)C(OCC(O)CC)C(COCC(O)CC)OC1OC1C(OCC(O)CC)C(OCC(O)CC)C(OCC(O)CC)OC1COCC(O)CC RPZANUYHRMRTTE-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920003108 Methocel™ A4M Polymers 0.000 description 1
- 208000022639 SchC6pf-Schulz-Passarge syndrome Diseases 0.000 description 1
- 208000001364 Schopf-Schulz-Passarge syndrome Diseases 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- QZVSYHUREAVHQG-UHFFFAOYSA-N diberyllium;silicate Chemical compound [Be+2].[Be+2].[O-][Si]([O-])([O-])[O-] QZVSYHUREAVHQG-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 102220076896 rs767072861 Human genes 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98402839 | 1998-11-16 | ||
| EP98402839.9 | 1998-11-16 | ||
| EP99402401.6 | 1999-09-27 | ||
| EP99402401 | 1999-09-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2001116572A RU2001116572A (ru) | 2003-06-27 |
| RU2235115C2 true RU2235115C2 (ru) | 2004-08-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2001116572/04A RU2235115C2 (ru) | 1998-11-16 | 1999-11-12 | Способ каталитической депарафинизации и каталитическая композиция для его осуществления |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6576120B1 (enExample) |
| EP (1) | EP1137741B1 (enExample) |
| JP (1) | JP2002530470A (enExample) |
| CN (2) | CN1264954C (enExample) |
| AT (1) | ATE305499T1 (enExample) |
| AU (1) | AU754266B2 (enExample) |
| CA (1) | CA2350581C (enExample) |
| DE (1) | DE69927519T2 (enExample) |
| DK (1) | DK1137741T3 (enExample) |
| ES (1) | ES2251249T3 (enExample) |
| HU (1) | HUP0104314A3 (enExample) |
| PL (1) | PL191326B1 (enExample) |
| RU (1) | RU2235115C2 (enExample) |
| WO (1) | WO2000029511A1 (enExample) |
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| US6709570B1 (en) | 1999-09-27 | 2004-03-23 | Shell Oil Company | Method for preparing a catalyst |
| RU2263706C2 (ru) | 2000-07-17 | 2005-11-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения бесцветного смазочного базового масла |
| JP4496633B2 (ja) | 2000-09-29 | 2010-07-07 | 東ソー株式会社 | トリエチレンジアミン製造用成形体触媒とその製造法及びトリエチレンジアミンの製造方法 |
| CA2432034A1 (en) | 2000-12-19 | 2002-06-27 | Shell Internationale Research Maatschappij B.V. | Process to prepare a spindle oil, light machine oil and a medium machine oil |
| DK1370633T3 (da) | 2001-02-13 | 2005-11-21 | Shell Int Research | Smöremiddelsammensætning |
| AR032932A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Procedimiento para preparar un aceite de base lubricante y un gas oil |
| MY139353A (en) | 2001-03-05 | 2009-09-30 | Shell Int Research | Process to prepare a lubricating base oil and a gas oil |
| AR032941A1 (es) | 2001-03-05 | 2003-12-03 | Shell Int Research | Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones |
| CN1503835A (zh) | 2001-04-19 | 2004-06-09 | ���ʿ����о�����˾ | 一种制备高饱和物含量基油的方法 |
| TWI277649B (en) | 2001-06-07 | 2007-04-01 | Shell Int Research | Process to prepare a base oil from slack-wax |
| BR0213160A (pt) | 2001-10-16 | 2004-09-14 | Shell Int Research | Processo para beneficiamento adicional de um óleo lubrificante usado pré-processado |
| EP1487942B2 (en) | 2002-02-25 | 2011-08-24 | Shell Internationale Research Maatschappij B.V. | Process to prepare a catalytically dewaxed gas oil or gas oil blending component |
| EP1666569B1 (en) | 2002-07-12 | 2018-12-26 | Shell International Research Maatschappij B.V. | Lubricant formulation and its use |
| BR0312667B1 (pt) | 2002-07-18 | 2012-11-27 | processo para preparar uma cera microcristalina e um combustìvel de destilado médio. | |
| KR20050025627A (ko) | 2002-07-19 | 2005-03-14 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | Ｅｐｄｍ 및 파라핀계 오일을 함유하는 조성물 |
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| ITMI20040798A1 (it) * | 2004-04-23 | 2004-07-23 | Eni Spa | Processo e catalizzatori per l'apertura di anelli naftenici |
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| US20060068986A1 (en) * | 2004-09-27 | 2006-03-30 | Dimascio Felice | Catalyst elements and methods of making and using |
| BRPI0517784A (pt) | 2004-11-18 | 2008-10-21 | Shell Int Research | processo para otimizar o rendimento de gasóleos |
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| US20060129013A1 (en) * | 2004-12-09 | 2006-06-15 | Abazajian Armen N | Specific functionalization and scission of linear hydrocarbon chains |
| EP1853682A1 (en) * | 2004-12-23 | 2007-11-14 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil |
| WO2007003623A1 (en) | 2005-07-01 | 2007-01-11 | Shell Internationale Research Maatschappij B.V. | Process to prepare a blended brightstock |
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| US20070278134A1 (en) * | 2006-06-01 | 2007-12-06 | Chevron U.S.A. Inc. | Process for producing light neutral base oil having a high viscosity index |
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| EP1997868A1 (en) * | 2007-05-30 | 2008-12-03 | Shell Internationale Researchmaatschappij B.V. | Process for producing a naphthenic base oil |
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| US8343335B2 (en) * | 2008-02-21 | 2013-01-01 | Exxonmobil Research And Engineering Company | Production of shaped silica bodies |
| CN102105225A (zh) | 2008-07-04 | 2011-06-22 | 国际壳牌研究有限公司 | 催化剂和异构化方法 |
| JP5564769B2 (ja) * | 2008-08-12 | 2014-08-06 | 株式会社明電舎 | 低級炭化水素芳香族化触媒及び芳香族化合物の製造方法 |
| JP5587003B2 (ja) * | 2010-03-25 | 2014-09-10 | 日本碍子株式会社 | ゼオライト構造体の製造方法 |
| RU2581043C2 (ru) * | 2010-10-25 | 2016-04-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Композиция для катализатора конверсии углеводородов |
| EP2455161A1 (en) | 2010-11-18 | 2012-05-23 | Shell Internationale Research Maatschappij B.V. | Isomerisation catalyst preparation process |
| EP2455160A1 (en) * | 2010-11-18 | 2012-05-23 | Shell Internationale Research Maatschappij B.V. | Isomerisation catalyst preparation process |
| WO2013090534A1 (en) * | 2011-12-16 | 2013-06-20 | Shell Oil Company | A titania-bound zsm-12 zeolite composition and method of making and using such composition |
| WO2013127592A1 (en) * | 2012-02-29 | 2013-09-06 | Shell Internationale Research Maatschappij B.V. | A titania-bound zeolite eu-2 catalyst composition and method of making and using such composition |
| BR112014031227A8 (pt) | 2012-06-21 | 2020-09-24 | Shell Int Research | composição lubrificante, uso de uma composição lubrificante, e, uso de um material de mistura aromático alquilado |
| US20150144528A1 (en) | 2012-06-28 | 2015-05-28 | Shell Oil Company | Process to prepare a gas oil fraction and a residual base oil |
| RU2674703C2 (ru) * | 2012-12-17 | 2018-12-12 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения гидрированного воска |
| EP2746367A1 (en) | 2012-12-18 | 2014-06-25 | Shell Internationale Research Maatschappij B.V. | Process to prepare base oil and gas oil |
| EP3063254A1 (en) | 2013-10-31 | 2016-09-07 | Shell Internationale Research Maatschappij B.V. | Process for the conversion of a paraffinic feedstock |
| WO2016044646A1 (en) | 2014-09-17 | 2016-03-24 | Ergon, Inc. | Process for producing naphthenic bright stocks |
| EP3194533A1 (en) | 2014-09-17 | 2017-07-26 | Ergon, Inc. | Process for producing naphthenic base oils |
| WO2017109179A1 (en) | 2015-12-23 | 2017-06-29 | Shell Internationale Research Maatschappij B.V. | Process for preparing a base oil having a reduced cloud point |
| US11529618B2 (en) * | 2016-11-28 | 2022-12-20 | Basf Se | Catalyst composite comprising an alkaline earth metal containing CHA zeolite and use thereof in a process for the conversion of oxygenates to olefins |
| RU2768876C2 (ru) | 2016-12-16 | 2022-03-25 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Каталитическая система для депарафинизации |
| EP3559158B1 (en) | 2016-12-23 | 2022-08-03 | Shell Internationale Research Maatschappij B.V. | Method for producing fischer-tropsch feedstock derived haze-free base oil fractions |
| US11078430B2 (en) | 2016-12-23 | 2021-08-03 | Shell Oil Company | Haze-free base oils with high paraffinic content |
| US11351528B2 (en) | 2018-04-17 | 2022-06-07 | Shell Usa, Inc. | Catalyst system for dewaxing |
| WO2023247624A1 (en) | 2022-06-22 | 2023-12-28 | Shell Internationale Research Maatschappij B.V. | A process to prepare kerosene |
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- 1999-11-12 US US09/856,038 patent/US6576120B1/en not_active Expired - Lifetime
- 1999-11-12 WO PCT/EP1999/009024 patent/WO2000029511A1/en not_active Ceased
- 1999-11-12 DK DK99962151T patent/DK1137741T3/da active
- 1999-11-12 DE DE69927519T patent/DE69927519T2/de not_active Expired - Lifetime
- 1999-11-12 CN CN99814636.6A patent/CN1264954C/zh not_active Expired - Lifetime
- 1999-11-12 JP JP2000582498A patent/JP2002530470A/ja not_active Ceased
- 1999-11-12 HU HU0104314A patent/HUP0104314A3/hu unknown
- 1999-11-12 CN CN200410059025.5A patent/CN1597860A/zh active Pending
- 1999-11-12 ES ES99962151T patent/ES2251249T3/es not_active Expired - Lifetime
- 1999-11-12 AU AU18594/00A patent/AU754266B2/en not_active Ceased
- 1999-11-12 RU RU2001116572/04A patent/RU2235115C2/ru active
- 1999-11-12 AT AT99962151T patent/ATE305499T1/de not_active IP Right Cessation
- 1999-11-12 EP EP99962151A patent/EP1137741B1/en not_active Revoked
- 1999-11-12 PL PL348352A patent/PL191326B1/pl unknown
- 1999-11-12 CA CA002350581A patent/CA2350581C/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| ES2251249T3 (es) | 2006-04-16 |
| EP1137741A1 (en) | 2001-10-04 |
| PL348352A1 (en) | 2002-05-20 |
| ATE305499T1 (de) | 2005-10-15 |
| CN1597860A (zh) | 2005-03-23 |
| DE69927519T2 (de) | 2006-06-14 |
| US6576120B1 (en) | 2003-06-10 |
| DE69927519D1 (de) | 2006-02-09 |
| CA2350581C (en) | 2009-12-29 |
| CN1264954C (zh) | 2006-07-19 |
| HUP0104314A2 (hu) | 2002-03-28 |
| AU754266B2 (en) | 2002-11-07 |
| WO2000029511A1 (en) | 2000-05-25 |
| AU1859400A (en) | 2000-06-05 |
| DK1137741T3 (da) | 2006-02-13 |
| CN1330699A (zh) | 2002-01-09 |
| JP2002530470A (ja) | 2002-09-17 |
| EP1137741B1 (en) | 2005-09-28 |
| HUP0104314A3 (en) | 2003-05-28 |
| PL191326B1 (pl) | 2006-04-28 |
| CA2350581A1 (en) | 2000-05-25 |
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