RU2018122476A - Водная полимерная эмульсия и полученная из нее водная адгезивная композиция - Google Patents
Водная полимерная эмульсия и полученная из нее водная адгезивная композиция Download PDFInfo
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- RU2018122476A RU2018122476A RU2018122476A RU2018122476A RU2018122476A RU 2018122476 A RU2018122476 A RU 2018122476A RU 2018122476 A RU2018122476 A RU 2018122476A RU 2018122476 A RU2018122476 A RU 2018122476A RU 2018122476 A RU2018122476 A RU 2018122476A
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- polymer emulsion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (17)
1. Водная полимерная эмульсия, содержащая:
i) в виде полимеризованных звеньев, от 20% до 80% сухой массы винилацетата в расчете на общую сухую массу полимера;
ii) в виде полимеризованных звеньев, от 20% до 80% сухой массы мономера α,β-этиленненасыщенного эфира карбоновой кислоты в расчете на общую сухую массу полимера;
iii) в виде полимеризованных звеньев, от 0,1% до 5% сухой массы мономерного стабилизатора в расчете на общую сухую массу полимера;
iv) от 0,05% до 1% сухой массы поверхностно-активного вещества в расчете на общую сухую массу полимера,
при этом вязкость указанной водной полимерной эмульсии составляет менее 100 сПз.
2. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанная вязкость водной полимерной эмульсии составляет менее 50 сПз.
3. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанная вязкость водной полимерной эмульсии составляет менее 30 сПз.
4. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанная водная полимерная эмульсия содержит от 0,05% до 0,5% сухой массы поверхностно-активного вещества в расчете на общую сухую массу полимера.
5. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанное поверхностно-активное вещество представляет собой комбинацию анионного поверхностно-активного вещества и неионного поверхностно-активного вещества, при этом мольное соотношение ионного поверхностно-активного вещества к мольному соотношению неионного поверхностно-активного вещества составляет от 0,5 до 20.
6. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанная водная полимерная эмульсия не содержит защитный коллоид.
7. Водная полимерная эмульсия по п. 1, отличающаяся тем, что температура стеклования указанной водной полимерной эмульсии составляет от 8ºC до -43ºC.
8. Водная полимерная эмульсия по п. 1, отличающаяся тем, что температура стеклования указанной водной полимерной эмульсии составляет от -23ºC до -30ºC.
9. Водная полимерная эмульсия по п. 1, отличающаяся тем, что размер частиц в указанной водной полимерной эмульсии составляет от 150 нм до 500 нм.
10. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанный мономер α,β-этиленненасыщенного эфира карбоновой кислоты представляет собой мономер (мет)акрилового эфира.
11. Водная полимерная эмульсия по п. 1, отличающаяся тем, что указанная водная полимерная эмульсия дополнительно содержит мономер сложного винилового эфира, отличный от винилацетата.
12. Водная адгезивная композиция, содержащая водную полимерную эмульсию по любому из пп. 1 - 11.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2015/096614 WO2017096514A1 (en) | 2015-12-08 | 2015-12-08 | An aqueous polymer emulsion and an aqueous adhesive composition formed therefrom |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2018122476A true RU2018122476A (ru) | 2019-12-20 |
| RU2018122476A3 RU2018122476A3 (ru) | 2019-12-20 |
| RU2754556C2 RU2754556C2 (ru) | 2021-09-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2018122476A RU2754556C2 (ru) | 2015-12-08 | 2015-12-08 | Водная полимерная эмульсия и полученная из нее водная адгезивная композиция |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10975273B2 (ru) |
| EP (1) | EP3387029B1 (ru) |
| JP (1) | JP6849679B2 (ru) |
| CN (1) | CN108290986B (ru) |
| AR (1) | AR106828A1 (ru) |
| BR (1) | BR112018009945B1 (ru) |
| MX (1) | MX2018006262A (ru) |
| RU (1) | RU2754556C2 (ru) |
| TW (1) | TWI791421B (ru) |
| WO (1) | WO2017096514A1 (ru) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019115050A1 (en) * | 2017-12-14 | 2019-06-20 | Amcor Flexibles Italia S.R.L. | Alkaline resistant multilayer structure |
| CN113072663A (zh) * | 2021-03-31 | 2021-07-06 | 海南必凯水性新材料有限公司 | 一种纸张用的热封型丙烯酸乳液及其制备方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL131848C (ru) * | 1963-11-20 | 1900-01-01 | ||
| DE2256154C3 (de) * | 1972-11-16 | 1984-10-04 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von wäßrigen Dispersionen von Polymerisaten monoolefinisch ungesättigter Carbonsäureester |
| US5037700A (en) | 1981-01-19 | 1991-08-06 | National Starch And Chemical Investment Holding Corporation | Flexible laminates |
| US5201948A (en) * | 1991-05-24 | 1993-04-13 | Rohm And Haas Company | Method for improving scrub resistance |
| US6251213B1 (en) | 1992-10-01 | 2001-06-26 | Rohm And Haas Company | Laminating construction adhesive compositions with improved performance |
| US6087425A (en) | 1994-02-18 | 2000-07-11 | Rohm And Haas Company | Laminating adhesive composition |
| DE19709254A1 (de) * | 1997-03-06 | 1998-09-10 | Wacker Chemie Gmbh | Verfahren zur Herstellung von schutzkolloidfreien Dispersionen und Dispersionspulvern |
| RU2315062C1 (ru) * | 2006-09-18 | 2008-01-20 | Федеральное государственное унитарное предприятие "Научно-исследовательский институт химии и технологии полимеров имени акад. В.А. Каргина с опытным заводом" (ФГУП "НИИ полимеров") | Способ получения водной дисперсии акрилового сополимера для клеев, чувствительных к давлению |
| CN102037065B (zh) * | 2007-08-10 | 2015-01-07 | 埃瑟克斯化学有限责任公司 | 乳液聚合中的苯乙烯酚乙氧基化物 |
| ES2361642T3 (es) * | 2008-06-23 | 2011-06-20 | Wacker Chemie Ag | Dispersión polimérica en emulsión resistente al calor. |
| CN101585894B (zh) * | 2009-07-03 | 2010-12-01 | 四川大学 | 一种纳米醋酸乙烯-丙烯酸酯共聚乳液的制备方法 |
| WO2011009800A1 (en) | 2009-07-21 | 2011-01-27 | Basf Se | Film-to-film laminate, made by using an aqueous polymer dispersion as adhesive agent |
| CN102471632B (zh) * | 2009-07-22 | 2014-12-03 | 巴斯夫欧洲公司 | 用作具有改善的火行为的灰泥和涂料的粘合剂的水性聚合物分散体 |
| ES2422272T3 (es) | 2010-11-18 | 2013-09-10 | Cognis Ip Man Gmbh | Composiciones acuosas de baja viscosidad |
| CN103059211B (zh) * | 2011-10-18 | 2015-06-24 | 中国石油化工集团公司 | 一种醋酸乙烯-丙烯酸酯共聚乳液及其合成方法和用途 |
| CN102559104B (zh) | 2011-12-26 | 2013-10-30 | 北京高盟新材料股份有限公司 | 水性凹印镀铝复合胶及其制备方法 |
| CN103435736B (zh) * | 2013-08-22 | 2016-03-02 | 华南理工大学 | 一种用于水性膨胀型防火涂料的乳液及其制备方法 |
| CN106460342A (zh) | 2014-04-11 | 2017-02-22 | 巴斯夫欧洲公司 | 含有乙酸乙烯酯和丙烯酸酯单体的纸张用聚合物水分散体 |
| EP3129439B1 (en) | 2014-04-11 | 2023-08-16 | Basf Se | Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative |
| US9688800B2 (en) | 2014-07-07 | 2017-06-27 | Columbia Insurance Company | Sequentially polymerized hybrid latex |
| CN105086886B (zh) * | 2015-09-23 | 2017-05-10 | 广州宏昌胶粘带厂 | 单组分自交联型耐高温乳液压敏胶及其制备方法和应用 |
-
2015
- 2015-12-08 CN CN201580084758.0A patent/CN108290986B/zh active Active
- 2015-12-08 MX MX2018006262A patent/MX2018006262A/es unknown
- 2015-12-08 US US15/767,004 patent/US10975273B2/en active Active
- 2015-12-08 JP JP2018524408A patent/JP6849679B2/ja active Active
- 2015-12-08 WO PCT/CN2015/096614 patent/WO2017096514A1/en active Application Filing
- 2015-12-08 EP EP15909989.4A patent/EP3387029B1/en active Active
- 2015-12-08 RU RU2018122476A patent/RU2754556C2/ru active
- 2015-12-08 BR BR112018009945-7A patent/BR112018009945B1/pt active IP Right Grant
-
2016
- 2016-11-16 TW TW105137520A patent/TWI791421B/zh active
- 2016-11-25 AR ARP160103626A patent/AR106828A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| TWI791421B (zh) | 2023-02-11 |
| TW201720899A (zh) | 2017-06-16 |
| JP6849679B2 (ja) | 2021-03-24 |
| WO2017096514A1 (en) | 2017-06-15 |
| RU2754556C2 (ru) | 2021-09-03 |
| EP3387029B1 (en) | 2021-10-20 |
| US10975273B2 (en) | 2021-04-13 |
| CN108290986A (zh) | 2018-07-17 |
| AR106828A1 (es) | 2018-02-21 |
| BR112018009945B1 (pt) | 2022-01-04 |
| US20180298247A1 (en) | 2018-10-18 |
| MX2018006262A (es) | 2018-11-09 |
| BR112018009945A2 (pt) | 2018-11-06 |
| CN108290986B (zh) | 2023-11-28 |
| JP2019504132A (ja) | 2019-02-14 |
| EP3387029A4 (en) | 2019-07-03 |
| EP3387029A1 (en) | 2018-10-17 |
| RU2018122476A3 (ru) | 2019-12-20 |
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