BR112018009945A2 - uma emulsão aquosa de polímero e uma composição adesiva aquosa formada da mesma - Google Patents

uma emulsão aquosa de polímero e uma composição adesiva aquosa formada da mesma

Info

Publication number
BR112018009945A2
BR112018009945A2 BR112018009945A BR112018009945A BR112018009945A2 BR 112018009945 A2 BR112018009945 A2 BR 112018009945A2 BR 112018009945 A BR112018009945 A BR 112018009945A BR 112018009945 A BR112018009945 A BR 112018009945A BR 112018009945 A2 BR112018009945 A2 BR 112018009945A2
Authority
BR
Brazil
Prior art keywords
dry weight
aqueous
polymer emulsion
adhesive composition
polymer
Prior art date
Application number
BR112018009945A
Other languages
English (en)
Other versions
BR112018009945B1 (pt
Inventor
Pan Yuanjia
Qu Zhaohui
Original Assignee
Dow Global Technologies Llc
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc, Rohm & Haas filed Critical Dow Global Technologies Llc
Publication of BR112018009945A2 publication Critical patent/BR112018009945A2/pt
Publication of BR112018009945B1 publication Critical patent/BR112018009945B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26Emulsion polymerisation with the aid of emulsifying agents anionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/30Emulsion polymerisation with the aid of emulsifying agents non-ionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02Esters of monocarboxylic acids
    • C08F218/04Vinyl esters
    • C08F218/08Vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04Homopolymers or copolymers of vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10Homopolymers or copolymers of methacrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

uma emulsão aquosa de polímero compreendendo: i) como unidades polimerizadas, de 20% a 80% em peso seco, com base no peso seco total do polímero, de vinil acetato; ii) como unidades polimerizadas, de 20% a 80% em peso seco, com base no peso seco total do polímero, de um de um monômero ¿,¿- etilenicamente insaturado de éster carboxílico; iii) como unidades polimerizadas, de 0,1% a 5% em peso seco, com base no peso seco total do polímero, de um monômero estabilizador; iv) de 0,05% a 1% em peso seco, com base no peso seco total do polímero, de um tensoativo, em que a referida emulsão aquosa de polímero tem uma viscosidadede menos de 100cps. uma composição adesiva aquosa compreendendo a referida emulsão aquosa de polímero.
BR112018009945-7A 2015-12-08 2015-12-08 Emulsão aquosa de polímero e composição adesiva aquosa BR112018009945B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2015/096614 WO2017096514A1 (en) 2015-12-08 2015-12-08 An aqueous polymer emulsion and an aqueous adhesive composition formed therefrom

Publications (2)

Publication Number Publication Date
BR112018009945A2 true BR112018009945A2 (pt) 2018-11-06
BR112018009945B1 BR112018009945B1 (pt) 2022-01-04

Family

ID=59012531

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018009945-7A BR112018009945B1 (pt) 2015-12-08 2015-12-08 Emulsão aquosa de polímero e composição adesiva aquosa

Country Status (10)

Country Link
US (1) US10975273B2 (pt)
EP (1) EP3387029B1 (pt)
JP (1) JP6849679B2 (pt)
CN (1) CN108290986B (pt)
AR (1) AR106828A1 (pt)
BR (1) BR112018009945B1 (pt)
MX (1) MX2018006262A (pt)
RU (1) RU2754556C2 (pt)
TW (1) TWI791421B (pt)
WO (1) WO2017096514A1 (pt)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3723978A1 (en) * 2017-12-14 2020-10-21 Amcor Flexibles Italia S.R.L. Alkaline resistant multilayer structure
CN113072663A (zh) * 2021-03-31 2021-07-06 海南必凯水性新材料有限公司 一种纸张用的热封型丙烯酸乳液及其制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
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NL131848C (pt) * 1963-11-20 1900-01-01
DE2256154C3 (de) * 1972-11-16 1984-10-04 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von wäßrigen Dispersionen von Polymerisaten monoolefinisch ungesättigter Carbonsäureester
US5037700A (en) 1981-01-19 1991-08-06 National Starch And Chemical Investment Holding Corporation Flexible laminates
US5201948A (en) 1991-05-24 1993-04-13 Rohm And Haas Company Method for improving scrub resistance
US6251213B1 (en) 1992-10-01 2001-06-26 Rohm And Haas Company Laminating construction adhesive compositions with improved performance
US6087425A (en) 1994-02-18 2000-07-11 Rohm And Haas Company Laminating adhesive composition
DE19709254A1 (de) * 1997-03-06 1998-09-10 Wacker Chemie Gmbh Verfahren zur Herstellung von schutzkolloidfreien Dispersionen und Dispersionspulvern
RU2315062C1 (ru) * 2006-09-18 2008-01-20 Федеральное государственное унитарное предприятие "Научно-исследовательский институт химии и технологии полимеров имени акад. В.А. Каргина с опытным заводом" (ФГУП "НИИ полимеров") Способ получения водной дисперсии акрилового сополимера для клеев, чувствительных к давлению
CA2695239C (en) * 2007-08-10 2017-01-24 Lawrence C. Davis Styrenated phenol ethoxylates in emulsion polymerization
ES2361642T3 (es) * 2008-06-23 2011-06-20 Wacker Chemie Ag Dispersión polimérica en emulsión resistente al calor.
CN101585894B (zh) * 2009-07-03 2010-12-01 四川大学 一种纳米醋酸乙烯-丙烯酸酯共聚乳液的制备方法
WO2011009800A1 (en) 2009-07-21 2011-01-27 Basf Se Film-to-film laminate, made by using an aqueous polymer dispersion as adhesive agent
CN102471632B (zh) * 2009-07-22 2014-12-03 巴斯夫欧洲公司 用作具有改善的火行为的灰泥和涂料的粘合剂的水性聚合物分散体
ES2422272T3 (es) * 2010-11-18 2013-09-10 Cognis Ip Man Gmbh Composiciones acuosas de baja viscosidad
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Also Published As

Publication number Publication date
TW201720899A (zh) 2017-06-16
EP3387029B1 (en) 2021-10-20
AR106828A1 (es) 2018-02-21
EP3387029A1 (en) 2018-10-17
RU2754556C2 (ru) 2021-09-03
CN108290986B (zh) 2023-11-28
EP3387029A4 (en) 2019-07-03
BR112018009945B1 (pt) 2022-01-04
MX2018006262A (es) 2018-11-09
US10975273B2 (en) 2021-04-13
WO2017096514A1 (en) 2017-06-15
JP6849679B2 (ja) 2021-03-24
US20180298247A1 (en) 2018-10-18
RU2018122476A (ru) 2019-12-20
JP2019504132A (ja) 2019-02-14
TWI791421B (zh) 2023-02-11
RU2018122476A3 (pt) 2019-12-20
CN108290986A (zh) 2018-07-17

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Legal Events

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B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 08/12/2015, OBSERVADAS AS CONDICOES LEGAIS.