RU2019115090A - Полукристаллическая композиция суперконцентрата добавки на основе полиолефина - Google Patents

Полукристаллическая композиция суперконцентрата добавки на основе полиолефина Download PDF

Info

Publication number
RU2019115090A
RU2019115090A RU2019115090A RU2019115090A RU2019115090A RU 2019115090 A RU2019115090 A RU 2019115090A RU 2019115090 A RU2019115090 A RU 2019115090A RU 2019115090 A RU2019115090 A RU 2019115090A RU 2019115090 A RU2019115090 A RU 2019115090A
Authority
RU
Russia
Prior art keywords
composition
semi
polyolefin
masterbatch
crystalline
Prior art date
Application number
RU2019115090A
Other languages
English (en)
Other versions
RU2019115090A3 (ru
RU2768478C2 (ru
Inventor
Дачао ЛИ
Раджен М. ПАТЕЛ
Тимоти Дж. ПЁРСОН
Джеффри М. КОГЕН
Бхарат И. ЧАУДХАРИ
Original Assignee
Дау Глоубл Текнолоджиз Ллк
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дау Глоубл Текнолоджиз Ллк filed Critical Дау Глоубл Текнолоджиз Ллк
Publication of RU2019115090A publication Critical patent/RU2019115090A/ru
Publication of RU2019115090A3 publication Critical patent/RU2019115090A3/ru
Application granted granted Critical
Publication of RU2768478C2 publication Critical patent/RU2768478C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/223—Packed additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/24—Derivatives of hydrazine
    • C08K5/25—Carboxylic acid hydrazides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/372—Sulfides, e.g. R-(S)x-R'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/50—Phosphorus bound to carbon only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/02—Disposition of insulation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)
  • Insulated Conductors (AREA)

Claims (13)

1. Композиция суперконцентрата добавки, содержащая (А) полукристаллический полиолефиновый полимерный носитель и набор добавок, содержащий продукт реакции (В) кислотного катализатора конденсации и (С) вторичного диариламина формулы (I): (R1-Ar)2NH (I), где каждый Ar представляет собой бензол-1,4-диил, или оба Ar связаны друг с другом и вместе с NH формулы (I) представляют собой карбазол-3,6-диил; и каждый R1 независимо представляет собой (С1-С20)гидрокарбил; причем (А) составляет от 50 до 99 массовых процентов (мас. %), а набор добавок составляет от 1 до 50 мас. % от общей массы (100,00 мас. %) данной композиции суперконцентрата добавки; причем указанная композиция суперконцентрата добавки не содержит сополимера этилена с силаном.
2. Композиция суперконцентрата добавки по п. 1, отличающаяся тем, что (А) полукристаллический полиолефиновый полимерный носитель состоит по существу из: (i) полукристаллического полиэтилена средней плотности; (ii) полукристаллического полиэтилена высокой плотности; (iii) полукристаллического полипропилена; (iv) полукристаллического сополимера этилена с пропиленом; (v) полукристаллического сополимера этилена с альфа-олефином; (vi) комбинации любых двух или более из (i), (ii) и (v); (vii) (А) полукристаллический полиолефиновый полимерный носитель имеет степень кристалличности от 50 до <100 мас. %; или (viii) любое из ограничений от (i) до (vi) и (А) полукристаллический полиолефиновый полимерный носитель имеет степень кристалличности от 50 до <100 мас. %.
3. Композиция суперконцентрата добавки по п. 1 или 2, отличающаяся тем, что (A) полукристаллический полиолефиновый полимерный носитель имеет (i) плотность по меньшей мере 0,925 г/см3 и представляет собой полиэтилен, или плотность от 0,89 до 0,90 г/см3 и представляет собой полипропилен; (ii) степень кристалличности по меньшей мере 50 мас. % и представляет собой полиэтилен; (iii) индекс текучести расплава (ПТР) от 0,1 до 20 грамм в течение 10 минут (г/10 мин) при 190°С/2,16 кг нагрузке и представляет собой полиэтилен, или показатель текучести расплава (ПТР) от 0,5 до 50 г/10 мин при 230°С/2,16 кг нагрузке и представляет собой полипропилен; (iv) молекулярно-массовое распределение (ММР), которое является мономодальным; (v) ММР, которое является бимодальным; (vi) оба (i) и (ii); (vii) оба (i) и (iii); (viii) оба (ii) и (iii); (ix) (iv) и по меньшей мере один из (i) - (iii); или (x) (v) и по меньшей мере один из (i) - (iii).
4. Композиция суперконцентрата добавки по любому из пп. 1-3, отличающаяся тем, что: (i) продукт реакции (B) и (C) содержит соль, образованную кислотно-основной реакцией (B) и (C); (ii) набор добавок дополнительно содержит непрореагировавший (B), но не непрореагировавший (C); (iii) набор добавок дополнительно содержит непрореагировавший (C), но не непрореагировавший (B); или (iv) набор добавок дополнительно содержит непрореагировавший (B) и непрореагировавший (C).
5. Композиция суперконцентрата добавки по любому из пп. 1-4, отличающаяся тем, что (B) кислотный катализатор конденсации представляет собой (i) органосульфоновую кислоту, органофосфоновую кислоту, или галогеноводород; (ii) органосульфоновую кислоту; (iii) алкилзамещенную арилсульфоновую кислоту; (iv) алкилзамещенную арилсульфоновую кислоту с 1 или 2 (С5-С20)алкильными заместителями и 1 ароматической группой, которая представляет собой фенил или нафтил; (v) (C1-C5)алкилфосфоновую кислоту, в которой (C1-C5)алкил является незамещенным или замещен одной -NH2 группой; (vi) HF, HCl или HBr; или (vii) комбинацию любых двух или более из (i) - (vi).
6. Композиция суперконцентрата добавки по любому из пп. 1-5, дополнительно содержащая по меньшей мере одну добавку, выбранную из: (D) одного или двух вторых антиоксидантов, каждый из которых имеет структуру, отличную от формулы (I) и от структуры другого; (E) технологической добавки; (F) красителя; (G) деактиватора металлов; (Н) гидролизуемого силана без ненасыщенных углерод-углеродных связей; (I) ингибитора коррозии; и (J) комбинации любых двух или более добавок (D) - (I).
7. Композиция суперконцентрата добавки по п. 2, отличающаяся тем, что (А) полукристаллический полиолефиновый полимерный носитель содержит по существу ограничение (viii) и имеет степень кристалличности от 58 до 78 мас. %.
8. Влагоотверждаемая полиолефиновая композиция, содержащая композицию суперконцентрата добавки по любому из пп. 1-7 и полиолефиновый форполимер с гидролизуемыми силильными функциональными группами; причем в полиолефиновом форполимере с гидролизуемыми силильными функциональными группами: (i) каждая гидролизуемая силильная группа независимо представляет собой одновалентную группу формулы (II): (R2)m(R3)3-mSi- (II); где индекс m представляет собой целое число 1, 2 или 3; каждый R2 независимо представляет собой H, HO-, (C1-C6)алкокси, (C2-C6)карбокси, ((C1-C6)алкил)2N-, (C1-C6)алкил(H)C=NO-, или ((С1-С6)алкил)2C=NO-; и каждый R3 независимо представляет собой (C1-C6)алкил или фенил; (ii) основой полиолефина является полиэтилен, сополимер этилена с (С3-С40)альфа-олефином, или их комбинация; или (iii) оба (i) и (ii).
9. Способ изготовления влагоотверждаемой полиолефиновой композиции, включающий смешение полиолефинового форполимера с гидролизуемыми силильными функциональными группами и измельченной твердой формы композиции суперконцентрата добавки по любому из пп. 1-7 для получения смеси; и плавление или экструдирование данной смеси для изготовления влагоотверждаемой полиолефиновой композиции.
10. Отвержденная влагой полиолефиновая композиция, которая является продуктом отверждения влагой влагоотверждаемой полиолефиновой композиции по п. 8, или композиции, изготовленной способом по п. 9, для получения отвержденной влагой полиолефиновой композиции.
11. Изготовленное изделие, содержащее сформованную деталь из отвержденной влагой полиолефиновой композиции по п. 10.
12. Проводник с покрытием, содержащий проводящий сердечник и полимерный слой, по меньшей мере частично окружающий проводящий сердечник, причем по меньшей мере часть полимерного слоя содержит отвержденную влагой полиолефиновую композицию по п. 10.
13. Способ проведения электричества, способ, включающий подачу напряжения на проводящий сердечник проводника с покрытием по п. 12 для создания электрического тока через проводящий сердечник.
RU2019115090A 2016-11-02 2017-10-31 Полукристаллическая композиция суперконцентрата добавки на основе полиолефина RU2768478C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662416407P 2016-11-02 2016-11-02
US62/416,407 2016-11-02
PCT/US2017/059224 WO2018085239A1 (en) 2016-11-02 2017-10-31 Semi-crystalline polyolefin-based additive masterbatch composition

Publications (3)

Publication Number Publication Date
RU2019115090A true RU2019115090A (ru) 2020-11-16
RU2019115090A3 RU2019115090A3 (ru) 2021-03-02
RU2768478C2 RU2768478C2 (ru) 2022-03-24

Family

ID=60473605

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2019115090A RU2768478C2 (ru) 2016-11-02 2017-10-31 Полукристаллическая композиция суперконцентрата добавки на основе полиолефина

Country Status (10)

Country Link
US (1) US11186711B2 (ru)
EP (1) EP3535314A1 (ru)
JP (1) JP7073354B2 (ru)
KR (1) KR102569632B1 (ru)
CN (1) CN109790300B (ru)
BR (1) BR112019007054B1 (ru)
CA (1) CA3042237A1 (ru)
MX (1) MX2019004498A (ru)
RU (1) RU2768478C2 (ru)
WO (1) WO2018085239A1 (ru)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2019004997A (es) * 2016-11-02 2019-08-05 Dow Global Technologies Llc Composicion de mezcla madre aditiva a base de poliolefina semicristalina.

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU167628B (ru) * 1973-03-06 1975-11-28
US3984940A (en) 1973-05-08 1976-10-12 Murray Reich Degradable plastic
US4255303A (en) 1979-04-25 1981-03-10 Union Carbide Corporation Polyethylene composition containing talc filler for electrical applications
US4368280A (en) 1980-12-31 1983-01-11 Mitsubishi Petrochemical Company, Ltd. Partially cross-linkable compositions and process for preparing partially cross-linked thermoplastic elastomers
US5202191A (en) 1981-06-19 1993-04-13 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Coated article with metallic finish
JPH062843B2 (ja) 1988-08-19 1994-01-12 協和化学工業株式会社 難燃剤および難燃性樹脂組成物
IT1240647B (it) * 1990-05-14 1993-12-17 Himont Inc Concentrati non estrusi di addittivi, cariche o pigmenti
US5066752A (en) 1990-06-20 1991-11-19 Great Lakes Chemical Corporation Flame retardant brominated styrene-based polymers
CA2061465A1 (en) 1991-02-25 1992-08-26 Craig C. Meverden Filled hydrolyzable copolymer compositions resistant to premature crosslinking
US5367030A (en) 1993-02-08 1994-11-22 Union Carbide Chemicals & Plastics Technology Corporation Process for crosslinking thermoplastic silane polymers
SE502171C2 (sv) 1993-12-20 1995-09-04 Borealis Holding As Polyetenkompatibla sulfonsyror som silanförnätningskatalysatorer
US5430091A (en) 1994-05-11 1995-07-04 At Plastics Inc. Moisture crosslinkable flame retardant compositions for cable applications
US6384156B1 (en) 1994-08-02 2002-05-07 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization process
US5929129A (en) 1994-09-19 1999-07-27 Sentinel Products Corp. Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene
KR0138403B1 (ko) * 1995-02-03 1998-05-01 권문구 전선용 실란가교 폴리올레핀 조성물의 제조방법
JP3322818B2 (ja) * 1997-03-04 2002-09-09 住友ベークライト株式会社 シラン架橋ポリオレフィンの製造方法
JP2000086905A (ja) 1998-09-14 2000-03-28 Tatsuta Electric Wire & Cable Co Ltd 水架橋用シラン混和物及びそれを用いた水架橋成形体
JP3430938B2 (ja) 1998-10-06 2003-07-28 住友電装株式会社 柔軟性を有する難燃性樹脂組成物及びこれを用いた電線
WO2000037552A1 (en) 1998-12-22 2000-06-29 Great Lakes Chemical Corporation Additive concentrates for olefinic polymers
US6476132B1 (en) 1999-07-23 2002-11-05 Advanced Elastomer Systems, L.P. Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set
JP4215356B2 (ja) 1999-10-14 2009-01-28 日本ユニカー株式会社 水架橋ポリオレフィン系樹脂組成物、その製造方法、これに用いるシランブレンド、並びに該樹脂組成物の成形物
US6441097B1 (en) 2000-08-03 2002-08-27 King Industries, Inc. Alkylaryl and arylalkyl monosulfonic acid catalysts for crosslinking polyethylene
DE60122674T2 (de) 2001-05-02 2007-08-30 Borealis Technology Oy Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren
JP2004098635A (ja) 2002-09-13 2004-04-02 Mitsubishi Chemicals Corp シラン架橋ポリエチレン成形体の製造方法
MY136027A (en) 2003-04-02 2008-07-31 Basell Poliolefine Spa Polyolefin masterbatch and composition suitable for injection molding
US20070155866A1 (en) 2003-06-25 2007-07-05 Biscoglio Michael B Moisture crosslinkable polymeric composition containing special antioxidants
ITMI20031579A1 (it) * 2003-08-01 2005-02-02 Basell Poliolefine Spa Concentrati di additivi, adatti all'impiego nella
US6936655B2 (en) 2003-09-02 2005-08-30 Equistar Chemicals, Lp Crosslinkable flame retardant wire and cable compositions having improved abrasion resistance
US6998443B2 (en) * 2003-09-02 2006-02-14 Equistar Chemicals, Lp Flame retardant insulation compositions having improved abrasion resistance
JP2005105105A (ja) * 2003-09-30 2005-04-21 Sumitomo Chemical Co Ltd 樹脂組成物ペレット
US6936671B2 (en) 2003-10-08 2005-08-30 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
US20080097038A1 (en) 2004-08-05 2008-04-24 Biscoglio Michael B Moisture-Curable, Silane Crosslinking Compositions
CN101133465B (zh) 2005-03-03 2012-03-07 联合碳化化学及塑料技术有限责任公司 压力通风系统电缆部件和包括其的通信电缆
US20080176981A1 (en) * 2005-03-18 2008-07-24 Biscoglio Michael B Moisture Crosslinkable Polymeric Composition-Improved Heat Aging Performance
US7851558B2 (en) 2005-11-12 2010-12-14 Dow Global Technologies Inc. Brominated butadiene/vinyl aromatic copolymers, blends of such copolymers with a vinyl aromatic polymer and polymeric foams formed from such blends
US7514489B2 (en) 2005-11-28 2009-04-07 Martin Marietta Materials, Inc. Flame-retardant magnesium hydroxide compositions and associated methods of manufacture and use
EP1849816B1 (en) * 2006-04-26 2008-06-25 Borealis Technology Oy Crosslinkable polyolefin composition comprising high molecular weight silanol condensation catalyst
JP4270237B2 (ja) 2006-07-31 2009-05-27 日立電線株式会社 非ハロゲン難燃性熱可塑性エラストマー組成物及びその製造方法並びにこれを用いた電線・ケーブル
DE602007002200D1 (de) * 2007-12-21 2009-10-08 Borealis Tech Oy Polypropylenzusammensetzung mit einer vernetzbaren dispergierten Phase mit Nanofüllstoffe enthaltenden Silanolgruppen
US8962718B2 (en) 2010-04-26 2015-02-24 Momentive Performance Materials Inc. Chlorine-resistant crosslinkable polyolefin compositions and articles made therefrom
CN103210020B (zh) 2010-10-25 2015-01-14 应用矿物公司 用于聚乙烯的成核剂
WO2012094395A2 (en) 2011-01-04 2012-07-12 Primex Plastics Corporation Fire retardant and method of use
EP2736971A1 (en) * 2011-07-29 2014-06-04 Dow Global Technologies LLC Semi-crystalline polyolefin composition, method of producing the same, and articles made therefrom
US20150004343A1 (en) 2012-02-01 2015-01-01 Icl-Ip America Inc. Polyolefin flame retardant composition and synergists thereof
JP6078967B2 (ja) 2012-03-29 2017-02-15 大日本印刷株式会社 太陽電池モジュール用封止材シート
WO2014014648A2 (en) 2012-07-18 2014-01-23 Rohm And Haas Company Textiles with brominated polymer flame retardant
JP6108782B2 (ja) 2012-11-19 2017-04-05 アイ‐コンポロジー株式会社 添加剤マスターバッチ
CN103059374B (zh) 2012-12-07 2014-09-10 江苏德威新材料股份有限公司 一种汽车电线用耐高温硅烷交联阻燃绝缘材料及其制备方法
EP2889323A1 (en) 2013-12-30 2015-07-01 Abu Dhabi Polymers Company Limited (Borouge) Polymer composition comprising carbon black and a carrier polymer for the carbon black
WO2015149221A1 (en) 2014-03-31 2015-10-08 Dow Global Technologies Llc Crosslinkable polymeric compositions with n,n,n',n',n",n"-hexaallyl-1,3,5-triazine-2,4,6-triamine crosslinking coagent, methods for making the same, and articles made therefrom
JP6636469B2 (ja) * 2014-06-27 2020-01-29 ダウ グローバル テクノロジーズ エルエルシー 安定化された水分硬化性ポリマー組成物
EP3161063B1 (en) 2014-06-27 2024-03-06 Dow Global Technologies LLC Stabilized moisture-curable polymeric compositions
CN104262769A (zh) 2014-09-16 2015-01-07 安徽美腾特种电缆材料有限公司 耐高温型一步法硅烷交联聚乙烯绝缘料及其制备方法
JP2018507940A (ja) 2015-03-12 2018-03-22 トタル リサーチ アンド テクノロジー フエリユイ 改良された電導性を有する半結晶性ポリマーをベースにした複合材料を製造するためのマスターバッチと、その製造方法と、それから製造された複合材料
JP6287919B2 (ja) 2015-03-24 2018-03-07 株式会社オートネットワーク技術研究所 電線被覆材組成物、絶縁電線及びワイヤーハーネス

Also Published As

Publication number Publication date
US11186711B2 (en) 2021-11-30
CN109790300B (zh) 2022-09-13
BR112019007054A2 (pt) 2019-07-02
US20190248993A1 (en) 2019-08-15
WO2018085239A1 (en) 2018-05-11
KR20190077396A (ko) 2019-07-03
CA3042237A1 (en) 2018-05-11
EP3535314A1 (en) 2019-09-11
KR102569632B1 (ko) 2023-08-25
JP2020513422A (ja) 2020-05-14
CN109790300A (zh) 2019-05-21
BR112019007054B1 (pt) 2023-05-09
RU2019115090A3 (ru) 2021-03-02
JP7073354B2 (ja) 2022-05-23
MX2019004498A (es) 2019-08-05
RU2768478C2 (ru) 2022-03-24

Similar Documents

Publication Publication Date Title
TW201905061A (zh) 可輻射固化聚烯烴調配物
RU2019115076A (ru) Композиция концентрата добавок на основе полукристаллического полиолефина
JP2015520916A (ja) ポリブタジエン共架橋剤を用いて作製されたエチレンポリマー導体コーティング
KR20200119741A (ko) 저유전 방열필름용 조성물 및 저유전 방열필름
KR101696122B1 (ko) 전도성 외피
KR20180097648A (ko) 응력 백화 저항성이 개선된 중합체 조성물
JP6344201B2 (ja) 難燃性樹脂組成物及び難燃性絶縁電線・ケーブル
RU2019115090A (ru) Полукристаллическая композиция суперконцентрата добавки на основе полиолефина
WO2015029621A1 (ja) ハロゲンフリー難燃絶縁電線
KR20200077147A (ko) 전력 케이블의 절연층 조성물 및 이로부터 제조된 전력 케이블
JP6012508B2 (ja) 表面平滑性に優れた樹脂組成物
JP2023507089A (ja) ポリオレフィン組成物
JP2022538737A (ja) 架橋ポリマー組成物および被覆導体
EP3535312B1 (en) Semi-crystalline polyolefin-based additive masterbatch composition
CN114008127B (zh) 含有三有机氨基膦的基于乙烯的聚合物组合物
KR20190074188A (ko) 전력 케이블의 절연층용 폴리머 조성물 및 이를 포함하는 절연층, 전력 케이블
Mauri Alternative polyethylene crosslinking concepts for power cable insulation
KR102053591B1 (ko) 내한성 및 내유성을 갖는 쉬스 조성물
JP6182328B2 (ja) 表面平滑性に優れた樹脂組成物
JPS61183335A (ja) 難燃性樹脂組成物
RU2021124250A (ru) Отверждаемый влагой состав полиолефина
TWI681994B (zh) 聚烯烴組合物
JP2023038166A (ja) 耐トラッキング性に優れたポリオレフィン樹脂組成物およびそれにより製造された成形品
JP2634715B2 (ja) 難燃性ポリオレフィン系ゴム組成物
JPH08185712A (ja) 電線・ケーブル