RU2177059C2 - Эмульсия блокированного изоцианата, водо- и маслоотталкивающий состав, текстильный материал - Google Patents
Эмульсия блокированного изоцианата, водо- и маслоотталкивающий состав, текстильный материал Download PDFInfo
- Publication number
- RU2177059C2 RU2177059C2 RU98119538/04A RU98119538A RU2177059C2 RU 2177059 C2 RU2177059 C2 RU 2177059C2 RU 98119538/04 A RU98119538/04 A RU 98119538/04A RU 98119538 A RU98119538 A RU 98119538A RU 2177059 C2 RU2177059 C2 RU 2177059C2
- Authority
- RU
- Russia
- Prior art keywords
- water
- emulsion
- blocked isocyanate
- oil
- oil repellent
- Prior art date
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- 239000000839 emulsion Substances 0.000 title claims abstract description 57
- 239000012948 isocyanate Substances 0.000 title claims abstract description 47
- 150000002513 isocyanates Chemical class 0.000 title claims abstract description 47
- 239000005871 repellent Substances 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000463 material Substances 0.000 title claims abstract description 7
- 239000004753 textile Substances 0.000 title claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 230000002940 repellent Effects 0.000 claims description 41
- 239000002245 particle Substances 0.000 claims description 16
- 239000002736 nonionic surfactant Substances 0.000 claims description 12
- 238000002441 X-ray diffraction Methods 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000002244 precipitate Substances 0.000 abstract description 2
- 239000002657 fibrous material Substances 0.000 abstract 1
- -1 MDI containing 2-4'- Chemical compound 0.000 description 41
- 239000003921 oil Substances 0.000 description 35
- 239000003093 cationic surfactant Substances 0.000 description 13
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- 125000004432 carbon atom Chemical group C* 0.000 description 9
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- 239000003925 fat Substances 0.000 description 8
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- ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
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- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
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- 238000005406 washing Methods 0.000 description 7
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 6
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
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- 238000005470 impregnation Methods 0.000 description 2
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- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 description 1
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Images
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/196—Percarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
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- C08G18/8077—Oximes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/395—Isocyanates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/438—Sulfonamides ; Sulfamic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/572—Reaction products of isocyanates with polyesters or polyesteramides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
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Landscapes
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- Chemical Kinetics & Catalysis (AREA)
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- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
- Image Analysis (AREA)
- Lubricants (AREA)
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| JP8/76265 | 1996-03-29 | ||
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| RU98119538A RU98119538A (ru) | 2000-07-20 |
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| KR (1) | KR20000004967A (enExample) |
| CN (1) | CN1101493C (enExample) |
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| RU (1) | RU2177059C2 (enExample) |
| TW (1) | TW336263B (enExample) |
| WO (1) | WO1997037076A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2275402C2 (ru) * | 2000-09-18 | 2006-04-27 | Родиа Шими | Способ придания деревянной основе повышенной стойкости к воздействию химических продуктов |
| RU2307207C1 (ru) * | 2006-05-26 | 2007-09-27 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Способ обработки текстильных материалов |
| RU2349614C2 (ru) * | 2004-06-04 | 2009-03-20 | Униматэк Ко., Лтд. | Способ получения водо- и маслоотталкивающего агента |
| RU2496799C2 (ru) * | 2009-03-27 | 2013-10-27 | Карл Фройденберг Кг | Способ получения реакционно-способной полиуретановой эмульсии |
| RU2629564C1 (ru) * | 2016-09-23 | 2017-08-30 | Общество с ограниченной ответственностью "Многофункциональные покрытия" | Способ получения комплексной добавки на основе фторполимеров для придания гидрофобных, антиобледенительных свойств защитному композиционному покрытию |
| RU2697553C2 (ru) * | 2014-09-22 | 2019-08-15 | Ноф Корпорейшн | Композиция, предотвращающая запотевание стекла, и изделие c ее использованием |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4741075B2 (ja) * | 1998-04-09 | 2011-08-03 | クラリアント ファイナンス (ビーブイアイ) リミティド | ブロック化オリゴマーイソシアネート、その製造および使用 |
| JP2000136377A (ja) | 1998-08-24 | 2000-05-16 | Asahi Glass Co Ltd | 水分散型撥水撥油剤組成物 |
| US6586522B1 (en) | 2000-06-12 | 2003-07-01 | 3M Innovative Properties Company | Water- and oil-repellent composition |
| KR100686196B1 (ko) * | 2005-03-14 | 2007-02-22 | 박명수 | 일면 수유분 반발 특성 섬유포의 제조방법 및 그에 의해제조된 섬유포 |
| NZ563633A (en) | 2005-06-29 | 2011-01-28 | Hexion Speciality Chemicals Inc | Wax formulations for lignocellulosic products, methods of their manufacture and products formed therefrom |
| KR100795970B1 (ko) * | 2007-11-08 | 2008-01-21 | 강인숙 | 염색공정에 사용되는 쇼핑유연제 조성물 및 그 제조방법 |
| KR101821600B1 (ko) * | 2011-06-13 | 2018-01-24 | 디아이씨 가부시끼가이샤 | 폴리우레탄 조성물, 발수제, 피혁상 시트의 표피층 형성용 폴리우레탄 수지 조성물 및 피혁상 시트 |
| CN106008904A (zh) | 2011-10-25 | 2016-10-12 | 旭化成株式会社 | 封端多异氰酸酯的水分散体、纤维处理剂组合物以及布帛 |
| JP6280298B2 (ja) * | 2011-12-28 | 2018-02-14 | ダイキン工業株式会社 | 表面処理剤 |
| JP2014062348A (ja) * | 2012-09-24 | 2014-04-10 | Teijin Frontier Co Ltd | 撥水布帛 |
| CN107278221B (zh) * | 2014-09-26 | 2021-03-12 | 科慕埃弗西有限公司 | 基于非氟化氨基甲酸酯的涂料 |
| CN104986813A (zh) * | 2015-07-30 | 2015-10-21 | 李平兰 | 一种工业含油污水的处理方法 |
| CN109153908B (zh) * | 2016-05-17 | 2021-12-24 | 明成化学工业株式会社 | 拒水处理剂及其制造方法 |
| BR112022000269A2 (pt) * | 2019-07-09 | 2022-03-03 | Evonik Operations Gmbh | Uso conjunto de éteres de poliol e alcoxilatos de alquila ricos em óxido de etileno como aditivos, dispersão de polímero aquosa, revestimento de polímero poroso e seu processo de produção |
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| JPH064842B2 (ja) * | 1985-11-15 | 1994-01-19 | 日本メクトロン株式会社 | 撥水撥油剤 |
| DE4134284A1 (de) * | 1991-10-17 | 1993-04-22 | Bayer Ag | In wasser dispergierbare blockierte polyisocyanate, verfahren zu ihrer herstellung und ihre verwendung |
| JPH064842A (ja) * | 1992-06-23 | 1994-01-14 | Matsushita Electric Ind Co Ltd | 調整テープ |
| ATE213257T1 (de) * | 1993-03-31 | 2002-02-15 | Rhodia Chimie Sa | Verfahren zur herstellung von wässrigen emulsionen von ölen und/oder gummi und/oder vorzugsweise maskierten (poly)isocyanatharzen, und resultierende emulsionen |
| JPH08188969A (ja) * | 1994-12-28 | 1996-07-23 | Unitika Ltd | 獣毛系繊維布帛の加工方法 |
| JPH08296175A (ja) * | 1995-04-27 | 1996-11-12 | Toray Ind Inc | 合成繊維製品の処理方法およびその処理製品 |
-
1997
- 1997-03-26 IN IN756DE1997 patent/IN186438B/en unknown
- 1997-03-27 KR KR1019980707571A patent/KR20000004967A/ko not_active Withdrawn
- 1997-03-27 RU RU98119538/04A patent/RU2177059C2/ru not_active IP Right Cessation
- 1997-03-27 EP EP97914554A patent/EP0913517B1/en not_active Expired - Lifetime
- 1997-03-27 ID IDP971013A patent/ID16788A/id unknown
- 1997-03-27 WO PCT/JP1997/001059 patent/WO1997037076A1/ja not_active Ceased
- 1997-03-27 ES ES97914554T patent/ES2169372T3/es not_active Expired - Lifetime
- 1997-03-27 CA CA002250005A patent/CA2250005A1/en not_active Abandoned
- 1997-03-27 CN CN97194758A patent/CN1101493C/zh not_active Expired - Fee Related
- 1997-03-27 AT AT97914554T patent/ATE210213T1/de not_active IP Right Cessation
- 1997-03-27 DE DE69708877T patent/DE69708877T2/de not_active Expired - Fee Related
- 1997-03-27 BR BR9708372A patent/BR9708372A/pt not_active Application Discontinuation
- 1997-03-28 TW TW086103989A patent/TW336263B/zh active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2275402C2 (ru) * | 2000-09-18 | 2006-04-27 | Родиа Шими | Способ придания деревянной основе повышенной стойкости к воздействию химических продуктов |
| RU2349614C2 (ru) * | 2004-06-04 | 2009-03-20 | Униматэк Ко., Лтд. | Способ получения водо- и маслоотталкивающего агента |
| RU2307207C1 (ru) * | 2006-05-26 | 2007-09-27 | Государственное образовательное учреждение высшего профессионального образования Волгоградский государственный технический университет (ВолгГТУ) | Способ обработки текстильных материалов |
| RU2496799C2 (ru) * | 2009-03-27 | 2013-10-27 | Карл Фройденберг Кг | Способ получения реакционно-способной полиуретановой эмульсии |
| RU2697553C2 (ru) * | 2014-09-22 | 2019-08-15 | Ноф Корпорейшн | Композиция, предотвращающая запотевание стекла, и изделие c ее использованием |
| RU2629564C1 (ru) * | 2016-09-23 | 2017-08-30 | Общество с ограниченной ответственностью "Многофункциональные покрытия" | Способ получения комплексной добавки на основе фторполимеров для придания гидрофобных, антиобледенительных свойств защитному композиционному покрытию |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1219212A (zh) | 1999-06-09 |
| KR20000004967A (ko) | 2000-01-25 |
| EP0913517A1 (en) | 1999-05-06 |
| IN186438B (enExample) | 2001-09-01 |
| EP0913517B1 (en) | 2001-12-05 |
| TW336263B (en) | 1998-07-11 |
| ID16788A (id) | 1997-11-13 |
| DE69708877D1 (de) | 2002-01-17 |
| WO1997037076A1 (en) | 1997-10-09 |
| ES2169372T3 (es) | 2002-07-01 |
| CN1101493C (zh) | 2003-02-12 |
| BR9708372A (pt) | 1999-08-03 |
| CA2250005A1 (en) | 1997-10-09 |
| DE69708877T2 (de) | 2002-06-20 |
| ATE210213T1 (de) | 2001-12-15 |
| EP0913517A4 (en) | 2000-05-17 |
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