RU2019105713A - Способ изготовления чувствительных к давлению клеевых композиций на водной основе - Google Patents

Способ изготовления чувствительных к давлению клеевых композиций на водной основе Download PDF

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RU2019105713A
RU2019105713A RU2019105713A RU2019105713A RU2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A RU 2019105713 A RU2019105713 A RU 2019105713A
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ester
polyol
conjugate
unsaturated monomer
emulsion polymer
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RU2019105713A
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RU2738816C2 (ru
RU2019105713A3 (ru
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Цзигуан ЧЖАН
Мяо Ян
Шаогуан ФЭН
Чжаохуэй ЦЮЙ
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Дау Глоубл Текнолоджиз Ллк
Ром Энд Хаас Компани
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/062Copolymers with monomers not covered by C09J133/06
    • C09J133/064Copolymers with monomers not covered by C09J133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J191/00Adhesives based on oils, fats or waxes; Adhesives based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • C09J7/381Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385Acrylic polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/414Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of a copolymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)

Claims (13)

1. Способ изготовления клеевой композиции на водной основе, включающий:
диспергирование по меньшей мере одного ненасыщенного мономера в водной среде для образования эмульгированной смеси;
введение по меньшей мере одного инициатора в эмульгированную смесь, тем самым полимеризуя по меньшей мере один ненасыщенный мономер и образуя эмульсионный полимер; и
введение по меньшей мере одного сложного эфира полиола сопряженной кислоты в эмульсионный полимер по завершении полимеризации по меньшей мере одного ненасыщенного мономера, тем самым образуя клеевую композицию.
2. Способ по п. 1, отличающийся тем, что, по меньшей мере, одна сопряженная кислота содержит алифатическую карбоновую кислоту, содержащую по меньшей мере три сопряженные углерод-углеродные двойные связи.
3. Способ по п. 1, отличающийся тем, что по меньшей мере одна сопряженная кислота получена из тунгового масла.
4. Способ по п. 1, отличающийся тем, что, по меньшей мере, один сложный эфир полиола сопряженной кислоты представляет собой сложный эфир глицерина.
5. Способ по п. 1, отличающийся тем, что по меньшей мере один сложный эфир полиола сопряженной кислоты представляет собой тунговое масло.
6. Способ по п. 1, отличающийся тем, что, по меньшей мере, один сложный эфир полиола сопряженной кислоты составляет от 0,01 до 5% мас. клеевой композиции.
7. Способ по п. 1, дополнительно включающий введение инициаторов окисления-восстановления в эмульсионный полимер вместе со сложным эфиром полиола сопряженной кислоты.
8. Способ по п. 1, отличающийся тем, что, по меньшей мере, один ненасыщенный мономер выбран из группы, состоящей из 2-этилгексилакрилата, этилакрилата, бутилакрилата, метил(мет)акрилата, акриловой кислоты и смесей двух или более из них.
9. Способ по п. 1, дополнительно включающий введение в эмульсионный полимер по меньшей мере одной добавки, выбранной из группы, состоящей из загустителя, нейтрализующего агента, пластификатора, вещества для повышения клейкости, усилителя адгезии и комбинаций двух или более из них.
10. Чувствительный к давлению клей на водной основе, содержащий композицию, приготовленную согласно п. 1.
RU2019105713A 2016-08-12 2016-08-12 Способ изготовления чувствительной к давлению клеевой композиции на водной основе RU2738816C2 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2016/094830 WO2018027891A1 (en) 2016-08-12 2016-08-12 Method for making water-based pressure sensitive adhesive compositions

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RU2019105713A3 RU2019105713A3 (ru) 2020-08-28
RU2738816C2 RU2738816C2 (ru) 2020-12-17

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US (1) US20190225844A1 (ru)
EP (1) EP3497177B1 (ru)
JP (2) JP6954991B2 (ru)
CN (1) CN109790436B (ru)
AR (1) AR109202A1 (ru)
BR (1) BR112019002572B1 (ru)
MX (1) MX2019001540A (ru)
RU (1) RU2738816C2 (ru)
TW (1) TWI812593B (ru)
WO (1) WO2018027891A1 (ru)

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WO2021173301A2 (en) * 2020-02-27 2021-09-02 Illinois Tool Works Inc. Heat transfer label and process for the use thereof

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JP7344261B2 (ja) 2023-09-13
AR109202A1 (es) 2018-11-07
MX2019001540A (es) 2019-05-09
BR112019002572A2 (pt) 2019-05-21
CN109790436B (zh) 2022-11-01
EP3497177A1 (en) 2019-06-19
JP6954991B2 (ja) 2021-10-27
WO2018027891A1 (en) 2018-02-15
TWI812593B (zh) 2023-08-21
JP2022003137A (ja) 2022-01-11
RU2738816C2 (ru) 2020-12-17
EP3497177A4 (en) 2020-01-29
EP3497177B1 (en) 2024-01-17
TW201809019A (zh) 2018-03-16
BR112019002572B1 (pt) 2022-04-19
JP2019528346A (ja) 2019-10-10
US20190225844A1 (en) 2019-07-25
RU2019105713A3 (ru) 2020-08-28
CN109790436A (zh) 2019-05-21

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